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Benjamin J. Lear, Ph.D. - Publications

Affiliations: 
1997-2002 Biochemistry University of California, Davis, Davis, CA 
 2002-2007 Chemistry University of California, San Diego, La Jolla, CA 
 2007-2010 Chemistry and Biochemistry Ohio State University, Columbus, Columbus, OH 
 2010- Chemistry Pennsylvania State University, State College, PA, United States 
Area:
Inorganic, materials, and physical chemistry: electron transfer, catalysis, fixation and utilization of carbon dioxide.
Website:
http://research.chem.psu.edu/bulgroup/
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46 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Šrut A, Lear BJ, Krewald V. The Marcus dimension: identifying the nuclear coordinate for electron transfer from calculations. Chemical Science. 14: 9213-9225. PMID 37655015 DOI: 10.1039/d3sc01402a  0.343
2022 Litak NP, Mawby LM, Lear BJ. Surface Chemistry Controls the Density of States in Metallic Nanoparticles. Acs Nano. 16: 4479-4486. PMID 35274922 DOI: 10.1021/acsnano.1c10877  0.327
2021 Cruz SS, Tanygin V, Lear BJ. Asymmetries in the Electronic Properties of Spheroidal Metallic Nanoparticles, Revealed by Conduction Electron Spin Resonance and Surface Plasmon Resonance. Acs Nano. PMID 33646754 DOI: 10.1021/acsnano.0c08515  0.733
2019 Widstrom AL, Lear BJ. Structural and solvent control over activation parameters for a pair of retro Diels-Alder reactions. Scientific Reports. 9: 18267. PMID 31797942 DOI: 10.1038/S41598-019-54156-4  0.767
2019 Van Burns EN, Lear BJ. Controlled Rapid Formation of Polyurethane at 700 K: Thermodynamic and Kinetic Consequences of Extreme Photothermal Heating The Journal of Physical Chemistry C. 123: 14774-14780. DOI: 10.1021/Acs.Jpcc.9B01663  0.344
2019 Widstrom AL, Lear BJ. Nanoscale heat for organic transformations: a photothermally driven retro Diels–Alder reaction Applied Nanoscience. 10: 819-825. DOI: 10.1007/S13204-019-01175-2  0.777
2018 Johnson RJG, Schultz JD, Lear BJ. Photothermal Effectiveness of Magnetite Nanoparticles: Dependence upon Particle Size Probed by Experiment and Simulation. Molecules (Basel, Switzerland). 23. PMID 29786641 DOI: 10.3390/Molecules23051234  0.318
2017 Joseph Fortenbaugh R, Lear BJ. On-demand curing of polydimethylsiloxane (PDMS) using the photothermal effect of gold nanoparticles. Nanoscale. PMID 28513705 DOI: 10.1039/C7Nr01423F  0.349
2016 Cirri A, Silakov A, Jensen L, Lear BJ. Chain Length and Solvent Control over the Electronic Properties of Alkanethiolate-Protected Gold Nanoparticles at the Molecule-to-Metal Transition. Journal of the American Chemical Society. 138: 15987-15993. PMID 27960314 DOI: 10.1021/Jacs.6B09586  0.819
2016 Cirri A, Silakov A, Jensen L, Lear BJ. Probing ligand-induced modulation of metallic states in small gold nanoparticles using conduction electron spin resonance. Physical Chemistry Chemical Physics : Pccp. 18: 25443-25451. PMID 27711383 DOI: 10.1039/C6Cp02205G  0.818
2016 Kennedy SR, Kozar MN, Yennawar HP, Lear BJ. Steady-State Spectroscopic Analysis of Proton-Dependent Electron Transfer on Pyrazine-Appended Metal Dithiolenes [Ni(pdt)2], [Pd(pdt)2], and [Pt(pdt)2] (pdt = 2,3-Pyrazinedithiol). Inorganic Chemistry. PMID 27500686 DOI: 10.1021/Acs.Inorgchem.6B01065  0.741
