| Year |
Citation |
Score |
| 2018 |
Fernández-Sánchez L, Fernández-Salas JA, Maestro MC, García Ruano JL. Reformatsky Reaction to Alkynyl N- tert-Butanesulfinyl Imines: Lewis Acid Controlled Stereodivergent Synthesis of β-Alkynyl-β-Amino Acids. The Journal of Organic Chemistry. PMID 30216719 DOI: 10.1021/acs.joc.8b01918 |
0.3 |
|
| 2017 |
Esteban F, Boughani L, García Ruano JL, Fraile A, Alemán J. "Anti-Michael addition" of Grignard reagents to sulfonylacetylenes: synthesis of alkynes. Organic & Biomolecular Chemistry. PMID 28422251 DOI: 10.1039/C7Ob00783C |
0.325 |
|
| 2016 |
Rodrigo E, Alonso I, García Ruano JL, Cid MB. Expanding the Potential of Heteroaryl Vinyl Sulfones. The Journal of Organic Chemistry. PMID 27766863 DOI: 10.1021/acs.joc.6b01956 |
0.334 |
|
| 2016 |
Morales S, Aceña JL, García Ruano JL, Cid MB. Sustainable Synthesis of Oximes, Hydrazones, and Thiosemicarbazones under Mild Organocatalyzed Reaction Conditions. The Journal of Organic Chemistry. 81: 10016-10022. PMID 27668816 DOI: 10.1021/acs.joc.6b01912 |
0.409 |
|
| 2016 |
Valderas C, Marzo L, de la Torre MC, García Ruano JL, Alemán J, Casarrubios L, Sierra MA. Mono- and Bimetallic Alkynyl Metallocenes and Half-Sandwich Complexes: A Simple and Versatile Synthetic Approach. Chemistry (Weinheim An Der Bergstrasse, Germany). 22: 15645-15649. PMID 27595563 DOI: 10.1002/Chem.201603462 |
0.326 |
|
| 2014 |
Parra A, Amenós L, Guisán-Ceinos M, López A, García Ruano JL, Tortosa M. Copper-catalyzed diastereo- and enantioselective desymmetrization of cyclopropenes: synthesis of cyclopropylboronates. Journal of the American Chemical Society. 136: 15833-6. PMID 25340304 DOI: 10.1021/Ja510419Z |
0.365 |
|
| 2014 |
Arroyo Y, Sanz-Tejedor MA, Parra A, Alonso I, García Ruano JL. Asymmetric nucleophilic monofluorobenzylation of allyl and propargyl halides mediated by a remote sulfinyl group: synthesis of homoallylic and homopropargylic fluorides. The Journal of Organic Chemistry. 79: 6970-7. PMID 24977923 DOI: 10.1021/jo501096f |
0.399 |
|
| 2013 |
Rodrigo E, García Ruano JL, Cid MB. Organocatalytic Michael addition/intramolecular Julia-Kocienski olefination for the preparation of nitrocyclohexenes. The Journal of Organic Chemistry. 78: 10737-46. PMID 24063759 DOI: 10.1021/jo401686u |
0.411 |
|
| 2012 |
Alfaro R, Parra A, Alemán J, García Ruano JL, Tortosa M. Copper(I)-catalyzed formal carboboration of alkynes: synthesis of tri- and tetrasubstituted vinylboronates. Journal of the American Chemical Society. 134: 15165-8. PMID 22950573 DOI: 10.1021/Ja307670K |
0.371 |
|
| 2012 |
Parra A, Alfaro R, Marzo L, Moreno-Carrasco A, García Ruano JL, Alemán J. Enantioselective aza-Henry reactions of cyclic α-carbonyl ketimines under bifunctional catalysis. Chemical Communications (Cambridge, England). 48: 9759-61. PMID 22918139 DOI: 10.1039/C2Cc34053D |
0.443 |
|
| 2012 |
García Ruano JL, Marzo L, Marcos V, Alvarado C, Alemán J. Highly stereoselective synthesis of tertiary propargylic centers and their isomerization to enantiomerically enriched allenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 9775-9. PMID 22847833 DOI: 10.1002/Chem.201201607 |
0.654 |
|
| 2012 |
García Ruano JL, Torrente E, Parra A, Alemán J, Martín-Castro AM. Asymmetric intramolecular Pauson-Khand reaction mediated by a remote sulfenyl or sulfinyl group. The Journal of Organic Chemistry. 77: 6583-99. PMID 22804714 DOI: 10.1021/Jo3011039 |
0.438 |
|
| 2012 |
García Ruano JL, Alemán J, Marzo L, Alvarado C, Tortosa M, Díaz-Tendero S, Fraile A. Expanding the scope of arylsulfonylacetylenes as alkynylating reagents and mechanistic insights in the formation of Csp2-Csp and Csp3-Csp bonds from organolithiums. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 8414-22. PMID 22674492 DOI: 10.1002/Chem.201200939 |
