☰

cached image

Patrick L. Holland - Publications

Affiliations: 
Chemistry Yale University, New Haven, CT 
Area:
transition-metal complexes
Website:
http://www.chem.yale.edu/faculty/holland.html
Tree Info Similar researchers PubMed Report error

198 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Nagelski AL, Ozerov M, Fataftah MS, Krzystek J, Greer SM, Holland PL, Telser J. Electronic Structure of Three-Coordinate Fe and Co β-Diketiminate Complexes. Inorganic Chemistry. PMID 38408452 DOI: 10.1021/acs.inorgchem.3c03388  0.382
2024 Wilson DWN, Fataftah MS, Mathe Z, Mercado BQ, DeBeer S, Holland PL. Three-Coordinate Nickel and Metal-Metal Interactions in a Heterometallic Iron-Sulfur Cluster. Journal of the American Chemical Society. PMID 38308743 DOI: 10.1021/jacs.3c12157  0.316
2024 Wilson CV, Holland PL. Mechanism of Alkene Hydrofunctionalization by Oxidative Cobalt(salen) Catalyzed Hydrogen Atom Transfer. Journal of the American Chemical Society. 146: 2685-2700. PMID 38227206 DOI: 10.1021/jacs.3c12329  0.317
2023 Hooper RX, Mercado BQ, Holland PL. Desulfurization and N Binding at an Iron Complex Derived from the C-S Activation of Benzothiophene. Organometallics. 42: 2019-2027. PMID 38282963 DOI: 10.1021/acs.organomet.3c00220  0.423
2023 Wandzilak A, Grubel K, Skubi KL, McWilliams SF, Bessas D, Rana A, Hugenbruch S, Dey A, Holland PL, DeBeer S. Mössbauer and Nuclear Resonance Vibrational Spectroscopy Studies of Iron Species Involved in N-N Bond Cleavage. Inorganic Chemistry. PMID 37902987 DOI: 10.1021/acs.inorgchem.3c02594  0.824
2023 Genoux A, Pauly M, Rooney CL, Choi C, Shang B, McGuigan S, Fataftah MS, Kayser Y, Suhr SCB, DeBeer S, Wang H, Maggard PA, Holland PL. Well-Defined Iron Sites in Crystalline Carbon Nitride. Journal of the American Chemical Society. 145: 20739-20744. PMID 37703184 DOI: 10.1021/jacs.3c05417  0.302
2023 Fataftah MS, Mercado BQ, Holland PL. Valence delocalization in carbon-bridged mixed-valence iron complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). e202301962. PMID 37574453 DOI: 10.1002/chem.202301962  0.403
2023 Bhutto SM, Mercado BQ, Holland PL. Dinitrogen Binding and Functionalization from a Low-Coordinate Alkynyliron Complex. Inorganic Chemistry. 62: 9335-9342. PMID 37294074 DOI: 10.1021/acs.inorgchem.3c00167  0.475
2023 Hegg AS, Mercado BQ, Miller AJM, Holland PL. Catalytic reduction of dinitrogen to ammonia using molybdenum porphyrin complexes. Faraday Discussions. PMID 37077158 DOI: 10.1039/d2fd00166g  0.304
2023 McWilliams SF, Mercado BQ, MacLeod KC, Fataftah MS, Tarrago M, Wang X, Bill E, Ye S, Holland PL. Dynamic effects on ligand field from rapid hydride motion in an iron(ii) dimer with an = 3 ground state. Chemical Science. 14: 2303-2312. PMID 36873832 DOI: 10.1039/d2sc06412j  0.358
2023 Hasanayn F, Holland PL, Goldman AS, Miller AJM. Lewis Structures and the Bonding Classification of End-on Bridging Dinitrogen Transition Metal Complexes. Journal of the American Chemical Society. PMID 36796367 DOI: 10.1021/jacs.2c12243  0.357
2023 Bhutto SM, Hooper RX, Mercado BQ, Holland PL. Mechanism of Nitrogen-Carbon Bond Formation from Iron(IV) Disilylhydrazido Intermediates during N Reduction. Journal of the American Chemical Society. PMID 36794981 DOI: 10.1021/jacs.2c12382  0.35
2022 Wilson CV, Kim D, Sharma A, Hooper RX, Poli R, Hoffman BM, Holland PL. Cobalt-Carbon Bonding in a Salen-Supported Cobalt(IV) Alkyl Complex Postulated in Oxidative MHAT Catalysis. Journal of the American Chemical Society. 144: 10361-10367. PMID 35657101 DOI: 10.1021/jacs.2c02128  0.49
2022 Connor GP, Delony D, Weber JE, Mercado BQ, Curley JB, Schneider S, Mayer JM, Holland PL. Facile conversion of ammonia to a nitride in a rhenium system that cleaves dinitrogen. Chemical Science. 13: 4010-4018. PMID 35440977 DOI: 10.1039/d1sc04503b  0.38
2022 Skubi KL, Hooper RX, Mercado BQ, Bollmeyer MM, MacMillan SN, Lancaster KM, Holland PL. Iron Complexes of a Proton-Responsive SCS Pincer Ligand with a Sensitive Electronic Structure. Inorganic Chemistry. PMID 34986307 DOI: 10.1021/acs.inorgchem.1c03499  0.858
2021 Kim D, Wilson DWN, Fataftah MS, Mercado BQ, Holland PL. Spin states, bonding and magnetism in mixed valence iron(0)-iron(II) complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 34919297 DOI: 10.1002/chem.202104431  0.56
2021 Yamout LS, Ataya M, Hasanayn F, Holland PL, Miller AJM, Goldman AS. Understanding Terminal versus Bridging End-on N Coordination in Transition Metal Complexes. Journal of the American Chemical Society. PMID 34180663 DOI: 10.1021/jacs.1c01146  0.351
2021 Weber JE, Hasanayn F, Fataftah M, Mercado BQ, Crabtree RH, Holland PL. Electronic and Spin-State Effects on Dinitrogen Splitting to Nitrides in a Rhenium Pincer System. Inorganic Chemistry. PMID 33847125 DOI: 10.1021/acs.inorgchem.0c03778  0.514
2021 Kim D, Pillon G, DiPrimio DJ, Holland PL. Highly -Selective Double Bond Transposition in Simple Alkenes and Allylarenes through a Spin-Accelerated Allyl Mechanism. Journal of the American Chemical Society. PMID 33596058 DOI: 10.1021/jacs.1c00856  0.431
2021 Speelman AL, Skubi KL, Mercado BQ, Holland PL. Synthesis and Reactivity of Iron Complexes with a Biomimetic SCS Pincer Ligand. Inorganic Chemistry. PMID 33443404 DOI: 10.1021/acs.inorgchem.0c03427  0.856
2020 Nagelski AL, Fataftah MS, Bollmeyer MM, McWilliams SF, MacMillan SN, Mercado BQ, Lancaster KM, Holland PL. The influences of carbon donor ligands on biomimetic multi-iron complexes for N reduction. Chemical Science. 11: 12710-12720. PMID 34094466 DOI: 10.1039/d0sc03447a  0.4
2020 Shevick SL, Wilson CV, Kotesova S, Kim D, Holland PL, Shenvi RA. Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals. Chemical Science. 11: 12401-12422. PMID 33520153 DOI: 10.1039/d0sc04112b  0.442
2020 McWilliams SF, Broere DLJ, Halliday CJV, Bhutto SM, Mercado BQ, Holland PL. Coupling dinitrogen and hydrocarbons through aryl migration. Nature. 584: 221-226. PMID 32788733 DOI: 10.1038/S41586-020-2565-5  0.458
2020 Nagelski AL, Fataftah MS, Bollmeyer MM, McWilliams SF, MacMillan SN, Mercado BQ, Lancaster KM, Holland PL. The influences of carbon donor ligands on biomimetic multi-iron complexes for N2 reduction Chemical Science. DOI: 10.1039/D0Sc03447A  0.499
