Maurice S. Brookhart
Affiliations: | University of North Carolina, Chapel Hill, Chapel Hill, NC |
Area:
Synthetic Organometallic Chemistry, CatalysisWebsite:
http://www.chem.unc.edu/people/faculty/brookhart/Google:
"Maurice S. Brookhart"Bio:
http://www.nasonline.org/member-directory/members/2512664.html
Mean distance: 7.47 | S | N | B | C | P |
Parents
Sign in to add mentor| Saul Winstein | grad student | 1968 | UCLA | |
| (Direct observations of carbonium ions by NMR in strong acid media) | ||||
| Frank A.L. Anet | post-doc | 1968 | UCLA | |
Children
Sign in to add traineeCollaborators
Sign in to add collaborator| Malcolm L.H. Green | collaborator | 1983-1988 | |
| Joseph M. DeSimone | collaborator | 1991-2001 | UNC Chapel Hill |
| Gerard (Ged) F.R. Parkin | collaborator | 2007 | Columbia |
| Alan S. Goldman | collaborator | 2005-2012 | Rutgers, New Brunswick |
| Joseph L. Templeton | collaborator | 1990-2013 | UNC Chapel Hill |
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Publications
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| Daugulis O, Brookhart M, Janeta M, et al. (2020) 2,4,6-Triphenylpyridinium: A Bulky, Highly Electron-Withdrawing Substituent Which Enhances Properties of Nickel(II) Ethylene Polymerization Catalysts. Angewandte Chemie (International Ed. in English) |
| Han XW, Daugulis O, Brookhart M. (2020) Unsaturated Alcohols as Chain-Transfer Agents in Olefin Polymerization: Synthesis of Aldehyde End-Capped Oligomers and Polymers. Journal of the American Chemical Society |
| Tran QH, Brookhart M, Daugulis O. (2020) New Neutral Nickel and Palladium Sandwich Catalysts: Synthesis of Ultra-High Molecular Weight Polyethylene (UHMWPE) via Highly Controlled Polymerization and Mechanistic Studies of Chain Propagation. Journal of the American Chemical Society |
| Farquhar AH, Brookhart M, Miller AJM. (2020) Oligomerization and polymerization of 5-ethylidene-2-norbornene by cationic palladium and nickel catalysts Polymer Chemistry. 11: 2576-2584 |
| Kocen AL, Brookhart M, Daugulis O. (2019) A highly active Ni(II)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis. Nature Communications. 10: 438 |
| Böhm VP, Brookhart M. (2019) Dehydrocoupling of Phosphanes Catalyzed by a Rhodium(I) Complex We thank the National Institutes of Health (NIH) for financial support and O. Daugulis for samples of dimesitylphosphane and 2,4,6-tri-tert-butylphenylphosphane. V.P.W.B. acknowledges a Feodor Lynen fellowship of the Alexander-von-Humboldt-Stiftung (Germany). Angewandte Chemie (International Ed. in English). 40: 4694-4696 |
| Chen Z, Brookhart M. (2018) Exploring Ethylene/Polar Vinyl Monomer Copolymerizations Using Ni and Pd α-Diimine Catalysts. Accounts of Chemical Research |
| Chen Z, Leatherman MD, Daugulis O, et al. (2017) Nickel-Catalyzed Copolymerization of Ethylene and Vinyltrialkoxysilanes: Catalytic Production of Cross-Linkable Polyethylene and Elucidation of the Chain-Growth Mechanism. Journal of the American Chemical Society |
| Kocen AL, Brookhart M, Daugulis O. (2017) Palladium-catalysed alkene chain-running isomerization. Chemical Communications (Cambridge, England) |
| Bézier D, Daugulis O, Brookhart M. (2017) Polymerization of Ethylene Catalyzed by Phosphine-Iminophosphorane Palladium Complexes Organometallics. 36: 2947-2951 |