Year |
Citation |
Score |
2022 |
Chinn ES, Falvey DE. Photochemical generation and characterization of the 5-endo-10,11-dihydrodibenzoazepine nitrenium ion. Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society For Photobiology. PMID 35869409 DOI: 10.1007/s43630-022-00267-3 |
0.374 |
|
2020 |
Zeppuhar AN, Falvey DE. Generation of ,-Di(4-bromophenyl)nitrenium Ion under Acidic Conditions: Search for a Nitrenium Dication. The Journal of Organic Chemistry. PMID 32589031 DOI: 10.1021/Acs.Joc.0C00686 |
0.486 |
|
2020 |
Thum MD, Wolf S, Falvey DE. State Dependent Photochemical and Photophysical Behavior of Dithiolate Ester and Trithiocarbonate RAFT Polymerization Agents. The Journal of Physical Chemistry. A. PMID 32375484 DOI: 10.1021/Acs.Jpca.0C02678 |
0.363 |
|
2019 |
Zeppuhar AN, Hill-Byrne K, Falvey DE. Mechanism of the photorelease of alcohols from the 9-phenyl-9-tritylone protecting group. Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society For Photobiology. PMID 31243421 DOI: 10.1039/C9Pp00183B |
0.368 |
|
2018 |
Falvey DE. Discrete Existence of Singlet Nitrenium Ions Revisited: Computational Studies of Non-Aryl Nitrenium Ions and Their Rearrangements. Acs Omega. 3: 10418-10432. PMID 31459169 DOI: 10.1021/acsomega.8b01038 |
0.406 |
|
2018 |
Thum MD, Falvey DE. Photoreleasable Protecting Groups Triggered by Sequential Two-Photon Absorption of Visible Light: Release of Carboxylic Acids from a Linked Anthraquinone- N-Alkylpicolinium Ester Molecule. The Journal of Physical Chemistry. A. PMID 29518337 DOI: 10.1021/Acs.Jpca.8B00657 |
0.398 |
|
2017 |
Heymann RR, Thum MD, Hardee AL, Falvey DE. Visible light initiated release of calcium ions through photochemical electron transfer reactions. Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society For Photobiology. PMID 28497836 DOI: 10.1039/C6Pp00469E |
0.349 |
|
2017 |
Denning DM, Falvey DE. Substituent and Solvent Effects on the Stability of N-Heterocyclic Carbene Complexes with CO2. The Journal of Organic Chemistry. PMID 28067512 DOI: 10.1021/Acs.Joc.6B02755 |
0.304 |
|
2015 |
Denning DM, Pedowitz NJ, Thum MD, Falvey DE. Uncaging Alcohols Using UV or Visible Light Photoinduced Electron Transfer to 9-Phenyl-9-tritylone Ethers. Organic Letters. PMID 26605860 DOI: 10.1021/Acs.Orglett.5B02924 |
0.327 |
|
2015 |
Denning DM, Thum MD, Falvey DE. Photochemical Reduction of CO2 Using 1,3-Dimethylimidazolylidene. Organic Letters. 17: 4152-5. PMID 26273966 DOI: 10.1021/Acs.Orglett.5B01891 |
0.304 |
|
2015 |
Kunsberg DJ, Kipping AH, Falvey DE. Visible Light Photorelease of Carboxylic Acids via Charge-Transfer Excitation of N-Methylpyridinium Iodide Esters. Organic Letters. 17: 3454-7. PMID 26120927 DOI: 10.1021/Acs.Orglett.5B01490 |
0.396 |
|
2015 |
Falvey DE. Nitrenium ion analogues of nonclassical carbocations: cyclopropylnitrenium, allylnitrenium, and azetidenium ions and mechanisms for their interconversion. Organic Letters. 17: 484-7. PMID 25611763 DOI: 10.1021/Ol503488B |
0.457 |
|
2015 |
Falvey DE. Nitrenium ion analogues of nonclassical carbocations: Cyclopropylnitrenium, allylnitrenium, and azetidenium ions and mechanisms for their interconversion Organic Letters. 17: 484-487. DOI: 10.1021/ol503488b |
