Alison J. Frontier, Ph.D. - Publications

Affiliations: 
Chemistry University of Rochester, Rochester, NY 
Area:
Synthetic Organic Chemistry
Website:
http://www.chem.rochester.edu/faculty/faculty.php?name=frontier

117 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Hernandez JJ, Lawrie AP, Frontier AJ. Alkynyl Halo-Aza-Prins Annulative Couplings. The Journal of Organic Chemistry. PMID 37971946 DOI: 10.1021/acs.joc.3c01305  0.363
2023 Milosavljevic A, Holt C, Frontier AJ. Nitrogen-interrupted -Prins/-Nazarov fragment coupling cascade for the synthesis of indolines. Chemical Science. 14: 5431-5437. PMID 37234889 DOI: 10.1039/d3sc00986f  0.428
2022 Hernandez JJ, Frontier AJ. Alkynyl Prins carbocyclization cascades for the synthesis of linear-fused heterocyclic ring systems. Chemical Science. 13: 13836-13842. PMID 36544720 DOI: 10.1039/d2sc04750k  0.824
2022 Thoenen M, Gettings M, Holt C, Frontier AJ, Caruana PA, Zeller M, Byrd EFC, Piercey DG. Approach to High-Nitrogen Materials with Dual-Use Properties via Tetraaza-Nazarov Cyclization. Inorganic Chemistry. PMID 36318095 DOI: 10.1021/acs.inorgchem.2c02649  0.823
2022 Yadykov AV, Eremchenko AE, Milosavljevic A, Frontier AJ, Shirinian VZ. Divergent Reactivity of Triaryldivinyl Ketones: Competing 4π and Putative 6π Electrocyclization Pathways. The Journal of Organic Chemistry. 87: 13643-13652. PMID 36220664 DOI: 10.1021/acs.joc.2c01294  0.796
2021 Frontier AJ, Sinclair PP. Merging Strategy, Improvisation, and Conversation to Solve Problems in Target Synthesis. Accounts of Chemical Research. PMID 33705115 DOI: 10.1021/acs.accounts.0c00804  0.301
2021 Hernandez JJ, Frontier AJ. Synthesis of Spirocyclic Isoindolones Using an Alkynyl -Prins/Oxidative -Nazarov Cyclization Sequence. Organic Letters. PMID 33591209 DOI: 10.1021/acs.orglett.1c00191  0.824
2020 Frontier AJ, Hernandez JJ. New Twists in Nazarov Cyclization Chemistry. Accounts of Chemical Research. PMID 32790284 DOI: 10.1021/Acs.Accounts.0C00284  0.815
2020 Alachouzos G, Holt C, Frontier AJ. Correction to "Stereochemical Relay through a Cationic Intermediate: Helical Preorganization Dictates Direction of Conrotation in the -Nazarov Cyclization". Organic Letters. 22: 5713. PMID 32633967 DOI: 10.1021/Acs.Orglett.0C02062  0.398
2020 Abdul-Rashed S, Alachouzos G, Brennessel WW, Frontier AJ. Correction to "One-Pot Double-Annulation Strategy for the Synthesis of Unusual Fused Bis-Heterocycles". Organic Letters. PMID 32598846 DOI: 10.1021/Acs.Orglett.0C01958  0.48
2020 Abdul-Rashed S, Alachouzos G, Brennessel WW, Frontier AJ. One-Pot Double-Annulation Strategy for the Synthesis of Unusual Fused Bis-Heterocycles. Organic Letters. PMID 32412769 DOI: 10.1021/Acs.Orglett.0C01351  0.483
2020 Alachouzos G, Holt C, Frontier AJ. Stereochemical Relay through a Cationic Intermediate: Helical Preorganization Dictates Direction of Conrotation in the -Nazarov Cyclization. Organic Letters. PMID 32352794 DOI: 10.1021/acs.orglett.0c01330  0.357
2020 Abdul-Rashed S, Holt C, Frontier AJ. Alkynyl Prins and Alkynyl Aza-Prins Annulations: Scope and Synthetic Applications Synthesis. 52: 1991-2007. DOI: 10.1055/S-0039-1690869  0.589
