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Alexander Michael Spokoyny, Ph. D. - Publications

Affiliations: 
2014- Chemistry and Biochemistry University of California, Los Angeles, Los Angeles, CA 
Area:
inorganic and organomimetic clusters and assemblies
Website:
http://www.chemistry.ucla.edu/directory/spokoyny-alexander
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68 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Kunkel GE, Treacy JW, Montgomery HR, Puente EG, Doud EA, Spokoyny AM, Maynard HD. Efficient end-group functionalization and diblock copolymer synthesis Au(III) polymer reagents. Chemical Communications (Cambridge, England). 60: 79-82. PMID 38055326 DOI: 10.1039/d3cc05350d  0.515
2022 Montgomery HR, Messina MS, Doud EA, Spokoyny AM, Maynard HD. Organometallic -arylation Reagents for Rapid PEGylation of Biomolecules. Bioconjugate Chemistry. PMID 35939764 DOI: 10.1021/acs.bioconjchem.2c00280  0.676
2021 Bernier NA, Teh J, Reichel D, Zahorsky-Reeves JL, Perez JM, Spokoyny AM. Ex Vivo and In Vivo Evaluation of Dodecaborate-Based Clusters Encapsulated in Ferumoxytol Nanoparticles. Langmuir : the Acs Journal of Surfaces and Colloids. 37: 14500-14508. PMID 34843246 DOI: 10.1021/acs.langmuir.1c02506  0.755
2021 Stevens SL, Phung AC, Gonzalez A, Shao Y, Moully EH, Nguyen VT, Martin JL, Mao C, Saebi A, Mosallaei D, Kirollos M, Chong P, Umanzor A, Qian K, Marin G, ... ... Spokoyny AM, et al. Narratives of Undergraduate Research, Mentorship, and Teaching at UCLA. Pure and Applied Chemistry. Chimie Pure Et Appliquee. 93: 207-221. PMID 33935303 DOI: 10.1515/pac-2020-1007  0.686
2020 Stauber JM, Schwan J, Zhang X, Axtell J, Jung D, McNicholas BJ, Oyala PH, Martinolich AJ, Winkler JR, See KA, Miller TF, Gray HB, Spokoyny AM. A Super-Oxidized Radical Cationic Icosahedral Boron Cluster. Journal of the American Chemical Society. PMID 32646209 DOI: 10.1021/Jacs.0C06159  0.351
2020 Anderson KP, Waddington MA, Balaich GJ, Stauber JM, Bernier NA, Caram JR, Djurovich PI, Spokoyny AM. A molecular boron cluster-based chromophore with dual emission. Dalton Transactions (Cambridge, England : 2003). PMID 32379258 DOI: 10.1039/D0Dt00826E  0.762
2020 Mills HA, Martin J, Rheingold AL, Spokoyny AM. Oxidative Generation of Boron-Centered Radicals in Carboranes. Journal of the American Chemical Society. PMID 32073842 DOI: 10.1021/Jacs.0C00300  0.325
2020 Jung D, Muni M, Marin G, Ramachandran R, El-Kady MF, Balandin T, Kaner RB, Spokoyny AM. Enhancing Cycling Stability of Tungsten Oxide Supercapacitor Electrodes via a Boron Cluster-Based Molecular Cross-Linking Approach Journal of Materials Chemistry. 8: 18015-18023. DOI: 10.1039/D0Ta05915C  0.324
2019 Mu X, Axtell JC, Bernier NA, Kirlikovali KO, Jung D, Umanzor A, Qian K, Chen X, Bay KL, Kirollos M, Rheingold AL, Houk KN, Spokoyny AM. Sterically Unprotected Nucleophilic Boron Cluster Reagents. Chem. 5: 2461-2469. PMID 32292833 DOI: 10.1016/J.Chempr.2019.07.018  0.781
2019 Stauber JM, Qian EA, Han Y, Rheingold AL, Král P, Fujita D, Spokoyny AM. An Organometallic Strategy for Assembling Atomically Precise Hybrid Nanomaterials. Journal of the American Chemical Society. PMID 31782986 DOI: 10.1021/Jacs.9B10770  0.364