0.324 |
|
2014 |
Denning DM, Falvey DE. Solvent-dependent decarboxylation of 1,3-dimethylimdazolium-2-carboxylate. The Journal of Organic Chemistry. 79: 4293-9. PMID 24762208 DOI: 10.1021/Jo5007575 |
0.329 |
|
2013 |
Denning DM, Falvey DE. Solvent-dependent photochemistry of 2,2,2-tribromoethyl-(2'-phenylacetate). The Journal of Organic Chemistry. 78: 1934-9. PMID 23075383 DOI: 10.1021/Jo301816Z |
0.319 |
|
2013 |
Perrotta RR, Falvey DE. The 3,5-dinitroanilide anion: A singlet anilide anion with evidence for a thermally accessible triplet state Journal of Physical Organic Chemistry. 26: 699-706. DOI: 10.1002/Poc.3118 |
0.712 |
|
2013 |
Falvey DE. Electronic Properties of Nitrenium Ions Nitrenes and Nitrenium Ions. 191-216. DOI: 10.1002/9781118560907.ch6 |
0.347 |
|
2011 |
Perrotta RR, Winter AH, Coldren WH, Falvey DE. 2-(3,5-Dinitrophenyl)-1,3-dithiane carbanion: a benzylic anion with a low energy triplet state. Journal of the American Chemical Society. 133: 15553-8. PMID 21870822 DOI: 10.1021/Ja204711A |
0.795 |
|
2011 |
Perrotta RR, Winter AH, Falvey DE. Photochemical heterolysis of 3,5-bis(dimethylamino)benzyl alcohols and esters: generation of a benzyl cation with a low-energy triplet state. Organic Letters. 13: 212-5. PMID 21158403 DOI: 10.1021/Ol102606M |
0.773 |
|
2011 |
Perrotta RR, Winter AH, Falvey DE. Photochemical heterolysis of 3,5-Bis(dimethylamino)benzyl alcohols and esters: Generation of a benzyl cation with a low-energy triplet state Organic Letters. 13: 212-215. DOI: 10.1021/ol102606m |
0.766 |
|
2011 |
Perrotta RR, Winter AH, Coldren WH, Falvey DE. 2-(3,5-Dinitrophenyl)-1,3-dithiane carbanion: A benzylic anion with a low energy triplet state Journal of the American Chemical Society. 133: 15553-15558. DOI: 10.1021/ja204711a |
0.763 |
|
2010 |
Borak JB, Lee HY, Raghavan SR, Falvey DE. Application of PET deprotection for orthogonal photocontrol of aqueous solution viscosity Chemical Communications. 46: 8983-8985. PMID 20967368 DOI: 10.1039/C0Cc02203A |
0.753 |
|
2010 |
Borak JB, Falvey DE. Ketocoumarin dyes as electron mediators for visible light induced carboxylate photorelease Photochemical and Photobiological Sciences. 9: 854-860. PMID 20527082 DOI: 10.1039/C0Pp00072H |
0.794 |
|
2010 |
Winter AH, Falvey DE. Vinyl cations substituted with beta pi-donors have triplet ground states. Journal of the American Chemical Society. 132: 215-22. PMID 19961230 DOI: 10.1021/Ja906139M |
0.674 |
|
2010 |
Winter AH, Falvey DE. Vinyl cations substituted with β π-donors have triplet ground states Journal of the American Chemical Society. 132: 215-222. DOI: 10.1021/ja906139m |
0.603 |
|
2009 |
Borak JB, Falvey DE. A new photolabile protecting group for release of carboxylic acids by visible-light-induced direct and mediated electron transfer. The Journal of Organic Chemistry. 74: 3894-9. PMID 19361187 DOI: 10.1021/Jo900182X |
0.788 |
|
2009 |
Borak JB, Falvey DE. A new photolabile protecting group for release of carboxylic acids by visible-light-induced direct and mediated electron transfer Journal of Organic Chemistry. 74: 3894-3899. DOI: 10.1021/jo900182x |
0.787 |
|
2008 |
