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Year Citation  Score
2003 Beachley OT, MacRae DJ, Churchill MR, Kovalevsky AY, Robirds ES. Cyclopentadiene elimination reactions for the preparation of organoindium(III) derivatives. Crystal and molecular structures of Me2In(acac), (Me3CCH2)2In(acac), (Me)(Me3CCH2)In(acac), and [Me2InNH(t-Bu)]2 Organometallics. 22: 3991-4000. DOI: 10.1021/Om0304154  0.321
2003 Beachley OT, Gardinier JR, Churchill MR. Chemistry of some dihalogallium(III) β-diketonate derivatives. Crystal and molecular structures of GaCl2(acac), GaCl2(tmhd), and [trans-Ga(acac)2(THF)2 +][GaCl4 - ] Organometallics. 22: 1145-1151. DOI: 10.1021/Om0209226  0.397
2003 Pérez J, Riera L, Riera V, García-Granda S, García-Rodríguez E, Churchill DG, Churchill MR, Janik TS. New tetrahedrane complexes from molybdenum alkynyls and Co2(CO)8 Inorganica Chimica Acta. 347: 189-193. DOI: 10.1016/S0020-1693(02)01442-1  0.752
2002 Beachley OT, Gardinier JR, Churchill MR, Churchill DG, Keil KM. Monomeric gallium(III) compounds containing three different ligands. Crystal and molecular structures of GaMeCl(acac) and GaCl[N(SiMe3)2](acac) Organometallics. 21: 946-951. DOI: 10.1021/Om010681M  0.404
2002 Churchill MR, Landers AG, Rheingold AL. CRYSTAL STRUCTURE AND MOLECULAR GEOMETRY OF ((η5‐C5H5)2FE)2AS4CL10O2, THE FERROCENIUM SALT OF A COMPLEX OXYCHLOROARSENATE(III) COUNTERION Cheminform. 12. DOI: 10.1002/Chin.198122084  0.526
2001 Huynh MH, Lasker JM, Wetzler M, Mort B, Szczepura LF, Witham LM, Cintron JM, Marschilok AC, Ackerman LJ, Castellano RK, Jameson DL, Churchill MR, Jircitano AJ, Takeuchi KJ. Remarkable spectator ligand effect on the rate constant of ligand substitution of (aqua)ruthenium(II) complexes. Journal of the American Chemical Society. 123: 8780-4. PMID 11535083 DOI: 10.1021/Ja0041977  0.391
2001 Churchill MR, Keil KM, Gilmartin BP, Schuster JJ, Keister JB, Janik TS. Linkage and redox isomerism in ruthenium complexes of catecholate, semi-quinone, and o-acylphenolate ligands derived from tri- and tetrahydroxy-9,10-anthracenediones. Inorganic Chemistry. 40: 4361-7. PMID 11487343 DOI: 10.1021/Ic010068V  0.742
2001 Epstein DM, Choudhary S, Churchill MR, Keil KM, Eliseev AV, Morrow JR. Chloroform-soluble schiff-base Zn(II) or Cd(II) complexes from a dynamic combinatorial library. Inorganic Chemistry. 40: 1591-6. PMID 11261969 DOI: 10.1021/Ic000938T  0.356
2001 Churchill MR, Keil KM, Janik TS, Willoughby MC. Synthesis of a dinuclear ylid complex derived from P(OPh)3: Crystal structures of [Cp2Fe2(CO)2(μ-CO) (μ-CHP(OPh)3)+][BF4 -] and [Cp2Fe2(CO)2 (μ-CO)(μ-CHPPH3)+][BF4 -] Journal of Coordination Chemistry. 52: 229-244. DOI: 10.1080/00958970108022589  0.759
2001 Beachley OT, Chao SHL, Churchill MR, Lake CH. Reactions of neopentylindium(III) derivatives with isopropylphosphorus compounds Organometallics. 20: 4896-4902. DOI: 10.1021/Om0101902  0.665
2001 Beachley OT, Mosscrop MT, Churchill MR. Chemistry of (tetramethylcyclopentadienyl)gallium(III) compounds Journal of Organometallic Chemistry. 626: 59-67. DOI: 10.1016/S0022-328X(01)00661-1  0.33
2001 Voss DA, Buttrey-Thomas LA, Janik TS, Churchill MR, Morrow JR. Lanthanide(III) hexaaza macrocyclic Schiff-base complexes and their decomposition in aqueous solution Inorganica Chimica Acta. 317: 149-156. DOI: 10.1016/S0020-1693(01)00345-0  0.69
2001 Huynh MHV, Smyth J, Wetzler M, Mort B, Gong PK, Witham LM, Jameson DL, Geiger DK, Lasker JM, Charepoo M, Gornikiewicz M, Cintron JM, Imahori G, Sanchez RR, Marschilok AC, ... ... Churchill MR, et al. Remarkable Rate Enhancement of Ligand Substitution Promoted by Geometrical Arrangement of Tridentate “Spectator” Ligands Angewandte Chemie. 113: 4601-4605. DOI: 10.1002/1521-3757(20011203)113:23<4601::Aid-Ange4601>3.0.Co;2-W  0.304
2000 Churchill MR, Keil KM, Bright FV, Pandey S, Baker GA, Keister JB. Linkage and redox isomerism in ruthenium complexes of catecholate, semiquinone, and o-acylphenolate ligands derived from 1,2-dihydroxy-9,10-anthracenedione (alizarin) and related species: syntheses, characterizations, and photophysics. Inorganic Chemistry. 39: 5807-16. PMID 11151384 DOI: 10.1021/Ic000529X  0.322
2000 Churchill MR, Lake CH, Buttrey LA, Morrow JR. Synthesis and crystallographic characterization of [Eu(C18H18N6)(OAc)2 +][Cl-] ̇ 7H2O, a ten-coordinate Eu(III) complex with a close-to-planar hexadentate C18H18N6 ligand: An interesting case of a structure with multiple disorder problems Journal of Coordination Chemistry. 50: 339-352. DOI: 10.1080/00958970008054939  0.748
2000 Churchill MR, Lake CH, Beachley OT, Noble MJ. Characterization of gallium-nitrogen adducts by X-ray structural and NMR spectral studies. Crystal structure of [(PhMe2CCH2)2GaCl]2 and of its monomeric t-butylamine adduct, (PhMe2CCH2)2GaCl[NH2(t-Bu)] Journal of Coordination Chemistry. 49: 309-324. DOI: 10.1080/00958970008022241  0.406
2000 Churchill MR, Churchill DG, Huynh MHV, Takeuchi KJ. Crystal structure of cis-[Ru(bpy)2{PMe(o-tol)2}Cl+][ClO- 4]: Steric effects in some PMen(o-tol)3-n (n = 1-3) derivatives of ruthenium(II) Journal of Chemical Crystallography. 30: 17-21. DOI: 10.1023/A:1009585713855  0.378
2000 Beachley, OT, Gardinier JR, Churchill MR. Gallium(II) Compounds Stabilized by β-Diketonate Ligands:  Synthesis, Characterization, and X-ray Structural Studies of [GaCl(acac)]2and [GaCl(tmhd)]2 Organometallics. 19: 4544-4549. DOI: 10.1021/Om0000764  0.363
2000 Davies HML, Stafford DG, Hansen T, Churchill MR, Keil KM. Effect of carbenoid structure on the reactions of rhodium-stabilized carbenoids with cycloheptatriene Tetrahedron Letters. 41: 2035-2038. DOI: 10.1016/S0040-4039(00)00104-0  0.302
1999 Churchill MR, Hall R, Lake CH, Toomey LM, Keister JB. LIGAND SUBSTITUTION ON HRu3(μ-NC5H3CO2Me)(CO)10AND H2Ru3(μ-NC5H3CO2Me)2(CO)8. CRYSTAL STRUCTURES OF (μ-H)Ru3(μ-η2-NC5H3CO2Me)(CO)9(PPh3)AND (μ-H)2Ru3(μ-η2-NC5H3CO2Me)2(CO)7(PPh3)∗ Journal of Coordination Chemistry. 47: 211-229. DOI: 10.1080/00958979908023055  0.415
1999 Perez WJ, Lake CH, See RF, Toomey LM, Churchill MR, Takeuchi KJ, Radano CP, Boyko WJ, Bessel CA. In situ syntheses of trans-spanned octahedral ruthenium complexes. Crystal structures of trans-[Ru(Cl)(trpy){Ph2PC6H4CH2O(CO)(CH2)4(CO)OCH2C6H4PPh2}][PF6]·0.25C6H5Me·0.5CH2Cl2 and trans-[Ru(Cl)(trpy)(PPh3)2][BF4]·CH2Cl2† Journal of the Chemical Society-Dalton Transactions. 2281-2292. DOI: 10.1039/A807574C  0.765
1999 Churchill MR, Churchill DG, Matasi JJ, Davies HM. Journal of Chemical Crystallography. 29: 1061-1066. DOI: 10.1023/A:1009589220678  0.36
1999 Churchill MR, Churchill DG, Ahmed G, Davies HM. Journal of Chemical Crystallography. 29: 713-717. DOI: 10.1023/A:1009584122919  0.337
1999 Churchill MR, Churchill DG, Ahmed G, Davies HM. Journal of Chemical Crystallography. 29: 707-711. DOI: 10.1023/A:1009532106081  0.33
1999 Churchill MR, Churchill DG, Huynh MHV, Takeuchi KJ, Distefano AJ, Jameson DL. Crystal and molecular structure of the symmetrical bidentate ligand 3,3-di(1-pyrazolyl)pentane, CH3CH2C(C3H3N2)2CH2CH3 Journal of Chemical Crystallography. 29: 463-467. DOI: 10.1023/A:1009523312846  0.407
1999 Churchill MR, Churchill DG, Huynh MHV, Takeuchi KJ, Distefano AJ, Jameson DL. Synthesis and crystal structures of two potential gem-di(pyrazolyl)cycloalkane ligands, 1,1-di(pyrazol-1-yl)cyclohexane [C6H10(C3N2H3)2] and 1,1-di(pyrazol-1-yl)cyclopentane [C5H8(C3N2H3)2] Journal of Chemical Crystallography. 29: 659-665. DOI: 10.1023/A:1009515602446  0.432
1999 Beachley OT, Rosenblum DB, Churchill MR, Churchill DG, Krajkowski LM. Monomeric organogallium-nitrogen compounds. Chemistry of Et2GaNH[C6H2(2,4,6-t-Bu)3] with decomposition to the metallacycle {EtGaNH[C6H2(4,6-t-Bu)2CMe2CH 2-2]}2 and of EtGa{NH[C6H2(2,4,6-t-Bu)3]}2 Organometallics. 18: 2543-2549. DOI: 10.1021/Om990136+  0.345
1999 Churchill MR, Hall R, Lake CH, Toomey LM, Keister JB. Ligand substitution on HRu3(μ-NC5H3CO2Me)(CO) 10 and H2Ru3(μ-NC5H3CO 2Me)2(CO)8. Crystal structures of (μ-H)Ru3(μ-η2-NC5H3CO 2Me)(CO)9(PPh3) Journal of Coordination Chemistry. 47: 211-229.  0.394
1999 Perez WJ, Lake CH, See RF, Toomey LM, Churchill MR, Takeuchi KJ, Radano CP, Boyko WJ, Bessel CA. In situ syntheses of trans-spanned octahedral ruthenium complexes. Crystal structures of Journal of the Chemical Society - Dalton Transactions. 2281-2292.  0.382
1998 Rominger RL, See RF, Lake CH, Churchill MR, Atwood JD. IRIDIUM COMPLEXES OF AMPHOS (AMPHOS = [PPh2CH2CH2NMe3 +]I−): CRYSTAL AND MOLECULAR STRUCTURES OF trans-Ir(CO)(CI)(PPh2CH2CH2NMe2)2 AND [trans-Ir(CO)(Cl)(PPh2CH2CH2NMe3)2 2+][I−]2·2DMSO Journal of Coordination Chemistry. 46: 165-181. DOI: 10.1080/00958979808053728  0.431
1998 Beachley, OT, Noble MJ, Churchill MR, Lake CH. Gallium−Nitrogen Compounds Prepared By Dihydronaphthalene and Thermal Elimination Reactions. Crystal and Molecular Structures of [(PhMe2CCH2)2GaNH(t-Bu)]2and [(H4C6)Me2CCH2]Ga[NH(t-Bu)]2Ga(CH2CMe2Ph)2 Organometallics. 17: 5153-5159. DOI: 10.1021/Om980492C  0.687
1998 Beachley OT, Noble MJ, Churchill MR, Lake CH. The dihydronaphthalene elimination reaction as a route to gallium-nitrogen compounds. Crystal and molecular structure of [(PhMe2CCH2)2GaNHPh]2 Organometallics. 17: 3311-3315. DOI: 10.1021/Om9801249  0.715
1998 Beachley OT, Gardinier JR, Churchill MR, Toomey LM. Diorganogallium Beta -Diketonates And Their Lewis Acid-Base Adducts. Crystal And Molecular Structures Of Mes2Ga(Hfac) And Me2Ga(Hfac).Nc5H5 Organometallics. 17: 1101-1108. DOI: 10.1021/Om970988E  0.415
1998 Miguel D, Moreno M, Perez J, Riera V, Churchill DG, Churchill MR, Janik TS. Synthesis of a tetrametallic acetylene. X-ray structures of [{CO)3Mo(μ-S2CPCy3)Mn(CO)3}2- (μ4-η1:η1:η(1'):η(1')-C2)] and [[(CO)3Mo(μ-CCPh)(μ-S2CPCy3)Mn(CO)3] Journal of the American Chemical Society. 120: 417-418. DOI: 10.1021/Ja9725155  0.747
1998 Rominger RL, See RF, Lake CH, Churchill MR, Atwood JD. Iridium complexes of amphos(amphos = [PPh2CH2 CH2NMe3 +]I-):Crystal and molecular structures of trans-Ir(CO)(Cl)(PPh2CH2CH2NMe 2)2 and [trans-Ir(CO)(Cl)(PPh2CH2 CH2NMe3)2 2+][I-] 2·2DMSO Journal of Coordination Chemistry. 46: 165-181.  0.371
1997 See RF, Churchill MR, Lance KA, Mersman DP, Williams KR. The crystal structure of Fe(II)((dpg)3(BF)2) · 2toluene; a study in the geometry of strained clathro-chelate compounds Inorganica Chimica Acta. 257: 285-290. DOI: 10.1016/S0020-1693(96)05488-6  0.407
1997 Churchill MR, Krajkowski LM, Huynh MHV, Takeuchi KJ. X-ray diffraction studies on cis-[Ru(bpy)2(PMe3)Cl+][ClO4-] and cis-[Ru(bpy)2{PMe2(o-tol)}Cl+][ClO 4 -]; two ordered structures in the cis-bis(bipyridyl)chloro(phosphine)-ruthenium(II) series Journal of Chemical Crystallography. 27: 589-597. DOI: 10.1007/Bf02576457  0.424
1997 Churchill DG, Churchill MR, Janik TS. Synthesis and crystal structure of [{CpFe(CO)}2(μ-CO)-(μ-CHPMe3)+][PF 6 − ] Journal of Chemical Crystallography. 27: 667-671. DOI: 10.1007/Bf02576410  0.715
1997 Churchill MR, Janik TS, Chin KOA, Morrow JR. Crystal and molecular structure of the triflate salt of diprotonated 1,4,8,11-tetrakis(2-hydroxyethyl)-1,4,8,11-tetraazacyclotetradecane, [C10H22N4(CH2CH2OH) 4 2+]-[CF3SO3 -] 2: Geometry of a diprotonated octadentate ligand Journal of Chemical Crystallography. 27: 319-324. DOI: 10.1007/Bf02575980  0.426
1997 Churchill DG, Churchill MR, Janik TS. Synthesis and crystal structure of [{CpFe(CO)}2(μ-CO)-(μ-CHPMe3)+][PF - 6] Journal of Chemical Crystallography. 27: 667-671.  0.373
1996 Szczepura LF, Kubow SA, Leising RA, Perez WJ, Huynh MHV, Lake CH, Churchill DG, Churchill MR, Takeuchi KJ. Synthesis, characterization and redox properties of mixed phosphine nitroruthenium(II) complexes. Crystal structure of trans-[Ru(NO2)(terpy)-(PMe3)(PPh3)][ClO 4]·H2O Journal of the Chemical Society - Dalton Transactions. 1463-1470. DOI: 10.1039/Dt9960001463  0.746
1996 Beachley OT, Rosenblum DB, Churchill MR, Lake CH, Toomey LM. Room temperature cyclopentadiene elimination reaction for the synthesis of diethylgallium-amides, -phosphides, and -thiolates. Crystal and molecular structures of [Et2GaP(t-Bu)2]2 and [Et2GaS(SiPh3)]2 Organometallics. 15: 3653-3658. DOI: 10.1021/Om960284P  0.709
1996 Beachley OT, Chao SHL, Churchill MR, Lake CH. Synthesis, characterization, and X-ray structural study of a dinuclear organoindium phosphide complex with two different phosphide moieties, (Me3CCH2)2InP(t-Bu)2In(CH 2CMe3)2PPh2 Organometallics. 15: 3088-3091. DOI: 10.1021/Om950986Z  0.717
1996 Miller CA, Janik TS, Churchill MR, Atwood JD. Reactions of Ir(CO)(H)(P(p-tolyl)3)3 with SO2 and O2 Mixtures and with H2SO4, Formation of a Sulfate-Bridged Dimer, and Crystal and Molecular Structure of Ir(CO)(H)(SO2)(P(p-tolyl)3)2 Inorganic Chemistry. 35: 3683-3686. DOI: 10.1021/Ic951249Y  0.694
1996 Churchill MR, See RF, Shuchart CE, Wojcicki A. Structure of (η5-C5H5)2Ru2Fe2(CO) 8(μ2-CO)(μ4-η6-C6H6): An unusual mixed-metal compound containing a bridging diallyl ligand derived by unsymmetrical coupling of two allenyl groups Journal of Organometallic Chemistry. 512: 189-196. DOI: 10.1016/0022-328X(95)06009-L  0.449
1996 Amin S, Marks C, Toomey LM, Churchill MR, Morrow JR. Synthesis and characterization of the yttrium(III) and lutetium(III) complexes of 1,4,7-tris(carbamoylmethyl)-1,4,7-triazacyclononane (TCMT). Crystal structure of [Y(TCMT)(CF3SO3)2(H2O)](CF 3SO3) Inorganica Chimica Acta. 246: 99-107. DOI: 10.1016/0020-1693(96)05056-6  0.438
1996 Shuchart CE, Calligaris M, Churchill MR, Faleschini P, See RF, Wojcicki A. Reaction of (η 1-allenyl)dicarbonyl(η 5-cyclopentadienyl)ruthenium with nonacarbonyldiiron: Synthesis and characterization of iron-ruthenium mixed-metal products 1 Inorganica Chimica Acta. 243: 109-120. DOI: 10.1016/0020-1693(95)04897-9  0.409