2020 Kim D, Chen C, Mercado BQ, Weix DJ, Holland PL. Mechanistic Study of Alkene Hydrosilylation Catalyzedby a β‑Dialdiminate Cobalt(I) Complex Organometallics. 39: 2415-2424. DOI: 10.1021/Acs.Organomet.0C00241  0.472
2019 MacLeod KC, DiMucci IM, Zovinka EP, McWilliams SF, Mercado BQ, Lancaster KM, Holland PL. Masked Radicals: Iron Complexes of Trityl, Benzophenone, and Phenylacetylene. Organometallics. 38: 4224-4232. PMID 34103782 DOI: 10.1021/acs.organomet.9b00534  0.481
2019 Chen C, Dugan TR, Brennessel WW, Weix DJ, Holland PL. Correction to "-Selective Alkene Isomerization by High-Spin Cobalt(II) Complexes". Journal of the American Chemical Society. PMID 31794206 DOI: 10.1021/Jacs.9B12184  0.794
2019 Bruch QJ, Connor GP, Chen CH, Holland PL, Mayer JM, Hasanayn F, Miller AJM. Dinitrogen Reduction to Ammonium at Rhenium Utilizing Light and Proton-Coupled Electron Transfer. Journal of the American Chemical Society. PMID 31751134 DOI: 10.1021/Jacs.9B10031  0.408
2019 DeRosha DE, Chilkuri VG, Van Stappen C, Bill E, Mercado BQ, DeBeer S, Neese F, Holland PL. Planar three-coordinate iron sulfide in a synthetic [4Fe-3S] cluster with biomimetic reactivity. Nature Chemistry. PMID 31611632 DOI: 10.1038/S41557-019-0341-7  0.428
2019 Speelman AL, Čorić I, Van Stappen C, DeBeer S, Mercado BQ, Holland PL. Nitrogenase-Relevant Reactivity of a Synthetic Iron-Sulfur-Carbon Site. Journal of the American Chemical Society. PMID 31403298 DOI: 10.1021/Jacs.9B05353  0.816
2019 Connor GP, Mercado BQ, Lant HMC, Mayer JM, Holland PL. Chemical Oxidation of a Coordinated PNP-Pincer Ligand Forms Unexpected Re-Nitroxide Complexes with Reversal of Nitride Reactivity. Inorganic Chemistry. PMID 31389243 DOI: 10.1021/Acs.Inorgchem.9B01075  0.497
2019 DeRosha DE, Arnet NA, Mercado BQ, Holland PL. A [2Fe-1S] Complex That Affords Access to Bimetallic and Higher-Nuclearity Iron-Sulfur Clusters. Inorganic Chemistry. PMID 31247861 DOI: 10.1021/Acs.Inorgchem.9B01212  0.429
2019 Bhutto SM, Holland PL. Dinitrogen Activation and Functionalization using β-Diketiminate Iron Complexes. European Journal of Inorganic Chemistry. 2019: 1861-1869. PMID 31213945 DOI: 10.1002/Ejic.201900133  0.459
2019 Kim D, Rahaman SMW, Mercado BQ, Poli R, Holland PL. Roles of Iron Complexes in Catalytic Radical Alkene Cross-Coupling: A Computational and Mechanistic Study. Journal of the American Chemical Society. PMID 31025567 DOI: 10.1021/Jacs.9B02117  0.611
2019 Roy L, Al-Afyouni MH, DeRosha DE, Mondal B, DiMucci IM, Lancaster KM, Shearer J, Bill E, Brennessel WW, Neese F, Ye S, Holland PL. Reduction of CO by a masked two-coordinate cobalt(i) complex and characterization of a proposed oxodicobalt(ii) intermediate. Chemical Science. 10: 918-929. PMID 30774886 DOI: 10.1039/C8Sc02599A  0.444
2019 Mercado B, Holland P, Coric I. Reduction and refinement choices Acta Crystallographica Section A. 75. DOI: 10.1107/S0108767319096673  0.708
2019 MacLeod KC, DiMucci IM, Zovinka EP, McWilliams SF, Mercado BQ, Lancaster KM, Holland PL. Masked Radicals: Iron Complexes of Trityl, Benzophenone, and Phenylacetylene Organometallics. 38: 4224-4232. DOI: 10.1021/Acs.Organomet.9B00534  0.567
2019 Connor GP, Kim D, Nagelski AL, Schmidt EO, Hass-Mitchell T, Atwater JT, Tridenti SA, Sohn S, Holland PL. Implementation of an Accessible Gas Chromatography Laboratory Experiment for High School Students Journal of Chemical Education. 96: 1707-1713. DOI: 10.1021/Acs.Jchemed.8B00789  0.365
2018 McWilliams SF, Bunting PC, Kathiresan V, Mercado BQ, Hoffman BM, Long JR, Holland PL. Isolation and characterization of a high-spin mixed-valent iron dinitrogen complex. Chemical Communications (Cambridge, England). PMID 30403226 DOI: 10.1039/C8Cc07294A  0.387
2018 McWilliams SF, Bill E, Lukat-Rodgers G, Rodgers KR, Mercado BQ, Holland PL. Effects of N Binding Mode on Iron-Based Functionalization of Dinitrogen to Form an Iron(III) Hydrazido Complex. Journal of the American Chemical Society. PMID 29957940 DOI: 10.1021/Jacs.8B04828  0.522
2018 Skubi KL, Holland PL. So Close, yet Sulfur Away: Opening the Nitrogenase Cofactor Structure Creates a Binding Site. Biochemistry. PMID 29927241 DOI: 10.1021/Acs.Biochem.8B00529  0.764
2018 Pelmenschikov V, Gee LB, Wang H, MacLeod KC, McWilliams SF, Skubi KL, Cramer SP, Holland PL. High-Frequency Fe-H Vibrations in a Bridging Hydride Complex Characterized by NRVS and DFT. Angewandte Chemie (International Ed. in English). PMID 29847703 DOI: 10.1002/Anie.201804601  0.822
2018 Bonyhady SJ, DeRosha DE, Vela J, Vinyard DJ, Cowley RE, Mercado BQ, Brennessel WW, Holland PL. Iron and Cobalt Diazoalkane Complexes Supported by β-Diketiminate Ligands: A Synthetic, Spectroscopic, and Computational Investigation. Inorganic Chemistry. PMID 29741884 DOI: 10.1021/Acs.Inorgchem.8B00468  0.837
2018 DeRosha DE, Holland PL. Incorporating light atoms into synthetic analogues of FeMoco. Proceedings of the National Academy of Sciences of the United States of America. PMID 29712851 DOI: 10.1073/Pnas.1805700115  0.34
2018 Broere D, Mercado B, Lukens J, Vilbert A, Banerjee G, Lant H, Lee SH, Bill E, Lancaster K, Sproules S, Holland P. Reversible Ligand-Centered Reduction in Low- Coordinate Iron Formazanate Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29663542 DOI: 10.1002/Chem.201801298  0.559
2018 Broere D, Mercado BQ, Holland PL. Selective Conversion of CO2 to Isocyanate by Low-Coordinate Fe. Angewandte Chemie (International Ed. in English). PMID 29633494 DOI: 10.1002/Anie.201802357  0.399
2018 Broere DLJ, Mercado BQ, Bill E, Lancaster KM, Sproules S, Holland PL. Alkali Cation Effects on Redox-Active Formazanate Ligands in Iron Chemistry. Inorganic Chemistry. PMID 29629752 DOI: 10.1021/Acs.Inorgchem.8B00226  0.513
2018 Broere DLJ, Holland PL. Boron compounds tackle dinitrogen. Science (New York, N.Y.). 359: 871. PMID 29472470 DOI: 10.1126/Science.Aar7395  0.403
2017 Rozen E, Erlich Y, Reesbeck ME, Holland PL, Sukenik CN. Functionalized Self-Assembled Monolayers Bearing Diiminate Complexes Immobilized through Covalently Anchored Ligands. Langmuir : the Acs Journal of Surfaces and Colloids. PMID 29048903 DOI: 10.1021/Acs.Langmuir.7B00984  0.625
