| Year |
Citation |
Score |
| 2021 |
Orfanopoulos M. Singlet Oxygen: Discovery, Chemistry, C - Sensitization. Photochemistry and Photobiology. PMID 34240450 DOI: 10.1111/php.13486 |
0.335 |
|
| 2021 |
Malliaros NG, Kellner ID, Drewello T, Orfanopoulos M. Decatungstate-Photocatalyzed Addition of Lactones to [60]Fullerene. The Journal of Organic Chemistry. 86: 9876-9882. PMID 34184900 DOI: 10.1021/acs.joc.1c00954 |
0.385 |
|
| 2020 |
Papastavrou AT, Kidonakis M, Stratakis M, Orfanopoulos M. Isomerization of Epoxides into Allylic Alcohols Catalyzed by Supported Au Nanoparticles on TiO2: A Mechanistic Insight. The Journal of Organic Chemistry. PMID 32965121 DOI: 10.1021/acs.joc.0c01889 |
0.766 |
|
| 2019 |
Tzirakis MD, Malliaros NG, Orfanopoulos M. Photochemical Reaction of o
-Phthalaldehyde with Fullerene C60
: The Stimulus for the Phthalide Additions to C60 European Journal of Organic Chemistry. 2019: 6961-6967. DOI: 10.1002/Ejoc.201901363 |
0.386 |
|
| 2019 |
Roubelakis MM, Malliaros NG, Orfanopoulos M. Diels-Alder Cycloaddition of C60
with Photochemically Generated Hydroxy to o
-quinodimethanes Governed by Steric Factors: A Mechanistic Study European Journal of Organic Chemistry. 2019: 5694-5703. DOI: 10.1002/Ejoc.201900859 |
0.323 |
|
| 2014 |
Kellner ID, Von Gernler MS, Tzirakis MD, Orfanopoulos M, Drewello T. Formation of singly bonded fullerene dimers in electrospray mass spectrometry Journal of Physical Chemistry C. 118: 30253-30259. DOI: 10.1021/Jp509704A |
0.352 |
|
| 2014 |
Kyriakopoulos J, Papastavrou AT, Panagiotou GD, Tzirakis MD, Triantafyllidis KS, Alberti MN, Bourikas K, Kordulis C, Orfanopoulos M, Lycourghiotis A. Deposition of fullerene C60 on the surface of MCM-41 via the one-step wet impregnation method: Active catalysts for the singlet oxygen mediated photooxidation of alkenes Journal of Molecular Catalysis a: Chemical. 381: 9-15. DOI: 10.1016/J.Molcata.2013.09.036 |
0.772 |
|
| 2013 |
Tzirakis MD, Orfanopoulos M. Radical reactions of fullerenes: from synthetic organic chemistry to materials science and biology. Chemical Reviews. 113: 5262-321. PMID 23570603 DOI: 10.1021/Cr300475R |
0.387 |
|
| 2012 |
Lykakis IN, Evgenidou E, Orfanopoulos M. Photo-catalysis and polyoxo-anion decatungstate in organic chemistry: A manifold concept for green chemistry Current Organic Chemistry. 16: 2400-2414. DOI: 10.2174/138527212803520092 |
0.391 |
|
| 2012 |
Kyriakopoulos J, Tzirakis MD, Panagiotou GD, Alberti MN, Triantafyllidis KS, Giannakaki S, Bourikas K, Kordulis C, Orfanopoulos M, Lycourghiotis A. Highly active catalysts for the photooxidation of organic compounds by deposition of [60] fullerene onto the MCM-41 surface: A green approach for the synthesis of fine chemicals Applied Catalysis B: Environmental. 117: 36-48. DOI: 10.1016/J.Apcatb.2011.12.024 |
0.374 |
|
| 2011 |
Tzirakis MD, Alberti MN, Orfanopoulos M. Photocycloaddition of biscyclopropyl alkenes to C60: an unprecedented approach toward cis-1 tricyclic-fused fullerenes. Organic Letters. 13: 3364-7. PMID 21644561 DOI: 10.1021/Ol201112A |
0.43 |
|
| 2010 |
Tzirakis MD, Alberti MN, Orfanopoulos M. Hydroxyalkylation of [60]fullerene: free radical addition of alcohols to C60. Chemical Communications (Cambridge, England). 46: 8228-30. PMID 20877845 DOI: 10.1039/C0Cc02836C |
0.392 |
|
| 2010 |
Tzirakis MD, Orfanopoulos M. Photochemical addition of ethers to C60: synthesis of the simplest [60]fullerene/crown ether conjugates. Angewandte Chemie (International Ed. in English). 49: 5891-3. PMID 20632349 DOI: 10.1002/Anie.201002285 |
0.38 |
|
| 2010 |
Alberti MN, Orfanopoulos M. Unraveling the mechanism of the singlet oxygen ene reaction: recent computational and experimental approaches. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 9414-21. PMID 20623729 DOI: 10.1002/Chem.201000752 |
0.443 |
|
| 2010 |