1996 Churchill MR, Krajkowski LM, Huynh MHV, Takeuchi KJ. A hydrogen-bonded dichloromethane-perchlorate-water channel in the crystal structure of cis-[Ru(bpy)2{PPh-(o-tolyl)2}Cl+][ClO 4 -]·CH2Cl2·H 2O Journal of Chemical Crystallography. 26: 67-73. DOI: 10.1007/Bf02018700  0.41
1996 Churchill MR, Korzenski MB, Janik TS. Synthesis and crystal structure of a dinuclear organometallic phosphonium ylid complex, [(η5-C5H5(CO)C2(ε-CO)(ε-CHP(C6H5)3)+][PF – 6 ] Journal of Chemical Crystallography. 26: 683-690. DOI: 10.1007/Bf01991964  0.745
1996 Churchill MR, See RF, Bessel CA, Takeuchi KJ. Crystal structure of the hemitoluene solvate of racemic cis-bis(bipyridyl)chloro(tri-n-propylphosphine)ruthenium(II) perchlorate, a species with disordered PPr3 and toluene moieties Journal of Chemical Crystallography. 26: 667-675. DOI: 10.1007/Bf01991962  0.428
1996 Churchill MR, Lake CH, Bessel CA, Huynh MHV, McCourt J, Takeuchi KJ. Synthesis ofcis-[Ru{4,4′-(t-Bu)2bpy}2(PPh3)Cl+][ClO 4 − ] and the crystal structure of its disordered hemiacetonitrile, hemitoluene solvate Journal of Chemical Crystallography. 26: 267-275. DOI: 10.1007/Bf01677780  0.73
1996 Churchill MR, Krajkowski LM, Huynh MHV, Takeuchi KJ. Crystal structure of cis-[Ru(bpy)2(PPh3)Cl+][ClO- 4]· (toluene)·∼0.5(CH2Cl2), a species with two different disordered solvent molecules of crystallization Journal of Chemical Crystallography. 26: 347-354. DOI: 10.1007/Bf01677099  0.422
1996 Churchill MR, Churchill DG, Huynh MHV, Takeuchi KJ, Castellano RK, Jameson DL. Crystal and molecular structure of the bidentate ligand 2,2-di(1-pyrazolyl)propane, CH3C(C3N2H3)2CH 3 Journal of Chemical Crystallography. 26: 179-183. DOI: 10.1007/Bf01673667  0.46
1996 Churchill MR, Krajkowski LM, Szczepura LF, Takeuchi KJ. Crystal structure ofmer,trans-[Ru(NO2)(trpy) (PPh3) 2 + ][PF 6 − ]: a “problem structure” Journal of Chemical Crystallography. 26: 853-859. DOI: 10.1007/Bf01670319  0.439
1996 Churchill MR, Krajkowski LM, Huynh MHV, Takeuchi KJ. Crystal structure of cis-[Ru(bpy)2{PPh2(o-tol)}Cl][ClO4] · 1.5(CH2Cl2), a structure containing both ordered and disordered dichloromethane molecules of crystallization Journal of Chemical Crystallography. 26: 111-116. DOI: 10.1007/Bf01669726  0.456
1996 Churchill MR, Churchill DG, Huynh MHV, Takeuchi KJ, Castellano RK, Jameson DL. Crystal and molecular structure of di(1-pyrazolyl)methane, CH2(C3N2H3)2 Journal of Chemical Crystallography. 26: 93-97. DOI: 10.1007/Bf01669723  0.401
1996 Churchill MR, See RF, Bessel CA, Takeuchi KJ. Crystal structure ofmer,trans-[Ru(NO2)(trpy)(PPr3) 2 + ][ClO 4 − ], a species with disordered PPr3 and NO2 ligands Journal of Chemical Crystallography. 26: 543-551. DOI: 10.1007/Bf01668413  0.411
1996 Churchill MR, Lake CH, Szczepura LF, Takeuchi KJ. Crystal structure of the methanol solvate of (η5-cyclopentadienyl)[1,2-bis(diphenylphosphino)ethane] nitroruthenium(II), Ru(η5-C5H5)(dppe)(NO2)·CH 3OH Journal of Chemical Crystallography. 26: 489-495. DOI: 10.1007/Bf01668310  0.467
1996 Churchill MR, See RF, Rominger RL, Atwood JD. Crystal and molecular structure of [(C6H5)2P(=0)(CH2CH2N(CH3)3 +][I−] Journal of Chemical Crystallography. 26: 747-752. DOI: 10.1007/Bf01664651  0.415
1996 Churchill MR, Krajkowski LM, Szczepura LF, Takeuchi KJ. Crystal structure of mer,trans-[Ru(NO2)(trpy) (PPh3)2 +][PF- 6]: A "problem structure" Journal of Chemical Crystallography. 26: 853-859.  0.341
1996 Churchill MR, Korzenski MB, Janik TS. Synthesis and crystal structure of a dinuclear organometallic phosphonium ylid complex, [(η5-C5H5)2Fe 2(CO)2(μ-CO)(μ-CHP(C6H5) 3)+][PF- 6] Journal of Chemical Crystallography. 26: 683-690.  0.336
1996 Churchill MR, See RF, Bessel CA, Takeuchi KJ. Crystal structure of mer,trans-[Ru(NO2)(trpy)(PPr3)+ 2][ClO- 4], a species with disordered PPr3 and NO2 ligands Journal of Chemical Crystallography. 26: 543-551.  0.308
1995 Miller CA, Lake CH, Churchill MR, Atwood JD. Reactivity Studies of Tricyclohexylphosphine (PCy3). Square-Planar Iridium Complexes with Small Gaseous Molecules (O2, H2, Cl2, and SO2). Molecular and Crystal Structure of Ir(CO)[OS(O)OH](SO2)(PCy3)2.cntdot.C6H6, the First Structurally Characterized Oxygen-Coordinated SO3H Complex Formed by Insertion of SO2(g) into an M-OH Bond Organometallics. 14: 5442-5445. DOI: 10.1021/Om00011A072  0.75
1995 Beachley OT, Rosenblum DB, Churchill MR, Lake CH, Krajkowski LM. Syntheses, characterization, crystal and molecular structures, and solution properties of Et2Ga(C5H5) and EtGa(C5H5)2 Organometallics. 14: 4402-4408. DOI: 10.1021/Om00009A050  0.728
1995 Paw W, Lake CH, Churchill MR, Keister JB. 47-Electron Organometallic Clusters. Synthesis, Characterization, and Reactivity toward Electrophiles/Oxidants of H2Ru3(RC2R')(CO)6(PPh3)3 and Crystal Structures of (.mu.-H)2Ru3(.mu.3-.eta.2-EtCCEt)(CO)7(PPh3)2 and (.mu.-H)2Ru3(.mu.3-.eta.2-EtCCEt)(CO)6(PPh3)3.cntdot.3CH2Cl2 Organometallics. 14: 3768-3782. DOI: 10.1021/Om00008A026  0.739
1995 Ren XF, Konaklieva MI, Turos E, Krajkowski LM, Lake CH, Janik TS, Churchill MR. Regiochemical and stereochemical studies on halogen-induced ring expansions of unsaturated episulfides Journal of Organic Chemistry. 60: 6484-6495. DOI: 10.1021/Jo00125A039  0.65
1995 Szczepura LF, Maricich SM, See RF, Churchill MR, Takeuchi KJ. Synthesis, characterization, and reactivity of an oxoruthenium(IV) complex containing a bis(oxazoline) ligand. Crystal structure of [Ru((S)-bpop)(Cl)(trpy)](BF4) Inorganic Chemistry. 34: 4198-4205. DOI: 10.1021/Ic00120A027  0.42
1995 Amin S, Voss DA, Horrocks WD, Lake CH, Churchill MR, Morrow JR. Laser-induced luminescence studies and crystal structure of the europium(III) complex of 1,4,7,10-tetrakis(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane. The link between phosphate diester binding and catalysis by lanthanide(III) macrocyclic complexes Inorganic Chemistry. 34: 3294-3300. DOI: 10.1021/Ic00116A023  0.702
1995 Szczepura LF, Giambra J, See RF, Lawson H, Janik TS, Jircitano AJ, Churchill MR, Takeuchi KJ. Crystal structures of trans-[Ru(dppe)2(CO)(Cl)](BF4)·2(toluene) and trans-[Ru(dppm)2(CO)(Cl)](BF4)·CH2Cl2: a study of the steric and electronic ligand effects of trans-positioned diphosphine ligands Inorganica Chimica Acta. 239: 77-85. DOI: 10.1016/0020-1693(95)04715-8  0.766
1995 Janik TS, Krajkowski LM, Churchill MR. Crystal structure of 751-1751-1751-1751-2751-2751-2 Journal of Chemical Crystallography. 25: 751-754. DOI: 10.1007/Bf01670330  0.731
1995 Churchill MR, Janik TS. Crystal structure of hexakis(tetrahydrofuran)sodium hexacarbonylvanadate(-I), [Na(THF)6 +][V(CO)6 -] Journal of Chemical Crystallography. 25: 597-599. DOI: 10.1007/Bf01667030  0.73
1995 Paw W, Lake CH, Churchill MR, Keister JB. 47-Electron organometallic clusters. Synthesis, characterization, and reactivity toward electrophiles/oxidants of H2Ru3(RC2R′)(CO)6(PPh 3)3 and crystal structures of (μ-H)2Ru3(μ3-η 2-EtCCEt)(CO)7(PPh3) ... Organometallics. 14: 3768-3782.  0.34
1995 Paw W, Keister JB, Lake CH, Churchill MR. Syntheses and reactions with Lewis bases of Ru4(CO)8(μs-O2C6H 2R2)2 (R = H, t-Bu), complexes containing 1,2-semiquinone ligands which bridge through oxygen and η6-C6 rings. Crystal structures of Ru4(CO)8(O2C6H ... Organometallics. 14: 767-779.  0.309
1995 Miller CA, Lake CH, Churchill MR, Atwood JD. Reactivity studies of tricyclohexylphosphine (PCy3) square-planar iridium complexes with small gaseous molecules (O2, H2, Cl2, and SO2). Molecular and crystal structure of Ir(CO)[OS(O)OH](SO2)(PCy3)2·C 6H6, the first structurally characterized ... Organometallics. 14: 5442-5445.  0.317
1994 Randall SL, Miller CA, See RF, Churchill MR, Janik TS, Lake CH, Atwood JD. Carbonylation of Iridium(I) and Iridium(III) Complexes, trans-Ir(CO)(R)(P(p-tolyl)3)2 (R = Me, OMe, OCH2Ph, OC6H4Me, OPh, OH) and Ir(CO)(Me)(SO4)(P(p-tolyl)3)2, and Facile Elimination of Hard Ligands: Crystal and Molecular Structures of Ir(CO)(Me)(SO4)(P(p-tolyl)3)2 and [Ir(CO)3(P(p-tolyl)3)2][HSO4] Organometallics. 13: 5088-5095. DOI: 10.1021/Om00024A060  0.791
1994 Miller CA, Janik TS, Lake CH, Toomey LM, Churchill MR, Atwood JD. Synthesis and Characterization of New Square Planar Iridium Complexes [trans-Ir(CO)L2X] (L = PCy3, X = OH or OCH3; L = P(p-tolyl)3, X = OCH2C6H5 or O(p-C6H4CH3)): Crystal and Molecular Structures of trans-Ir(CO)(OH)(PCy3)2, trans-Ir(CO)(OCH2C6H5)(P(p-tolyl)3)2, and trans-Ir(CO)(O-p-C6H4CH3)(P(p-tolyl)3)2 Organometallics. 13: 5080-5087. DOI: 10.1021/Om00024A059  0.795
1994 Park JT, Chi Y, Shapley JR, Churchill MR, Ziller JW. Characterization of the oxo-alkylidyne complex CpWOs3(CO) 10(μ-O)(μ3-CCH2Tol) resulting from acyl ligand C-O bond scission. Interconversion of alkylidyne, alkylidene, vinylidene, and alkyne ligand moieties in a single heterometallic cluster system Organometallics. 13: 813-821. DOI: 10.1021/Om00015A015  0.523
1994 Randall SL, Miller CA, Janik TS, Churchill MR, Atwood JD. Coordination of sulfur dioxide to iridium(I) centers. Sulfur dioxide insertion into a methoxo-metal bond: Crystal and molecular structure of carbonyl(methyl sulfito)(sulfur dioxide)bis(triphenylphosphine)iridium-hemitoluene, the first structurally characterized example of a transition metal complex containing an O-coordinated methyl sulfito ligand Organometallics. 13: 141-147. DOI: 10.1021/Om00013A024  0.748
1994 Churchill MR, Lake CH, Paw W, Keister JB. Syntheses and crystallographic characterizations of ruthenium complexes Ru4(CO)8(.mu.3-C6H2R2O2)2 (R = H, tert-Bu), complexes containing 1,2-semiquinone ligands which bridge through oxygen and .eta.6-C6 rings Organometallics. 13: 8-10. DOI: 10.1021/Om00013A004  0.718
1994 Chin KOA, Morrow JR, Lake CH, Churchill MR. Synthesis and solution properties of lanthanum(III), europium(III), and lutetium(III) THP complexes and an X-ray diffraction study of a crystal containing four stereoisomers of a europium(III) THP complex (THP = 1,4,7,10-Tetrakis(2-hydroxypropyl)-1,4,7,10-tetraazacyclododecane). Methyl groups impart rigidity to S,S,S,S-THP macrocyclic complexes Inorganic Chemistry. 33: 656-664. DOI: 10.1021/Ic00082A008  0.709
1994 Solooki D, Bradshaw JD, Tessier CA, Youngs WJ, See RF, Churchill M, Ferrara JD. Syntheses and crystal structures of 1,2:5,6:9,10:13,14:17,18:21,22-hexabenzo-3,7,11,15,19,23-hexadehydro[24]annulene (HBC), 1,2:5,6:9,10:13,14-tetrabenzo-3,7,11,15-tetradehydro[16]annulene (QBC) and a tetracobalt complex of QBC. The first example of a transition metal complex of QBC Journal of Organometallic Chemistry. 470: 231-236. DOI: 10.1016/0022-328X(94)80171-1  0.611
1994 Feighery WG, Kirss RU, Lake CH, Churchill MR. Alkyl for hydride exchange between alane-trimethylamine and group IVB metal alkryls Inorganica Chimica Acta. 218: 47-51. DOI: 10.1016/0020-1693(93)03788-C  0.368
1994 Churchill MR, Lake CH, Miller CA, Atwood JD. Crystal structure of trans-carbonylchlorobis-(tricyclohexylphosphine)iridium(I), trans-Ir(CO)Cl-[P(cyclo-C6H11)3]2, a disordered species Journal of Chemical Crystallography. 24: 557-560. DOI: 10.1007/Bf01666737  0.431
1994 Churchill MR, Lake CH, Wang P, Atwood JD. Crystal structure of bis(triphenylphosphine)iminium p-tolylsulfonate, [(PPh3)2N+][CH3C6H4SO3 -] Journal of Chemical Crystallography. 24: 473-476. DOI: 10.1007/Bf01666098  0.424
1994 Amin S, Morrow JR, Lake CH, Churchill MR. Lanthanide(III) tetraamide macrocyclic complexes as synthetic ribonucleases: Structure and catalytic properties of [La(tcmc)(CF3SO3)(EtOH)](CF3SO 3)2 Angewandte Chemie (International Edition in English). 33: 773-775. DOI: 10.1002/Anie.199407731  0.368
1993 Nalewajek D, Luly MH, Kaplan ML, Churchill MR, Ziller J, Schaber PM. Preparation, crystal and molecular structure and properties of 5,5′-bis-(1,3-dithiol-2-ylidene)[bicyclopenta-1,3-dien-1-yl]-2,2′,3, 3′-tetracarbonitrile Journal of the Chemical Society, Perkin Transactions 2. 373-376. DOI: 10.1039/P29930000373  0.557
1993 Bessel CA, See RF, Jameson DL, Churchill MR, Takeuchi KJ. Synthesis and characterization of ruthenium complexes which utilize a new family of terdentate ligands based upon 2,6-bis(pyrazol-1-yl)pyridine Journal of the Chemical Society, Dalton Transactions. 1563-1576. DOI: 10.1039/Dt9930001563  0.443
1993 Churchill MR, Lake CH, Chao SHL, Beachley OT. Silicone grease as a precursor to a pseudo crown ether ligand: Crystal structure of [K+]3[K(Me2SiO)7 +][InH(CH2CMe3)3 -] 4 Journal of the Chemical Society, Chemical Communications. 1577-1578. DOI: 10.1039/C39930001577  0.703
1993 Beachley OT, Chao SHL, Churchill MR, Lake CH. Synthesis, characterization, and molecular structure of a compound with a ring of Group 13, 15, and 16 atoms, [cyclic] (Me3CCH2)2InP(t-Bu)2In(CH2CMe3)2SePh Organometallics. 12: 5025-5028. DOI: 10.1021/Om00036A053  0.685
1993 Striejewske WS, See RF, Churchill MR, Atwood JD. Electron and bromine transfer reactions between metal carbonyl anions and metal carbonyl bromides. Crystal and molecular structure of dimeric indenyl molybdenum tricarbonyl Organometallics. 12: 4413-4419. DOI: 10.1021/Om00035A028  0.349
1993 Kirss RU, Quazi A, Lake CH, Churchill MR. Synthesis of unsymmetrical ruthenocenes by gas phase electrocyclic reactions of pentadienylruthenium complexes Organometallics. 12: 4145-4150. DOI: 10.1021/Om00034A058  0.654
1993 Beachley OT, Chao SHL, Churchill MR, Lake CH. Use of organoindium hydrides for the preparation of organoindium phosphides. Synthesis and molecular structure of [(Me3CCH2)2InP(t-Bu)2]2 Organometallics. 12: 3992-3997. DOI: 10.1021/Om00034A035  0.689
1993 Janik TS, Lake CH, Churchill MR. Synthesis and crystal structure of [(η6-C6H5CH3)V(CO) 2]2, a compound with a vanadium-vanadium triple bond Organometallics. 12: 1682-1685. DOI: 10.1021/Om00029A028  0.825