2017 Connor GP, Lease N, Casuras A, Goldman AS, Holland PL, Mayer JM. Protonation and electrochemical reduction of rhodium- and iridium-dinitrogen complexes in organic solution. Dalton Transactions (Cambridge, England : 2003). PMID 29019358 DOI: 10.1039/C7Dt03476H  0.435
2017 Horitani M, Grubel K, McWilliams SF, Stubbert BD, Mercado BQ, Yu Y, Gurubasavaraj PM, Lees NS, Holland PL, Hoffman BM. ENDOR characterization of an iron-alkene complex provides insight into a corresponding organometallic intermediate of nitrogenase. Chemical Science. 8: 5941-5948. PMID 28989623 DOI: 10.1039/C7Sc01602F  0.51
2017 Arnet NA, McWilliams SF, DeRosha DE, Mercado BQ, Holland PL. Synthesis and Mechanism of Formation of Hydride-Sulfide Complexes of Iron. Inorganic Chemistry. 56: 9185-9193. PMID 28726395 DOI: 10.1021/Acs.Inorgchem.7B01230  0.504
2017 Connor GP, Holland PL. Coordination chemistry insights into the role of alkali metal promoters in dinitrogen reduction. Catalysis Today. 286: 21-40. PMID 28344387 DOI: 10.1016/J.Cattod.2016.08.014  0.375
2017 Broere DL, Čorić I, Brosnahan A, Holland PL. Quantitation of the THF Content in Fe[N(SiMe3)2]2·xTHF. Inorganic Chemistry. PMID 28248496 DOI: 10.1021/Acs.Inorgchem.7B00056  0.796
2017 DeRosha DE, Mercado BQ, Lukat-Rodgers G, Rodgers KR, Holland PL. Enhancement of C-H Oxidizing Ability in Co-O2  Complexes through an Isolated Heterobimetallic Oxo Intermediate. Angewandte Chemie (International Ed. in English). 56: 3211-3215. PMID 28194845 DOI: 10.1002/Anie.201612010  0.492
2017 Lo JC, Kim D, Pan CM, Edwards JT, Yabe Y, Gui J, Qin T, Gutiérrez S, Giacoboni J, Smith MW, Holland PL, Baran PS. Fe-Catalyzed C-C Bond Construction from Olefins via Radicals. Journal of the American Chemical Society. PMID 28094980 DOI: 10.1021/Jacs.6B13155  0.511
2017 Reesbeck ME, Grubel K, Kim D, Brennessel WW, Mercado BQ, Holland PL. Diazoalkanes in Low-Coordinate Iron Chemistry: Bimetallic Diazoalkyl and Alkylidene Complexes of Iron(II). Inorganic Chemistry. 56: 1019-1022. PMID 28067506 DOI: 10.1021/Acs.Inorgchem.6B01952  0.662
2017 MacLeod KC, Lewis RA, DeRosha DE, Mercado BQ, Holland PL. C-H and C-N Activation at Redox-Active Pyridine Complexes of Iron. Angewandte Chemie (International Ed. in English). 56: 1069-1072. PMID 28000416 DOI: 10.1002/Anie.201610679  0.655
2017 Holland PL. Reaction: Opportunities for Sustainable Catalysts Chem. 2: 443-444. DOI: 10.1016/J.Chempr.2017.03.017  0.459
2016 Bellows SM, Brennessel WW, Holland PL. Effects of Ligand Halogenation on the Electron Localization, Geometry and Spin State of Low-Coordinate (β-Diketiminato)iron Complexes. European Journal of Inorganic Chemistry. 2016: 3344-3355. PMID 28835739 DOI: 10.1002/Ejic.201600112  0.538
2016 MacLeod KC, McWilliams SF, Mercado BQ, Holland PL. Stepwise N-H Bond Formation From N2-Derived Iron Nitride, Imide and Amide Intermediates to Ammonia. Chemical Science. 7: 5736-5746. PMID 28066537 DOI: 10.1039/C6Sc00423G  0.468
2016 Liu Y, Vinyard DJ, Reesbeck ME, Suzuki T, Manakongtreecheep K, Holland PL, Brudvig GW, Söll D. A [3Fe-4S] cluster is required for tRNA thiolation in archaea and eukaryotes. Proceedings of the National Academy of Sciences of the United States of America. PMID 27791189 DOI: 10.1073/Pnas.1615732113  0.308
2016 Bellows SM, Arnet NA, Gurubasavaraj PM, Brennessel WW, Bill E, Cundari TR, Holland PL. The Mechanism of N-N Double Bond Cleavage by an Iron(II) Hydride Complex. Journal of the American Chemical Society. PMID 27598037 DOI: 10.1021/Jacs.6B04654  0.487
2016 MacLeod KC, Menges FS, McWilliams SF, Craig SM, Mercado BQ, Johnson MA, Holland PL. Alkali-Controlled C-H Cleavage or N-C Bond Formation by N2-Derived Iron Nitrides and Imides. Journal of the American Chemical Society. 138: 11185-91. PMID 27571271 DOI: 10.1021/Jacs.6B04984  0.409
2016 Čorić I, Holland PL. Insight into the FeMoco of nitrogenase from synthetic iron complexes with sulfur, carbon, and hydride ligands. Journal of the American Chemical Society. PMID 27171599 DOI: 10.1021/Jacs.6B00747  0.81
2016 McWilliams SF, Rodgers KR, Lukat-Rodgers G, Mercado BQ, Grubel K, Holland PL. Alkali Metal Variation and Twisting of the FeNNFe Core in Bridging Diiron Dinitrogen Complexes. Inorganic Chemistry. 55: 2960-8. PMID 26925968 DOI: 10.1021/Acs.Inorgchem.5B02841  0.477
2015 Arnet NA, Dugan TR, Menges FS, Mercado BQ, Brennessel WW, Bill E, Johnson MA, Holland PL. Synthesis, Characterization, and Nitrogenase-Relevant Reactions of an Iron Sulfide Complex with a Bridging Hydride. Journal of the American Chemical Society. 137: 13220-3. PMID 26457740 DOI: 10.1021/Jacs.5B06841  0.823
2015 Čorić I, Mercado BQ, Bill E, Vinyard DJ, Holland PL. Binding of dinitrogen to an iron-sulfur-carbon site. Nature. 526: 96-9. PMID 26416755 DOI: 10.1038/Nature15246  0.794
2015 Al-Afyouni MH, Suturina E, Pathak S, Atanasov M, Bill E, DeRosha DE, Brennessel WW, Neese F, Holland PL. Spin Isomers and Ligand Isomerization in a Three-Coordinate Cobalt(I) Carbonyl Complex. Journal of the American Chemical Society. PMID 26267848 DOI: 10.1021/Jacs.5B06078  0.405
2015 Chen C, Bellows SM, Holland PL. Tuning steric and electronic effects in transition-metal β-diketiminate complexes. Dalton Transactions (Cambridge, England : 2003). PMID 26244489 DOI: 10.1039/C5Dt02215K  0.422
2015 McWilliams SF, Holland PL. Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes. Accounts of Chemical Research. PMID 26099821 DOI: 10.1021/Acs.Accounts.5B00213  0.506
2015 Reesbeck ME, Rodriguez MM, Brennessel WW, Mercado BQ, Vinyard D, Holland PL. Oxidized and reduced [2Fe-2S] clusters from an iron(I) synthon. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 20: 875-83. PMID 26044124 DOI: 10.1007/S00775-015-1272-4  0.687
2015 Holland PL. Distinctive Reaction Pathways at Base Metals in High-Spin Organometallic Catalysts. Accounts of Chemical Research. 48: 1696-702. PMID 25989357 DOI: 10.1021/Acs.Accounts.5B00036  0.44
2015 Bonyhady SJ, Goldberg JM, Wedgwood N, Dugan TR, Eklund AG, Brennessel WW, Holland PL. Cobalt(II) Complex of a Diazoalkane Radical Anion. Inorganic Chemistry. 54: 5148-50. PMID 25986783 DOI: 10.1021/Acs.Inorgchem.5B00673  0.824
2015 Das A, Han Z, Brennessel WW, Holland PL, Eisenberg R. Nickel complexes for robust light-driven and electrocatalytic hydrogen production from water Acs Catalysis. 5: 1397-1406. DOI: 10.1021/Acscatal.5B00045  0.545
