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Laurel L. Schafer, Ph.D. - Publications

Affiliations: 
Chemistry University of British Columbia, Vancouver, Vancouver, BC, Canada 
Area:
Inorganic Chemistry, Organometallic Chemistry, Lanthanide Chemistry, Catalysis
Website:
http://www2.chem.ubc.ca/faculty/schafer/Site/Home.html

126 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Scott SS, Kaur B, Zheng CHM, Brant P, Gilmour DJ, Schafer LL. Amine-Functionalized Polybutadiene Synthesis by Tunable Postpolymerization Hydroaminoalkylation. Journal of the American Chemical Society. PMID 37819801 DOI: 10.1021/jacs.3c07564  0.313
2023 Hao H, Manßen M, Schafer LL. Tantalum ureate complexes for photocatalytic hydroaminoalkylation. Chemical Science. 14: 4928-4934. PMID 37181785 DOI: 10.1039/d3sc00042g  0.796
2023 Verma V, Schafer LL. One-Pot Sequential Hydroamination Protocol for N-Heterocycle Synthesis: One Method To Access Five Different Classes of Tri-Substituted Pyridines. The Journal of Organic Chemistry. 88: 1378-1384. PMID 36634317 DOI: 10.1021/acs.joc.2c02155  0.304
2022 Griffin SE, Adamczyk OV, Schafer LL. Vanadium pyridonates: dimerization, redox behaviour, and metal-ligand cooperativity. Dalton Transactions (Cambridge, England : 2003). 51: 14654-14663. PMID 36093858 DOI: 10.1039/d2dt02177c  0.432
2022 Zheng CHM, Balatsky DA, DiPucchio RC, Schafer LL. The Catalytic Synthesis of -Aryl Indoles Featuring an Alternative Disconnection. Hydroaminoalkylation for a Telescoped Reaction Sequence. Organic Letters. 24: 6571-6575. PMID 36069521 DOI: 10.1021/acs.orglett.2c02510  0.331
2022 Verma V, Koperniku A, Edwards PM, Schafer LL. -Silylamines in catalysis: synthesis and reactivity. Chemical Communications (Cambridge, England). PMID 35929426 DOI: 10.1039/d2cc02915d  0.355
2022 DiPucchio RC, Rosca SC, Schafer LL. Hydroaminoalkylation for the Catalytic Addition of Amines to Alkenes or Alkynes: Diverse Mechanisms Enable Diverse Substrate Scope. Journal of the American Chemical Society. 144: 11459-11481. PMID 35731810 DOI: 10.1021/jacs.1c10397  0.341
2021 Scott SS, Roşca SC, Gilmour DJ, Brant P, Schafer LL. Commodity Polymers to Functional Aminated Materials: Single-Step and Atom-Economic Synthesis by Hydroaminoalkylation. Acs Macro Letters. 10: 1266-1272. PMID 35549039 DOI: 10.1021/acsmacrolett.1c00519  0.325
2021 He W, Beattie DD, Zhou H, Bowes EG, Schafer LL, Love JA, Kennepohl P. Direct metal-carbon bonding in symmetric bis(C-H) agostic nickel(i) complexes. Chemical Science. 12: 15298-15307. PMID 34976350 DOI: 10.1039/d1sc03578a  0.557
2021 DiPucchio RC, Lenzen KE, Daneshmand P, Ezhova MB, Schafer LL. Direct, Catalytic α-Alkylation of -Heterocycles by Hydroaminoalkylation: Substrate Effects for Regiodivergent Product Formation. Journal of the American Chemical Society. PMID 34278789 DOI: 10.1021/jacs.1c05498  0.311
2021 Hao H, Bagnol T, Pucheault M, Schafer LL. Using Catalysts To Make Catalysts: Titanium-Catalyzed Hydroamination To Access -Ligands for Assembling Catalysts in One Pot. Organic Letters. PMID 33661014 DOI: 10.1021/acs.orglett.0c04212  0.377
2021 Koperniku A, Schafer LL. Zirconium Catalyzed Hydroaminoalkylation for the Synthesis of α-Arylated Amines and N-Heterocycles. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 33427338 DOI: 10.1002/chem.202100014  0.328
2020 Bahena EN, Griffin SE, Schafer LL. Zirconium-Catalyzed Hydroaminoalkylation of Alkynes for the Synthesis of Allylic Amines. Journal of the American Chemical Society. 142: 20566-20571. PMID 33249842 DOI: 10.1021/jacs.0c10405  0.391
2020 Manßen M, Schafer LL. Titanium catalysis for the synthesis of fine chemicals - development and trends. Chemical Society Reviews. PMID 32852007 DOI: 10.1039/D0Cs00229A  0.788
2020 Daneshmand P, Roşca SC, Dalhoff R, Yin K, DiPucchio RC, Ivanovich RA, Polat DE, Beauchemin AM, Schafer LL. Cyclic Ureate Tantalum Catalyst for Preferential Hydroaminoalkylation with Aliphatic Amines: Mechanistic Insights into Substrate Controlled Reactivity. Journal of the American Chemical Society. PMID 32786765 DOI: 10.1021/Jacs.0C04579  0.402