1993 Churchill MR, Lake CH, Safarowic FJ, Parfitt DS, Nevinger LR, Keister JB. Structural studies on ruthenium carbonyl hydrides. 17. Tetrametallic alkylidyne clusters: (.mu.-H)Ru4(.mu.4-.eta.2-COMe)(CO)12, (.mu.-H)Ru4(.mu.3-COMe)(CO)9{(PPh2)3CH}, and (.mu.-H)Ru3Fe(.mu.4-.eta.2-CX)(CO)12 (X = OMe, NMe2). Crystal structures of (.mu.-H)Ru4(.mu.4-.eta.2-COMe)(CO)12 and (.mu.-H)Ru3Fe(.mu.4-.eta.2-COMe)(CO)12 Organometallics. 12: 671-679. DOI: 10.1021/Om00027A017  0.73
1993 Morrow JR, Amin S, Lake CH, Churchill MR. Synthesis, structure, and dynamic properties of the lanthanum (III) complex of 1,4,7,10-tetrakis(2-carbamoylethyl)-1,4,7,10-tetraazacyclododecane Inorganic Chemistry. 32: 4566-4572. DOI: 10.1021/Ic00073A017  0.338
1993 Morrow J, Amin S, Lake C, Churchill M. Synthesis, structure and dynamic properties of lanthanum(III) complexes of 1,4,7,10-tetrakis(carbamoylalkyl)-1,4,7,10. tetraazacyclododecane. Journal of Inorganic Biochemistry. 51: 524. DOI: 10.1016/0162-0134(93)85550-R  0.343
1993 Churchill MR, Lake CH, Lashewycz-Rubycz RA, Yao H, McCargar RD, Keister JB. Structural studies on ruthenium carbonyl hydrides. XVIII. Synthesis and characterization of.. Journal of Organometallic Chemistry. 452: 151-160. DOI: 10.1016/0022-328X(93)83184-W  0.734
1993 Churchill MR, See RF. Crystal structure of Fe(η6-C5H5BCMe3)2 a "problem structure" Journal of Organometallic Chemistry. 450: 171-176. DOI: 10.1016/0022-328X(93)80154-4  0.364
1993 Churchill MR, Lake CH, Safarowic FJ, Parfitt DS, Nevinger LR, Keister JB. Tetrametallic alkylidyne clusters: (μ-H)Ru4(μ4-η2-COMe)(CO) 12, (μ-H)Ru4(μ3-COMe)(CO)9{(PPh 2)3CH}, and (μ-H)Ru3Fe(μ4-η2-CX)(CO)12 (X = OMe, NMe2). Crystal structures .. Organometallics. 12: 671-679.  0.345
1992 Janik TS, Churchill MR, See RF, Randall SL, McFarland JM, Atwood JD. Structure of trans‐carbonylmethylbis(tri‐p‐tolylphosphine)iridium(I), trans‐[Ir(CO)(CH3){P(p‐C6H4CH3)3}2] Acta Crystallographica Section C. 48: 1493-1495. DOI: 10.1107/S0108270191014890  0.71
1992 Bessel CA, See RF, Jameson DL, Churchill MR, Takeuchi KJ. Structural considerations of terdentate ligands: Crystal structures of 2,2′: 6′,2′-terpyridine and 2,6-bis(pyrazol-1-yl)pyridine Journal of the Chemical Society, Dalton Transactions. 3223-3228. DOI: 10.1039/Dt9920003223  0.464
1992 Beachley OT, Lee JC, Gysling HJ, Chao SHL, Churchill MR, Lake CH. An organoindium compound containing an indium-selenium bond: Synthesis, properties, and molecular structure of [(Me3CCH2)2InSePh]2 Organometallics. 11: 3144-3148. DOI: 10.1021/Om00045A035  0.737
1992 Nevinger LR, Keister JB, Lake CH, Churchill MR. Reaction of cyclopentadiene with (alkylidyne)triruthenium clusters. Syntheses of Ru3(.mu.3-CPh)(.mu.-CO)2(CO)6(.eta.5-C5H5) and (.mu.-H)2Ru3(.mu.3-CPh)(.mu.-CO)(CO)6(.eta.5-C5H5). Crystal structures of Ru3(.mu.3-CPh)(.mu.-CO)2(CO)6(.eta.5-C5H5) and Ru3(.mu.3-CPh)(.mu.-CO)3(.eta.5-C5H5)3 Organometallics. 11: 1819-1824. DOI: 10.1021/Om00041A015  0.729
1992 Beachley OT, Chao SHL, Churchill MR, See RF. Chemistry of organoindium hydrides. Synthesis, characterization, and crystal structure of K{H[In(CH2CMe3)3]2} Organometallics. 11: 1486-1491. DOI: 10.1021/Om00040A018  0.386
1992 Beachley OT, Noble MJ, Churchill MR, Lake CH. Organogallium Compounds Containing the Neophyl Substituent. The Crystal and Molecular Structure of Trans-((PhMe2CCH2)2GaN(H)(Pr))2 Organometallics. 11: 1051-1055. DOI: 10.1021/Om00039A009  0.712
1992 Corraine MS, Lai CK, Zhen Y, Churchill MR, Buttrey LA, Ziller JW, Atwood JD. Kinetics of the reduction of Co(o-phen)33+ by the metal carbonyl anions Re(CO)5-, Mn(CO)4L- (L = CO, PEt3, PBu3, PPh3), Co(CO)4-, CpMo(CO)3- and CpFe(CO)2- (Cp = .eta.5-C5H5, o-phen = o-phenanthroline). Structural determinations of [PPN+][Mn(CO)5-] and [PPN+][Mn(CO)4(PEt3)-].cntdot.THF Organometallics. 11: 35-40. DOI: 10.1021/Om00037A014  0.48
1992 Szczepura LF, Muller JG, Bessel CA, See RF, Janik TS, Churchill MR, Takeuchi KJ. Characterization of protonated trans-bis(dioxime)ruthenium complexes: Crystal structures of trans-Ru(DPGH)2(NO)Cl, trans -[Ru(DMGH)(DMGH2)(NO)Cl]Cl, and trans-Ru(DMGH)2(NO)Cl Inorganic Chemistry. 31: 859-869. DOI: 10.1021/Ic00031A031  0.769
1992 Beachley OT, Noble MJ, Churchill MR, Lake CH. Organogallium compounds containing the neophyl substituent. Crystal and molecular structure of trans-[(PhMe2CCH2)2GaN(H)(Pr)]2 Organometallics. 11: 1051-1055.  0.327
1992 Nevinger LR, Keister JB, Lake CH, Churchill MR. Reaction of cyclopentadiene with (alkylidyne)triruthenium clusters. Syntheses of Ru3(μ3-CPh)(μ-CO)2(CO) 6(η5-C5H5) and (M-H)2Ru3(μ3-CPh)(μ-CO)(CO) 6(η5-C5H5). Crystal Structures of Ru .. Organometallics. 11: 1819-1824.  0.338
1991 Bessel CA, See RF, Jameson DL, Churchill MR, Takeuchi KJ. Synthesis, characterization and crystal structure of trans-[2,6-bis(3-phenylpyrazol-1-yl-κN 2)pyridine-κN]chloro-bis(trimethylphosphine)ruthenium(II) perchlorate: Evidence for meridional steric crowding Journal of the Chemical Society, Dalton Transactions. 2801-2805. DOI: 10.1039/Dt9910002801  0.481
1991 Beachley OT, Maloney JD, Churchill MR, Lake CH. Indium compounds that contain two different organic substituents. Crystal structure of [In(CH2CMe3)(CH2SiMe3)Cl] 2. An interesting case of partial ligand disorder in the solid state Organometallics. 10: 3568-3573. DOI: 10.1021/Om00056A029  0.719
1991 Beachley OT, Banks MA, Churchill MR, Feighery WG, Fettinger JC. Methylene-bridged group 13-15 compounds, R2MCH2PPh2 (R = CH2CMe3, CH2SiMe3; M = Ga, In). Crystal structure of [(Me3CCH2)2InCH2PPh 2]2·C6D6, a molecule containing an In-C-P-In-C-P ring in a chair conformation Organometallics. 10: 3036-3040. DOI: 10.1021/Om00055A014  0.531
1991 Churchill MR, Lake CH, Feighery WG, Keister JB. Structural studies on ruthenium carbonyl hydrides. 16. Isomerism in 47- and 48-electron (methylidyne)triruthenium clusters. Crystal structures of (.mu.-H)3Ru3(.mu.3-COMe)(CO)6{.mu.3-(PPh2CH2)3CMe} and (.mu.-H)3Ru3(.mu.3-COMe)(CO)7{.mu.2-(PPh2)3CH}.cntdot.1.25CH2Cl2 Organometallics. 10: 2384-2391. DOI: 10.1021/Om00053A048  0.751
1991 Banks MA, Beachley OT, Buttrey LA, Churchill MR, Fettinger JC. Diphenylphosphide derivatives of dineopentylgallium and -indium. Crystal and molecular structures of [(Me3CCH2)2GaPPh2]2 and [(Me3CCH2)2InPPh2]3 Organometallics. 10: 1901-1906. DOI: 10.1021/Om00052A040  0.586
1991 Randall SL, Thompson JS, Buttrey LA, Ziller JW, Churchill MR, Atwood JD. Displacement of hard bases from a soft center by a soft ligand: reaction of Ir(CO)(OH)(SO4)L2 (L = PPh3, P(p-tolyl)3) with carbon monoxide and the crystal structure of [Ir(CO)3(PPh3)2+][HSO4-].cntdot.1/3H2O Organometallics. 10: 683-688. DOI: 10.1021/Om00049A030  0.513
1991 Churchill MR, Lake CH, Feighery WG, Keister JB. Isomerism in 47- and 48-electron (methylidyne)triruthenium clusters. Crystal structures of (μ-H)3Ru3(μ3-COMe)(CO) 6{μ3-(PPh2CH2)3CMe}and (μ-H)3Ru3(μ3-COMe)(CO) 7{μ2-(PPh2) 3CH}·1.25CH2Cl2 Organometallics. 10: 2384-2391.  0.35
1990 Churchill MR, Barkan MD, Atwood JD, Ziller JW. Structure of a trinuclear rhodium(I) complex, [cis‐Rh(CO)(PPh3)]3(μ3‐O)(μ3‐OCMe3) Acta Crystallographica Section C. 46: 2462-2465. DOI: 10.1107/S0108270190006126  0.501
1990 Churchill MR, Buttrey LA, Keister JB, Ziller JW, Janik TS, Striejewske WS. Structural studies on ruthenium carbonyl hydrides. 15. X-ray structural analyses of symmetrically and unsymmetrically substituted .mu.3-.eta.3-C3R3 complexes of ruthenium: (.mu.-H)Ru3(.mu.3-.eta.3-CMeCMeCMe)(CO)9, (.mu.-H)Ru3(.mu.3-.eta.3-CMeCMeCOMe)(CO)9, and (.mu.-H)Ru3(.mu.3-.eta.3-CMeCMeCSEt)(CO)9. Influence of .pi.-donor substituents upon nido-arachno polyhedral distortion Organometallics. 9: 766-773. DOI: 10.1021/Om00117A036  0.77
1990 Churchill MR, Fettinger JC. Crystal structure of Fe2Os(CO)12, a structural analog of Fe3(CO)12 with no required site symmetry and only a ~12:1 "star of david" disorder pattern. Example of an acentric, but close to centric, structure. Some thoughts on the solid-state structure of Fe3(CO)12 Organometallics. 9: 446-452. DOI: 10.1021/Om00116A022  0.5
1990 Gates RA, D'Agostino MF, Sutin KA, McGlinchey MJ, Janik TS, Churchill MR. Syntheses and NMR spectra of Co3(CO)9[.mu.3-CCHAr2] clusters derived from DDT and related molecules: x-ray crystal structures of [[bis(4-chlorophenyl)methyl]carbynyl]tricobalt nonacarbonyl and of its bis(4-chloronaphthyl) analog Organometallics. 9: 20-26. DOI: 10.1021/Om00115A005  0.747
1990 Bernard KA, Churchill MR, Janik TS, Atwood JD. Carbon-oxygen bond formation on rhodium centers. Synthesis, characterization, crystal structure, and reactions of trans-(carbonyl)phenoxobis(triphenylphosphine)rhodium Organometallics. 9: 12-16. DOI: 10.1021/Om00115A003  0.734
1990 Leising RA, Kubow SA, Churchill MR, Buttrey LA, Ziller JW, Takeuchi KJ. Synthesis, characterization, and x-ray crystal structure of nitro(terpyridine)bis(trimethylphosphine)ruthenium(1+) perchlorate Inorganic Chemistry. 29: 1306-1312. DOI: 10.1021/Ic00332A004  0.571
1990 Lawson HJ, Janik TS, Churchill MR, Takeuchi KJ. The synthesis of an aqua trans-diphosphine complex of ruthenium: crystal structure of trans-[Ru(H2O)(PEt3) 2(trpy)](ClO4)2· 3H2O Inorganica Chimica Acta. 174: 197-204. DOI: 10.1016/S0020-1693(00)80300-X  0.748
1990 Churchill MR, Bueno C. Structural studies on polynuclear osmium carbonyl hydrides. XXXVI. The crystal structure of (μ-H)2Os3(CO)9(μ3-η1-CCO), a case wherein internally inconsistent OsOs bond lengths can be explained by the presence of both ordered and disordered molecular sites in the crystal Journal of Organometallic Chemistry. 396: 327-338. DOI: 10.1016/0022-328X(90)85474-D  0.768
1990 Churchill MR, Bueno C, Rheingold AL. Crystal structure of [Ph3PCH2CH2PPh2+3][Ru10(μ6-C)2(CO)20(μ-CO)2-4] · 2Me2CO and some brief comments on the severely disordered structure of [NEt+4]2[Ru10(μ6-C)2(CO)20(μ-CO)2-4] Journal of Organometallic Chemistry. 395: 85-103. DOI: 10.1016/0022-328X(90)85264-Y  0.522
1990 Churchill MR, Buttrey LA, Feighery WG, Keister JB, Ziller JW. Crystal structure of bis-1,2-(methyldiphenylphosphonium)-ethane perchlorate, [Ph2MePCH2CH2PMePh2 2+] [ClO4 -]2 Journal of Crystallographic and Spectroscopic Research. 20: 89-91. DOI: 10.1007/Bf01181680  0.596
1990 Leising RA, Kubow SA, Churchill MR, Buttrey LA, Ziller JW, Takeuchi KJ. Synthesis, characterization, and X-ray crystal structure of [Ru(NO2) (PMe3)2(trpy)](CIO4) Inorganic Chemistry. 29: 1306-1312.  0.512
1989 Ziller JW, Bower DK, Dalton DM, Keister JB, Churchill MR. Alkylidyne-alkyne coupling on triruthenium clusters. Isomerization of (.mu.-H)Ru3(.mu.3-.eta.3-EtSCCRCR)(CO)9 (R = Me or Ph) to Ru3(.mu.-SEt)(CO)9(.mu.3-.eta.3-CCRCHR), an intermediate in alkylidyne chain growth. The crystal structure of Ru3(.mu.-SEt)(.mu.3-.eta.3-CCPhCHPh)(CO)9 Organometallics. 8: 492-497. DOI: 10.1021/Om00104A034  0.538
1989 Beachley OT, Blom R, Churchill MR, Faegri K, Fettinger JC, Pazik JC, Victoriano L. (Pentamethylcyclopentadienyl)indium(I) and -indium(III) compounds. Syntheses, reactivities, and X-ray diffraction and electron diffraction studies of In(C5Me5) Organometallics. 8: 346-356. DOI: 10.1021/Om00104A012  0.548
1989 Schaber PM, Churchill MR, Fettinger JC. Crystal and molecular structures of Cu2([24]ANE N6)Br4 and [ZnBr([12]ANE N3)Br. Potential models for the active site in metallobiomolecules Journal of Inorganic Biochemistry. 36: 334. DOI: 10.1016/0162-0134(89)84548-9  0.519
1989 Churchill MR, Biondi LV. Iridium carbonyl clusters: VIII. The crystal structure of (η5-C5H5)2W2Ir2(CO)4 (μ-CO)2(μ3-CPh)(μ3-η3-C3Ph3), a “60-electron” cluster with a triangulated rhomboidal W2Ir2 skeleton☆ Journal of Organometallic Chemistry. 366: 265-274. DOI: 10.1016/0022-328X(89)87332-2  0.449
1989 Chi Y, Shapley JR, Churchill MR, Fettinger JC. Competitive addition and substitution reactions in the interaction of CpWOs3(CO)9(μ-O)(μ3-CCH2Tol) with phosphorus donors. The crystal structure of CpWOs3(CO)8(PPh2Me)(μ-O)(μ3-CCH2Tol) Journal of Organometallic Chemistry. 372: 273-285. DOI: 10.1016/0022-328X(89)87101-3  0.545
1989 Ziller JW, Bower DK, Dalton DM, Keister JB, Churchill MR. Alkylidyne-alkyne coupling on triruthenium clusters. Isomerization of (μ-H)Ru3(μ3-η3-EtSCCRCR)(CO) 9 (R = Me or Ph) to Ru3(μ-SEt)(CO)9(μ3-η 3-CCRCHR), an intermediate in alkylidyne chain growth. The crystal structure of Ru3(μ-SEt)(μ ... Organometallics. 8: 492-497.  0.303
1988 Park JT, Shapley JR, Bueno C, Ziller JW, Churchill MR. Structural studies on polynuclear osmium carbonyl hydrides. Part 35. Coordination and scission of alkynes on a tungsten-triosmium framework. Crystal structures of (.eta.5-C5H5)WOs3(CO)10[.mu.3-.eta.2-C2(C6H4CH3)2]H and (.eta.5-C5H5)WOs3(CO)10[.mu.3-.eta.2-C2(CO2C2H5)2]H - species with an alkyne ligand bound to Os3 and WOs2 faces of tetrahedral WOs3 clusters Organometallics. 7: 2307-2316. DOI: 10.1021/Om00101A010  0.811
1988 Rappoli BJ, Janik TS, Churchill MR, Thompson JS, Atwood JD. Silicon-oxygen bond-forming reactions upon addition of silanes and silyl halides to the 16-electron alkoxyiridium complexes trans-ROIr(CO)[P(p-tol)3]2 (R = Me or Ph; p-tol = p-Tolyl). Crystal and molecular structure of H2Ir(CO)(SiMe2Ph)[P(p-tol)3]2 Organometallics. 7: 1939-1944. DOI: 10.1021/Om00099A007  0.699
1988 Beachley OT, Pazik JC, Glassman TE, Churchill MR, Fettinger JC, Blom R. Synthesis, characterization, and structural studies of In(C5H4Me) by X-ray diffraction and electron diffraction techniques and a reinvestigation of the crystalline state of In(C5H5) by X-ray diffraction studies Organometallics. 7: 1051-1059. DOI: 10.1021/Om00095A007  0.569
1988 Schaber PM, Fettinger JC, Churchill MR, Nalewajek D, Fries K. Preparation, crystal and molecular structures, and properties of tetrabromo(1,5,9,13,17,21-hexaazacyclotetracosane)dicopper(II) and bromo(1,5,9-triazacyclododecane)zinc(II) bromide. Separation of mono- and binucleating ligands by selective complexation Inorganic Chemistry. 27: 1641-1646. DOI: 10.1021/Ic00282A027  0.542
