Thomas Braun - Publications

Affiliations: 
Humboldt-Universität zu Berlin, Berlin, Germany 

147 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Heinekamp C, Buzanich AG, Ahrens M, Braun T, Emmerling F. An amorphous Lewis-acidic zirconium chlorofluoride as HF shuttle: C-F bond activation and formation. Chemical Communications (Cambridge, England). 59: 11224-11227. PMID 37655607 DOI: 10.1039/d3cc03164k  0.306
2022 Sander S, Braun T. Platinum-Catalyzed Hydrofluorination of Alkynes: Hydrogen Bonding to Indolylphosphine Ligands to Provide Fluoride Reactivity. Angewandte Chemie (International Ed. in English). PMID 35420731 DOI: 10.1002/anie.202204678  0.323
2022 Talavera M, Braun T. Competing C-H and C-F bond activation reactions of a fluorinated olefin at Rh: a fluorido vinylidene complex as an intermediate in an unprecedented dehydrofluorination step. Chemical Science. 13: 1130-1135. PMID 35211279 DOI: 10.1039/d1sc06713c  0.327
2021 Rachor SG, Müller R, Wittwer P, Kaupp M, Braun T. Synthesis, Reactivity, and Bonding of Gold(I) Fluorido-Phosphine Complexes. Inorganic Chemistry. PMID 34913690 DOI: 10.1021/acs.inorgchem.1c02959  0.328
2021 Braun T, Talavera M. Versatile Reaction Pathways of 1,1,3,3,3-pentafluoropropene at Rh(I) complexes [Rh(E)(PEt3)3] (E = H, GePh3, Si(OEt)3, F, Cl): C-F versus C-H Bond Activation Steps. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 34118095 DOI: 10.1002/chem.202101508  0.355
2020 Talavera M, Hinze S, Braun T, Laubenstein R, Herrmann R. A SF Derivative of Triphenylphosphine as an Electron-Poor Ligand Precursor for Rh and Ir Complexes. Molecules (Basel, Switzerland). 25. PMID 32882799 DOI: 10.3390/Molecules25173977  0.322
2020 Talavera M, Meißner G, Rachor SG, Braun T. C-F activation reactions at germylium ions: dehydrofluorination of fluoralkanes. Chemical Communications (Cambridge, England). PMID 32196045 DOI: 10.1039/D0Cc01420F  0.345
2020 Braun T, Talavera M. Rhodium(I) Complexes as Useful Tools for the Activation of Fluoroolefins Synlett. 31: 1760-1774. DOI: 10.1055/S-0040-1707156  0.34
2020 Pfister N, Bui M, Braun T, Wittwer P, Ahrens M. Synthesis and Reactivity of Iridium(I) Fluorido Complexes: Oxidative Addition of SF 4 at trans ‐[Ir(F)(CO)(PEt 3 ) 2 ] Zeitschrift FüR Anorganische Und Allgemeine Chemie. 646: 808-815. DOI: 10.1002/Zaac.202000026  0.39
2019 Braun T, Dirican D, Pfister N, Wozniak M. Reactivity of binary and ternary sulfur halides towards transition metal compounds. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31840851 DOI: 10.1002/Chem.201904493  0.349
2019 Aoki Y, Bauer M, Braun T, Cadge J, Davies D, Durand DJ, Eisenstein O, Ess D, Fairlamb I, Fey N, Gallarati S, George M, Greaves M, Halse M, Hamilton A, et al. Physical methods for mechanistic understanding: general discussion. Faraday Discussions. PMID 31755887 DOI: 10.1039/C9Fd90070E  0.559
2019 Aoki Y, Braun T, Davies D, Eisenstein O, Fairlamb I, Fey N, George M, Goult C, Hamilton A, Huang Z, Ishii Y, Jakoobi M, Kuwata S, Lloyd-Jones G, Love J, et al. Understanding unusual element-element bond formation and activation: general discussion. Faraday Discussions. PMID 31755882 DOI: 10.1039/C9Fd90071C  0.595
2019 Aoki Y, Bauer M, Braun T, Cadge JA, Clarke GE, Durand DJ, Eisenstein O, Gallarati S, Greaves M, Harvey J, Haynes A, Hintermair U, Hulme AN, Ishii Y, Jakoobi M, et al. Mechanistic insight into organic and industrial transformations: general discussion. Faraday Discussions. PMID 31754665 DOI: 10.1039/C9Fd90072A  0.457
2019 Xu C, Talavera M, Sander S, Braun T. C-H and C-F bond activation reactions of pentafluorostyrene at rhodium complexes. Dalton Transactions (Cambridge, England : 2003). PMID 31617524 DOI: 10.1039/C9Dt03371H  0.477
2019 Talavera M, Müller R, Ahrens T, von Hahmann CN, Braun-Cula B, Kaupp M, Braun T. Activation of tetrafluoropropenes by rhodium(i) germyl and silyl complexes. Faraday Discussions. PMID 31538175 DOI: 10.1039/C9Fd00059C  0.421
2019 Braun T, Talavera M, von Hahmann C, Müller R, Ahrens M, Kaupp M. C-H and C-F Bond Activation Reactions of Fluorinated Propenes at Rhodium: Distinctive Reactivity of the Refrigerant HFO-1234yf. Angewandte Chemie (International Ed. in English). PMID 31102565 DOI: 10.1002/Anie.201902872  0.43
2019 Marshall CP, Scholz G, Braun T, Kemnitz E. Nb-doped variants of high surface aluminium fluoride: a very strong bi-acidic solid catalyst. Dalton Transactions (Cambridge, England : 2003). PMID 31020287 DOI: 10.1039/C9Dt00831D  0.335
2019 Torres Ò, Pfister N, Braun T, Wittwer P. C-F activation of perfluorophenazine at nickel: selectivity and mechanistic investigations. Dalton Transactions (Cambridge, England : 2003). PMID 30916690 DOI: 10.1039/C9Dt00780F  0.486