Vougioukalakis GC, Roubelakis MM, Orfanopoulos M. Radical reactivity of aza[60]fullerene: preparation of monoadducts and limitations. The Journal of Organic Chemistry. 75: 4124-30. PMID 20481575 DOI: 10.1021/Jo100277V |
0.722 |
|
| 2010 |
Vougioukalakis GC, Roubelakis MM, Orfanopoulos M. Open-cage fullerenes: towards the construction of nanosized molecular containers. Chemical Society Reviews. 39: 817-44. PMID 20111794 DOI: 10.1039/B913766A |
0.632 |
|
| 2010 |
Alberti MN, Orfanopoulos M. Recent mechanistic insights in the singlet oxygen ene reaction Synlett. 999-1026. DOI: 10.1055/S-0029-1219790 |
0.496 |
|
| 2010 |
Roubelakis MM, Vougioukalakis GC, Nye LC, Drewello T, Orfanopoulos M. Exploring the photoinduced electron transfer reactivity of aza[60]fullerene iminium cation Tetrahedron. 66: 9363-9369. DOI: 10.1016/J.Tet.2010.10.006 |
0.708 |
|
| 2010 |
Panagiotou GD, Tzirakis MD, Vakros J, Loukatzikou L, Orfanopoulos M, Kordulis C, Lycourghiotis A. Development of [60] fullerene supported on silica catalysts for the photo-oxidation of alkenes Applied Catalysis a: General. 372: 16-25. DOI: 10.1016/J.Apcata.2009.09.046 |
0.378 |
|
| 2009 |
Alberti MN, Vougioukalakis GC, Orfanopoulos M. Photosensitized oxidations of substituted pyrroles: unanticipated radical-derived oxygenated products. The Journal of Organic Chemistry. 74: 7274-82. PMID 19739608 DOI: 10.1021/Jo9012942 |
0.691 |
|
| 2009 |
Tzirakis MD, Lykakis IN, Orfanopoulos M. Decatungstate as an efficient photocatalyst in organic chemistry. Chemical Society Reviews. 38: 2609-21. PMID 19690741 DOI: 10.1039/B812100C |
0.339 |
|
| 2009 |
Tzirakis MD, Alberti MN, Nye LC, Drewello T, Orfanopoulos M. One-step synthesis of fullerene hydride C(60)H2 via hydrolysis of acylated fullerenes. The Journal of Organic Chemistry. 74: 5746-9. PMID 19572499 DOI: 10.1021/Jo900934J |
0.329 |
|
| 2009 |
Tzirakis MD, Orfanopoulos M. Acyl radical reactions in fullerene chemistry: direct acylation of [60]fullerene through an efficient decatungstate-photomediated approach. Journal of the American Chemical Society. 131: 4063-9. PMID 19292491 DOI: 10.1021/Ja808658B |
0.494 |
|
| 2009 |
Alberti MN, Orfanopoulos M. Concerning the reactivity of PTAD with isomeric dienes: the mechanism of the Diels-Alder cycloaddition. Organic Letters. 11: 1659-62. PMID 19281199 DOI: 10.1021/Ol900363N |
0.443 |
|
| 2009 |
Lykakis IN, Orfanopoulos M. Decatungstate-catalyzed photooxygenation of S-2-phenylbutane and cumene via a free carbon-radical intermediate Current Organic Chemistry. 13: 1737-1745. DOI: 10.2174/138527209789578018 |
0.337 |
|
| 2009 |
Tzirakis MD, Orfanopoulos M. Acyl Radical Addition to [60]Fullerene Synfacts. 2009: 735-735. DOI: 10.1055/S-0029-1217221 |
0.339 |
|
| 2009 |
Tzirakis MD, Vakros J, Loukatzikou L, Amargianitakis V, Orfanopoulos M, Kordulis C, Lycourghiotis A. γ-Alumina-supported [60]fullerene catalysts: Synthesis, properties and applications in the photooxidation of alkenes Journal of Molecular Catalysis a: Chemical. 316: 65-74. DOI: 10.1016/J.Molcata.2009.10.001 |
0.373 |
|
| 2008 |
Vougioukalakis GC, Roubelakis MM, Alberti MN, Orfanopoulos M. Solvent-dependent changes in the triazolinedione-alkene ene reaction mechanism. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 9697-705. PMID 18816558 DOI: 10.1002/Chem.200800920 |
0.699 |
|
| 2008 |
Alberti MN, Vassilikogiannakis G, Orfanopoulos M. Stereochemistry of the singlet oxygenation of simple alkenes: a stereospecific transformation. Organic Letters. 10: 3997-4000. PMID 18707107 DOI: 10.1021/Ol801488W |
0.473 |
|
| 2008 |
Alberti MN, Orfanopoulos M. The cyclopropyl group as a hypersensitive probe in the singlet oxygen ene reaction mechanism. Organic Letters. 10: 2465-8. PMID 18489176 DOI: 10.1021/Ol800759U |
0.46 |
|
| 2008 |