1988 Janik TS, Churchill MR, Duggan TP, Keister JB. Structural studies on ruthenium carbonyl hydrides. XIV. Synthesis, characterization, and crystal structure of (μ-H)2Ru3(η3-η2-CHC(O)OCH3)(CO)8(PPh3). An example of cis-labilization by an oxygen donor ligand Journal of Organometallic Chemistry. 353: 343-353. DOI: 10.1016/0022-328X(88)80324-3  0.759
1988 Churchill MR, Ziller JW, Shapley JR, Yeh WY. Reaction of (μ-H)Os3(CO)10(μ3-CPh) with diphenylacetylene. Alkylidynealkyne coupling and the crystal structure of Os3(CO)8(μ,η2-CPhCHPh)(μ,η3-C3Ph3) Journal of Organometallic Chemistry. 353: 103-117. DOI: 10.1016/0022-328X(88)80304-8  0.567
1988 Churchill MR, Biondi LV. Iridium carbonyl clusters VII. The crystal structure of (η5-C5H5)2W2Ir2(CO)7(CHCO2Et)2, a tetrahedral cluster with a simple bridging and a triply-bridging alkylidene-ester ligand Journal of Organometallic Chemistry. 353: 73-82. DOI: 10.1016/0022-328X(88)80301-2  0.465
1988 Churchill MR, Fettinger JC, Buttrey LA, Barkan MD, Thompson JS. An accurate X-ray diffraction study of Vaska's compound, trans-IrCl(CO)(PPh3)2, including resolution of the carbonyl/chloride disorder problem Journal of Organometallic Chemistry. 340: 257-266. DOI: 10.1016/0022-328X(88)80081-0  0.588
1988 Fettinger JC, Churchill MR, Bernard KA, Atwood JD. Synthesis, characterization and the unpleasantly disordered crystal structure of Ir(Ome)(CO)(PPh3)2(SO4) Journal of Organometallic Chemistry. 340: 377-388. DOI: 10.1016/0022-328X(88)80031-7  0.609
1988 WHITMIRE KH, LAGRONE CB, CHURCHILL MR, FETTINGER JC, ROBINSON BH. ChemInform Abstract: Oxidation/Reduction Chemistry of Iron Carbonyl Clusters Containing Germanium, Tin, or Lead: Crystal and Molecular Structures of (Et4N)2(Fe3(CO)9(μ3-CO)(μ3-Ge(Fe(CO)4))) and Pb(Fe2(CO)8)2. Cheminform. 19. DOI: 10.1002/chin.198807304  0.453
1988 Park JT, Shapley JR, Bueno C, Ziller JW, Churchill MR. Coordination and scission of alkynes on a tungsten-triosmium framework. Crystal structures of (η5-C5H5)WOs3(CO) 10[μ3η2-C2(C 6H4CH3)2]H and (η5-C5H5)WOs3(CO) .. Organometallics. 7: 2307-2316.  0.316
1988 Park JT, Shapley JR, Bueno C, Ziller JW, Churchill MR. Coordination and scission of alkynes on a tungsten-triosmium framework. Crystal structures of (η5-C5H5)WOs3(CO) 10[μ3η2-C2(C 6H4CH3)2]H and (η5-C5H5)WOs3(CO) .. Organometallics. 7: 2307-2316.  0.505
1987 Churchill MR, Duggan TP, Keister JB, Ziller JW. Structure of nonacarbonyl-tri-μ-hydrido-μ3-(p-tolylmethylidyne)-triangulo-triruthenium, (μ-H)3Ru3(CO)9[μ3-CC6H4(p-CH3)] Acta Crystallographica Section C Crystal Structure Communications. 43: 203-205. DOI: 10.1107/S0108270187096434  0.515
1987 Churchill MR, Fettinger JC, Rappoli BJ, Atwood JD. Structure of trans-carbonylchlorobis(tri-p-tolylphosphine)iridium(I) Acta Crystallographica Section C Crystal Structure Communications. 43: 1697-1699. DOI: 10.1107/S0108270187090504  0.514
1987 Beachley OT, Churchill MR, Pazik JC, Ziller JW. Synthesis and characterization of mesitylgallium chloride compounds including the crystal and molecular structure of dichloromesitylgallium(III), an inorganic polymer Organometallics. 6: 2088-2093. DOI: 10.1021/Om00153A010  0.555
1987 Churchill MR, Ziller JW, Dalton DM, Keister JB. Structural studies on ruthenium carbonyl hydrides. 13. Synthesis of (.mu.-H)3Ru3(.mu.3-CSEt)(CO)9 and its rearrangement to (.mu.-H)Ru3(.mu.3-.eta.2-CH2SEt)(CO)9. Crystal structure of (.mu.-H)Ru3(.mu.3-.eta.2-CH2SEt)(CO)9 Organometallics. 6: 806-812. DOI: 10.1021/Om00147A020  0.558
1987 Churchill MR, Janik TS, Duggan TP, Keister JB. Structural studies on ruthenium carbonyl hydrides. 12. Synthesis, characterization, and crystal structure of (.mu.-H)2Ru3(.mu.3-.eta.2-CHC(O)OCH3)(CO)9, a stabilized intermediate in the reductive elimination of hydrocarbons from trimetallic clusters Organometallics. 6: 799-805. DOI: 10.1021/Om00147A019  0.762
1987 Chi Y, Shapley JR, Ziller JW, Churchill MR. Synthesis, crystal structure, and stereoisomerism of the alkylidene complex (.eta.5-C5H5)WOs3(CO)9(.mu.-O)(.mu.-Cl)(.mu.-CHCH2C6H4Me-4) and related complexes Organometallics. 6: 301-307. DOI: 10.1021/Om00145A011  0.597
1987 Yeh WY, Shapley JR, Ziller JW, Churchill MR. Phenylation reactions with triosmium carbyne and carbene cluster complexes. The crystal structure of Os3(CO)8[.mu.3,.eta.5-C(OMe)C(1,2-C6H4CPh)], a cluster complex containing an osmacyclopentadiene system linked to a Fischer-type carbene ligand Organometallics. 6: 1-7. DOI: 10.1021/Om00144A001  0.569
1987 Rappoli BJ, Churchill MR, Janik TS, Rees WM, Atwood JD. Crystal structure of the quasitetrahedral iridium(I) complex, Ir(COCH2CMe3)[P(p-tolyl)3]2[C 2(CO2Me)2]. An intermediate in cyclotrimerization of activated alkynes by 16-electron alkyl complexes of iridium, trans-RIr(CO)L2 (R = Me, CH2CMe3; L = PPh3, P(p-tolyl)3) Journal of the American Chemical Society. 109: 5145-5149. DOI: 10.1021/Ja00251A017  0.716
1987 Whitmire KH, Lagrone CB, Churchill MR, Fettinger JC, Robinson BH. Oxidation/reduction chemistry of iron carbonyl clusters containing germanium, tin, or lead: crystal and molecular structures of [Et4N]2[Fe3(CO)9(.mu.3-CO)(.mu.3-Ge{Fe(CO)4})] and Pb[Fe2(CO)8]2 Inorganic Chemistry. 26: 3491-3499. DOI: 10.1021/Ic00268A017  0.499
1987 Whitmire KH, Shieh M, Lagrone CB, Robinson BH, Churchill MR, Fettinger JC, See RF. Transformations in the Bismuth-Iron Carbonyl Cluster System: Importance of Oxidation/Reduction Reactions. Crystal Structures of [Me4N]3[Bi2Fe4(CO)13]Cl and [Et4N][Bi2Fe2Co(CO)10] Inorganic Chemistry. 26: 2798-2807. DOI: 10.1021/Ic00264A016  0.524
1987 Janik TS, Bernard KA, Churchill MR, Atwood JD. Reaction of alkenes with trans-MeOIr(CO)(PPh3)2. Crystal and molecular structure of the pentacoordinate alkoxy-alkene iridium(I) complex, MeOIr(CO)(PPh3)2(TCNE) Journal of Organometallic Chemistry. 323: 247-259. DOI: 10.1016/0022-328X(87)80373-X  0.754
1987 Churchill MR, Fettinger JC, Janik TS, Rees WM, Thompson JS, Tomaszewski S, Atwood JD. Formation of carboncarbon bonds on di(organo)iridium complexes, rr′Ir(CO)(PPh3)2X (R,R′ = Me, Ph, CH2Ph, C(O)CH3; X = Cl, I) and the crystal structure of cis,cis,trans-[Ir(CH3)2(CO)2(PPh3)2 +][CF3SO3 -] Journal of Organometallic Chemistry. 323: 233-246. DOI: 10.1016/0022-328X(87)80372-8  0.775
1987 WHITMIRE KH, SHIEH M, LAGRONE CB, ROBINSON BH, CHURCHILL MR, FETTINGER JC, SEE RF. ChemInform Abstract: Transformations in the Bismuth-Iron Carbonyl Cluster System: Importance of Oxidation/Reduction Reactions. Crystal Structures of (Me4N)3(Bi2Fe4(CO)13)Cl and (Et4N) (Bi2Fe2Co(CO)10). Cheminform. 18. DOI: 10.1002/chin.198750286  0.481
1987 Churchill MR, Ziller JW, Dalton DM, Keister JB. Synthesis of (μ-H)3Ru3(μ3-CSEt)(CO)9 and its rearrangement to (μ-H)Ru3(μ3-η2-CH 2SEt)(CO)9. Crystal structure of (μ-H)Ru3(μ3-η2-CH 2SEt)(CO)9 Organometallics. 6: 806-812.  0.314
1987 Whitmire KH, Lagrone CB, Churchill MR, Fettinger JC, Robinson BH. Oxidation/reduction chemistry of iron carbonyl clusters containing germanium, tin, or lead: Crystal and molecular structures of [Et4N]2[Fe3(CO)9(μ 3-CO)(μ3-Ge{Fe(CO)4})] and Pb[Fe2(CO)8]2 Inorganic Chemistry. 26: 3491-3499.  0.452
1987 Churchill MR, Janik TS, Duggan TP, Keister JB. Synthesis, characterization, and crystal structure of (μ-H)2Ru3(μ3-η 2-CHC(O)OCH3)(CO)9, a stabilized intermediate in the reductive elimination of hydrocarbons from trimetallic clusters Organometallics. 6: 799-805.  0.344
1987 Yeh WY, Shapley JR, Ziller JW, Churchill MR. Phenylation reactions with triosmium carbyne and carbene cluster complexes. The crystal structure of Os3(CO)8(μ3,η 5-C(OMe)C(1,2-C6H4CPh)), a cluster complex containing an osmacyclopentadiene system linked to a Fischer-type carbene ligand Organometallics. 6: 1-6.  0.512
1987 Chi Y, Shapley JR, Ziller JW, Churchill MR. Synthesis, crystal structure, and stereoisomerism of the alkylidene complex (η5-C5H5)WOs3(CO) 9(μ-O)(μ-Cl)(μ-CHCH2Tol) and related complexes Organometallics. 6: 301-307.  0.371
1986 Beachley OT, Churchill MR, Pazik JC, Ziller JW. Synthesis, characterization, and crystal and molecular structure of trimesitylgallium(III) Organometallics. 5: 1814-1817. DOI: 10.1021/Om00140A010  0.587
1986 Yeh WY, Shapley JR, Ziller JW, Churchill MR. Synthesis, crystal structure, and some reactions of Os3(CO)9(.mu.3-CPh)(.mu.3-COMe) Organometallics. 5: 1757-1763. DOI: 10.1021/Om00140A001  0.558
1986 Schrock RR, Murdzek JS, Freudenberger JH, Churchill MR, Ziller JW. Multiple metal-carbon bonds. 39. Preparation of molybdenum and tungsten neopentylidyne complexes of the type M(CCMe3)(O2CR)3, their reactions with acetylenes, and the x-ray structure of the .eta.3-cyclopropenyl complex W[C3(CMe3)Et2](O2CCH3)3 Organometallics. 5: 25-33. DOI: 10.1021/Om00132A005  0.373
1986 Whitmire KH, Raghuveer KS, Churchill MR, Fettinger JC, See RF. Effect of charge on bond formation and cleavage in main-group-transition-metal clusters: The reactions of Bi2Fe3(CO)9 with [Fe(CO)4]2- and [Co(CO)4]- [22] Journal of the American Chemical Society®. 108: 2778-2780. DOI: 10.1021/Ja00270A060  0.467
1986 Chi Y, Shapley JR, Churchill MR, Li YJ. Formation of tungsten-triosmium clusters. Crystal structure and reactivity of (η5-C5H5)WOs3(CO) 12(μ3-CC6H4CH 3)(μ-H)2 Inorganic Chemistry. 25: 4165-4170. DOI: 10.1021/Ic00243A022  0.815
1986 Whitmire KH, Albright TA, Kang SK, Churchill MR, Fettinger JC. Structural and theoretical discussion of tridecacarbonyltetrabismuthtetraferrate(2-): application of MO and Teo electron counting theories to a Zintl-metal carbonylate Inorganic Chemistry. 25: 2799-2805. DOI: 10.1021/Ic00236A029  0.471
1986 Lagrone CB, Whitmire KH, Churchill MR, Fettinger JC. Synthesis and characterization of an iron carbonyl cluster containing lead: Crystal and molecular structure of [Et4N]2[Pb{Fe(CO)4}2{Fe 2(CO)8}] Inorganic Chemistry. 25: 2080-2085. DOI: 10.1021/Ic00232A034  0.53
1986 Churchill MR, Fettinger JC, Rees WM, Atwood JD. Synthesis and crystals structure of a carbomethoxy complex of pentacoordinate iridium(I), MeOC(O)Ir(CO)2(PPh3)2 Journal of Organometallic Chemistry. 304: 227-238. DOI: 10.1016/S0022-328X(00)99688-8  0.583
1986 Churchill MR, Fettinger JC, Rees WM, Atwood JD. Formation and crystal structure of MeIr(CO)(PPh3)2(MeCO2CHCHCO2Me). Comparison of the structures of analogous alkene and alkyne complexes Journal of Organometallic Chemistry. 301: 99-108. DOI: 10.1016/0022-328X(86)82059-9  0.612
1986 Churchill MR, Li YJ. The W(μ-N2)W system. II. Crystal structure of [(η5-C5Me5)W(CH3)3]2(μ-N2), AN organotungsten(VI) complex containing a WNNW core Journal of Organometallic Chemistry. 301: 49-59. DOI: 10.1016/0022-328X(86)82055-1  0.817
1986 Churchill MR, Li YJ, Shapley JR, Foose DS, Uchiyama WS. Iridium-carbonyl clusters. VI. Mixed-metal clusters via metal-hydride coupling. Synthesis of CpMM′3(CO)11 (M = Mo, W; M′ = Co, Ir) and the crystal structure of CpMoIr3(CO)11 Journal of Organometallic Chemistry. 312: 121-131. DOI: 10.1016/0022-328X(86)80285-6  0.82
1986 Whitmire KH, Albright TA, Kang SK, Churchill MR, Fettinger JC. Structural and theoretical discussion of [Bi4Fe4(CO)13]2-: Application of MO and TEC theories to a zintl-metal carbonylate Inorganic Chemistry. 25: 2799-2805. DOI: 10.1002/Chin.198649053  0.477
1986 Beachley OT, Churchill MR, Fettinger JC, Pazik JC, Victoriano L. Synthesis and crystal and molecular structure of In(C5Me5): An apparent octahedral cluster Journal of the American Chemical Society. 108: 4666-4668. DOI: 10.1002/Chin.198648082  0.585
1986 Yeh WY, Shapley JR, Ziller JW, Churchill MR. Synthesis, crystal structure, and some reactions of Os3(CO)9(μ3-CPh)(μ3-COMe) Organometallics. 5: 1757-1763.  0.515
1985 Rees WM, Churchill MR, Fettinger JC, Atwood JD. Formation of carboalkoxyiridium complexes by carbonylation of alkoxyiridium complexes and the crystal structure of trans-PhOIr(CO)(PPh3)2 Organometallics. 4: 2179-2185. DOI: 10.1021/Om00131A021  0.604
1985 Churchill MR, Fettinger JC, Keister JB, See RF, Ziller JW. Synthesis and crystallographic characterization of (.mu.-H)2Ru3(CO)9(.mu.3-.eta.2-MeCCOMe) Organometallics. 4: 2112-2116. DOI: 10.1021/Om00131A008  0.61
1985 Shapley JR, Yeh WY, Churchill MR, Li YJ. Synthesis and crystal structure of (.mu.-H)Os3(CO)9(.eta.1-C(OMe)2)(.mu.3-CPh), a mixed carbene carbyne cluster complex Organometallics. 4: 1898-1900. DOI: 10.1021/Om00129A039  0.468
1985 Churchill MR, Fettinger JC, Keister JB. Substitutional isomerism for trimetallic clusters having icosahedral ligand arrangements. The crystal structures of (.mu.-H)Ru3[.mu.-CN(CH3)2](CO)9(C5H5N) and (.mu.-H)Ru3[.mu.-CN(CH2C6H5)2](CO)9(PPh3) Organometallics. 4: 1867-1875. DOI: 10.1021/Om00129A029  0.614
1985 Rees WM, Churchill MR, Li YJ, Atwood JD. Addition reactions and crystal structure of trans-CH3Ir(CO)(PPh3)2 Organometallics. 4: 1162-1167. DOI: 10.1021/Om00126A004  0.426
1985 Yeh WY, Shapley JR, Li YJ, Churchill MR. Structural studies on polynuclear osmium carbonyl hydrides. 30. Synthesis, crystal structure, and reactivity of (.mu.-H)Os3(CO)10(.mu.3-CPh) Organometallics. 4: 767-772. DOI: 10.1021/Om00123A026  0.395
1985 DePue RT, Collum DB, Ziller JW, Churchill MR. Alkoxide triggered ligand substitution. Highly stereoselective formation of unsaturated phosphinite ester-molybdenum tetracarbonyl chelates and the x-ray crystal structure of (1-phenylallyl dimethylphosphinite)molybdenum tetracarbonyl Journal of the American Chemical Society. 107: 2131-2137. DOI: 10.1021/Ja00293A050  0.586
1985 Whitmire KH, Churchill MR, Fettinger JC. Synthesis and crystal structure of the bismuth-iron carbonyl cluster [Et4N]2[Bi4Fe4(CO)13]. Discovery of a hybrid Zintl-metal carbonyl cluster Journal of the American Chemical Society. 107: 1056-1057. DOI: 10.1021/Ja00290A050  0.539