2020 Griffin SE, Schafer LL. Vanadium Pyridonate Catalysts: Isolation of Intermediates in the Reductive Coupling of Alcohols. Inorganic Chemistry. PMID 32223129 DOI: 10.1021/Acs.Inorgchem.0C00071  0.412
2020 Hao H, Schafer LL. Metal–Ligand Cooperativity in Titanium-CatalyzedAnti-Markovnikov Hydroamination Acs Catalysis. 10: 7100-7111. DOI: 10.1021/Acscatal.0C00491  0.328
2019 Bauer M, Cadge J, Davies D, Durand DJ, Eisenstein O, Ess D, Fey N, Gallarati S, George M, Hamilton A, Harvey J, Hintermair U, Hulme AN, Ishii Y, Jensen VR, ... ... Schafer L, et al. Computational and theoretical approaches for mechanistic understanding: general discussion. Faraday Discussions. PMID 31764927 DOI: 10.1039/C9Fd90073J  0.486
2019 Aoki Y, Bauer M, Braun T, Cadge J, Davies D, Durand DJ, Eisenstein O, Ess D, Fairlamb I, Fey N, Gallarati S, George M, Greaves M, Halse M, Hamilton A, ... ... Schafer L, et al. Physical methods for mechanistic understanding: general discussion. Faraday Discussions. PMID 31755887 DOI: 10.1039/C9Fd90070E  0.484
2019 Aoki Y, Bauer M, Braun T, Cadge JA, Clarke GE, Durand DJ, Eisenstein O, Gallarati S, Greaves M, Harvey J, Haynes A, Hintermair U, Hulme AN, Ishii Y, Jakoobi M, ... ... Schafer L, et al. Mechanistic insight into organic and industrial transformations: general discussion. Faraday Discussions. PMID 31754665 DOI: 10.1039/C9Fd90072A  0.494
2019 Koperniku A, Foth PJ, Sammis GM, Schafer LL. Zirconium Hydroaminoalkylation. An Alternative Disconnection for the Catalytic Synthesis of α-Arylated Primary Amines. Journal of the American Chemical Society. PMID 31718171 DOI: 10.1021/Jacs.9B10465  0.423
2019 Perry MR, Gilmour DJ, Schafer LL. Mono, bis, and tris(phosphoramidate) titanium complexes: synthesis, structure, and reactivity investigations. Dalton Transactions (Cambridge, England : 2003). PMID 31070221 DOI: 10.1039/C9Dt00911F  0.56
2019 Griffin SE, Pacheco J, Schafer LL. Reversible C–N Bond Formation in the Zirconium-Catalyzed Intermolecular Hydroamination of 2-Vinylpyridine Organometallics. 38: 1011-1016. DOI: 10.1021/Acs.Organomet.8B00904  0.405
2019 Braun C, Nieger M, Bräse S, Schafer LL. Planar‐Chiral [2.2]Paracyclophane‐Based Pyridonates as Ligands for Tantalum‐Catalyzed Hydroaminoalkylation Chemcatchem. 11: 5264-5268. DOI: 10.1002/Cctc.201900416  0.363
2019 DiPucchio RC, Rosca S, Athavan G, Schafer LL. Exploiting Natural Complexity: Synthetic Terpenoid‐Alkaloids by Regioselective and Diastereoselective Hydroaminoalkylation Catalysis Chemcatchem. 11: 3871-3876. DOI: 10.1002/Cctc.201900398  0.501
2018 Lui EKJ, Hergesell D, Schafer LL. N-Silylenamines as Reactive Intermediates: Hydroamination for the Modular Synthesis of Selectively Substituted Pyridines. Organic Letters. PMID 30351966 DOI: 10.1021/Acs.Orglett.8B02703  0.464
2018 Edwards PM, Schafer LL. Early transition metal-catalyzed C-H alkylation: hydroaminoalkylation for C-C bond formation in the synthesis of selectively substituted amines. Chemical Communications (Cambridge, England). PMID 30334025 DOI: 10.1039/C8Cc06445H  0.46
2018 Beattie DD, Grunwald AC, Perse T, Schafer LL, Love JA. Understanding Ni(II) Mediated C(sp3)-H Activation: Tertiary Ureas as Model Substrates. Journal of the American Chemical Society. PMID 30185028 DOI: 10.1021/Jacs.8B07708  0.615
2018 Lui EKJ, Brandt JW, Schafer LL. Regio- and Stereoselective Hydroamination of Alkynes Using an Ammonia Surrogate - Synthesis of N-Silylenamines as Reactive Synthons. Journal of the American Chemical Society. PMID 29528631 DOI: 10.1021/Jacs.7B13783  0.481
2018 DiPucchio RC, Rosca SC, Schafer L. Catalytic and Atom Economic Csp3 - Csp3 Bond Formation α-to Nitrogen. Alkyl Tantalum Ureates for Hydroaminoalkylation. Angewandte Chemie (International Ed. in English). PMID 29330909 DOI: 10.1002/Anie.201712668  0.501