2019 Holt C, Alachouzos G, Frontier AJ. Leveraging the Halo-Nazarov Cyclization for the Chemodivergent Assembly of Functionalized Haloindenes and Indanones. Journal of the American Chemical Society. PMID 30900884 DOI: 10.1021/Jacs.9B00198  0.491
2019 Parsons DE, Frontier AJ. Noncanonical Cation-π Cyclizations of Alkylidene β-Ketoesters: Synthesis of Spiro-fused and Bridged Bicyclic Ring Systems. Organic Letters. PMID 30869901 DOI: 10.1021/Acs.Orglett.9B00094  0.499
2018 Alachouzos G, Frontier AJ. Cationic Cascade for Building Complex Polycyclic Molecules from Simple Precursors: Diastereoselective Installation of Three Contiguous Stereogenic Centers in a One-Pot Process. Journal of the American Chemical Society. PMID 30571090 DOI: 10.1021/Jacs.8B11713  0.434
2018 Frontier A, Carlsen P, Stoutenburg E. SYNTHESIS–SYNLETT Lecture: Toward the Asymmetric Synthesis of Tetrapetalone A: Preparation of an Enantioenriched Indane Intermediate and Strategy for Endgame Glycosylation Synthesis. 50: 1238-1245. DOI: 10.1055/S-0036-1591747  0.833
2018 Frontier A, Carlsen P, Stoutenburg E. SYNTHESIS–SYNLETT Lecture: Toward the Asymmetric Synthesis of Tetrapetalone A: Preparation of an Enantioenriched Indane Intermediate and Strategy for Endgame Glycosylation Synthesis. 50: 1238-1245. DOI: 10.1055/s-0036-1591747  0.416
2018 Frontier A, Carlsen P, Stoutenburg E. SYNTHESIS–SYNLETT Lecture: Toward the Asymmetric Synthesis of Tetrapetalone A: Preparation of an Enantioenriched Indane Intermediate and Strategy for Endgame Glycosylation Synthesis. 50: 1238-1245. DOI: 10.1055/s-0036-1591747  0.416
2018 Frontier A, Carlsen P, Stoutenburg E. SYNTHESIS–SYNLETT Lecture: Toward the Asymmetric Synthesis of Tetrapetalone A: Preparation of an Enantioenriched Indane Intermediate and Strategy for Endgame Glycosylation Synthesis. 50: 1238-1245. DOI: 10.1055/s-0036-1591747  0.416
2018 Frontier A, Carlsen P, Stoutenburg E. SYNTHESIS–SYNLETT Lecture: Toward the Asymmetric Synthesis of Tetrapetalone A: Preparation of an Enantioenriched Indane Intermediate and Strategy for Endgame Glycosylation Synthesis. 50: 1238-1245. DOI: 10.1055/s-0036-1591747  0.416
2018 Frontier A, Carlsen P, Stoutenburg E. SYNTHESIS–SYNLETT Lecture: Toward the Asymmetric Synthesis of Tetrapetalone A: Preparation of an Enantioenriched Indane Intermediate and Strategy for Endgame Glycosylation Synthesis. 50: 1238-1245. DOI: 10.1055/s-0036-1591747  0.416
2018 Frontier A, Carlsen P, Stoutenburg E. SYNTHESIS–SYNLETT Lecture: Toward the Asymmetric Synthesis of Tetrapetalone A: Preparation of an Enantioenriched Indane Intermediate and Strategy for Endgame Glycosylation Synthesis. 50: 1238-1245. DOI: 10.1055/s-0036-1591747  0.416
2018 Frontier A, Carlsen P, Stoutenburg E. SYNTHESIS–SYNLETT Lecture: Toward the Asymmetric Synthesis of Tetrapetalone A: Preparation of an Enantioenriched Indane Intermediate and Strategy for Endgame Glycosylation Synthesis. 50: 1238-1245. DOI: 10.1055/s-0036-1591747  0.416
2018 Frontier A, Carlsen P, Stoutenburg E. SYNTHESIS–SYNLETT Lecture: Toward the Asymmetric Synthesis of Tetrapetalone A: Preparation of an Enantioenriched Indane Intermediate and Strategy for Endgame Glycosylation Synthesis. 50: 1238-1245. DOI: 10.1055/s-0036-1591747  0.416
