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John F. Hartwig - Publications

Affiliations: 
University of California, Berkeley, Berkeley, CA, United States 
Area:
reactions catalyzed by transition metal complexes
Website:
http://chem.berkeley.edu/faculty/hartwig/
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Year Citation  Score
2024 Venetos MC, Elkin M, Delaney C, Hartwig JF, Persson KA. Deconvolution and Analysis of the H NMR Spectra of Crude Reaction Mixtures. Journal of Chemical Information and Modeling. PMID 38573053 DOI: 10.1021/acs.jcim.3c01864  0.609
2024 Yu IF, D'Angelo KA, Hernandez-Mejías ÁD, Cheng N, Hartwig JF. 2-Aminophenanthroline Ligands Enable Mild, Undirected, Iridium-Catalyzed Borylation of Alkyl C-H Bonds. Journal of the American Chemical Society. PMID 38456743 DOI: 10.1021/jacs.3c12981  0.86
2024 Sterling AJ, Ciccia NR, Guo Y, Hartwig JF, Head-Gordon M. Mechanistic Insights into the Origins of Selectivity in a Cu-Catalyzed C-H Amidation Reaction. Journal of the American Chemical Society. PMID 38381006 DOI: 10.1021/jacs.3c13822  0.361
2024 Pierson CN, Hartwig JF. Mapping the mechanisms of oxidative addition in cross-coupling reactions catalysed by phosphine-ligated Ni(0). Nature Chemistry. PMID 38355826 DOI: 10.1038/s41557-024-01451-x  0.317
2024 Bloomer BJ, Joyner IA, Garcia-Borràs M, Hu DB, Garçon M, Quest A, Ugarte Montero C, Yu IF, Clark DS, Hartwig JF. Enantio- and Diastereodivergent Cyclopropanation of Allenes by Directed Evolution of an Iridium-Containing Cytochrome. Journal of the American Chemical Society. PMID 38190322 DOI: 10.1021/jacs.3c13011  0.805
2023 Yu IF, Wilson JW, Hartwig JF. Transition-Metal-Catalyzed Silylation and Borylation of C-H Bonds for the Synthesis and Functionalization of Complex Molecules. Chemical Reviews. 123: 11619-11663. PMID 37751601 DOI: 10.1021/acs.chemrev.3c00207  0.826
2023 Shi JX, Ciccia NR, Pal S, Kim DD, Brunn JN, Lizandara-Pueyo C, Ernst M, Haydl AM, Messersmith PB, Helms BA, Hartwig JF. Chemical Modification of Oxidized Polyethylene Enables Access to Functional Polyethylenes with Greater Reuse. Journal of the American Chemical Society. PMID 37733607 DOI: 10.1021/jacs.3c07186  0.774
2023 Delaney CP, Lin E, Huang Q, Yu IF, Rao G, Tao L, Jed A, Fantasia SM, Püntener KA, Britt RD, Hartwig JF. Cross-coupling by a noncanonical mechanism involving the addition of aryl halide to Cu(II). Science (New York, N.Y.). 381: 1079-1085. PMID 37676958 DOI: 10.1126/science.adi9226  0.814
2023 Luo Y, Li Y, Wu J, Xue XS, Hartwig JF, Shen Q. Oxidative addition of an alkyl halide to form a stable Cu(III) product. Science (New York, N.Y.). 381: 1072-1079. PMID 37676952 DOI: 10.1126/science.adg9232  0.602
2023 Wilson JW, Su B, Yoritate M, Shi JX, Hartwig JF. Iridium-Catalyzed, Site-Selective Silylation of Secondary C(sp)-H Bonds in Secondary Alcohols and Ketones. Journal of the American Chemical Society. PMID 37638874 DOI: 10.1021/jacs.3c03127  0.564
2023 Caldeweyher E, Elkin M, Gheibi G, Johansson M, Sköld C, Norrby PO, Hartwig JF. Hybrid Machine Learning Approach to Predict the Site Selectivity of Iridium-Catalyzed Arene Borylation. Journal of the American Chemical Society. 145: 17367-17376. PMID 37523755 DOI: 10.1021/jacs.3c04986  0.609
2023 Ma S, Hartwig JF. Progression of Hydroamination Catalyzed by Late Transition-Metal Complexes from Activated to Unactivated Alkenes. Accounts of Chemical Research. 56: 1565-1577. PMID 37272995 DOI: 10.1021/acs.accounts.3c00141  0.417
2023 Huang J, Quest A, Cruz-Morales P, Deng K, Pereira JH, Van Cura D, Kakumanu R, Baidoo EEK, Dan Q, Chen Y, Petzold CJ, Northen TR, Adams PD, Clark DS, Balskus EP, ... Hartwig JF, et al. Complete integration of carbene-transfer chemistry into biosynthesis. Nature. PMID 37138074 DOI: 10.1038/s41586-023-06027-2  0.309
2023 Yu IF, Manske JL, Diéguez-Vázquez A, Misale A, Pashenko AE, Mykhailiuk PK, Ryabukhin SV, Volochnyuk DM, Hartwig JF. Catalytic undirected borylation of tertiary C-H bonds in bicyclo[1.1.1]pentanes and bicyclo[2.1.1]hexanes. Nature Chemistry. PMID 36973434 DOI: 10.1038/s41557-023-01159-4  0.829
2023 Ma S, Fan H, Day CS, Xi Y, Hartwig JF. Remote Hydroamination of Disubstituted Alkenes by a Combination of Isomerization and Regioselective N-H Addition. Journal of the American Chemical Society. PMID 36780535 DOI: 10.1021/jacs.2c13054  0.681
2022 Choi K, Mormino MG, Kalkman ED, Park J, Hartwig JF. Palladium-Catalyzed Aryldifluoromethylation of Aryl Halides with Aryldifluoromethyl Trimethylsilanes. Angewandte Chemie (International Ed. in English). PMID 35960816 DOI: 10.1002/anie.202208204  0.442
2022 Ma S, Xi Y, Fan H, Roediger S, Hartwig JF. Enantioselective hydroamination of unactivated terminal alkenes. Chem. 8: 532-542. PMID 35647390 DOI: 10.1016/j.chempr.2021.12.005  0.39
2021 Tlahuext-Aca A, Hartwig JF. Site-Selective Silver-Catalyzed C-H Bond Deuteration of Five-Membered Aromatic Heterocycles and Pharmaceuticals. Acs Catalysis. 11: 1119-1127. PMID 35586574 DOI: 10.1021/acscatal.0c04917  0.364
2021 Tlahuext-Aca A, Lee SY, Sakamoto S, Hartwig JF. Direct Arylation of Simple Arenes with Aryl Bromides by Synergistic Silver and Palladium Catalysis. Acs Catalysis. 11: 1430-1434. PMID 34790433 DOI: 10.1021/acscatal.0c05254  0.577
2021 Su B, Hartwig JF. Development of Chiral Ligands for the Transition Metal-catalyzed Enantioselective Silylation and Borylation of C-H Bonds. Angewandte Chemie (International Ed. in English). PMID 34729899 DOI: 10.1002/anie.202113343  0.605
2021 Butcher TW, Amberg WM, Hartwig JF. Transition-Metal-Catalyzed Monofluoroalkylation: Strategies for the Synthesis of Alkyl Fluorides by C-C Bond Formation. Angewandte Chemie (International Ed. in English). PMID 34658121 DOI: 10.1002/anie.202112251  0.368
2021 Day CS, Fawcett A, Chatterjee R, Hartwig JF. Mechanistic Investigation of the Iron-Catalyzed Azidation of Alkyl C()-H Bonds with Zhdankin's λ-Azidoiodane. Journal of the American Chemical Society. PMID 34559970 DOI: 10.1021/jacs.1c07330  0.679
2021 Sakamoto S, Butcher TW, Yang JL, Hartwig JF. gem-Difluoroallylation of Aryl Halides and Pseudo Halides with Difluoroallylboron Reagents in High Regioselectivity. Angewandte Chemie (International Ed. in English). PMID 34555220 DOI: 10.1002/anie.202111476  0.423
2021 Kalkman ED, Hartwig JF. Direct Observation of Diastereomeric α-C-Bound Enolates during Enantioselective α-Arylations: Synthesis, Characterization, and Reactivity of Arylpalladium Fluorooxindole Complexes. Journal of the American Chemical Society. 143: 11741-11750. PMID 34308646 DOI: 10.1021/jacs.1c05346  0.401
2021 Fuentes MA, Gava R, Saper NI, Romero E, Caballero A, Hartwig JF, Pérez PJ. Copper-Catalyzed Dehydrogenative Amidation of Light Alkanes. Angewandte Chemie (International Ed. in English). PMID 33979475 DOI: 10.1002/anie.202104737  0.371
2021 Ji P, Park J, Gu Y, Clark DS, Hartwig JF. Abiotic reduction of ketones with silanes catalysed by carbonic anhydrase through an enzymatic zinc hydride. Nature Chemistry. PMID 33603222 DOI: 10.1038/s41557-020-00633-7  0.593
2021 Hartwig JF, Fawcett A, Keller MJ, Herrera Z. Site Selective Chlorination of C(sp3)-H Bonds Suitable for Late-Stage Functionalization. Angewandte Chemie (International Ed. in English). PMID 33480134 DOI: 10.1002/anie.202016548  0.337
2020 Richers CP, Roediger S, Laserna V, Hartwig JF. Effects of ligands on the migratory insertion of alkenes into rhodium-oxygen bonds. Chemical Science. 11: 10449-10456. PMID 34123185 DOI: 10.1039/d0sc04402d  0.341
2020 Ray R, Hartwig JF. Oxalohydrazide Ligands for Copper-Catalyzed C-O Coupling Reactions with High Turnover Numbers. Angewandte Chemie (International Ed. in English). PMID 33377249 DOI: 10.1002/anie.202015654  0.689
2020 Ma S, Hill CK, Olen CL, Hartwig JF. Ruthenium-Catalyzed Hydroamination of Unactivated Terminal Alkenes with Stoichiometric Amounts of Alkene and an Ammonia Surrogate by Sequential Oxidation and Reduction. Journal of the American Chemical Society. PMID 33356181 DOI: 10.1021/jacs.0c11043  0.447
2020 Larsen MA, Oeschger RJ, Hartwig JF. Effect of Ligand Structure on the Electron Density and Activity of Iridium Catalysts for the Borylation of Alkanes. Acs Catalysis. 10: 3415-3424. PMID 33178481 DOI: 10.1021/acscatal.0c00152  0.379
2020 Xi Y, Ma S, Hartwig JF. Catalytic asymmetric addition of an amine N-H bond across internal alkenes. Nature. PMID 33142305 DOI: 10.1038/s41586-020-2919-z  0.413
2020 Qiu Y, Hartwig JF. Mechanism of Ni-Catalyzed Oxidations of Unactivated C(sp)-H Bonds. Journal of the American Chemical Society. PMID 33111517 DOI: 10.1021/jacs.0c09157  0.341
2020 Karmel C, Rubel CZ, Kharitonova EV, Hartwig JF. Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand. Angewandte Chemie (Weinheim An Der Bergstrasse, Germany). 132: 6130-6137. PMID 33071367 DOI: 10.1002/ange.201916015  0.456
2020 Xi Y, Su B, Qi X, Pedram S, Liu P, Hartwig JF. Application of Trimethylgermanyl-Substituted Bisphosphine Ligands with Enhanced Dispersion Interactions to Copper-Catalyzed Hydrobo-ration of Disubstituted Alkenes. Journal of the American Chemical Society. PMID 32962336 DOI: 10.1021/jacs.0c08746  0.572
2020 Wang JY, Choi K, Zuend SJ, Borate K, Shinde H, Goetz R, Hartwig JF. Cross-Coupling between Hydrazine and Aryl Halides with Hydroxide Base at Low Loadings of Palladium by Rate-Determining Deprotonation of Bound Hydrazine. Angewandte Chemie (International Ed. in English). PMID 32929852 DOI: 10.1002/Anie.202011161  0.515
2020 Butcher TW, Yang JL, Hartwig JF. Copper-Catalyzed Defluorinative Borylation and Silylation of -Difluoroallyl Groups. Organic Letters. PMID 32841569 DOI: 10.1021/Acs.Orglett.0C02321  0.422
2020 Butcher TW, Yang JL, Amberg WM, Watkins NB, Wilkinson ND, Hartwig JF. Desymmetrization of difluoromethylene groups by C-F bond activation. Nature. PMID 32480398 DOI: 10.1038/S41586-020-2399-1  0.421
2020 Oeschger R, Su B, Yu I, Ehinger C, Romero E, He S, Hartwig J. Diverse functionalization of strong alkyl C-H bonds by undirected borylation. Science (New York, N.Y.). 368: 736-741. PMID 32409470 DOI: 10.1126/Science.Aba6146  0.813
2020 Karmel C, Hartwig JF. Mechanism of the Iridium-Catalyzed Silylation of Aromatic C-H Bonds. Journal of the American Chemical Society. 142: 10494-10505. PMID 32375477 DOI: 10.1021/Jacs.0C03301  0.514
2020 Su B, Bunescu A, Qiu Y, Zuend SJ, Ernst M, Hartwig JF. Palladium-catalyzed oxidation of β-C(sp3)-H bond of primary alkylamines through a rare four-membered palladacycle intermediate. Journal of the American Chemical Society. PMID 32216373 DOI: 10.1021/Jacs.0C01629  0.639
2020 Saper NI, Ohgi A, Small DW, Semba K, Nakao Y, Hartwig JF. Nickel-catalysed anti-Markovnikov hydroarylation of unactivated alkenes with unactivated arenes facilitated by non-covalent interactions. Nature Chemistry. PMID 32042137 DOI: 10.1038/S41557-019-0409-4  0.491
2020 Karmel C, Rubel CZ, Kharitonova EV, Hartwig JF. Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand. Angewandte Chemie (International Ed. in English). PMID 31968139 DOI: 10.1002/Anie.201916015  0.547
2020 Richers CP, Roediger S, Laserna V, Hartwig JF. Effects of Ancillary Ligands on the Insertion of Alkenes into Rhodium-Oxygen Bonds§ Chemical Science. DOI: 10.1039/D0Sc04402D  0.444
2020 Hanna S, Wills T, Butcher TW, Hartwig JF. Palladium-Catalyzed Oxidative Dehydrosilylation forContra-Thermodynamic Olefin Isomerization Acs Catalysis. 10: 8736-8741. DOI: 10.1021/Acscatal.0C02697  0.436
2020 Larsen MA, Oeschger RJ, Hartwig JF. Effect of Ligand Structure on the Electron Density and Activity of Iridium Catalysts for the Borylation of Alkanes Acs Catalysis. 10: 3415-3424. DOI: 10.1021/Acscatal.0C00152  0.451
2019 Dorel R, Boehm P, Schwinger DP, Hartwig JF. Copper-mediated Fluorination of Aryl Trisiloxanes with Nucleophilic Fluoride. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31872488 DOI: 10.1002/Chem.201905040  0.479
2019 Yoritate M, Londregan AT, Lian Y, Hartwig JF. Sequential Xanthalation and -Trifluoromethylation of Phenols: A Procedure for the Synthesis of Aryl Trifluoromethyl Ethers. The Journal of Organic Chemistry. PMID 31738556 DOI: 10.1021/Acs.Joc.9B02717  0.468
2019 Hartwig JF, Romero EA. Iridium-Catalyzed Silylation of Unactivated C-H Bonds. Tetrahedron. 75: 4059-4070. PMID 31723309 DOI: 10.1016/J.Tet.2019.05.055  0.444
2019 Kalkman ED, Mormino MG, Hartwig JF. Unusual Electronic Effects of Ancillary Ligands on the Perfluoroalkylation of Aryl Iodides and Bromides Mediated by Copper(I) Pentafluoro-ethyl Complexes of Substituted Bipyridines. Journal of the American Chemical Society. PMID 31722521 DOI: 10.1021/Jacs.9B10540  0.456
2019 Oeschger RJ, Larsen MA, Bismuto A, Hartwig JF. Origin of the Difference in Reactivity between Ir Catalysts for the Borylation of C-H Bonds. Journal of the American Chemical Society. PMID 31539230 DOI: 10.1021/Jacs.9B08920  0.496
2019 He ZT, Hartwig JF. Palladium-catalyzed α-arylation for the addition of small rings to aromatic compounds. Nature Communications. 10: 4083. PMID 31501444 DOI: 10.1038/S41467-019-12090-Z  0.414
2019 Hanna S, Butcher TW, Hartwig JF. Contra-thermodynamic Olefin Isomerization by Chain-Walking Hydrofunctionalization and Formal Retro-hydrofunctionalization. Organic Letters. PMID 31424215 DOI: 10.1021/Acs.Orglett.9B02695  0.419
2019 Gu Y, Natoli SN, Liu Z, Clark DS, Hartwig JF. Site-Selective Functionalization of (sp3)C-H Bonds Catayzed by Artificial Metalloenzymes Containing an Iridium-Porphyrin Cofactor. Angewandte Chemie (International Ed. in English). PMID 31356719 DOI: 10.1002/Anie.201907460  0.453
2019 He ZT, Jiang X, Hartwig JF. Stereodivergent Construction of Tertiary Fluorides in Vicinal Stereogenic Pairs by Allylic Substitution with Iridium and Copper Catalysts. Journal of the American Chemical Society. PMID 31343170 DOI: 10.1021/Jacs.9B04440  0.481
2019 He ZT, Hartwig JF. Palladium-Catalyzed α-Arylation of Carboxylic Acids and Secondary Amides via a Traceless Protecting Strategy. Journal of the American Chemical Society. PMID 31287682 DOI: 10.1021/Jacs.9B03291  0.432
2019 Karmel C, Chen Z, Hartwig JF. Iridium-Catalyzed Silylation of C-H bonds in Unactivated Arenes: A Sterically-Encumbered Phenanthroline Ligand Accelerates Catalysis Enabling New Reactivity. Journal of the American Chemical Society. PMID 30971087 DOI: 10.1021/Jacs.9B01972  0.51
2019 Haydl AM, Hartwig JF. Palladium-Catalyzed Methylation of Aryl, Heteroaryl, and Vinyl Boronate Esters. Organic Letters. PMID 30763109 DOI: 10.1021/Acs.Orglett.9B00025  0.824