2018 Schafer L, Hill M, Tonks I. Organometallic Complexes of Electrophilic Elements for Selective Synthesis Organometallics. 37: 4311-4312. DOI: 10.1021/Acs.Organomet.8B00849  0.423
2018 Gilmour DJ, Lauzon JMP, Clot E, Schafer LL. Ta-Catalyzed Hydroaminoalkylation of Alkenes: Insights into Ligand-Modified Reactivity Using DFT Organometallics. 37: 4387-4394. DOI: 10.1021/Acs.Organomet.8B00674  0.505
2018 Leeb NM, Drover MW, Love JA, Schafer LL, Slattery JM. Phosphoramidate-Assisted Alkyne Activation: Probing the Mechanism of Proton Shuttling in a N,O-Chelated Cp*Ir(III) Complex Organometallics. 37: 4630-4638. DOI: 10.1021/Acs.Organomet.8B00656  0.81
2018 Beattie DD, Lascoumettes G, Kennepohl P, Love JA, Schafer LL. Disproportionation Reactions of an Organometallic Ni(I) Amidate Complex: Scope and Mechanistic Investigations Organometallics. 37: 1392-1399. DOI: 10.1021/Acs.Organomet.8B00074  0.662
2017 Hao H, Thompson KA, Hudson ZM, Schafer L. Ti-Catalyzed Hydroamination for the Synthesis of Amine-Containing π-Conjugated Materials. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29282775 DOI: 10.1002/Chem.201704500  0.384
2017 Edwards PM, Schafer LL. In Situ Generation of a Regio- and Diastereoselective Hydroaminoalkylation Catalyst Using Commercially Available Starting Materials. Organic Letters. PMID 29043821 DOI: 10.1021/Acs.Orglett.7B02149  0.482
2017 Drover MW, Schafer LL, Love JA. Dehydrogenation of cyclic amines by a coordinatively unsaturated Cp*Ir(iii) phosphoramidate complex. Dalton Transactions (Cambridge, England : 2003). PMID 28644489 DOI: 10.1039/C7Dt01499F  0.819
2017 Clarkson JM, Schafer LL. Bis(tert-butylimido)bis(N,O-chelate)tungsten(VI) Complexes: Probing Amidate and Pyridonate Hemilability. Inorganic Chemistry. PMID 28443662 DOI: 10.1021/Acs.Inorgchem.6B02959  0.508
2017 Drover MW, Love JA, Schafer LL. 1,3-N,O-Complexes of late transition metals. Ligands with flexible bonding modes and reaction profiles. Chemical Society Reviews. PMID 28426030 DOI: 10.1039/C6Cs00715E  0.804
2017 Brandt JW, Chong E, Schafer LL. Ligand Effects and Kinetic Investigations of Sterically Accessible 2-Pyridonate Tantalum Complexes for Hydroaminoalkylation Acs Catalysis. 7: 6323-6330. DOI: 10.1021/Acscatal.7B01486  0.726
2017 Lauzon JM, Eisenberger P, Roşca S, Schafer LL. Amidate Complexes of Tantalum and Niobium for the Hydroaminoalkylation of Unactivated Alkenes Acs Catalysis. 7: 5921-5931. DOI: 10.1021/Acscatal.7B01293  0.698
2017 Braun C, Bräse S, Schafer LL. Planar-Chiral [2.2]Paracyclophane-Based Amides as Proligands for Titanium- and Zirconium-Catalyzed Hydroamination European Journal of Organic Chemistry. 2017: 1760-1764. DOI: 10.1002/Ejoc.201700101  0.504
2017 Drover MW, Christopherson CJ, Schafer LL, Love JA. C(sp3 )-H Bond Activation Induced by Monohydroborane Coordination at an Iridium(III)-Phosphoramidate Complex European Journal of Inorganic Chemistry. 2017: 2639-2642. DOI: 10.1002/Ejic.201700486  0.785
2017 Drover MW, Christopherson CJ, Schafer LL, Love JA. C(sp3 )-H Bond Activation Induced by Monohydroborane Coordination at an Iridium(III)-Phosphoramidate Complex European Journal of Inorganic Chemistry. 2017: 2638-2638. DOI: 10.1002/ejic.201700486  0.775
2017 Drover MW, Christopherson CJ, Schafer LL, Love JA. Front Cover: C(sp3 )-H Bond Activation Induced by Monohydroborane Coordination at an Iridium(III)-Phosphoramidate Complex (Eur. J. Inorg. Chem. 20/2017) European Journal of Inorganic Chemistry. 2017: 2637-2637. DOI: 10.1002/Ejic.201700485  0.785
2017 Drover MW, Christopherson CJ, Schafer LL, Love JA. C(sp3)-H Bond Activation Induced by Monohydroborane Coordination at an Iridium(III)-Phosphoramidate Complex: C(sp3)-H Bond Activation Induced by Monohydroborane Coordination at an Iridium(III)-Phosphoramidate Complex European Journal of Inorganic Chemistry. 2017: 2639-2642. DOI: 10.1002/Ejic.201601518  0.787