2019 Braun T, Kaupp M, Roesch P, Müller R, Dallmann A, Scholz G, Braun-Cula B, Wittwer P. A Silylene-Borane Lewis Pair as a Tool for Trapping a Water Molecule: Silanol Formation and Dehydrogenation. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30724403 DOI: 10.1002/Chem.201900481  0.337
2019 Kervarec M, Marshall CP, Braun T, Kemnitz E. Selective dehydrofluorination of 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) to 2-chloro-3,3,3-trifluoropropene (HFO-1233xf) using nanoscopic aluminium fluoride catalysts at mild conditions Journal of Fluorine Chemistry. 221: 61-65. DOI: 10.1016/J.Jfluchem.2019.04.001  0.362
2018 Baumgarth H, Meier G, von Hahmann CN, Braun T. Reactivity of rhodium and iridium peroxido complexes towards hydrogen in the presence of B(CF) or [H(OEt)][B{3,5-(CF)CH}]. Dalton Transactions (Cambridge, England : 2003). PMID 30403233 DOI: 10.1039/C8Dt03853H  0.393
2018 Tomar P, Braun T, Kemnitz E. Photochemical activation of SF by N-heterocyclic carbenes to provide a deoxyfluorinating reagent. Chemical Communications (Cambridge, England). PMID 30109328 DOI: 10.1039/C8Cc05494K  0.314
2018 Ellwanger MA, von Randow C, Steinhauer S, Zhou Y, Wiesner A, Beckers H, Braun T, Riedel S. Tuning the Lewis acidity of difluorido gold(iii) complexes: the synthesis of [AuClF(SIMes)] and [AuF(OTeF)(SIMes)]. Chemical Communications (Cambridge, England). PMID 30070660 DOI: 10.1039/C8Cc05233F  0.355
2018 von Hahmann C, Talavera M, Xu C, Braun T. Reactivity of 3,3,3-Trifluoropropyne at Rhodium Complexes: Development of Hydroboration Reactions. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29791749 DOI: 10.1002/Chem.201801662  0.405
2018 Hasenstab-Riedel S, Ellwanger M, Steinhauer S, Golz P, Braun T. Stabilization of Lewis Acidic AuF3 as Carbene Complex: Preparation and Characterization of [AuF3(SIMes)]. Angewandte Chemie (International Ed. in English). PMID 29645333 DOI: 10.1002/Anie.201802952  0.421
2018 Braun T, Berg C, Pfister N, Braun-Cula B. Diverse Reactivity of Platinum SF3 and SF2 Complexes Towards EtOH and Me3SiOEt. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29524283 DOI: 10.1002/Chem.201800503  0.393
2018 Mebs S, Kalläne SI, Braun T. Hapticity of asymmetric rhodium-allyl compounds in the light of real-space bonding indicators Zeitschrift FüR Kristallographie - Crystalline Materials. 233: 615-626. DOI: 10.1515/Zkri-2017-2141  0.404
2018 Wozniak M, Braun T, Ahrens M, Braun-Cula B, Wittwer P, Herrmann R, Laubenstein R. Activation of SF6at a Xantphos-Type Rhodium Complex Organometallics. 37: 821-828. DOI: 10.1021/Acs.Organomet.7B00858  0.416
2018 Raza AL, Kuehnel MF, Talavera M, Teltewskoi M, Ahrens M, Kläring P, Braun T, Lentz D. Reactivity of rhodium hydrido and silyl complexes towards 1,1-difluoroallene Journal of Fluorine Chemistry. 214: 80-85. DOI: 10.1016/J.Jfluchem.2018.08.002  0.421
2018 Pfister N, Braun T, Wittwer P, Ahrens M. Selective Formation and Characterization of a RhIII Difluorido λ4 -Trifluorosulfanyl Complex Zeitschrift FüR Anorganische Und Allgemeine Chemie. 644: 1064-1070. DOI: 10.1002/Zaac.201800323  0.352
2017 Braun T, Meißner G, Kemnitz E, Kretschmar K. Consecutive Transformations of Tetrafluoropropenes: Hydrogermylation and Catalytic C-F Activation Steps at a Lewis-acidic Aluminium Fluoride. Angewandte Chemie (International Ed. in English). PMID 28981989 DOI: 10.1002/Anie.201707759  0.415
2017 Hasenstab-Riedel S, Mathias EA, Steinhauer S, Wiesner A, Golz P, Beckers H, Braun T, Braun-Cula B. Taming the High Reactivity of Gold(III) Fluoride: Fluorido Gold(III) Complexes with N-based Ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28759145 DOI: 10.1002/Chem.201702663  0.357
2017 Braun T, Roesch P, Warzok U, Enke M, Müller R, Schattenberg C, Schalley C, Kaupp M, Wittwer P. Reactivity of the Sterically Demanding Siloxanediol Mes2Si(OH)(µ-O)Si(OH)Mes2 Towards Water and Ether Molecules. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28755523 DOI: 10.1002/Chem.201702393  0.313
2017 Braun T, Berger J, Ahrens T, Kläring P, Laubenstein R, Braun-Cula B. The Versatile Behavior of Platinum Alkyne Complexes Towards XeF2: Formation of Fluorovinyl and Fluorido Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28472555 DOI: 10.1002/Chem.201700403  0.416
2017 Berg C, Braun T, Ahrens M, Wittwer P, Herrmann R. Activation of SF6 at Platinum Complexes: Formation of SF3 Derivatives and their Application in Deoxyfluorination Reactions. Angewandte Chemie (International Ed. in English). PMID 28319294 DOI: 10.1002/Anie.201612417  0.471
2017 Braun T, Kohlmann J, Laubenstein R, Herrmann R. Suzuki-Miyaura Cross-Coupling Reactions of Highly Fluorinated Arylboronic Esters: Catalytic Studies and Stoichiometric Model Reactions on the Transmetallation Step. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28295723 DOI: 10.1002/Chem.201700549  0.435
