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Raymond F. De Hont, Ph.D. - Publications

Affiliations: 
2010 Carnegie Mellon University, Pittsburgh, PA 
Area:
Metalloproteins, Bioinorganic models, Magnetochemistry, Mössbauer and EPR Spectroscopy, Theory of transition metal complexes
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6 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2012 Van Heuvelen KM, Fiedler AT, Shan X, De Hont RF, Meier KK, Bominaar EL, Münck E, Que L. One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center. Proceedings of the National Academy of Sciences of the United States of America. 109: 11933-8. PMID 22786933 DOI: 10.1073/Pnas.1206457109  0.571
2010 McDonald AR, Bukowski MR, Farquhar ER, Jackson TA, Koehntop KD, Seo MS, De Hont RF, Stubna A, Halfen JA, Münck E, Nam W, Que L. Sulfur versus iron oxidation in an iron-thiolate model complex. Journal of the American Chemical Society. 132: 17118-29. PMID 21070030 DOI: 10.1021/Ja1045428  0.589
2010 De Hont RF, Xue G, Hendrich MP, Que L, Bominaar EL, Münck E. Mössbauer, electron paramagnetic resonance, and density functional theory studies of synthetic S = 1/2 Fe(III)-O-Fe(IV)═O complexes. Superexchange-mediated spin transition at the Fe(IV)═O site. Inorganic Chemistry. 49: 8310-22. PMID 20795646 DOI: 10.1021/Ic100870V  0.767
2010 Xue G, De Hont R, Münck E, Que L. Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage. Nature Chemistry. 2: 400-5. PMID 20414242 DOI: 10.1038/Nchem.586  0.775
2009 Alexander Merrill W, Stich TA, Brynda M, Yeagle GJ, Fettinger JC, De Hont R, Reiff WM, Schulz CE, Britt RD, Power PP. Direct spectroscopic observation of large quenching of first-order orbital angular momentum with bending in monomeric, two-coordinate Fe(II) primary amido complexes and the profound magnetic effects of the absence of Jahn- and Renner-Teller distortions in rigorously linear coordination. Journal of the American Chemical Society. 131: 12693-702. PMID 19670870 DOI: 10.1021/Ja903439T  0.441
2007 Xue G, Wang D, De Hont R, Fiedler AT, Shan X, Münck E, Que L. A synthetic precedent for the [FeIV2(mu-O)2] diamond core proposed for methane monooxygenase intermediate Q. Proceedings of the National Academy of Sciences of the United States of America. 104: 20713-8. PMID 18093922 DOI: 10.1073/Pnas.0708516105  0.746
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