0.341 |
|
| 2012 |
García Ruano JL, Fernández-Salas JA, Maestro MC. Stereocontrolled fluorobenzylation of vinyl sulfones and α,β-unsaturated esters mediated by a remote sulfinyl group. Synthesis of functionalized enantiomerically pure benzylic fluorides. The Journal of Organic Chemistry. 77: 2893-900. PMID 22352832 DOI: 10.1021/jo300174k |
0.355 |
|
| 2011 |
Fustero S, Sánchez-Roselló M, Báez C, Del Pozo C, García Ruano JL, Alemán J, Marzo L, Parra A. Asymmetric synthesis of quaternary α-amino acid derivatives and their fluorinated analogues. Amino Acids. 41: 559-73. PMID 21424810 DOI: 10.1007/S00726-011-0881-7 |
0.327 |
|
| 2010 |
García Ruano JL, Schöpping C, Alvarado C, Alemán J. Synthesis of unfunctionalized carbonated fragments containing two vicinal chiral centers: stereocontrolled benzylation of vinylsulfones mediated by a remote sulfinyl group. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 8968-71. PMID 20623808 DOI: 10.1002/Chem.201001006 |
0.314 |
|
| 2010 |
Arroyo Y, Meana A, Sanz-Tejedor MA, Alonso I, García Ruano JL. 2-(p-Tolylsulfinyl)benzyl halides as efficient precursors of optically pure trans-2,3-disubstituted aziridines. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 9874-83. PMID 20391562 DOI: 10.1002/chem.201000217 |
0.414 |
|
| 2009 |
García Ruano JL, Marcos V, Alemán J. The organocatalytic addition of bis(arylsulfonyl)methane to alpha,beta-unsaturated aldehydes and the synthesis of optically-enriched 3-methyl-alkanols. Chemical Communications (Cambridge, England). 4435-7. PMID 19597617 DOI: 10.1039/B908963B |
0.602 |
|
| 2009 |
García Ruano JL, Parra A, Marcos V, del Pozo C, Catalán S, Monteagudo S, Fustero S, Poveda A. Asymmetric synthesis of indolines through intramolecular shifting of aromatic sulfinyl groups. Role of the pi,pi-stacking interactions in these unusual S(N)Ar processes. Journal of the American Chemical Society. 131: 9432-41. PMID 19527024 DOI: 10.1021/ja8096527 |
0.653 |
|
| 2009 |
García Ruano JL, Marcos V, Suanzes JA, Marzo L, Alemán J. One-pot synthesis of pentasubstituted cyclohexanes by a Michael addition followed by a tandem inter-intra double Henry reaction. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 6576-80. PMID 19492386 DOI: 10.1002/Chem.200900894 |
0.62 |
|
| 2009 |
Arroyo Y, Meana A, Rodríguez JF, Sanz-Tejedor MA, Alonso I, García Ruano JL. Stereoselective control of planar alpha-dimethylsulfonium benzyl carbanions. Synthesis of optically pure trans-aziridines. The Journal of Organic Chemistry. 74: 4217-24. PMID 19422209 DOI: 10.1021/jo900381b |
0.408 |
|
| 2009 |
Cruz Cruz D, Yuste F, Martín MR, Tito A, García Ruano JL. 1,3-dipolar cycloaddition of diazoalkanes to (S)-(+)-3-[(4-methylphenyl)sulfinyl]-5,6-dihydropyran-2-one. Synthesis of optically pure cyclopropanes by denitrogenation of sulfinyl and sulfonyl pyrazolines. The Journal of Organic Chemistry. 74: 3820-6. PMID 19374392 DOI: 10.1021/jo900525s |
0.615 |
|
| 2009 |
García Ruano JL, Alemán J, Parra A, Alcudia A, Maya C. Synthesis and stereoselective halogenolysis of optically pure benzylstannanes. The Journal of Organic Chemistry. 74: 2145-52. PMID 19209914 DOI: 10.1021/Jo802725R |
0.544 |
|
| 2009 |
García Ruano JL, Fernández-Ibáñez MA, Fernández-Salas JA, Maestro MC, Márquez-López P, Rodríguez-Fernández MM. Remote stereocontrol mediated by a sulfinyl group: synthesis of allylic alcohols via chemoselective and diastereoselective reduction of gamma-methylene delta-ketosulfoxides. The Journal of Organic Chemistry. 74: 1200-4. PMID 19113884 DOI: 10.1021/jo802378s |