2018 Frontier A, Carlsen P, Stoutenburg E. SYNTHESIS–SYNLETT Lecture: Toward the Asymmetric Synthesis of Tetrapetalone A: Preparation of an Enantioenriched Indane Intermediate and Strategy for Endgame Glycosylation Synthesis. 50: 1238-1245. DOI: 10.1055/s-0036-1591747  0.416
2017 Alachouzos G, Frontier AJ. Diastereoselective Construction of Densely Functionalized 1-Halocyclopentenes Using an Alkynyl Halo-Prins/Halo-Nazarov Cyclization Strategy. Angewandte Chemie (International Ed. in English). PMID 29065241 DOI: 10.1002/Anie.201709482  0.451
2016 Huang YW, Frontier AJ. Nazarov Cyclization/Internal Redox Cyclization Sequence for the Synthesis of N-Heterocyclic Bridged Ring Systems. Organic Letters. PMID 27652822 DOI: 10.1021/Acs.Orglett.6B02369  0.525
2015 Carlsen P, Jiang C, Herrick IR, Frontier AJ. Studies toward the AB ring system of the tetrapetalone natural products. Tetrahedron. 71: 5886-5896. PMID 26309334 DOI: 10.1016/J.Tet.2015.05.021  0.806
2015 Huang YW, Frontier AJ. Enantioselective Nazarov Cyclization Catalyzed by a Cinchona Alkaloid Derivative. Tetrahedron Letters. 56: 3523-3526. PMID 26085696 DOI: 10.1016/J.Tetlet.2014.12.136  0.496
2015 Carlsen PN, Jiang C, Herrick IR, Frontier AJ. Studies toward the AB ring system of the tetrapetalone natural products Tetrahedron. DOI: 10.1016/j.tet.2015.05.021  0.776
2014 Jacob SD, Brooks JL, Frontier AJ. No acid required: 4π and 6π electrocyclization reactions of dienyl diketones for the synthesis of cyclopentenones and 2H-Pyrans. The Journal of Organic Chemistry. 79: 10296-302. PMID 25325706 DOI: 10.1021/Jo501914W  0.493
2014 Carlsen PN, Mann TJ, Hoveyda AH, Frontier AJ. Synthesis of (±)-tetrapetalone A-Me aglycon. Angewandte Chemie (International Ed. in English). 53: 9334-8. PMID 25045072 DOI: 10.1002/Anie.201404410  0.834
2014 Vaidya T, Cheng R, Carlsen PN, Frontier AJ, Eisenberg R. Cationic cyclizations and rearrangements promoted by a heterogeneous gold catalyst. Organic Letters. 16: 800-3. PMID 24432741 DOI: 10.1021/Ol403542K  0.798
2014 Ciesielski J, Frontier A. The phomactin natural products from isolation to total synthesis: A review Organic Preparations and Procedures International. 46: 214-251. DOI: 10.1080/00304948.2014.903142  0.729
2014 Leboeuf D, Ciesielski J, Frontier AJ. Gold(I)-catalyzed iodination of arenes Synlett. 25: 399-402. DOI: 10.1055/S-0034-1380682  0.776
2014 Brooks JL, Huang YW, Frontier AJ. Preparation of 5-hydroxycyclopentenones via conjugate addition-initiated nazarov cyclization Organic Syntheses. 91: 93-105. DOI: 10.1002/0471264229.Os091.09  0.514
2013 Spencer WT, Vaidya T, Frontier AJ. Beyond the Divinyl Ketone: Innovations in the Generation and Nazarov Cyclization of Pentadienyl Cation Intermediates. European Journal of Organic Chemistry. 2013. PMID 24348092 DOI: 10.1002/Ejoc.201300134  0.807
2013 Ciesielski J, Lebœuf D, Stern HA, Frontier AJ. Gold (III) Chloride-Catalyzed 6-endo-trig Oxa-Michael Addition Reactions for Diastereoselective Synthesis of Fused Tetrahydropyranones. Advanced Synthesis & Catalysis. 355: 2077-2082. PMID 24032002 DOI: 10.1002/Adsc.201300265  0.803
2013 Ciesielski J, Gandon V, Frontier AJ. Cascade cyclizations of acyclic and macrocyclic alkynones: studies toward the synthesis of phomactin A. The Journal of Organic Chemistry. 78: 9541-52. PMID 23724905 DOI: 10.1021/Jo4007514  0.824