2016 Kennedy SR, Goyal P, Kozar MN, Yennawar HP, Hammes-Schiffer S, Lear BJ. Effect of Protonation upon Electronic Coupling in the Mixed Valence and Mixed Protonated Complex, [Ni(2,3-pyrazinedithiol)2]. Inorganic Chemistry. PMID 26812117 DOI: 10.1021/Acs.Inorgchem.5B02035  0.741
2016 Cirri A, Silakov A, Jensen L, Lear BJ. Probing ligand-induced modulation of metallic states in small gold nanoparticles using conduction electron spin resonance Physical Chemistry Chemical Physics. 18: 25443-25451. DOI: 10.1039/c6cp02205g  0.816
2016 Kennedy SR, Kozar MN, Yennawar HP, Lear BJ. Synthesis and characterization of the gold dithiolene monoanion, (Bu4N)[Au(pdt = 2,3-pyrazinedithiol)2] Polyhedron. 103: 100-104. DOI: 10.1016/J.Poly.2015.09.023  0.7
2015 Haas KM, Lear BJ. Billion-fold rate enhancement of urethane polymerization the photothermal effect of plasmonic gold nanoparticles. Chemical Science. 6: 6462-6467. PMID 30090265 DOI: 10.1039/C5Sc02149A  0.639
2015 Cirri A, Silakov A, Lear BJ. Ligand Control over the Electronic Properties within the Metallic Core of Gold Nanoparticles. Angewandte Chemie (International Ed. in English). 54: 11750-3. PMID 26274014 DOI: 10.1002/Anie.201505933  0.821
2015 Kim J, Silakov A, Yennawar HP, Lear BJ. Structural, Electronic, and Magnetic Characterization of a Dinuclear Zinc Complex Containing TCNQ(-) and a μ-[TCNQ-TCNQ](2-) Ligand. Inorganic Chemistry. 54: 6072-4. PMID 26085029 DOI: 10.1021/Acs.Inorgchem.5B00808  0.69
2015 Giordano AN, Lear BJ. Comparing the energetic and dynamic contributions of solvent to very low barrier isomerization using dynamic steady-state vibrational spectroscopy. The Journal of Physical Chemistry. A. 119: 3545-55. PMID 25811244 DOI: 10.1021/Acs.Jpca.5B00510  0.583
2015 Henderson J, Glover SD, Lear BJ, Walker D, Winkler JR, Gray HB, Kubiak CP. Electron-Transfer Reactions of Electronically Excited Zinc Tetraphenylporphyrin with Multinuclear Ruthenium Complexes. The Journal of Physical Chemistry. B. 119: 7473-9. PMID 25494985 DOI: 10.1021/Jp511213P  0.792
2015 Johnson RJ, Haas KM, Lear BJ. Fe3O4 nanoparticles as robust photothermal agents for driving high barrier reactions under ambient conditions. Chemical Communications (Cambridge, England). 51: 417-20. PMID 25406790 DOI: 10.1039/C4Cc07966C  0.701
2015 Haas KM, Lear BJ. Billion-fold rate enhancement of urethane polymerization via the photothermal effect of plasmonic gold nanoparticles Chemical Science. 6: 6462-6467. DOI: 10.1039/c5sc02149a  0.594
2015 Kim J, Dolgos MR, Lear BJ. Isolation and Chemical Transformations Involving a Reactive Intermediate of MOF-5 Crystal Growth and Design. 15: 4781-4786. DOI: 10.1021/Acs.Cgd.5B00411  0.635
2014 Alberding BG, Lear BJ. Concentration-dependent dynamics of hydrogen bonding between acetonitrile and methanol as determined by 1D vibrational spectroscopy. The Journal of Physical Chemistry. A. 118: 4363-71. PMID 24911870 DOI: 10.1021/Jp4110147  0.72