2019 Natoli SN, Hartwig JF. Noble-Metal Substitution in Hemoproteins: An Emerging Strategy for Abiological Catalysis. Accounts of Chemical Research. PMID 30693758 DOI: 10.1021/Acs.Accounts.8B00586  0.464
2019 Hanna S, Holder JC, Hartwig JF. Multicatalytic Approach to the Hydroaminomethylation of α-Olefins. Angewandte Chemie (International Ed. in English). PMID 30635956 DOI: 10.1002/Anie.201811297  0.46
2019 Jiang Q, Peacock DM, Hartwig JF, Cundari TR. Carbon(sp3)-nitrogen bond-forming reductive elimination from phosphine-ligated alkylpalladium(II) amide complexes: A DFT study Tetrahedron. 75: 137-143. DOI: 10.1016/J.Tet.2018.11.044  0.45
2019 Hartwig JF, Shaughnessy KH, Shekhar S, Green RA. Palladium‐Catalyzed Amination of Aryl Halides Organic Reactions. 853-958. DOI: 10.1002/0471264180.Or100.14  0.791
2018 He ZT, Hartwig JF. Enantioselective α-functionalizations of ketones via allylic substitution of silyl enol ethers. Nature Chemistry. PMID 30455430 DOI: 10.1038/S41557-018-0165-X  0.488
2018 He ZT, Li H, Haydl AM, Whiteker GT, Hartwig JF. Trimethylphosphate as a Methylating Agent for Cross Coupling: A Slow-release Mechanism for the Methylation of Arylboronic Esters. Journal of the American Chemical Society. PMID 30419749 DOI: 10.1021/Jacs.8B10076  0.828
2018 Su B, Lee T, Hartwig JF. Iridium-catalyzed, β-selective C(sp3)-H silylation of aliphatic amines to form silapyrrolidines and 1,2-amino alcohols. Journal of the American Chemical Society. PMID 30354144 DOI: 10.1021/Jacs.8B10428  0.66
2018 Butcher TW, Hartwig JF. Enantioselective Synthesis of Tertiary Allylic Fluorides by Iridium-Catalyzed Allylic Fluoroalkylation. Angewandte Chemie (International Ed. in English). PMID 30136379 DOI: 10.1002/Anie.201807474  0.5
2018 Zhang QW, Hartwig JF. Synthesis of heteroaromatic trifluoromethyl ethers with trifluoromethyl triflate as the source of the trifluoromethoxy group. Chemical Communications (Cambridge, England). PMID 30129643 DOI: 10.1039/C8Cc05084H  0.429
2018 Litman ZC, Wang Y, Zhao H, Hartwig JF. Cooperative asymmetric reactions combining photocatalysis and enzymatic catalysis. Nature. 560: 355-359. PMID 30111790 DOI: 10.1038/S41586-018-0413-7  0.491
2018 Wang JY, Strom AE, Hartwig JF. Mechanistic Studies of Palladium-Catalyzed Aminocarbonylation of Aryl Chlorides with Carbon Monoxide and Ammonia. Journal of the American Chemical Society. PMID 29852736 DOI: 10.1021/Jacs.8B04073  0.56
2018 Su B, Hartwig JF. Ir-Catalyzed, Silyl-Directed, peri-Borylation of C-H Bonds in Fused Polycyclic Arenes and Heteroarenes. Angewandte Chemie (International Ed. in English). PMID 29779224 DOI: 10.1002/Anie.201805086  0.603
2018 Peacock DM, Jiang Q, Hanley PS, Cundari TR, Hartwig JF. Reductive Elimination from Phosphine-ligated Alkylpalladium(II) Amido Complexes to Form sp3 Carbon-Nitrogen Bonds. Journal of the American Chemical Society. PMID 29537835 DOI: 10.1021/Jacs.8B00928  0.803
2018 Jiang X, Boehm P, Hartwig JF. Stereodivergent Allylation of Azaaryl Acetamides and Acetates by Synergistic Iridium and Copper Catalysis. Journal of the American Chemical Society. PMID 29319306 DOI: 10.1021/Jacs.7B12824  0.502
2018 Karmel C, Li BJ, Hartwig JF. Rhodium-Catalyzed Regioselective Silylation of Alkyl C-H Bonds for the Synthesis of 1,4-Diols. Journal of the American Chemical Society. PMID 29293327 DOI: 10.1021/Jacs.7B11964  0.478
2018 Peacock DM, Jiang Q, Cundari TR, Hartwig JF. Reductive Elimination to Form C(sp3)–N Bonds from Palladium(II) Primary Alkyl Complexes Organometallics. 37: 3243-3247. DOI: 10.1021/Acs.Organomet.8B00617  0.488
2018 Karimov RR, Hartwig JF. Übergangsmetall-katalysierte selektive Funktionalisierung von C(sp3 )-H-Bindungen in Naturstoffen Angewandte Chemie. 130: 4309-4317. DOI: 10.1002/Ange.201710330  0.302
2017 Litman ZC, Sharma A, Hartwig JF. Oxidation of Hindered Allylic C-H Bonds with Applications to the Functionalization of Complex Molecules. Acs Catalysis. 7: 1998-2001. PMID 29910970 DOI: 10.1021/Acscatal.6B03648  0.455
2017 Bunescu A, Butcher TW, Hartwig JF. Traceless silylation of β-C(sp3)-H bonds of alcohols via perfluorinated acetals. Journal of the American Chemical Society. PMID 29283571 DOI: 10.1021/Jacs.7B12150  0.379
2017 Karimov RR, Hartwig JF. Transition-Metal-Catalyzed Selective Functionalization of C(sp3)-H Bonds in Natural Products. Angewandte Chemie (International Ed. in English). PMID 29228463 DOI: 10.1002/Anie.201710330  0.801
2017 Giri R, Brusoe A, Troshin K, Wang JY, Font M, Hartwig JF. Mechanism of the Ullmann Biaryl Ether Synthesis Catalyzed by Complexes of Anionic Ligands. Evidence for the Reaction of Iodoarenes With Ligated Anionic CuI Intermediates. Journal of the American Chemical Society. PMID 29224350 DOI: 10.1021/Jacs.7B11853  0.837
2017 Hill CK, Hartwig JF. Site-selective oxidation, amination and epimerization reactions of complex polyols enabled by transfer hydrogenation. Nature Chemistry. 9: 1213-1221. PMID 29168493 DOI: 10.1038/Nchem.2835  0.393
2017 Saper N, Hartwig JF. Mechanistic Investigations of the Hydrogenolysis of Diaryl Ethers Catalyzed by Nickel Complexes of N-Heterocyclic Carbene Ligands. Journal of the American Chemical Society. PMID 29116776 DOI: 10.1021/Jacs.7B10537  0.535
2017 Arlow SI, Hartwig JF. Synthesis, Characterization, and Reactivity of Palladium Fluoroenolate Complexes. Journal of the American Chemical Society. PMID 29077395 DOI: 10.1021/Jacs.7B09949  0.525
2017 Hartwig JF. Catalyst-Controlled Site-Selective Bond Activation. Accounts of Chemical Research. 50: 549-555. PMID 28945414 DOI: 10.1021/Acs.Accounts.6B00546  0.431
2017 Bunescu A, Lee S, Li Q, Hartwig JF. Catalytic Hydroxylation of Polyethylenes. Acs Central Science. 3: 895-903. PMID 28852704 DOI: 10.1021/Acscentsci.7B00255  0.393
2017 Su B, Hartwig JF. Iridium-Catalyzed Enantioselective Silylation of Unactivated C(sp3)-H Bonds. Journal of the American Chemical Society. PMID 28820264 DOI: 10.1021/Jacs.7B06679  0.624
2017 Xi Y, Hartwig JF. Mechanistic Studies of Copper-Catalyzed Asymmetric Hydroboration of Alkenes. Journal of the American Chemical Society. PMID 28787137 DOI: 10.1021/Jacs.7B07124  0.507
2017 Troshin K, Hartwig JF. Snap deconvolution: An informatics approach to high-throughput discovery of catalytic reactions. Science (New York, N.Y.). 357: 175-181. PMID 28706066 DOI: 10.1126/Science.Aan1568  0.435
2017 Jiang X, Hartwig JF. Iridium-Catalyzed Enantioselective Allylic Substitutions of Aliphatic Esters via Silyl Ketene Acetals. Angewandte Chemie (International Ed. in English). PMID 28597600 DOI: 10.1002/Anie.201704354  0.454
2017 Su B, Zhou TG, Xu PL, Shi ZJ, Hartwig JF. Enantioselective Borylation of Aromatic C-H Bonds with Chiral Dinitrogen Ligands. Angewandte Chemie (International Ed. in English). PMID 28508564 DOI: 10.1002/Anie.201702628  0.691
2017 Key HM, Dydio P, Liu Z, Rha JY, Nazarenko A, Seyedkazemi V, Clark DS, Hartwig JF. Beyond Iron: Iridium-Containing P450 Enzymes for Selective Cyclopropanations of Structurally Diverse Alkenes. Acs Central Science. 3: 302-308. PMID 28470047 DOI: 10.1021/Acscentsci.6B00391  0.423
2017 Xia T, He L, Liu YA, Hartwig JF, Liao X. Palladium-Catalyzed Cross-Coupling of Ethyl Bromodifluoroacetate with Aryl Bromides or Triflates and Cross-Coupling of Ethyl Bromofluoroacetate with Aryl Iodides. Organic Letters. PMID 28467714 DOI: 10.1021/Acs.Orglett.7B00938  0.485
2017 Lee T, Hartwig JF. Mechanistic Studies on Rhodium-Catalyzed Enantioselective Silylation of Aryl C-H Bonds. Journal of the American Chemical Society. PMID 28278372 DOI: 10.1021/Jacs.7B00737  0.465
2017 Jin Y, Chen M, Ge S, Hartwig JF. Palladium-Catalyzed, Enantioselective α-Arylation of α-Fluorooxindoles. Organic Letters. PMID 28263071 DOI: 10.1021/Acs.Orglett.7B00294  0.387
2017 Ge S, Green RA, Hartwig JF. Correction to "Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex". Journal of the American Chemical Society. PMID 28212008 DOI: 10.1021/jacs.7b01463  0.321
2017 Dydio P, Key HM, Hayashi H, Clark DS, Hartwig JF. Chemoselective, Enzymatic C-H Bond Amination Catalyzed by a Cytochrome P450 Containing an Ir(Me)-PIX Cofactor. Journal of the American Chemical Society. PMID 28080030 DOI: 10.1021/Jacs.6B11410  0.465
2017 Wang Y, Bartlett MJ, Denard CA, Hartwig JF, Zhao H. Combining Rh-Catalyzed Diazocoupling and Enzymatic Reduction To Efficiently Synthesize Enantioenriched 2-Substituted Succinate Derivatives Acs Catalysis. 7: 2548-2552. DOI: 10.1021/Acscatal.7B00254  0.839
2017 Fier PS, Hartwig JF. Site‐Selective C‐H Fluorination of Pyridines and Diazines with AgF2 Organic Syntheses. 94: 46-53. DOI: 10.1002/0471264229.Os094.04  0.742
2016 Strom AE, Balcells D, Hartwig JF. Synthetic and Computational Studies on the Rhodium-Catalyzed Hydroamination of Aminoalkenes. Acs Catalysis. 6: 5651-5665. PMID 28713642 DOI: 10.1021/Acscatal.6B01320  0.442
2016 Jiang X, Beiger JJ, Hartwig JF. Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis. Journal of the American Chemical Society. PMID 27977923 DOI: 10.1021/Jacs.6B11692  0.44
2016 Su B, Zhou TG, Li XW, Shao XR, Xu PL, Wu WL, Hartwig JF, Shi ZJ. A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C-H Bonds. Angewandte Chemie (International Ed. in English). PMID 27976482 DOI: 10.1002/Anie.201609939  0.721
2016 Jiao Z, Beiger JJ, Jin Y, Ge S, Zhou JS, Hartwig JF. Palladium-Catalyzed Enantioselective α-Arylation of α-Fluoroketones. Journal of the American Chemical Society. 138: 15980-15986. PMID 27960323 DOI: 10.1021/jacs.6b09580  0.662
2016 Morstein J, Kalkman ED, Bold C, Cheng C, Hartwig JF. Correction to "Copper-Mediated C-N Coupling of Arylsilanes with Nitrogen Nucleophiles". Organic Letters. 18: 6216. PMID 27934346 DOI: 10.1021/Acs.Orglett.6B03242  0.327
2016 Zhang J, Shrestha R, Hartwig JF, Zhao P. A decarboxylative approach for regioselective hydroarylation of alkynes. Nature Chemistry. 8: 1144-1151. PMID 27874862 DOI: 10.1038/Nchem.2602  0.759
2016 Dydio P, Key HM, Nazarenko A, Rha JY, Seyedkazemi V, Clark DS, Hartwig JF. An artificial metalloenzyme with the kinetics of native enzymes. Science (New York, N.Y.). 354: 102-106. PMID 27846500 DOI: 10.1126/Science.Aah4427  0.383
2016 Karimov RR, Sharma A, Hartwig JF. Late Stage Azidation of Complex Molecules. Acs Central Science. 2: 715-724. PMID 27800554 DOI: 10.1021/Acscentsci.6B00214  0.833
2016 Lee SY, Hartwig JF. Palladium-Catalyzed, Site-Selective Direct Allylation of Aryl C-H Bonds by Silver-Mediated C-H Activation: A Synthetic and Mechanistic Investigation. Journal of the American Chemical Society. PMID 27797512 DOI: 10.1021/Jacs.6B10220  0.663
2016 Peacock DM, Roos CB, Hartwig JF. Palladium-Catalyzed Cross Coupling of Secondary and Tertiary Alkyl Bromides with a Nitrogen Nucleophile. Acs Central Science. 2: 647-652. PMID 27725963 DOI: 10.1021/Acscentsci.6B00187  0.531
2016 Morstein J, Kalkman ED, Cheng C, Hartwig JF. Copper-Mediated C-N Coupling of Arylsilanes with Nitrogen Nucleophiles. Organic Letters. PMID 27689746 DOI: 10.1021/Acs.Orglett.6B02543  0.399
2016 Cheng C, Watts A, Hillmyer MA, Hartwig JF. Polysilylether: A Degradable Polymer from Biorenewable Feedstocks. Angewandte Chemie (International Ed. in English). PMID 27572134 DOI: 10.1002/Anie.201606282  0.368
2016 Chen M, Hartwig JF. Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles. Angewandte Chemie (International Ed. in English). PMID 27531137 DOI: 10.1002/Anie.201607053  0.514
2016 Zhang QW, Brusoe AT, Mascitti V, Hesp KD, Blakemore DC, Kohrt JT, Hartwig JF. Fluorodecarboxylation for the Synthesis of Trifluoromethyl Aryl Ethers. Angewandte Chemie (International Ed. in English). PMID 27384710 DOI: 10.1002/Anie.201604793  0.834
2016 Key HM, Dydio P, Clark DS, Hartwig JF. Abiological catalysis by artificial haem proteins containing noble metals in place of iron. Nature. PMID 27296224 DOI: 10.1038/Nature17968  0.337
2016 Hartwig JF, Larsen MA. Undirected, Homogeneous C-H Bond Functionalization: Challenges and Opportunities. Acs Central Science. 2: 281-92. PMID 27294201 DOI: 10.1021/Acscentsci.6B00032  0.421
2016 Lee T, Hartwig JF. Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C-H Bonds. Angewandte Chemie (International Ed. in English). PMID 27253898 DOI: 10.1002/Anie.201603153  0.463
2016 Morstein J, Hou H, Cheng C, Hartwig JF. Trifluoromethylation of Arylsilanes with [(phen)CuCF3 ]. Angewandte Chemie (International Ed. in English). PMID 27214849 DOI: 10.1002/Anie.201601163  0.445
2016 Xi Y, Hartwig JF. Diverse Asymmetric Hydrofunctionalization of Aliphatic Internal Alkenes Through Catalytic Regioselective Hydroboration. Journal of the American Chemical Society. PMID 27167490 DOI: 10.1021/Jacs.6B02478  0.454
2016 Jiang X, Chen W, Hartwig JF. Iridium-Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic α-Alkoxy Ketones. Angewandte Chemie (International Ed. in English). PMID 27038004 DOI: 10.1002/Anie.201600235  0.472
2016 Arlow SI, Hartwig JF. Synthesis of Aryldifluoroamides by Copper-Catalyzed Cross-Coupling. Angewandte Chemie (International Ed. in English). PMID 26929068 DOI: 10.1002/Anie.201600105  0.42
2016 Larsen MA, Cho SH, Hartwig JF. Iridium-Catalyzed, Hydrosilyl-Directed Borylation of Unactivated Alkyl C-H Bonds. Journal of the American Chemical Society. PMID 26745739 DOI: 10.1021/Jacs.5B12153  0.61
2016 Gao F, Webb JD, Sorek H, Wemmer DE, Hartwig JF. Fragmentation of Lignin Samples with Commercial Pd/C under Ambient Pressure of Hydrogen Acs Catalysis. 6: 7385-7392. DOI: 10.1021/Acscatal.6B02028  0.414
2016 Strom AE, Balcells D, Hartwig JF. Synthetic and Computational Studies on the Rhodium-Catalyzed Hydroamination of Aminoalkenes Acs Catalysis. 6: 5651-5665. DOI: 10.1021/acscatal.6b01320  0.331
2015 Gao F, Webb JD, Hartwig JF. Chemo- and Regioselective Hydrogenolysis of Diaryl Ether CO Bonds by a Robust Heterogeneous Ni/C Catalyst: Applications to the Cleavage of Complex Lignin-Related Fragments. Angewandte Chemie (International Ed. in English). PMID 26666391 DOI: 10.1002/Anie.201509133  0.411
2015 Wang DY, Choliy Y, Haibach MC, Hartwig JF, Krogh-Jespersen K, Goldman AS. Assessment of the Electronic Factors Determining the Thermodynamics of 'Oxidative Addition' of C-H and N-H Bonds to Ir(I) Complexes. Journal of the American Chemical Society. PMID 26652221 DOI: 10.1021/Jacs.5B09522  0.417
2015 Xi Y, Butcher TW, Zhang J, Hartwig JF. Regioselective, Asymmetric Formal Hydroamination of Unactivated Internal Alkenes. Angewandte Chemie (International Ed. in English). PMID 26592363 DOI: 10.1002/Anie.201509235  0.512
2015 Hartwig JF. Evolution of C-H Bond Functionalization from Methane to Methodology. Journal of the American Chemical Society. PMID 26566092 DOI: 10.1021/Jacs.5B08707  0.475