2013 Lebœuf D, Theiste E, Gandon V, Daifuku SL, Neidig ML, Frontier AJ. Efficient Nazarov cyclization/Wagner-Meerwein rearrangement terminated by a Cu(II)-promoted oxidation: synthesis of 4-alkylidene cyclopentenones. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 4842-8. PMID 23436470 DOI: 10.1002/Chem.201203396  0.493
2013 Lebœuf D, Wright CM, Frontier AJ. Reagent control of [1,2]-Wagner-Meerwein shift chemoselectivity following the Nazarov cyclization: application to the total synthesis of enokipodin B. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 4835-41. PMID 23436444 DOI: 10.1002/Chem.201203395  0.428
2012 Brooks JL, Frontier AJ. Cyclization cascades initiated by 1,6-conjugate addition. Journal of the American Chemical Society. 134: 16551-3. PMID 23004564 DOI: 10.1021/Ja308451Y  0.524
2012 Spencer WT, Frontier AJ. Cycloaromatization protocol for synthesis of polysubstituted phenol derivatives: method development and mechanistic studies. The Journal of Organic Chemistry. 77: 7730-6. PMID 22891882 DOI: 10.1021/Jo3010952  0.797
2012 Ciesielski J, Cariou K, Frontier AJ. A macrocyclic β-iodoallenolate intermediate is key: synthesis of the ABD core of phomactin A. Organic Letters. 14: 4082-5. PMID 22853449 DOI: 10.1021/Ol3017116  0.838
2012 Lebœuf D, Gandon V, Ciesielski J, Frontier AJ. Experimental and theoretical studies on the Nazarov cyclization/Wagner-Meerwein rearrangement sequence. Journal of the American Chemical Society. 134: 6296-308. PMID 22471833 DOI: 10.1021/Ja211970P  0.762
2012 Malona JA, Cariou K, Spencer WT, Frontier AJ. Total synthesis of (±)-rocaglamide via oxidation-initiated Nazarov cyclization. The Journal of Organic Chemistry. 77: 1891-908. PMID 22283818 DOI: 10.1021/Jo202366C  0.824
2012 Lautens M, Newman SG, Lebœuf D, Huang J, Gandon V, Frontier AJ. Advances in Nazarov Cyclizations through Control of [1,2]-Migrations Synfacts. 8: 57-57. DOI: 10.1055/S-0031-1289508  0.382
2011 Lebœuf D, Huang J, Gandon V, Frontier AJ. Using Nazarov electrocyclization to stage chemoselective [1,2]-migrations: stereoselective synthesis of functionalized cyclopentenones. Angewandte Chemie (International Ed. in English). 50: 10981-5. PMID 21953873 DOI: 10.1002/Anie.201104870  0.46
2011 Trost BM, Frontier AJ, Thiel OR, Yang H, Dong G. Total synthesis of bryostatins: the development of methodology for the atom-economic and stereoselective synthesis of the ring C subunit. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 9762-76. PMID 21793057 DOI: 10.1002/Chem.201002898  0.822
2011 Brooks JL, Caruana PA, Frontier AJ. Conjugate addition-initiated Nazarov cyclization. Journal of the American Chemical Society. 133: 12454-7. PMID 21780785 DOI: 10.1021/Ja205440X  0.826
2011 Huang J, Lebœuf D, Frontier AJ. Understanding the fate of the oxyallyl cation following Nazarov electrocyclization: sequential Wagner-Meerwein migrations and the synthesis of spirocyclic cyclopentenones. Journal of the American Chemical Society. 133: 6307-17. PMID 21466152 DOI: 10.1021/Ja111504W  0.547