2017 Meißner G, Dirican D, Jäger C, Braun T, Kemnitz E. Et3GeH versus Et3SiH: controlling reaction pathways in catalytic C–F bond activations at a nanoscopic aluminum chlorofluoride Catalysis Science & Technology. 7: 3348-3354. DOI: 10.1039/C7Cy00845G  0.347
2017 Meißner G, Feist M, Braun T, Kemnitz E. Selective reduction of a C Cl bond in halomethanes with Et3GeH at nanoscopic Lewis acidic Aluminium fluoride Journal of Organometallic Chemistry. 847: 234-241. DOI: 10.1016/J.Jorganchem.2017.04.030  0.412
2017 Kohlmann J, Braun T. Synthesis and reactivity of a cationic palladium complex as possible intermediate in a Suzuki-Miyaura cross-coupling reaction Journal of Fluorine Chemistry. 203: 140-145. DOI: 10.1016/J.Jfluchem.2017.08.003  0.434
2017 Laubenstein R, Ahrens M, Braun T. Front Cover: Synthesis and Structures of Gallium-β-Diketiminate Complexes: Isolation of a Dinuclear Gallium(II) Complex (Z. Anorg. Allg. Chem. 22/2017) Zeitschrift FüR Anorganische Und Allgemeine Chemie. 643: 1721-1721. DOI: 10.1002/Zaac.201770221  0.342
2017 Laubenstein R, Ahrens M, Braun T. Synthesis and Structures of Gallium-β-Diketiminate Complexes: Isolation of a Dinuclear Gallium(II) Complex Zeitschrift FüR Anorganische Und Allgemeine Chemie. 643: 1723-1729. DOI: 10.1002/Zaac.201700276  0.42
2017 Ahrens T, Schmiedecke B, Braun T, Herrmann R, Laubenstein R. Activation of CS2and COS at a Rhodium(I) Germyl Complex: Generation of CS and Carbido Complexes European Journal of Inorganic Chemistry. 2017: 713-722. DOI: 10.1002/Ejic.201601122  0.359
2017 Calvo B, Braun T, Kemnitz E. Hydrogen/Deuterium-Exchange Reactions of Methane with Aromatics and Cyclohexane Catalyzed by a Nanoscopic Aluminum Chlorofluoride Chemcatchem. 10: 403-406. DOI: 10.1002/Cctc.201701327  0.333
2017 Siwek AK, Ahrens M, Feist M, Braun T, Kemnitz E. Activation of Chlorinated Methanes at the Surface of Nanoscopic Lewis Acidic Aluminum Fluorides Chemcatchem. 9: 839-845. DOI: 10.1002/Cctc.201601238  0.406
2016 Ahrens T, Teltewskoi M, Ahrens M, Braun T, Laubenstein R. Competing reaction pathways of 3,3,3-trifluoropropene at rhodium hydrido, silyl and germyl complexes: C-F bond activation versus hydrogermylation. Dalton Transactions (Cambridge, England : 2003). PMID 27739544 DOI: 10.1039/C6Dt03027K  0.482
2016 Mitzenheim C, Braun T, Laubenstein R, Braun B, Herrmann R. Hydrodealkoxylation reactions of silyl ligands at platinum: reactivity of SiH3 and SiH2Me complexes. Dalton Transactions (Cambridge, England : 2003). 45: 6394-404. PMID 26948049 DOI: 10.1039/C5Dt04923G  0.42
2016 Berg C, Braun T, Laubenstein R, Braun B. Palladium-mediated borylation of pentafluorosulfanyl functionalized compounds: the crucial role of metal fluorido complexes. Chemical Communications (Cambridge, England). 52: 3931-4. PMID 26872070 DOI: 10.1039/C5Cc10219G  0.392
2016 Ahrens T, Ahrens M, Braun T, Braun B, Herrmann R. Synthesis of a rhodium(i) germyl complex: a useful tool for C-H and C-F bond activation reactions. Dalton Transactions (Cambridge, England : 2003). 45: 4716-28. PMID 26863494 DOI: 10.1039/C5Dt04845A  0.479
2016 Baumgarth H, Meier G, Braun T, Braun-Cula B. Front Cover: Rhodium and Iridium Fluorido and Bifluorido Complexes Derived from Peroxido Precursors (Eur. J. Inorg. Chem. 28/2016) European Journal of Inorganic Chemistry. 2016: 4532. DOI: 10.1002/Ejic.201670281  0.381
2016 Baumgarth H, Meier G, Braun T, Braun-Cula B. Rhodium and Iridium Fluorido and Bifluorido Complexes Derived from Peroxido Precursors European Journal of Inorganic Chemistry. 2016: 4565-4572. DOI: 10.1002/Ejic.201601152  0.35
2016 Baumgarth H, Meier G, Braun T, Braun-Cula B. Rhodium and Iridium Fluorido and Bifluorido Complexes Derived from Peroxido Precursors: Rhodium and Iridium Fluorido and Bifluorido Complexes Derived from Peroxido Precursors European Journal of Inorganic Chemistry. 2016: 4565-4572. DOI: 10.1002/Ejic.201600682  0.39
2016 Herrmann R, Wittwer P, Braun T. Platinum Complexes Bearing a Tripodal Germyl Ligand European Journal of Inorganic Chemistry. DOI: 10.1002/Ejic.201600652  0.418
2016 Kalläne SI, Laubenstein R, Braun T, Dietrich M. Activation of Si-Si and Si-H Bonds at a Platinum Bis(diphenylphosphanyl)ferrocene (dppf) Complex: Key Steps for the Catalytic Hydrogenolysis of Disilanes European Journal of Inorganic Chemistry. 2016: 530-537. DOI: 10.1002/Ejic.201501210  0.393
2016 Calvo B, Wuttke J, Braun T, Kemnitz E. Heterogeneous Catalytic Hydroarylation of Olefins at a Nanoscopic Aluminum Chlorofluoride Chemcatchem. 8: 1945-1950. DOI: 10.1002/Cctc.201600257  0.395
2015 Berger J, Braun T, Herrmann R, Braun B. Reactivity of platinum alkyne complexes towards N-fluorobenzenesulfonimide: formation of platinum compounds bearing a β-fluorovinyl ligand. Dalton Transactions (Cambridge, England : 2003). PMID 26308149 DOI: 10.1039/C5Dt02306H  0.367