Gan D, Jia M, Vaughan PP, Falvey DE, Blough NV. Aqueous photochemistry of methyl-benzoquinone. The Journal of Physical Chemistry. A. 112: 2803-12. PMID 18302352 DOI: 10.1021/Jp710724E |
0.374 |
|
2008 |
Vieira RC, Falvey DE. Solvent-mediated photoinduced electron transfer in a pyridinium ionic liquid. Journal of the American Chemical Society. 130: 1552-3. PMID 18193874 DOI: 10.1021/Ja077797F |
0.818 |
|
2008 |
Borak JB, López-Sola S, Falvey DE. Photorelease of carboxylic acids mediated by visible-light-absorbing gold-nanoparticles. Organic Letters. 10: 457-60. PMID 18163639 DOI: 10.1021/Ol702813W |
0.781 |
|
2008 |
Borak JB, López-Sola S, Falvey DE. Photorelease of carboxylic acids mediated by visible-light-absorbing gold-nanoparticles Organic Letters. 10: 456-460. DOI: 10.1021/ol702813w |
0.753 |
|
2008 |
Vieira RC, Falvey DE. Solvent-mediated photoinduced electron transfer in a pyridinium ionic liquid Journal of the American Chemical Society. 130: 1552-1553. DOI: 10.1021/ja077797f |
0.784 |
|
2007 |
Winter AH, Gibson HH, Falvey DE. Carbazolyl nitrenium ion: electron configuration and antiaromaticity assessed by laser flash photolysis, trapping rate constants, product analysis, and computational studies. The Journal of Organic Chemistry. 72: 8186-95. PMID 17892298 DOI: 10.1021/Jo0708184 |
0.733 |
|
2007 |
Winter AH, Falvey DE, Cramer CJ, Gherman BF. Benzylic cations with triplet ground states: computational studies of aryl carbenium ions, silylenium ions, nitrenium ions, and oxenium ions substituted with meta pi donors. Journal of the American Chemical Society. 129: 10113-9. PMID 17655230 DOI: 10.1021/Ja070143M |
0.733 |
|
2007 |
Thomas SI, Falvey DE. N,N-Di(4-halophenyl)nitrenium ions: nucleophilic trapping, aromatic substitution, and hydrogen atom transfer. The Journal of Organic Chemistry. 72: 4626-34. PMID 17536861 DOI: 10.1021/Jo062578I |
0.837 |
|
2007 |
Vieira RC, Falvey DE. Photoinduced electron-transfer reactions in two room-temperature ionic liquids: 1-butyl-3-methylimidazolium hexafluorophosphate and 1-octyl-3-methylimidazolium hexafluorophosphate. The Journal of Physical Chemistry. B. 111: 5023-9. PMID 17474706 DOI: 10.1021/Jp0630471 |
0.788 |
|
2007 |
Vieira RC, Falvey DE. Photoinduced electron-transfer reactions in two room-temperature ionic liquids: 1-Butyl-3-methylimidazolium hexafluorophosphate and 1-octyl-3-methylimidazolium hexafluorophosphate Journal of Physical Chemistry B. 111: 5023-5029. DOI: 10.1021/jp0630471 |
0.786 |
|
2007 |
Winter AH, Gibson HH, Falvey DE. Carbazolyl nitrenium ion: Electron configuration and antiaromaticity assessed by laser flash photolysis, trapping rate constants, product analysis, and computational studies Journal of Organic Chemistry. 72: 8186-8195. DOI: 10.1021/jo0708184 |
0.689 |
|
2007 |
Thomas SI, Falvey DE. N,N-di(4-halophenyl)nitrenium ions: Nucleophilic trapping, aromatic substitution, and hydrogen atom transfer Journal of Organic Chemistry. 72: 4626-4634. DOI: 10.1021/jo062578i |
0.812 |
|
2006 |
Sundararajan C, Falvey DE. Photorelease of carboxylic and amino acids from N-methyl-4-picolinium esters by mediated electron transfer Photochemical and Photobiological Sciences. 5: 116-121. PMID 16395436 DOI: 10.1039/B511269A |
0.702 |
|
2006 |