1985 Churchill MR, Biondi LV, Shapley JR, McAteer CH. Synthesis and X-ray structure of (η5-C5H5)2W2Ir2(CO)7(CHCO2Et)2, a tetrahedral heterometal cluster with two different environments for ethylcarboxylatocarbene ligands Journal of Organometallic Chemistry. 280: c63-c66. DOI: 10.1016/0022-328X(85)88123-7  0.408
1985 Churchill MR, Li YJ. Structural studies on polynuclear osmium carbonyl hydrides. XXXII. Crystal and molecular structure of CpWOs3(CO)9(μ-H)(μ-O)[μ-CCH(p-tol)], a hydrido-vinylidene cluster complex produced by rearrangement of a μ3-alkylidyne cluster Journal of Organometallic Chemistry. 294: 367-377. DOI: 10.1016/0022-328X(85)87452-0  0.81
1985 Churchill MR, Ziller JW, Beanan LR. Crystal structure of CpWOs3(CO)9(μ-O)(μ3-CCH2Tol), a tetrahedral oxo-alkylidyne complex derived from a planar μ3-μ2-acyl complex Journal of Organometallic Chemistry. 287: 235-246. DOI: 10.1016/0022-328X(85)87260-0  0.591
1985 Churchill MR, Ziller JW. X-ray structural analysis of W[C(t-Bu)CHC(t-Bu)][OCH(CF3)2]3 A molecule containing a planar tungstenacyclobutadiene ring with no alkyl substituent on the β-carbon atom Journal of Organometallic Chemistry. 286: 27-36. DOI: 10.1016/0022-328X(85)87232-6  0.545
1985 Churchill MR, Li YJ. Crystal and molecular structure of W(CCMe3)(PMe3)3Cl3; a seven-coordinate tungsten(VI) alkylidyne complex with a regular capped octahedral (C5v) stereochemistry Journal of Organometallic Chemistry. 282: 239-246. DOI: 10.1016/0022-328X(85)87174-6  0.806
1985 Churchill MR, Ziller JW. Crystal structure of a deprotonated tungstenacyclobutadiene complex, (η5-C5H5)W[C3(CMe3)2]Cl; characterization of an η3-RCCCR ligand Journal of Organometallic Chemistry. 281: 237-248. DOI: 10.1016/0022-328X(85)87113-8  0.576
1985 Churchill MR, Ziller JW. Crystal structure of (η5-C5H5)W[C(Ph)C(CMe3)C(Ph)]Cl2, a molecule possessing a localized, non-planar tungstenacyclobutadiene ring Journal of Organometallic Chemistry. 279: 403-412. DOI: 10.1016/0022-328X(85)87038-8  0.535
1985 Churchill MR, Ziller JW, Keister JB. Structural studies on ruthenium carbonyl hydrides. X. Crystal structure of (μ-H)Ru3(CO)10(μ-SEt) Journal of Organometallic Chemistry. 297: 93-101. DOI: 10.1016/0022-328X(85)80400-9  0.608
1985 Churchill MR, Li YJ. Structural studies on osmium carbonyl hydrides. XXXI. Crystal and molecular structure of CpWOs3(CO)9(μ-H)(μ-O)(μ-CHCH2C6H4Me), a hydrido-alkylidene produced by hydrogenation of a μ3-alkylidyne Journal of Organometallic Chemistry. 291: 61-70. DOI: 10.1016/0022-328X(85)80203-5  0.825
1985 Churchill MR, Fettinger JC, Whitmire KH. Synthesis and x-ray crystallographic characterization of (μ3-Bi)2Fe3(CO)9: A reformulation of Hieber's Bi2Fe5(CO)20 Journal of Organometallic Chemistry. 284: 13-23. DOI: 10.1016/0022-328X(85)80008-5  0.56
1985 Churchill MR, Li YJ, Nalewajek D, Schaber PM, Dorfman J. Preparation, crystal and molecular structure, and properties of tetrakis(ferrocenecarboxylato)bis(tetrahydrofuran)dicopper(II). A structure containing both eclipsed and staggered ferrocenyl fragments Inorganic Chemistry. 24: 2684-2687. DOI: 10.1002/Chin.198549279  0.451
1985 WHITMIRE KH, CHURCHILL MR, FETTINGER JC. ChemInform Abstract: SYNTHESIS AND CRYSTAL STRUCTURE OF THE BISMUTH-IRON CARBONYL CLUSTER (ET4N)2(BI4FE4(CO)13). DISCOVERY OF A HYBRID ZINTL-METAL CARBONYL CLUSTER Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198527309  0.477
1985 CHURCHILL MR, LI Y, THEOPOLD KH, SCHROCK RR. ChemInform Abstract: HIGH OXIDATION STATE DINITROGEN COMPLEXES. SYNTHESIS AND CRYSTAL STRUCTURE OF (W(C6H5CCC6H5)(CH3OCH2CH2OCH3)CL2)2(μ-N2).0.5CH3OCH2CH2OCH3 Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198520277  0.427
1985 PARK JT, SHAPLEY JR, CHURCHILL MR, BUENO C. ChemInform Abstract: STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES. 29. DEGENERATE FRAMEWORK REARRANGEMENT IN A CAPPED-SQUARE-PYRAMIDAL METAL-CARBON CLUSTER AND ITS CONVERSION TO A CAPPED-TRIGONAL-BIPYRAMIDAL CLUSTER. CRYSTAL STRUCTURES OF (η Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198520263  0.403
1985 Whitmire KH, Lagrone CB, Churchill MR, Fettinger JC, Biondi LV. SYNTHESIS AND CHARACTERIZATION OF AN IRON CARBONYL CLUSTER CONTAINING BISMUTH: CRYSTAL AND MOLECULAR STRUCTURE OF TETRAETHYLAMMONIU (μ3-BISMUTHIDO)NONACARBONYL(μ3-CARBONYL)-TRIANGULO-TRIFERRATE(1-) (ET4N)((μ3-BI)FE3(CO)9(μ3-CO)), A CL Cheminform. 16. DOI: 10.1002/Chin.198517267  0.592
1985 CHURCHILL MR, ZILLER JW, FREUDENBERGER JH, SCHROCK RR. ChemInform Abstract: METATHESIS OF ACETYLENES BY TRIPHENOXYTUNSTENACYCLOBUTADIENE COMPLEXES AND THE CRYSTAL STRUCTURE OF W(C3ET3)(O-2,6-C6H3(I-PR)2)3 Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198504263  0.589
1985 Shapley JR, Yeh WY, Churchill MR, Li YJ. Synthesis and crystal structure of (μ-H)Os3(CO)9(η1-C(OMe) 2)(μ3-CPh), a mixed carbene-carbyne cluster complex Organometallics. 4: 1898-1900.  0.381
1985 DePue RT, Collum DB, Ziller JW, Churchill MR. Alkoxide triggered ligand substitution. Highly stereoselective formation of unsaturated phosphinite ester - Mo(CO)4 chelates and the X-ray crystal structure of (PMe2OCHPhCH=CH2)Mo(CO)4 Journal of the American Chemical Society. 107: 2131-2137.  0.377
1985 Churchill MR, Fettinger JC, Keister JB. Substitutional isomerism for trimetallic clusters having icosahedral ligand arrangements. The crystal structures of (μ-H)Ru3[μ-CN(CH3)2](CO) 9(C5H5N) and (μ-H)Ru3[μ-CN(CH2C6H5) 2](CO)9(PPh3) Organometallics. 4: 1867-1875.  0.375
1985 Yeh WY, Shapley JR, Li YJ, Churchill MR. Synthesis, crystal structure, and reactivity of (μ-H)Os3(CO)10(μ3-CPh) Organometallics. 4: 767-772.  0.363
1984 Churchill MR, Ziller JW, Pedersen SF, Schrock RR. Formation of a tetrahedral WC3 framework from a cyclic WC3(tungstenacyclobutadiene) system via attack on tungsten by nitrogen-doner ligands: X-ray study of W[C3Me2(But)][Me2N(CH2)2NMe2]Cl3 Journal of the Chemical Society, Chemical Communications. 485-486. DOI: 10.1039/C39840000485  0.555
1984 Shapley JR, McAteer CH, Churchill MR, Biondi LV. Coordination and scission of alkynes on a ditungsten-diiridium framework. The crystal structure of (.eta.5-C5H5)2W2Ir2(CO)6(.mu.3-CPh)(.mu.3-.eta.3-C3Ph3) Organometallics. 3: 1595-1596. DOI: 10.1021/Om00088A027  0.348
1984 Schrock RR, Pedersen SF, Churchill MR, Ziller JW. Formation of cyclopentadienyl complexes from tungstenacyclobutadiene complexes and the x-ray crystal structure of an .eta.3-cyclopropenyl complex, W[C(CMe3)C(Me)C(Me)](Me2NCH2CH2NMe2)Cl3 Organometallics. 3: 1574-1583. DOI: 10.1021/Om00088A020  0.556
1984 Holmes SJ, Schrock RR, Churchill MR, Wasserman HJ. Multiple metal-carbon bonds. 33. Some reactions of tungsten methylidyne complexes and the crystal structure of [W2(CPMe3)2(PMe3)4Cl4][AlCl4]2 Organometallics. 3: 476-484. DOI: 10.1021/Om00081A024  0.71
1984 Churchill MR, Li YJ, Blum L, Schrock RR. Synthesis and crystallographic characterization of a dinuclear 1,2-hydrazido(2-) complex of tungsten(VI), [W(.eta.5-C5Me4(CMe3))(CCMe3)I]2(.mu.-N2H2).CH2Cl2 Organometallics. 3: 109-113. DOI: 10.1021/Om00079A020  0.323
1984 Churchill MR, Fettinger JC. Transformation of a tungstenacyclobutadiene complex into a nonfluxional .eta.3-cyclopropenyl complex by addition of a donor ligand. The x-ray structure of the tungstenacyclobutadiene-.eta.3-cyclopropenyl complex W(.eta.5-C5H5)[C3(CMe3)2Me](PMe3)Cl2 Journal of the American Chemical Society. 106: 3356-3357. DOI: 10.1021/Ja00323A051  0.582
1984 Shapley JR, Park JT, Churchill MR, Ziller JW, Beanan LR. Thermal carbon-oxygen bond scission in a .mu.3-.eta.2-coordinated acyl. Structural characterization of a doubly bridging four-electron oxo ligand Journal of the American Chemical Society. 106: 1144-1145. DOI: 10.1021/Ja00316A069  0.547
1984 Park JT, Shapley JR, Churchill MR, Bueno C. Structural studies on polynuclear osmium carbonyl hydrides. 29. Degenerate framework rearrangement in a capped-square-pyramidal metal-carbon cluster and its conversion to a capped-trigonal-bipyramidal cluster. Crystal structures of (.eta.5-C5H5)WOs3(CO)10(.mu.3-CC6H4CH3)2H and (.eta.5-C5H5)WOs3(CO)9(.mu.3-CC6H4CH3)2H Inorganic Chemistry. 23: 4476-4486. DOI: 10.1021/Ic00194A016  0.773
1984 Churchill MR, Li YJ, Theopold KH, Schrock RR. High oxidation state dinitrogen complexes. Synthesis and crystal structure of [W(C6H5C.tplbond.CC6H5)(CH3OCH2CH2OCH3)Cl2]2(.mu.-N2).0.5CH3OCH2CH2OCH3 Inorganic Chemistry. 23: 4472-4476. DOI: 10.1021/Ic00194A015  0.422
1984 Whitmire KH, Lagrone CB, Churchill MR, Fettinger JC, Biondi LV. Synthesis and characterization of an iron carbonyl cluster containing bismuth: crystal and molecular structure of tetraethylammonium (.mu.3-bismuthido)nonacarbonyl(.mu.3-carbonyl)-triangulo-triferrate(1-), [Et4N][(.mu.3-Bi)Fe3(CO)9(.mu.3-CO)], a closo cluster of the first transition series with a large heteroatom Inorganic Chemistry. 23: 4227-4232. DOI: 10.1021/Ic00193A026  0.555
1984 Churchill MR, Bueno C, Park JT, Shapley JR. Structural studies on polynuclear osmium carbonyl hydrides. 28. Synthesis and structure of (.eta.5-C5H5)WOs3(CO)8(.mu.-O)(.mu.3-.eta.2-C2H2)(.mu.-H), a tetrahedral tungsten-triosmium cluster complex with a unique unsymmetrical (W, Os) edge-bridging oxo ligand Inorganic Chemistry. 23: 1017-1021. DOI: 10.1021/Ic00176A006  0.779
1984 Churchill MR, Davies G, El-Sayed MA, Fournier JA, Hutchinson JP, Zubieta JA. Crystal and molecular structure of bis(.mu.-bromo)bis(N,N,N',N'-tetraethylethylenediamine)dicopper(I) and the kinetics of its oxidation by dioxygen in nitrobenzene Inorganic Chemistry. 23: 783-787. DOI: 10.1021/Ic00174A029  0.728
1984 Samkoff DE, Shapley JR, Churchill MR, Wasserman HJ. Structural studies on polynuclear osmium carbonyl hydrides. 25. Synthesis, characterization, and reversible photochemical/thermal interconversion of .eta.1- and .eta.2-bridged (aryldiazo)triosmium clusters. Crystal structure of (.mu.-H)Os3(CO)10(.mu.-.eta.2-N:NPh) Inorganic Chemistry. 23: 397-402. DOI: 10.1021/Ic00172A004  0.722
1984 Rahman ZA, Beanan LR, Bavaro LM, Modi SP, Keister JB, Churchill MR. Relative rates of ligand substitution on nonacarbonyltris(μ-hydrido)(μ3-methylidyne)triruthenium clusters. The crystal structure of (μ-H)3Ru3(μ3-CPh)(CO)7(AsPh3)2 Journal of Organometallic Chemistry. 263: 75-92. DOI: 10.1016/0022-328X(84)85012-3  0.47
1984 Churchill MR, Wasserman HJ. Crystal structure of (Me)]Cl3, the archetypal example of a planar delocalized tungstenacyclobutadiene complex Journal of Organometallic Chemistry. 270: 201-210. DOI: 10.1016/0022-328X(84)80360-5  0.706
1984 Freudenberger JH, Schrock RR, Churchill MR, Rheingold AL, Ziller JW. Metathesis of acetylenes by (fluoroalkoxy)tungstenacyclobutadiene complexes and the crystal structure of W(C3Et3)[OCH(CF3)2]3. A higher order mechanism for acetylene metathesis Cheminform. 16: 1563-1573. DOI: 10.1002/Chin.198504264  0.605
1984 Churchill MR, Fettinger JC, Mccullough LG, Schrock RR. Transformation of a Tungstenacyclobutadiene Complex into a Nonfluxional η3-Cyclopropenyl Complex by Addition of a Donor Ligand. The X-Ray Structure of W(η5-C5H5)[C3(CMe3)2Me](PMe3)Cl2. Cheminform. 15. DOI: 10.1002/Chin.198436278  0.434
1984 CHURCHILL MR, BUENO C, PARK JT, SHAPLEY JR. ChemInform Abstract: STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES. 28. SYNTHESIS AND D STRUCTURE OF (η5-C5H5)WOS3(CO)8(μ-O)(μ3-η2-C2H2)(μ-H), A TETRAHEDRAL TUNGSTEN-TRIOSMIUM CLUSTER COMPLEX WITH A UNIQUE UNSYMMETRICAL (W, OS) EDGE-BRIDGING Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198429297  0.443
1984 Churchill MR, Davies G, El-Sayed MA, Fournier JA, Hutchinson JP, Zubieta JA. Crystal and molecular structure of bis(μ-bromo)bis(N,N,N′,N′-tetraethylethylenediamine)dicopper(I) and the kinetics of its oxidation by dioxgen in nitrobenzene Inorganic Chemistry. 23: 783-787. DOI: 10.1002/Chin.198425272  0.527
1984 SAMKOFF DE, SHAPLEY JR, CHURCHILL MR, WASSERMAN HJ. ChemInform Abstract: STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES. 25. SYNTHESIS, CHARACTERIZATION, AND REVERSIBLE PHOTOCHEMICAL/THERMAL INTERCONVERSION OF η1- AND η2-BRIDGED (ARYLDIAZO)TRIOSMIUM CLUSTERS. CRYSTAL STRUCTURE OF (μ-H)OS3(CO)10 Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198421308  0.738
1984 Shapley JR, Park JT, Churchill MR, Ziller JW, Beanan LR. THERMAL CARBON-OXYGEN BOND SCISSION IN A μ3-η2-COORDINATED ACYL. STRUCTURAL CHARACTERIZATION OF A DOUBLY BRIDGING FOUR-ELECTRON OXO LIGAND Cheminform. 15. DOI: 10.1002/Chin.198421306  0.516
1984 Schrock RR, Pedersen SF, Churchill MR, Ziller JW. Formation of cyclopentadienyl complexes from tungstenacyclobutadiene complexes and the X-ray crystal structure of an η3-cyclopropenyl complex, W[C(CMe3)C(Me)C(Me)](Me2NCH2CH 2NMe2)Cl3 Organometallics. 3: 1574-1583.  0.497
1984 Churchill MR, Ziller JW, Freudenberger JH, Schrock RR. Metathesis of acetylenes by triphenoxytungstenacyclobutadiene complexes and the crystal structure of W(C3Et3) [O-2,6-C6H3(i-Pr)2]3 Organometallics. 3: 1554-1562.  0.348
1984 Shapley JR, McAteer CH, Churchill MR, Biondi LV. Coordination and scission of alkynes on a ditungsten-dilridium framework. The crystal structure of (η5-C5H5)2W2Ir 2(CO)6(μ3-CPh)(μ3-η 3-C3Ph) Organometallics. 3: 1595-1596.  0.378
1984 Shapley JR, Park JT, Churchill MR, Ziller JW, Beanan LR. Thermal C-O bond scission in a μ3-η2-coordinated acyl. Structural characterization of a doubly bridging four-electron oxo ligand Journal of the American Chemical Society. 106: 1144-1145.  0.468
1984 Freudenberger JH, Schrock RR, Churchill MR, Rheingold AL, Ziller JW. Metathesis of acetylenes by (fluoroalkoxy)tungstenacyclobutadiene complexes and the crystal structure of W(C3Et3)[OCH(CF3)2]3. A higher order mechanism for acetylene metathesis Organometallics. 3: 1563-1573.  0.583