2014 Bischof AM, Zhang S, Meyer TY, Lear BJ. Quantitative assessment of the connection between steric hindrance and electronic coupling in 2,5-Bis(alkoxy)benzene-based mixed-valence dimers Journal of Physical Chemistry C. 118: 12693-12699. DOI: 10.1021/Jp504887S  0.439
2013 Giordano AN, Lear BJ. Solvent versus temperature control over the infrared band shape and position in Fe(CO)3(η(4)-ligand) complexes. The Journal of Physical Chemistry. A. 117: 12313-9. PMID 24175634 DOI: 10.1021/Jp407955X  0.6
2013 Kim J, Yennawar HP, Lear BJ. Synthesis and characterization of ruthenium polypyridyl complexes with hydroxypyridine derivatives: effect of protonation and ethylation at the pyridyl nitrogen. Dalton Transactions (Cambridge, England : 2003). 42: 15656-62. PMID 24045324 DOI: 10.1039/C3Dt52094C  0.724
2013 Haas KM, Lear BJ. Degradation of polypropylene carbonate through plasmonic heating. Nanoscale. 5: 5247-51. PMID 23657671 DOI: 10.1039/C3Nr01498C  0.627
2013 Giordano AN, Morton SM, Jensen L, Lear BJ. Direct test of the equivalency of dynamic IR and dynamic raman spectroscopies as techniques for observing ultrafast molecular dynamics. The Journal of Physical Chemistry. A. 117: 2067-74. PMID 23402708 DOI: 10.1021/Jp400696F  0.585
2013 Tunc AV, Giordano AN, Ecker B, Da Como E, Lear BJ, Von Hauff E. Silica nanoparticles for enhanced carrier transport in polymer-based short channel transistors Journal of Physical Chemistry C. 117: 22613-22618. DOI: 10.1021/Jp4088173  0.539
2011 Alberding BG, Chisholm MH, Lear BJ, Naseri V, Reed CR. Synthesis and characterization of trans-M2(T(i)PB)2(O2C-CH=CH-2-C4H3S)2 (M = Mo or W) and comments on the metal-to-ligand charge transfer bands in MM quadruply bonded complexes of the type trans-M2(T(i)PB)2L2, where T(i)PB = 2,4,6-triisopropylbenzoate and L = π-accepting carboxylate ligand. Dalton Transactions (Cambridge, England : 2003). 40: 10658-63. PMID 21931912 DOI: 10.1039/C1Dt10788G  0.758
2011 Chisholm MH, Lear BJ. M2δ to ligand π-conjugation: testbeds for current theories of mixed valence in ground and photoexcited states of molecular systems. Chemical Society Reviews. 40: 5254-65. PMID 21720650 DOI: 10.1039/C1Cs15061H  0.514
2011 Bunting P, Chisholm MH, Gallucci JC, Lear BJ. Extent of M2 δ to ligand π-conjugation in neutral and mixed valence states of bis(4-isonicotinate)-bis(2,4,6-triisopropylbenzoate) dimetal complexes (MM), where M = Mo or W, and their adducts with tris(pentafluorophenyl)boron. Journal of the American Chemical Society. 133: 5873-81. PMID 21434631 DOI: 10.1021/Ja109522B  0.486
2011 Alberding BG, Chisholm MH, Lear BJ, Naseri V, Reed CR. Synthesis and characterization of trans-M2(TiPB) 2(O2C-CHCH-2-C4H3S)2 (M = Mo or W) and comments on the metal-to-ligand charge transfer bands in MM quadruply bonded complexes of the type trans-M2(TiPB) 2L2, where TiPB = 2,4,6-triisopropylbenzoate Dalton Transactions. 40: 10658-10663. DOI: 10.1039/c1dt10788g  0.741
2011 Chisholm MH, Lear BJ. M2δ to ligand π-conjugation: Testbeds for current theories of mixed valence in ground and photoexcited states of molecular systems Chemical Society Reviews. 40: 5254-5265. DOI: 10.1039/c1cs15061h  0.391