Tzirakis MD, Orfanopoulos M. Decatungstate-mediated radical reactions of C60 with substituted toluenes and anisoles: a new photochemical functionalization strategy for fullerenes. Organic Letters. 10: 873-6. PMID 18237181 DOI: 10.1021/Ol7030125 |
0.471 |
|
| 2007 |
Roubelakis MM, Murata Y, Komatsu K, Orfanopoulos M. Efficient synthesis of open-cage fullerene derivatives having 16-membered-ring orifices. The Journal of Organic Chemistry. 72: 7042-5. PMID 17665956 DOI: 10.1021/Jo0710026 |
0.413 |
|
| 2007 |
Roubelakis MM, Vougioukalakis GC, Orfanopoulos M. Open-cage fullerene derivatives having 11-, 12-, and 13-membered-ring orifices: chemical transformations of the organic addends on the rim of the orifice. The Journal of Organic Chemistry. 72: 6526-33. PMID 17655360 DOI: 10.1021/Jo070796L |
0.644 |
|
| 2007 |
Tanielian C, Lykakis IN, Seghrouchni R, Cougnon F, Orfanopoulos M. Mechanism of decatungstate photocatalyzed oxygenation of aromatic alcohols. Part I. Continuous photolysis and laser flash photolysis studies Journal of Molecular Catalysis a: Chemical. 262: 170-175. DOI: 10.1016/J.Molcata.2006.08.092 |
0.401 |
|
| 2007 |
Lykakis IN, Tanielian C, Seghrouchni R, Orfanopoulos M. Mechanism of decatungstate photocatalyzed oxygenation of aromatic alcohols. Part II. Kinetic isotope effects studies Journal of Molecular Catalysis a: Chemical. 262: 176-184. DOI: 10.1016/J.Molcata.2006.08.064 |
0.431 |
|
| 2007 |
Orfanopoulos M, Vougioukalakis GC, Stratakis M. Selective Formation of Allylic Hydroperoxides via Singlet Oxygen Ene Reaction Cheminform. 38. DOI: 10.1002/9780470682531.Pat0355 |
0.716 |
|
| 2006 |
Kotsiris SG, Vasil'ev YV, Streletskii AV, Han M, Mark LP, Boltalina OV, Chronakis N, Orfanopoulos M, Hungerbühler H, Drewello T. Application and evaluation of solvent-free matrix-assisted laser desorption/ionization mass spectrometry for the analysis of derivatized fullerenes. European Journal of Mass Spectrometry (Chichester, England). 12: 397-408. PMID 17404429 DOI: 10.1255/Ejms.824 |
0.318 |
|
| 2006 |
Lykakis IN, Vougioukalakis GC, Orfanopoulos M. Homogeneous decatungstate-catalyzed photooxygenation of tetrasubstituted alkenes: a deuterium kinetic isotope effect study. The Journal of Organic Chemistry. 71: 8740-7. PMID 17081001 DOI: 10.1021/Jo061238U |
0.693 |
|
| 2006 |
Hatzimarinaki M, Orfanopoulos M. Novel methodology for the preparation of five-, seven-, and nine-membered fused rings on C60. Organic Letters. 8: 1775-8. PMID 16623548 DOI: 10.1021/Ol0600887 |
0.441 |
|
| 2006 |
Vougioukalakis GC, Hatzimarinaki M, Lykakis IN, Orfanopoulos M. Reaction of an Aza[60]fullerene radical with diphenylmethanes and fluorenes: a mechanistic approach. The Journal of Organic Chemistry. 71: 829-32. PMID 16409005 DOI: 10.1021/Jo051838D |
0.732 |
|
| 2006 |
Roubelakis MM, Vougioukalakis GC, Angelis YS, Orfanopoulos M. Solvent-dependent changes in the ene reaction of RTAD with alkenes: the cyclopropyl group as a mechanistic probe. Organic Letters. 8: 39-42. PMID 16381562 DOI: 10.1021/Ol052342L |
0.726 |
|
| 2006 |
Alberti MN, Orfanopoulos M. Stereoelectronic and solvent effects on the allylic oxyfunctionalization of alkenes with singlet oxygen Tetrahedron. 62: 10660-10675. DOI: 10.1016/J.Tet.2006.07.106 |
0.501 |
|
| 2006 |
Vrantza D, Kaloudis P, Leondiadis L, Gimisis T, Vougioukalakis GC, Orfanopoulos M, Gasparutto D, Cadet J, Encinas S, Paris C, Miranda MA. Modification of guanine with photolabile N-hydroxypyridine-2(1H)-thione: Monomer synthesis, oligonucleotide elaboration, and photochemical studies Helvetica Chimica Acta. 89: 2371-2386. DOI: 10.1002/Hlca.200690220 |
0.732 |
|
| 2005 |
Hatzimarinaki M, Roubelakis MM, Orfanopoulos M. Biradical intermediate in the [2 + 2] photocycloaddition of dienes and alkenes to [60]fullerene. Journal of the American Chemical Society. 127: 14182-3. PMID 16218602 DOI: 10.1021/Ja053431W |
0.402 |
|
| 2005 |
Vougioukalakis GC, Orfanopoulos M. Mechanistic studies in triazolinedione ene reactions Synlett. 713-731. DOI: 10.1055/S-2005-864793 |