1984 Samkoff DE, Shapley JR, Churchill MR, Wasserman HJ. Synthesis, characterization, and reversible photochemical/thermal interconversion of η1- And η2-bridged (aryldiazo)triosmium clusters. Crystal structure of (μ-H)Os3(CO)10(μ-η2-N=NPh) Inorganic Chemistry. 23: 397-402.  0.363
1984 Churchill MR, Fettinger JC, McCullough LG, Schrock RR. Transformation of a tungstenacyclobutadiene complex into a nonfluxional η3-cyclopropenyl complex by addition of a donor ligand. The X-ray structure of W(η5-C5H5)[C3(CMe 3)2Me](PMe3)Cl2 Journal of the American Chemical Society. 106: 3356-3357.  0.532
1984 Churchill MR, Bueno C, Park JT, Shapley JR. Synthesis and structure of (η5-C5H5)WOs3(CO) 8(μ-O)(μ3-η2-C2H 2)(μ-H), a tetrahedral tungsten-triosmium cluster complex with a unique unsymmetrical (W, Os) edge-bridging oxo ligand Inorganic Chemistry. 23: 1017-1021.  0.326
1983 Edwards DS, Biondi LV, Zillen JW, Churchill MR, Schrock RR. Multiple metal-carbon bonds. 32. Rhenium(VII) neopentylidene and neopentylidyne complexes and the x-ray structure of Re(CCMe3)(CHCMe3)(C5H5N)2 Organometallics. 2: 1505-1513. DOI: 10.1021/Om50005A005  0.382
1983 Churchill MR, Beanan LR, Wasserman HJ, Bueno C, Rahman ZA, Keister JB. Synthesis of cyclohexadiene complexes of (methylidyne)triruthenium clusters. The crystal structure of (.mu.-H)Ru3(.mu.3-COMe)(CO)8(1,3-C6H8) and a redetermination of the structure of (.mu.-H)Ru3(.mu.-COMe)(CO)10 Organometallics. 2: 1179-1186. DOI: 10.1021/Om50003A019  0.831
1983 Tessier-Youngs C, Youngs WJ, Beachley OT, Churchill MR. The reaction chemistry of transition metal diphenylphosphorus complexes with organoaluminum compounds. The synthesis, characterization and crystal and molecular structure of Cr(CO)5[PPh2(CH2)4OAl(CH2SiMe3)2], an example of THF cleavage Organometallics. 2: 1128-1138. DOI: 10.1021/om50003a011  0.343
1983 Tessier-Youngs C, Youngs WJ, Beachley OT, Churchill MR. The reaction chemistry of transition-metal diphenylphosphorus complexes with organoaluminum compounds. The synthesis, characterization, and crystal and molecular structure of Cr(CO)5[PPh2(CH2)4OAl(CH 2SiMe3)2], an example of THF cleavage Organometallics. 2: 1128-1138. DOI: 10.1021/Om50003A011  0.624
1983 Churchill MR, Ziller JW, McCullough L, Pedersen SF, Schrock RR. W(.eta.5-C5H5)[C(Ph)C(CMe3)C(Ph)]Cl2: a molecule having a localized, nonplanar, fluxional metallacyclobutadiene ring Organometallics. 2: 1046-1048. DOI: 10.1021/Om50002A020  0.461
1983 Churchill MR, Wasserman HJ. Structural study of W[.eta.5-C5Me4(tert-Bu)](.eta.2-MeC.tplbond.CMe)Cl2, a paramagnetic tungsten(III) species with a four-electron acetylene-metal bond Organometallics. 2: 755-759. DOI: 10.1021/Om00078A011  0.672
1983 Shapley JR, Strickland DS, St. George GM, Churchill MR, Bueno C. Coupling of methylidyne and carbonyl ligands on the triosmium cluster framework. Crystal structure of (.mu.-H)2Os3(CO)9(.mu.3-.eta.1-CCO) Organometallics. 2: 185-187. DOI: 10.1021/Om00073A044  0.778
1983 McCullough LG, Listemann ML, Schrock RR, Churchill MR, Ziller JW. Multiple metal-carbon bonds. 34. Why terminal alkynes cannot be metathesized. Preparation and crystal structure of a deprotonated tungstacyclobutadiene complex, W(.eta.5-C5H5)[C3(CMe3)2]Cl Journal of the American Chemical Society. 105: 6729-6730. DOI: 10.1021/Ja00360A040  0.592
1983 Park JT, Shapley JR, Churchill MR, Bueno C. Coordination and scission of alkynes on a tungsten-triosmium framework Journal of the American Chemical Society. 105: 6182-6184. DOI: 10.1021/Ja00357A053  0.347
1983 Shore SG, Hsu WL, Churchill MR, Bueno C. Unusual ligand replacement: displacement of .eta.5-cyclopentadienyl by .eta.6-arenes in the syntheses of H3(.eta.6-X)RhOs3(CO)9 (X = C6H6, PhMe). Crystal and molecular structure of H3(.eta.6-PhMe)RhOs3(CO)9 Journal of the American Chemical Society. 105: 655-656. DOI: 10.1021/Ja00341A074  0.785
1983 Park JT, Shapley JR, Churchill MR, Bueno C. Reaction of (.mu.-H)2Os3(CO)10 with (.eta.5-C5H5)(CO)2W.tplbond.CC6H4CH3. Crystal structure of (.eta.5-C5H5)WOs3(CO)11[C(O)CH2C6H4CH3]..apprx.0.5CCl4, a complex with a triply bridging (.mu.3,.eta.2) acyl ligand on the surface of a triangulated rhomboidal metal cluster Inorganic Chemistry. 22: 1579-1584. DOI: 10.1021/Ic00153A003  0.786
1983 Churchill MR, Wasserman HJ. X-ray structural study of an alkylidene-carbonyl complex of tungsten(IV): W(:CHCMe3)(CO)(PMe3)2Cl2 Inorganic Chemistry. 22: 1574-1578. DOI: 10.1021/Ic00153A002  0.695
1983 Churchill MR, Bueno C. Structural studies on polynuclear osmium carbonyl hydrides. 24. Crystal structures of the 60-electron cluster (.mu.-H)3Os3Ni(CO)9(.eta.5-C5H5) and the 59-electron radical cluster (.mu.-H)3Os3Co(CO)9(.eta.5-C5H5) Inorganic Chemistry. 22: 1510-1515. DOI: 10.1021/Ic00152A018  0.767
1983 Tessier-Youngs C, Bueno C, Beachley OT, Churchill MR. Transition-metal complexes of organoaluminum phosphides. Synthesis, characterization, and crystal and molecular structure of Cr(CO)5(PPh2Al)(CH2SiMe3)2.NMe3 Inorganic Chemistry. 22: 1054-1059. DOI: 10.1021/Ic00149A009  0.767
1983 Churchill MR, Wasserman HJ. Crystal and molecular structure of W(.eta.2-HC.tplbond.COAlCl3)(CO)(PMe3)3Cl, a product of the coupling of methylidyne and carbonyl ligands on tungsten Inorganic Chemistry. 22: 41-44. DOI: 10.1021/Ic00143A011  0.684
1983 Churchill MR, Bueno C. Structural studies on osmium carbonyl hydrides XXVII. The heteronuclear rhodium-triosmium cluster (μ-H)3Os3Rh(CO)9(η6-C6H5me) Journal of Organometallic Chemistry. 256: 357-364. DOI: 10.1016/S0022-328X(00)99211-8  0.781
1983 Churchill MR, Missert JR. Structural studies on osmium carbonyl hydrides XXVI. Crystal structure of a complex with a 2-methylimidazolyl ligand bound to a triosmium cluster: (μ-H)Os3(CO)10[μ-3,4-η2-C3N2H2(2-CH3)] ☆ Journal of Organometallic Chemistry. 256: 349-356. DOI: 10.1016/S0022-328X(00)99210-6  0.525
1983 Churchill MR, Wasserman HJ. Structure of an asymmetric dinuclear organotantalum complex with three different bridging ligands: [(η5-C5Me4Et)TaCl2](μ-η1-N,η2-C,N-NCHMe)(μ-Cl)(μ-H)[(η5-C5Me4Et)TaCl] Journal of Organometallic Chemistry. 247: 175-186. DOI: 10.1016/S0022-328X(00)98753-9  0.71
1983 Churchill MR, Wasserman HJ. Crystal structure of a complex with a substituted methylene ligand bound to a triosmium cluster: Os3(CO)10(μ-CO)(μ-CHSiMe3) Journal of Organometallic Chemistry. 248: 365-373. DOI: 10.1016/S0022-328X(00)98718-7  0.729
1983 Rheingold AL, Churchill MR. The synthesis and structural characterization of [η-C5H5Mo(CO)2]2[μ-catena-(CH3As)5]. An example of a ring → chain conversion upon coordination Journal of Organometallic Chemistry. 243: 165-173. DOI: 10.1016/0022-328X(83)89527-8  0.497
1983 Rosen RP, Geoffroy GL, Bueno C, Churchill MR, Ortega RB. Photoinduced formation of phosphido-bridged clusters derived from Ru3(CO)9(PPh2H)3. Crystal and molecular structure of Ru3(μ-H)(μ-PPh2)3(CO)7 Journal of Organometallic Chemistry. 254: 89-103. DOI: 10.1016/0022-328X(83)85121-3  0.799
1983 Park JT, Shapley JR, Churchill MR, Bueno C. Coordination And Scission Of Alkynes On A Tungsten-Triosmium Framework Cheminform. 14. DOI: 10.1002/Chin.198351309  0.312
1983 PARK JT, SHAPLEY JR, CHURCHILL MR, BUENO C. ChemInform Abstract: REACTION OF (μ-H)2OS3(CO)10 WITH (η5-C5H5)(CO)2WCC6H4CH3. CRYSTAL STRUCTURE OF (η5-C5H5)WOS3(CO)11(C(O)CH2C6H4CH3).≅0.5CCL4, A COMPLEX WITH A TRIPLY BRIDGING (μ3,η2) ACYL LIGAND ON THE SURFACE OF A TRIANGULATED RHOMBOIDAL METAL CLUST Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198335338  0.463
1983 CHURCHILL MR, WASSERMAN HJ. ChemInform Abstract: X-RAY STRUCTURAL STUDY OF AN ALKYLIDENE-CARBONYL COMPLEX OF TUNGSTEN(IV): W(:CHCME3)(CO)(PME3)2CL2 Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198335069  0.695
1983 TESSIER-YOUNGS C, BUENO C, BEACHLEY OTJ, CHURCHILL MR. ChemInform Abstract: TRANSITION-METAL COMPLEXES OF ORGANOALUMINUM PHOSPHIDES. SYNTHESIS, CHARACTERIZATION, AND CRYSTAL AND MOLECULAR STRUCTURE OF CR(CO)5(PPH2AL)(CH2SIME3)2.NME3 Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198327287  0.768
1983 SHORE SG, HSU W, CHURCHILL MR, BUENO C. ChemInform Abstract: UNUSUAL LIGAND REPLACEMENT: DISPLACEMENT OF η5-CYCLOPENTADIENYL BY η6-ARENES IN THE SYNTHESES OF H3(η6-X)RHOS3(CO)9 (X = C6H6, PHME). CRYSTAL AND MOLECULAR STRUCTURE OF H3(η6-PHME)RHOS3(CO)9 Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198321297  0.789
1983 CHURCHILL MR, WASSERMAN HJ. ChemInform Abstract: CRYSTAL AND MOLECULAR STRUCTURE OF W(η2-HCCOALCL3)(CO)(PME3)3CL, A PRODUCT OF THE COUPLING OF METHYLIDYNE AND CARBONYL LIGANDS ON TUNGSTEN Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198315086  0.351
1982 Shore SG, Hsu WL, Weisenberger CR, Caste ML, Churchill MR, Bueno C. New synthesis of mixed-metal clusters from H2Os3(CO)10. Crystal and molecular structure of the paramagnetic cluster H3(.eta.5-C5H5)CoOs3(CO)9 and its diamagnetic structural analog H3(.eta.C5H5)NiOs3(CO)9 Organometallics. 1: 1405-1407. DOI: 10.1021/Om00070A028  0.775
1982 Rocklage SM, Schrock RR, Churchill MR, Wasserman HJ. Multiple metal carbon bonds. Part 29. Facile conversion of tungsten(VI) neopentylidyne complexes into oxo and imido neopentylidene complexes and the crystal structure of W(CCMe3)(PHPh)(PEt3)2Cl2 Organometallics. 1: 1332-1338. DOI: 10.1021/Om00070A015  0.712
1982 Churchill MR, Wasserman HJ, Holmes SJ, Schrock RR. Coupling of methylidyne and carbonyl ligands on tungsten. Crystal structure of W(.eta.2-HC.tplbond.COAlCl3)(CO)(PMe3)3Cl Organometallics. 1: 766-768. DOI: 10.1021/Om00065A022  0.729
1982 Boland-Lussier BE, Churchill MR, Hughes RP, Rheingold AL. Synthesis and characterization of cationic iron vinylidene compounds: formation of carbon-hydrogen, carbon-nitrogen and carbon-phosphorus bonds and the x-ray crystal structure of [Fe(.eta.-C5H5)(CO)(PPh3) {C(PPh3):CH2}]+BF4- Organometallics. 1: 628-634. DOI: 10.1021/Om00064A010  0.49
1982 Churchill MR, Wasserman HJ, Belmonte PA, Schrock RR. Reduction of nitriles by a binuclear tantalum hydride complex. Structural study of [(.eta.5-C5Me4Et)TaCl2](.mu.-.eta.1-N,.eta.2-C,N-NCHMe)(.mu.-Cl)(.mu.-H)[.eta.5-C5Me4Et)TaCl] Organometallics. 1: 559-561. DOI: 10.1021/Om00063A028  0.686
1982 Hayward CMT, Shapley JR, Churchill MR, Bueno C, Rheingold AL. Synthesis, characterization, and crystal structure of the [Ru10C2(CO)24] dianion. An edge-fused bioctahedral dicarbide cluster Journal of the American Chemical Society. 104: 7347-7349. DOI: 10.1021/Ja00389A090  0.502
1982 Pedersen SF, Schrock RR, Churchill MR, Wasserman HJ. Reaction of tungsten(VI) alkylidyne complexes with acetylenes to give tungstenacyclobutadiene and cyclopentadienyl complexes Cheminform. 14: 6808-6809. DOI: 10.1021/Ja00388A068  0.659
1982 Wengrovius JH, Schrock RR, Churchill MR, Wasserman HJ. Multiple metal-carbon bonds. 25. Preparation and structure of tungsten neopentylidene hydride, neopentylidene carbonyl, and neopentylidene ethylene complexes Journal of the American Chemical Society. 104: 1739-1740. DOI: 10.1021/Ja00370A051  0.67
1982 Churchill MR, Wasserman HJ, Turner HW, Schrock RR. .alpha.-Hydride elimination: the first observable equilibriums between alkylidene complexes and alkylidyne hydride complexes Journal of the American Chemical Society. 104: 1710-1716. DOI: 10.1021/Ja00370A044  0.636
1982 Churchill MR, Wasserman HJ. Crystal and molecular structure of [W(CH2PMe3)(CO)2Cl(PMe3)3][CF3SO3], a seven-coordinate tungsten(II) complex produced by transfer of a trimethylphosphine to the W:CH2 system Inorganic Chemistry. 21: 3913-3916. DOI: 10.1021/Ic00141A011  0.736
1982 Shapley JR, St. George GM, Churchill MR, Hollander FJ. Structural studies on polynuclear osmium carbonyl hydrides. 23. Vibrational study and crystal structure of (.mu.-hydrido)(.mu.-formato)decacarbonyltriosmium (.mu.-H)(.mu.-O2CH)Os3(CO)10 Inorganic Chemistry. 21: 3295-3303. DOI: 10.1021/Ic00139A010  0.681
1982 Churchill MR, Bueno C, Hsu WL, Plotkin JS, Shore SG. Structural studies on polynuclear osmium carbonyl hydrides. 22. Crystal structure and carbon-13 NMR spectra of (.mu.-H)2Os3Fe(CO)13 Inorganic Chemistry. 21: 1958-1963. DOI: 10.1021/Ic00135A049  0.769
1982 Churchill MR, Bueno C, Hutchinson JP. Iridium carbonyl clusters. 5. Crystal structure and molecular geometry of (.eta.5-C5H5)2W2Ir2(CO)10 Inorganic Chemistry. 21: 1359-1363. DOI: 10.1021/Ic00134A017  0.785
1982 Churchill MR, Rheingold AL. Crystal structure and molecular geometry of an octahedral oxo-alkylidene complex of tungsten(VI), W(:O)(:CHCMe3)(PMe3)2Cl2 Inorganic Chemistry. 21: 1357-1359. DOI: 10.1021/Ic00134A016  0.544
1982 Churchill MR, Davies G, El-Sayed MA, Hutchinson JP. Synthesis, physical properties and structural characterization of .mu.-carbonato-dicopper(II) complexes. 3. Isolation of a racemic crystal form of .mu.-carbonato-dichlorobis(N,N,N',N'-tetramethyl-1,3-propanediamine)dicopper(II) from a substitution reaction of biscarbonatotetrakis[chloro(N,N-diethylnicotinamide)copper(II)] Inorganic Chemistry. 21: 1002-1007. DOI: 10.1021/Ic00133A026  0.311
1982 Churchill MR, Davies G, El-Sayed MA, Hutchinson JP, Rupich MW. Synthesis, structure and properties of the tetranuclear complexes [(DENC)CuX]4 (DENC = N,N-diethylnicotinamide; X = Cl, Br, I) and the kinetics of oxidation of the chloride and bromide by dioxygen in aprotic solvents Inorganic Chemistry. 21: 995-1001. DOI: 10.1021/Ic00133A025  0.347
1982 Churchill MR, Wasserman HJ. Crystal structure of Os3(CO)10(.mu.-CO)(.mu.-CH2). A 4-fold disordered structure in a crystal isomorphous with carbonyliron (Fe3(CO)12) Inorganic Chemistry. 21: 825-827. DOI: 10.1021/Ic00132A070  0.727