Thomas SI, Falvey DE. Fast reactions of arylnitrenium ions with amino acids and proteins: A laser flash photolysis study Journal of Physical Organic Chemistry. 19: 291-294. DOI: 10.1002/Poc.1031 |
0.817 |
|
2005 |
Kung AC, McIlroy SP, Falvey DE. Diphenylnitrenium ion: cyclization, electron transfer, and polymerization reactions. The Journal of Organic Chemistry. 70: 5283-90. PMID 15960533 DOI: 10.1021/Jo050598Z |
0.812 |
|
2005 |
Sundararajan C, Falvey DE. Photolytic release of carboxylic acids using linked donor-acceptor molecules: direct versus mediated photoinduced electron transfer to N-alkyl-4-picolinium esters. Organic Letters. 7: 2631-4. PMID 15957908 DOI: 10.1021/Ol050744N |
0.704 |
|
2005 |
Sundararajan C, Falvey DE. Photorelease of carboxylic acids, amino acids, and phosphates from N-alkylpicolinium esters using photosensitization by high wavelength laser dyes Journal of the American Chemical Society. 127: 8000-8001. PMID 15926809 DOI: 10.1021/Ja050760F |
0.692 |
|
2005 |
Kung AC, Falvey DE. Photogenerated N-methyl-N-1-naphthylnitrenium ion: laser flash photolysis, trapping rates, and product study. The Journal of Organic Chemistry. 70: 3127-32. PMID 15822974 DOI: 10.1021/Jo0477749 |
0.802 |
|
2005 |
Sundararajan C, Falvey DE. Photolytic release of carboxylic acids using linked donor-acceptor molecules: Direct versus mediated photoinduced electron transfer to N-alkyl-4-picolinium esters Organic Letters. 7: 2631-2634. DOI: 10.1021/ol050744n |
0.666 |
|
2005 |
Kung AC, McIlroy SP, Falvey DE. Diphenylnitrenium ion: Cyclization, electron transfer, and polymerization reactions Journal of Organic Chemistry. 70: 5283-5290. DOI: 10.1021/jo050598z |
0.784 |
|
2005 |
Kung AC, Falvey DE. Photogenerated N-methyl-N-1-naphthylnitrenium ion: Laser flash photolysis, trapping rates, and product study Journal of Organic Chemistry. 70: 3127-3132. DOI: 10.1021/jo0477749 |
0.774 |
|
2004 |
Winter AH, Thomas SI, Kung AC, Falvey DE. Photochemical generation of nitrenium ions from protonated 1,1-diarylhydrazines. Organic Letters. 6: 4671-4. PMID 15575657 DOI: 10.1021/Ol048250Y |
0.804 |
|
2004 |
Falvey DE, Sundararajan C. Photoremovable protecting groups based on electron transfer chemistry. Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society For Photobiology. 3: 831-8. PMID 15346183 DOI: 10.1039/B406866A |
0.649 |
|
2004 |
Sundararajan C, Falvey DE. C-O bond fragmentation of 4-picolyl- and N-methyl-4-picolinium esters triggered by photochemical electron transfer. The Journal of Organic Chemistry. 69: 5547-54. PMID 15307722 DOI: 10.1021/Jo049501J |
0.715 |
|
2004 |
Winter AH, Falvey DE, Cramer CJ. Effect of meta electron-donating groups on the electronic structure of substituted phenyl nitrenium ions. Journal of the American Chemical Society. 126: 9661-8. PMID 15291569 DOI: 10.1021/Ja047677X |
0.727 |
|
2004 |
Falvey DE, Sundararajan C. Photoremovable protecting groups based on electron transfer chemistry Photochemical and Photobiological Sciences. 3: 831-838. DOI: 10.1039/b406866a |
0.637 |
|
2004 |
Winter AH, Thomas SI, Kung AC, Falvey DE. Photochemical generation of nitrenium ions from protonated 1,1-diarylhydrazines Organic Letters. 6: 4671-4674. DOI: 10.1021/ol048250y |
0.79 |
|
2004 |