0.714 |
|
| 2005 |
Lykakis IN, Orfanopoulos M. Deuterium kinetic isotope effects in homogeneous decatungstate catalyzed photooxygenation of 1,1-diphenylethane and 9-methyl-9H-fluorene: Evidence for a hydrogen abstraction mechanism Tetrahedron Letters. 46: 7835-7839. DOI: 10.1016/J.Tetlet.2005.09.017 |
0.372 |
|
| 2004 |
Vougioukalakis GC, Orfanopoulos M. Photoinduced electron transfer reactivity of aza[60]fullerene: three discrete functionalization pathways with a single substrate. Journal of the American Chemical Society. 126: 15956-7. PMID 15584717 DOI: 10.1021/Ja045495X |
0.68 |
|
| 2004 |
Vougioukalakis GC, Prassides K, Campanera JM, Heggie MI, Orfanopoulos M. Open-cage fullerene derivatives with 15-membered-ring orifices. The Journal of Organic Chemistry. 69: 4524-6. PMID 15202912 DOI: 10.1021/Jo049842X |
0.67 |
|
| 2004 |
Vougioukalakis GC, Prassides K, Orfanopoulos M. Novel open-cage fullerenes having a 12-membered-ring orifice: removal of the organic addends from the rim of the orifice. Organic Letters. 6: 1245-7. PMID 15070308 DOI: 10.1021/Ol049843B |
0.626 |
|
| 2004 |
Lykakis IN, Orfanopoulos M. Lone selectivity of the decatungstate-sensitized photooxidation of 1-substituted cycloalkenes Synlett. 2131-2134. DOI: 10.1055/S-2004-832803 |
0.371 |
|
| 2004 |
Vougioukalakis GC, Angelis Y, Vakros J, Panagiotou G, Kordulis C, Lycourghiotis A, Orfanopoulos M. [60]Fullerene supported on silica and γ-alumina sensitized photooxidation of olefins: Chemical evidence for singlet oxygen and electron transfer mechanism Synlett. 971-974. DOI: 10.1055/S-2004-820041 |
0.669 |
|
| 2004 |
Lykakis IN, Orfanopoulos M. Photooxidation of aryl alkanes by a decatungstate/triethylsilane system in the presence of molecular oxygen Tetrahedron Letters. 45: 7645-7649. DOI: 10.1016/J.Tetlet.2004.08.096 |
0.42 |
|
| 2003 |
Vougioukalakis GC, Chronakis N, Orfanopoulos M. Addition of electron-rich aromatics to azafullerenium carbocation. A stepwise electrophilic substitution mechanism. Organic Letters. 5: 4603-6. PMID 14627394 DOI: 10.1021/Ol0357604 |
0.735 |
|
| 2003 |
Lykakis IN, Tanielian C, Orfanopoulos M. Decatungstate photocatalyzed oxidation of aryl alkanols. Electron transfer or hydrogen abstraction mechanism? Organic Letters. 5: 2875-8. PMID 12889897 DOI: 10.1021/Ol0349211 |
0.451 |
|
| 2003 |
Adam W, Krebs O, Orfanopoulos M, Stratakis M, Vougioukalakis GC. Intramolecular and intermolecular kinetic isotope effects (KIE) in the nitrosoarene ene reaction: experimental evidence for reversible intermediate formation. The Journal of Organic Chemistry. 68: 2420-5. PMID 12636411 DOI: 10.1021/Jo0266240 |
0.653 |
|
| 2003 |
Vakros J, Panagiotou G, Kordulis C, Lycourghiotis A, Vougioukalakis GC, Angelis Y, Orfanopoulos M. Fullerene C60 supported on silica and γ-alumina catalyzed photooxidations of alkenes Catalysis Letters. 89: 269-273. DOI: 10.1023/A:1025770916765 |
0.696 |
|
| 2003 |
Lykakis IN, Lestakis S, Orfanopoulos M. 9,10-Dicyanoanthracene photosensitized oxidation of aryl alkanols: Evidence for an electron transfer mechanism Tetrahedron Letters. 44: 6247-6251. DOI: 10.1016/S0040-4039(03)01549-1 |
0.402 |
|
| 2003 |
Alberti MN, Vougioukalakis GC, Orfanopoulos M. Electronic effects in the regioselectivity of the singlet oxygen and 4-methyl-1,2,4-triazoline-3,5-dione ene reactions with isobutenylarenes Tetrahedron Letters. 44: 903-905. DOI: 10.1016/S0040-4039(02)02783-1 |
0.715 |
|
| 2003 |
Vougioukalakis GC, Orfanopoulos M. Functionalization of azafullerene C59N. Radical reactions with 9-substituted fluorenes Tetrahedron Letters. 44: 8649-8652. DOI: 10.1016/J.Tetlet.2003.09.158 |
0.725 |
|
| 2002 |