1982 Churchill MR, Bueno C, Wasserman HJ. X-ray structural study of (.eta.5-C5H5)2W2Os(CO)7[.mu.3-MeC6H4C.tplbond.CC6H4Me]. An unusual example of two isomers of a complex in an ordered single crystal Inorganic Chemistry. 21: 640-644. DOI: 10.1021/Ic00132A035  0.84
1982 Shapley JR, Samkoff DE, Bueno C, Churchill MR. Reaction of Os3(CO)10(NCCH3)2 with imidazole and related aromatic heterocycles. The crystal and molecular structure of (.mu.-H)Os3(CO)10(.mu.-3,4-.eta.2-N2C3H3) Inorganic Chemistry. 21: 634-639. DOI: 10.1021/Ic00132A034  0.774
1982 Churchill MR, Bueno C, Kennedy S, Bricker JC, Plotkin JS, Shore SG. Structural studies on polynuclear osmium carbonyl hydrides. Part 20. Crystal structure and NMR spectra of (.mu.-H)2Os3Co(CO)10(.eta.5-C5H5) Inorganic Chemistry. 21: 627-633. DOI: 10.1021/Ic00132A033  0.789
1982 Churchill MR, Wasserman HJ. Crystal structure and molecular geometry of a dinuclear formyl complex of tantalum, [(.eta.5-C5Me4Et)TaCl2]2(.mu.-H)(.mu.-CHO). A unique "side-on" bridging mode for the formyl ligand Inorganic Chemistry. 21: 226-230. DOI: 10.1021/Ic00131A042  0.735
1982 Churchill MR, Wasserman HJ. The Ta(.mu.-N2)Ta system. 3. Crystal structure of an octahedral tantalum(V) imide complex, mer-Ta(:NPh)(THF)(PEt3)Cl3, and comparisons with related Ta(.mu.-N2)Ta systems Inorganic Chemistry. 21: 223-226. DOI: 10.1021/Ic00131A041  0.692
1982 Churchill MR, Wasserman HJ. The Ta(.mu.-N2)Ta system. 2. Crystal structure of [TaCl3(P(bz)3)(THF)]2(.mu.-N2)..apprx.0.7CH2Cl2. A binuclear di-imido complex of octahedral tantalum (V) Inorganic Chemistry. 21: 218-222. DOI: 10.1021/Ic00131A040  0.7
1982 SHAPLEY JR, GEORGE GMS, CHURCHILL MR, HOLLANDER FJ. ChemInform Abstract: Structural Studies on Polynuclear Osmium Carbonyl Hydrides. Part 23. Chemischer Informationsdienst. 13. DOI: 10.1002/Chin.198248071  0.642
1982 CHURCHILL MR, DAVIES G, EL-SAYED MA, HUTCHINSON JP. ChemInform Abstract: SYNTHESIS, PHYSICAL PROPERTIES AND STRUCTURAL CHARACTERIZATION OF μ-CARBONATO-DICOPPER(II) COMPLEXES. 3. ISOLATION OF A RACEMIC CRYSTAL FORM M OF μ-CARBONATO-DICHLOROBIS(N,N,N′,N′-TETRAMETHYL-1,3-PROPANEDIAMINE)DICOPPER(II# ) FROM A S Chemischer Informationsdienst. 13. DOI: 10.1002/Chin.198225270  0.381
1982 Churchill MR, Bueno C, Wasserman HJ. X-RAY STRUCTURAL STUDY OF (η5-C5H5)2W2OS(CO)7(μ3-MEC6H4CCC6H4ME). AN UNUSUAL EXAMPLE OF TWO ISOMERS OF A COMPLEX IN AN ORDERED SINGLE CRYSTAL Cheminform. 13. DOI: 10.1002/Chin.198219062  0.84
1982 Churchill MR, Bueno C, Kennedy S, Bricker JC, Plotkin JS, Shore SG. Structural studies on polynuclear osmium carbonyl hydrides. 20. Crystal structure and NMR spectra of (μ-H)2Os3Co(CO)10(η5-C 5H5) Inorganic Chemistry. 21: 627-633. DOI: 10.1002/Chin.198219061  0.773
1982 CHURCHILL MR, WASSERMAN HJ. ChemInform Abstract: CRYSTAL STRUCTURE OF OS3(CO)10(μ-CO)(μ-CH2). A 4-FOLD DISORDERED STRUCTURE IN A CRYSTAL ISOMORPHOUS WITH CARBONYLIRON (FE3(CO)12) Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198217059  0.361
1982 CHURCHILL MR, WASSERMAN HJ. ChemInform Abstract: CRYSTAL STRUCTURE AND MOLECULAR GEOMETRY OF A DINUCLEAR FORMYL COMPLEX OF TANTALUM, ((η5-C5ME4ET)TACL2)2(μ-H)(μ-CHO). A UNIQUE “SIDE-ON” BRIDGING MODE FOR THE FORMYL LIGAND Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198215084  0.386
1982 CHURCHILL MR, WASSERMAN HJ. ChemInform Abstract: THE TA(μ-N2)TA SYSTEM. 2. CRYSTAL STRUCTURE OF (TACL3(P(BZ)3)(THF))2(μ-N2).≅0.7CH2CL2. A BINUCLEAR DI-IMIDO COMPLEX OF OCTAHEDRAL TANTALUM (V) Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198214070  0.3
1982 Churchill MR, Hollander FJ. STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES. 19. SYNTHESIS AND D CRYSTAL STRUCTURE OF (μ-H)OS3RE(CO)15(NCME), AN EQUATORIALLY METALLO-LIGATED TRIANGULAR CLUSTER COMPLEX Cheminform. 13. DOI: 10.1002/Chin.198212089  0.699
1982 CHURCHILL MR, WASSERMAN HJ. ChemInform Abstract: ALUMINATED METAL ALKYLIDYNE COMPLEXES. CRYSTAL AND MOLECULAR STRUCTURE OF W(CAL2ME4CL)(CH3)(PME3)2(η2-C2H4) Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198212088  0.331
1982 Churchill MR, Hutchinson JP. Iridium carbonyl clusters. 4. Crystal structure and molecular geometry of (.eta.5-C5H5)WIr3(CO)11 Cheminform. 13. DOI: 10.1002/Chin.198212087  0.465
1982 SHAPLEY JR, HARDWICK SJ, FOOSE DS, STUCKY GD, CHURCHILL MR, BUENO C, HUTCHINSON JP. ChemInform Abstract: BIMETALLIC CATALYSTS FROM PSEUDOTETRAHEDRAL IRIDIUM-TUNGSTEN CLUSTERS. SYNTHESIS AND CRYSTAL STRUCTURES OF (η5-C5H5)WIR3(CO)11 AND (η5-C5H5)2W2IR2(CO)10 Chemischer Informationsdienst. 13. DOI: 10.1002/Chin.198211325  0.766
1982 SHAPLEY JR, PARK JT, CHURCHILL MR, BUENO C, WASSERMAN HJ. ChemInform Abstract: REMARKABLY FACILE OSMIUM-OSMIUM BOND CLEAVAGE IN THE REACTION OF H2OS3(CO)10 WITH A TUNGSTEN CARBYNE. CRYSTAL STRUCTURES OF CPWOS3(CO)11(C(O)CH2C6H4ME) AND CP2W2OS(CO)7(C2(C6H4ME)2) Chemischer Informationsdienst. 13. DOI: 10.1002/Chin.198211323  0.81
1982 Shapley JR, Sievert AC, Churchill MR, Wasserman HJ. Coordination and coupling of alkylidene groups on a triosmium cluster framework. Crystal structure of Os3(CO)10(.mu.-CO)(.mu.-CHSiMe3) Cheminform. 13. DOI: 10.1002/Chin.198208335  0.706
1982 CHURCHILL MR, RHEINGOLD AL, WASSERMAN HJ. ChemInform Abstract: STRUCTURAL STUDIES ON TUNGSTEN METHYLIDYNE COMPLEXES. MOLECULAR GEOMETRY OF W(CH)(CL)(PME3)4 AND W(CH.ALME2-XCL1+X)(CL)(PME3)3 (X ≅ 0.18), A LEWIS ACID ADDUCT OF THE TUNGSTEN-METHYLIDYNE TRIPLE BOND Chemischer Informationsdienst. 13. DOI: 10.1002/Chin.198202073  0.717
1981 Churchill MR, Harris GM, Inoue T, Lashewycz RA. The meridional isomer of (diethylenetriamine)trinitrocobalt(III), mer-[Co(dien)(NO2)3] Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 37: 933-934. DOI: 10.1107/S0567740881004652  0.769
1981 Churchill MR, Harris GM, Inoue T, Lashewycz RA. The symmetrical-facial isomer of ammine(diethylenetriamine)dinitrocobalt(III) chloride, s-fac-[Co(dien)(NH3)(NO2)2] Cl Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 37: 695-697. DOI: 10.1107/S056774088100397X  0.754
1981 Churchill MR, Wasserman HJ. A unique ‘side-on’ bridging mode for the formyl (CHO) ligand in a binuclear tantalum complex; X-ray structural study of [(η5-C5Me4Et)TaCl2]2(µ-H)(µ-CHO) Journal of the Chemical Society, Chemical Communications. 274-275. DOI: 10.1039/C39810000274  0.71
1981 Shapley JR, Park JT, Churchill MR, Bueno C, Wasserman HJ. Remarkably facile Os-Os bond cleavage in the reaction of H2Os3(CO)10 with a tungsten carbyne. Crystal structures of CpWOs3(CO)11[C(O)CH2C6H 4Me] and Cp2W2Os(CO)7[C2(C6H 4Me)2] Journal of the American Chemical Society. 103: 7385-7387. DOI: 10.1021/Ja00414A081  0.82
1981 Shapley JR, Hardwick SJ, Foose DS, Stucky GD, Churchill MR, Bueno C, Hutchinson JP. Bimetallic catalysts from pseudotetrahedral iridium-tungsten clusters. Synthesis and crystal structures of (.eta.5-C5H5)WIr3(CO)11 and (.eta.5-C5H5)2W2Ir2(CO)10 Journal of the American Chemical Society. 103: 7383-7385. DOI: 10.1021/Ja00414A080  0.764
1981 Shapley JR, Sievert AC, Churchill MR, Wasserman HJ. Coordination and coupling of alkylidene groups on a triosmium cluster framework. Crystal structure of Os3(CO)10(.mu.-CO)(.mu.-CHSiMe3) Journal of the American Chemical Society. 103: 6975-6977. DOI: 10.1021/Ja00413A041  0.706
1981 Churchill MR, Hollander FJ, Lashewycz RA, Pearson GA, Shapley JR. Mixed-metal clusters by metal hydride coupling. Crystal structures of (.mu.-H)Os3Re(CO)15(NCCH3) and (.mu.-H)5Os3Re(CO)12. Direct conversion of a metalloligated cluster to a closed polyhedron Journal of the American Chemical Society. 103: 2430-2431. DOI: 10.1021/Ja00399A059  0.806
1981 Sharp PR, Holmes SJ, Schrock RR, Churchill MR, Wasserman HJ. Multiple metal-carbon bonds. 20. Tungsten methylidyne complexes Journal of the American Chemical Society. 103: 965-966. DOI: 10.1021/Ja00394A053  0.638
1981 Churchill MR, Hollander FJ. Structural studies on polynuclear osmium carbonyl hydrides. 19. Synthesis and crystal structure of (.mu.-H)Os3Re(CO)15(NCMe), an equatorially metallo-ligated triangular cluster complex Inorganic Chemistry. 20: 4124-4128. DOI: 10.1021/Ic50226A018  0.706
1981 Churchill MR, Wasserman HJ. Aluminated metal alkylidyne complexes. Crystal and molecular structure of W(CAl2Me4Cl)(CH3)(PMe3)2(.eta.2-C2H4) Inorganic Chemistry. 20: 4119-4123. DOI: 10.1021/Ic50226A017  0.717
1981 Churchill MR, Hutchinson JP. Iridium carbonyl clusters. 4. Crystal structure and molecular geometry of (.eta.5-C5H5)WIr3(CO)11 Inorganic Chemistry. 20: 4112-4114. DOI: 10.1021/Ic50226A015  0.465
1981 Churchill MR, Rheingold AL, Wasserman HJ. Structural studies on tungsten methylidyne complexes. Molecular geometry of W(.tplbond.CH)(Cl)(PMe3)4 and W(.tplbond.CH.AlMe2-xCl1+x)(Cl)(PMe3)3 (x .simeq. 0.18), a Lewis acid adduct of the tungsten-methylidyne triple bond Inorganic Chemistry. 20: 3392-3399. DOI: 10.1021/Ic50224A048  0.724
1981 Churchill MR, Missert JR, Youngs WJ. Crystal structure and molecular geometry of a trigonal-bipyramidal oxo-alkylidene complex of tungsten(VI), W(=O)(=CHCMe3)(PEt3)Cl2 Inorganic Chemistry. 20: 3388-3391. DOI: 10.1021/Ic50224A047  0.636
1981 Churchill MR, Wasserman HJ. Structural studies of polynuclear osmium carbonyl hydrides. 18. Molecular geometry of (.mu.-H)Os3(CO)10(.mu.-NH-N:CPh2) Inorganic Chemistry. 20: 2905-2909. DOI: 10.1021/Ic50223A032  0.687
1981 Churchill MR, Wasserman HJ. Crystal and molecular structure of [Ta(:CHCMe3)(CH2CMe3)(PMe3)2]2(.mu.-N2), a molecule with a dinitrogen ligand behaving as a diimido group in a Ta:NN:Ta bridge Inorganic Chemistry. 20: 2899-2904. DOI: 10.1021/Ic50223A031  0.719
1981 Churchill MR, Rheingold AL, Keiter RL. Crystal structure and molecular geometry of (OC)4WPPh2CH(CH2CH2PPh2)CH2PPh2.CH3CO2C2H5. Free radical addition of diphenylphosphine to a coordinated phosphinoalkene Inorganic Chemistry. 20: 2730-2734. DOI: 10.1021/Ic50222A072  0.533
1981 Beachley OT, Bueno C, Churchill MR, Hallock RB, Simmons RG. Nature of the dimethylaluminum, -gallium, and -indium methylphenylamide dimers in solution and the molecular structure of [(CH3)2InN(CH3)(C6H5)]2 Inorganic Chemistry. 20: 2423-2428. DOI: 10.1021/Ic50222A012  0.737
1981 Bueno C, Churchill MR. Structural studies on some (.eta.5-C5H5)M(CO)3X molecules: (.eta.5-C5H5)W(CO)3Cl, (.eta.5-C5H5)Mo(CO)3Cl, and (.eta.5-C5H5)Mo(CO)3HgCl Inorganic Chemistry. 20: 2197-2202. DOI: 10.1021/Ic50221A051  0.741
1981 Churchill MR, Amoh KN, Wasserman HJ. Redetermination of the crystal structure of dimanganese decacarbonyl and determination of the crystal structure of dirhenium decacarbonyl. Revised values for the manganese-manganese and rhenium-rhenium bond lengths in dimanganese decacarbonyl and dirhenium decacarbonyl Inorganic Chemistry. 20: 1609-1611. DOI: 10.1021/Ic50219A056  0.72
1981 Churchill MR, Landers AG, Rheingold AL. Crystal structure and molecular geometry of [(.eta.5-C5H5)2Fe]2As4Cl10O2, the ferrocenium salt of a complex oxychloroarsenate(III) counterion Inorganic Chemistry. 20: 849-853. DOI: 10.1021/Ic50217A042  0.551
1981 Churchill MR, Missert JR. Molecules with an M4X4 core. 12. Disruption of tetrameric (triphenylarsine)copper(I) iodide in acetonitrile solution. Crystal structure of [(AsPh3)(MeCN)CuI]2 Inorganic Chemistry. 20: 619-621. DOI: 10.1021/Ic50216A057  0.389
1981 Smith G, Schrock RR, Churchill MR, Youngs WJ. Synthesis of alkyne complexes of the type Ta(.eta.5-C5Me5)(alkyne)Cl2 and crystal structure of (.eta.5-pentamethylcyclopentadienyl)(diphenylacetylene)dichlorotantalum Inorganic Chemistry. 20: 387-393. DOI: 10.1021/Ic50216A014  0.656
1981 Churchill MR, Youngs WJ. Crystal structure and molecular geometry of a dinuclear "disrupted formyl" complex of tantalum, [(.eta.5-C5Me4Et)TaCl2]2(H)(.mu.-CHPMe3)(.mu.-O) Inorganic Chemistry. 20: 382-387. DOI: 10.1021/Ic50216A013  0.648
1981 Churchill MR, Bueno C, Young DA. Synthesis and structure of FeRu3(CO)13(μ-PPh2)2; A “64-electron” cluster complex with a planar triangulated rhomboidal array of metal atoms Journal of Organometallic Chemistry. 213: 139-150. DOI: 10.1016/S0022-328X(00)93955-X  0.784
1981 Churchill MR, Rheingold AL, Youngs WJ, Schrock RR, Wengrovius JH. X-ray crystallographic studies on octahedral oxo alkylidene complexes of tungsten(VI): W(O)(CHCMe3)(PMe3)2Cl2 and W(O)(CHCMe3)(PEt3)2Cl2 Journal of Organometallic Chemistry. 204: C17-C20. DOI: 10.1016/S0022-328X(00)84595-7  0.656
1981 BEACHLEY OTJ, BUENO C, CHURCHILL MR, HALLOCK RB, SIMMONS RG. ChemInform Abstract: NATURE OF THE DIMETHYLALUMINUM, -GALLIUM, AND -INDIUM METHYLPHENYLAMIDE DIMERS IN SOLUTION AND THE MOLECULAR STRUCTURE OF ((CH3)2INN(CH3)(C6H5))2 Chemischer Informationsdienst. 12. DOI: 10.1002/Chin.198145261  0.76
1981 CHURCHILL MR, AMOH KN, WASSERMAN HJ. ChemInform Abstract: REDETERMINATION OF THE CRYSTAL STRUCTURE OF DIMANGANESE DECACARBONYL AND DETERMINATION OF THE CRYSTAL STRUCTURE OF DIRHENIUM DECACARBONYL. REVISED VALUES FOR THE MANGANESE-MANGANESE AND RHENIUM-RHENIUM BOND LENGTHS IN DIMANGANESE DECA Chemischer Informationsdienst. 12. DOI: 10.1002/Chin.198132068  0.721
1981 Churchill MR, Wasserman HJ. Structural studies on polynuclear osmium carbonyl hydrides. 17. (.mu.-H)Os3(CO)10[.mu.-N:N(p-tol)] Inorganic Chemistry. 20: 1580-1584. DOI: 10.1002/Chin.198132066  0.655
1981 CHURCHILL MR, HOLLANDER FJ, LASHEWYCZ RA, PEARSON GA, SHAPLEY JR. ChemInform Abstract: MIXED-METAL CLUSTERS BY METAL HYDRIDE COUPLING. CRYSTAL STRUCTURES OF (μ-H)OS3RE(CO)15(NCCH3) AND (μ-H)5OS3RE(CO)12. DIRECT CONVERSION OF A METALLOLIGATED CLUSTER TO A CLOSED POLYHEDRON Chemischer Informationsdienst. 12. DOI: 10.1002/chin.198131077  0.61
1981 Churchill MR, Hollander FJ, Lashewycz RA, Pearson GA, Shapley JR. Mixed-metal clusters by metal hydride coupling. Crystal structures of (μ-H)Os3Re(CO)15(NCCH3) and (μ-H)5Os3Re(CO)12. Direct conversion of a metalloligated cluster to a closed polyhedron Journal of the American Chemical Society. 103: 2430-2431. DOI: 10.1002/Chin.198131077  0.808
