Year |
Citation |
Score |
2012 |
Belmar J, Funk RL. Total synthesis of (±)-communesin F via a cycloaddition with indol-2-one. Journal of the American Chemical Society. 134: 16941-3. PMID 22978807 DOI: 10.1021/Ja307277W |
0.703 |
|
2012 |
Funk RL, Belmar J. Total synthesis of (±)-isophellibiline. Tetrahedron Letters. 53: 176-178. PMID 22308006 DOI: 10.1016/J.Tetlet.2011.10.161 |
0.77 |
|
2011 |
Huntley RJ, Funk RL. Total synthesis of (±)-γ-lycorane via the electrocyclic ring closure of a divinylpyrroline. Tetrahedron Letters. 52: 6671-6674. PMID 22081730 DOI: 10.1016/J.Tetlet.2011.09.138 |
0.801 |
|
2011 |
Nilson MG, Funk RL. Total synthesis of (±)-cortistatin J from furan. Journal of the American Chemical Society. 133: 12451-3. PMID 21761900 DOI: 10.1021/Ja206138D |
0.828 |
|
2010 |
Nilson MG, Funk RL. Total synthesis of (-)-nakadomarin A. Organic Letters. 12: 4912-5. PMID 20932022 DOI: 10.1021/Ol102079Z |
0.826 |
|
2010 |
Maeng J, Funk RL. ChemInform Abstract: Total Synthesis of (.+-.)-Fasicularin via a 2-Amidoacrolein Cycloaddition. Cheminform. 33: no-no. DOI: 10.1002/chin.200225199 |
0.483 |
|
2010 |
Greshock TJ, Funk RL. ChemInform Abstract: Total Synthesis of (.+-.)-Lepadiformine via an Amidoacrolein Cycloaddition. Cheminform. 33: no-no. DOI: 10.1002/chin.200209218 |
0.766 |
|
2010 |
Aungst Jr. RA, Funk RL. ChemInform Abstract: Synthesis of (Z)-2-Acyl-2-enals via Retrocycloadditions of 5-Acyl-4-alkyl-4H-1,3-dioxins: Application in the Total Synthesis of the Cytotoxin (.+-.)-Euplotin A (X). Cheminform. 33: no-no. DOI: 10.1002/chin.200204245 |
0.389 |
|
2006 |
Huntley RJ, Funk RL. A strategy for the total synthesis of dragmacidin E. Construction of the core ring system. Organic Letters. 8: 4775-8. PMID 17020300 DOI: 10.1021/Ol0617547 |
0.812 |
|
2006 |
Crawley SL, Funk RL. Generation of aza-ortho-xylylenes via ring opening of 2-(2-acylaminophenyl)aziridines: application in the construction of the communesin ring system. Organic Letters. 8: 3995-8. PMID 16928057 DOI: 10.1021/Ol061461D |
0.816 |
|
2006 |
Nilson MG, Funk RL. Generation of N-acyliminium ions via intramolecular conjugate addition reactions: a strategy for the total synthesis of nakadomarin A. Organic Letters. 8: 3833-6. PMID 16898829 DOI: 10.1021/Ol061463Y |
0.808 |
|
2006 |
He Y, Funk RL. Total syntheses of (+/-)-beta-erythroidine and (+/-)-8-oxo-beta-erythroidine by an intramolecular Diels-Alder cycloaddition of a 2-amidoacrolein. Organic Letters. 8: 3689-92. PMID 16898793 DOI: 10.1021/Ol061267R |
0.461 |
|
2006 |
Huntley RJ, Funk RL. Total syntheses of (+/-)-cis-trikentrin A and (+/-)-cis-trikentrin B via electrocyclic ring closures of 2,3-divinylpyrrolines. Organic Letters. 8: 3403-6. PMID 16836416 DOI: 10.1021/Ol061259A |
0.807 |
|
2006 |
Greshock TJ, Funk RL. An approach to the total synthesis of welwistatin. Organic Letters. 8: 2643-5. PMID 16737334 DOI: 10.1021/Ol0608799 |