2016 Lau YY, Zhai H, Schafer LL. Catalytic Asymmetric Synthesis of Morpholines. Using Mechanistic Insights To Realize the Enantioselective Synthesis of Piperazines. The Journal of Organic Chemistry. PMID 27668321 DOI: 10.1021/Acs.Joc.6B01884  0.48
2016 Beattie DD, Bowes EG, Drover MW, Love JA, Schafer LL. Oxidation State Dependent Coordination Modes: Accessing an Amidate-Supported Nickel(I) δ-bis(C-H) Agostic Complex. Angewandte Chemie (International Ed. in English). PMID 27649631 DOI: 10.1002/Anie.201607243  0.779
2016 Drover MW, Love JA, Schafer LL. Toward Anti-Markovnikov 1-Alkyne O-Phosphoramidation: Exploiting Metal-Ligand Cooperativity in a 1,3-N,O Chelated Cp*Ir(III) Complex. Journal of the American Chemical Society. PMID 27327491 DOI: 10.1021/Jacs.6B05143  0.792
2016 Drover MW, Bowes EG, Schafer LL, Love JA, Weller AS. Phosphoramidate-Supported Cp*Ir(III) Aminoborane H2B=NR2 Complexes: Synthesis, Structure, and Solution Dynamics. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26946099 DOI: 10.1002/Chem.201600951  0.827
2016 Drover MW, Schafer LL, Love JA. Capturing HBCy2 : Using N,O-Chelated Complexes of Rhodium(I) and Iridium(I) for Chemoselective Hydroboration. Angewandte Chemie (International Ed. in English). PMID 26847809 DOI: 10.1002/Anie.201511448  0.795
2016 Drover MW, Bowes EG, Love JA, Schafer LL. Accessing δ-B–H Coordinated Complexes of Rh(I) and Ir(I) Using Mono- and Dihydroboranes: Cooperative Stabilization by a Phosphoramidate Coligand Organometallics. 36: 331-341. DOI: 10.1021/Acs.Organomet.6B00784  0.781
2016 Perry MR, Ebrahimi T, Morgan E, Edwards PM, Hatzikiriakos SG, Schafer LL. Catalytic Synthesis of Secondary Amine-Containing Polymers: Variable Hydrogen Bonding for Tunable Rheological Properties Macromolecules. 49: 4423-4430. DOI: 10.1021/Acs.Macromol.6B00306  0.358
2016 Lui EKJ, Schafer LL. Facile Synthesis and Isolation of Secondary Amines via a Sequential Titanium(IV)-Catalyzed Hydroamination and Palladium-Catalyzed Hydrogenation Advanced Synthesis and Catalysis. DOI: 10.1002/Adsc.201500861  0.449
2015 Drover MW, Schafer LL, Love JA. Isocyanate deinsertion from κ(1)-O amidates: facile access to perfluoroaryl rhodium(i) complexes. Dalton Transactions (Cambridge, England : 2003). PMID 26255960 DOI: 10.1039/C5Dt01981H  0.782
2015 Ryken SA, Schafer LL. N,O-Chelating Four-Membered Metallacyclic Titanium(IV) Complexes for Atom-Economic Catalytic Reactions. Accounts of Chemical Research. PMID 26247696 DOI: 10.1021/Acs.Accounts.5B00224  0.586
2015 Schafer LL, Mountford P, Piers WE. Earth abundant element compounds in homogeneous catalysis. Dalton Transactions (Cambridge, England : 2003). PMID 26090922 DOI: 10.1039/C5Dt90105G  0.474
2015 Gilmour DJ, Webster RL, Perry MR, Schafer LL. Titanium pyridonates for the homo- and copolymerization of rac-lactide and ε-caprolactone. Dalton Transactions (Cambridge, England : 2003). 44: 12411-9. PMID 26018788 DOI: 10.1039/C5Dt01162K  0.641
2015 Horrillo-Martinez P, Leitch DC, Ryken SA, Thomson RK, Beard JD, Patrick BO, Schafer LL, Giesbrecht GR. Titanium amidate complexes as active catalysts for the synthesis of high molecular weight polyethylene Canadian Journal of Chemistry. 93: 775-783. DOI: 10.1139/Cjc-2015-0081  0.817
2015 Drover MW, Schafer LL, Love JA. Amidate-ligated complexes of rhodium(I): A showcase of coordination flexibility Organometallics. 34: 1783-1786. DOI: 10.1021/Om501209C  0.773
2015 Chong E, Xue W, Storr T, Kennepohl P, Schafer LL. Pyridonate-Supported Titanium(III). Benzylamine as an Easy-To-Use Reductant Organometallics. 34: 4941-4945. DOI: 10.1021/Acs.Organomet.5B00469  0.652
2015 Drover MW, Johnson HC, Schafer LL, Love JA, Weller AS. Reactivity of an Unsaturated Iridium(III) Phosphoramidate Complex, [Cp∗Ir{κ2- N,O }][BArF4] Organometallics. 34: 3849-3856. DOI: 10.1021/Acs.Organomet.5B00397  0.814
2015 Lauzon JMP, Schafer LL. Tethered bis(amidate) and bis(ureate) supported zirconium precatalysts for the intramolecular hydroamination of aminoalkenes Zeitschrift Fur Anorganische Und Allgemeine Chemie. 641: 128-135. DOI: 10.1002/Zaac.201400201  0.514