0.419 |
|
| 2009 |
Arroyo Y, Meana A, Sanz-Tejedor MA, Alonso I, García Ruano JL. Stereoselective addition of alpha-methylsulfenyl benzyl carbanions to N-sulfinylketimines: asymmetric synthesis of alpha,alpha-dibranched beta-sulfanyl amines. The Journal of Organic Chemistry. 74: 764-72. PMID 19035765 DOI: 10.1021/jo802200f |
0.338 |
|
| 2009 |
García Ruano JL, Duce S, Alemán J, López-Cantarero J, Remuiñán MJ, Cid MB. The role of the sulfinyl group in the copper catalyzed benzyl reactions from 2-p-tolylsulfinylbenzylstannanes Journal of Sulfur Chemistry. 30: 370-376. DOI: 10.1080/17415990902998595 |
0.319 |
|
| 2008 |
García Ruano JL, Núñez A, Martín MR, Fraile A. Totally regio- and stereoselective behavior of mono- and diactivated cyclic alkenes in the Lu reaction: synthesis of enantiopure functionalized cyclopentanes. The Journal of Organic Chemistry. 73: 9366-71. PMID 18954109 DOI: 10.1021/jo801896a |
0.336 |
|
| 2008 |
García Ruano JL, Alemán J, Catalán S, Marcos V, Monteagudo S, Parra A, Del Pozo C, Fustero S. Anionic-anionic asymmetric tandem reactions: one-pot synthesis of optically pure fluorinated indolines from 2-p-tolylsulfinyl alkylbenzenes. Angewandte Chemie (International Ed. in English). 47: 7941-4. PMID 18780405 DOI: 10.1002/Anie.200802885 |
0.696 |
|
| 2008 |
García Ruano JL, Marcos V, Alemán J. Configurational control of benzyl carbanion-copper complexes by sulfinyl groups: synthesis of optically pure allenes with central and axial chirality. Angewandte Chemie (International Ed. in English). 47: 6836-9. PMID 18661466 DOI: 10.1002/Anie.200802158 |
0.667 |
|
| 2007 |
García Ruano JL, Alemán J, Alonso I, Parra A, Marcos V, Aguirre J. Pi-pi stacking versus steric effects in stereoselectivity control: highly diastereoselective synthesis of syn-1,2-diarylpropylamines. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 6179-95. PMID 17479999 DOI: 10.1002/Chem.200601893 |
0.634 |
|
| 2006 |
García Ruano JL, Fernández-Ibáñez MA, Maestro MC. Efficient trans-selectivity in the cyclocondensation of (S)-2-[2-(p-tolylsulfinyl)phenyl]acetaldehyde with activated dienes catalyzed by Yb(OTf)3. The Journal of Organic Chemistry. 71: 7683-9. PMID 16995674 DOI: 10.1021/jo061128n |
0.43 |
|
| 2005 |
García Ruano JL, Topp M, López-Cantarero J, Alemán J, Remuiñán MJ, Cid MB. Asymmetric aza-Henry reactions from N-p-tolylsulfinylimines. Organic Letters. 7: 4407-10. PMID 16178545 DOI: 10.1021/Ol051580D |
0.398 |
|
| 2005 |
García Ruano JL, Alemán J, Parra A. Highly stereoselective benzylation of N-sulfinylketimines. Journal of the American Chemical Society. 127: 13048-54. PMID 16159300 DOI: 10.1021/Ja0515203 |
0.488 |
|
| 2005 |
García Ruano JL, Martín-Castro AM, Tato F, Pastor CJ. New strategy for the asymmetric synthesis of phenyl ketone cyanohydrins: quaternization of cyanohydrins derived from 2-p-tolylsulfinyl benzaldehyde. The Journal of Organic Chemistry. 70: 7346-52. PMID 16122258 DOI: 10.1021/jo051029u |
0.332 |
|
| 2005 |
Arroyo Y, Meana A, Rodríguez JF, Santos M, Sanz-Tejedor MA, García Ruano JL. Synthesis of optically pure 1,2-diaryl- and 1,2-alkylaryl-1,2-amino sulfides. The Journal of Organic Chemistry. 70: 3914-20. PMID 15876079 DOI: 10.1021/jo050129x |
0.441 |
|
| 2004 |
García Ruano JL, Alemán J, del Prado M, Fernández I. Stereoselective addition of alpha-sulfinyl carbanions to N-p-tolylsulfinylketimines: synthesis of optically pure 1,2,2'-trialkyl-2-aminoethanols. The Journal of Organic Chemistry. 69: 4454-63. PMID 15202901 DOI: 10.1021/Jo049666S |
0.472 |
|
| 2004 |