2015 Kalläne SI, Braun T, Teltewskoi M, Braun B, Herrmann R, Laubenstein R. Remarkable reactivity of a rhodium(I) boryl complex towards CO2 and CS2: isolation of a carbido complex. Chemical Communications (Cambridge, England). 51: 14613-6. PMID 26288856 DOI: 10.1039/C5Cc05606C  0.424
2015 Zámostná L, Braun T. Catalytic Degradation of Sulfur Hexafluoride by Rhodium Complexes. Angewandte Chemie (International Ed. in English). 54: 10652-6. PMID 26190201 DOI: 10.1002/Anie.201505462  0.376
2015 Bittner A, Braun T, Herrmann R, Mebs S. Rhodium-Mediated Oxygenation of Nitriles with Dioxygen: Isolation of Rhodium Derivatives of Peroxyimidic Acids. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 12299-302. PMID 26190065 DOI: 10.1002/Chem.201502481  0.374
2015 Zámostná L, Sander S, Braun T, Laubenstein R, Braun B, Herrmann R, Kläring P. Synthesis and structure of rhodium(i) silyl carbonyl complexes: photochemical C-F and C-H bond activation of fluorinated aromatic compounds. Dalton Transactions (Cambridge, England : 2003). 44: 9450-69. PMID 25915856 DOI: 10.1039/C5Dt00819K  0.478
2015 Chilleck MA, Hartenstein L, Braun T, Roesky PW, Braun B. Cationic zinc organyls as precatalysts for hydroamination reactions. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 2594-602. PMID 25522205 DOI: 10.1002/Chem.201405662  0.487
2015 Ahrens T, Kohlmann J, Ahrens M, Braun T. Functionalization of fluorinated molecules by transition-metal-mediated C-F bond activation to access fluorinated building blocks. Chemical Reviews. 115: 931-72. PMID 25347593 DOI: 10.1021/Cr500257C  0.344
2015 Raza AL, Braun T. Consecutive C-F bond activation and C-F bond formation of heteroaromatics at rhodium: The peculiar role of FSi(OEt)<inf>3</inf> Chemical Science. 6: 4255-4260. DOI: 10.1039/c5sc00877h  0.327
2015 Kalläne SI, Teltewskoi M, Braun T, Braun B. C-H and C-F Bond Activations at a Rhodium(I) Boryl Complex: Reaction Steps for the Catalytic Borylation of Fluorinated Aromatics Organometallics. 34: 1156-1169. DOI: 10.1021/Om500952X  0.478
2015 Liebau F, Braun T, Braun B. Dehydrogenation of cycloalkanes at rhodium complexes bearing fluorinated cyclopentadienyl ligands Journal of Fluorine Chemistry. 180: 192-200. DOI: 10.1016/J.Jfluchem.2015.09.014  0.419
2015 Baumgarth H, Braun T, Braun B, Laubenstein R, Herrmann R. Synthesis of an Iridium Peroxido Complex and Its Reactivity Towards Brønsted Acids European Journal of Inorganic Chemistry. 2015: 3157-3168. DOI: 10.1002/Ejic.201500384  0.385
2014 Kalläne SI, Braun T. Catalytic borylation of SCF₃-functionalized arenes by rhodium(I) boryl complexes: regioselective C-H activation at the ortho-position. Angewandte Chemie (International Ed. in English). 53: 9311-5. PMID 25088814 DOI: 10.1002/Anie.201406424  0.421
2014 Kalläne SI, Braun T, Braun B, Mebs S. Versatile reactivity of a rhodium(I) boryl complex towards ketones and imines. Dalton Transactions (Cambridge, England : 2003). 43: 6786-801. PMID 24647920 DOI: 10.1039/C4Dt00080C  0.379
2014 Zámostná L, Braun T, Braun B. S ? F and S ? C Activation of SF6 and SF5 Derivatives at Rhodium: Conversion of SF6 into H2S Angewandte Chemie. 53: 2745-2749. PMID 24453166 DOI: 10.1002/Anie.201308254  0.382
2014 Chilleck MA, Braun T, Braun B, Mebs S. Neutral and Cationic Zinc Complexes with N- and S-Donor-Functionalized Cyclopentadienyl Ligands Organometallics. 33: 551-560. DOI: 10.1021/Om401076G  0.402
2014 Herrmann R, Braun T, Mebs S. [Ge(H)(2-C6H4PPh2)3] as Ligand Precursor at Ruthenium: Formation and Reactivity of [Ru(Cl){Ge(2-C6H4PPh2)3}] European Journal of Inorganic Chemistry. 2014: 4826-4835. DOI: 10.1002/Ejic.201402256  0.437
2013 Rábay B, Braun T, Falkenhagen JP. Photolytic C-H activation and dehydrogenation of alkanes at cyclopentadienyl iridium complexes in a perfluorinated solvent. Dalton Transactions (Cambridge, England : 2003). 42: 8058-65. PMID 23571648 DOI: 10.1039/C3Dt33022B  0.398
2013 Kuehnel MF, Lentz D, Braun T. Synthesis of fluorinated building blocks by transition-metal-mediated hydrodefluorination reactions. Angewandte Chemie (International Ed. in English). 52: 3328-48. PMID 23355490 DOI: 10.1002/Anie.201205260  0.634
2013 Voigt J, Chilleck MA, Braun T. Activation of Si-Si and Si-H bonds at Pt: a catalytic hydrogenolysis of silicon-silicon bonds. Dalton Transactions (Cambridge, England : 2003). 42: 4052-8. PMID 23340919 DOI: 10.1039/C3Dt32530J  0.363
2013 Raza AL, Panetier JA, Teltewskoi M, Macgregor SA, Braun T. Rhodium(I) silyl complexes for C-F bond activation reactions of aromatic compounds: Experimental and computational studies Organometallics. 32: 3795-3807. DOI: 10.1021/Om400150P  0.421