2014 Chong E, Brandt JW, Schafer LL. 2-Pyridonate tantalum complexes for the intermolecular hydroaminoalkylation of sterically demanding alkenes. Journal of the American Chemical Society. 136: 10898-901. PMID 25041474 DOI: 10.1021/Ja506187M  0.687
2014 Haehnel M, Priebe JB, Yim JC, Spannenberg A, Brückner A, Schafer LL, Rosenthal U. Four-membered heterometallacyclic d⁰ and d¹ complexes of Group 4 metallocenes with amidato ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 7752-8. PMID 24863638 DOI: 10.1002/Chem.201402571  0.628
2014 Yim JC, Bexrud JA, Ayinla RO, Leitch DC, Schafer LL. Bis(amidate)bis(amido) titanium complex: a regioselective intermolecular alkyne hydroamination catalyst. The Journal of Organic Chemistry. 79: 2015-28. PMID 24506303 DOI: 10.1021/Jo402668Q  0.812
2014 Chong E, Garcia P, Schafer LL. Hydroaminoalkylation: Early-transition-metal-catalyzed α-alkylation of amines Synthesis (Germany). 46: 2884-2896. DOI: 10.1055/S-0034-1379216  0.711
2014 Yonson N, Yim JCH, Schafer LL. Alkene hydroamination with a chiral zirconium catalyst. Connecting ligand design, precatalyst structure and reactivity trends Inorganica Chimica Acta. 422: 14-20. DOI: 10.1016/J.Ica.2014.07.073  0.666
2014 Yim JCH, Schafer LL. Efficient anti-Markovnikov-selective catalysts for intermolecular alkyne hydroamination: Recent advances and synthetic applications European Journal of Organic Chemistry. 2014: 6825-6840. DOI: 10.1002/Ejoc.201402300  0.412
2013 Chong E, Schafer LL. 2-Pyridonate titanium complexes for chemoselectivity. Accessing intramolecular hydroaminoalkylation over hydroamination. Organic Letters. 15: 6002-5. PMID 24224611 DOI: 10.1021/Ol402890M  0.697
2013 Payne PR, Thomson RK, Medeiros DM, Wan G, Schafer LL. Synthesis, structure, and reactivity of tris(amidate) mono(amido) and tetrakis(amidate) complexes of group 4 transition metals. Dalton Transactions (Cambridge, England : 2003). 42: 15670-7. PMID 24045287 DOI: 10.1039/C3Dt51868J  0.808
2013 Haehnel M, Yim JC, Schafer LL, Rosenthal U. Facile access to tuneable Schwartz's reagents: oxidative addition products from the reaction of amide N-H bonds with reduced zirconocene complexes. Angewandte Chemie (International Ed. in English). 52: 11415-9. PMID 24038845 DOI: 10.1002/Anie.201305246  0.642
2013 Garcia P, Lau YY, Perry MR, Schafer LL. Phosphoramidate tantalum complexes for room-temperature C-H functionalization: hydroaminoalkylation catalysis. Angewandte Chemie (International Ed. in English). 52: 9144-8. PMID 23881625 DOI: 10.1002/Anie.201304153  0.602
2013 Zhang Z, Hamel JD, Schafer LL. TaMe3Cl2-catalyzed intermolecular hydroaminoalkylation: a simple complex for enhanced reactivity and expanded substrate scope. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 8751-4. PMID 23686833 DOI: 10.1002/Chem.201300992  0.476
2013 Borzenko A, Pajouhesh H, Morrison JL, Tringham E, Snutch TP, Schafer LL. Modular, efficient synthesis of asymmetrically substituted piperazine scaffolds as potent calcium channel blockers. Bioorganic & Medicinal Chemistry Letters. 23: 3257-61. PMID 23639535 DOI: 10.1016/J.Bmcl.2013.03.114  0.702
2013 Payne PR, Garcia P, Eisenberger P, Yim JC, Schafer LL. Tantalum catalyzed hydroaminoalkylation for the synthesis of α- and β-substituted N-heterocycles. Organic Letters. 15: 2182-5. PMID 23600625 DOI: 10.1021/Ol400729V  0.82
2013 Webster RL, Noroozi N, Hatzikiriakos SG, Thomson JA, Schafer LL. Titanium pyridonates and amidates: novel catalysts for the synthesis of random copolymers. Chemical Communications (Cambridge, England). 49: 57-9. PMID 23165249 DOI: 10.1039/C2Cc37201K  0.622
2013 Chong E, Qayyum S, Schafer LL, Kempe R. 2-Aminopyridinate titanium complexes for the catalytic hydroamination of primary aminoalkenes Organometallics. 32: 1858-1865. DOI: 10.1021/Om3012695  0.755