2015 Madrahimov ST, Li Q, Sharma A, Hartwig JF. Origins of Regioselectivity in Iridium Catalyzed Allylic Substitution. Journal of the American Chemical Society. PMID 26498382 DOI: 10.1021/Jacs.5B08911  0.804
2015 Chen M, Hartwig JF. Iridium-Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides. Journal of the American Chemical Society. PMID 26441002 DOI: 10.1021/Jacs.5B09980  0.51
2015 Schramm Y, Takeuchi M, Semba K, Nakao Y, Hartwig JF. Anti-Markovnikov Hydroheteroarylation of Unactivated Alkenes with Indoles, Pyrroles, Benzofurans, and Furans Catalyzed by a Nickel-N-Heterocyclic Carbene System. Journal of the American Chemical Society. 137: 12215-8. PMID 26334367 DOI: 10.1021/Jacs.5B08039  0.556
2015 Larsen MA, Wilson CV, Hartwig JF. Iridium-Catalyzed Borylation of Primary Benzylic C-H Bonds without a Directing Group: Scope, Mechanism, and Origins of Selectivity. Journal of the American Chemical Society. PMID 26076367 DOI: 10.1021/Jacs.5B04899  0.518
2015 Brusoe AT, Hartwig JF. Palladium-Catalyzed Arylation of Fluoroalkylamines. Journal of the American Chemical Society. PMID 26065341 DOI: 10.1021/Jacs.5B02512  0.861
2015 Key HM, Clark DS, Hartwig JF. Generation, Characterization, and Tunable Reactivity of Organometallic Fragments Bound to a Protein Ligand. Journal of the American Chemical Society. 137: 8261-8. PMID 26020584 DOI: 10.1021/Jacs.5B04431  0.433
2015 Lee T, Wilson TW, Berg R, Ryberg P, Hartwig JF. Rhodium-catalyzed enantioselective silylation of arene C-h bonds: desymmetrization of diarylmethanols. Journal of the American Chemical Society. 137: 6742-5. PMID 25948056 DOI: 10.1021/Jacs.5B03091  0.452
2015 Cheng C, Hartwig JF. Catalytic Silylation of Unactivated C-H Bonds. Chemical Reviews. PMID 25714857 DOI: 10.1021/Cr5006414  0.392
2015 Green RA, Hartwig JF. Nickel-catalyzed amination of aryl chlorides with ammonia or ammonium salts. Angewandte Chemie (International Ed. in English). 54: 3768-72. PMID 25711163 DOI: 10.1002/Anie.201500404  0.484
2015 Sharma A, Hartwig JF. Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization. Nature. 517: 600-4. PMID 25631448 DOI: 10.1038/Nature14127  0.489
2015 Cheng C, Hartwig JF. Iridium-catalyzed silylation of aryl C-H bonds. Journal of the American Chemical Society. 137: 592-5. PMID 25514197 DOI: 10.1021/Ja511352U  0.526
2015 Snieckus V, Garcia-Irizarry CN, Schramm Y, Takeuchi M, Semba K, Nakao Y, Hartwig JF. Nickel-Catalyzed Anti-Markovnikov Hydroheteroarylation of Nonactivated Alkenes Synfacts. 11: 1251-1251. DOI: 10.1055/S-0035-1560902  0.347
2015 Denard CA, Bartlett MJ, Wang Y, Lu L, Hartwig JF, Zhao H. Development of a One-Pot tandem reaction combining ruthenium-catalyzed alkene metathesis and enantioselective enzymatic oxidation to produce Aryl epoxides Acs Catalysis. 5: 3817-3822. DOI: 10.1021/Acscatal.5B00533  0.84
2014 Tran BL, Driess M, Hartwig JF. Copper-catalyzed oxidative dehydrogenative carboxylation of unactivated alkanes to allylic esters via alkenes. Journal of the American Chemical Society. 136: 17292-301. PMID 25389772 DOI: 10.1021/Ja510093X  0.444
2014 Chen W, Chen M, Hartwig JF. Diastereo- and enantioselective iridium-catalyzed allylation of cyclic ketone enolates: synergetic effect of ligands and barium enolates. Journal of the American Chemical Society. 136: 15825-8. PMID 25337972 DOI: 10.1021/Ja506500U  0.531
2014 Ge S, Arlow SI, Mormino MG, Hartwig JF. Pd-catalyzed α-arylation of trimethylsilyl enolates of α,α-difluoroacetamides. Journal of the American Chemical Society. 136: 14401-4. PMID 25254966 DOI: 10.1021/Ja508590K  0.347
2014 Chen M, Hartwig JF. Iridium-catalyzed regio- and enantioselective allylic substitution of silyl dienolates derived from dioxinones. Angewandte Chemie (International Ed. in English). 53: 12172-6. PMID 25223593 DOI: 10.1002/Anie.201406778  0.501
2014 Bair JS, Schramm Y, Sergeev AG, Clot E, Eisenstein O, Hartwig JF. Linear-selective hydroarylation of unactivated terminal and internal olefins with trifluoromethyl-substituted arenes. Journal of the American Chemical Society. 136: 13098-101. PMID 25171744 DOI: 10.1021/Ja505579F  0.508
2014 Green RA, Hartwig JF. Palladium-catalyzed amination of aryl chlorides and bromides with ammonium salts. Organic Letters. 16: 4388-91. PMID 25133675 DOI: 10.1021/Ol501739G  0.484
2014 Cheng C, Hartwig JF. Mechanism of the rhodium-catalyzed silylation of arene C-H bonds. Journal of the American Chemical Society. 136: 12064-72. PMID 25082802 DOI: 10.1021/Ja505844K  0.471
2014 Sevov CS, Hartwig JF. Iridium-catalyzed oxidative olefination of furans with unactivated alkenes. Journal of the American Chemical Society. 136: 10625-31. PMID 25032781 DOI: 10.1021/Ja504414C  0.807
2014 Li Q, Driess M, Hartwig JF. Iridium-catalyzed regioselective silylation of aromatic and benzylic C-H bonds directed by a secondary amine. Angewandte Chemie (International Ed. in English). 53: 8471-4. PMID 24962972 DOI: 10.1002/Anie.201404620  0.478
2014 Fier PS, Hartwig JF. Synthesis and late-stage functionalization of complex molecules through C-H fluorination and nucleophilic aromatic substitution. Journal of the American Chemical Society. 136: 10139-47. PMID 24918484 DOI: 10.1021/Ja5049303  0.766
2014 Chen M, Hartwig JF. Iridium-catalyzed enantioselective allylic substitution of unstabilized enolates derived from α,β-unsaturated ketones. Angewandte Chemie (International Ed. in English). 53: 8691-5. PMID 24917569 DOI: 10.1002/Anie.201403844  0.442
2014 Li Q, Liskey CW, Hartwig JF. Regioselective borylation of the C-H bonds in alkylamines and alkyl ethers. Observation and origin of high reactivity of primary C-H bonds beta to nitrogen and oxygen. Journal of the American Chemical Society. 136: 8755-65. PMID 24836159 DOI: 10.1021/Ja503676D  0.83
2014 Li B, Driess M, Hartwig JF. Iridium-catalyzed regioselective silylation of secondary alkyl C-H bonds for the synthesis of 1,3-diols. Journal of the American Chemical Society. 136: 6586-9. PMID 24734777 DOI: 10.1021/Ja5026479  0.434
2014 Mormino MG, Fier PS, Hartwig JF. Copper-mediated perfluoroalkylation of heteroaryl bromides with (phen)CuRF. Organic Letters. 16: 1744-7. PMID 24621138 DOI: 10.1021/Ol500422T  0.773
2014 Ge S, ChaÅ‚adaj W, Hartwig JF. Pd-catalyzed α-arylation of α,α-difluoroketones with aryl bromides and chlorides. A route to difluoromethylarenes. Journal of the American Chemical Society. 136: 4149-52. PMID 24588379 DOI: 10.1021/Ja501117V  0.508
2014 Cheng C, Hartwig JF. Rhodium-catalyzed intermolecular C-H silylation of arenes with high steric regiocontrol. Science (New York, N.Y.). 343: 853-7. PMID 24558154 DOI: 10.1126/Science.1248042  0.495
2014 Denard CA, Huang H, Bartlett MJ, Lu L, Tan Y, Zhao H, Hartwig JF. Cooperative tandem catalysis by an organometallic complex and a metalloenzyme. Angewandte Chemie (International Ed. in English). 53: 465-9. PMID 24536102 DOI: 10.1002/Anie.201305778  0.81
2014 Larsen MA, Hartwig JF. Iridium-catalyzed C-H borylation of heteroarenes: scope, regioselectivity, application to late-stage functionalization, and mechanism. Journal of the American Chemical Society. 136: 4287-99. PMID 24506058 DOI: 10.1021/Ja412563E  0.487
2014 Sevov CS, Zhou JS, Hartwig JF. Iridium-catalyzed, intermolecular hydroamination of unactivated alkenes with indoles. Journal of the American Chemical Society. 136: 3200-7. PMID 24483848 DOI: 10.1021/Ja412116D  0.85
2014 Tran BL, Li B, Driess M, Hartwig JF. Copper-catalyzed intermolecular amidation and imidation of unactivated alkanes. Journal of the American Chemical Society. 136: 2555-63. PMID 24405209 DOI: 10.1021/Ja411912P  0.489
2014 Ge S, Green RA, Hartwig JF. Controlling first-row catalysts: amination of aryl and heteroaryl chlorides and bromides with primary aliphatic amines catalyzed by a BINAP-ligated single-component Ni(0) complex. Journal of the American Chemical Society. 136: 1617-27. PMID 24397570 DOI: 10.1021/Ja411911S  0.456
2014 Chen W, Hartwig JF. Cation control of diastereoselectivity in iridium-catalyzed allylic substitutions. Formation of enantioenriched tertiary alcohols and thioethers by allylation of 5H-oxazol-4-ones and 5H-thiazol-4-ones. Journal of the American Chemical Society. 136: 377-82. PMID 24295427 DOI: 10.1021/Ja410650E  0.464
2014 Cho SH, Hartwig JF. Iridium-catalyzed diborylation of benzylic C-H bonds directed by a hydrosilyl group: Synthesis of 1,1-benzyldiboronate esters Chemical Science. 5: 694-698. DOI: 10.1039/C3Sc52824C  0.624
2013 Fier PS, Hartwig JF. Selective C-H fluorination of pyridines and diazines inspired by a classic amination reaction. Science (New York, N.Y.). 342: 956-60. PMID 24264986 DOI: 10.1126/Science.1243759  0.789
2013 Sharma A, Hartwig JF. Enantioselective functionalization of allylic C-H bonds following a strategy of functionalization and diversification. Journal of the American Chemical Society. 135: 17983-9. PMID 24156776 DOI: 10.1021/Ja409995W  0.479
2013 Gallego D, Brück A, Irran E, Meier F, Kaupp M, Driess M, Hartwig JF. From bis(silylene) and bis(germylene) pincer-type nickel(II) complexes to isolable intermediates of the nickel-catalyzed Sonogashira cross-coupling reaction. Journal of the American Chemical Society. 135: 15617-26. PMID 24053603 DOI: 10.1021/Ja408137T  0.469
2013 Hama T, Ge S, Hartwig JF. Palladium-catalyzed α-arylation of zinc enolates of esters: reaction conditions and substrate scope. The Journal of Organic Chemistry. 78: 8250-66. PMID 23931445 DOI: 10.1021/Jo401476F  0.545
2013 Strom AE, Hartwig JF. One-pot anti-Markovnikov hydroamination of unactivated alkenes by hydrozirconation and amination. The Journal of Organic Chemistry. 78: 8909-14. PMID 23899320 DOI: 10.1021/Jo401498W  0.394
2013 Cheng C, Simmons EM, Hartwig JF. Iridium-catalyzed, diastereoselective dehydrogenative silylation of terminal alkenes with (TMSO)2MeSiH. Angewandte Chemie (International Ed. in English). 52: 8984-9. PMID 23857914 DOI: 10.1002/Anie.201304084  0.467
2013 Hanley PS, Hartwig JF. Migratory insertion of alkenes into metal-oxygen and metal-nitrogen bonds. Angewandte Chemie (International Ed. in English). 52: 8510-25. PMID 23832532 DOI: 10.1002/Anie.201300134  0.781
2013 Sevov CS, Hartwig JF. Iridium-catalyzed, intermolecular hydroetherification of unactivated aliphatic alkenes with phenols. Journal of the American Chemical Society. 135: 9303-6. PMID 23758128 DOI: 10.1021/Ja4052153  0.793
2013 Cho SH, Hartwig JF. Iridium-catalyzed borylation of secondary benzylic C-H bonds directed by a hydrosilane. Journal of the American Chemical Society. 135: 8157-60. PMID 23682736 DOI: 10.1021/Ja403462B  0.63
2013 Shrestha R, Mukherjee P, Tan Y, Litman ZC, Hartwig JF. Sterically controlled, palladium-catalyzed intermolecular amination of arenes. Journal of the American Chemical Society. 135: 8480-3. PMID 23678959 DOI: 10.1021/Ja4032677  0.77
2013 Liskey CW, Hartwig JF. Iridium-catalyzed C-H borylation of cyclopropanes. Journal of the American Chemical Society. 135: 3375-8. PMID 23421575 DOI: 10.1021/Ja400103P  0.839
2013 Fier PS, Luo J, Hartwig JF. Copper-mediated fluorination of arylboronate esters. Identification of a copper(III) fluoride complex. Journal of the American Chemical Society. 135: 2552-9. PMID 23384209 DOI: 10.1021/Ja310909Q  0.756
2013 Sevov CS, Hartwig JF. Iridium-catalyzed intermolecular asymmetric hydroheteroarylation of bicycloalkenes. Journal of the American Chemical Society. 135: 2116-9. PMID 23346874 DOI: 10.1021/Ja312360C  0.815
2013 Fier PS, Hartwig JF. Synthesis of difluoromethyl ethers with difluoromethyltriflate. Angewandte Chemie (International Ed. in English). 52: 2092-5. PMID 23307535 DOI: 10.1002/Anie.201209250  0.703
2013 Chen W, Hartwig JF. Control of diastereoselectivity for iridium-catalyzed allylation of a prochiral nucleophile with a phosphate counterion. Journal of the American Chemical Society. 135: 2068-71. PMID 23286279 DOI: 10.1021/Ja311363A  0.487
2013 Partridge BM, Hartwig JF. Sterically controlled iodination of arenes via iridium-catalyzed C-H borylation. Organic Letters. 15: 140-3. PMID 23256483 DOI: 10.1021/Ol303164H  0.431
2013 Robbins DW, Hartwig JF. Sterically controlled alkylation of arenes through iridium-catalyzed C-H borylation. Angewandte Chemie (International Ed. in English). 52: 933-7. PMID 23233236 DOI: 10.1002/Anie.201208203  0.711
2013 Liskey CW, Hartwig JF. Borylation of arenes with bis(hexylene glycolato)diboron Synthesis (Germany). 45: 1837-1842. DOI: 10.1055/S-0033-1338863  0.835
2013 Denard CA, Hartwig JF, Zhao H. Multistep one-pot reactions combining biocatalysts and chemical catalysts for asymmetric synthesis Acs Catalysis. 3: 2856-2864. DOI: 10.1021/Cs400633A  0.807
2013 Hanley PS, Hartwig JF. Migratorische Insertion von Alkenen in Metall-Sauerstoff- und Metall-Stickstoff-Bindungen Angewandte Chemie. 125: 8668-8684. DOI: 10.1002/Ange.201300134  0.726
2012 Chen C, Weng Z, Hartwig JF. Synthesis of Copper(I) Thiolate Complexes in the Thioetherification of Aryl Halides. Organometallics. 31: 8031-8037. PMID 23316098 DOI: 10.1021/Om300711C  0.458
2012 Sergeev AG, Webb JD, Hartwig JF. A heterogeneous nickel catalyst for the hydrogenolysis of aryl ethers without arene hydrogenation. Journal of the American Chemical Society. 134: 20226-9. PMID 23163756 DOI: 10.1021/Ja3085912  0.407
2012 Ge S, Hartwig JF. Highly reactive, single-component nickel catalyst precursor for Suzuki-Miyuara cross-coupling of heteroaryl boronic acids with heteroaryl halides. Angewandte Chemie (International Ed. in English). 51: 12837-41. PMID 23136047 DOI: 10.1002/Anie.201207428  0.44
2012 Brück A, Gallego D, Wang W, Irran E, Driess M, Hartwig JF. Pushing the σ-donor strength in iridium pincer complexes: bis(silylene) and bis(germylene) ligands are stronger donors than bis(phosphorus(III)) ligands. Angewandte Chemie (International Ed. in English). 51: 11478-82. PMID 23073912 DOI: 10.1002/Anie.201205570  0.349
2012 Chen W, Hartwig JF. Iridium-catalyzed regioselective and enantioselective allylation of trimethylsiloxyfuran. Journal of the American Chemical Society. 134: 15249-52. PMID 22954355 DOI: 10.1021/Ja306850B  0.519
2012 Hanley PS, Marquard SL, Cundari TR, Hartwig JF. Reductive elimination of alkylamines from low-valent, alkylpalladium(II) amido complexes. Journal of the American Chemical Society. 134: 15281-4. PMID 22934822 DOI: 10.1021/Ja307558X  0.828
2012 Robbins DW, Hartwig JF. A C-H borylation approach to Suzuki-Miyaura coupling of typically unstable 2-heteroaryl and polyfluorophenyl boronates. Organic Letters. 14: 4266-9. PMID 22853624 DOI: 10.1021/Ol301570T  0.735