2013 Chilleck MA, Braun T, Herrmann R, Braun B. Zinc Complexes with the N-Donor-Functionalized Cyclopentadienyl Ligand C5Me4(CH2)2NMe2 Organometallics. 32: 1067-1074. DOI: 10.1021/Om301181E  0.414
2013 Zámostná L, Ahrens M, Braun T. Catalytic hydrodefluorination of fluoroaromatics with silanes as hydrogen source at a binuclear rhodium complex: Characterization of key intermediates Journal of Fluorine Chemistry. 155: 132-142. DOI: 10.1016/J.Jfluchem.2013.05.021  0.486
2013 Ahrens T, Braun T, Braun B. Activation of 1, 2-Dihydrodisilanes at Platinum(0) Phosphine Complexes: Syntheses and Structures of Bissilyl Platinum(II) Complexes Zeitschrift FüR Anorganische Und Allgemeine Chemie. 640: 93-99. DOI: 10.1002/Zaac.201300451  0.454
2013 Teltewskoi M, Kalläne SI, Braun T, Herrmann R. Synthesis of Rhodium(I) Boryl Complexes: Catalytic N-H Activation of Anilines and Ammonia European Journal of Inorganic Chemistry. 2013: 5762-5768. DOI: 10.1002/Ejic.201300972  0.401
2013 Eiβler A, Kläring P, Emmerling F, Braun T. α-Dialdimine Complexes of Rhodium(I) and Iridium(I): Their Reactivity with Dioxygen and Dihydrogen European Journal of Inorganic Chemistry. 2013: 4775-4788. DOI: 10.1002/Ejic.201300625  0.379
2013 Kläring P, Braun T. Insertion of CS2into Iridium-Fluorine Bonds Angewandte Chemie International Edition. 52: 11096-11101. DOI: 10.1002/Anie.201305106  0.408
2012 Meier G, Braun T. Hydrogenation of a rhodium peroxido complex by formate derivatives: mechanistic studies and the catalytic formation of H2O2 from O2. Angewandte Chemie (International Ed. in English). 51: 12564-9. PMID 23125187 DOI: 10.1002/Anie.201207073  0.356
2012 Jungton AK, Herwig C, Braun T, Limberg C. Activation and coordination of ammonia at [Cp*Ir(H)2]: NMR and matrix isolation studies. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 10009-13. PMID 22782696 DOI: 10.1002/Chem.201201295  0.354
2012 Chilleck MA, Braun T, Braun B. Cationic cyclopentadienyl zinc complexes with slipped triple-decker and half-sandwich structures. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 12902-5. PMID 22167877 DOI: 10.1002/Chem.201102699  0.342
2012 Breyer D, Braun T, Kläring P. Synthesis and Reactivity of the Fluoro Complex trans-[Pd(F)(4-C5NF4)(iPr2PCH2CH2OCH3)2]: C–F Bond Formation and Catalytic C–F Bond Activation Reactions Organometallics. 31: 1417-1424. DOI: 10.1021/Om200998D  0.361
2012 Breyer D, Berger J, Braun T, Mebs S. Nickel fluoro complexes as intermediates in catalytic cross-coupling reactions Journal of Fluorine Chemistry. 143: 263-271. DOI: 10.1016/J.Jfluchem.2012.06.025  0.413
2012 Jungton A, Kläring P, Braun T, Eißler A. Synthesis, Reactivity and Structures of Iridium Tetrafluoropyridyl Complexes: Ammonia Coordination and Activation Zeitschrift FüR Anorganische Und Allgemeine Chemie. 638: 505-511. DOI: 10.1002/Zaac.201100440  0.391
2011 Prechtl MH, Teltewskoi M, Dimitrov A, Kemnitz E, Braun T. Catalytic C-H bond activation at nanoscale Lewis acidic aluminium fluorides: H/D exchange reactions at aromatic and aliphatic hydrocarbons. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 14385-8. PMID 22125129 DOI: 10.1002/Chem.201102853  0.368
2011 Voigt J, Braun T. Si-H and Si-Si activation at Pt: synthesis and reactivity of neutral and cationic silyl complexes. Dalton Transactions (Cambridge, England : 2003). 40: 12699-704. PMID 21989593 DOI: 10.1039/C1Dt11351H  0.392
2011 Kläring P, Pahl S, Braun T, Penner A. Facile oxidative addition of water at iridium: reactivity of trans-[Ir(4-C5NF4)(H)(OH)(PiPr3)2] towards CO2 and NH3. Dalton Transactions (Cambridge, England : 2003). 40: 6785-91. PMID 21611655 DOI: 10.1039/C1Dt10173K  0.391
2011 Meier G, Braun T. A rhodium peroxido complex in mono-, di-, and peroxygenation reactions. Angewandte Chemie (International Ed. in English). 50: 3280-4. PMID 21370368 DOI: 10.1002/Anie.201007315  0.418
2011 Braun T, Wehmeier F. C-F Bond Activation of Highly Fluorinated Molecules at Rhodium: From Model Reactions to Catalysis (Eur. J. Inorg. Chem. 5/2011) European Journal of Inorganic Chemistry. 2011: n/a-n/a. DOI: 10.1002/Ejic.201190009  0.417
2011 Kläring P, Jungton A, Braun T, Müller C. Synthesis, Structure and Reactivity of Iridium Hydrido Fluorido Complexes European Journal of Inorganic Chemistry. 2012: 1430-1436. DOI: 10.1002/Ejic.201100917  0.376
2011 Penner A, Braun T. Rhodium and Iridium Complexes with α-Diketimine Ligands: Oxidative Addition of H2 and O2 European Journal of Inorganic Chemistry. 2011: 2579-2587. DOI: 10.1002/Ejic.201100135  0.362
2011 Braun T, Wehmeier F. C–F Bond Activation of Highly Fluorinated Molecules at Rhodium: From Model Reactions to Catalysis European Journal of Inorganic Chemistry. 2011: 613-625. DOI: 10.1002/Ejic.201001184  0.424