0.802 |
|
2006 |
Greshock TJ, Funk RL. Synthesis of indoles via 6pi-electrocyclic ring closures of trienecarbamates. Journal of the American Chemical Society. 128: 4946-7. PMID 16608316 DOI: 10.1021/Ja060282O |
0.757 |
|
2006 |
Greshock TJ, Funk RL. 6-(2-Haloethyl)-2,2-dimethyl-4H-1,3-dioxins: versatile haloethyl vinyl ketone equivalents for carbocycle construction Tetrahedron Letters. 47: 5437-5439. DOI: 10.1016/J.Tetlet.2006.05.171 |
0.762 |
|
2005 |
Fuchs JR, Funk RL. Indol-2-one intermediates: mechanistic evidence and synthetic utility. Total syntheses of (+/-)-flustramines A and C. Organic Letters. 7: 677-80. PMID 15704923 DOI: 10.1021/Ol047532V |
0.65 |
|
2004 |
Cossey KN, Funk RL. Diastereoselective synthesis of 2,3,6-trisubstituted tetrahydropyran-4-ones via Prins cyclizations of enecarbamates: a formal synthesis of (+)-ratjadone A. Journal of the American Chemical Society. 126: 12216-7. PMID 15453725 DOI: 10.1021/Ja046940R |
0.527 |
|
2004 |
Fuchs JR, Funk RL. Total synthesis of (+/-)-perophoramidine. Journal of the American Chemical Society. 126: 5068-9. PMID 15099080 DOI: 10.1021/Ja049569G |
0.702 |
|
2003 |
Crawley SL, Funk RL. A synthetic approach to nomofungin/communesin B. Organic Letters. 5: 3169-71. PMID 12943379 DOI: 10.1021/Ol034407V |
0.809 |
|
2002 |
Maeng JH, Funk RL. Total synthesis of (+/-)fasicularin via a 2-amidoacrolein cycloaddition. Organic Letters. 4: 331-3. PMID 11820872 DOI: 10.1021/Ol016850G |
0.655 |
|
2002 |
Greshock TJ, Funk RL. 6-Bromomethyl-4H-1,3-dioxin: a versatile bromomethyl vinyl ketone equivalent for heterocycle and carbocycle construction. Journal of the American Chemical Society. 124: 754-5. PMID 11817942 DOI: 10.1021/Ja0123554 |
0.775 |
|
2002 |
Aungst RA, Funk RL, Harmata M. Stereoselective preparation of (Z)-2-(trialkylsilyloxy)-2-alkenals by retrocycloaddition reactions of 4h-4-alkyl-5-(trialkylsilyloxy)-1,3-dioxins. Useful reactants for Lewis acid-catalyzed [4 + 3] cyclizations Chemtracts. 15: 189-194. DOI: 10.1002/chin.200302273 |
0.404 |
|
2001 |
Fuchs JR, Funk RL. Total synthesis of (+/-)-lennoxamine and (+/-)-aphanorphine by intramolecular electrophilic aromatic substitution reactions of 2-amidoacroleins. Organic Letters. 3: 3923-5. PMID 11720570 DOI: 10.1021/Ol016795B |
0.773 |
|
2001 |
Aungst RA, Funk RL. Stereoselective preparation of (Z)-2-(trialkylsilyloxy)-2-alkenals by retrocycloaddition reactions of 4H-4-Alkyl-5-(trialkylsilyloxy)-1,3-dioxins. Useful reactants for Lewis acid catalyzed [4 + 3] cyclizations. Organic Letters. 3: 3553-5. PMID 11678706 DOI: 10.1021/Ol016668F |
0.52 |
|
2001 |
Greshock TJ, Funk RL. Total synthesis of (+/-)-lepadiformine via an amidoacrolein cycloaddition. Organic Letters. 3: 3511-4. PMID 11678695 DOI: 10.1021/Ol0165903 |
0.832 |
|
2001 |