2012 Liskey CW, Hartwig JF. Iridium-catalyzed borylation of secondary C-H bonds in cyclic ethers. Journal of the American Chemical Society. 134: 12422-5. PMID 22804581 DOI: 10.1021/Ja305596V  0.816
2012 Sevov CS, Zhou J, Hartwig JF. Iridium-catalyzed intermolecular hydroamination of unactivated aliphatic alkenes with amides and sulfonamides. Journal of the American Chemical Society. 134: 11960-3. PMID 22780090 DOI: 10.1021/Ja3052848  0.812
2012 Fier PS, Hartwig JF. Copper-mediated fluorination of aryl iodides. Journal of the American Chemical Society. 134: 10795-8. PMID 22709145 DOI: 10.1021/Ja304410X  0.795
2012 Madrahimov ST, Hartwig JF. Origins of enantioselectivity during allylic substitution reactions catalyzed by metallacyclic iridium complexes. Journal of the American Chemical Society. 134: 8136-47. PMID 22486270 DOI: 10.1021/Ja212217J  0.823
2012 Fier PS, Hartwig JF. Copper-mediated difluoromethylation of aryl and vinyl iodides. Journal of the American Chemical Society. 134: 5524-7. PMID 22397683 DOI: 10.1021/Ja301013H  0.787
2012 Simmons EM, Hartwig JF. On the interpretation of deuterium kinetic isotope effects in C-H bond functionalizations by transition-metal complexes. Angewandte Chemie (International Ed. in English). 51: 3066-72. PMID 22392731 DOI: 10.1002/Anie.201107334  0.382
2012 Simmons EM, Hartwig JF. Catalytic functionalization of unactivated primary C-H bonds directed by an alcohol. Nature. 483: 70-3. PMID 22382981 DOI: 10.1038/Nature10785  0.45
2012 Klinkenberg JL, Hartwig JF. Reductive elimination from arylpalladium cyanide complexes. Journal of the American Chemical Society. 134: 5758-61. PMID 22352451 DOI: 10.1021/Ja300827T  0.441
2012 Tan Y, Barrios-Landeros F, Hartwig JF. Mechanistic studies on direct arylation of pyridine N-oxide: evidence for cooperative catalysis between two distinct palladium centers. Journal of the American Chemical Society. 134: 3683-6. PMID 22313324 DOI: 10.1021/Ja2122156  0.83
2012 Huang Z, Hartwig JF. Copper(I) enolate complexes in α-arylation reactions: synthesis, reactivity, and mechanism. Angewandte Chemie (International Ed. in English). 51: 1028-32. PMID 22162321 DOI: 10.1002/Anie.201106719  0.469
2012 Litvinas ND, Fier PS, Hartwig JF. A general strategy for the perfluoroalkylation of arenes and arylbromides by using arylboronate esters and [(phen)CuR(F)]. Angewandte Chemie (International Ed. in English). 51: 536-9. PMID 22083965 DOI: 10.1002/Anie.201106668  0.76
2012 Hartwig JF. Borylation and silylation of C-H bonds: a platform for diverse C-H bond functionalizations. Accounts of Chemical Research. 45: 864-73. PMID 22075137 DOI: 10.1021/Ar200206A  0.531
2012 Huang DS, DeLuca RJ, Hartwig JF. α‐Arylation of Esters Catalyzed by the Pd(I) Dimer [P(t‐Bu)3Pd(μ‐Br)]2 Organic Syntheses. 4-13. DOI: 10.1002/0471264229.Os088.01  0.423
2011 Ge S, Hartwig JF. Nickel-catalyzed asymmetric α-arylation and heteroarylation of ketones with chloroarenes: effect of halide on selectivity, oxidation state, and room-temperature reactions. Journal of the American Chemical Society. 133: 16330-3. PMID 21916501 DOI: 10.1021/Ja2082087  0.457
2011 Robbins DW, Hartwig JF. A simple, multidimensional approach to high-throughput discovery of catalytic reactions. Science (New York, N.Y.). 333: 1423-7. PMID 21903809 DOI: 10.1126/Science.1207922  0.744
2011 Hanley PS, Hartwig JF. Intermolecular migratory insertion of unactivated olefins into palladium-nitrogen bonds. Steric and electronic effects on the rate of migratory insertion. Journal of the American Chemical Society. 133: 15661-73. PMID 21815675 DOI: 10.1021/Ja205722F  0.783
2011 Marquard SL, Hartwig JF. C(sp3)-O bond-forming reductive elimination of ethers from bisphosphine-ligated benzylpalladium(II) aryloxide complexes. Angewandte Chemie (International Ed. in English). 50: 7119-23. PMID 21688359 DOI: 10.1002/Anie.201101088  0.736
2011 Sergeev AG, Hartwig JF. Selective, nickel-catalyzed hydrogenolysis of aryl ethers. Science (New York, N.Y.). 332: 439-43. PMID 21512027 DOI: 10.1126/Science.1200437  0.444
2011 Morimoto H, Tsubogo T, Litvinas ND, Hartwig JF. A broadly applicable copper reagent for trifluoromethylations and perfluoroalkylations of aryl iodides and bromides. Angewandte Chemie (International Ed. in English). 50: 3793-8. PMID 21442711 DOI: 10.1002/Anie.201100633  0.42
2011 Hartwig JF. Regioselectivity of the borylation of alkanes and arenes. Chemical Society Reviews. 40: 1992-2002. PMID 21336364 DOI: 10.1039/C0Cs00156B  0.457
2011 Tan Y, Hartwig JF. Assessment of the intermediacy of arylpalladium carboxylate complexes in the direct arylation of benzene: evidence for C-H bond cleavage by "ligandless" species. Journal of the American Chemical Society. 133: 3308-11. PMID 21314146 DOI: 10.1021/Ja1113936  0.71
2011 Liu Z, Yamamichi H, Madrahimov ST, Hartwig JF. Rhodium phosphine-π-arene intermediates in the hydroamination of alkenes. Journal of the American Chemical Society. 133: 2772-82. PMID 21309512 DOI: 10.1021/Ja1057949  0.836
2011 Carrow BP, Hartwig JF. Distinguishing between pathways for transmetalation in Suzuki-Miyaura reactions. Journal of the American Chemical Society. 133: 2116-9. PMID 21280669 DOI: 10.1021/Ja1108326  0.78
2011 Liao X, Stanley LM, Hartwig JF. Enantioselective total syntheses of (-)-taiwaniaquinone H and (-)-taiwaniaquinol B by iridium-catalyzed borylation and palladium-catalyzed asymmetric α-arylation. Journal of the American Chemical Society. 133: 2088-91. PMID 21268578 DOI: 10.1021/Ja110215B  0.488
2011 Hartwig JF. Hydrocarbon synthesis: Ringing the chains. Nature Chemistry. 3: 99-101. PMID 21258380 DOI: 10.1038/Nchem.978  0.439
2011 Klinkenberg JL, Hartwig JF. Catalytic organometallic reactions of ammonia. Angewandte Chemie (International Ed. in English). 50: 86-95. PMID 20857466 DOI: 10.1002/Anie.201002354  0.471
2011 Hartwig JF, Pouy MJ. Iridium-catalyzed allylic substitution Topics in Organometallic Chemistry. 34: 169-208. DOI: 10.1007/978-3-642-15334-1_7  0.842
2011 Liao X, Stanley LM, Hartwig JF. ChemInform Abstract: Enantioselective Total Syntheses of (-)-Taiwaniaquinone H (I) and (-)-Taiwaniaquinol B (II) by Iridium-Catalyzed Borylation and Palladium-Catalyzed Asymmetric α-Arylation. Cheminform. 42: no-no. DOI: 10.1002/CHIN.201127191  0.315
2010 Simmons EM, Hartwig JF. Iridium-catalyzed arene ortho-silylation by formal hydroxyl-directed C-H activation. Journal of the American Chemical Society. 132: 17092-5. PMID 21077625 DOI: 10.1021/Ja1086547  0.474
2010 Giri R, Hartwig JF. Cu(I)-amido complexes in the Ullmann reaction: reactions of Cu(I)-amido complexes with iodoarenes with and without autocatalysis by CuI. Journal of the American Chemical Society. 132: 15860-3. PMID 20977264 DOI: 10.1021/Ja105695S  0.655
2010 Hartwig JF, Stanley LM. Mechanistically driven development of iridium catalysts for asymmetric allylic substitution. Accounts of Chemical Research. 43: 1461-75. PMID 20873839 DOI: 10.1021/Ar100047X  0.517
2010 Julian LD, Hartwig JF. Intramolecular hydroamination of unbiased and functionalized primary aminoalkenes catalyzed by a rhodium aminophosphine complex. Journal of the American Chemical Society. 132: 13813-22. PMID 20839807 DOI: 10.1021/Ja1052126  0.533
2010 Klinkenberg JL, Hartwig JF. Slow reductive elimination from arylpalladium parent amido complexes. Journal of the American Chemical Society. 132: 11830-3. PMID 20695642 DOI: 10.1021/Ja1023404  0.389
2010 Liskey CW, Liao X, Hartwig JF. Cyanation of arenes via iridium-catalyzed borylation. Journal of the American Chemical Society. 132: 11389-91. PMID 20677758 DOI: 10.1021/Ja104442V  0.831
2010 Huang Z, Zhou JS, Hartwig JF. N-H activation of hydrazines by iridium(I). Double N-H activation to form iridium aminonitrene complexes. Journal of the American Chemical Society. 132: 11458-60. PMID 20672808 DOI: 10.1021/Ja1053835  0.455
2010 Huang DS, Hartwig JF. Palladium-catalyzed gamma-arylation of alpha,beta-unsaturated esters from silyl ketene acetals. Angewandte Chemie (International Ed. in English). 49: 5757-61. PMID 20607784 DOI: 10.1002/Anie.201002328  0.428
2010 Stanley LM, Bai C, Ueda M, Hartwig JF. Iridium-catalyzed kinetic asymmetric transformations of racemic allylic benzoates. Journal of the American Chemical Society. 132: 8918-20. PMID 20552969 DOI: 10.1021/Ja103779E  0.518
2010 Hanley PS, Markovi? D, Hartwig JF. Intermolecular insertion of ethylene and octene into a palladium-amide bond. Spectroscopic evidence for an ethylene amido intermediate. Journal of the American Chemical Society. 132: 6302-3. PMID 20408534 DOI: 10.1021/Ja102172M  0.819
2010 Robbins DW, Boebel TA, Hartwig JF. Iridium-catalyzed, silyl-directed borylation of nitrogen-containing heterocycles. Journal of the American Chemical Society. 132: 4068-9. PMID 20199022 DOI: 10.1021/Ja1006405  0.737
2010 Tye JW, Weng Z, Giri R, Hartwig JF. Copper(I) phenoxide complexes in the etherification of aryl halides. Angewandte Chemie (International Ed. in English). 49: 2185-9. PMID 20198667 DOI: 10.1002/Anie.200902245  0.827
2010 Tan Y, Hartwig JF. Palladium-catalyzed amination of aromatic C-H bonds with oxime esters. Journal of the American Chemical Society. 132: 3676-7. PMID 20187645 DOI: 10.1021/Ja100676R  0.684
2010 Wei CS, Jiménez-Hoyos CA, Videa MF, Hartwig JF, Hall MB. Origins of the selectivity for borylation of primary over secondary C-H bonds catalyzed by Cp*-rhodium complexes. Journal of the American Chemical Society. 132: 3078-91. PMID 20121104 DOI: 10.1021/Ja909453G  0.412
2010 Fernández-Rodríguez MA, Hartwig JF. One-pot synthesis of unsymmetrical diaryl thioethers by palladium-catalyzed coupling of two aryl bromides and a thiol surrogate. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 2355-9. PMID 20112309 DOI: 10.1002/Chem.200902313  0.41
2010 Sawyer KR, Cahoon JF, Shanoski JE, Glascoe EA, Kling MF, Schlegel JP, Zoerb MC, Hapke M, Hartwig JF, Webster CE, Harris CB. Time-resolved IR studies on the mechanism for the functionalization of primary C-H bonds by photoactivated Cp*W(CO)3(Bpin). Journal of the American Chemical Society. 132: 1848-59. PMID 20099849 DOI: 10.1021/Ja906438A  0.717
2010 Mkhalid IA, Barnard JH, Marder TB, Murphy JM, Hartwig JF. C-H activation for the construction of C-B bonds. Chemical Reviews. 110: 890-931. PMID 20028025 DOI: 10.1021/Cr900206P  0.65
2010 Marquard SL, Rosenfeld DC, Hartwig JF. C(sp(3))-N bond-forming reductive elimination of amines: reactions of bisphosphine-ligated benzylpalladium(II) diarylamido complexes. Angewandte Chemie (International Ed. in English). 49: 793-6. PMID 20025002 DOI: 10.1002/Anie.200904032  0.774
2010 Carrow BP, Hartwig JF. Ligandless, anionic, arylpalladium halide intermediates in the Heck reaction. Journal of the American Chemical Society. 132: 79-81. PMID 20014842 DOI: 10.1021/Ja909306F  0.798
2010 Ueda M, Hartwig JF. Iridium-catalyzed, regio- and enantioselective allylic substitution with aromatic and aliphatic sulfinates. Organic Letters. 12: 92-4. PMID 19954200 DOI: 10.1021/Ol9023248  0.501
2010 Hartwig J, Stanley L, Bai C, Ueda M. Kinetic Asymmetric Substitution of Racemic Allylic Esters Synfacts. 2010: 1163-1163. DOI: 10.1055/s-0030-1258643  0.346
2010 Ishiyama T, Takagi J, Hartwig JF, Miyaura N. ChemInform Abstract: A Stoichiometric Aromatic C-H Borylation Catalyzed by Iridium(I)/2,2′-Bipyridine Complexes at Room Temperature. Cheminform. 33: no-no. DOI: 10.1002/CHIN.200251174  0.302
2010 Takagi J, Sato K, Hartwig JF, Ishiyama T, Miyaura N. ChemInform Abstract: Iridium-Catalyzed C-H Coupling Reaction of Heteroaromatic Compounds with Bis(pinacolato)diboron: Regioselective Synthesis of Heteroarylboronates. Cheminform. 33: no-no. DOI: 10.1002/CHIN.200244181  0.362
2010 Beare NA, Hartwig JF. ChemInform Abstract: Palladium-Catalyzed Arylation of Malonates and Cyanoesters Using Sterically Hindered Trialkyl- and Ferrocenyldialkylphosphine Ligands. Cheminform. 33: no-no. DOI: 10.1002/CHIN.200226065  0.359
2010 Lee S, Joergensen M, Hartwig JF. ChemInform Abstract: Palladium-Catalyzed Synthesis of Arylamines from Aryl Halides and Lithium Bis(trimethylsilyl)amide as an Ammonia Equivalent. Cheminform. 32: no-no. DOI: 10.1002/CHIN.200151097  0.388
2010 Lee S, Hartwig JF. ChemInform Abstract: Improved Catalysts for the Palladium-Catalyzed Synthesis of Oxindoles by Amide α-Arylation. Rate Acceleration, Use of Aryl Chloride Substrates, and a New Carbene Ligand for Asymmetric Transformations. Cheminform. 32: no-no. DOI: 10.1002/CHIN.200140113  0.346
2010 Loeber O, Kawatsura M, Hartwig JF. ChemInform Abstract: Palladium-Catalyzed Hydroamination of 1,3-Dienes: A Colorimetric Assay and Enantioselective Additions. Cheminform. 32: no-no. DOI: 10.1002/CHIN.200137094  0.357
2010 Goodson FE, Hauck SI, Hartwig JF. ChemInform Abstract: Palladium-Catalyzed Synthesis of Pure, Regiodefined Polymeric Triarylamines. Cheminform. 30: no-no. DOI: 10.1002/CHIN.199952235  0.335
2010 Kawatsura M, Hartwig JF. ChemInform Abstract: Simple, Highly Active Palladium Catalysts for Ketone and Malonate Arylation: Dissecting the Importance of Chelation and Steric Hindrance. Cheminform. 30: no-no. DOI: 10.1002/CHIN.199928079  0.306
2010 SHAUGHNESSY KH, HAMANN BC, HARTWIG JF. ChemInform Abstract: Palladium-Catalyzed Inter- and Intramolecular α-Arylation of Amides. Application of Intramolecular Amide Arylation to the Synthesis of Oxindoles. Cheminform. 30: no-no. DOI: 10.1002/CHIN.199907067  0.34
2010 HAMANN BC, HARTWIG JF. ChemInform Abstract: Sterically Hindered Chelating Alkyl Phosphines Provide Large Rate Accelerations in Palladium-Catalyzed Amination of Aryl Iodides, Bromides, and Chlorides, and the First Amination of Aryl Tosylates. Cheminform. 29: no-no. DOI: 10.1002/CHIN.199847091  0.413
2010 MANN G, HARTWIG JF, DRIVER MS, FERNANDEZ-RIVAS C. ChemInform Abstract: Palladium-Catalyzed C-N(sp2) Bond Formation: N-Arylation of Aromatic and Unsaturated Nitrogen and the Reductive Elimination Chemistry of Palladium Azolyl and Methyleneamido Complexes. Cheminform. 29: no-no. DOI: 10.1002/CHIN.199825077  0.35
2010 HAMANN BC, HARTWIG JF. ChemInform Abstract: Palladium-Catalyzed Direct α-Arylation of Ketones. Rate Acceleration by Sterically Hindered Chelating Ligands and Reductive Elimination from a Transition Metal Enolate Complex. Cheminform. 29: no-no. DOI: 10.1002/CHIN.199817100  0.322
2010 MANN G, HARTWIG JF. ChemInform Abstract: Palladium-Catalyzed Formation of Diaryl Ethers from Aryl Bromides. Electron Poor Phosphines Enhance Reaction Yields. Cheminform. 29: no-no. DOI: 10.1002/CHIN.199807121  0.391
2010 MANN G, HARTWIG JF. ChemInform Abstract: Nickel- vs Palladium-Catalyzed Synthesis of Protected Phenols from Aryl Halides. Cheminform. 28: no-no. DOI: 10.1002/CHIN.199752100  0.369