2019 Qian EA, Han Y, Messina MS, Maynard HD, Král P, Spokoyny AM. Multivalent Cluster Nanomolecules for Inhibiting Protein-Protein Interactions. Bioconjugate Chemistry. PMID 31498600 DOI: 10.1021/Acs.Bioconjchem.9B00526  0.671
2019 Anderson KP, Mills HA, Mao C, Kirlikovali KO, Axtell JC, Rheingold AL, Spokoyny AM. Improved synthesis of icosahedral carboranes containing exopolyhedral B-C and C-C bonds. Tetrahedron. 75: 187-191. PMID 31303685 DOI: 10.1016/J.Tet.2018.11.040  0.404
2019 Axtell JC, Messina MS, Liu JY, Galaktionova D, Schwan J, Porter TM, Savage MD, Wixtrom AI, Rheingold AL, Kubiak CP, Winkler JR, Gray HB, Král P, Alexandrova AN, Spokoyny AM. Photooxidative Generation of Dodecaborate-Based Weakly Coordinating Anions. Inorganic Chemistry. PMID 31247818 DOI: 10.1021/Acs.Inorgchem.9B00935  0.574
2019 Jung D, Raffan-Montoya F, Ramachandran R, Zhang Y, Islamoglu T, Marin G, Qian EA, Dziedzic RM, Farha OK, Stoliarov SI, Spokoyny AM. Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents. Chemical Communications (Cambridge, England). PMID 31187812 DOI: 10.1039/C9Cc03350E  0.35
2019 Aubry TJ, Axtell JC, Basile VM, Winchell KJ, Lindemuth JR, Porter TM, Liu JY, Alexandrova AN, Kubiak CP, Tolbert SH, Spokoyny AM, Schwartz BJ. Dodecaborane-Based Dopants Designed to Shield Anion Electrostatics Lead to Increased Carrier Mobility in a Doped Conjugated Polymer. Advanced Materials (Deerfield Beach, Fla.). e1805647. PMID 30672037 DOI: 10.1002/Adma.201805647  0.323
2019 Dziedzic RM, Spokoyny AM. Metal-catalyzed cross-coupling chemistry with polyhedral boranes. Chemical Communications (Cambridge, England). 55: 430-442. PMID 30525176 DOI: 10.1039/C8Cc08693A  0.366
2019 Messina MS, Graefe CT, Chong P, Ebrahim OM, Pathuri RS, Bernier NA, Mills HA, Rheingold AL, Frontiera RR, Maynard HD, Spokoyny AM. Carborane RAFT agents as tunable and functional molecular probes for polymer materials Polymer Chemistry. 10: 1660-1667. DOI: 10.1039/C9Py00199A  0.73
2019 Zhang C, Vinogradova EV, Spokoyny AM, Buchwald SL, Pentelute BL. Arylierungschemie für die Biokonjugation Angewandte Chemie. 131: 4860-4892. DOI: 10.1002/Ange.201806009  0.621
2018 Pentelute B, Zhang C, Vinogradova E, Spokoyny A, Buchwald S. Arylation Chemistry for Bioconjugation. Angewandte Chemie (International Ed. in English). PMID 30399206 DOI: 10.1002/Anie.201806009  0.742
2018 Ramachandran R, Jung D, Bernier NA, Logan JK, Waddington MA, Spokoyny AM. Sonochemical Synthesis of Small Boron Oxide Nanoparticles. Inorganic Chemistry. PMID 29939022 DOI: 10.1021/Acs.Inorgchem.8B01189  0.743
2018 Messina MS, Stauber JM, Waddington MA, Rheingold AL, Maynard HD, Spokoyny AM. Organometallic Gold(III) Reagents for Cysteine Arylation. Journal of the American Chemical Society. PMID 29790740 DOI: 10.1021/Jacs.8B04115  0.707
2018 Wixtrom AI, Parvez ZA, Savage MD, Qian EA, Jung D, Khan SI, Rheingold AL, Spokoyny AM. Tuning the electrochemical potential of perfunctionalized dodecaborate clusters through vertex differentiation. Chemical Communications (Cambridge, England). PMID 29785419 DOI: 10.1039/C8Cc03477J  0.341