2010 Breyer D, Braun T, Penner A. Isolation and reactivity of palladium hydrido complexes: intermediates in the hydrodefluorination of pentafluoropyridine. Dalton Transactions (Cambridge, England : 2003). 39: 7513-20. PMID 20552114 DOI: 10.1039/C0Dt00086H  0.336
2010 Jungton AK, Meltzer A, Präsang C, Braun T, Driess M, Penner A. Addition of [(eta(5)-C(5)Me(5))IrH(4)] to a zwitterionic silylene: stepwise formation of iridium(V)-silyl and iridium(III)-silylene complexes. Dalton Transactions (Cambridge, England : 2003). 39: 5436-8. PMID 20445932 DOI: 10.1039/C0Dt00236D  0.429
2010 Teltewskoi M, Panetier JA, Macgregor SA, Braun T. A highly reactive rhodium(I)-boryl complex as a useful tool for C-H bond activation and catalytic C-F bond borylation. Angewandte Chemie (International Ed. in English). 49: 3947-51. PMID 20419724 DOI: 10.1002/Anie.201001070  0.426
2010 Teltewskoi M, Panetier JA, Macgregor SA, Braun T. A highly reactive rhodium(I)-boryl complex as a useful tool for C-H bond activation and catalytic C-F bond borylation Angewandte Chemie - International Edition. 49: 3947-3951. DOI: 10.1002/anie.201001070  0.316
2009 Salomon MA, Jungton AK, Braun T. Activation of ethylene and ammonia at iridium: C-H versus N-H oxidative addition. Dalton Transactions (Cambridge, England : 2003). 7669-77. PMID 19759939 DOI: 10.1039/B906189D  0.38
2009 Roscher A, Bockholt A, Braun T. Towards a catalytic hydrogenolysis of silicon-silicon bonds: formation of Si-H bonds from disilanes and H2 at platinum. Dalton Transactions (Cambridge, England : 2003). 1378-82. PMID 19462659 DOI: 10.1039/B815586K  0.375
2009 Braun T, Salomon MA, Altenhöner K, Teltewskoi M, Hinze S. C-F activation at rhodium boryl complexes: formation of 2-fluoroalkyl-1,3,2-dioxaborolanes by catalytic functionalization of hexafluoropropene. Angewandte Chemie (International Ed. in English). 48: 1818-22. PMID 19180624 DOI: 10.1002/Anie.200805041  0.44
2009 Meier G, Braun T. Catalytic C-F activation and hydrodefluorination of fluoroalkyl groups. Angewandte Chemie (International Ed. in English). 48: 1546-8. PMID 19148912 DOI: 10.1002/Anie.200805237  0.354
2009 Braun T, Wehmeier F, Altenhöner K. Catalytic C-F bond activation of hexafluoropropene by rhodium: formation of (3,3,3-trifluoropropyl)silanes. Angewandte Chemie (International Ed. in English). 46: 5321-4. PMID 17546716 DOI: 10.1002/Anie.200700711  0.395
2009 Penner A, Schröder T, Braun T, Ziemer B. Synthesis, Structure, and Reactivity of Rhodium Bipyridine Compounds: Formation of a RhIIHydrido Cluster and a RhIIIPeroxido Complex European Journal of Inorganic Chemistry. 2009: 4464-4470. DOI: 10.1002/Ejic.200900531  0.426
2009 Meier G, Braun T. Katalytische C-F-Aktivierung und Hydrodefluorierung von Fluoralkylgruppen Angewandte Chemie. 121: 1575-1577. DOI: 10.1002/Ange.200805237  0.319
2008 Salomon MA, Braun T, Krossing I. Iridium derivatives of fluorinated aromatics by C-H activation: isolation of classical and non-classical hydrides. Dalton Transactions (Cambridge, England : 2003). 5197-206. PMID 18813374 DOI: 10.1039/B807077F  0.384
2008 Schaub T, Fischer P, Steffen A, Braun T, Radius U, Mix A. C-F activation of fluorinated arenes using NHC-stabilized nickel(0) complexes: selectivity and mechanistic investigations. Journal of the American Chemical Society. 130: 9304-17. PMID 18588290 DOI: 10.1021/Ja074640E  0.73
2008 Ahijado M, Braun T. Rhodium derivatives of peroxoboronic acids and peroxoboric acid: formation of metallatrioxaborolanes from an eta2-peroxo complex. Angewandte Chemie (International Ed. in English). 47: 2954-8. PMID 18327761 DOI: 10.1002/Anie.200705715  0.305
2007 Steffen A, Braun T, Neumann B, Stammler HG. Palladium fluoro complexes: useful tools to access organometallic metallamacrocycles. Angewandte Chemie (International Ed. in English). 46: 8674-8. PMID 17924387 DOI: 10.1002/Anie.200703393  0.624
2007 Braun T, Noveski D, Ahijado M, Wehmeier F. Hydrodefluorination of pentafluoropyridine at rhodium using dihydrogen: detection of unusual rhodium hydrido complexes. Dalton Transactions (Cambridge, England : 2003). 3820-5. PMID 17712449 DOI: 10.1039/B706846H  0.428
2007 Steffen A, Hagemeister T, Braun T, Jutzi P, Neumann B, Stammler H. Synthesis of 3,3,3-Trifluoropropyl Substituted Cyclopentadienes and Their Zirconocene Derivatives:  Catalytic Applications in the Polymerization of Ethylene Organometallics. 26: 5289-5294. DOI: 10.1021/Om700457C  0.699
2007 Weber L, Noveski G, Braun T, Stammler H, Neumann B. Synthesis of the η2-1-Phosphaallene Complexes [(η5-C5H5)(CO)(NO)W{η2-R1P=C=C(R2)H}] (R1 =tBu, Cy; R2 = Ph, H) from [(η5-C5H5)(CO)(NO)W=C=C(R2)H] (R2 = Ph, H) and Inversely Polarized Phosphaalkenes R1P=C(NMe2)2 (R1 =tBu, Cy), and Their Structure European Journal of Inorganic Chemistry. 2007: 562-567. DOI: 10.1002/Ejic.200600922  0.34