2015 Schofield JA, Brennessel WW, Urnezius E, Rokhsana D, Boshart MD, Juers DH, Holland PL, Machonkin TE. Metal-Halogen Secondary Bonding in a 2,5-Dichlorohydroquinonate Cobalt(II) Complex: Insight into Substrate Coordination in the Chlorohydroquinone Dioxygenase PcpA European Journal of Inorganic Chemistry. 2015: 4643-4647. DOI: 10.1002/Ejic.201500845  0.461
2014 Grubel K, Brennessel WW, Mercado BQ, Holland PL. Alkali metal control over N-N cleavage in iron complexes. Journal of the American Chemical Society. 136: 16807-16. PMID 25412468 DOI: 10.1021/Ja507442B  0.398
2014 Machonkin TE, Boshart MD, Schofield JA, Rodriguez MM, Grubel K, Rokhsana D, Brennessel WW, Holland PL. Structural and spectroscopic characterization of iron(II), cobalt(II), and nickel(II) ortho-dihalophenolate complexes: insights into metal-halogen secondary bonding. Inorganic Chemistry. 53: 9837-48. PMID 25167329 DOI: 10.1021/Ic501424E  0.715
2014 Lewis RA, MacLeod KC, Mercado BQ, Holland PL. Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons. Chemical Communications (Cambridge, England). 50: 11114-7. PMID 25111358 DOI: 10.1039/C4Cc05495D  0.586
2014 MacLeod KC, Vinyard DJ, Holland PL. A multi-iron system capable of rapid N2 formation and N2 cleavage. Journal of the American Chemical Society. 136: 10226-9. PMID 25004280 DOI: 10.1021/Ja505193Z  0.51
2014 Dugan TR, Bill E, MacLeod KC, Brennessel WW, Holland PL. Synthesis, spectroscopy, and hydrogen/deuterium exchange in high-spin iron(II) hydride complexes. Inorganic Chemistry. 53: 2370-80. PMID 24555749 DOI: 10.1021/Ic4013137  0.826
2014 Chen C, Dugan TR, Brennessel WW, Weix DJ, Holland PL. Z-selective alkene isomerization by high-spin cobalt(II) complexes. Journal of the American Chemical Society. 136: 945-55. PMID 24386941 DOI: 10.1021/Ja408238N  0.808
2014 Chiang KP, Bellows SM, Brennessel WW, Holland PL. Multimetallic Cooperativity in Activation of Dinitrogen at Iron-Potassium Sites. Chemical Science (Royal Society of Chemistry : 2010). 5. PMID 24379972 DOI: 10.1039/C3Sc52487F  0.729
2014 Rodriguez MM, Bill E, Brennessel WW, Holland PL. N2 reduction and hydrogenation to ammonia by a molecular iron-potassium complex (PLoS ONE (2011) (780)) Science. 343: 839. DOI: 10.1126/science.343.6173.839-b  0.38
2014 Gladysz JA, Bedford RB, Fujita M, Gabbaï FP, Goldberg KI, Holland PL, Kiplinger JL, Krische MJ, Louie J, Lu CC, Norton JR, Petrukhina MA, Ren T, Stahl SS, Tilley TD, et al. Organometallics roundtable 2013-2014 Organometallics. 33: 1505-1527. DOI: 10.1021/Om500253Z  0.713
2013 Stubbert BD, Vela J, Brennessel WW, Holland PL. A Sulfide-Bridged Diiron(II) Complex with a cis-N2H4Ligand. Zeitschrift Fur Anorganische Und Allgemeine Chemie. 639: 1351-1355. PMID 24678131 DOI: 10.1002/Zaac.201300163  0.672
2013 Dugan TR, Macleod KC, Brennessel WW, Holland PL. Cobalt-Magnesium and Iron-Magnesium Complexes with Weakened Dinitrogen Bridges. European Journal of Inorganic Chemistry. 2013. PMID 24367236 DOI: 10.1002/Ejic.201300187  0.831
2013 Han Z, Shen L, Brennessel WW, Holland PL, Eisenberg R. Nickel pyridinethiolate complexes as catalysts for the light-driven production of hydrogen from aqueous solutions in noble-metal-free systems. Journal of the American Chemical Society. 135: 14659-69. PMID 24004329 DOI: 10.1021/Ja405257S  0.589
2013 Davydov RM, McLaughlin MP, Bill E, Hoffman BM, Holland PL. Generation of high-spin iron(I) in a protein environment using cryoreduction. Inorganic Chemistry. 52: 7323-5. PMID 24004284 DOI: 10.1021/Ic4011339  0.671
2013 Pollock CJ, Grubel K, Holland PL, DeBeer S. Experimentally quantifying small-molecule bond activation using valence-to-core X-ray emission spectroscopy. Journal of the American Chemical Society. 135: 11803-8. PMID 23862983 DOI: 10.1021/Ja3116247  0.361
2013 Macleod KC, Holland PL. Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron. Nature Chemistry. 5: 559-65. PMID 23787744 DOI: 10.1038/Nchem.1620  0.48
2013 Chen Z, Glasson CR, Holland PL, Meyer TJ. Electrogenerated polypyridyl ruthenium hydride and ligand activation for water reduction to hydrogen and acetone to iso-propanol. Physical Chemistry Chemical Physics : Pccp. 15: 9503-7. PMID 23681418 DOI: 10.1039/C3Cp51946E  0.376
2013 Chandrasekaran P, Chiang KP, Nordlund D, Bergmann U, Holland PL, DeBeer S. Sensitivity of X-ray core spectroscopy to changes in metal ligation: a systematic study of low-coordinate, high-spin ferrous complexes. Inorganic Chemistry. 52: 6286-98. PMID 23662855 DOI: 10.1021/Ic3021723  0.723
2013 Cowley RE, Golder MR, Eckert NA, Al-Afyouni MH, Holland PL. Mechanism of catalytic nitrene transfer using Iron(I)-isocyanide complexes Organometallics. 32: 5289-5298. DOI: 10.1021/Om400379P  0.834
2013 Bellows SM, Cundari TR, Holland PL. Spin Crossover during β-Hydride Elimination in High-Spin Iron(II)- and Cobalt(II)-Alkyl Complexes Organometallics. 32: 4741-4751. DOI: 10.1021/Om400325X  0.462
2012 Dugan TR, Bill E, MacLeod KC, Christian GJ, Cowley RE, Brennessel WW, Ye S, Neese F, Holland PL. Reversible C-C bond formation between redox-active pyridine ligands in iron complexes. Journal of the American Chemical Society. 134: 20352-64. PMID 23181620 DOI: 10.1021/Ja305679M  0.845
2012 McLaughlin MP, Retegan M, Bill E, Payne TM, Shafaat HS, Peña S, Sudhamsu J, Ensign AA, Crane BR, Neese F, Holland PL. Azurin as a protein scaffold for a low-coordinate nonheme iron site with a small-molecule binding pocket. Journal of the American Chemical Society. 134: 19746-57. PMID 23167247 DOI: 10.1021/Ja308346B  0.754
2012 Han Z, Qiu F, Eisenberg R, Holland PL, Krauss TD. Robust photogeneration of H2 in water using semiconductor nanocrystals and a nickel catalyst. Science (New York, N.Y.). 338: 1321-4. PMID 23138979 DOI: 10.1126/Science.1227775  0.482
2012 Rodriguez MM, Stubbert BD, Scarborough CC, Brennessel WW, Bill E, Holland PL. Isolation and characterization of stable iron(I) sulfide complexes. Angewandte Chemie (International Ed. in English). 51: 8247-50. PMID 22821816 DOI: 10.1002/Anie.201202211  0.702
2012 Cowley RE, Holland PL. Ligand effects on hydrogen atom transfer from hydrocarbons to three-coordinate iron imides. Inorganic Chemistry. 51: 8352-61. PMID 22800175 DOI: 10.1021/Ic300870Y  0.818