2011 Vaidya T, Manbeck GF, Chen S, Frontier AJ, Eisenberg R. Divergent reaction pathways of a cationic intermediate: rearrangement and cyclization of 2-substituted furyl and benzofuryl enones catalyzed by iridium(III). Journal of the American Chemical Society. 133: 3300-3. PMID 21322633 DOI: 10.1021/Ja111317Q  0.654
2011 Spencer WT, Levin MD, Frontier AJ. Oxidation-initiated Nazarov cyclization of vinyl alkoxyallenes. Organic Letters. 13: 414-7. PMID 21155592 DOI: 10.1021/Ol1027255  0.817
2011 Brooks JL, Caruana PA, Frontier AJ. Nazarov Cyclizations of Dienyl Diketones Initiated by ConjugateAddition Synfacts. 2011: 1091-1091. DOI: 10.1055/S-0030-1261134  0.472
2011 Trost BM, Frontier AJ, Thiel OR, Yang H, Dong G. ChemInform Abstract: Total Synthesis of Bryostatins: The Development of Methodology for the Atom-Economic and Stereoselective Synthesis of the Ring C Subunit. Cheminform. 43: no-no. DOI: 10.1002/chin.201202195  0.773
2011 Vaidya T, Eisenberg R, Frontier AJ. Catalytic nazarov cyclization: The state of the art Chemcatchem. 3: 1531-1548. DOI: 10.1002/Cctc.201100137  0.489
2010 Atesin AC, Zhang J, Vaidya T, Brennessel WW, Frontier AJ, Eisenberg R. Synthesis, characterization, and catalytic properties of new electrophilic iridium(III) complexes containing the (R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl ligand. Inorganic Chemistry. 49: 4331-42. PMID 20361755 DOI: 10.1021/Ic100300Y  0.566
2010 Vaidya T, Atesin AC, Herrick IR, Frontier AJ, Eisenberg R. A highly reactive dicationic iridium(III) catalyst for the polarized Nazarov cyclization reaction. Angewandte Chemie (International Ed. in English). 49: 3363-6. PMID 20358570 DOI: 10.1002/Anie.201000100  0.801
2010 Zhang J, Vaidya T, Brennessel WW, Frontier AJ, Eisenberg R. Dicationic palladium(II) complexes as active lewis acid catalysts for polarized nazarov cyclization Organometallics. 29: 3341-3349. DOI: 10.1021/Om100274G  0.491
2010 Ciesielski J, Canterbury DP, Frontier AJ. ChemInform Abstract: β-Iodoallenolates as Springboards for Annulation Reactions. Cheminform. 41. DOI: 10.1002/chin.201008030  0.719
2009 Canterbury DP, Herrick IR, Um J, Houk KN, Frontier AJ. A Torquoselective Extrusion of Isoxazoline N-Oxides. Application to the Synthesis of Aryl Vinyl and Divinyl Ketones for Nazarov Cyclization. Tetrahedron. 65: 3165-3179. PMID 20161228 DOI: 10.1016/J.Tet.2008.10.003  0.836
2009 Ciesielski J, Canterbury DP, Frontier AJ. Beta-iodoallenolates as springboards for annulation reactions. Organic Letters. 11: 4374-7. PMID 19736911 DOI: 10.1021/Ol901721Y  0.794
2009 Malona JA, Cariou K, Frontier AJ. Nazarov cyclization initiated by peracid oxidation: the total synthesis of (+/-)-rocaglamide. Journal of the American Chemical Society. 131: 7560-1. PMID 19445456 DOI: 10.1021/Ja9029736  0.827
2009 Bitar AY, Frontier AJ. Formal synthesis of (+/-)-roseophilin. Organic Letters. 11: 49-52. PMID 19053717 DOI: 10.1021/Ol802329Y  0.845
2009 Bitar AY, Frontier AJ. Formal Synthesis of ()-Roseophilin Synfacts. 2009: 824-824. DOI: 10.1055/S-0029-1217579  0.822
2009 Canterbury DP, Herrick IR, Um J, Houk KN, Frontier AJ. ChemInform Abstract: A Torquoselective Extrusion of Isoxazoline N-Oxides. Application to the Synthesis of Aryl Vinyl and Divinyl Ketones for Nazarov Cyclization. Cheminform. 40. DOI: 10.1002/chin.200933137  0.817