2013 Duis JM, Schafer LL, Nussbaum S, Stewart JJ. A process for developing introductory science laboratory learning goals to enhance student learning and instructional alignment Journal of Chemical Education. 90: 1144-1150. DOI: 10.1021/Ed4000102  0.718
2013 Garcia P, Payne PR, Chong E, Webster RL, Barron BJ, Behrle AC, Schmidt JAR, Schafer LL. Easily assembled, modular N,O-chelating ligands for Ta(V) complexation: A comparative study of ligand effects in hydroaminoalkylation with N-methylaniline and 4-methoxy-N-methylaniline Tetrahedron. 69: 5737-5743. DOI: 10.1016/J.Tet.2013.04.070  0.813
2013 Payne PR, Garcia P, Eisenberger P, Yim JC, Schafer LL. ChemInform Abstract: Tantalum Catalyzed Hydroaminoalkylation for the Synthesis of α- and β-Substituted N-Heterocycles. Cheminform. 44: no-no. DOI: 10.1002/chin.201335157  0.682
2012 Zhai H, Borzenko A, Lau YY, Ahn SH, Schafer LL. Catalytic asymmetric synthesis of substituted morpholines and piperazines. Angewandte Chemie (International Ed. in English). 51: 12219-23. PMID 23109242 DOI: 10.1002/Anie.201206826  0.715
2012 Platel RH, Schafer LL. Zirconium catalyzed alkyne dimerization for selective Z-enyne synthesis. Chemical Communications (Cambridge, England). 48: 10609-11. PMID 22996142 DOI: 10.1039/C2Cc35913H  0.768
2012 Lauzon JM, Schafer LL. Tantallaaziridines: from synthesis to catalytic applications. Dalton Transactions (Cambridge, England : 2003). 41: 11539-50. PMID 22728652 DOI: 10.1039/C2Dt30781B  0.503
2012 Thomson JA, Schafer LL. Yttrium (amidate) complexes for catalytic C-N bond formation. Rapid, room temperature amidation of aldehydes. Dalton Transactions (Cambridge, England : 2003). 41: 7897-904. PMID 22555513 DOI: 10.1039/C2Dt30214D  0.452
2012 Horrillo-Martinez P, Patrick BO, Schafer LL, Fryzuk MD. Oxygen extrusion from amidate ligands to generate terminal Ta=O units under reducing conditions. How to successfully use amidate ligands in dinitrogen coordination chemistry. Dalton Transactions (Cambridge, England : 2003). 41: 1609-16. PMID 22146773 DOI: 10.1039/C1Dt11595B  0.66
2012 Hayes CE, Platel RH, Schafer LL, Leznoff DB. Diamido-ether actinide complexes as catalysts for the intramolecular hydroamination of aminoalkenes Organometallics. 31: 6732-6740. DOI: 10.1021/Om300410H  0.789
2011 Leitch DC, Platel RH, Schafer LL. Mechanistic elucidation of intramolecular aminoalkene hydroamination catalyzed by a tethered bis(ureate) complex: evidence for proton-assisted C-N bond formation at zirconium. Journal of the American Chemical Society. 133: 15453-63. PMID 21851117 DOI: 10.1021/Ja202448B  0.835
2011 Ayinla RO, Schafer LL. Intermolecular hydroamination of oxygen-substituted allenes. New routes for the synthesis of N,O-chelated zirconium and titanium amido complexes. Dalton Transactions (Cambridge, England : 2003). 40: 7769-76. PMID 21725526 DOI: 10.1039/C1Dt10448A  0.555
2011 Payne PR, Bexrud JA, Leitch DC, Schafer LL. Asymmetric hydroamination catalyzed by in situ generated chiral amidate and ureate complexes of zirconium - Probing the role of the tether in ligand design Canadian Journal of Chemistry. 89: 1222-1229. DOI: 10.1139/V11-091  0.825
2011 Antunes MA, Munhá RF, Alves LG, Schafer LL, Martins AM. Intramolecular hydroamination catalysis using trans-N,N′- dibenzylcyclam zirconium complexes Journal of Organometallic Chemistry. 696: 2-6. DOI: 10.1016/J.Jorganchem.2010.08.039  0.304
2011 Ayinla RO, Gibson T, Schafer LL. Amidate ligand design effects in zirconium-catalyzed enantioselective hydroamination of aminoalkenes Journal of Organometallic Chemistry. 696: 50-60. DOI: 10.1016/J.Jorganchem.2010.07.023  0.564
2011 Lauterwasser F, Hayes PG, Piers WE, Schafer LL, Bräse S. Highly active and diastereoselective N,O- and N,N-yttrium complexes for intramolecular hydroamination Advanced Synthesis and Catalysis. 353: 1384-1390. DOI: 10.1002/Adsc.201000892  0.757
2010 Leitch DC, Turner CS, Schafer LL. Isolation of catalytic intermediates in hydroamination reactions: insertion of internal alkynes into a zirconium-amido bond. Angewandte Chemie (International Ed. in English). 49: 6382-6. PMID 20665612 DOI: 10.1002/Anie.201001927  0.717