Adam W, Bottke N, Krebs O, Lykakis I, Orfanopoulos M, Stratakis M. Ene reaction of singlet oxygen, triazolinedione, and nitrosoarene with chiral deuterium-labeled allylic alcohols: the interdependence of diastereoselectivity and regioselectivity discloses mechanistic insights into the hydroxy-group directivity. Journal of the American Chemical Society. 124: 14403-9. PMID 12452715 DOI: 10.1021/Ja027800P |
0.414 |
|
| 2002 |
Adam W, Krebs O, Orfanopoulos M, Stratakis M. Control of regioselectivity by the lone substituent through steric and electronic effects in the nitrosoarene ene reaction of deuterium-labeled trisubstituted alkenes. The Journal of Organic Chemistry. 67: 8395-9. PMID 12444616 DOI: 10.1021/Jo026198I |
0.499 |
|
| 2002 |
Chronakis N, Froudakis G, Orfanopoulos M. Stereochemistry of the [4 + 2] cycloadditions of trans,trans- and cis,trans-2,4-hexadiene to C(60). The Journal of Organic Chemistry. 67: 3284-9. PMID 12003537 DOI: 10.1021/Jo0109570 |
0.356 |
|
| 2002 |
Chronakis N, Vougioukalakis GC, Orfanopoulos M. Synthesis and self-photooxygenation of alkenyl-linked [60]fullerene derivatives. A regioselective ene reaction. Organic Letters. 4: 945-8. PMID 11893192 DOI: 10.1021/Ol025690L |
0.699 |
|
| 2002 |
Vassilikogiannakis G, Stratakis M, Orfanopoulos M. Primary and secondary H/D isotope effects in the addition of triazolinedione to 2,5-dimethyl-2,4-hexadiene. Mechanistic insights into the reaction pathways Arkivoc. 2002: 9-16. DOI: 10.3998/Ark.5550190.0003.D02 |
0.472 |
|
| 2002 |
Orfanopoulos M, Grdina MB, Stephenson LM. Site specificity in the singlet oxygen-trisubstituted olefin reaction Cheminform. 10. DOI: 10.1002/Chin.197915140 |
0.404 |
|
| 2001 |
Stratakis M, Hatzimarinaki M, Froudakis GE, Orfanopoulos M. Stereochemistry in the reaction of 4-methyl-1,2,4-triazoline-3,5-dione (MTAD) with beta,beta dimethyl-p-methoxystyrene. Are open biradicals the reaction intermediates? The Journal of Organic Chemistry. 66: 3682-7. PMID 11374985 DOI: 10.1021/Jo0005518 |
0.467 |
|
| 2001 |
Chronakis N, Orfanopoulos M. [4 + 2] Cycloadditions of rigid s-cis dienes to C(60). A synchronous Diels-Alder reaction. Organic Letters. 3: 545-8. PMID 11178821 DOI: 10.1021/Ol0003735 |
0.459 |
|
| 2001 |
Angelis YS, Hatzakis NS, Smonou I, Orfanopoulos M. Oxidation of benzyl alcohols by dimethyldioxirane. The question of concerted versus stepwise mechanisms probed by kinetic isotope effects Tetrahedron Letters. 42: 3753-3756. DOI: 10.1016/S0040-4039(01)00539-1 |
0.355 |
|
| 2001 |
Chronakis N, Orfanopoulos M. Concerted Diels-Alder reaction between anthracene and C60 Tetrahedron Letters. 42: 1201-1204. DOI: 10.1016/S0040-4039(00)02211-5 |
0.476 |
|
| 2000 |
Vassilikogiannakis G, Hatzimarinaki M, Orfanopoulos M. Mechanism of the The Journal of Organic Chemistry. 65: 8180-7. PMID 11101371 DOI: 10.1021/Jo0006223 |
0.317 |
|
| 2000 |
Vassilikogiannakis G, Stratakis M, Orfanopoulos M. Isotope effects and syn selectivity in the ene reaction of triazolinedione with conjugated enones: aziridinium imide or an open intermediate mechanism? Organic Letters. 2: 2245-8. PMID 10930254 DOI: 10.1021/Ol000109B |
0.416 |
|
| 2000 |
Vassilikogiannakis G, Elemes Y, Orfanopoulos M. Stereochemistry of the triazollinedione - Alkene ene reaction: A stereospecific suprafacial transformation [2] Journal of the American Chemical Society. 122: 9540-9541. DOI: 10.1021/Ja001190G |
0.414 |
|
| 2000 |
Hatzimarinaki M, Vassilikogiannakis G, Orfanopoulos M. Stereochemistry and steric isotope effect on the [2+2] photocycloaddition of β,β-dimethyl-p-methoxystyrene to C60: The nature of the transition state structures Tetrahedron Letters. 41: 4667-4670. DOI: 10.1016/S0040-4039(00)00684-5 |
0.349 |
|
| 2000 |
Stratakis M, Orfanopoulos M. Regioselectivity in the ene reaction of singlet oxygen with alkenes Tetrahedron. 56: 1595-1615. DOI: 10.1016/S0040-4020(99)00950-3 |
0.506 |
|
| 1999 |
Vassilikogiannakis G, Orfanopoulos M. Regio- and Stereoselectivity of the [2 + 2] Photocycloaddition of Acyclic Enones to C(60). The Journal of Organic Chemistry. 64: 3392-3393. PMID 11674456 DOI: 10.1021/Jo982486W |
