Benjamin M. Schmiege, Ph.D.

Affiliations: 
2011 Chemistry - Ph.D. University of California, Irvine, Irvine, CA 
Area:
Inorganic and Organometallic Chemistry; Rare Earth, Actinide, and Bismuth Metal Chemistry
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"Benjamin Schmiege"
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William J. Evans grad student 2011 UC Irvine
 (Lanthanide Hydride Reduction Chemistry Including New Routes to Lanthanide Metallocene Dinitrogen Complexes.)
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Publications

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Schmiege BM, Fieser ME, Ziller JW, et al. (2012) Reactivity of the Y 3+ tuck-over hydride complex, (C 5Me 5) 2Y(μ-H)(μ-CH 2C 5Me 4)Y(C 5Me 5) Organometallics. 31: 5591-5598
Lorenz V, Schmiege BM, Hrib CG, et al. (2011) Unprecedented bending and rearrangement of f-element sandwich complexes induced by superbulky cyclooctatetraenide ligands. Journal of the American Chemical Society. 133: 1257-9
Schmiege BM, Ziller JW, Evans WJ. (2010) Reduction of dinitrogen with an yttrium metallocene hydride precursor, [(C5Me5)2YH]2. Inorganic Chemistry. 49: 10506-11
Lorenz SE, Schmiege BM, Lee DS, et al. (2010) Synthesis and reactivity of bis(tetramethylcyclopentadienyl) yttrium metallocenes including the reduction of Me(3)SiN(3) to [(Me(3)Si)(2)N](-) with [(C(5)Me(4)H)(2)Y(THF)](2)(mu-eta(2):eta(2)-N(2)). Inorganic Chemistry. 49: 6655-63
Evans WJ, Schmiege BM, Lorenz SE, et al. (2008) Reductive reactivity of the organolanthanide hydrides, [(C5Me5)2LnH]x, leads to ansa-allyl cyclopentadienyl (eta(5)-C5Me4CH2-C5Me4CH2-eta(3))2- and trianionic cyclooctatetraenyl (C8H7)3- ligands. Journal of the American Chemical Society. 130: 8555-63
Schmiege BM, Carney MJ, Small BL, et al. (2007) Alternatives to pyridinediimine ligands: syntheses and structures of metal complexes supported by donor-modified alpha-diimine ligands. Dalton Transactions (Cambridge, England : 2003). 2547-62
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