Fuchs JR, Funk RL. Intramolecular electrophilic aromatic substitution reactions of 2-amidoacroleins: a new method for the preparation of tetrahydroisoquinolines, tetrahydro-3-benzazepines, and hexahydro-3-benzazocines. Organic Letters. 3: 3349-51. PMID 11594831 DOI: 10.1021/Ol016592N |
0.753 |
|
2001 |
Aungst RA, Funk RL. Synthesis of (Z)-2-acyl-2-enals via retrocycloadditions of 5-acyl-4-alkyl-4H-1,3-dioxins: application in the total synthesis of the cytotoxin (+/-)-euplotin A. Journal of the American Chemical Society. 123: 9455-6. PMID 11562234 DOI: 10.1021/Ja011470B |
0.515 |
|
2001 |
Aungst RA, Chan C, Funk RL. Total synthesis of the sesquiterpene (+/-)-illudin C via an intramolecular nitrile oxide cycloaddition. Organic Letters. 3: 2611-3. PMID 11483073 DOI: 10.1021/Ol016314O |
0.577 |
|
2001 |
Maeng JH, Funk RL. Total synthesis of the immunosuppressant FR901483 via an amidoacrolein cycloaddition. Organic Letters. 3: 1125-8. PMID 11348175 DOI: 10.1021/Ol015506G |
0.641 |
|
2001 |
Greshock TJ, Funk RL. Total synthesis of (±)-lepadiformine via an amidoacrolein cycloaddition Organic Letters. 3: 3511-3514. DOI: 10.1021/ol0165903 |
0.699 |
|
2000 |
Fearnley SP, Funk RL, Gregg RJ. Preparation of 2-alkyl- and 2-acylpropenals from 5-(trifluoromethanesulfonyloxy)-4H-1,3-dioxin: A versatile acrolein α-cation synthon Tetrahedron. 56: 10275-10281. DOI: 10.1016/S0040-4020(00)00872-3 |
0.462 |
|
1999 |
Funk RL, Yang G. C(1)-substituted menthol derivatives: Self-removing chiral auxiliaries for asymmetric conjugate additions to cycloalkenones Tetrahedron Letters. 40: 1073-1074. DOI: 10.1016/S0040-4039(98)02627-6 |
0.488 |
|
1998 |
Young ERR, Funk RL. A practical synthesis of pyrene-4,5-dione Journal of Organic Chemistry. 63: 9995-9996. DOI: 10.1021/Jo970344G |
0.428 |
|
1996 |
Funk RL, Yost KJ. Preparation and Diels-Alder Cycloaddition of 2-Acyloxyacroleins. Facile Synthesis of Functionalized Taxol A-Ring Synthons. The Journal of Organic Chemistry. 61: 2598-2599. PMID 11667085 DOI: 10.1021/Jo960340W |
0.614 |
|
1996 |
Funk RL, Young ERR, Williams RM, Flanagan MF, Cecil TL. Photochemical cycloaromatization reactions of ortho-dialkynylarenes: A new class of DNA photocleaving agents Journal of the American Chemical Society. 118: 3291-3292. DOI: 10.1021/Ja9521482 |
0.327 |
|
1993 |
Funk RL, Olmstead TA, Parvez M, Stallman JB. Stereoselective construction of the complete ingenane ring system Journal of Organic Chemistry. 58: 5873-5875. DOI: 10.1021/Jo00074A003 |
0.485 |
|
1993 |
Funk RL, Fitzgerald JF, Olmstead TA, Para KS, Wos JA. Titanium-mediated cyclizations of .beta.-keto esters with acetals: a convenient route to 2-carbalkoxycycloalkenones Journal of the American Chemical Society. 115: 8849-8850. DOI: 10.1021/Ja00072A052 |
0.343 |
|
1993 |
Funk RL, Stallman JB, Wos JA. Claisen rearrangements of enol phosphates Journal of the American Chemical Society. 115: 8847-8848. DOI: 10.1021/Ja00072A051 |