2010 LOUIE J, DRIVER MS, HAMANN BC, HARTWIG JF. ChemInform Abstract: Palladium-Catalyzed Amination of Aryl Triflates and Importance of Triflate Addition Rate. Cheminform. 28: no-no. DOI: 10.1002/chin.199730084  0.598
2010 DRIVER MS, HARTWIG JF. ChemInform Abstract: A Second-Generation Catalyst for Aryl Halide Amination: Mixed Secondary Amines from Aryl Halides and Primary Amines Catalyzed by ( dppf)PdCl2 Cheminform. 27: no-no. DOI: 10.1002/CHIN.199645087  0.359
2010 LOUIE J, HARTWIG JF. ChemInform Abstract: Palladium-Catalyzed Synthesis of Arylamines from Aryl Halides. Mechanistic Studies Lead to Coupling in the Absence of Tin Reagents. Cheminform. 26: no-no. DOI: 10.1002/chin.199541128  0.597
2010 Huang D, Hartwig J. Corrigendum: Palladium-Catalyzed γ-Arylation of α,β-Unsaturated Esters from Silyl Ketene Acetals Angewandte Chemie International Edition. 49: 7154-7154. DOI: 10.1002/Anie.201090130  0.333
2010 Huang D, Hartwig J. Berichtigung: Palladium-Catalyzed γ-Arylation of α,β-Unsaturated Esters from Silyl Ketene Acetals Angewandte Chemie. 122: 7310-7310. DOI: 10.1002/Ange.201090130  0.333
2010 Zhou J, Hartwig JF. Intermolecular, catalytic asymmetric hydroamination of bicyclic alkenes and dienes in high yield and enantioselectivity Chemtracts. 23: 115-118.  0.341
2009 Tye JW, Hartwig JF. Computational studies of the relative rates for migratory insertions of alkenes into square-planar, methyl, -amido, and -hydroxo complexes of rhodium. Journal of the American Chemical Society. 131: 14703-12. PMID 19778020 DOI: 10.1021/Ja901945B  0.762
2009 Stanley LM, Hartwig JF. Iridium-catalyzed regio- and enantioselective N-allylation of indoles. Angewandte Chemie (International Ed. in English). 48: 7841-4. PMID 19760689 DOI: 10.1002/Anie.200904338  0.488
2009 Liskey CW, Wei CS, Pahls DR, Hartwig JF. Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C-H bonds. Chemical Communications (Cambridge, England). 5603-5. PMID 19753371 DOI: 10.1039/B913949D  0.831
2009 Pouy MJ, Stanley LM, Hartwig JF. Enantioselective, iridium-catalyzed monoallylation of ammonia. Journal of the American Chemical Society. 131: 11312-3. PMID 19722644 DOI: 10.1021/Ja905059R  0.838
2009 Vo GD, Hartwig JF. Palladium-catalyzed coupling of ammonia with aryl chlorides, bromides, iodides, and sulfonates: a general method for the preparation of primary arylamines. Journal of the American Chemical Society. 131: 11049-61. PMID 19591470 DOI: 10.1021/Ja903049Z  0.839
2009 Weix DJ, Marković D, Ueda M, Hartwig JF. Direct, intermolecular, enantioselective, iridium-catalyzed allylation of carbamates to form carbamate-protected, branched allylic amines. Organic Letters. 11: 2944-7. PMID 19552468 DOI: 10.1021/Ol901151U  0.746
2009 Stanley LM, Hartwig JF. Regio- and enantioselective N-allylations of imidazole, benzimidazole, and purine heterocycles catalyzed by single-component metallacyclic iridium complexes. Journal of the American Chemical Society. 131: 8971-83. PMID 19480431 DOI: 10.1021/Ja902243S  0.485
2009 Barrios-Landeros F, Carrow BP, Hartwig JF. Effect of ligand steric properties and halide identity on the mechanism for oxidative addition of haloarenes to trialkylphosphine Pd(0) complexes. Journal of the American Chemical Society. 131: 8141-54. PMID 19469511 DOI: 10.1021/Ja900798S  0.807
2009 Alvaro E, Hartwig JF. Resting state and elementary steps of the coupling of aryl halides with thiols catalyzed by alkylbisphosphine complexes of palladium. Journal of the American Chemical Society. 131: 7858-68. PMID 19453106 DOI: 10.1021/Ja901793W  0.471
2009 Madrahimov ST, Markovic D, Hartwig JF. The allyl intermediate in regioselective and enantioselective iridium-catalyzed asymmetric allylic substitution reactions. Journal of the American Chemical Society. 131: 7228-9. PMID 19432473 DOI: 10.1021/Ja902609G  0.815
2009 Fernández-Rodríguez MA, Hartwig JF. A general, efficient, and functional-group-tolerant catalyst system for the palladium-catalyzed thioetherification of aryl bromides and iodides. The Journal of Organic Chemistry. 74: 1663-72. PMID 19154131 DOI: 10.1021/Jo802594D  0.506
2009 Pouy MJ, Stanley LM, Hartwig JF. Enantioselective Monoallylation of Ammonia Synfacts. 2009: 1231-1231. DOI: 10.1055/S-0029-1218131  0.377
2009 Weix DJ, Marković D, Ueda M, Hartwig JF. Iridium-Catalyzed Allylation of Carbamates Synfacts. 2009: 1113-1113. DOI: 10.1055/S-0029-1217913  0.743
2009 Liskey CW, Wei CS, Pahls DR, Hartwig JF. Erratum: Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C-H bonds (Chemical Communications (2009) (5603-5605) DOI: 10.1039/b913949d) Chemical Communications. DOI: 10.1039/B924083G  0.815
2008 Alexanian EJ, Hartwig JF. Mechanistic study of beta-hydrogen elimination from organoplatinum(II) enolate complexes. Journal of the American Chemical Society. 130: 15627-35. PMID 18954048 DOI: 10.1021/Ja8056908  0.739
2008 Herzon SB, Hartwig JF. Hydroaminoalkylation of unactivated olefins with dialkylamines. Journal of the American Chemical Society. 130: 14940-1. PMID 18937477 DOI: 10.1021/Ja806367E  0.745
2008 Ogata T, Hartwig JF. Palladium-catalyzed amination of aryl and heteroaryl tosylates at room temperature. Journal of the American Chemical Society. 130: 13848-9. PMID 18811161 DOI: 10.1021/Ja805810P  0.527
2008 Hartwig JF. Carbon-heteroatom bond formation catalysed by organometallic complexes. Nature. 455: 314-22. PMID 18800130 DOI: 10.1038/Nature07369  0.457
2008 Shen Q, Hartwig JF. [(CyPF-(t)Bu)PdCl2]: an air-stable, one-component, highly efficient catalyst for amination of heteroaryl and aryl halides. Organic Letters. 10: 4109-12. PMID 18715012 DOI: 10.1021/Ol801615U  0.639
2008 Zhou JS, Hartwig JF. Intermolecular, catalytic asymmetric hydroamination of bicyclic alkenes and dienes in high yield and enantioselectivity. Journal of the American Chemical Society. 130: 12220-1. PMID 18715004 DOI: 10.1021/Ja803523Z  0.534
2008 Hartwig JF. Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides. Accounts of Chemical Research. 41: 1534-44. PMID 18681463 DOI: 10.1021/Ar800098P  0.504
2008 Tye JW, Weng Z, Johns AM, Incarvito CD, Hartwig JF. Copper complexes of anionic nitrogen ligands in the amidation and imidation of aryl halides. Journal of the American Chemical Society. 130: 9971-83. PMID 18597458 DOI: 10.1021/Ja076668W  0.841
2008 Zhou J, Hartwig JF. Iridium-catalyzed H/D exchange at vinyl groups without olefin isomerization. Angewandte Chemie (International Ed. in English). 47: 5783-7. PMID 18576446 DOI: 10.1002/Anie.200801992  0.621
2008 Boebel TA, Hartwig JF. Silyl-directed, iridium-catalyzed ortho-borylation of arenes. A one-pot ortho-borylation of phenols, arylamines, and alkylarenes. Journal of the American Chemical Society. 130: 7534-5. PMID 18494474 DOI: 10.1021/Ja8015878  0.483
2008 Shen Q, Ogata T, Hartwig JF. Highly reactive, general and long-lived catalysts for palladium-catalyzed amination of heteroaryl and aryl chlorides, bromides, and iodides: scope and structure-activity relationships. Journal of the American Chemical Society. 130: 6586-96. PMID 18444639 DOI: 10.1021/Ja077074W  0.634
2008 Barrios-Landeros F, Carrow BP, Hartwig JF. Autocatalytic oxidative addition of PhBr to Pd(PtBu3)2 via Pd(PtBu3)2(H)(Br). Journal of the American Chemical Society. 130: 5842-3. PMID 18402444 DOI: 10.1021/Ja711159Y  0.791
2008 Hama T, Hartwig JF. Palladium-catalyzed alpha-arylation of esters with chloroarenes. Organic Letters. 10: 1549-52. PMID 18358039 DOI: 10.1021/Ol800258U  0.475
2008 Hama T, Hartwig JF. Alpha-arylation of esters catalyzed by the Pd(I) dimer {[P(t-Bu)3]PdBr}2. Organic Letters. 10: 1545-8. PMID 18358038 DOI: 10.1021/Ol8002578  0.443
2008 Vo GD, Hartwig JF. Palladium-catalyzed alpha-arylation of aldehydes with bromo- and chloroarenes catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos. Angewandte Chemie (International Ed. in English). 47: 2127-30. PMID 18260078 DOI: 10.1002/Anie.200705357  0.814
2008 Ueno S, Hartwig JF. Direct, iridium-catalyzed enantioselective and regioselective allylic etherification with aliphatic alcohols. Angewandte Chemie (International Ed. in English). 47: 1928-31. PMID 18236502 DOI: 10.1002/Anie.200705267  0.372
2008 Liu Z, Hartwig JF. Mild, rhodium-catalyzed intramolecular hydroamination of unactivated terminal and internal alkenes with primary and secondary amines. Journal of the American Chemical Society. 130: 1570-1. PMID 18183986 DOI: 10.1021/Ja710126X  0.492
2008 Liao X, Weng Z, Hartwig JF. Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel. Journal of the American Chemical Society. 130: 195-200. PMID 18076166 DOI: 10.1021/Ja074453G  0.514
2008 Hartwig J, Hama T. Palladium-Catalyzed α-Arylation of Esters Synfacts. 2008: 0750-0750. DOI: 10.1055/S-2008-1077836  0.389
2008 Ueno S, Hartwig JF. Iridium-Catalyzed Asymmetric Allylic Etherification Synfacts. 2008: 500-500. DOI: 10.1055/S-2008-1072667  0.504
2008 Liao X, Weng Z, Hartwig JF. Difluorphos Complexes of Palladium and Nickel-Catalyzed α-Arylation of Ketones Synfacts. 2008: 385-385. DOI: 10.1055/S-2008-1042872  0.441
2008 Boebel TA, Hartwig JF. Iridium-catalyzed preparation of silylboranes by silane borylation and their use in the catalytic borylation of arenes Organometallics. 27: 6013-6019. DOI: 10.1021/Om800696D  0.557
2008 Zhao P, Hartwig JF. Insertions of ketones and nitriles into organorhodium(i) complexes and β-hydrocarbyl eliminations from rhodium(I) alkoxo and iminyl complexes Organometallics. 27: 4749-4757. DOI: 10.1021/Om800378V  0.582
2008 Boebel TA, Hartwig JF. Conversion of 1,3-disubstituted arenes to chiral α,α-diaryl methylammonium chlorides using arene borylation Tetrahedron. 64: 6824-6830. DOI: 10.1016/J.Tet.2008.04.060  0.379
2008 Vo GD, Hartwig JF. ChemInform Abstract: Palladium-Catalyzed α-Arylation of Aldehydes with Bromo- and Chloroarenes Catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos. Cheminform. 39. DOI: 10.1002/chin.200829078  0.819
2008 Stavropoulos P, Çelenligil-Çetin R, Kiani S, Tapper A, Pinnapareddy D, Paraskevopoulou P, Adam W, Zhao CG, Bühler B, Schmid A, Bhalla G, Mironov O, Jones CJ, Tenn WJ, Nakamura S, ... ... Hartwig JF, et al. C-H Transformation at Unfunctionalized Alkanes Handbook of C-H Transformations: Applications in Organic Synthesis. 2: 497-651. DOI: 10.1002/9783527619450.ch9  0.398
2007 Shekhar S, Hartwig JF. Effects of Bases and Halides on the Amination of Chloroarenes Catalyzed by Pd(PBu). Organometallics. 26: 340-351. PMID 29962646 DOI: 10.1021/Om0607548  0.617
2007 Murphy JM, Liao X, Hartwig JF. Meta halogenation of 1,3-disubstituted arenes via iridium-catalyzed arene borylation. Journal of the American Chemical Society. 129: 15434-5. PMID 18027947 DOI: 10.1021/Ja076498N  0.712
2007 Stambuli JP, Weng Z, Incarvito CD, Hartwig JF. Reductive elimination of ether from T-shaped, monomeric arylpalladium alkoxides. Angewandte Chemie (International Ed. in English). 46: 7674-7. PMID 17786903 DOI: 10.1002/Anie.200702809  0.788
2007 Pouy MJ, Leitner A, Weix DJ, Ueno S, Hartwig JF. Enantioselective iridium-catalyzed allylic amination of ammonia and convenient ammonia surrogates. Organic Letters. 9: 3949-52. PMID 17725361 DOI: 10.1021/Ol701562P  0.839
2007 Marković D, Hartwig JF. Resting state and kinetic studies on the asymmetric allylic substitutions catalyzed by iridium-phosphoramidite complexes. Journal of the American Chemical Society. 129: 11680-1. PMID 17725356 DOI: 10.1021/Ja074584H  0.456
2007 Johns AM, Liu Z, Hartwig JF. Primary tert- and sec-allylamines via palladium-catalyzed hydroamination and allylic substitution with hydrazine and hydroxylamine derivatives. Angewandte Chemie (International Ed. in English). 46: 7259-61. PMID 17594679 DOI: 10.1002/Anie.200701899  0.803
2007 Shen Q, Hartwig JF. Lewis acid acceleration of C-N bond-forming reductive elimination from heteroarylpalladium complexes and catalytic amidation of heteroaryl bromides. Journal of the American Chemical Society. 129: 7734-5. PMID 17542591 DOI: 10.1021/Ja0722473  0.659
2007 Weix DJ, Hartwig JF. Regioselective and enantioselective iridium-catalyzed allylation of enamines. Journal of the American Chemical Society. 129: 7720-1. PMID 17542586 DOI: 10.1021/Ja071455S  0.717
2007 Yamashita Y, Gopalarathnam A, Hartwig JF. Iridium-catalyzed, asymmetric amination of allylic alcohols activated by Lewis acids. Journal of the American Chemical Society. 129: 7508-9. PMID 17523648 DOI: 10.1021/Ja0730718  0.391
2007 Herzon SB, Hartwig JF. Direct, catalytic hydroaminoalkylation of unactivated olefins with N-alkyl arylamines. Journal of the American Chemical Society. 129: 6690-1. PMID 17474747 DOI: 10.1021/Ja0718366  0.732
2007 Hartwig JF. Electronic effects on reductive elimination to form carbon-carbon and carbon-heteroatom bonds from palladium(II) complexes. Inorganic Chemistry. 46: 1936-47. PMID 17348724 DOI: 10.1021/Ic061926W  0.4
2007 Murphy JM, Tzschucke CC, Hartwig JF. One-pot synthesis of arylboronic acids and aryl trifluoroborates by Ir-catalyzed borylation of arenes. Organic Letters. 9: 757-60. PMID 17274623 DOI: 10.1021/Ol062903O  0.807
2007 Tzschucke CC, Murphy JM, Hartwig JF. Arenes to anilines and aryl ethers by sequential iridium-catalyzed borylation and copper-catalyzed coupling. Organic Letters. 9: 761-4. PMID 17274622 DOI: 10.1021/Ol062902W  0.803
2007 Zhao P, Incarvito CD, Hartwig JF. Directly observed transmetalation from boron to rhodium. beta-aryl elimination from Rh(I) arylboronates and diarylborinates. Journal of the American Chemical Society. 129: 1876-7. PMID 17256944 DOI: 10.1021/Ja068587Q  0.549
2007 Hartwig J, Tzschucke C, Murphy J. Ir-Catalyzed Borylation and Sequential Functionalization of Arenes Synfacts. 2007: 0534-0534. DOI: 10.1055/S-2007-968425  0.377
2007 Hartwig J, Takemiya A. Synthesis of Aryl Ketones by Coupling of Aryl Bromides with an Acyl Equivalent Synfacts. 2007: 0193-0193. DOI: 10.1055/s-2006-955803  0.313
2007 Hartwig J, Murphy J, Lawrence J, Kawamura K, Incarvito C. Ru-Catalyzed Regiospecific Borylation of Methyl C-H Bonds Synfacts. 2007: 0081-0081. DOI: 10.1055/S-2006-955708  0.4
2007 Shekhar S, Hartwig JF. Effects of bases and halides on the amination of chloroarenes catalyzed by Pd(PtBu3)2 Organometallics. 26: 340-351. DOI: 10.1021/om0607548  0.498
2007 Hartwig JF, Shekhar S, Shen Q, Barrios-Landeros F. Synthesis of Anilines Cheminform. 38. DOI: 10.1002/9780470682531.Pat0391  0.843
2007 Pouy MJ, Hartwig JF. Enantioselective iridium-catalyzed allylic amination with ammonia and ammonia surrogates Acs National Meeting Book of Abstracts.  0.843