2012 Figg TM, Holland PL, Cundari TR. Cooperativity between low-valent iron and potassium promoters in dinitrogen fixation. Inorganic Chemistry. 51: 7546-50. PMID 22734966 DOI: 10.1021/Ic300150U  0.486
2012 McNamara WR, Han Z, Yin CJ, Brennessel WW, Holland PL, Eisenberg R. Cobalt-dithiolene complexes for the photocatalytic and electrocatalytic reduction of protons in aqueous solutions. Proceedings of the National Academy of Sciences of the United States of America. 109: 15594-9. PMID 22691494 DOI: 10.1073/Pnas.1120757109  0.781
2012 Chiang KP, Scarborough CC, Horitani M, Lees NS, Ding K, Dugan TR, Brennessel WW, Bill E, Hoffman BM, Holland PL. Characterization of the Fe-H bond in a three-coordinate terminal hydride complex of iron(I). Angewandte Chemie (International Ed. in English). 51: 3658-62. PMID 22374689 DOI: 10.1002/Anie.201109204  0.843
2012 Grubel K, Holland PL. New iron-sulfur clusters help hydrogenases tolerate oxygen. Angewandte Chemie (International Ed. in English). 51: 3308-10. PMID 22323270 DOI: 10.1002/Anie.201108761  0.367
2012 Han Z, McNamara WR, Eum MS, Holland PL, Eisenberg R. A nickel thiolate catalyst for the long-lived photocatalytic production of hydrogen in a noble-metal-free system. Angewandte Chemie (International Ed. in English). 51: 1667-70. PMID 22237945 DOI: 10.1002/Anie.201107329  0.751
2012 Edelbach BL, Pharoah BM, Bellows SM, Thayer PR, Fennie CN, Cowley RE, Holland PL. An expedient synthesis of 2,4,6-tris(trifluoromethyl)aniline Synthesis (Germany). 44: 3595-3597. DOI: 10.1055/S-0032-1316809  0.735
2012 Dugan TR, Goldberg JM, Brennessel WW, Holland PL. Low-coordinate cobalt fluoride complexes: Synthesis, reactions, and production from C-F activation reactions Organometallics. 31: 1349-1360. DOI: 10.1021/Om200991K  0.816
2012 Ding K, Brennessel WW, Holland PL. Correction to Three-Coordinate and Four-Coordinate Cobalt Hydride Complexes That React with Dinitrogen Journal of the American Chemical Society. 134: 9020-9020. DOI: 10.1021/Ja303855M  0.664
2012 Cowley RE, Christian GJ, Brennessel WW, Neese F, Holland PL. A reduced (β-diketiminato)iron complex with end-on and side-on nitriles: Strong backbonding or ligand non-innocence? European Journal of Inorganic Chemistry. 479-483. DOI: 10.1002/Ejic.201100787  0.806
2011 Rodriguez MM, Bill E, Brennessel WW, Holland PL. N₂reduction and hydrogenation to ammonia by a molecular iron-potassium complex. Science (New York, N.Y.). 334: 780-3. PMID 22076372 DOI: 10.1126/Science.1211906  0.716
2011 McLaughlin MP, Darrah TH, Holland PL. Palladium(II) and platinum(II) bind strongly to an engineered blue copper protein. Inorganic Chemistry. 50: 11294-6. PMID 22026434 DOI: 10.1021/Ic2017648  0.666
2011 McCormick TM, Han Z, Weinberg DJ, Brennessel WW, Holland PL, Eisenberg R. Impact of ligand exchange in hydrogen production from cobaloxime-containing photocatalytic systems. Inorganic Chemistry. 50: 10660-6. PMID 21980978 DOI: 10.1021/Ic2010166  0.549
2011 Delgado-Jaime MU, Dible BR, Chiang KP, Brennessel WW, Bergmann U, Holland PL, DeBeer S. Identification of a single light atom within a multinuclear metal cluster using valence-to-core X-ray emission spectroscopy. Inorganic Chemistry. 50: 10709-17. PMID 21954894 DOI: 10.1021/Ic201173J  0.672
2011 McNamara WR, Han Z, Alperin PJ, Brennessel WW, Holland PL, Eisenberg R. A cobalt-dithiolene complex for the photocatalytic and electrocatalytic reduction of protons. Journal of the American Chemical Society. 133: 15368-71. PMID 21863808 DOI: 10.1021/Ja207842R  0.784
2011 Holland PL. Techniques for functional and structural modeling of nitrogenase. Methods in Molecular Biology (Clifton, N.J.). 766: 249-63. PMID 21833873 DOI: 10.1007/978-1-61779-194-9_17  0.345
2011 Dugan TR, Sun X, Rybak-Akimova EV, Olatunji-Ojo O, Cundari TR, Holland PL. A masked two-coordinate cobalt(I) complex that activates C-F bonds. Journal of the American Chemical Society. 133: 12418-21. PMID 21770365 DOI: 10.1021/Ja2052914  0.81
2011 Holland PL. Coordination chemistry: all square for high-spin iron(II). Nature Chemistry. 3: 507-8. PMID 21697870 DOI: 10.1038/Nchem.1078  0.499
2011 McLaughlin MP, McCormick TM, Eisenberg R, Holland PL. A stable molecular nickel catalyst for the homogeneous photogeneration of hydrogen in aqueous solution. Chemical Communications (Cambridge, England). 47: 7989-91. PMID 21681322 DOI: 10.1039/C1Cc12347E  0.689
2011 Cowley RE, Eckert NA, Vaddadi S, Figg TM, Cundari TR, Holland PL. Selectivity and mechanism of hydrogen atom transfer by an isolable imidoiron(III) complex. Journal of the American Chemical Society. 133: 9796-811. PMID 21563763 DOI: 10.1021/Ja2005303  0.845
2011 Dible BR, Cowley RE, Holland PL. Remote substitution on N-heterocyclic carbenes heightens the catalytic reactivity of their palladium complexes Organometallics. 30: 5123-5132. DOI: 10.1021/Om200349Y  0.779
2011 Cowley RE, Holland PL. C-H activation by a terminal imidoiron(III) complex to form a cyclopentadienyliron(II) product Inorganica Chimica Acta. 369: 40-44. DOI: 10.1016/J.Ica.2010.11.031  0.789
2010 Rocks SS, Brennessel WW, Machonkin TE, Holland PL. Solution and structural characterization of iron(II) complexes with ortho-halogenated phenolates: insights into potential substrate binding modes in hydroquinone dioxygenases. Inorganic Chemistry. 49: 10914-29. PMID 21058671 DOI: 10.1021/Ic101377U  0.842
2010 Cowley RE, DeYonker NJ, Eckert NA, Cundari TR, DeBeer S, Bill E, Ottenwaelder X, Flaschenriem C, Holland PL. Three-coordinate terminal imidoiron(III) complexes: structure, spectroscopy, and mechanism of formation. Inorganic Chemistry. 49: 6172-87. PMID 20524625 DOI: 10.1021/Ic100846B  0.858
2010 Holland PL. Metal-dioxygen and metal-dinitrogen complexes: where are the electrons? Dalton Transactions (Cambridge, England : 2003). 39: 5415-25. PMID 20361098 DOI: 10.1039/C001397H  0.424
2010 Machonkin TE, Holland PL, Smith KN, Liberman JS, Dinescu A, Cundari TR, Rocks SS. Determination of the active site of Sphingobium chlorophenolicum 2,6-dichlorohydroquinone dioxygenase (PcpA). Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 15: 291-301. PMID 19924449 DOI: 10.1007/S00775-009-0602-9  0.773