2007 Steffen A, Braun T, Neumann B, Stammler HG. Palladium fluoro complexes: Useful tools to access organometallic metallamacrocycles Angewandte Chemie - International Edition. 46: 8674-8678. DOI: 10.1002/anie.200703393  0.61
2007 Braun T, Wehmeier F, Altenhöner K. Katalytische C-F-Aktivierung von Hexafluorpropen an Rhodium: Synthese von (3,3,3-Trifluorpropyl)silanen† Angewandte Chemie. 119: 5415-5418. DOI: 10.1002/Ange.200700711  0.344
2006 Braun T, Izundu J, Steffen A, Neumann B, Stammler HG. Reactivity of a palladium fluoro complex towards silanes and Bu 3SnCH=CH2: Catalytic derivatisation of pentafluoropyridine based on carbon-fluorine bond activation reactions Dalton Transactions. 5118-5123. PMID 17077884 DOI: 10.1039/B608410A  0.669
2006 Weber L, Domke I, Schmidt C, Braun T, Stammler H, Neumann B. Syntheses, structures, luminescence and electrochemistry of benzene- and biphenyl-centered bis- and tris-1,3,2-diazaboroles and -1,3,2-diazaborolidines Dalton Transactions. 2127-32. PMID 16625257 DOI: 10.1039/B514920G  0.354
2006 Weber L, Bayer P, Braun T, Stammler HG, Neumann B. Arsaalkenes R-As=C(NMe2)2 [R = PhC(O), 4-EtC 6H4C(O), 2,4,6-Me3C6H 2C(O), tBuC(O), Me3Si]: Versatile reagents in the chemistry of heterocumulenes Organometallics. 25: 1786-1794. DOI: 10.1021/Om051084T  0.322
2006 Braun T, Schorlemer V, Neumann B, Stammler H. Palladium mediated activation of C–F bonds in 2,4,6-trifluoropyrimidine: Synthesis and structure of palladium pyrimidyloxy and pyrimidinone derivatives Journal of Fluorine Chemistry. 127: 367-372. DOI: 10.1016/J.Jfluchem.2005.12.025  0.424
2006 Weber L, Bayer P, Uthmann S, Braun T, Stammler HG, Neumann B. Reactivity of the inversely polarized arsaalkenes R-As=C(NMe 2)2 {R = [(η5-C5Me 5)(CO)2Fe], tBuC(O), 4-Et-C6H4C(O)} towards phosphavinylidene complexes [η5-(C5H 5)(CO)2M=P=C(SiMe3)2] (M = Mo, W) European Journal of Inorganic Chemistry. 137-143. DOI: 10.1002/Ejic.200500674  0.368
2005 Braun T, Steffen A, Schorlemer V, Neumann B, Stammler HG. Routes to unique palladium A-frame complexes with a bridging fluoro-ligand. Dalton Transactions (Cambridge, England : 2003). 3331-6. PMID 16193151 DOI: 10.1039/B509032F  0.668
2005 Braun T, Steffen A, Schorlemer V, Neumann B, Stammler HG. Routes to unique palladium A-frame complexes with a bridging fluoro-ligand Dalton Transactions. 3331-3336. DOI: 10.1039/b509032f  0.647
2005 Steffen A, Sladek MI, Braun T, Neumann B, Stammler H. Catalytic C—C Coupling Reactions at Nickel by C—F Activation of a Pyrimidine in the Presence of a C—Cl Bond: The Crucial Role of Highly Reactive Fluoro Complexes. Cheminform. 36. DOI: 10.1021/Om050080L  0.688
2005 Steffen A, Sladek MI, Braun T, Neumann B, Stammler H. Catalytic C−C Coupling Reactions at Nickel by C−F Activation of a Pyrimidine in the Presence of a C−Cl Bond:  The Crucial Role of Highly Reactive Fluoro Complexes Organometallics. 24: 4057-4064. DOI: 10.1021/OM050080L  0.643
2004 Noveski D, Braun T, Neumann B, Stammler A, Stammler HG. C-F or C-H bond activation and C-C coupling reactions of fluorinated pyridines at rhodium: synthesis, structure and reactivity of a variety of tetrafluoropyridyl complexes. Dalton Transactions (Cambridge, England : 2003). 4106-19. PMID 15573161 DOI: 10.1039/B414734K  0.405
2004 Jasim NA, Perutz RN, Whitwood AC, Braun T, Izundu J, Neumann B, Rothfeld S, Stammler HG. Contrasting reactivity of fluoropyridines at palladium and platinum: C-F oxidative addition at palladium, P-C and C-F activation at platinum Organometallics. 23: 6140-6149. DOI: 10.1021/Om049448P  0.627
2004 Noveski D, Braun T, Krückemeier S. Synthesis and reactivity of rhodium fluoro complexes Journal of Fluorine Chemistry. 125: 959-966. DOI: 10.1016/J.Jfluchem.2004.01.024  0.403
2003 Braun T, Münch G, Windmüller B, Gevert O, Laubender M, Werner H. Synthesis, molecular structure, and C-C coupling reactions of carbeneruthenium(II) complexes with C5H5Ru(=CRR') and C5Me5Ru(=CRR') as molecular units. Chemistry (Weinheim An Der Bergstrasse, Germany). 9: 2516-30. PMID 12794894 DOI: 10.1002/Chem.200304740  0.459
2003 Braun T, Noveski D, Neumann B, Stammler HG. Conversion of hexafluoropropene into 1,1,1-trifluoropropane by rhodium-mediated C[bond]F activation. Angewandte Chemie (International Ed. in English). 41: 2745-8. PMID 12203472 DOI: 10.1002/1521-3773(20020802)41:15<2745::Aid-Anie2745>3.0.Co;2-C  0.371
2003 Noveski D, Braun T, Schulte M, Neumann B, Stammler H. C–F Activation and hydrodefluorination of fluorinated alkenes at rhodium Dalton Transactions. 4075-4083. DOI: 10.1039/B306635E  0.409