0.334 |
|
| 1999 |
Chronakis N, Orfanopoulos M. Ene Reaction of Arylallyl Alkenes with C60. A Mechanistic Approach Organic Letters. 1: 1909-1912. DOI: 10.1021/Ol990204O |
0.469 |
|
| 1999 |
Vassilikogiannakis G, Stratakis M, Orfanopoulos M, Foote CS. Stereochemistry in the ene reactions of singlet oxygen and triazolinediones with allylic alcohols. A mechanistic comparison Journal of Organic Chemistry. 64: 4130-4139. DOI: 10.1021/Jo990258B |
0.642 |
|
| 1998 |
Vassilikogiannakis G, Stratakis M, Orfanopoulos M. Primary and Secondary Isotope Effects in the Photooxidation of 2,5-Dimethyl-2,4-hexadiene. Elucidation of the Reaction Energy Profile. The Journal of Organic Chemistry. 63: 6390-6393. PMID 11672275 DOI: 10.1021/Jo971994N |
0.391 |
|
| 1998 |
Stratakis M, Orfanopoulos M, Foote CS. Reactions of singlet oxygen and N-methyltriazolinediones with β,β-dimethylstyrene. exceptional syn selectivity in the ene products Journal of Organic Chemistry. 63: 1315-1318. DOI: 10.1021/Jo9715332 |
0.564 |
|
| 1998 |
Vassilikogiannakis G, Chronakis N, Orfanopoulos M. A new [2 + 2] functionalization of C60 with alkyl-substituted 1,3- butadienes: A mechanistic approach. Stereochemistry and isotope effects Journal of the American Chemical Society. 120: 9911-9920. DOI: 10.1021/Ja981377W |
0.385 |
|
| 1998 |
Stratakis M, Vassilikogiannakis G, Orfanopoulos M. Diastereoselective ene reactions of triazolinediones with chiral allylic alcohols. Evidence for a hydroxyl-enophile steering effect Tetrahedron Letters. 39: 2393-2396. DOI: 10.1016/S0040-4039(98)00207-X |
0.403 |
|
| 1997 |
Vassilikogiannakis G, Orfanopoulos M. Stereochemistry and isotope effects of the [2 + 2] photocycloadditions of arylalkenes to C60. A stepwise mechanism Journal of the American Chemical Society. 119: 7394-7395. DOI: 10.1021/Ja970916E |
0.328 |
|
| 1997 |
Elemes Y, Stratakis M, Orfanopoulos M. An interplay in the regioselectivity induced by non bonding interactions, in the ene reactions of singlet oxygen and triazolinediones with tetrasubstituted alkenes Tetrahedron Letters. 38: 6437-6440. DOI: 10.1016/S0040-4039(97)01471-8 |
0.451 |
|
| 1997 |
Vassilikogiannakis G, Orfanopoulos M. [2+2] Photocycloadditions of cis/trans-4-propenylanisole to C60. A step-wise mechanism Tetrahedron Letters. 38: 4323-4326. DOI: 10.1016/S0040-4039(97)00891-5 |
0.322 |
|
| 1997 |
Stratakis M, Orfanopoulos M. Regioselectivity in the ene reaction of singlet oxygen with alkenes bearing an electron withdrawing group at β-position Tetrahedron Letters. 38: 1067-1070. DOI: 10.1016/S0040-4039(96)02469-0 |
0.389 |
|
| 1996 |
Stratakis M, Orfanopoulos M, Foote CS. Solvent effects in the stereoselectivity of the ene reaction of singlet oxygen with allylic alcohols Tetrahedron Letters. 37: 7159-7162. DOI: 10.1016/0040-4039(96)01621-8 |
0.617 |
|
| 1996 |
Angelis Y, Zhang X, Orfanopoulos M. Secondary isotope effects in dioxirane epoxidations. Concerted or step-wise mechanism? Tetrahedron Letters. 37: 5991-5994. DOI: 10.1016/0040-4039(96)01256-7 |
0.395 |
|
| 1996 |
Stratakis M, Orfanopoulos M, Chen JS, Foote CS. Reaction profile of the photooxygenation of trisubstituted alkenes Tetrahedron Letters. 37: 4105-4108. DOI: 10.1016/0040-4039(96)00776-9 |
0.613 |
|
| 1996 |
Vassilikogiannakis G, Orfanopoulos M. Remote ε-secondary isotope effect in the reaction of tetracyanoethylene with 2,5-dimethyl-2,4-hexadiene. A step-wise mechanism Tetrahedron Letters. 37: 3075-3078. DOI: 10.1016/0040-4039(96)00473-X |
0.389 |
|
| 1996 |
Vassilikogiannakis G, Stratakis M, Karabatsos GJ, Orfanopoulos M. Mechanistic studies in the reaction of 4‐phenyl‐1,2,4‐triazoline‐3,5‐dione with 2,5‐dimethyl‐2,4‐hexadiene Journal of Heterocyclic Chemistry. 33: 993-995. DOI: 10.1002/Jhet.5570330374 |
0.504 |
|
| 1996 |