2009 Bitar AY, Frontier AJ. ChemInform Abstract: Formal Synthesis of (.+-.)-Roseophilin (I). Cheminform. 40. DOI: 10.1002/chin.200919190  0.824
2009 Bitar AY, Frontier AJ. ChemInform Abstract: Formal Synthesis of (.+-.)-Roseophilin (I). Cheminform. 40. DOI: 10.1002/chin.200919190  0.377
2009 Bitar AY, Frontier AJ. ChemInform Abstract: Formal Synthesis of (.+-.)-Roseophilin (I). Cheminform. 40. DOI: 10.1002/chin.200919190  0.377
2009 Bitar AY, Frontier AJ. ChemInform Abstract: Formal Synthesis of (.+-.)-Roseophilin (I). Cheminform. 40. DOI: 10.1002/chin.200919190  0.377
2009 Bitar AY, Frontier AJ. ChemInform Abstract: Formal Synthesis of (.+-.)-Roseophilin (I). Cheminform. 40. DOI: 10.1002/chin.200919190  0.377
2009 Bitar AY, Frontier AJ. ChemInform Abstract: Formal Synthesis of (.+-.)-Roseophilin (I). Cheminform. 40. DOI: 10.1002/chin.200919190  0.377
2009 Bitar AY, Frontier AJ. ChemInform Abstract: Formal Synthesis of (.+-.)-Roseophilin (I). Cheminform. 40. DOI: 10.1002/chin.200919190  0.377
2009 Bitar AY, Frontier AJ. ChemInform Abstract: Formal Synthesis of (.+-.)-Roseophilin (I). Cheminform. 40. DOI: 10.1002/chin.200919190  0.377
2009 Bitar AY, Frontier AJ. ChemInform Abstract: Formal Synthesis of (.+-.)-Roseophilin (I). Cheminform. 40. DOI: 10.1002/chin.200919190  0.377
2009 Bitar AY, Frontier AJ. ChemInform Abstract: Formal Synthesis of (.+-.)-Roseophilin (I). Cheminform. 40. DOI: 10.1002/chin.200919190  0.377
2009 Canterbury DP, Frontier AJ, Um JM, Cheong PH, Goldfeld DA, Huhn RA, Houk KN. ChemInform Abstract: Origins of Stereoselectivity in the Oxido-Alkylidenation of Alkynes. Cheminform. 40. DOI: 10.1002/chin.200910073  0.767
2009 Canterbury DP, Frontier AJ, Um JM, Cheong PH, Goldfeld DA, Huhn RA, Houk KN. ChemInform Abstract: Origins of Stereoselectivity in the Oxido-Alkylidenation of Alkynes. Cheminform. 40. DOI: 10.1002/chin.200910073  0.767
2009 Canterbury DP, Frontier AJ, Um JM, Cheong PH, Goldfeld DA, Huhn RA, Houk KN. ChemInform Abstract: Origins of Stereoselectivity in the Oxido-Alkylidenation of Alkynes. Cheminform. 40. DOI: 10.1002/chin.200910073  0.767
2008 Canterbury DP, Frontier AJ, Um JM, Cheong PH, Goldfeld DA, Huhn RA, Houk KN. Origins of stereoselectivity in the oxido-alkylidenation of alkynes. Organic Letters. 10: 4597-600. PMID 18798638 DOI: 10.1021/Ol8019154  0.749
2008 He W, Herrick IR, Atesin TA, Caruana PA, Kellenberger CA, Frontier AJ. Polarizing the Nazarov cyclization: the impact of dienone substitution pattern on reactivity and selectivity. Journal of the American Chemical Society. 130: 1003-11. PMID 18161974 DOI: 10.1021/Ja077162G  0.796
2008 He W, Huang J, Sun X, Frontier AJ. Total synthesis of (+/-)-merrilactone A. Journal of the American Chemical Society. 130: 300-8. PMID 18067294 DOI: 10.1021/Ja0761986  0.553
2008 He W, Herrick IR, Atesin TA, Caruana PA, Kellenberger CA, Frontier AJ. Lewis Acid Catalyzed Nazarov Cyclization of Dienones Bearing Polar Substituents Synfacts. 2008: 400-400. DOI: 10.1055/S-2008-1042869  0.391
2007 Jiang C, Frontier AJ. Stereoselective synthesis of pyrrolidine derivatives via reduction of substituted pyrroles. Organic Letters. 9: 4939-42. PMID 17960937 DOI: 10.1021/Ol701962W  0.485