2011 Bunting P, Chisholm MH, Gallucci JC, Lear BJ. Extent of M2 δ to ligand π-conjugation in neutral and mixed valence states of bis(4-isonicotinate)-bis(2,4,6-triisopropylbenzoate) dimetal complexes (MM), where M = Mo or W, and their adducts with tris(pentafluorophenyl)boron Journal of the American Chemical Society. 133: 5873-5881. DOI: 10.1021/ja109522b  0.414
2010 Chisholm MH, Lear BJ, Moscatelli A, Peteanu LA. Electroabsorption of dimers containing MM (M = Mo, W) quadruply bonded units: insights into the electronic structure of neutral coupled redox centers and their relationship with mixed valence ions. Inorganic Chemistry. 49: 3706-13. PMID 20232822 DOI: 10.1021/Ic901387Q  0.578
2010 Glover SD, Goeltz JC, Lear BJ, Kubiak CP. Inter- or intramolecular electron transfer between triruthenium clusters: we'll cross that bridge when we come to it Coordination Chemistry Reviews. 254: 331-345. DOI: 10.1016/J.Ccr.2009.09.005  0.801
2009 Lear BJ, Chisholm MH. Oxalate bridged MM (MM = Mo2, MoW, and W2) quadruply bonded complexes as test beds for current mixed valence theory: looking beyond the intervalence charge transfer transition. Inorganic Chemistry. 48: 10954-71. PMID 19860456 DOI: 10.1021/Ic900995U  0.56
2009 Lear BJ, Chisholm MH. Oxalate bridged MM (MM = Mo2, MoW, and W2) quadruply bonded complexes as test beds for current mixed valence theory: Looking beyond the intervalence charge transfer transition Inorganic Chemistry. 48: 10954-10971. DOI: 10.1021/ic900995u  0.392
2009 Glover SD, Goeltz JC, Lear BJ, Kubiak CP. Mixed Valency at the Nearly Delocalized Limit: Fundamentals and Forecast (Eur. J. Inorg. Chem. 5/2009) European Journal of Inorganic Chemistry. 2009: 575-575. DOI: 10.1002/Ejic.200990006  0.789
2009 Goeltz JC, Lear BJ, Kubiak CP. Mixed valency at the nearly delocalized limit: Fundamentals and forecast European Journal of Inorganic Chemistry. 585-594. DOI: 10.1002/Ejic.200800910  0.801
2008 Glover SD, Lear BJ, Salsman JC, Londergan CH, Kubiak CP. Electron transfer at the class II/III borderline of mixed valency: dependence of rates on solvent dynamics and observation of a localized-to-delocalized transition in freezing solvents. Philosophical Transactions. Series a, Mathematical, Physical, and Engineering Sciences. 366: 177-85. PMID 17827120 DOI: 10.1098/Rsta.2007.2149  0.774
2007 Lear BJ, Glover SD, Salsman JC, Londergan CH, Kubiak CP. Solvent dynamical control of ultrafast ground state electron transfer: implications for Class II-III mixed valency. Journal of the American Chemical Society. 129: 12772-9. PMID 17902656 DOI: 10.1021/Ja072653M  0.773
2007 Lear BJ, Kubiak CP. Origins of cooperative noncovalent host-guest chemistry in mixed valence complexes. The Journal of Physical Chemistry. B. 111: 6766-71. PMID 17439272 DOI: 10.1021/Jp068964L  0.583
2006 Lear BJ, Kubiak CP. Charge gating and electronic delocalization over a denderimeric assembly of trinuclear ruthenium clusters. Inorganic Chemistry. 45: 7041-3. PMID 16933898 DOI: 10.1021/Ic060766L  0.613
2006 Londergan CH, Salsman JC, Lear BJ, Kubiak CP. Observation and dynamics of "mixed-valence isomers" and a thermodynamic estimate of electronic coupling parameters Chemical Physics. 324: 57-62. DOI: 10.1016/J.Chemphys.2005.10.021  0.786
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