Rachel Koren Behan
Affiliations: | 2008 | Pennsylvania State University, State College, PA, United States |
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Sign in to add mentor| Michael Thomas Green | grad student | 2008 | Penn State | |
| (Spectroscopic characterization of high-valent intermediates in cytochrome P450s and other heme enzymes.) | ||||
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| Yosca TH, Behan RK, Krest CM, et al. (2014) Setting an upper limit on the myoglobin iron(IV)hydroxide pK(a): insight into axial ligand tuning in heme protein catalysis. Journal of the American Chemical Society. 136: 9124-31 |
| Yosca TH, Rittle J, Krest CM, et al. (2013) Iron(IV)hydroxide pK(a) and the role of thiolate ligation in C-H bond activation by cytochrome P450. Science (New York, N.Y.). 342: 825-9 |
| Behan RK, Lippard SJ. (2010) The aging-associated enzyme CLK-1 is a member of the carboxylate-bridged diiron family of proteins Biochemistry. 49: 9679-9681 |
| Song WJ, McCormick MS, Behan RK, et al. (2010) Active site threonine facilitates proton transfer during dioxygen activation at the diiron center of toluene/o-xylene monooxygenase hydroxylase. Journal of the American Chemical Society. 132: 13582-5 |
| Song WJ, Behan RK, Naik SG, et al. (2009) Characterization of a peroxodiiron(III) intermediate in the T201S variant of toluene/o-xylene monooxygenase hydroxylase from Pseudomonas sp. OX1. Journal of the American Chemical Society. 131: 6074-5 |
| Behan RK, Hoffart LM, Stone KL, et al. (2007) Reaction of cytochrome P450BM3 and peroxynitrite yields nitrosyl complex. Journal of the American Chemical Society. 129: 5855-9 |
| Hendrich MP, Gunderson W, Behan RK, et al. (2006) On the feasibility of N2 fixation via a single-site FeI/FeIV cycle: Spectroscopic studies of FeI(N2)FeI, FeIV[triple bond]N, and related species. Proceedings of the National Academy of Sciences of the United States of America. 103: 17107-12 |
| Behan RK, Hoffart LM, Stone KL, et al. (2006) Evidence for basic ferryls in cytochromes P450. Journal of the American Chemical Society. 128: 11471-4 |
| Stone KL, Behan RK, Green MT. (2006) Resonance Raman spectroscopy of chloroperoxidase compound II provides direct evidence for the existence of an iron(IV)-hydroxide Proceedings of the National Academy of Sciences of the United States of America. 103: 12307-12310 |
| Parsell TH, Behan RK, Green MT, et al. (2006) Preparation and properties of a monomeric Mn(IV)-oxo complex. Journal of the American Chemical Society. 128: 8728-9 |