García Ruano JL, Aleman J, Padwa A. A novel asymmetric vinylogous tin-Pummerer rearrangement. Organic Letters. 6: 1757-60. PMID 15151407 DOI: 10.1021/Ol0495725 |
0.383 |
|
| 2003 |
García Ruano JL, Alemán J. Stereocontrolled reactions mediated by a remote sulfoxide group: synthesis of optically pure anti-beta-amino alcohols. Organic Letters. 5: 4513-6. PMID 14602038 DOI: 10.1021/Ol0358410 |
0.394 |
|
| 2003 |
García Ruano JL, Alemán J, Soriano JF. Facile synthesis of optically pure 1,2-diaryl (and 1-Alkyl-2-aryl) ethyl and propylamines. Organic Letters. 5: 677-80. PMID 12605488 DOI: 10.1021/ol027464h |
0.535 |
|
| 2003 |
García Ruano JL, Alemparte C, Aranda MT, Zarzuelo MM. A general and expeditious one-pot synthesis of sulfoxides in high optical purity from norephedrine-derived sulfamidites. Organic Letters. 5: 75-8. PMID 12509894 DOI: 10.1021/ol027232i |
0.46 |
|
| 2002 |
García Ruano JL, Clemente FR, González Gutiérrez L, Gordillo R, Martín Castro AM, Rodríguez Ramos JH. Cyclic vinyl p-tolyl sulfilimines as chiral dienophiles: theoretical study on the stereoselectivity, Lewis acid catalysis, and solvent effects in their Diels-Alder reactions. The Journal of Organic Chemistry. 67: 2926-33. PMID 11975548 |
0.365 |
|
| 2002 |
García Ruano JL, Alemparte C, Clemente FR, González Gutiérrez L, Gordillo R, Martín Castro AM, Rodríguez Ramos JH. Cyclic vinyl p-tolyl sulfilimines as chiral dienophiles: Diels-Alder reactions with furan and acyclic dienes. The Journal of Organic Chemistry. 67: 2919-25. PMID 11975547 |
0.396 |
|
| 2002 |
García Ruano JL, Tito A, Peromingo MT. Asymmetric 1,3-dipolar cycloaddition of N-metalated azomethine ylides to methyl (S)-2-(p-tolylsulfinyl)acrylate. Synthesis of optically pure 2,4,5-trisubstituted 2,5-dihydro-1H-pyrroles. The Journal of Organic Chemistry. 67: 981-7. PMID 11856048 |
0.382 |
|
| 2002 |
García Ruano JL, Cifuentes García M, Martín Castro AM, Rodríguez Ramos JH. First highly stereoselective synthesis of fungicide systhane. Organic Letters. 4: 55-7. PMID 11772089 |
0.382 |
|
| 2001 |
García Ruano JL, Cifuentes García M, Laso NM, Martín Castro AM, Rodríguez Ramos JH. Stereoselective Hydrocyanation of Alkenyl Sulfoxides as a Method to Highly Enantiomerically Enriched Compounds with Tertiary and Quaternary Chiral Carbon Atoms. Angewandte Chemie (International Ed. in English). 40: 2507-2509. PMID 29712294 DOI: 10.1002/1521-3773(20010702)40:13<2507::AID-ANIE2507>3.0.CO;2-R |
0.31 |
|
| 2000 |
Carreño MC, García Ruano JL, Toledo MA. Enantioselective synthesis of (+)-royleanone from sulfinyl quinones. Chemistry (Weinheim An Der Bergstrasse, Germany). 6: 288-91. PMID 11931108 DOI: 10.1002/(SICI)1521-3765(20000117)6:2<288::AID-CHEM288>3.0.CO;2-2 |
0.401 |
|
| 1996 |
Carreño MC, García Ruano JL, Urbano A. Remote Regiocontrol by a Thioether Group in Diels-Alder Reactions of Naphthazarin: Regioselective Access to Tetracyclic Polyhydroxyquinones. The Journal of Organic Chemistry. 61: 6136-6138. PMID 11667447 |
0.331 |
|
| 1996 |
Carreño MC, García Ruano JL, Toledo MA, Urbano A, Remor CZ, Stefani V, Fischer J. Influence of the Sulfinyl Group on the Chemoselectivity and pi-Facial Selectivity of Diels-Alder Reactions of (S)-2-(p-Tolylsulfinyl)-1,4-benzoquinone. The Journal of Organic Chemistry. 61: 503-509. PMID 11666967 |
0.357 |
|
| 1996 |
Carreno MC, Garcia Ruano JL, Toledo MA, Urbano A, Remor CZ, Stefani V, Fischer J. Influence of the sulfinyl group on the chemoselectivity and π-facial selectivity of diels-alder reactions of (S)-2-(p Tolylsulfinyl)-1,4-benzoquinone Journal of Organic Chemistry. 61: 503-509. |
0.364 |
|
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