2007 Huang J, Frontier AJ. Development of a Nazarov cyclization/Wagner-Meerwein rearrangement sequence for the stereoselective synthesis of spirocycles. Journal of the American Chemical Society. 129: 8060-1. PMID 17555319 DOI: 10.1021/Ja0716148  0.478
2007 Trost BM, Yang H, Thiel OR, Frontier AJ, Brindle CS. Synthesis of a ring-expanded bryostatin analogue. Journal of the American Chemical Society. 129: 2206-7. PMID 17279751 DOI: 10.1021/Ja067305J  0.814
2007 He W, Huang J, Sun X, Frontier AJ. Total synthesis of (+/-)-merrilactone A via catalytic Nazarov cyclization. Journal of the American Chemical Society. 129: 498-9. PMID 17227006 DOI: 10.1021/Ja068150I  0.555
2007 Frontier A, He W, Huang J, Sun X. Synthesis of (±)-Merrilactone A Synfacts. 2007: 0669-0669. DOI: 10.1055/S-2007-968603  0.304
2007 Frontier A, Malona J, Colbourne J. Catalytic Nazarov Cyclization of Heteroaromatic Compounds Synfacts. 2007: 0186-0186. DOI: 10.1055/S-2006-958970  0.786
2007 Caruana PA, Frontier AJ. Palladium(II)- and mercury(II)-catalyzed rearrangements of propargyl acetates Tetrahedron. 63: 10646-10656. DOI: 10.1016/J.Tet.2007.08.008  0.8
2006 Malona JA, Colbourne JM, Frontier AJ. A general method for the catalytic nazarov cyclization of heteroaromatic compounds. Organic Letters. 8: 5661-4. PMID 17107097 DOI: 10.1021/Ol062403V  0.826
2006 Janka M, He W, Haedicke IE, Fronczek FR, Frontier AJ, Eisenberg R. Tandem Nazarov cyclization-michael addition sequence catalyzed by an Ir(III) complex. Journal of the American Chemical Society. 128: 5312-3. PMID 16620081 DOI: 10.1021/Ja058772O  0.634
2006 Frontier A, Eisenberg R, Janka M, He W, Haedicke I, Fronczek F. Ir(III)-Catalyzed Tandem Nazarov Cyclization/Michael Addition Synfacts. 2006: 0683-0683. DOI: 10.1055/S-2006-941865  0.56
2006 Frontier A, Eisenberg R, Janka M, He W, Haedicke I, Fronczek F. Ir(III)-Catalyzed Tandem Nazarov Cyclization/Michael Addition Synfacts. 2006: 0683-0683. DOI: 10.1055/S-2006-941865  0.56
2006 Frontier A, Eisenberg R, Janka M, He W, Haedicke I, Fronczek F. Ir(III)-Catalyzed Tandem Nazarov Cyclization/Michael Addition Synfacts. 2006: 0683-0683. DOI: 10.1055/s-2006-941865  0.361
2006 Frontier A, Eisenberg R, Janka M, He W, Haedicke I, Fronczek F. Ir(III)-Catalyzed Tandem Nazarov Cyclization/Michael Addition Synfacts. 2006: 0683-0683. DOI: 10.1055/s-2006-941865  0.361
2006 Frontier A, Eisenberg R, Janka M, He W, Haedicke I, Fronczek F. Ir(III)-Catalyzed Tandem Nazarov Cyclization/Michael Addition Synfacts. 2006: 0683-0683. DOI: 10.1055/s-2006-941865  0.361
2006 Frontier A, Eisenberg R, Janka M, He W, Haedicke I, Fronczek F. Ir(III)-Catalyzed Tandem Nazarov Cyclization/Michael Addition Synfacts. 2006: 0683-0683. DOI: 10.1055/s-2006-941865  0.361
2006 Frontier A, Eisenberg R, Janka M, He W, Haedicke I, Fronczek F. Ir(III)-Catalyzed Tandem Nazarov Cyclization/Michael Addition Synfacts. 2006: 0683-0683. DOI: 10.1055/s-2006-941865  0.361
2006 Frontier A, Eisenberg R, Janka M, He W, Haedicke I, Fronczek F. Ir(III)-Catalyzed Tandem Nazarov Cyclization/Michael Addition Synfacts. 2006: 0683-0683. DOI: 10.1055/s-2006-941865  0.361
2006 Frontier A, Eisenberg R, Janka M, He W, Haedicke I, Fronczek F. Ir(III)-Catalyzed Tandem Nazarov Cyclization/Michael Addition Synfacts. 2006: 0683-0683. DOI: 10.1055/S-2006-941865  0.56