Vassilikogiannakis G, Stratakis M, Karabatsos GJ, Orfanopoulos M. Mechanistic studies in the reaction of 4-phenyl-1,2,4-triazoline-3,5-dione with 2,5-dimethyl-2,4-hexadiene Journal of Heterocyclic Chemistry. 33: 993-995. |
0.418 |
|
| 1995 |
Smonou I, Khan S, Foote CS, Elemes Y, Mavridis IM, Pantidou A, Orfanopoulos M. Reactions of phenyltriazolinedione with alkenes. Stereochemistry of methanol adducts to aziridinium imide intermediates Journal of the American Chemical Society. 117: 7081-7087. DOI: 10.1021/Ja00132A006 |
0.651 |
|
| 1995 |
Stratakis M, Orfanopoulos M. Anti "cis effect" selectivity in the reaction of singlet oxygen with trisubstituted alkenes Tetrahedron Letters. 36: 4291-4294. DOI: 10.1016/0040-4039(95)00742-U |
0.44 |
|
| 1995 |
Orfanopoulos M, Kambourakis S. Chemical evidence of singlet oxygen production from C60 and C70 in aqueous and other polar media Tetrahedron Letters. 36: 435-438. DOI: 10.1016/0040-4039(94)02277-I |
0.357 |
|
| 1994 |
Orfanopoulos M, Kambourakis S. Fullerene C60 and C70 photosensitized oxygenation of olefins Tetrahedron Letters. 35: 1945-1948. DOI: 10.1016/S0040-4039(00)73202-3 |
0.433 |
|
| 1993 |
Stratakis M, Orfanopoulos M. Regioselective formation of cyclic and allylic hydroperoxides Synthetic Communications. 23: 425-430. DOI: 10.1080/00397919308009797 |
0.429 |
|
| 1992 |
Elemes Y, Orfanopoulos M. Quantum mechanical tunneling in the ene reaction of triazolinedione with sterically hindered alkenes Journal of the American Chemical Society. 114: 11007-11009. DOI: 10.1021/Ja00053A074 |
0.362 |
|
| 1991 |
Orfanopoulos M, Stratakis M, Elemes Y, Jensen F. Do rotational barriers dictate the regioselectivity in the ene reactions of singlet oxygen and triazolinedione with alkenes? Journal of the American Chemical Society. 113: 3180-3181. DOI: 10.1021/Ja00008A061 |
0.481 |
|
| 1991 |
Orfanopoulos M, Stratakis M, Elemes Y, Smonou I. Regioselectivity of singlet oxygen ene reactions. The non-bonding large group effect Studies in Surface Science and Catalysis. 66: 565-571. DOI: 10.1016/S0167-2991(08)62877-3 |
0.435 |
|
| 1991 |
Stratakis M, Orfanopoulos M, Foote CS. Nucleophilic oxygen transfer from a perepoxide to phosphites Tetrahedron Letters. 32: 863-866. DOI: 10.1016/S0040-4039(00)92106-3 |
0.574 |
|
| 1991 |
Elemes Y, Orfanopoulos M. Triazolinedione additions to alkenes in protic solvents. A remarkable temperature dependence of the competing reaction paths Tetrahedron Letters. 32: 2667-2670. DOI: 10.1016/S0040-4039(00)78814-9 |
0.47 |
|
| 1991 |
Orfanopoulos M, Stratakis M. Solvent effects on the side selectivity of singlet oxygen with α,β unsaturated esters. New evidence for a perepoxide intermediate Tetrahedron Letters. 32: 7321-7324. DOI: 10.1016/0040-4039(91)80509-5 |
0.439 |
|
| 1990 |
Orfanopoulos M, Stratakis M, Elemes Y. Geminal selectivity of singlet oxygen ene reactions. The nonbonding large group effect Journal of the American Chemical Society. 112: 6417-6419. DOI: 10.1021/Ja00173A051 |
0.451 |
|
| 1990 |
Orfanopoulos M, Smonou I, Foote CS. Intermediates in the ene reactions of singlet oxygen and N-phenyl-1,2,4-triazoline-3,5-dione with olefins Journal of the American Chemical Society. 112: 3607-3614. DOI: 10.1021/Ja00165A053 |
0.624 |
|
| 1990 |
Orfanopoulos M, Elemes Y, Stratakis M. Reactions of triazolinedione with alkenes. A remarkable geminal selectivity Tetrahedron Letters. 31: 5775-5778. DOI: 10.1016/S0040-4039(00)97956-5 |
0.481 |
|
| 1989 |
Elemes Y, Stratakis M, Orfanopoulos M. Reactions of triazolinediones with cis-alkenes. A highly regioselective ene reaction Tetrahedron Letters. 30: 6903-6906. DOI: 10.1016/S0040-4039(01)93384-2 |
0.47 |
|
| 1989 |
Orfanopoulos M, Stratakis M, Elemes Y. Regioselective reaction of singlet oxygen with cis-alkenes Tetrahedron Letters. 30: 4875-4878. DOI: 10.1016/S0040-4039(01)80532-3 |
0.475 |
|
| 1988 |
