Timothy M. Champagne, Ph.D.
Affiliations: | 2006 | University of California, Irvine, Irvine, CA |
Area:
Inorganic and Organometallic Chemistry; Rare Earth, Actinide, and Bismuth Metal ChemistryGoogle:
"Timothy Champagne"Mean distance: 8.39 | S | N | B | C | P |
Parents
Sign in to add mentor| William J. Evans | grad student | 2006 | UC Irvine | |
| (Expanding the limits of lanthanide metallocenes to advance catalysis, inert bond activation, redox, and heterocyclic chemistry.) | ||||
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Publications
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| Evans WJ, Montalvo E, Champagne TM, et al. (2009) Synthetic diversity in the formation of triazoles from nitriles and diazo compounds using metallocenes of electropositive metals Organometallics. 28: 2897-2903 |
| Evans WJ, Walensky JR, Champagne TM, et al. (2009) Displacement, reduction, and ligand redistribution reactivity of the cationic mono-C5Me5 Ln2+ complexes (C5Me5)Ln(BPh4) (Ln = Sm, Yb) Journal of Organometallic Chemistry. 694: 1238-1243 |
| Evans WJ, Schmiege BM, Lorenz SE, et al. (2008) Reductive reactivity of the organolanthanide hydrides, [(C5Me5)2LnH]x, leads to ansa-allyl cyclopentadienyl (eta(5)-C5Me4CH2-C5Me4CH2-eta(3))2- and trianionic cyclooctatetraenyl (C8H7)3- ligands. Journal of the American Chemical Society. 130: 8555-63 |
| Evans WJ, Montalvo E, Champagne TM, et al. (2008) Organolanthanide-based synthesis of 1,2,3-triazoles from nitriles and diazo compounds. Journal of the American Chemical Society. 130: 16-7 |
| Evans WJ, Montalvo E, Champagne TM, et al. (2008) Diazomethane insertion into lanthanide- and yttrium-C(allyl) bonds to form the η2-hydrazonato complexes (C5Me5) 2Ln[η2(N/N′)-RNN=CHSiMe3] (R = C 3H5) Organometallics. 27: 3582-3586 |
| Evans WJ, Montalvo E, Champagne TM, et al. (2008) Organolanthanide-based synthesis of 1,2,3-triazoles from nitriles and diazo compounds Journal of the American Chemical Society. 130: 16-17 |
| Evans WJ, Champagne TM, Ziller JW. (2007) Synthesis and reactivity of mono(pentamethylcyclopentadienyl) tetraphenylborate lanthanide complexes of ytterbium and samarium: Tris(ring) precursors to (C5Me5)Ln moieties Organometallics. 26: 1204-1211 |
| Evans WJ, Champagne TM, Ziller JW, et al. (2006) Planar trimethylenemethane dianion chemistry of lanthanide metallocenes: synthesis, structure, density functional theory analysis, and reactivity of [(C5Me5)2Ln]2[mu-eta3:eta3-C(CH2)(3] Complexes. Journal of the American Chemical Society. 128: 16178-89 |
| Evans WJ, Champagne TM, Ziller JW. (2006) Organolutetium vinyl and tuck-over complexes via C-H bond activation. Journal of the American Chemical Society. 128: 14270-1 |
| Evans WJ, Davis BL, Champagne TM, et al. (2006) C-H bond activation through steric crowding of normally inert ligands in the sterically crowded gadolinium and yttrium (C5Me5)3M complexes. Proceedings of the National Academy of Sciences of the United States of America. 103: 12678-83 |