2010 Bexrud JA, Schafer LL. Zirconium bis(pyridonate): a modified amidate complex for enhanced substrate scope in aminoalkene cyclohydroamination. Dalton Transactions (Cambridge, England : 2003). 361-3. PMID 20023969 DOI: 10.1039/B913393C  0.847
2010 Eisenberger P, Schafer LL. Catalytic synthesis of amines and N-containing heterocycles: Amidate complexes for selective C-N and C-C bond-forming reactions Pure and Applied Chemistry. 82: 1503-1515. DOI: 10.1351/Pac-Con-09-11-27  0.692
2010 Thomson RK, Schafer LL. Synthesis, structure, and insertion reactivity of zirconium and hafnium amidate benzyl complexes Organometallics. 29: 3546-3555. DOI: 10.1021/Om100424J  0.759
2010 Leitch DC, Schafer LL. Zirconium alkyl complexes supported by ureate ligands: Synthesis, characterization, and precursors to metal-element multiple bonds Organometallics. 29: 5162-5172. DOI: 10.1021/Om100381D  0.782
2010 Wood MC, Leitch DC, Yeung CS, Kozak JA, Schafer LL. Corrigendum: Chiral Neutral Zirconium Amidate Complexes for the Asymmetric Hydroamination of Alkenes Angewandte Chemie. 49: 6475-6475. DOI: 10.1002/Anie.201090117  0.832
2009 Leitch DC, Payne PR, Dunbar CR, Schafer LL. Broadening the scope of group 4 hydroamination catalysis using a tethered ureate ligand. Journal of the American Chemical Society. 131: 18246-7. PMID 19994887 DOI: 10.1021/Ja906955B  0.805
2009 Eisenberger P, Ayinla RO, Lauzon JM, Schafer LL. Tantalum-amidate complexes for the hydroaminoalkylation of secondary amines: enhanced substrate scope and enantioselective chiral amine synthesis. Angewandte Chemie (International Ed. in English). 48: 8361-5. PMID 19787670 DOI: 10.1002/Anie.200903656  0.703
2009 Bexrud JA, Eisenberger P, Leitch DC, Payne PR, Schafer LL. Selective C-H activation alpha to primary amines. Bridging metallaaziridines for catalytic, intramolecular alpha-alkylation. Journal of the American Chemical Society. 131: 2116-8. PMID 19173650 DOI: 10.1021/Ja808862W  0.794
2009 Lee AV, Sajitz M, Schafer LL. The direct synthesis of unsymmetrical vicinal diamines from terminal alkynes: A tandem sequential approach for the synthesis of imidazolidinones Synthesis. 97-104. DOI: 10.1055/S-0028-1083279  0.385
2009 Stanlake LJE, Schafer LL. Bis- and mono(amidate) complexes of yttrium: Synthesis, characterization, and use as precatalysts for the hydroamination of aminoalkenes Organometallics. 28: 3990-3998. DOI: 10.1021/Om801190T  0.542
2009 Leitch DC, Beard JD, Thomson RK, Wright VA, Patrick BO, Schafer LL. N,O-chelates of group 4 Metals: Contrasting the use of amidates and ureates in the synthesis of metal dichlorides European Journal of Inorganic Chemistry. 2009: 2691-2701. DOI: 10.1002/Ejic.200900254  0.844
2009 Bexrud JA, Eisenberger P, Leitch DC, Payne PR, Schafer LL. ChemInform Abstract: Selective C-H Activation α to Primary Amines. Bridging Metallaaziridines for Catalytic, Intramolecular α-Alkylation. Cheminform. 40. DOI: 10.1002/chin.200926068  0.782
2008 Stanlake LJ, Beard JD, Schafer LL. Rare-earth amidate complexes. Easily accessed initiators for epsilon-caprolactone ring-opening polymerization. Inorganic Chemistry. 47: 8062-8. PMID 18710213 DOI: 10.1021/Ic8010635  0.48
2007 Zhang Z, Leitch DC, Lu M, Patrick BO, Schafer LL. An easy-to-use, regioselective, and robust bis(amidate) titanium hydroamination precatalyst: mechanistic and synthetic investigations toward the preparation of tetrahydroisoquinolines and benzoquinolizine alkaloids. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 2012-22. PMID 17131447 DOI: 10.1002/Chem.200600735  0.781
2007 Wood MC, Leitch DC, Yeung CS, Kozak JA, Schafer LL. Chiral neutral zirconium amidate complexes for the asymmetric hydroamination of alkenes. Angewandte Chemie (International Ed. in English). 46: 354-8. PMID 17029322 DOI: 10.1002/Anie.200603017  0.832