Sundararajan C, Falvey DE. C-O bond fragmentation of 4-picolyl- and N-methyl-4-picolinium esters triggered by photochemical electron transfer Journal of Organic Chemistry. 69: 5547-5554. DOI: 10.1021/jo049501j |
0.65 |
|
2003 |
Kung AC, Chiapperino D, Falvey DE. Photochemically generated arylnitrenium ions: substituent effects on reactivity studied by laser flash photolysis. Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society For Photobiology. 2: 1205-8. PMID 14690235 DOI: 10.1039/B307994E |
0.822 |
|
2003 |
Kung AC, Chiapperino D, Falvey DE. Photochemically generated arylnitrenium ions: Substituent effects on reactivity studied by laser flash photolysis Photochemical and Photobiological Sciences. 2: 1205-1208. DOI: 10.1039/b307994e |
0.802 |
|
2002 |
Joseph A, Falvey DE. Photoinduced electron transfer cleavage of oxetane adducts of uracil and cytosine Photochemical and Photobiological Sciences. 1: 632-635. PMID 12665298 DOI: 10.1039/B201740G |
0.645 |
|
2002 |
Vath P, Wamer WG, Falvey DE. Photochemistry and phototoxicity of aloe emodin Photochemistry and Photobiology. 75: 346-352. PMID 12003123 DOI: 10.1562/0031-8655(2002)0750346Papoae2.0.Co2 |
0.301 |
|
2002 |
Chiapperino D, McIlroy S, Falvey DE. Reactions of N-methyl-N-(4-biphenylyl)nitrenium ion with electron-rich arenes: Laser flash photolysis and product studies Journal of the American Chemical Society. 124: 3567-3577. PMID 11929245 DOI: 10.1021/Ja011049N |
0.839 |
|
2002 |
Pochon A, Vaughan PP, Gan D, Vath P, Blough NV, Falvey DE. Photochemical oxidation of water by 2-methyl-1,4-benzoquinone: Evidence against the formation of free hydroxyl radical Journal of Physical Chemistry A. 106: 2889-2894. DOI: 10.1021/Jp012856B |
0.379 |
|
2001 |
McIlroy S, Falvey DE. Reactions of nitrenium ions with arenes: Laser flash photoylsis detection of a σ-complex between N,N-diphenylnitrenium ion and alkoxybenzenes [1] Journal of the American Chemical Society. 123: 11329-11330. PMID 11697991 DOI: 10.1021/Ja016557B |
0.491 |
|
2001 |
Joseph A, Falvey DE. Photolysis of thymine oxetanes produces triplet excited carbonyl compounds with high efficiency Journal of the American Chemical Society. 123: 3145-3146. PMID 11457030 DOI: 10.1021/Ja0040363 |
0.53 |
|
2001 |
Falvey DE. ChemInform Abstract: Photochemical Generation and Studies of Nitrenium Ions Cheminform. 32: no-no. DOI: 10.1002/chin.200101280 |
0.336 |
|
2000 |
McIlroy S, Cramer CJ, Falvey DE. Singlet-triplet energy gaps in highly stabilized nitrenium ions: experimental and theoretical study of 1,3-dimethylbenzotriazolium Ion Organic Letters. 2: 2451-4. PMID 10956519 DOI: 10.1021/Ol006106G |
0.456 |
|
2000 |
McIlroy S, Moran RJ, Falvey DE. Photogenerated nitrenium ions: A search for triplet-state reactivity in the chemistry of the diphenylnitrenium ion Journal of Physical Chemistry A. 104: 11154-11158. DOI: 10.1021/Jp002756Q |
0.481 |
|
2000 |
Lee K, Falvey DE. Photochemically removable protecting groups based on covalently linked electron donor - Acceptor systems Journal of the American Chemical Society. 122: 9361-9366. DOI: 10.1021/Ja9939441 |
0.437 |
|
2000 |