0.351 |
|
1993 |
Funk RL, Bolton GL, Brummond KM, Ellestad KE, Stallman JB. Facile intramolecular carbolithiation reactions of alkylthio- and alkoxyacetylenes by stabilized carbanions. A novel strategy for the synthesis of functionalized carbocycles Journal of the American Chemical Society. 115: 7029-7030. DOI: 10.1021/Ja00068A090 |
0.726 |
|
1993 |
Funk RL, Umstead-Daggett J, Brummond KM. Stereoselective preparation of vinyl sulfones by protodesilylation of allyl silanes Tetrahedron Letters. 34: 2867-2870. DOI: 10.1016/S0040-4039(00)60467-7 |
0.726 |
|
1989 |
Funk R, Abelman M, Jellison K. Generation of Ketenes From Carboxylic Acids Using the Mukaiyama Reagent (1-Methyl-2-chloropyridinium Iodide) Synlett. 1989: 36-37. DOI: 10.1055/S-1989-34706 |
0.318 |
|
1988 |
Funk RL, Olmstead TA, Parvez M. A solution to the in,out-bicyclo[4.4.1]undecan-7-one problem inherent in ingenane total synthesis Journal of the American Chemical Society. 110: 3298-3300. DOI: 10.1021/Ja00218A049 |
0.326 |
|
1988 |
Funk RL, Novak PM, Abelman MM. Preparation of bridged bicycloalkanes via intramolecular [2+2] cycloadditions of ketenes a short total synthesis of (±)-clovene. Tetrahedron Letters. 29: 1493-1496. DOI: 10.1016/S0040-4039(00)80333-0 |
0.38 |
|
1988 |
FUNK RL, NOVAK PM, ABELMAN MM. ChemInform Abstract: Preparation of Bridged Bicycloalkanes via Intramolecular (2 + 2)Cycloadditions of Ketenes: A Short Total Synthesis of (.+-.)-Clovene. Cheminform. 19. DOI: 10.1002/chin.198834123 |
0.477 |
|
1987 |
Funk RL, Daggett JU. Intermolecular cycloaddition reactions of exocyclic nitrones facile synthesis of 1-azaspirocycles Heterocycles. 26: 2175-2182. DOI: 10.3987/R-1987-08-2175 |
0.376 |
|
1987 |
Funk RL, Bolton GL. A new approach to the cedrane ring system via intramolecular [4 + 2] tropone-olefin cycloaddition. Total synthesis of (.+-.)-.alpha.- and .beta.-pipitzol The Journal of Organic Chemistry. 52: 3173-3174. DOI: 10.1021/Jo00390A042 |
0.453 |
|
1987 |
FUNK RL, BOLTON GL. ChemInform Abstract: A New Approach to the Cedrane Ring System via Intramolecular (4 + 2) Tropone-Olefin Cycloaddition. Total Synthesis of (.+-.)-α- and (.+-.)-β-Pipitzol (I). Cheminform. 18. DOI: 10.1002/chin.198752365 |
0.362 |
|
1987 |
Funk RL, Bolton GL. A new approach to the cedrane ring system via intramolecular [4 + 2] tropone-olefin cycloaddition. Total synthesis of (±)-α- and (±)-β-pipitzol Journal of Organic Chemistry. 52: 3173-3174. |
0.318 |
|
1986 |
Funk RL, Abelman MM. Synthesis of bridged bicycloalkanes via the alicyclic claisen rearrangement. A new approach to quadrone Journal of Organic Chemistry. 51: 3247-3248. DOI: 10.1021/Jo00366A046 |
0.448 |
|
1986 |
Funk RL, Bolton GL. Intramolecular [6 + 4] and [4 + 2] tropone-olefin cycloaddition reactions. Facile synthesis of the ingenane ring system Journal of the American Chemical Society. 108: 4655-4657. DOI: 10.1021/Ja00275A069 |