2018 Jung D, Saleh LAM, Berkson ZJ, El-Kady MF, Hwang JY, Mohamed N, Wixtrom AI, Titarenko E, Shao Y, McCarthy K, Guo J, Martini IB, Kraemer S, Wegener EC, Saint-Cricq P, ... ... Spokoyny AM, et al. A molecular cross-linking approach for hybrid metal oxides. Nature Materials. PMID 29507417 DOI: 10.1038/S41563-018-0021-9  0.32
2018 Axtell JC, Saleh LMA, Qian EA, Wixtrom AI, Spokoyny AM. Synthesis and Applications of Perfunctionalized Boron Clusters. Inorganic Chemistry. PMID 29465227 DOI: 10.1021/Acs.Inorgchem.7B02912  0.336
2018 Kirlikovali KO, Cho E, Downard TJ, Grigoryan L, Han Z, Hong S, Jung D, Quintana JC, Reynoso V, Ro S, Shen Y, Swartz K, Ter Sahakyan E, Wixtrom AI, Yoshida B, ... ... Spokoyny AM, et al. Buchwald-Hartwig amination using Pd(i) dimer precatalysts supported by biaryl phosphine ligands. Dalton Transactions (Cambridge, England : 2003). PMID 29464254 DOI: 10.1039/C8Dt00119G  0.342
2018 Kirlikovali KO, Axtell JC, Anderson K, Djurovich PI, Rheingold AL, Spokoyny AM. Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands Organometallics. 37: 3122-3131. DOI: 10.1021/Acs.Organomet.8B00475  0.372
2017 Dziedzic RM, Martin JL, Axtell JC, Saleh LMA, Ong TC, Yang YF, Messina MS, Rheingold AL, Houk KN, Spokoyny AM. Cage-walking: Vertex Differentiation by Palladium-Catalyzed Isomerization of B(9)-Bromo-meta-Carborane. Journal of the American Chemical Society. PMID 28541671 DOI: 10.1021/Jacs.7B04080  0.533
2017 Qian EA, Wixtrom AI, Axtell JC, Saebi A, Jung D, Rehak P, Han Y, Moully EH, Mosallaei D, Chow S, Messina MS, Wang JY, Royappa AT, Rheingold AL, Maynard HD, ... ... Spokoyny AM, et al. Atomically precise organomimetic cluster nanomolecules assembled via perfluoroaryl-thiol SNAr chemistry. Nature Chemistry. 9: 333-340. PMID 28485398 DOI: 10.1038/Nchem.2686  0.69
2017 Axtell JC, Kirlikovali KO, Jung D, Dziedzic RM, Rheingold AL, Spokoyny AM. Metal-Free Peralkylation of thecloso-Hexaborate Anion Organometallics. 36: 1204-1210. DOI: 10.1021/Acs.Organomet.7B00078  0.363
2017 Axtell JC, Kirlikovali KO, Dziedzic RM, Gembicky M, Rheingold AL, Spokoyny AM. Cover Feature: Magnesium Reagents Featuring a 1,1′-Bis(o -carborane) Ligand Platform (Eur. J. Inorg. Chem. 38-39/2017) European Journal of Inorganic Chemistry. 2017: 4346-4346. DOI: 10.1002/Ejic.201701119  0.308
2017 Axtell JC, Kirlikovali KO, Dziedzic RM, Gembicky M, Rheingold AL, Spokoyny AM. Magnesium Reagents Featuring a 1,1′-Bis(o-carborane) Ligand Platform European Journal of Inorganic Chemistry. 2017: 4411-4416. DOI: 10.1002/Ejic.201700604  0.332
2016 Kirlikovali KO, Axtell JC, Gonzalez A, Phung AC, Khan SI, Spokoyny AM. Luminescent Metal Complexes Featuring Photophysically Innocent Boron Cluster Ligands. Chemical Science. 7: 5132-5138. PMID 28191302 DOI: 10.1039/C6Sc01146B  0.441
2016 Axtell JC, Kirlikovali KO, Djurovich PI, Jung D, Nguyen VT, Munekiyo B, Royappa AT, Rheingold AL, Spokoyny AM. Blue Phosphorescent Zwitterionic Iridium(III) Complexes Featuring Weakly Coordinating nido-Carborane-Based Ligands. Journal of the American Chemical Society. 138: 15758-15765. PMID 27934013 DOI: 10.1021/Jacs.6B10232  0.422