Joseph A, Prakash G, Falvey DE. Model studies of the (6-4) photoproduct photolyase enzyme: Laser flash photolysis experiments confirm radical ion intermediates in the sensitized repair of thymine oxetane adducts Journal of the American Chemical Society. 122: 11219-11225. DOI: 10.1021/Ja002541U |
0.602 |
|
2000 |
Srivastava S, Ruane PH, Toscano JP, Sullivan MB, Cramer CJ, Chiapperino D, Reed EC, Falvey DE. Structures of reactive nitrenium ions: Time-resolved infrared laser flash photolysis and computational studies of substituted N-methyl-N-arylnitrenium ions Journal of the American Chemical Society. 122: 8271-8278. DOI: 10.1021/Ja001184K |
0.83 |
|
2000 |
McIlroy S, Cramer CJ, Falvey DE. Singlet - Triplet energy gaps in highly stabilized nitrenium ions: Experimental and theoretical study of 1,3-dimethylbenzotriazolium ion Organic Letters. 2: 2451-2454. |
0.325 |
|
1999 |
Srivastava S, Kercher M, Falvey DE. On the solution chemistry of parent nitrenium ion NH2 +: The role of the singlet and triplet states in its reactions with water, methanol, and hydrocarbons Journal of Organic Chemistry. 64: 5853-5857. DOI: 10.1021/Jo990324+ |
0.413 |
|
1999 |
Banerjee A, Lee K, Falvey DE. Photoreleasable protecting groups based on electron transfer chemistry. Donor sensitized release of phenacyl groups from alcohols, phosphates and diacids Tetrahedron. 55: 12699-12710. DOI: 10.1016/S0040-4020(99)00754-1 |
0.399 |
|
1999 |
Falvey DE. Singlet and triplet states in the reactions of nitrenium ions Journal of Physical Organic Chemistry. 12: 589-596. DOI: 10.1002/(Sici)1099-1395(199908)12:8<589::Aid-Poc170>3.0.Co;2-T |
0.449 |
|
1998 |
Su Z, Mariano PS, Falvey DE, Yoon UC, Oh SW. Dynamics of anilinium radical α-heterolytic fragmentation processes. Electrofugal group, substituent, and medium effects on desilylation, decarboxylation, and retro-aldol cleavage pathways Journal of the American Chemical Society. 120: 10676-10686. DOI: 10.1021/Ja981541F |
0.363 |
|
1998 |
Banerjee A, Falvey DE. Direct Photolysis of Phenacyl Protecting Groups Studied by Laser Flash Photolysis: An Excited State Hydrogen Atom Abstraction Pathway Leads to Formation of Carboxylic Acids and Acetophenone Journal of the American Chemical Society. 120: 2965-2966. DOI: 10.1021/Ja971431T |
0.341 |
|
1998 |
Banerjee A, Lee K, Yu Q, Fang AG, Falvey DE. Protecting group release through photoinduced electron transfer: Wavelength control through sensitized irradiation Tetrahedron Letters. 39: 4635-4638. DOI: 10.1016/S0040-4039(98)00857-0 |
0.365 |
|
1997 |
Moran RJ, Cramer C, Falvey DE. Reactions of Diarylnitrenium Ions with Electron Rich Alkenes: An Experimental and Theoretical Study. The Journal of Organic Chemistry. 62: 2742-2751. PMID 11671634 DOI: 10.1021/Jo9623649 |
0.457 |
|
1997 |
Scannell MP, Prakash G, Falvey DE. Photoinduced electron transfer to pyrimidines and 5,6-dihydropyrimidine derivatives: Reduction potentials determined by fluorescence quenching kinetics Journal of Physical Chemistry A. 101: 4332-4337. DOI: 10.1021/Jp970164A |
0.326 |
|
1997 |
Banerjee A, Falvey DE. Protecting Groups that can be Removed through Photochemical Electron Transfer: Mechanistic and Product Studies on Photosensitized Release of Carboxylates from Phenacyl Esters Journal of Organic Chemistry. 62: 6245-6251. DOI: 10.1021/Jo970495J |
0.473 |
|
1997 |