2006 Frontier A, Eisenberg R, Janka M, He W, Haedicke I, Fronczek F. Ir(III)-Catalyzed Tandem Nazarov Cyclization/Michael Addition Synfacts. 2006: 0683-0683. DOI: 10.1055/s-2006-941865  0.361
2005 Frontier AJ, Collison C. The Nazarov cyclization in organic synthesis. Recent advances Tetrahedron. 61: 7577-7606. DOI: 10.1016/J.Tet.2005.05.019  0.388
2005 Janka M, He W, Frontier AJ, Flaschenriem C, Eisenberg R. Preorganization in the Nazarov cyclization: The role of adjacent coordination sites in the highly Lewis acidic catalyst [IrMe(CO)(dppe)(DIB)] (BAr4 f)2 Tetrahedron. 61: 6193-6206. DOI: 10.1016/J.Tet.2005.03.114  0.572
2004 Janka M, He W, Frontier AJ, Eisenberg R. Efficient catalysis of Nazarov cyclization using a cationic iridium complex possessing adjacent labile coordination sites. Journal of the American Chemical Society. 126: 6864-5. PMID 15174845 DOI: 10.1021/Ja049643V  0.536
2004 He W, Sun X, Frontier AJ. Polarizing the Nazarov Cyclization:  Efficient Catalysis under Mild Conditions [J. Am. Chem.Soc.2003,125, 14278−14279]. Journal of the American Chemical Society. 126: 10493-10493. DOI: 10.1021/Ja0457258  0.419
2004 Caruana PA, Frontier AJ. Dearomatization of furans via [2,3]-Still-Wittig rearrangement Tetrahedron. 60: 10921-10926. DOI: 10.1016/J.Tet.2004.09.029  0.813
2003 He W, Sun X, Frontier AJ. Polarizing the Nazarov cyclization: efficient catalysis under mild conditions. Journal of the American Chemical Society. 125: 14278-9. PMID 14624567 DOI: 10.1021/Ja037910B  0.515
2001 Inoue M, Carson MW, Frontier AJ, Danishefsky SJ. Total synthesis and determination of the absolute configuration of frondosin B. Journal of the American Chemical Society. 123: 1878-89. PMID 11456808 DOI: 10.1021/Ja0021060  0.623
2001 Trost BM, Frontier AJ. ChemInform Abstract: Atom Economical Syntheses of Oxygen Heterocycles via Tandem Palladium-Catalyzed Reactions. Cheminform. 32: no-no. DOI: 10.1002/chin.200111129  0.439
2001 Trost BM, Frontier AJ. ChemInform Abstract: Atom Economical Syntheses of Oxygen Heterocycles via Tandem Palladium-Catalyzed Reactions. Cheminform. 32: no-no. DOI: 10.1002/chin.200111129  0.439
2000 Inoue M, Frontier AJ, Danishefsky SJ. The Total Synthesis of Frondosin B. Angewandte Chemie (International Ed. in English). 39: 761-764. PMID 10760861 DOI: 10.1002/(Sici)1521-3757(20000218)112:4<777::Aid-Ange777>3.0.Co;2-K  0.503
2000 Frontier AJ, Raghavan S, Danishefsky SJ. A highly stereoselective total synthesis of hispidospermidin: Derivation of a pharmacophore model Journal of the American Chemical Society. 122: 6151-6159. DOI: 10.1021/Ja9944960  0.575
2000 Trost BM, Frontier AJ. Atom economical syntheses of oxygen heterocycles via tandem palladium-catalyzed reactions [2] Journal of the American Chemical Society. 122: 11727-11728. DOI: 10.1021/Ja0022268  0.41
1998 Frontier AJ, Danishefsky SJ, Koppel GA, Meng D. A useful α, α' - Annulation reaction of enamines Tetrahedron. 54: 12721-12736. DOI: 10.1016/S0040-4020(98)00788-1  0.448
1997 Frontier AJ, Raghavan S, Danishefsky SJ. Stereocontrolled total synthesis of hispidospermidin Journal of the American Chemical Society. 119: 6686-6687. DOI: 10.1021/Ja970889S  0.59
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