2003 Braun T, Rothfeld S, Schorlemer V, Stammler A, Stammler H. Palladium mediated activation of a C–F bond in pentafluoropyridine: synthesis, structure and reactivity of a pyridyloxy complex Inorganic Chemistry Communications. 6: 752-755. DOI: 10.1016/S1387-7003(03)00099-6  0.374
2002 Braun T, Perutz RN. Routes to fluorinated organic derivatives by nickel mediated C-F activation of heteroaromatics. Chemical Communications (Cambridge, England). 2749-57. PMID 12478732 DOI: 10.1039/B206154F  0.579
2002 Sladek MI, Braun T, Neumann B, Stammler H. 3-Fluoropyridyl nickel complexes as useful tools for the selective synthesis of new 2,4,5,6-tetrafluoropyridines: a route complementing the established methods to access fluorinated pyridines New Journal of Chemistry. 27: 313-318. DOI: 10.1039/B207943G  0.458
2002 Braun T, Blöcker B, Schorlemer V, Neumann B, Stammler A, Stammler H. Synthesis, structure and reactivity of fluorovinyl nickel complexes: formation of a phosphonioethenyl complex Journal of the Chemical Society-Dalton Transactions. 2213-2218. DOI: 10.1039/B200739H  0.43
2002 Sladek MI, Braun T, Neumann B, Stammler H. Aromatic C–F activation at Ni in the presence of a carbon–chlorine bond: the nickel mediated synthesis of new pyrimidines Journal of the Chemical Society-Dalton Transactions. 297-299. DOI: 10.1039/B110128E  0.354
2002 Atheaux I, Delpech F, Donnadieu B, Sabo-Etienne S, Chaudret B, Hussein K, Barthelat JC, Braun T, Duckett SB, Perutz RN. Exchange processes in complexes with two ruthenium (η2-silane) linkages: Role of the secondary interactions between silicon and hydrogen atoms Organometallics. 21: 5347-5357. DOI: 10.1021/Om0206148  0.694
2001 Braun T, Perutz RN, Sladek MI. Catalytic C-F activation of polyfluorinated pyridines by nickel-mediated cross-coupling reactions. Chemical Communications (Cambridge, England). 2254-5. PMID 12240137 DOI: 10.1039/B106646C  0.587
2001 Braun T, Cronin L, Higgitt CL, McGrady JE, Perutz RN, Reinhold M. Coordination and oxidative addition of octafluoronaphthalene at a nickel centre: Isolation of an intermediate in C-F bond activation New Journal of Chemistry. 25: 19-21. DOI: 10.1039/B006368L  0.618
2000 Archibald SJ, Braun T, Gaunt JA, Hobson JE, Perutz RN. Chemistry of nickel tetrafluoropyridyl derivatives: Their versatile behaviour with Brønsted acids and the Lewis acid BF3 Journal of the Chemical Society, Dalton Transactions. 2013-2018. DOI: 10.1039/B002333G  0.563
1999 Braun T, Foxon SP, Perutz RN, Walton PH. Nickel-Assisted Carbon-Fluorine Bond Activation of 2,4,6-Trifluoropyrimidine: Synthesis of New Pyrimidine and Pyrimidinone Derivatives. Angewandte Chemie (International Ed. in English). 38: 3326-3329. PMID 10602185 DOI: 10.1002/(Sici)1521-3773(19991115)38:22<3326::Aid-Anie3326>3.0.Co;2-7  0.616
1999 Braun T, Parsons S, Perutz RN, Voith M. Reactivity of a Nickel Fluoride Complex: Preparation of New Tetrafluoropyridyl Derivatives Organometallics. 18: 1710-1716. DOI: 10.1021/Om980935C  0.607
1997 Werner H, Braun T, Daniel T, Gevert O, Schulz M. Cyclopentadienyl— und Pentamethylcyclopentadienyl—Rutheniumkomplexe mit Carboxylat-, Vinylester- und Carben-Liganden Journal of Organometallic Chemistry. 541: 127-141. DOI: 10.1016/S0022-328X(97)00045-4  0.495
1997 Braun T, Laubender M, Gevert O, Werner H. Halfsandwich‐Type Triisopropylstibane Ruthenium Complexes with 16‐, 17‐, and 18‐Electron Configurations and an Unsymmetrical Binuclear 18/16‐Electron Ru2(SbiPr3) Species Chemische Berichte. 130: 559-563. DOI: 10.1002/Cber.19971300505  0.546
1996 Braun T, Meuer P, Werner H. (2-4-Eta )-Butadienyl- And (3-5-Eta )-Pentatrienylruthenium Complexes Fromvinylidene And Allenylidene Precursors Organometallics. 15: 4075-4077. DOI: 10.1021/Om960390R  0.509
1995 Braun T, Gevert O, Werner H. A Ruthenium-Mediated C1+C2 Coupling Reaction : Formation Of Pi -Allyl Complexes From Carbenemetal Precursors Journal of the American Chemical Society. 117: 7291-7292. DOI: 10.1021/Ja00132A048  0.518
1995 Braun T, Steinert P, Werner H. Vinylidene transition metal complexes XXXIV the preparation and structure of neutral vinylidene and allenylidene ruthenium(II) compounds of the half-sandwich type containing iPr2PCH2CO2Me as supporting ligand Journal of Organometallic Chemistry. 488: 169-176. DOI: 10.1016/0022-328X(94)00015-5  0.506
1994 Werner H, Daniel T, Braun T, Nürnberg O. Five-membered OsC3N heterocycles from osmium azavinylidenes as precursors Journal of Organometallic Chemistry. 480: 145-153. DOI: 10.1016/0022-328X(94)87110-8  0.514
1993 Daniel T, Mahr N, Braun T, Werner H. Vinylidene transition-metal complexes. XXIII. Insertion of a vinylidene unit into a ruthenium-oxygen bond: synthesis and molecular structure of [cyclic] [C5H5(PPh3)RuC(:CHCO2Me)OC(Me)O] Organometallics. 12: 1475-1477. DOI: 10.1021/Om00028A080  0.489
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