2016 Wixtrom AI, Shao Y, Jung D, Machan CW, Kevork SN, Qian EA, Axtell JC, Khan SI, Kubiak CP, Spokoyny AM. Rapid Synthesis of Redox-Active Dodecaborane B12(OR)12 Clusters Under Ambient Conditions. Inorganic Chemistry Frontiers. 3: 711-717. PMID 27885335 DOI: 10.1039/C5Qi00263J  0.674
2016 Dziedzic RM, Saleh LM, Axtell JC, Martin JL, Stevens SL, Royappa AT, Rheingold AL, Spokoyny AM. B-N, B-O and B-CN Bond Formation via Palladium Catalyzed Cross-Coupling of B-Bromo-Carboranes. Journal of the American Chemical Society. PMID 27384544 DOI: 10.1021/Jacs.6B05505  0.318
2016 Messina MS, Axtell JC, Wang Y, Chong P, Wixtrom AI, Kirlikovali KO, Upton BM, Hunter BM, Shafaat OS, Khan SI, Winkler JR, Gray HB, Alexandrova AN, Maynard HD, Spokoyny AM. Visible Light-Induced Olefin Activation using 3D Aromatic Boron-Rich Cluster Photooxidants. Journal of the American Chemical Society. PMID 27186856 DOI: 10.1021/Jacs.6B03568  0.781
2016 Schwartz JJ, Mendoza AM, Wattanatorn N, Zhao Y, Nguyen VT, Spokoyny AM, Mirkin CA, Base T, Weiss PS. Surface Dipole Control of Liquid Crystal Alignment. Journal of the American Chemical Society. PMID 27090503 DOI: 10.1021/Jacs.6B02026  0.41
2016 Spokoyny A, Saleh L, Dziedzic R, Khan S. Forging Unsupported Metal-Boryl Bonds with Icosahedral Carboranes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27017293 DOI: 10.1002/Chem.201601292  0.329
2016 Kirlikovali KO, Axtell JC, Gonzalez A, Phung AC, Khan SI, Spokoyny AM. Luminescent metal complexes featuring photophysically innocent boron cluster ligands Chemical Science. 7: 5132-5138. DOI: 10.1039/c6sc01146b  0.334
2016 Wixtrom AI, Shao Y, Jung D, Machan CW, Kevork SN, Qian EA, Axtell JC, Khan SI, Kubiak CP, Spokoyny AM. Rapid synthesis of redox-active dodecaborane B12(OR)12 clusters under ambient conditions Inorganic Chemistry Frontiers. 3: 711-717. DOI: 10.1039/c5qi00263j  0.648
2015 Vinogradova EV, Zhang C, Spokoyny AM, Pentelute BL, Buchwald SL. Organometallic palladium reagents for cysteine bioconjugation. Nature. 526: 687-91. PMID 26511579 DOI: 10.1038/Nature15739  0.758
2015 Thomas JC, Schwartz JJ, Hohman JN, Claridge SA, Auluck HS, Serino AC, Spokoyny AM, Tran G, Kelly KF, Mirkin CA, Gilles J, Osher SJ, Weiss PS. Defect-Tolerant Aligned Dipoles within Two-Dimensional Plastic Lattices. Acs Nano. 9: 4734-42. PMID 25867638 DOI: 10.1021/Acsnano.5B01329  0.405
2014 Zhang C, Dai P, Spokoyny AM, Pentelute BL. Enzyme-catalyzed macrocyclization of long unprotected peptides. Organic Letters. 16: 3652-5. PMID 25002256 DOI: 10.1021/Ol501609Y  0.616
2014 Simon MD, Heider PL, Adamo A, Vinogradov AA, Mong SK, Li X, Berger T, Policarpo RL, Zhang C, Zou Y, Liao X, Spokoyny AM, Jensen KF, Pentelute BL. Rapid flow-based peptide synthesis. Chembiochem : a European Journal of Chemical Biology. 15: 713-20. PMID 24616230 DOI: 10.1002/Cbic.201300796  0.617
2014 Zou Y, Spokoyny AM, Zhang C, Simon MD, Yu H, Lin YS, Pentelute BL. Convergent diversity-oriented side-chain macrocyclization scan for unprotected polypeptides. Organic & Biomolecular Chemistry. 12: 566-73. PMID 24310320 DOI: 10.1039/C3Ob42168F  0.64