0.659 |
|
1986 |
Funk RL, Abelman MM, Munger JD. Claisen-rearrangement-mediated ring contraction of macrocyclic lactones. A new approach to carbocycles and heterocycles Tetrahedron. 42: 2831-2846. DOI: 10.1016/S0040-4020(01)90572-1 |
0.397 |
|
1986 |
FUNK RL, BOLTON GL. ChemInform Abstract: Intramolecular [6 + 4] and [4 + 2] Tropone-Olefin Cycloaddition Reactions. Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198648161 |
0.414 |
|
1985 |
Funk RL, Bolton GL, Daggett JU, Hansen MM, Horcher LHM. Intramolecular cycloaddition reactions of exocyclic nitrones. Application in the total synthesis of terpenes Tetrahedron. 41: 3479-3495. DOI: 10.1016/S0040-4020(01)96702-X |
0.487 |
|
1985 |
Funk RL, Munger JDJ. A New Approach To Heterocycles: Synthesis Of (.+-.)-N-Benzoylmeroquinene Methyl Ester Cheminform. 16. DOI: 10.1002/Chin.198519222 |
0.426 |
|
1985 |
Funk RL, Munger JD. The stereospecific total synthesis of (±)-cis-chrysanthemic acid via the alicyclic claisen rearrangement Journal of Organic Chemistry. 50: 707-709. |
0.308 |
|
1984 |
Funk RL, Munger JD. A new approach to heterocycles: synthesis of (.+-.)-N-benzoylmeroquinene methyl ester Journal of Organic Chemistry. 49: 4319-4320. DOI: 10.1021/Jo00196A048 |
0.426 |
|
1984 |
Funk RL, Mossman CJ, Zeller WE. Hypocholesterolemic agent compactin. an alternative diels-alder strategy for the synthesis of the hexahydronaphthalene portion Tetrahedron Letters. 25: 1655-1658. DOI: 10.1016/S0040-4039(01)81136-9 |
0.345 |
|
1984 |
Funk RL, Bolton GL. The nitrone route to linearly fused tricyclopentanoids. Another synthesis of hirsutene Journal of Organic Chemistry. 49: 5021-5022. DOI: 10.1002/Chin.198519160 |
0.541 |
|
1984 |
Funk RL, Munger JD. A new approach to heterocycles: Synthesis of (±)-N-benzoylmeroquinene methyl ester Journal of Organic Chemistry. 49: 4319-4320. |
0.319 |
|
1983 |
Funk RL, Horcher LHM, Daggett JU, Hansen MM. Facile bridged bicycloalkane synthesis via intramolecular nitrone-olefin cycloaddition Journal of Organic Chemistry. 48: 2632-2634. DOI: 10.1021/Jo00163A052 |
0.603 |
|
1982 |
Funk RL, Zeller WE. Hypocholesterolemic agent compactin (ML-236B). Total synthesis of the hexahydronaphthalene portion Journal of Organic Chemistry. 47: 180-182. DOI: 10.1021/Jo00340A050 |
0.38 |
|
1982 |
Abelman MM, Funk RL, Munger JD. Alicyclic claisen rearrangement. A general carbocycle synthesis based on four-atom-ring contractions of lactones Journal of the American Chemical Society. 104: 4030-4032. DOI: 10.1021/Ja00378A054 |
0.491 |
|
1980 |
Danishefsky S, Funk RL, Kerwin JF. Claisen rearrangements of lactonic (silyl) enolates: a new route to functionalized cycloalkenes Journal of the American Chemical Society. 102: 6889-6891. DOI: 10.1021/Ja00542A058 |
0.536 |
|
1980 |