2006 Johns AM, Tye JW, Hartwig JF. Relative rates for the amination of eta3-allyl and eta3-benzyl complexes of palladium. Journal of the American Chemical Society. 128: 16010-1. PMID 17165734 DOI: 10.1021/Ja067084H  0.847
2006 Takemiya A, Hartwig JF. Palladium-catalyzed synthesis of aryl ketones by coupling of aryl bromides with an acyl anion equivalent. Journal of the American Chemical Society. 128: 14800-1. PMID 17105278 DOI: 10.1021/Ja064782T  0.498
2006 Murphy JM, Lawrence JD, Kawamura K, Incarvito C, Hartwig JF. Ruthenium-catalyzed regiospecific borylation of methyl C-H bonds. Journal of the American Chemical Society. 128: 13684-5. PMID 17044685 DOI: 10.1021/Ja064092P  0.732
2006 Fernández-Rodríguez MA, Shen Q, Hartwig JF. Highly efficient and functional-group-tolerant catalysts for the palladium-catalyzed coupling of aryl chlorides with thiols. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 7782-96. PMID 17009367 DOI: 10.1002/Chem.200600949  0.682
2006 Rosenfeld DC, Shekhar S, Takemiya A, Utsunomiya M, Hartwig JF. Hydroamination and hydroalkoxylation catalyzed by triflic acid. Parallels to reactions initiated with metal triflates. Organic Letters. 8: 4179-82. PMID 16956181 DOI: 10.1021/Ol061174+  0.613
2006 Shekhar S, Trantow B, Leitner A, Hartwig JF. Sequential catalytic isomerization and allylic substitution. Conversion of racemic branched allylic carbonates to enantioenriched allylic substitution products. Journal of the American Chemical Society. 128: 11770-1. PMID 16953612 DOI: 10.1021/Ja0644273  0.64
2006 Shen Q, Hartwig JF. Palladium-catalyzed coupling of ammonia and lithium amide with aryl halides. Journal of the American Chemical Society. 128: 10028-9. PMID 16881628 DOI: 10.1021/Ja064005T  0.686
2006 Zhao P, Incarvito CD, Hartwig JF. Carbon-oxygen bond formation between a terminal alkoxo ligand and a coordinated olefin. Evidence for olefin insertion into a rhodium alkoxide. Journal of the American Chemical Society. 128: 9642-3. PMID 16866513 DOI: 10.1021/Ja063347W  0.532
2006 Johns AM, Sakai N, Ridder A, Hartwig JF. Direct measurement of the thermodynamics of vinylarene hydroamination. Journal of the American Chemical Society. 128: 9306-7. PMID 16848446 DOI: 10.1021/Ja062773E  0.724
2006 Su W, Raders S, Verkade JG, Liao X, Hartwig JF. Pd-catalyzed alpha-arylation of trimethylsilyl enol ethers with aryl bromides and chlorides: a synergistic effect of two metal fluorides as additives. Angewandte Chemie (International Ed. in English). 45: 5852-5. PMID 16847853 DOI: 10.1002/Anie.200601887  0.815
2006 Fujita K, Yamashita M, Puschmann F, Alvarez-Falcon MM, Incarvito CD, Hartwig JF. Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II). Journal of the American Chemical Society. 128: 9044-5. PMID 16834372 DOI: 10.1021/Ja062333N  0.557
2006 Sakai N, Ridder A, Hartwig JF. Tropene derivatives by sequential intermolecular and transannular, intramolecular palladium-catalyzed hydroamination of cycloheptatriene. Journal of the American Chemical Society. 128: 8134-5. PMID 16787067 DOI: 10.1021/Ja061349A  0.497
2006 Takemiya A, Hartwig JF. Rhodium-catalyzed intramolecular, anti-Markovnikov hydroamination. Synthesis of 3-arylpiperidines. Journal of the American Chemical Society. 128: 6042-3. PMID 16669666 DOI: 10.1021/Ja058299E  0.522
2006 Hama T, Culkin DA, Hartwig JF. Palladium-catalyzed intermolecular alpha-arylation of zinc amide enolates under mild conditions. Journal of the American Chemical Society. 128: 4976-85. PMID 16608331 DOI: 10.1021/Ja056076I  0.843
2006 Shekhar S, Ryberg P, Hartwig JF, Mathew JS, Blackmond DG, Strieter ER, Buchwald SL. Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes. Journal of the American Chemical Society. 128: 3584-91. PMID 16536531 DOI: 10.1021/Ja045533C  0.658
2006 Zhao P, Incarvito CD, Hartwig JF. Direct observation of beta-aryl eliminations from Rh(I) alkoxides. Journal of the American Chemical Society. 128: 3124-5. PMID 16522075 DOI: 10.1021/Ja058550Q  0.581
2006 Shekhar S, Ryberg P, Hartwig JF. Oxidative addition of phenyl bromide to Pd(BINAP) vs Pd(BINAP)(amine). Evidence for addition to Pd(BINAP). Organic Letters. 8: 851-4. PMID 16494457 DOI: 10.1021/Ol0528890  0.558
2006 Fernández-Rodríguez MA, Shen Q, Hartwig JF. A general and long-lived catalyst for the palladium-catalyzed coupling of aryl halides with thiols. Journal of the American Chemical Society. 128: 2180-1. PMID 16478149 DOI: 10.1021/Ja0580340  0.696
2006 Johns AM, Utsunomiya M, Incarvito CD, Hartwig JF. A highly active palladium catalyst for intermolecular hydroamination. Factors that control reactivity and additions of functionalized anilines to dienes and vinylarenes. Journal of the American Chemical Society. 128: 1828-39. PMID 16464081 DOI: 10.1021/Ja056003Z  0.785
2006 Hartwig J, Shekhar S, Tantrow B, Leitner A. Pd(0)/Ir(I)-Catalyzed Sequential Allylic Isomerization and Substitution Synfacts. 2006: 1257-1257. DOI: 10.1055/S-2006-955630  0.576
2006 Verkade J, Hartwig J, Su W, Raders S, Liao X. Pd-Catalyzed α-Arylation of Trimethylsilyl Enol Ethers Synfacts. 2006: 1164-1164. DOI: 10.1055/S-2006-949478  0.805
2006 Hartwig J, Hama T, Culkin D. Pd-Catalyzed α-Arylation of Zinc Amide Enolates Synfacts. 2006: 0714-0714. DOI: 10.1055/S-2006-941887  0.795
2006 Hartwig JF. Discovery and understanding of transition-metal-catalyzed aromatic substitution reactions Synlett. 1283-1294. DOI: 10.1055/S-2006-939728  0.458
2006 Leitner A, Shekar S, Pouy MJ, Hartwig JF. Ir(I)/Phosphoramidite-Catalyzed Asymmetric Allylic Amination Synfacts. 2006: 137-137. DOI: 10.1055/S-2005-924770  0.477
2006 Su W, Raders S, Verkade JG, Liao X, Hartwig JF. Cover Picture: Pd-Catalyzed α-Arylation of Trimethylsilyl Enol Ethers with Aryl Bromides and Chlorides: A Synergistic Effect of Two Metal Fluorides as Additives (Angew. Chem. Int. Ed. 35/2006) Angewandte Chemie International Edition. 45: 5717-5717. DOI: 10.1002/Anie.200690118  0.819
2005 Graening T, Hartwig JF. Iridium-catalyzed regio- and enantioselective allylation of ketone enolates. Journal of the American Chemical Society. 127: 17192-3. PMID 16332060 DOI: 10.1021/JA0566275  0.538
2005 Wu L, Hartwig JF. Mild palladium-catalyzed selective monoarylation of nitriles. Journal of the American Chemical Society. 127: 15824-32. PMID 16277525 DOI: 10.1021/Ja053027X  0.475
2005 Limmert ME, Roy AH, Hartwig JF. Kumada coupling of aryl and vinyl tosylates under mild conditions. The Journal of Organic Chemistry. 70: 9364-70. PMID 16268609 DOI: 10.1021/JO051394L  0.754
2005 Leitner A, Shekhar S, Pouy MJ, Hartwig JF. A simple iridium catalyst with a single resolved stereocenter for enantioselective allylic amination. Catalyst selection from mechanistic analysis. Journal of the American Chemical Society. 127: 15506-14. PMID 16262414 DOI: 10.1021/Ja054331T  0.825
2005 Boller TM, Murphy JM, Hapke M, Ishiyama T, Miyaura N, Hartwig JF. Mechanism of the mild functionalization of arenes by diboron reagents catalyzed by iridium complexes. Intermediacy and chemistry of bipyridine-ligated iridium trisboryl complexes. Journal of the American Chemical Society. 127: 14263-78. PMID 16218621 DOI: 10.1021/Ja053433G  0.83
2005 Hartwig J. Synthetic chemistry: recipes for excess. Nature. 437: 487-488. PMID 16177775 DOI: 10.1038/437487A  0.319
2005 Bae C, Hartwig JF, Chung H, Harris NK, Switek KA, Hillmyer MA. Regiospecific side-chain functionalization of linear low-density polyethylene with polar groups. Angewandte Chemie (International Ed. in English). 44: 6410-3. PMID 16145705 DOI: 10.1002/Anie.200501837  0.474
2005 Zhao P, Krug C, Hartwig JF. Transfer of amido groups from isolated rhodium(I) amides to alkenes and vinylarenes. Journal of the American Chemical Society. 127: 12066-73. PMID 16117547 DOI: 10.1021/Ja052473H  0.792
2005 Zhao P, Hartwig JF. Beta-aryl eliminations from Rh(I) iminyl complexes. Journal of the American Chemical Society. 127: 11618-9. PMID 16104735 DOI: 10.1021/Ja054132+  0.601
2005 Yan XZ, Pawlas J, Goodson T, Hartwig JF. Polaron delocalization in ladder macromolecular systems. Journal of the American Chemical Society. 127: 9105-16. PMID 15969589 DOI: 10.1021/Ja050184N  0.31
2005 Barrios-Landeros F, Hartwig JF. Distinct mechanisms for the oxidative addition of chloro-, bromo-, and iodoarenes to a bisphosphine palladium(0) complex with hindered ligands. Journal of the American Chemical Society. 127: 6944-5. PMID 15884925 DOI: 10.1021/Ja042959I  0.809
2005 Takaya J, Hartwig JF. Mechanistic studies of ruthenium-catalyzed anti-Markovnikov hydroamination of vinylarenes: Intermediates and evidence for catalysis through π-arene complexes Journal of the American Chemical Society. 127: 5756-5757. PMID 15839651 DOI: 10.1021/Ja0506410  0.492
2005 Tsukada N, Hartwig JF. Intermolecular and intramolecular, platinum-catalyzed, acceptorless dehydrogenative coupling of hydrosilanes with aryl and aliphatic methyl C-H bonds. Journal of the American Chemical Society. 127: 5022-3. PMID 15810828 DOI: 10.1021/Ja050612P  0.495
2005 Lee DY, Hartwig JF. Zinc trimethylsilylamide as a mild ammonia equivalent and base for the amination of aryl halides and triflates. Organic Letters. 7: 1169-72. PMID 15760166 DOI: 10.1021/Ol050141B  0.457
2005 Leitner A, Shu C, Hartwig JF. Effects of catalyst activation and ligand steric properties on the enantioselective allylation of amines and phenoxides. Organic Letters. 7: 1093-6. PMID 15760147 DOI: 10.1021/Ol050029D  0.469
2005 Hartwig JF, Cook KS, Hapke M, Incarvito CD, Fan Y, Webster CE, Hall MB. Rhodium boryl complexes in the catalytic, terminal functionalization of alkanes. Journal of the American Chemical Society. 127: 2538-52. PMID 15725009 DOI: 10.1021/Ja045090C  0.747
2005 Zhao J, Goldman AS, Hartwig JF. Oxidative addition of ammonia to form a stable monomeric amido hydride complex. Science (New York, N.Y.). 307: 1080-2. PMID 15718464 DOI: 10.1126/Science.1109389  0.508
2005 Shen Q, Shekhar S, Stambuli JP, Hartwig JF. Highly reactive, general, and long-lived catalysts for coupling heteroaryl and aryl chlorides with primary nitrogen nucleophiles. Angewandte Chemie (International Ed. in English). 44: 1371-5. PMID 15666413 DOI: 10.1002/Anie.200462629  0.811
2005 Bae C, Hartwig JF, Boaen Harris NK, Long RO, Anderson KS, Hillmyer MA. Catalytic hydroxylation of polypropylenes. Journal of the American Chemical Society. 127: 767-76. PMID 15643903 DOI: 10.1021/ja044440s  0.509
2005 Zhao J, Hartwig JF. Acceptorless, neat, ruthenium-catalyzed dehydrogenative cyclization of diols to lactones Organometallics. 24: 2441-2446. DOI: 10.1021/Om048983M  0.423
2005 Tsukada N, Hartwig JF. Intermolecular and Intramolecular, Platinum-Catalyzed, Acceptorless Dehydrogenative Coupling of Hydrosilanes with Aryl and Aliphatic Methyl C—H Bonds. Cheminform. 36. DOI: 10.1002/CHIN.200534227  0.304
2005 Lee D, Hartwig JF. Zinc Trimethylsilylamide as a Mild Ammonia Equivalent and Base for the Amination of Aryl Halides and Triflates. Cheminform. 36. DOI: 10.1002/CHIN.200531089  0.331
2004 Lawrence JD, Takahashi M, Bae C, Hartwig JF. Regiospecific functionalization of methyl C-H bonds of alkyl groups in reagents with heteroatom functionality. Journal of the American Chemical Society. 126: 15334-5. PMID 15563132 DOI: 10.1021/Ja044933X  0.644
2004 Leitner A, Larsen J, Steffens C, Hartwig JF. Palladium-catalyzed addition of mono- and dicarbonyl compounds to conjugated dienes. The Journal of Organic Chemistry. 69: 7552-7. PMID 15497981 DOI: 10.1021/Jo0490999  0.547
2004 Cook KS, Incarvito CD, Webster CE, Fan Y, Hall MB, Hartwig JF. Rhodium silyl boryl hydride complexes: comparison of bonding and the rates of elimination of borane, silane, and dihydrogen. Angewandte Chemie (International Ed. in English). 43: 5474-7. PMID 15484256 DOI: 10.1002/Anie.200460430  0.396
2004 Shekhar S, Hartwig JF. Distinct electronic effects on reductive eliminations of symmetrical and unsymmetrical bis-aryl platinum complexes. Journal of the American Chemical Society. 126: 13016-27. PMID 15469300 DOI: 10.1021/Ja0480365  0.576
2004 Shu C, Leitner A, Hartwig JF. Enantioselective allylation of aromatic amines after in situ generation of an activated cyclometalated iridium catalyst. Angewandte Chemie (International Ed. in English). 43: 4797-800. PMID 15366091 DOI: 10.1002/Anie.200460276  0.394
2004 Shu C, Hartwig JF. Iridium-catalyzed intermolecular allylic etherification with aliphatic alkoxides: asymmetric synthesis of dihydropyrans and dihydrofurans. Angewandte Chemie (International Ed. in English). 43: 4794-7. PMID 15366090 DOI: 10.1002/Anie.200460214  0.474
2004 Yamashita M, Hartwig JF. Synthesis, structure, and reductive elimination chemistry of three-coordinate arylpalladium amido complexes. Journal of the American Chemical Society. 126: 5344-5. PMID 15113190 DOI: 10.1021/Ja0315107  0.587
2004 Liu X, Hartwig JF. Palladium-catalyzed arylation of trimethylsilyl enolates of esters and imides. High functional group tolerance and stereoselective synthesis of alpha-aryl carboxylic acid derivatives. Journal of the American Chemical Society. 126: 5182-91. PMID 15099101 DOI: 10.1021/Ja031544E  0.465
2004 Leitner A, Shu C, Hartwig JF. Editing the stereochemical elements in an iridium catalyst for enantioselective allylic amination. Proceedings of the National Academy of Sciences of the United States of America. 101: 5830-3. PMID 15067140 DOI: 10.1073/Pnas.0307967101  0.463
2004 Utsunomiya M, Hartwig JF. Ruthenium-catalyzed anti-Markovnikov hydroamination of vinylarenes. Journal of the American Chemical Society. 126: 2702-3. PMID 14995178 DOI: 10.1021/Ja031542U  0.517
2004 Krug C, Hartwig JF. Imine insertion into a late metal-carbon bond to form a stable amido complex. Journal of the American Chemical Society. 126: 2694-5. PMID 14995174 DOI: 10.1021/Ja038819A  0.809
2004 Stambuli JP, Incarvito CD, Bühl M, Hartwig JF. Synthesis, structure, theoretical studies, and Ligand exchange reactions of monomeric, T-shaped arylpalladium(II) halide complexes with an additional, weak agostic interaction. Journal of the American Chemical Society. 126: 1184-94. PMID 14746489 DOI: 10.1021/Ja037928M  0.766
2004 Ishiyama T, Nobuta Y, Hartwig JF, Miyaura N. Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent. Chemical Communications (Cambridge, England). 2924-5. PMID 14680243 DOI: 10.1039/B311103B  0.477
2004 Utsunomiya M, Kawatsura M, Hartwig JF. Palladium-catalyzed equilibrium addition of acidic OH groups across dienes. Angewandte Chemie (International Ed. in English). 42: 5865-8. PMID 14673921 DOI: 10.1002/Anie.200352621  0.371