2013 Spokoyny AM. New ligand platforms featuring boron-rich clusters as organomimetic substituents(.) Pure and Applied Chemistry. Chimie Pure Et Appliquee. 85. PMID 24311823 DOI: 10.1351/Pac-Con-13-01-13  0.383
2013 Zhang C, Spokoyny AM, Zou Y, Simon MD, Pentelute BL. Enzymatic "click" ligation: selective cysteine modification in polypeptides enabled by promiscuous glutathione S-transferase. Angewandte Chemie (International Ed. in English). 52: 14001-5. PMID 24222025 DOI: 10.1002/Anie.201306430  0.623
2013 Lifschitz AM, Shade CM, Spokoyny AM, Mendez-Arroyo J, Stern CL, Sarjeant AA, Mirkin CA. Boron-dipyrromethene-functionalized hemilabile ligands as "turn-on" fluorescent probes for coordination changes in weak-link approach complexes. Inorganic Chemistry. 52: 5484-92. PMID 23570551 DOI: 10.1021/Ic400383T  0.745
2013 Spokoyny AM, Zou Y, Ling JJ, Yu H, Lin YS, Pentelute BL. A perfluoroaryl-cysteine S(N)Ar chemistry approach to unprotected peptide stapling. Journal of the American Chemical Society. 135: 5946-9. PMID 23560559 DOI: 10.1021/Ja400119T  0.597
2012 Spokoyny AM, Lewis CD, Teverovskiy G, Buchwald SL. Extremely Electron-Rich, Boron-Functionalized, Icosahedral Carborane-Based Phosphinoboranes. Organometallics. 31: 8478-8481. PMID 23667288 DOI: 10.1021/Om301116X  0.777
2011 Spokoyny AM, Machan CW, Clingerman DJ, Rosen MS, Wiester MJ, Kennedy RD, Stern CL, Sarjeant AA, Mirkin CA. A coordination chemistry dichotomy for icosahedral carborane-based ligands. Nature Chemistry. 3: 590-6. PMID 21778977 DOI: 10.1038/Nchem.1088  0.748
2011 Machan CW, Spokoyny AM, Jones MR, Sarjeant AA, Stern CL, Mirkin CA. Plasticity of the nickel(II) coordination environment in complexes with hemilabile phosphino thioether ligands. Journal of the American Chemical Society. 133: 3023-33. PMID 21319748 DOI: 10.1021/Ja109624M  0.756
2011 Rosen MS, Spokoyny AM, Machan CW, Stern C, Sarjeant A, Mirkin CA. Chelating effect as a driving force for the selective formation of heteroligated Pt(II) complexes with bidentate phosphino-chalcoether ligands. Inorganic Chemistry. 50: 1411-9. PMID 21189032 DOI: 10.1021/Ic101973S  0.794
2011 Pandey P, Farha OK, Spokoyny AM, Mirkin CA, Kanatzidis MG, Hupp JT, Nguyen ST. A "click-based" porous organic polymer from tetrahedral building blocks Journal of Materials Chemistry. 21: 1700-1703. DOI: 10.1039/C0Jm03483E  0.42
2011 Li TC, Fabregat-Santiago F, Farha OK, Spokoyny AM, Raga SR, Bisquert J, Mirkin CA, Marks TJ, Hupp JT. SiO2 aerogel templated, porous TiO2 photoanodes for enhanced performance in dye-sensitized solar cells containing a Ni(III)/(IV) Bis(dicarbollide) shuttle Journal of Physical Chemistry C. 115: 11257-11264. DOI: 10.1021/Jp112139H  0.442
2011 Li TC, Spokoyny AM, She C, Farha OK, Mirkin CA, Marks TJ, Hupp JT. Erratum: Ni(III)/(IV) Bis(dicarbollide) as a fast, noncorrosive redox shuttle for dye-sensitized solar cells (Journal of the American Chemical Society (2010) 132 (4580-4582)) Journal of the American Chemical Society. 133. DOI: 10.1021/Ja201960H  0.415