2010 Stubbert BD, Holland PL, Adhikari D, Mindiola DJ. Complexes of Bulky β-Diketiminate Ligands: IRON 2,4-BIS-(2,6-Diisopropylphenylimido)Pentyl Chloride (LMe,iPr2FeCl) Inorganic Syntheses. 35: 38-41. DOI: 10.1002/9780470651568.ch1  0.393
2009 Clark MM, Brennessel WW, Holland PL. Bis(η-penta-methyl-cyclo-penta-dien-yl)cobalt(II). Acta Crystallographica. Section E, Structure Reports Online. 65: m391. PMID 21582340 DOI: 10.1107/S1600536809007971  0.333
2009 Dugan TR, Holland PL. New Routes to Low-Coordinate Iron Hydride Complexes: The Binuclear Oxidative Addition of H(2). Journal of Organometallic Chemistry. 694: nihms111237. PMID 20161197 DOI: 10.1016/J.Jorganchem.2009.04.005  0.841
2009 Ding K, Brennessel WW, Holland PL. Three-coordinate and four-coordinate cobalt hydride complexes that react with dinitrogen. Journal of the American Chemical Society. 131: 10804-5. PMID 19621923 DOI: 10.1021/Ja902812Y  0.678
2009 Ding K, Pierpont AW, Brennessel WW, Lukat-Rodgers G, Rodgers KR, Cundari TR, Bill E, Holland PL. Cobalt-dinitrogen complexes with weakened N-N bonds. Journal of the American Chemical Society. 131: 9471-2. PMID 19537787 DOI: 10.1021/Ja808783U  0.634
2009 Chiang KP, Barrett PM, Ding F, Smith JM, Kingsley S, Brennessel WW, Clark MM, Lachicotte RJ, Holland PL. Ligand dependence of binding to three-coordinate Fe(II) complexes. Inorganic Chemistry. 48: 5106-16. PMID 19438179 DOI: 10.1021/Ic802440H  0.799
2009 Sadique AR, Brennessel WW, Holland PL. A diketiminate-bound diiron complex with a bridging carbonate ligand. Acta Crystallographica. Section C, Crystal Structure Communications. 65: m174-6. PMID 19407402 DOI: 10.1107/S0108270109011275  0.521
2009 Cowley RE, Bill E, Neese F, Brennessel WW, Holland PL. Iron(II) complexes with redox-active tetrazene (RNNNNR) ligands. Inorganic Chemistry. 48: 4828-36. PMID 19397284 DOI: 10.1021/Ic900001Y  0.82
2009 Cowley RE, Eckert NA, Elhaïk J, Holland PL. Catalytic nitrene transfer from an imidoiron(III) complex to form carbodiimides and isocyanates. Chemical Communications (Cambridge, England). 1760-2. PMID 19294287 DOI: 10.1039/B820620A  0.823
2009 Ding K, Dugan TR, Brennessel WW, Bill E, Holland PL. Synthesis, properties, and reactivity of diketiminate-supported cobalt fluoride complexes Organometallics. 28: 6650-6656. DOI: 10.1021/Om900394T  0.836
2009 Ding K, Zannat F, Morris JC, Brennessel WW, Holland PL. Coordination of N-methylpyrrolidone to iron(II) Journal of Organometallic Chemistry. 694: 4204-4208. DOI: 10.1016/J.Jorganchem.2009.09.005  0.721
2009 Rocks SS, Brennessel WW, Machonkin TE, Holland PL. Solid-state and proton NMR characterization of an iron(II) complex of a tridentate, facially coordinating N,N,O donor ligand Inorganica Chimica Acta. 362: 1387-1390. DOI: 10.1016/J.Ica.2008.05.037  0.845
2008 Stoian SA, Smith JM, Holland PL, Münck E, Bominaar EL. Mössbauer, electron paramagnetic resonance, and theoretical study of a high-spin, four-coordinate Fe(II) diketiminate complex. Inorganic Chemistry. 47: 8687-95. PMID 18781730 DOI: 10.1021/Ic8004568  0.543
2008 Holland PL. Electronic structure and reactivity of three-coordinate iron complexes. Accounts of Chemical Research. 41: 905-14. PMID 18646779 DOI: 10.1021/Ar700267B  0.591
2008 Yu Y, Sadique AR, Smith JM, Dugan TR, Cowley RE, Brennessel WW, Flaschenriem CJ, Bill E, Cundari TR, Holland PL. The reactivity patterns of low-coordinate iron-hydride complexes. Journal of the American Chemical Society. 130: 6624-38. PMID 18444648 DOI: 10.1021/Ja710669W  0.85
2008 Cowley RE, Elhaïk J, Eckert NA, Brennessel WW, Bill E, Holland PL. A bridging hexazene (RNNNNNNR) ligand from reductive coupling of azides. Journal of the American Chemical Society. 130: 6074-5. PMID 18419120 DOI: 10.1021/Ja801375G  0.821
2008 Sadique AR, Brennessel WW, Holland PL. Reduction of CO2 to CO using low-coordinate iron: formation of a four-coordinate iron dicarbonyl complex and a bridging carbonate complex. Inorganic Chemistry. 47: 784-6. PMID 18171059 DOI: 10.1021/Ic701914M  0.5
2008 Lees NS, McNaughton RL, Gregory WV, Holland PL, Hoffman BM. ENDOR characterization of a synthetic diiron hydrazido complex as a model for nitrogenase intermediates. Journal of the American Chemical Society. 130: 546-55. PMID 18092774 DOI: 10.1021/Ja073934X  0.53
2007 Vela J, Zhu L, Flaschenriem CJ, Brennessel WW, Lachicotte RJ, Holland PL. Macrocyclic Binucleating β-Diketiminate Ligands and their Lithium, Aluminum, and Zinc Complexes. Organometallics. 26: 3416-3423. PMID 19132137 DOI: 10.1021/Om0700258  0.671
2007 Yu Y, Brennessel WW, Holland PL. Borane B-C Bond Cleavage by a Low-Coordinate Iron Hydride Complex and N-N Bond Cleavage by the Hydridoborate Product. Organometallics. 26: 3217-3226. PMID 18725998 DOI: 10.1021/Om7003805  0.466
2007 Sadique AR, Gregory EA, Brennessel WW, Holland PL. Mechanistic insight into N=N cleavage by a low-coordinate iron(II) hydride complex. Journal of the American Chemical Society. 129: 8112-21. PMID 17564444 DOI: 10.1021/Ja069199R  0.521
2007 Vela J, Cirera J, Smith JM, Lachicotte RJ, Flaschenriem CJ, Alvarez S, Holland PL. Quantitative geometric descriptions of the belt iron atoms of the iron-molybdenum cofactor of nitrogenase and synthetic iron(II) model complexes. Inorganic Chemistry. 46: 60-71. PMID 17198413 DOI: 10.1021/Ic0609148  0.741
2006 Eckert NA, Vaddadi S, Stoian S, Lachicotte RJ, Cundari TR, Holland PL. Coordination-number dependence of reactivity in an imidoiron(III) complex. Angewandte Chemie (International Ed. in English). 45: 6868-71. PMID 16991160 DOI: 10.1002/Anie.200601927  0.804
2006 Hebden TJ, Brennessel WW, Flaschenriem CJ, Holland PL. A dinucleating ligand related to the beta-diketiminates. Dalton Transactions (Cambridge, England : 2003). 3855-7. PMID 16896444 DOI: 10.1039/B607440E  0.342
2006 Stoian SA, Vela J, Smith JM, Sadique AR, Holland PL, Münck E, Bominaar EL. Mössbauer and computational study of an N2-bridged diiron diketiminate complex: parallel alignment of the iron spins by direct antiferromagnetic exchange with activated dinitrogen. Journal of the American Chemical Society. 128: 10181-92. PMID 16881648 DOI: 10.1021/Ja062051N  0.7