2007 Schafer L, Wood M, Leitch D, Yeung C, Kozak J. Zirconium-Catalyzed Asymmetric Cyclohydroamination of Alkenes Synfacts. 2007: 0369-0369. DOI: 10.1055/s-2007-968371  0.341
2007 Bexrud JA, Li C, Schäfer LL. Enhanced reactivity results in reduced catalytic performance: 1 Unexpected ligand reactivity of a bis(N-2,6-diisopropylphenylperflourophenyl-amidate) titanium-bis(diethylamido) Hydroamination precatalyst Organometallics. 26: 6366-6372. DOI: 10.1021/Om700653T  0.85
2007 Lee AV, Schafer LL. Modular N,O-chelating ligands: Group-4 amidate complexes for catalytic hydroamination European Journal of Inorganic Chemistry. 2243-2255. DOI: 10.1002/Ejic.200700036  0.537
2006 Lee AV, Schafer LL. A sequential C-N, C-C bond-forming reaction: Direct synthesis of α-amino acids from terminal alkynes Synlett. 2973-2976. DOI: 10.1055/S-2006-944211  0.373
2006 Lee AV, Schafer LL. Group 4 bis(pyrimidinoxide) complexes. Investigations of electronic effects in catalytic hydroamination Organometallics. 25: 5249-5254. DOI: 10.1021/Om060587B  0.532
2006 Thomson RK, Bexrud JA, Schafer LL. A pentagonal pyramidal zirconium imido complex for catalytic hydroamination of unactivated alkenes Organometallics. 25: 4069-4071. DOI: 10.1021/Om060545N  0.839
2006 Ayinla RO, Schafer LL. Bis(amidate) titanium precatalyst for the intermolecular hydroamination of allenes Inorganica Chimica Acta. 359: 3097-3102. DOI: 10.1016/J.Ica.2005.12.041  0.424
2005 Thomson RK, Zahariev FE, Zhang Z, Patrick BO, Wang YA, Schafer LL. Structure, bonding, and reactivity of Ti and Zr amidate complexes: DFT and X-ray crystallographic studies. Inorganic Chemistry. 44: 8680-9. PMID 16296821 DOI: 10.1021/Ic0502980  0.754
2005 Bexrud JA, Beard JD, Leitch DC, Schafer LL. Intramolecular hydroamination of unactived olefins with Ti(NMe2)4 as a precatalyst. Organic Letters. 7: 1959-62. PMID 15876029 DOI: 10.1021/Ol0503992  0.81
2005 Thomson RK, Patrick BO, Schafer LL. Synthesis, characterization, and reactivity of the first hafnium alkyl complex stabilized by amidate ligands Canadian Journal of Chemistry. 83: 1037-1042. DOI: 10.1139/V05-030  0.692
2004 Lauterwasser F, Hayes PG, Bräse S, Piers WE, Schafer LL. Scandium-catalyzed intramolecular hydroamination. Development of a highly active cationic catalyst Organometallics. 23: 2234-2237. DOI: 10.1021/Om0498551  0.766
2003 Zhang Z, Schafer LL. Anti-Markovnikov intermolecular hydroamination: a bis(amidate) titanium precatalyst for the preparation of reactive aldimines. Organic Letters. 5: 4733-6. PMID 14627427 DOI: 10.1021/Ol0359214  0.573
2003 Li C, Thomson RK, Gillon B, Patrick BO, Schafer LL. Amidate complexes of titanium and zirconium: a new class of tunable precatalysts for the hydroamination of alkynes. Chemical Communications (Cambridge, England). 2462-3. PMID 14587732 DOI: 10.1039/B304176J  0.758
2003 Li C, Thomson RK, Gillon B, Patrick BO, Schafer LL. Amidate complexes of titanium and zirconium: A new class of tunable precatalysts for the hydroamination of alkynes Chemical Communications. 9: 2462-2463.  0.691
2002 Schafer LL, Nitschke JR, Mao SS, Liu FQ, Harder G, Haufe M, Tilley TD. Zirconocene-mediated, high-yielding macrocyclizations of silyl-terminated diynes. Chemistry (Weinheim An Der Bergstrasse, Germany). 8: 74-83. PMID 11826866 DOI: 10.1002/1521-3765(20020104)8:1<74::Aid-Chem74>3.0.Co;2-P  0.671
2001 Payne CK, Snee PT, Yang H, Kotz KT, Schafer LL, Tilley TD, Harris CB. Intramolecular rearrangements on ultrafast timescales: femtosecond infrared studies of ring slip in (eta(1)-C(5)Cl(5))Mn(CO)(5). Journal of the American Chemical Society. 123: 7425-6. PMID 11472175 DOI: 10.1021/ja003905l  0.433
2001 Schafer LL, Tilley TD. Efficient diastereoselective syntheses of chiral macrocycles via zirconocene coupling. Synthetic control of size and geometry. Journal of the American Chemical Society. 123: 2683-4. PMID 11456946 DOI: 10.1021/Ja015509O  0.503
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