Jian Yuan, Ph.D.
Affiliations: | 2009 | Chemistry | Dartmouth College, Hanover, NH, United States |
Area:
Organometallic mechanism and synthesis, CF bond activation, catalysisGoogle:
"Jian Yuan"Mean distance: 11.45 | S | N | B | C | P |
Parents
Sign in to add mentorZhenfeng Xi | research assistant | 2003-2004 | Peking University | |
Russell P. Hughes | grad student | 2009 | Dartmouth | |
(Activation of carbon-fluorine bonds and carbon-hydrogen bonds with transition metal compounds.) | ||||
Richard Royce Schrock | post-doc | MIT |
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Publications
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Yuan J, Bourgeois CJ, Rheingold AL, et al. (2015) Synthesis, structure, and reactivity of iridium perfluorocarbene complexes: regio- and stereo-specific addition of HCl across a metal carbon double bond. Dalton Transactions (Cambridge, England : 2003) |
Yuan J, Hughes RP, Rheingold AL. (2015) A (pentafluoroethyl)(trifluoromethyl)carbene complex of iridium and reductive activation of its sp(3) α, β, and γ carbon-fluorine bonds to give perfluoro-2-butyne, perfluoro-1,2,3-butatriene and perfluoro-1-irida-2-methyl-2-cyclobutene) complexes. Dalton Transactions (Cambridge, England : 2003) |
Dobereiner GE, Yuan J, Schrock RR, et al. (2013) Catalytic synthesis of n-alkyl arenes through alkyl group cross-metathesis. Journal of the American Chemical Society. 135: 12572-5 |
Yuan J, Schrock RR, Gerber LCH, et al. (2013) Synthesis and ROMP chemistry of decafluoroterphenoxide molybdenum imido alkylidene and ethylene complexes Organometallics. 32: 2983-2992 |
Yuan J, Schrock RR, Müller P, et al. (2012) Pentafluorophenylimido alkylidene complexes of molybdenum and tungsten Organometallics. 31: 4650-4653 |
Yuan J, Hughes RP, Rheingold AL. (2011) Unexpected synthesis of a perfluoroacyl complex, Cp*Ir(CO)(COC 6F 11)Br, by direct fluoroalkylation of a CO ligand, and elimination of perfluorocyclohexene by activation of a γ-C-F bond Organometallics. 30: 1744-1746 |
Yuan J, Townsend EM, Schrock RR, et al. (2011) Preparation of tungsten-based olefin metathesis catalysts supported on alumina Advanced Synthesis and Catalysis. 353: 1985-1992 |
Yuan J, Hughes RP, Golen JA, et al. (2010) Synthesis and structural and computational studies of a conformationally locked (η1-Perfluoroalkylidene)(η2-alkene) transition metal complex: Ir(Cp*)(CFCF3)(C2H 4) Organometallics. 29: 1942-1947 |
Yuan J, Hughes RP, Rheingold AL. (2010) Synthesis and crystallographic characterization of dimeric perfluoroalkyl iridium complexes: [Cp*Ir(X)(RF)]2 (X = I, R F = CF3, CF2CF3, CF 2CF2CF3, CF(CF3)2, CF(CF3)(CF2CF3); X = Cl and Br, RF = CF2CF3) Inorganica Chimica Acta. 364: 96-101 |
Huang H, Hurubeanu NR, Bourgeois CJ, et al. (2009) Octahedral perfluoroalkyl complexes of Ir(III) formed by oxidative addition of perfluoroalkyl iodides to Ir(acac)(CO)2 Canadian Journal of Chemistry. 87: 151-160 |