2004 Utsunomiya M, Hartwig JF. Intermolecular, markovnikov hydroamination of vinylarenes with alkylamines. Journal of the American Chemical Society. 125: 14286-7. PMID 14624571 DOI: 10.1021/Ja0375535  0.549
2004 Hartwig JF. Development of catalysts for the hydroamination of olefins Pure and Applied Chemistry. 76: 507-516. DOI: 10.1351/Pac200476030507  0.401
2004 Culkin DA, Hartwig JF. Carbon-carbon bond-forming reductive elimination from arylpalladium complexes containing functionalized alkyl groups. Influence of ligand steric and electronic properties on structure, stability, and reactivity Organometallics. 23: 3398-3416. DOI: 10.1021/Om049726K  0.818
2004 Krug C, Hartwig JF. Reactions of an Arylrhodium Complex with Aldehydes, Imines, Ketones, and Alkynones. New Classes of Insertion Reactions Organometallics. 23: 4594-4607. DOI: 10.1021/Om0496582  0.808
2004 Roy AH, Hartwig JF. Reductive elimination of aryl halides upon addition of hindered alkylphosphines to dimeric arylpalladium(II) halide complexes Organometallics. 23: 1533-1541. DOI: 10.1021/Om034277U  0.767
2004 Roy AH, Hartwig JF. Oxidative Addition of Aryl Sulfonates to Palladium (0) Complexes of Mono- and Bidentate Phosphines. Mild Addition of Aryl Tosylates and the Effects of Anions on Rate and Mechanism Organometallics. 23: 194-202. DOI: 10.1021/Om034187P  0.747
2004 Shu C, Hartwig JF. Iridium-Catalyzed Intermolecular Allylic Etherification with Aliphatic Alkoxides: Asymmetric Synthesis of Dihydropyrans and Dihydrofurans. Cheminform. 35. DOI: 10.1002/CHIN.200452047  0.369
2004 Hartwig JF. Metal Complexes as Catalysts for Carbon—Heteroatom Cross-Coupling Reactions Cheminform. 35. DOI: 10.1002/chin.200441257  0.314
2004 Liu X, Hartwig JF. Palladium-Catalyzed Arylation of Trimethylsilyl Enolates of Esters and Imides. High Functional Group Tolerance and Stereoselective Synthesis of α-Aryl Carboxylic Acid Derivatives. Cheminform. 35. DOI: 10.1002/CHIN.200435044  0.316
2004 Ishiyama T, Takagi J, Yonekawa Y, Hartwig JF, Miyaura N. Iridium-Catalyzed Direct Borylation of Five-Membered Heteroarenes by Bis(pinacolato)diboron: Regioselective, Stoichiometric, and Room Temperature Reactions. Cheminform. 35. DOI: 10.1002/Adsc.200303058  0.471
2003 Hama T, Liu X, Culkin DA, Hartwig JF. Palladium-catalyzed alpha-arylation of esters and amides under more neutral conditions. Journal of the American Chemical Society. 125: 11176-7. PMID 16220921 DOI: 10.1021/Ja036792P  0.839
2003 Yamashita M, Cuevas Vicario JV, Hartwig JF. Trans influence on the rate of reductive elimination. Reductive elimination of amines from isomeric arylpalladium amides with unsymmetrical coordination spheres. Journal of the American Chemical Society. 125: 16347-60. PMID 14692777 DOI: 10.1021/Ja037425G  0.613
2003 Kiener CA, Shu C, Incarvito C, Hartwig JF. Identification of an activated catalyst in the iridium-catalyzed allylic amination and etherification. Increased rates, scope, and selectivity. Journal of the American Chemical Society. 125: 14272-3. PMID 14624564 DOI: 10.1021/Ja038319H  0.505
2003 Roy AH, Hartwig JF. Directly observed reductive elimination of aryl halides from monomeric arylpalladium(II) halide complexes. Journal of the American Chemical Society. 125: 13944-5. PMID 14611215 DOI: 10.1021/Ja037959H  0.752
2003 Kanzelberger M, Zhang X, Emge TJ, Goldman AS, Zhao J, Incarvito C, Hartwig JF. Distinct thermodynamics for the formation and cleavage of N-H bonds in aniline and ammonia. Directly-observed reductive elimination of ammonia from an isolated amido hydride complex. Journal of the American Chemical Society. 125: 13644-5. PMID 14599186 DOI: 10.1021/Ja037363U  0.424
2003 Roy AH, Hartwig JF. Oxidative addition of aryl tosylates to palladium(0) and coupling of unactivated aryl tosylates at room temperature. Journal of the American Chemical Society. 125: 8704-5. PMID 12862447 DOI: 10.1021/Ja035835Z  0.766
2003 Stambuli JP, Hartwig JF. Recent advances in the discovery of organometallic catalysts using high-throughput screening assays. Current Opinion in Chemical Biology. 7: 420-6. PMID 12826131 DOI: 10.1016/S1367-5931(03)00056-5  0.712
2003 Stauffer SR, Hartwig JF. Fluorescence resonance energy transfer (FRET) as a high-throughput assay for coupling reactions. Arylation of amines as a case study. Journal of the American Chemical Society. 125: 6977-85. PMID 12783551 DOI: 10.1021/Ja034161P  0.444
2003 Liu X, Hartwig JF. Palladium-catalyzed alpha-arylation of azlactones to form quaternary amino acid derivatives. Organic Letters. 5: 1915-8. PMID 12762685 DOI: 10.1021/Ol034570Q  0.454
2003 Utsunomiya M, Kuwano R, Kawatsura M, Hartwig JF. Rhodium-catalyzed anti-Markovnikov hydroamination of vinylarenes. Journal of the American Chemical Society. 125: 5608-9. PMID 12733880 DOI: 10.1021/JA0293608  0.375
2003 Culkin DA, Hartwig JF. Palladium-catalyzed alpha-arylation of carbonyl compounds and nitriles. Accounts of Chemical Research. 36: 234-45. PMID 12693921 DOI: 10.1021/Ar0201106  0.844
2003 Hooper MW, Utsunomiya M, Hartwig JF. Scope and mechanism of palladium-catalyzed amination of five-membered heterocyclic halides. The Journal of Organic Chemistry. 68: 2861-73. PMID 12662063 DOI: 10.1021/Jo0266339  0.482
2003 López F, Ohmura T, Hartwig JF. Regio- and enantioselective iridium-catalyzed intermolecular allylic etherification of achiral allylic carbonates with phenoxides. Journal of the American Chemical Society. 125: 3426-7. PMID 12643693 DOI: 10.1021/Ja029790Y  0.51
2003 Webster CE, Fan Y, Hall MB, Kunz D, Hartwig JF. Experimental and computational evidence for a boron-assisted, sigma-bond metathesis pathway for alkane borylation. Journal of the American Chemical Society. 125: 858-9. PMID 12537470 DOI: 10.1021/Ja028394C  0.428
2003 Ohmura T, Hartwig JF. Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex. Journal of the American Chemical Society. 124: 15164-5. PMID 12487578 DOI: 10.1021/Ja028614M  0.497
2003 Wolkowski JP, Hartwig JF. Generation of reactivity from typically stable ligands: CbondC bond-forming reductive elimination from aryl palladium(II) complexes of malonate anions. Angewandte Chemie (International Ed. in English). 41: 4289-91. PMID 12434365 DOI: 10.1002/1521-3773(20021115)41:22<4289::Aid-Anie4289>3.0.Co;2-4  0.448
2003 Kuwano R, Utsunomiya M, Hartwig JF. Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides. The Journal of Organic Chemistry. 67: 6479-86. PMID 12201770 DOI: 10.1021/Jo0258913  0.491
2003 Hooper MW, Hartwig JF. Understanding the coupling of heteroaromatic substrates: Synthesis, structures, and reductive eliminations of heteroarylpalladium amido complexes Organometallics. 22: 3394-3403. DOI: 10.1021/Om030257G  0.458
2003 Mann G, Shelby Q, Roy AH, Hartwig JF. Electronic and steric effects on the reductive elimination of diaryl ethers from palladium(II) Organometallics. 22: 2775-2789. DOI: 10.1021/Om030230X  0.759
2003 Anastasi NR, Waltz KM, Weerakoon WL, Hartwig JF. A short synthesis of tetraalkoxydiborane(4) reagents Organometallics. 22: 365-369. DOI: 10.1021/Om0208016  0.79
2003 Hooper MW, Utsunomiya M, Hartwig JF. Scope and Mechanism of Palladium-Catalyzed Amination of Five-Membered Heterocyclic Halides. Cheminform. 34. DOI: 10.1002/CHIN.200333052  0.368
2003 Culkin DA, Hartwig JF. Palladium-Catalyzed α-Arylation of Carbonyl Compounds and Nitriles Cheminform. 34. DOI: 10.1002/chin.200326269  0.783
2003 Ohmura T, Hartwig JF. Regio- and Enantioselective Allylic Amination of Achiral Allylic Esters Catalyzed by an Iridium—Phosphoramidite Complex. Cheminform. 34. DOI: 10.1002/CHIN.200319051  0.414
2003 Joergensen M, Lee S, Liu X, Wolkowski JP, Hartwig JF. Efficient Synthesis of α-Aryl Esters by Room-Temperature Palladium-Catalyzed Coupling of Aryl Halides with Ester Enolates. Cheminform. 34. DOI: 10.1002/CHIN.200307081  0.302
2003 Kuwano R, Utsunomiya M, Hartwig JF. Aqueous Hydroxide as a Base for Palladium-Catalyzed Amination of Aryl Chlorides and Bromides. Cheminform. 34. DOI: 10.1002/CHIN.200306053  0.41
2003 Kataoka N, Shelby Q, Stambuli JP, Hartwig JF. Air-Stable, Sterically Hindered Ferrocenyl Dialkylphosphines for Palladium-Catalyzed C—C, C—N, and C—O Bond-Forming Cross-Couplings. Cheminform. 34. DOI: 10.1002/chin.200303026  0.709
2003 Ishiyama T, Takagi J, Yonekawa Y, Hartwig J, Miyaura N. Iridium-Catalyzed Direct Borylation of Five-Membered Heteroarenes by Bis(pinacolato)diboron: Regioselective, Stoichiometric, and Room Temperature Reactions Advanced Synthesis & Catalysis. 345: 1103-1106. DOI: 10.1002/ADSC.200303058  0.318
2002 Stambuli JP, Kuwano R, Hartwig JF. Unparalleled rates for the activation of aryl chlorides and bromides: coupling with amines and boronic acids in minutes at room temperature. Angewandte Chemie (International Ed. in English). 41: 4746-8. PMID 12481346 DOI: 10.1002/Anie.200290036  0.71
2002 Jørgensen M, Lee S, Liu X, Wolkowski JP, Hartwig JF. Efficient synthesis of alpha-aryl esters by room-temperature palladium-catalyzed coupling of aryl halides with ester enolates. Journal of the American Chemical Society. 124: 12557-65. PMID 12381200 DOI: 10.1021/Ja027643U  0.47
2002 Hartwig JF. Chemical synthesis. Raising the bar for the "perfect reaction". Science (New York, N.Y.). 297: 1653-4. PMID 12215631 DOI: 10.1126/Science.1076371  0.416
2002 Ishiyama T, Takagi J, Hartwig JF, Miyaura N. A stoichiometric aromatic CbondH borylation catalyzed by iridium(i)/2,2'-bipyridine complexes at room temperature. Angewandte Chemie (International Ed. in English). 41: 3056-8. PMID 12203457 DOI: 10.1002/1521-3773(20020816)41:16<3056::Aid-Anie3056>3.0.Co;2-#  0.378
2002 Stambuli JP, Bühl M, Hartwig JF. Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand. Journal of the American Chemical Society. 124: 9346-7. PMID 12167009 DOI: 10.1021/Ja0264394  0.794
2002 Culkin DA, Hartwig JF. Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: selection of catalysts for the alpha-arylation of nitriles. Journal of the American Chemical Society. 124: 9330-1. PMID 12167001 DOI: 10.1021/Ja026584H  0.833
2002 Kataoka N, Shelby Q, Stambuli JP, Hartwig JF. Air stable, sterically hindered ferrocenyl dialkylphosphines for palladium-catalyzed C[bond]C, C[bond]N, and C[bond]O bond-forming cross-couplings. The Journal of Organic Chemistry. 67: 5553-66. PMID 12153253 DOI: 10.1021/Jo025732J  0.797
2002 Ranasinghe MI, Varnavski OP, Pawlas J, Hauck SI, Louie J, Hartwig JF, Goodson T. Femtosecond excitation energy transport in triarylamine dendrimers. Journal of the American Chemical Society. 124: 6520-1. PMID 12047157 DOI: 10.1021/Ja025505Z  0.571
2002 Schlummer B, Hartwig JF. Brønsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines. Organic Letters. 4: 1471-4. PMID 11975606 DOI: 10.1021/Ol025659J  0.446
2002 Pawlas J, Nakao Y, Kawatsura M, Hartwig JF. A general nickel-catalyzed hydroamination of 1,3-dienes by alkylamines: catalyst selection, scope, and mechanism. Journal of the American Chemical Society. 124: 3669-79. PMID 11929257 DOI: 10.1021/Ja017575W  0.548
2002 Krug C, Hartwig JF. Direct observation of aldehyde insertion into rhodium-aryl and -alkoxide complexes. Journal of the American Chemical Society. 124: 1674-9. PMID 11853443 DOI: 10.1021/Ja017401E  0.838
2002 Nettekoven U, Hartwig JF. A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes. Journal of the American Chemical Society. 124: 1166-7. PMID 11841274 DOI: 10.1021/Ja017521M  0.494
2002 Kondo Y, García-Cuadrado D, Hartwig JF, Boaen NK, Wagner NL, Hillmyer MA. Rhodium-catalyzed, regiospecific functionalization of polyolefins in the melt. Journal of the American Chemical Society. 124: 1164-5. PMID 11841273 DOI: 10.1021/Ja016763J  0.312
2002 Beare NA, Hartwig JF. Palladium-catalyzed arylation of malonates and cyanoesters using sterically hindered trialkyl- and ferrocenyldialkylphosphine ligands. The Journal of Organic Chemistry. 67: 541-55. PMID 11798329 DOI: 10.1021/Jo016226H  0.523
2002 Ishiyama T, Takagi J, Ishida K, Miyaura N, Anastasi NR, Hartwig JF. Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate. Journal of the American Chemical Society. 124: 390-1. PMID 11792205 DOI: 10.1021/Ja0173019  0.845
2002 Lee S, Hartwig JF. Improved catalysts for the palladium-catalyzed synthesis of oxindoles by amide alpha-arylation. Rate acceleration, use of aryl chloride substrates, and a new carbene ligand for asymmetric transformations. The Journal of Organic Chemistry. 66: 3402-15. PMID 11348123 DOI: 10.1021/Jo005761Z  0.501
2002 Alcazar-Roman LM, Hartwig JF. Mechanistic studies on oxidative addition of aryl halides and triflates to Pd(BINAP)2 and structural characterization of the product from aryl triflate addition in the presence of amine Organometallics. 21: 491-502. DOI: 10.1021/Om0108088  0.823
2002 Takagi J, Sato K, Hartwig JF, Ishiyama T, Miyaura N. Iridium-catalyzed C–H coupling reaction of heteroaromatic compounds with bis(pinacolato)diboron: regioselective synthesis of heteroarylboronates Tetrahedron Letters. 43: 5649-5651. DOI: 10.1016/S0040-4039(02)01135-8  0.509
2001 Alcazar-Roman LM, Hartwig JF. Mechanism of aryl chloride amination: base-induced oxidative addition. Journal of the American Chemical Society. 123: 12905-6. PMID 11749551 DOI: 10.1021/Ja016491K  0.794
2001 Kawamura K, Hartwig JF. Isolated Ir(V) boryl complexes and their reactions with hydrocarbons. Journal of the American Chemical Society. 123: 8422-3. PMID 11516302 DOI: 10.1021/Ja015975D  0.4
2001 Lee S, Beare NA, Hartwig JF. Palladium-catalyzed alpha-arylation of esters and protected amino acids. Journal of the American Chemical Society. 123: 8410-1. PMID 11516296 DOI: 10.1021/Ja016032J  0.329
2001 Lee S, Jørgensen M, Hartwig JF. Palladium-catalyzed synthesis of arylamines from aryl halides and lithium bis(trimethylsilyl)amide as an ammonia equivalent. Organic Letters. 3: 2729-32. PMID 11506620 DOI: 10.1021/Ol016333Y  0.533
2001 Zhao J, Hesslink H, Hartwig JF. Mechanism of beta-hydrogen elimination from square planar iridium(I) alkoxide complexes with labile dative ligands. Journal of the American Chemical Society. 123: 7220-7. PMID 11472149 DOI: 10.1021/Ja010417K  0.446
2001 Stauffer SR, Beare NA, Stambuli JP, Hartwig JF. Palladium-catalyzed arylation of ethyl cyanoacetate. Fluorescence resonance energy transfer as a tool for reaction discovery. Journal of the American Chemical Society. 123: 4641-2. PMID 11457267 DOI: 10.1021/Ja0157402  0.723
2001 Löber O, Kawatsura M, Hartwig JF. Palladium-catalyzed hydroamination of 1,3-dienes: a colorimetric assay and enantioselective additions. Journal of the American Chemical Society. 123: 4366-7. PMID 11457216 DOI: 10.1021/Ja005881O  0.47