2010 Spokoyny AM, Li TC, Farha OK, Machan CW, She C, Stern CL, Marks TJ, Hupp JT, Mirkin CA. Electronic tuning of nickel-based bis(dicarbollide) redox shuttles in dye-sensitized solar cells. Angewandte Chemie (International Ed. in English). 49: 5339-43. PMID 20586090 DOI: 10.1002/Anie.201002181  0.688
2010 Bae YS, Spokoyny AM, Farha OK, Snurr RQ, Hupp JT, Mirkin CA. Separation of gas mixtures using Co(II) carborane-based porous coordination polymers. Chemical Communications (Cambridge, England). 46: 3478-80. PMID 20405064 DOI: 10.1039/B927499E  0.455
2010 Li TC, Spokoyny AM, She C, Farha OK, Mirkin CA, Marks TJ, Hupp JT. Ni(III)/(IV) bis(dicarbollide) as a fast, noncorrosive redox shuttle for dye-sensitized solar cells. Journal of the American Chemical Society. 132: 4580-2. PMID 20230034 DOI: 10.1021/Ja100396N  0.451
2010 Farha OK, Bae YS, Hauser BG, Spokoyny AM, Snurr RQ, Mirkin CA, Hupp JT. Chemical reduction of a diimide based porous polymer for selective uptake of carbon dioxide versus methane. Chemical Communications (Cambridge, England). 46: 1056-8. PMID 20126711 DOI: 10.1039/B922554D  0.444
2010 Spokoyny AM, Rosen MS, Ulmann PA, Stern C, Mirkin CA. Selective formation of heteroligated Pt(II) complexes with bidentate phosphine-thioether (P,S) and phosphine-Selenoether (P,Se) ligands via the halide-induced ligand rearrangement reaction. Inorganic Chemistry. 49: 1577-86. PMID 20095594 DOI: 10.1021/Ic901991W  0.776
2010 Spokoyny AM, Farha OK, Mulfort KL, Hupp JT, Mirkin CA. Porosity tuning of carborane-based metal-organic frameworks (MOFs) via coordination chemistry and ligand design Inorganica Chimica Acta. 364: 266-271. DOI: 10.1016/J.Ica.2010.08.007  0.534
2009 Spokoyny AM, Reuter MG, Stern CL, Ratner MA, Seideman T, Mirkin CA. Carborane-based pincers: synthesis and structure of SeBSe and SBS Pd(II) complexes. Journal of the American Chemical Society. 131: 9482-3. PMID 19583431 DOI: 10.1021/Ja902526K  0.508
2009 Spokoyny AM, Kim D, Sumrein A, Mirkin CA. Infinite coordination polymer nano- and microparticle structures. Chemical Society Reviews. 38: 1218-27. PMID 19384433 DOI: 10.1039/B807085G  0.483
2009 Farha OK, Spokoyny AM, Mulfort KL, Galli S, Hupp JT, Mirkin CA. Gas-sorption properties of cobalt(II)--carborane-based coordination polymers as a function of morphology. Small (Weinheim An Der Bergstrasse, Germany). 5: 1727-31. PMID 19367598 DOI: 10.1002/Smll.200900085  0.455
2009 Farha OK, Spokoyny AM, Hauser BG, Bae YS, Brown SE, Snurr RQ, Mirkin CA, Hupp JT. Synthesis, properties, and gas separation studies of a robust diimide-based microporous organic polymer Chemistry of Materials. 21: 3033-3035. DOI: 10.1021/Cm901280W  0.443
2008 Bae YS, Farha OK, Spokoyny AM, Mirkin CA, Hupp JT, Snurr RQ. Carborane-based metal-organic frameworks as highly selective sorbents for CO(2) over methane. Chemical Communications (Cambridge, England). 4135-7. PMID 18802507 DOI: 10.1039/B805785K  0.426
2007 Farha OK, Spokoyny AM, Mulfort KL, Hawthorne MF, Mirkin CA, Hupp JT. Synthesis and hydrogen sorption properties of carborane based metal-organic framework materials. Journal of the American Chemical Society. 129: 12680-1. PMID 17900124 DOI: 10.1021/Ja076167A  0.561
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