Cramer CJ, Truhlar DG, Falvey DE. Singlet-triplet splittings and 1,2-hydrogen shift barriers for methylphenylborenide, methylphenylcarbene, and methylphenylnitrenium in the gas phase and solution. What a difference a charge makes Journal of the American Chemical Society. 119: 12338-12342. DOI: 10.1021/Ja9723390 |
0.322 |
|
1997 |
Scannell MP, Fenick DJ, Yeh SR, Falvey DE. Model studies of DNA photorepair: Reduction potentials of thymine and cytosine cyclobutane dimers measured by fluorescence quenching Journal of the American Chemical Society. 119: 1971-1977. DOI: 10.1021/Ja963360O |
0.344 |
|
1997 |
Cramer CJ, Falvey DE. Computational prediction of a ground-state triplet arylnitrenium ion and a possible ground-state triplet silylene Tetrahedron Letters. 38: 1515-1518. DOI: 10.1016/S0040-4039(97)00126-3 |
0.336 |
|
1997 |
Chiapperino D, Falvey DE. N-methyl-N-phenylnitrenium ion from photolysis of N-(methylphenylamino)-2,4,6-trimethylpyridinium tetrafluoroborate Journal of Physical Organic Chemistry. 10: 917-924. DOI: 10.1002/(Sici)1099-1395(199712)10:12<917::Aid-Poc954>3.0.Co;2-6 |
0.834 |
|
1997 |
Moran RJ, Cramer C, Falvey DE. Reactions of Diarylnitrenium Ions with Electron Rich Alkenes: An Experimental and Theoretical Study Journal of Organic Chemistry. 62: 2742-2751. |
0.37 |
|
1996 |
Chiapperino D, Anderson GB, Robbins RJ, Falvey DE. Photochemically Generated Arylnitrenium Ions: Laser Flash Photolysis and Product Studies of the Photochemistry of N-tert-Butyl-3-methyl-6-chloroanthranilium Ions. The Journal of Organic Chemistry. 61: 3195-3199. PMID 11667186 DOI: 10.1021/Jo952149C |
0.829 |
|
1996 |
Scannell MP, Yeh SR, Falvey DE. Model studies of DNA photorepair: enthalpy of cleavage of a pyrimidine dimer measured by photothermal beam deflection calorimetry. Photochemistry and Photobiology. 64: 764-8. PMID 8931373 DOI: 10.1111/J.1751-1097.1996.Tb01832.X |
0.357 |
|
1996 |
Robbins RJ, Laman DM, Falvey DE. Substituent effects on the lifetimes and reactivities of arylnitrenium ions studied by laser flash photolysis and photothermal beam deflection Journal of the American Chemical Society. 118: 8127-8135. DOI: 10.1021/Ja961518Z |
0.403 |
|
1996 |
Moran RJ, Falvey DE. Photogenerated diarylnitrenium ions: Laser flash photolysis and product studies on diphenylnitrenium ion generated from photolysis of 1-(N,N-diphenylamino)pyridinium ions Journal of the American Chemical Society. 118: 8965-8966. DOI: 10.1021/Ja961086S |
0.498 |
|
1996 |
Srivastava S, Falvey DE. Photolysis of 3-hydroxy-2,3-dihydro-2,1-benzisoxazole derivatives studied by EPR spectroscopy: Competing N-O and C-O bond scission Tetrahedron Letters. 37: 2895-2898. DOI: 10.1016/0040-4039(96)00438-8 |
0.323 |
|
1996 |
Chiapperino D, Anderson GB, Robbins RJ, Falvey DE. Photochemically generated arylnitrenium ions: Laser flash photolysis and product studies of the photochemistry of N-tert-butyl-3-methyl-6-chloroanthranilium ions Journal of Organic Chemistry. 61: 3195-3199. |
0.831 |
|
1995 |
Srivastava S, Falvey DE. Reactions of a triplet arylnitrenium ion: Laser flash photolysis and product studies of N-tert-butyl(2-acetyl-4-nitrophenyl)nitrenium ion Journal of the American Chemical Society. 117: 10186-10193. DOI: 10.1021/Ja00146A003 |