Funk RL, Vollhardt KPC. Transition-metal-catalyzed alkyne cyclizations. A cobalt-mediated total synthesis of dl-estrone Journal of the American Chemical Society. 102: 5253-5261. DOI: 10.1021/Ja00536A023 |
0.411 |
|
1980 |
Funk RL, Vollhardt KPC. Cooligomerizations of 3-substituted 1,5-hexadiynes with bis(trimethylsilyl)acetylene catalyzed by cobalt. A general synthesis of tricyclic ring systems from acyclic precursors Journal of the American Chemical Society. 102: 5245-5253. DOI: 10.1021/Ja00536A022 |
0.586 |
|
1980 |
FUNK RL, VOLLHARDT KPC. ChemInform Abstract: TRANSITION-METAL-CATALYZED ALKYNE CYCLIZATIONS. A COBALT-MEDIATED TOTAL SYNTHESIS OF DL-ESTRONE Chemischer Informationsdienst. 11. DOI: 10.1002/chin.198044294 |
0.313 |
|
1977 |
Funk RL, Vollhardt KP. A cobalt-catalyzed steroid synthesis. Journal of the American Chemical Society. 99: 5483-4. PMID 886107 DOI: 10.1021/Ja00458A044 |
0.562 |
|
1977 |
FUNK RL, VOLLHARDT KPC. ChemInform Abstract: A COBALT-CATALYZED STEROID SYNTHESIS Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/chin.197745335 |
0.474 |
|
1977 |
FUNK RL, VOLLHARDT KPC. ChemInform Abstract: HEXA-1,5-DIYN-3-OL ETHERS AS TETRAMETHYNYL SYNTHONS IN COBALT-CATALYZED ACETYLENE COOLIGOMERIZATIONS, A ONE-STEP SYNTHESIS OF 2,3,6,7-TETRAKISTRIMETHYLSILYLNAPHTHALENE Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/chin.197707243 |
0.522 |
|
1977 |
FUNK RL, VOLLHARDT KPC. ChemInform Abstract: IN SITU GENERATION AND INTRAMOLECULAR TRAPPING OF O-XYLYLENES BY COBALT-CATALYZED ACETYLENE COOLIGOMERIZATIONS. A ONE-STEP SYNTHESIS OF POLYCYCLES Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/chin.197701098 |
0.371 |
|
1976 |
Funk RL, Vollhardt KPC. Hexa-1,5-diyn-3-ol ethers as tetramethynyl synthons in cobalt-catalysed acetylene co-oligomerisations; a one-step synthesis of 2,3,6,7- tetrakistrimethylsilylnaphthalene Journal of the Chemical Society, Chemical Communications. 833-834. DOI: 10.1039/C39760000833 |
0.593 |
|
1976 |
Funk RL, Peter K, Vollhardt C. In situ generation and intramolecular trapping of o-xylylenes by cobalt-catalyzed acetylene cooligomerizations. A one-step synthesis of polycycles [43] Journal of the American Chemical Society. 98: 6755-6757. DOI: 10.1021/Ja00437A086 |
0.464 |
|
1975 |
Aalbersberg WGL, Barkovich AJ, Funk RL, Hillard RL, Vollhardt KPC. Transition metal catalyzed acetylene cyclizations. 4,5-Bis(trimethylsilyl)benzocyclobutene, a highly strained, versatile synthetic intermediate [14] Journal of the American Chemical Society. 97: 5600-5602. DOI: 10.1021/Ja00852A057 |
0.341 |
|
1975 |
AALBERSBERG WGL, BARKOVICH AJ, FUNK RL, HILLARD RLI, VOLLHARDT KPC. ChemInform Abstract: TRANSITION METAL CATALYZED ACETYLEN CYCLIZATIONS, 4,5-BIS-(TRIMETHYLSILYL)BENZOCYCLOBUTENE, A HIGHLY STRAINED, VERSATILE SYNTHETIC INTERMEDIATE Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/Chin.197549349 |
0.355 |
|
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