2001 Stambuli JP, Stauffer SR, Shaughnessy KH, Hartwig JF. Screening of homogeneous catalysts by fluorescence resonance energy transfer. Identification of catalysts for room-temperature Heck reactions. Journal of the American Chemical Society. 123: 2677-8. PMID 11456943 DOI: 10.1021/ja0058435  0.777
2001 Roy AH, Hartwig JF. Reductive elimination of aryl halides from palladium(II). Journal of the American Chemical Society. 123: 1232-3. PMID 11456679 DOI: 10.1021/Ja0034592  0.719
2001 Culkin DA, Hartwig JF. C-C bond-forming reductive elimination of ketones, esters, and amides from isolated arylpalladium(II) enolates. Journal of the American Chemical Society. 123: 5816-7. PMID 11403622 DOI: 10.1021/Ja015732L  0.797
2001 Kawatsura M, Hartwig JF. Transition Metal-Catalyzed Addition of Amines to Acrylic Acid Derivatives. A High-Throughput Method for Evaluating Hydroamination of Primary and Secondary Alkylamines Organometallics. 20: 1960-1964. DOI: 10.1021/Om0009987  0.469
2001 Ishiyama T, Hartwig J. ChemInform Abstract: A Heck-Type Reaction Involving Carbon-Heteroatom Double Bonds. Rhodium(I)-Catalyzed Coupling of Aryl Halides with N-Pyrazyl Aldimines. Cheminform. 32: no-no. DOI: 10.1002/CHIN.200116114  0.35
2001 Kawatsura M, Hartwig JF. ChemInform Abstract: Palladium-Catalyzed Intermolecular Hydroamination of Vinylarenes Using Arylamines. Cheminform. 32: no-no. DOI: 10.1002/CHIN.200104101  0.396
2000 Stauffer SR, Lee S, Stambuli JP, Hauck SI, Hartwig JF. High turnover number and rapid, room-temperature amination of chloroarenes using saturated carbene ligands. Organic Letters. 2: 1423-6. PMID 10814463 DOI: 10.1021/Ol005751K  0.767
2000 Chen H, Schlecht S, Semple TC, Hartwig JF. Thermal, catalytic, regiospecific functionalization of alkanes Science (New York, N.Y.). 287: 1995-7. PMID 10720320 DOI: 10.1126/Science.287.5460.1995  0.473
2000 Alcazar-Roman LM, Hartwig JF, Rheingold AL, Liable-Sands LM, Guzei IA. Mechanistic studies of the palladium-catalyzed amination of aryl halides and the oxidative addition of aryl bromides to Pd(BINAP)2 and Pd(DPPF)2: An unusual case of zero-order kinetic behavior and product inhibition Journal of the American Chemical Society. 122: 4618-4630. DOI: 10.1021/Ja9944599  0.836
2000 Ishiyama T, Hartwig J. A Heck-Type Reaction Involving Carbon−Heteroatom Double Bonds. Rhodium(I)-Catalyzed Coupling of Aryl Halides withN-Pyrazyl Aldimines Journal of the American Chemical Society. 122: 12043-12044. DOI: 10.1021/Ja003306E  0.476
2000 Waltz KM, Hartwig JF. Functionalization of alkanes by isolated transition metal boryl complexes Journal of the American Chemical Society. 122: 11358-11369. DOI: 10.1021/Ja002840J  0.812
2000 Shelby Q, Kataoka N, Mann G, Hartwig J. Unusual in Situ Ligand Modification to Generate a Catalyst for Room Temperature Aromatic C−O Bond Formation Journal of the American Chemical Society. 122: 10718-10719. DOI: 10.1021/Ja002543E  0.41
2000 Kawatsura M, Hartwig JF. Palladium-Catalyzed Intermolecular Hydroamination of Vinylarenes Using Arylamines Journal of the American Chemical Society. 122: 9546-9547. DOI: 10.1021/Ja002284T  0.536
2000 Schlecht S, Hartwig JF. σ-Borane complexes of manganese and rhenium Journal of the American Chemical Society. 122: 9435-9443. DOI: 10.1021/Ja001546O  0.418
1999 Hartwig JF, Kawatsura M, Hauck SI, Shaughnessy KH, Alcazar-Roman LM. Room-Temperature Palladium-Catalyzed Amination of Aryl Bromides and Chlorides and Extended Scope of Aromatic C-N Bond Formation with a Commercial Ligand. The Journal of Organic Chemistry. 64: 5575-5580. PMID 11674624 DOI: 10.1021/Jo990408I  0.838
1999 Chen H, Hartwig JF. Catalytic, Regiospecific End‐Functionalization of Alkanes: Rhenium‐Catalyzed Borylation under Photochemical Conditions Angewandte Chemie. 38: 3391-3393. PMID 10602206 DOI: 10.1002/(Sici)1521-3773(19991115)38:22<3391::Aid-Anie3391>3.0.Co;2-N  0.468
1999 Hartwig JF. Approaches to catalyst discovery. New carbon–heteroatom and carbon–carbon bond formation Pure and Applied Chemistry. 71: 1417-1423. DOI: 10.1351/Pac199971081417  0.503
1999 Waltz KM, Muhoro CN, Hartwig JF. C−H Activation and Functionalization of Unsaturated Hydrocarbons by Transition-Metal Boryl Complexes Organometallics. 18: 3383-3393. DOI: 10.1021/Om990113V  0.817
1999 Hauck SI, Lakshmi KV, Hartwig JF. Tetraazacyclophanes by Palladium-Catalyzed Aromatic Amination. Geometrically Defined, Stable, High-Spin Diradicals Organic Letters. 1: 2057-2060. DOI: 10.1021/Ol9912276  0.345
1999 Goodson FE, Hauck SI, Hartwig JF. Palladium-catalyzed synthesis of pure, regiodefined polymeric triarylamines Journal of the American Chemical Society. 121: 7527-7539. DOI: 10.1021/Ja990632P  0.415
1999 Muhoro CN, He X, Hartwig JF. Titanocene Borane σ-Complexes Journal of the American Chemical Society. 121: 5033-5046. DOI: 10.1021/Ja9900757  0.447
1999 Mann G, Incarvito C, Rheingold AL, Hartwig JF. Palladium-Catalyzed C−O Coupling Involving Unactivated Aryl Halides. Sterically Induced Reductive Elimination To Form the C−O Bond in Diaryl Ethers Journal of the American Chemical Society. 121: 3224-3225. DOI: 10.1021/Ja984321A  0.54
1999 Shaughnessy KH, Kim P, Hartwig JF. A fluorescence-based assay for high-throughput screening of coupling reactions. Application to Heck chemistry Journal of the American Chemical Society. 121: 2123-2132. DOI: 10.1021/Ja983419M  0.672
1999 Kawatsura M, Hartwig JF. Simple, Highly Active Palladium Catalysts for Ketone and Malonate Arylation:  Dissecting the Importance of Chelation and Steric Hindrance Journal of the American Chemical Society. 121: 1473-1478. DOI: 10.1021/Ja983378U  0.527
1998 Hartwig JF. Synthesis, Structure, and Reactivity of a Palladium Hydrazonato Complex: A New Type of Reductive Elimination Reaction To Form C-N Bonds and Catalytic Arylation of Benzophenone Hydrazone. Angewandte Chemie (International Ed. in English). 37: 2090-2093. PMID 29711062 DOI: 10.1002/(Sici)1521-3773(19980817)37:15<2090::Aid-Anie2090>3.0.Co;2-A  0.54
1998 Hartwig JF. Transition Metal Catalyzed Synthesis of Arylamines and Aryl Ethers from Aryl Halides and Triflates: Scope and Mechanism. Angewandte Chemie (International Ed. in English). 37: 2046-2067. PMID 29711045 DOI: 10.1002/(Sici)1521-3773(19980817)37:15<2046::Aid-Anie2046>3.0.Co;2-L  0.505
1998 Driver MS, Hartwig JF. Oxidative Addition and Reductive Elimination Reactions oftrans-[Ir(PPh3)2(CO)(NC4H4)] andtrans,cis-[Ir(PPh3)2(H)2(CO)(NC4H4)], Including N−H Bond-Forming Reductive Elimination of Pyrrole Organometallics. 17: 1134-1143. DOI: 10.1021/Om971049P  0.493
1998 Louie J, Hartwig JF. The Largest Discrete Oligo(m-aniline). An Exponential Growth Strategy Using Palladium-Catalyzed Amination of Aryl Sulfonates Macromolecules. 31: 6737-6739. DOI: 10.1021/Ma981073U  0.569
1998 Goodson FE, Hartwig JF. Regiodefined Poly(N-arylaniline)s and Donor−Acceptor Copolymers via Palladium-Mediated Amination Chemistry Macromolecules. 31: 1700-1703. DOI: 10.1021/Ma980027R  0.305
1998 Shaughnessy KH, Hamann BC, Hartwig JF. Palladium-Catalyzed Inter- and Intramolecular α-Arylation of Amides. Application of Intramolecular Amide Arylation to the Synthesis of Oxindoles The Journal of Organic Chemistry. 63: 6546-6553. DOI: 10.1021/Jo980611Y  0.74
1998 Hamann BC, Hartwig JF. Sterically Hindered Chelating Alkyl Phosphines Provide Large Rate Accelerations in Palladium-Catalyzed Amination of Aryl Iodides, Bromides, and Chlorides, and the First Amination of Aryl TosylatesJ. Am. Chem. Soc.1998,120, 7369−7370 Journal of the American Chemical Society. 120: 12706-12706. DOI: 10.1021/Ja985527E  0.481
1998 Mann G, Baranano D, Hartwig JF, Rheingold AL, Guzei IA. Carbon−Sulfur Bond-Forming Reductive Elimination Involving sp-, sp2-, and sp3-Hybridized Carbon. Mechanism, Steric Effects, and Electronic Effects on Sulfide Formation Journal of the American Chemical Society. 120: 9205-9219. DOI: 10.1021/Ja981428P  0.491
1998 Hamann BC, Hartwig JF. Sterically hindered chelating alkyl phosphines provide large rate accelerations in palladium-catalyzed amination of aryl iodides, bromides, and chlorides, and the first amination of aryl tosylates [12] Journal of the American Chemical Society. 120: 7369-7370. DOI: 10.1021/Ja981318I  0.515
1998 Mann G, Hartwig JF, Driver MS, Fernández-Rivas C. Palladium-Catalyzed C−N(sp2) Bond Formation: N-Arylation of Aromatic and Unsaturated Nitrogen and the Reductive Elimination Chemistry of Palladium Azolyl and Methyleneamido Complexes Journal of the American Chemical Society. 120: 827-828. DOI: 10.1021/Ja973524G  0.483
1998 Hamann BC, Hartwig JF. Systematic variation of bidentate ligands used in aryl halide amination. Unexpected effects of steric, electronic, and geometric perturbations Journal of the American Chemical Society. 120: 3694-3703. DOI: 10.1021/Ja9721881  0.431
1998 Hartwig JF. Carbon−Heteroatom Bond-Forming Reductive Eliminations of Amines, Ethers, and Sulfides Accounts of Chemical Research. 31: 852-860. DOI: 10.1021/Ar970282G  0.397
1998 Hartwig JF. Synthese, Struktur und Reaktionen eines Palladium-Hydrazonatokomplexes – neuartige reduktive Eliminierung unter Knüpfung von C-N-Bindungen sowie katalytische Arylierung von Benzophenonhydrazon Angewandte Chemie. 110: 2249-2252. DOI: 10.1002/(Sici)1521-3757(19980803)110:15<2249::Aid-Ange2249>3.0.Co;2-F  0.325
1998 Hartwig JF. Übergangsmetall-katalysierte Synthese von Arylaminen und Arylethern aus Arylhalogeniden und -triflaten: Anwendungen und Reaktionsmechanismus Angewandte Chemie. 110: 2154-2177. DOI: 10.1002/(Sici)1521-3757(19980803)110:15<2154::Aid-Ange2154>3.0.Co;2-C  0.367
1997 Waltz KM, Hartwig JF. Selective functionalization of alkanes by transition-metal boryl complexes Science. 277: 211-213. DOI: 10.1126/Science.277.5323.211  0.826
1997 Hartwig J. Palladium-Catalyzed Amination of Aryl Halides: Mechanism and Rational Catalyst Design Synlett. 1997: 329-340. DOI: 10.1055/S-1997-789  0.551
1997 Driver MS, Hartwig JF. Energetics and Mechanism of Alkylamine N−H Bond Cleavage by Palladium Hydroxides:  N−H Activation by Unusual Acid−Base Chemistry Organometallics. 16: 5706-5715. DOI: 10.1021/Om970856L  0.505
1997 Mann G, Hartwig JF. Nickel- vs Palladium-Catalyzed Synthesis of Protected Phenols from Aryl Halides The Journal of Organic Chemistry. 62: 5413-5418. DOI: 10.1021/Jo970453V  0.554
1997 Louie J, Driver MS, Hamann BC, Hartwig JF. Palladium-Catalyzed Amination of Aryl Triflates and Importance of Triflate Addition Rate The Journal of Organic Chemistry. 62: 1268-1273. DOI: 10.1021/Jo961930X  0.679
1997 Louie J, Hartwig JF, Fry AF. Discrete high molecular weight triarylamine dendrimers prepared by palladium-catalyzed amination Journal of the American Chemical Society. 119: 11695-11696. DOI: 10.1021/Ja972806D  0.557
1997 Hamann BC, Hartwig JF. Palladium-Catalyzed Direct α-Arylation of Ketones. Rate Acceleration by Sterically Hindered Chelating Ligands and Reductive Elimination from a Transition Metal Enolate Complex Journal of the American Chemical Society. 119: 12382-12383. DOI: 10.1021/Ja9727880  0.433
1997 Driver MS, Hartwig JF. Carbon−Nitrogen-Bond-Forming Reductive Elimination of Arylamines from Palladium(II) Phosphine Complexes Journal of the American Chemical Society. 119: 8232-8245. DOI: 10.1021/Ja971057X  0.454
1997 Mann G, Hartwig JF. Palladium-Catalyzed Formation of Diaryl Ethers from Aryl Bromides. Electron Poor Phosphines enhance Reaction Yields Tetrahedron Letters. 38: 8005-8008. DOI: 10.1016/S0040-4039(97)10175-7  0.48
1996 Hartwig JF, He X. Structural and Reaction Chemistry of Tungstenocene Boryl Complexes Organometallics. 15: 5350-5358. DOI: 10.1021/Om9606303  0.444
1996 Louie J, Paul F, Hartwig JF. Catalysis with Platinum-Group Alkylamido Complexes. The Active Palladium Amide in Catalytic Aryl Halide Aminations As Deduced from Kinetic Data and Independent Generation Organometallics. 15: 2794-2805. DOI: 10.1021/Om960188O  0.493
1996 He X, Hartwig JF. Boryls Bound to Iron Carbonyl. Structure of a Rare Bis(boryl) Complex, Synthesis of the First Anionic Boryl, and Reaction Chemistry That Includes the Synthetic Equivalent of Boryl Anion Transfer Organometallics. 15: 400-407. DOI: 10.1021/Om950437T  0.486
1996 Mann G, Hartwig JF. Palladium Alkoxides:  Potential Intermediacy in Catalytic Amination, Reductive Elimination of Ethers, and Catalytic Etheration. Comments on Alcohol Elimination from Ir(III) Journal of the American Chemical Society. 118: 13109-13110. DOI: 10.1021/Ja963273W  0.383
1996 Hartwig JF, Muhoro CN, He X, Eisenstein O, Bosque R, Maseras F. Catecholborane bound to titanocene. Unusual coordination of ligand σ-bonds Journal of the American Chemical Society. 118: 10936-10937. DOI: 10.1021/Ja962086V  0.349
1996 Hartwig JF. Directly-Observed β-Hydrogen Elimination of a Late Transition Metal Amido Complex and Unusual Fate of Imine Byproducts Journal of the American Chemical Society. 118: 7010-7011. DOI: 10.1021/Ja961439N  0.326
1996 Driver MS, Hartwig JF. A Second-Generation Catalyst for Aryl Halide Amination:  Mixed Secondary Amines from Aryl Halides and Primary Amines Catalyzed by (DPPF)PdCl2 Journal of the American Chemical Society. 118: 7217-7218. DOI: 10.1021/Ja960937T  0.463
1996 Rablen PR, Hartwig JF. Accurate Borane Sequential Bond Dissociation Energies by High-Level ab Initio Computational Methods Journal of the American Chemical Society. 118: 4648-4653. DOI: 10.1021/Ja9542451  0.308
1996 Hartwig JF, Richards S, Barañano D, Paul F. Influences on the Relative Rates for C−N Bond-Forming Reductive Elimination and β-Hydrogen Elimination of Amides. A Case Study on the Origins of Competing Reduction in the Palladium-Catalyzed Amination of Aryl Halides Journal of the American Chemical Society. 118: 3626-3633. DOI: 10.1021/Ja954121O  0.477
1996 He X, Hartwig JF. True Metal-Catalyzed Hydroboration with Titanium Journal of the American Chemical Society. 118: 1696-1702. DOI: 10.1021/Ja9516773  0.473
1996 Hartwig JF, He X. Reactivity of Tungstenocene with BB and BH Bonds versus CH Bonds Angewandte Chemie International Edition in English. 35: 315-317. DOI: 10.1002/Anie.199603151  0.309
1996 Louie J, Hartwig JF. Von PdII-Metallacyclen zu Pd0-Komplexen in Aminierungen und Kreuzkupplungen Angewandte Chemie. 108: 2531-2533. DOI: 10.1002/Ange.19961082022  0.524
1995 Paul F, Patt J, Hartwig JF. Structural Characterization and Simple Synthesis of {Pd[P(o-Tol)3]2}. Spectroscopic Study and Structural Characterization of the Dimeric Palladium(II) Complexes Obtained by Oxidative Addition of Aryl Bromides and Their Reactivity with Amines Organometallics. 14: 3030-3039. DOI: 10.1021/Om00006A053  0.414
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