0.512 |
|
1995 |
Robbins RJ, Yang LL-, Anderson GB, Falvey DE. Photogenerated Arylnitrenium Ions: Reactions of N-tert-Butyl(4-substituted 2-acetylphenyl)nitrenium Ions with Alcohols and Water Studied by Laser Flash Photolysis Journal of the American Chemical Society. 117: 6544-6552. DOI: 10.1021/Ja00129A019 |
0.48 |
|
1995 |
Robbins RJ, Yang LLN, Anderson GB, Falvey DE. Photogenerated arylnitrenium ions: Reactions of N-tert-butyl (2-acetyl-4-substituted)phenyl nitrenium ions with alcohols and water studied by laser flash photolysis Journal of the American Chemical Society. 117: 6544-6552. |
0.383 |
|
1994 |
Fenick DJ, Falvey DE. Free radical rearrangements in uracil derivatives Journal of Organic Chemistry. 59: 4791-4799. DOI: 10.1021/Jo00096A021 |
0.37 |
|
1994 |
Robbins RJ, Falvey DE. Photogenerated nitrenium ions: Singlet and triplet state reactions of tert-butyl-(2-acetyl-4-methyl)phenyl nitrenium ion Tetrahedron Letters. 35: 4943-4946. DOI: 10.1016/S0040-4039(00)73288-6 |
0.437 |
|
1993 |
Robbins RJ, Falvey DE. Radical anion reactions of cyclobutane derivatives: Electron-transfer cleavage of dithymoquinone Journal of Organic Chemistry. 58: 3616-3618. DOI: 10.1021/Jo00066A009 |
0.401 |
|
1993 |
Anderson GB, Falvey DE. Photogenerated arylnitrenium ions: absorption spectra and absolute rate constants for tert-butyl(4-halo-2-acetylphenyl)nitrenium ions measured by time-resolved laser spectroscopy Journal of the American Chemical Society. 115: 9870-9871. DOI: 10.1021/Ja00074A092 |
0.443 |
|
1993 |
Anderson GB, Yang LLN, Falvey DE. Photogenerated arylnitrenium ions: Photoisomerization of the N-tert-butyl-S-methylanthranilium ion and spin-selective reactivity of the isomeric arylnitrenium ion Journal of the American Chemical Society. 115: 7254-7262. DOI: 10.1021/Ja00069A026 |
0.494 |
|
1991 |
Yeh SR, Falvey DE. Model studies of DNA photorepair: Radical anion cleavage of thymine dimers probed by nanosecond laser spectroscopy Journal of the American Chemical Society. 113: 8557-8558. DOI: 10.1021/Ja00022A072 |
0.318 |
|
1990 |
Falvey DE, Khambatta BS, Schuster GB. Neophyl-like rearrangement of alkoxy radicals: Direct detection of a bridged intermediate by time-resolved absorption spectroscopy Journal of Physical Chemistry. 94: 1056-1059. DOI: 10.1021/J100366A006 |
0.499 |
|
1988 |
Shields CJ, Falvey DE, Schuster GB, Buchardt O, Nielsen PE. Competitive singlet-singlet energy transfer and electron transfer activation of aryl azides: Application to photo-cross-linking experiments Journal of Organic Chemistry. 53: 3501-3507. DOI: 10.1021/Jo00250A017 |
0.536 |
|
1987 |
Rak SF, Lapin SC, Falvey DE, Schuster GB. Investigation of the 2,7-dihalofluorenylidenes: Search for heavy atom effects in the reactions of triplet carbenes Journal of the American Chemical Society. 109: 5003-5008. DOI: 10.1021/Ja00250A039 |
0.476 |
|
1986 |
Falvey DE, Schuster GB. Picosecond time scale dynamics of perester photodecomposition: Evidence for an acyloxy radical intermediate in the photolysis of tert-butyl 9-methylfluorene-9-percarboxylate Journal of the American Chemical Society. 108: 7419-7420. DOI: 10.1021/Ja00283A053 |
0.478 |
|
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