2006 Yu Y, Smith JM, Flaschenriem CJ, Holland PL. Binding affinity of alkynes and alkenes to low-coordinate iron. Inorganic Chemistry. 45: 5742-51. PMID 16841977 DOI: 10.1021/Ic052136+  0.632
2006 Vela J, Vaddadi S, Kingsley S, Flaschenriem CJ, Lachicotte RJ, Cundari TR, Holland PL. Bidentate coordination of pyrazolate in low-coordinate iron(II) and nickel(II) complexes. Angewandte Chemie (International Ed. in English). 45: 1607-11. PMID 16470750 DOI: 10.1002/Anie.200503535  0.682
2006 Smith JM, Sadique AR, Cundari TR, Rodgers KR, Lukat-Rodgers G, Lachicotte RJ, Flaschenriem CJ, Vela J, Holland PL. Studies of low-coordinate iron dinitrogen complexes. Journal of the American Chemical Society. 128: 756-69. PMID 16417365 DOI: 10.1021/Ja052707X  0.729
2005 Eckert NA, Dinescu A, Cundari TR, Holland PL. A T-shaped three-coordinate nickel(I) carbonyl complex and the geometric preferences of three-coordinate d9 complexes. Inorganic Chemistry. 44: 7702-4. PMID 16241116 DOI: 10.1021/Ic0510213  0.81
2005 Stoian SA, Yu Y, Smith JM, Holland PL, Bominaar EL, Münck E. Mössbauer, electron paramagnetic resonance, and crystallographic characterization of a high-spin Fe(I) diketiminate complex with orbital degeneracy. Inorganic Chemistry. 44: 4915-22. PMID 15998018 DOI: 10.1021/Ic050321H  0.611
2005 Eckert NA, Stoian S, Smith JM, Bominaar EL, Münck E, Holland PL. Synthesis, structure, and spectroscopy of an oxodiiron(II) complex. Journal of the American Chemical Society. 127: 9344-5. PMID 15984842 DOI: 10.1021/Ja0436704  0.844
2005 Vela J, Smith JM, Yu Y, Ketterer NA, Flaschenriem CJ, Lachicotte RJ, Holland PL. Synthesis and reactivity of low-coordinate iron(II) fluoride complexes and their use in the catalytic hydrodefluorination of fluorocarbons. Journal of the American Chemical Society. 127: 7857-70. PMID 15913376 DOI: 10.1021/Ja042672L  0.74
2005 Holland PL. Low-coordinate iron complexes as synthetic models of nitrogenase Canadian Journal of Chemistry. 83: 296-301. DOI: 10.1139/V05-005  0.544
2005 Gregory EA, Lachicotte RJ, Holland PL. A cationic three-coordinate iron(II) complex and the reaction of β-diketiminate with ethyl diazoacetate Organometallics. 24: 1803-1805. DOI: 10.1021/Om0489913  0.546
2004 Eckert NA, Smith JM, Lachicotte RJ, Holland PL. Low-coordinate iron(II) amido complexes of beta-diketiminates: synthesis, structure, and reactivity. Inorganic Chemistry. 43: 3306-21. PMID 15132641 DOI: 10.1021/Ic035483X  0.847
2004 Vela J, Stoian S, Flaschenriem CJ, Münck E, Holland PL. A sulfido-bridged diiron(II) compound and its reactions with nitrogenase-relevant substrates. Journal of the American Chemical Society. 126: 4522-3. PMID 15070362 DOI: 10.1021/Ja049417L  0.667
2004 Vela J, Vaddadi S, Cundari TR, Smith JM, Gregory EA, Lachicotte RJ, Flaschenriem CJ, Holland PL. Reversible beta-hydrogen elimination of three-coordinate iron(II) alkyl complexes: Mechanistic and thermodynamic studies Organometallics. 23: 5226-5239. DOI: 10.1021/Om049415+  0.691
2003 Smith JM, Lachicotte RJ, Holland PL. N=N bond cleavage by a low-coordinate ironII hydride complex. Journal of the American Chemical Society. 125: 15752-3. PMID 14677959 DOI: 10.1021/Ja038152S  0.664
2003 Jazdzewski BA, Reynolds AM, Holland PL, Young VG, Kaderli S, Zuberbühler AD, Tolman WB. Copper(I)-phenolate complexes as models of the reduced active site of galactose oxidase: synthesis, characterization, and O2 reactivity. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 8: 381-93. PMID 12761659 DOI: 10.1007/S00775-002-0420-9  0.782
2003 Eckert NA, Bones EM, Lachicotte RJ, Holland PL. Nickel complexes of a bulky beta-diketiminate ligand. Inorganic Chemistry. 42: 1720-5. PMID 12611544 DOI: 10.1021/Ic025986N  0.782
2003 Holland PL, Cundari TR, Perez LL, Eckert aNA, Lachicotte RJ. Electronically Unsaturated Three-Coordinate Chloride and Methyl Complexes of Iron, Cobalt, and Nickel [J. Am. Chem. Soc. 2002, 124 (48), 14416−14424]. Journal of the American Chemical Society. 125: 11772-11772. DOI: 10.1021/Ja0378411  0.478
2002 Vela J, Smith JM, Lachicotte RJ, Holland PL. Alkyl isomerisation in three-coordinate iron(II) complexes. Chemical Communications (Cambridge, England). 2886-7. PMID 12478796 DOI: 10.1039/B209389H  0.76
2002 Holland PL, Cundari TR, Perez LL, Eckert NA, Lachicotte RJ. Electronically unsaturated three-coordinate chloride and methyl complexes of iron, cobalt, and nickel. Journal of the American Chemical Society. 124: 14416-24. PMID 12452717 DOI: 10.1021/Ja025583M  0.834
2002 Spencer DJ, Reynolds AM, Holland PL, Jazdzewski BA, Duboc-Toia C, Le Pape L, Yokota S, Tachi Y, Itoh S, Tolman WB. Copper chemistry of beta-diketiminate ligands: monomer/dimer equilibria and a new class of bis(mu-oxo)dicopper compounds. Inorganic Chemistry. 41: 6307-21. PMID 12444774 DOI: 10.1021/Ic020369K  0.813
2002 Andres H, Bominaar EL, Smith JM, Eckert NA, Holland PL, Münck E. Planar three-coordinate high-spin Fe(II) complexes with large orbital angular momentum: Mössbauer, electron paramagnetic resonance, and electronic structure studies. Journal of the American Chemical Society. 124: 3012-25. PMID 11902893 DOI: 10.1021/Ja012327L  0.81
2002 Spencer DJ, Aboelella NW, Reynolds AM, Holland PL, Tolman WB. beta-diketiminate ligand backbone structural effects on Cu(I)/O(2) reactivity: unique copper-superoxo and bis(mu-oxo) complexes. Journal of the American Chemical Society. 124: 2108-9. PMID 11878952 DOI: 10.1021/Ja017820B  0.798
2002 Smith JM, Lachicotte RJ, Holland PL. Three-coordinate, 12-electron organometallic complexes of iron(II) supported by a bulky β-diketiminate ligand: Synthesis and insertion of CO to give square-pyramidal complexes Organometallics. 21: 4808-4814. DOI: 10.1021/Om020571V  0.659
2002 Chowdhury A, Peteanu LA, Holland PL, Tolman WB. The electronic properties of a model active site for blue copper proteins as probed by Stark spectroscopy Journal of Physical Chemistry B. 106: 3007-3012. DOI: 10.1021/Jp0115751  0.52
2001 Smith JM, Lachicotte RJ, Holland PL. Tuning metal coordination number by ancillary ligand steric effects: synthesis of a three-coordinate iron(II) complex. Chemical Communications (Cambridge, England). 1542-3. PMID 12240372 DOI: 10.1039/B103635C  0.667
2001 Jazdzewski BA, Holland PL, Pink M, Young VG, Spencer DJ, Tolman WB. Three-coordinate copper(II)-phenolate complexes. Inorganic Chemistry. 40: 6097-107. PMID 11703106 DOI: 10.1021/Ic010615C  0.795