Orfanopoulos M, Smonou I. Selective reduction of diaryl or aryl alkyl alcohols in the presence of primary hydroxyl or ester groups by etherated boron trifluoride-triethylsilane system Synthetic Communications. 18: 833-839. DOI: 10.1080/00397918808057852 |
0.31 |
|
| 1988 |
Orfanopoulos M, Foote CS. Intermediate in the ene reaction of singlet oxygen with 1,4-diphenyl-cis-2-butene and 2-butene Journal of the American Chemical Society. 110: 6583-6584. DOI: 10.1021/Ja00227A060 |
0.622 |
|
| 1988 |
Smonou I, Orfanopoulos M. Stereoisotopic study of the reduction of 1-phynylethanol by etherated boron trifluoride-triethylsilane system Tetrahedron Letters. 29: 5793-5796. DOI: 10.1016/S0040-4039(00)82194-2 |
0.387 |
|
| 1988 |
Smonou I, Orfanopoulos M, Foote CS. Reaction of 4-phenyl-1,2,4-triazoline-3,5-dione with substituted indenes Tetrahedron Letters. 29: 2769-2772. DOI: 10.1016/0040-4039(88)85204-3 |
0.581 |
|
| 1987 |
Orfanopoulos M, Foote CS. The ene reaction of singlet oxygen with olefins. Free Radical Research Communications. 2: 321-6. PMID 3504812 DOI: 10.3109/10715768709065298 |
0.618 |
|
| 1987 |
Orfanopoulos M, Foote CS, Smonou I. Stereochemical dependence of isotope effects in the ene reaction of N-phenyl-1,2,4-triazoline-3,5-dione with isomers of butene-d3 Tetrahedron Letters. 28: 15-18. DOI: 10.1016/S0040-4039(00)95637-5 |
0.628 |
|
| 1985 |
Makino T, Orfanopoulos M, You TP, Wu B, Mosher CW, Mosher HS. Chiral benzhydrol-2,3,4,5,6-d5 Journal of Organic Chemistry. 50: 5357-5360. DOI: 10.1021/Jo00225A067 |
0.491 |
|
| 1985 |
Orfanopoulos M, Foote CS. Regioselective reaction of singlet oxygen with α,β-unsaturated esters Tetrahedron Letters. 26: 5991-5994. DOI: 10.1016/S0040-4039(00)98279-0 |
0.599 |
|
| 1981 |
Stephenson LM, Orfanopoulos M. Changes in ene reaction mechanisms with Lewis acid catalysis Journal of Organic Chemistry. 12: 2200-2201. DOI: 10.1021/Jo00323A053 |
0.388 |
|
| 1981 |
Stephenson LM, Orfanopoulos M. Changes in ene reaction mechanisms with Lewis acid catalysis [2] Journal of Organic Chemistry. 46: 2200-2201. |
0.699 |
|
| 1980 |
Stephenson LM, Grdina MJ, Orfanopoulos M. Mechanism of the ene reaction between singlet oxygen and olefins Accounts of Chemical Research. 13: 419-425. DOI: 10.1021/Ar50155A006 |
0.718 |
|
| 1980 |
Orfanopoulos M, Stephenson LM. Stereochemistry of the singlet oxygen olefin-ene reaction [2] Journal of the American Chemical Society. 102: 1417-1418. |
0.701 |
|
| 1979 |
Grdina MB, Orfanopoulos M, Stephenson LM. A convenient synthetic sequence for the deuterium labeling of olefins in the allylic position Journal of Organic Chemistry. 44: 2936-2938. DOI: 10.1021/Jo01330A024 |
0.604 |
|
| 1979 |
Grdina B, Orfanopoulos M, Stephenson LM. Stereochemical dependence of isotope effects in the singlet oxygen-olefin reaction [1] Journal of the American Chemical Society. 101: 3111-3112. DOI: 10.1021/Ja00505A044 |
0.719 |
|
| 1979 |
Orfanopoulos M, Grdina SMB, Stephenson LM. Site specificity in the singlet oxygen-trisubstituted olefin reaction Journal of the American Chemical Society. 101: 275-276. DOI: 10.1021/Ja00495A075 |
0.456 |
|
| 1979 |
Grdina SMB, Grdina M, Orfanopoulos M, Stephenson LM. Concerning zwitterionic peroxide or diradical intermediates in the singlet oxygen-olefin ene reaction Tetrahedron Letters. 20: 4351-4354. DOI: 10.1016/S0040-4039(01)86586-2 |
0.723 |
|
| 1979 |
Orfanopoulos M, Grdina MB, Stephenson LM. Site specificity in the singlet oxygen-trisubstituted olefin reaction [42] Journal of the American Chemical Society. 101: 275-276. |
0.675 |
|
| 1978 |
Fry JL, Orfanopoulos M, Adlington MG, Dittman WR, Silverman SB. Reduction of aldehydes and ketones to alcohols and hydrocarbons through use of the organosilane-boron trifluoride system Journal of Organic Chemistry. 43: 374-375. DOI: 10.1021/Jo00396A056 |
0.318 |
|
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