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Dinesh V. Vidhani, Ph.D.

Affiliations: 
2010 Florida State University, Tallahassee, FL, United States 
Area:
Organic Chemistry
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Marie E. Krafft grad student 2010 Florida State
 (Adventures in gold-catalyzed cascade reactions and rearrangements.)

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Publications

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Vidhani DV, Alabugin IV. (2019) Controlled Evolution of the Cope Rearrangement: Transition from Concerted to Interrupted and Aborted Pericyclic Reactions Regulated by a Switch Built from an Intramolecular Frustrated Lewis Pair. The Journal of Organic Chemistry
Vidhani DV, Krafft ME, Alabugin IV. (2016) Gold(I)-catalyzed allenyl Cope rearrangement: evolution from asynchronicity to trappable intermediates assisted by stereoelectronic switching. Journal of the American Chemical Society
Vidhani DV, Krafft ME. (2015) Proximity effect: insight into the fundamental forces governing chemical reactivity of aromatic systems. The Journal of Physical Chemistry. A. 119: 3141-6
Vidhani DV, Krafft ME, Alabugin IV. (2014) Rh(I)-catalyzed transformation of propargyl vinyl ethers into (E,Z)-dienals: stereoelectronic role of trans effect in a metal-mediated pericyclic process and a shift from homogeneous to heterogeneous catalysis during a one-pot reaction. The Journal of Organic Chemistry. 79: 352-64
Cran J, Vidhani D, Krafft M. (2014) Copper-Catalyzed N-tert-Butylation of Aromatic Amines under Mild Condi­tions Using tert-Butyl 2,2,2-Trichloroacetimidate Synlett. 25: 1550-1554
Cran JW, Vidhani DV, Krafft ME. (2014) ChemInform Abstract: Copper-Catalyzed N-tert-Butylation of Aromatic Amines under Mild Conditions Using tert-Butyl 2,2,2-Trichloroacetimidate. Cheminform. 45: no-no
Vidhani DV, Krafft ME, Alabugin IV. (2013) Stereocontrolled synthesis of (E,Z)-dienals via tandem Rh(I)-catalyzed rearrangement of propargyl vinyl ethers. Organic Letters. 15: 4462-5
Vidhani DV, Cran JW, Krafft ME, et al. (2013) Overriding the alkynophilicity of gold: catalytic pathways from higher energy Au(I)-substrate complexes and reactant deactivation via unproductive complexation in the gold(I)-catalyzed propargyl Claisen rearrangement. Organic & Biomolecular Chemistry. 11: 1624-30
Vidhani DV, Cran JW, Krafft ME, et al. (2013) Gold(I)-catalyzed Claisen rearrangement of allenyl vinyl ethers: missing transition states revealed through evolution of aromaticity, Au(I) as an oxophilic Lewis acid, and lower energy barriers from a high energy complex. The Journal of Organic Chemistry. 78: 2059-73
Krafft ME, Vidhani DV, Cran JW. (2012) ChemInform Abstract: Tributyltin Hydride as a Selective Reducing Agent for Aryl Enones. Cheminform. 43: no-no
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