2001 Smith JM, Lachicotte RJ, Pittard KA, Cundari TR, Lukat-Rodgers G, Rodgers KR, Holland PL. Stepwise reduction of dinitrogen bond order by a low-coordinate iron complex. Journal of the American Chemical Society. 123: 9222-3. PMID 11552855 DOI: 10.1021/Ja016094+  0.643
2000 Lam BM, Halfen JA, Young VG, Hagadorn JR, Holland PL, Lledós A, Cucurull-Sánchez L, Novoa JJ, Alvarez S, Tolman WB. Ligand macrocycle structural effects on copper-dioxygen reactivity. Inorganic Chemistry. 39: 4059-72. PMID 11198861 DOI: 10.1021/Ic000248P  0.597
2000 Itoh S, Taki M, Nakao H, Holland PL, Tolman WB, Que Jr, Fukuzumi S. Aliphatic Hydroxylation by a Bis(µ-oxo)dicopper(III) Complex. Angewandte Chemie (International Ed. in English). 39: 398-400. PMID 10649424 DOI: 10.1002/(Sici)1521-3773(20000117)39:2<398::Aid-Anie398>3.0.Co;2-2  0.64
2000 Holland PL, Cramer CJ, Wilkinson EC, Mahapatra S, Rodgers KR, Itoh S, Taki M, Fukuzumi S, Que L, Tolman WB. Resonance Raman spectroscopy as a probe of the bis(μ-oxo)dicopper core Journal of the American Chemical Society. 122: 792-802. DOI: 10.1021/Ja992003L  0.544
2000 Holland PL, Andersen RA, Bergman RG, Huang J, Nolan SP. Monomeric Cyclopentadienylnickel Methoxo and Amido Complexes:  Synthesis, Characterization, Reactivity, and Use for Exploring the Relationship between M−X and H−X Bond Energies [J. Am. Chem. Soc.1997,119, 12800−12814]. Journal of the American Chemical Society. 122: 9352-9352. DOI: 10.1021/Ja004657W  0.618
2000 Meggers E, Holland PL, Tolman WB, Romesberg FE, Schultz PG. A novel copper-mediated DNA base pair [6] Journal of the American Chemical Society. 122: 10714-10715. DOI: 10.1021/Ja0025806  0.466
2000 Randall DW, George SD, Holland PL, Hedman B, Hodgson KO, Tolman WB, Solomon EI. Spectroscopic and electronic structural studies of blue copper model complexes. 2. Comparison of three-and four-coordinate Cu(II)-thiolate complexes and fungal laccase Journal of the American Chemical Society. 122: 11632-11648. DOI: 10.1021/Ja001592O  0.577
2000 Holland PL, Tolman WB. A structural model of the type 1 copper protein active site: N2S(thiolate)s(thioether) ligation in a Cu(II) complex [23] Journal of the American Chemical Society. 122: 6331-6332. DOI: 10.1021/Ja001328V  0.558
2000 Itoh S, Taki M, Nakao H, Holland PL, Tolman WB, Que L, Fukuzumi S. Aliphatische Hydroxylierung mit einem Bis(μ-oxo)dikupfer(III)-Komplex Angewandte Chemie. 112: 409-411. DOI: 10.1002/(Sici)1521-3757(20000117)112:2<409::Aid-Ange409>3.0.Co;2-J  0.591
1999 Holland PL, Rodgers KR, Tolman WB. Is the Bis(μ-oxo)dicopper Core Capable of Hydroxylating an Arene? Angewandte Chemie (International Ed. in English). 38: 1139-42. PMID 25138522 DOI: 10.1002/(Sici)1521-3773(19990419)38:8<1139::Aid-Anie1139>3.0.Co;2-0  0.603
1999 Cahoy J, Holland PL, Tolman WB. Experimental Studies of the Interconversion of &mgr;-eta(2):eta(2)-Peroxo- and Bis(&mgr;-oxo)dicopper Complexes. Inorganic Chemistry. 38: 2161-2168. PMID 11671001 DOI: 10.1021/Ic990095+  0.518
1999 Holland PL, Andersen RA, Bergman RG. Application of theE-CApproach to Understanding the Bond Energies Thermodynamics of Late-Metal Amido, Aryloxo and Alkoxo Complexes: An Alternative to pπ/dπ Repulsion Comments On Inorganic Chemistry. 21: 115-129. DOI: 10.1080/02603599908020418  0.644
1999 Holland PL, Tolman WB. Three-coordinate Cu(II) complexes: Structural models of trigonal-planar type 1 copper protein active sites [5] Journal of the American Chemical Society. 121: 7270-7271. DOI: 10.1021/Ja991533E  0.559
1999 Holland PL, Tolman WB. Dioxygen activation by copper sites: Relative stability and reactivity of (μ-η2:η2-peroxo)- and bis(μ-oxo)dicopper cores Coordination Chemistry Reviews. 190: 855-869. DOI: 10.1016/S0010-8545(99)00125-3  0.627
1999 Holland PL, Rodgers KR, Tolman WB. Ist der Bis(μ-oxo)dikupfer-Kern fähig, ein Aren zu hydroxylieren? Angewandte Chemie. 111: 1210-1213. DOI: 10.1002/(Sici)1521-3757(19990419)111:8<1210::Aid-Ange1210>3.0.Co;2-U  0.549
1999 Holland PL, Andersen RA, Bergman RG. Application of the E-C approach to understanding the bond energies thermodynamics of late-metal amido, aryloxo and alkoxo complexes: An alternative to pπ/dπ repulsion Comments On Inorganic Chemistry. 21: 115-129.  0.463
1999 Cahoy J, Holland PL, Tolman WB. Experimental studies of the interconversion of μ-η2:η2-peroxo- and bis(μ-oxo)dicopper complexes Inorganic Chemistry. 38: 2161-2168.  0.563
1998 Holland PL, Andersen RA, Bergman RG. Cyclopentadienyl and Imide Ligand Transfer from Zirconium to Iridium:  Can Early Transition Metal Imido Compounds Be Used as Imide Transfer Reagents? Organometallics. 17: 433-437. DOI: 10.1021/Om970827A  0.644
1998 Golden JT, Peterson TH, Holland PL, Bergman RG, Andersen RA. Adduct formation and single and double deprotonation of Cp*(PMe3)Ir(H)2 with main group metal alkyls and aryls: Synthesis and structure of three novel Ir-Al and Ir-Mg heterobimetallics Journal of the American Chemical Society. 120: 223-224. DOI: 10.1021/Ja973230V  0.786
1998 Holland PL, Andersen RA, Bergman RG. Cyclopentadienyl and imide ligand transfer from zirconium to iridium: Can early transition metal imido compounds be used as imide transfer reagents? Organometallics. 17: 433-437.  0.453
1997 Holland PL, Smith ME, Andersen RA, Bergman RG. X-ray crystal structures of Cp*Ni(PEt3)X [X = Br, O(p-C6H4Me), NH(p- C6H4Me), S(p-C6H4Me), OCH3, CH2C6H5, Me, H, PEt3 +]. Understanding distortions and trans influences in cyclopentadienyl complexes Journal of the American Chemical Society. 119: 12815-12823. DOI: 10.1021/Ja971830O  0.608
1997 Holland PL, Andersen RA, Bergman RG, Huang J, Nolan SP. Monomeric cyclopentadienylnickel methoxo and amido complexes: Synthesis, characterization, reactivity, and use for exploring the relationship between H-X and M-X bond energies Journal of the American Chemical Society. 119: 12800-12814. DOI: 10.1021/Ja971829P  0.633
1996 Holland PL, Andersen RA, Bergman RG. Synthesis, characterization, isomerization, and reactivity of dimeric cyclopentadienylnickel amido complexes Journal of the American Chemical Society. 118: 1092-1104. DOI: 10.1021/Ja952882L  0.648
Show low-probability matches.