1981 SHARP PR, HOLMES SJ, SCHROCK RR, CHURCHILL MR, WASSERMAN HJ. ChemInform Abstract: MULTIPLE METAL-CARBON BONDS. 20. TUNGSTEN METHYLIDYNE COMPLEXES Chemischer Informationsdienst. 12. DOI: 10.1002/Chin.198122284  0.639
1981 CHURCHILL MR, LASHEWYCZ RA, KOSHY K, DASGUPTA TP. ChemInform Abstract: SYNTHESIS, PROPERTIES, AND CRYSTALLOGRAPHIC CHARACTERIZATION OF A DINUCLEAR μ-CARBONATO COMPLEX OF COBALT(III): ((NH3)3CO(μ-OH)2(μ-CO3)CO(NH3)3)SO4.5H2O Chemischer Informationsdienst. 12. DOI: 10.1002/Chin.198118038  0.764
1981 Smith G, Schrock RR, Churchill MR, Youngs WJ. SYNTHESIS OF ALKYNE COMPLEXES OF THE TYPE TA(η5-C5ME5)(ALKYNE)CL2 AND CRYSTAL STRUCTURE OF (η5-PENTAMETHYLCYCLOPENTADIENYL)(DIPHENYLACETYLENE)DICHLOROTANTALUM Cheminform. 12. DOI: 10.1002/Chin.198117105  0.661
1981 CHURCHILL MR, YOUNGS WJ. ChemInform Abstract: CRYSTAL STRUCTURE AND MOLECULAR GEOMETRY OF A DINUCLEAR “DISRUPTED FORMYL” COMPLEX OF TANTALUM, ((η5-C5ME4ET)TACL2)2(H)(μ-CHPME3)(μ-O) Chemischer Informationsdienst. 12. DOI: 10.1002/chin.198117104  0.379
1980 Turner HW, Fellmann JD, Rocklage SM, Schrock RR, Churchill MR, Wasserman HJ. Tantalum complexes containing diimido bridging dinitrogen ligands Journal of the American Chemical Society. 102: 7809-7811. DOI: 10.1021/Ja00546A044  0.678
1980 Wengrovius JH, Schrock RR, Churchill MR, Missert JR, Youngs WJ. Multiple metal-carbon bonds. 16. Tungsten-oxo alkylidene complexes as olefins metathesis catalysts and the crystal structure of W(O)(CHCMe3(PEt3)Cl2 Journal of the American Chemical Society. 102: 4515-4516. DOI: 10.1021/Ja00533A035  0.606
1980 Belmonte P, Schrock RR, Churchill MR, Youngs WJ. Preparation Of A “Stabilized Formyl” Complex From Carbon Monoxide And Hydrogen And The Crystal Structure Of A Derivative In Which The Carbon‐Oxygen Bond Has Been Cleaved Journal of the American Chemical Society. 11: 2858-2860. DOI: 10.1021/Ja00528A067  0.59
1980 Churchill MR, Youngs WJ. Discovery of an "opened-envelope" conformation for the TaC4 ring in tantalacyclopentane complexes. Crystal and molecular structures of Ta(.eta.5-C5Me5)(C4H8)Cl2 and Ta(.eta.5-C5Me5)(C7H12)Cl2 Inorganic Chemistry. 19: 3106-3112. DOI: 10.1021/Ic50212A056  0.635
1980 Wasserman HJ, Wovkulich MJ, Atwood JD, Churchill MR. Synthesis and molecular geometry of [(.eta.6-C6H5)As(C6H5)2]Cr(CO)3 Inorganic Chemistry. 19: 2831-2834. DOI: 10.1021/Ic50211A069  0.662
1980 Churchill MR, Hutchinson JP. Iridium carbonyl clusters. 3. Crystal structure and molecular geometry of Ir4(CO)10(diars), a derivative of dodecacarbonyltetrairidium (Ir4(CO)12) with one bridging and two "semibridging" carbonyl ligands Inorganic Chemistry. 19: 2765-2769. DOI: 10.1021/Ic50211A054  0.47
1980 Churchill MR, Wasserman HJ. Structural studies on polynuclear osmium carbonyl hydrides. 16. Crystal structure of (.mu.-H)(.mu.-OMe)Os3(CO)10 and a comparison of the hinged Os(.mu.-H)2Os, Os(.mu.-H)(.mu.-OMe)Os, and Os(.mu.-OMe)2Os bridges in trinuclear (.mu.-H)n(.mu.-OMe)2-nOs3(CO)10 (n = 0-2) complexes Inorganic Chemistry. 19: 2391-2395. DOI: 10.1021/Ic50210A043  0.688
1980 Churchill MR, Lashewycz RA, Shapley JR, Richter SI. Synthesis, crystal structure, and dynamic behavior of tetra-.mu.-hydrido-.mu.-[1,2-bis(diphenylphosphino)ethane]-decacarbonyltetraruthenium, an isomer of (.mu.-H)4Ru4(CO)10(diphos) with a bridging diphos ligand Inorganic Chemistry. 19: 1277-1285. DOI: 10.1021/Ic50207A034  0.804
1980 Churchill MR, Hollander FJ, Shapley JR, Keister JB. Structural studies on polynuclear osmium carbonyl hydrides. 15. Preparation and x-ray crystal structure of (.mu.-H) Os3(CO)10(.mu.-NHSO2C6H4Me), a complex with an Os(.mu.-H)(.mu.-N)Os bridge Inorganic Chemistry. 19: 1272-1277. DOI: 10.1021/Ic50207A033  0.692
1980 Churchill MR, Wasserman HJ, Young GJ. Cyclometalation of 2-p-tolylbenzthiazole and 2-p-tolylbenzoxazole with palladium(II) acetate. Synthesis and crystal structures of the acetate-bridged dimers [(MeC6H3C7H4NS)Pd]2(.mu.-O2CMe)2 and [(MeC6H3C7H4NO)Pd]2(.mu.-O2CMe)2 Inorganic Chemistry. 19: 762-770. DOI: 10.1021/Ic50205A037  0.655
1980 Churchill MR, Hollander FJ. Structural studies on polynuclear osmium carbonyl hydrides. 14. X-ray diffraction study of (.mu.-H)4Os4(CO)11(CNMe), including the direct location of all four bridging hydride ligands Inorganic Chemistry. 11: 306-310. DOI: 10.1021/Ic50204A006  0.669
1980 Churchill MR, Davies G, El-Sayed MA, El-Shazly MF, Hutchinson JP, Rupich MW. Synthesis, physical properties and structural characterization of .mu.-carbonato-dicopper(II) complexes. 2. Products of oxidation of Cu(I) by dioxygen in aprotic media containing carbon dioxide and alkylated diamine ligands and the crystal structure of paramagnetic (Et2NCH2CH2NEt2)2Cu2Cl2(asym.mu.-CO3) Inorganic Chemistry. 19: 201-208. DOI: 10.1021/Ic50203A041  0.408
1980 Wasserman HJ, Wovkulich MJ, Atwood JD, Churchill MR. Synthesis and molecular geometry of [(.eta.6-C6H5)As(C6H5)2]Cr(CO)3 Cheminform. 11. DOI: 10.1002/Chin.198048251  0.662
1980 Churchill MR, Hutchinson JP. Iridium carbonyl clusters. 3. Crystal structure and molecular geometry of Ir4(CO)10(diars), a derivative of dodecacarbonyltetrairidium (Ir4(CO)12) with one bridging and two "semibridging" carbonyl ligands Cheminform. 11. DOI: 10.1002/Chin.198048081  0.47
1980 Churchill MR, Lashewycz RA, Shapley JR, Richter SI. Synthesis, crystal structure, and dynamic behavior of tetra-.mu.-hydrido-.mu.-[1,2-bis(diphenylphosphino)ethane]-decacarbonyltetraruthenium, an isomer of (.mu.-H)4Ru4(CO)10(diphos) with a bridging diphos ligand Cheminform. 11. DOI: 10.1002/Chin.198032072  0.804
1980 Churchill MR, Julis SA. Dimeric (pentamethylcyclopentadienyl)rhodium and -iridium complexes. 6. Crystal structure of [(.eta.5-C5Me5)RhI]2(.mu.-I)2.2C6H5Me and systematics in the series [(.eta.5-C5Me5)RhX]2 (X = chlorine, bromine, iodine) Cheminform. 11. DOI: 10.1002/Chin.198002084  0.846
1979 Stobart SR, Churchill MR, Hollander FJ, Youngs WJ. Characterization and X-ray crystal structure of a monomeric germylene derivative, Ge(acac)I (hacac = acetylacetone) Journal of the Chemical Society, Chemical Communications. 911-912. DOI: 10.1039/C39790000911  0.757
1979 Churchill MR, Youngs WJ. X-Ray crystal structure of W(≡CCMe3)(=CHCMe 3)(CH2CMe3)(Me2PCH 2CH2PMe2), an ordered five-co-ordinate tungsten(VI) complex with metal-alkyl, metal-alkylidene, and metal-alkylidyne linkages Journal of the Chemical Society, Chemical Communications. 321-322. DOI: 10.1039/C39790000321  0.606
1979 Shapley JR, Stuntz GF, Churchill MR, Hutchinson JP. X-Ray crystal structure and dynamic behaviour of [Ir4(CO) 11(CNBut)] Journal of the Chemical Society, Chemical Communications. 219-220. DOI: 10.1039/C39790000219  0.365
1979 Churchill MR, Youngs WJ. X-ray crystallographic results on tantallacyclopentane complexes derived from ethylene and 1,6-heptadiene: Ta(.eta.5-C5Me5)(C4H8)Cl2 and Ta(.eta.5-C5Me5)(C7H12)Cl2 Journal of the American Chemical Society. 101: 6462-6463. DOI: 10.1021/Ja00515A067  0.591
1979 McLain SJ, Schrock RR, Sharp PR, Churchill MR, Youngs WJ. Synthesis of monomeric niobium- and tantalum-benzyne complexes and the molecular structure of Ta(.eta.5-C5Me5)(C6H4)Me2 Journal of the American Chemical Society. 101: 263-265. DOI: 10.1021/Ja00495A067  0.623
1979 Churchill MR, Lashewycz RA. Structural studies on polynuclear osmium carbonyl hydrides. 13. Molecular geometry of .mu.-bromo-.mu.-hydrido-decacarbonyltriosmium, (.mu.-H)(.mu.-Br)Os3(CO)10, and a comparison of Os(.mu.-H)(.mu.-X)Os bridges Inorganic Chemistry. 18: 3261-3267. DOI: 10.1021/Ic50201A063  0.772
1979 Bereman RD, Churchill MR, Schaber PM, Winkler ME. Preparation and crystal and molecular structure of dibromo(1,4,7-triazacyclononane)copper(II) Inorganic Chemistry. 18: 3122-3125. DOI: 10.1021/Ic50201A033  0.42
1979 Bereman RD, Churchill MR, Shields G. Coordination chemistry of new sulfur-containing ligands. 17. Preparation, characterization and crystal and molecular structure of [N,N'-trimethylenebis(methyl 2-amino-1-cyclopentenedithiocarboxylato)] copper(II), a highly distorted CuN2S2 compound Inorganic Chemistry. 18: 3117-3121. DOI: 10.1021/Ic50201A032  0.414
1979 Bereman RD, Churchill MR, Nalewajek D. Coordination chemistry of new sulfur-containing ligands. 16. Crystal and molecular structure of tris(pyrrole-n-carbodithioato)iron(III)-hemikis(dichloromethane), Fe(S2CNC4H4)3.0.5CH2Cl2, a low-spin dithiocarbamate complex of iron(III) Inorganic Chemistry. 18: 3112-3117. DOI: 10.1021/Ic50201A031  0.371
1979 Churchill MR, Julis SA. Dimeric (pentamethylcyclopentadienyl)rhodium and -iridium complexes. 6. Crystal structure of [(.eta.5-C5Me5)RhI]2(.mu.-I)2.2C6H5Me and systematics in the series [(.eta.5-C5Me5)RhX]2 (X = chlorine, bromine, iodine) Inorganic Chemistry. 18: 2918-2920. DOI: 10.1021/Ic50200A058  0.846
1979 Churchill MR, Youngs WJ. Crystal structure and molecular geometry of W(.tplbond.CCMe3)(:CHCMe3)(CH2CMe3)(dmpe), a mononuclear tungsten(VI) complex with metal-alkylidyne, metal-alkylidene, and metal-alkyl linkages Inorganic Chemistry. 18: 2454-2458. DOI: 10.1021/Ic50199A025  0.577
1979 Churchill MR, Hutchinson JP. Iridium carbonyl clusters. 2. Crystal structure and molecular geometry of Ir4(CO)11[CN(t-Bu)], a derivative of Ir4(CO)12 with no bridging carbonyl ligands Inorganic Chemistry. 10: 2451-2454. DOI: 10.1021/Ic50199A024  0.454
1979 Churchill MR, Harris GM, Lashewycz RA, Dasgupta TP, Koshy K. Binuclear complexes of transition metals containing carbonate ligands. Preparation, properties, and crystal structure of .mu.-amido-.mu.-hydroxo-tetraamminebis(carbonato)dicobalt(III) pentahydrate Inorganic Chemistry. 18: 2290-2295. DOI: 10.1021/Ic50198A048  0.796
1979 Churchill MR, Youngs WJ. Crystal structure and molecular geometry of Ta(:CHCMe3)2(mesityl)(PMe3)2, a bis(alkylidene) complex of tantalum with remarkably obtuse Ta:C(.alpha.)-C(.beta.) angles of 154.0(6) and 168.9(6).degree. Inorganic Chemistry. 18: 1930-1935. DOI: 10.1021/Ic50197A042  0.592
1979 Churchill MR, Lashewycz RA. Structural studies on polynuclear osmium carbonyl hydrides. 12. Molecular geometry of .mu.-chloro-.mu.-hydrido-decacarbonyltriosmium, (.mu.-H)(.mu.-Cl)Os3(CO)10, and characterization of the Os(.mu.-H)(.mu.-Cl)Os bridge Inorganic Chemistry. 18: 1926-1930. DOI: 10.1021/Ic50197A041  0.775
1979 Churchill MR, Youngs WJ. Crystal structure and molecular geometry of (.eta.2-benzyne)(.eta.5-pentamethylcyclopentadienyl)dimethyltantalum, a mononuclear tantalum-benzyne complex Inorganic Chemistry. 18: 1697-1702. DOI: 10.1021/Ic50196A060  0.667
1979 Churchill MR, Julis SA. Dimeric (pentamethylcyclopentadienyl)rhodium and -iridium complexes. 5. Structural studies on the homogeneous hydrogenation catalysts [(.eta.5-C5Me5)IrBr]2(.mu.-Br)2 and [(.eta.5-C5Me5)IrI]2(.mu.-I)2 and systematics in the series [(.eta.5-C5Me5)IrX]2(.mu.-X)2 (X = chlorine, bromine, iodine) Inorganic Chemistry. 18: 1215-1221. DOI: 10.1021/Ic50195A007  0.806
1979 Churchill MR, Youngs WJ. Molecules with an M4X4 core. Part 11. The unexpected isolation of the cubane-like isomer of tetrameric (triphenylarsine)copper(I) iodide. Crystal structure of [(AsPh3)CuI]4.C6H6 Inorganic Chemistry. 18: 1133-1138. DOI: 10.1021/Ic50194A046  0.637
1979 Churchill MR, Rotella FJ. Crystal structure and molecular configuration of a tetranuclear copper(II) complex active as a catalyst in the oxidative coupling of phenols by dioxygen: Cu4OCl6(nmp)3(OH2.cntdot..cntdot..cntdot.nmp) (nmp = N-methyl-2-pyrrolidinone) Inorganic Chemistry. 18: 853-860. DOI: 10.1021/Ic50193A063  0.385
1979 Churchill MR, Lashewycz RA. Structural studies on polynuclear osmium carbonyl hydrides. 11. Crystal structure and molecular geometry of (.mu.-H)Os3(CO)10(CHCH:NEt2), a species containing a .mu.2-hydride ligand and a .mu.2-1,3-dipolar >C-HCH:N+Et2 ligand Inorganic Chemistry. 18: 848-853. DOI: 10.1021/Ic50193A062  0.809
1979 Churchill MR, Hollander FJ. Structural studies on polynuclear osmium carbonyl hydrides. 10. Molecular geometry and comments on the location of the .mu.2-hydride ligand in (.mu.-H)Os3W(CO)12(.eta.5-C5H5) Inorganic Chemistry. 18: 843-848. DOI: 10.1021/Ic50193A061  0.683
1979 Churchill MR, Youngs WJ. Crystal and molecular structure of a tantalum-benzylidyne complex, Ta(.eta.5-C5Me5)(CPh)(PMe3)2Cl. Evidence for a tantalum-carbon triple bond Inorganic Chemistry. 18: 171-176. DOI: 10.1021/Ic50191A036  0.647
1979 Churchill MR, Rotella FJ. Molecules with an M4X4 core. 10. Failure of the 1:1:1 tricyclohexylphosphine-copper(I)-chloride complex to form a tetramer. Crystal structure of dimeric (tricyclohexylphosphine)copper(I) chloride, [(P(cHx)3)CuCl]2 Inorganic Chemistry. 18: 166-171. DOI: 10.1021/Ic50191A035  0.405
1979 Churchill MR, Hollander FJ. Structural studies on polynuclear osmium carbonyl hydrides. 9. The molecular geometry of (.mu.-H)3Os3W(CO)11(.eta.5-C5H5) including some comments on the positions of .mu.-hydride ligands in tetranuclear metal clusters Inorganic Chemistry. 18: 161-166. DOI: 10.1021/Ic50191A034  0.68
1979 Churchill MR, Lashewycz RA. Structural studies on polynuclear osmium caronyl hydrides. 8. Elucidation of the geometry and connectivity of (.mu.-H)Os3(CO)9-.mu.3-L, a molecule with a 3-ethylidene-4-ethyl-1-oxocyclopent-4-en-2-yl ligand(L) bridging three osmium atoms Inorganic Chemistry. 18: 156-161. DOI: 10.1021/Ic50191A033  0.77
1979 Shapley JR, Stuntz GF, Churchill MR, Hutchinson JP. Crystal structure and dynamic behavior of Ir4(CO)10(diars). A new pathway for carbonyl scrambling in M4(CO)12 derivatives [16] Journal of the American Chemical Society. 101: 7425-7428. DOI: 10.1002/Chin.198010051  0.359
1979 CHURCHILL MR, LASHEWYCZ RA. ChemInform Abstract: STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES. 12. MOLECULAR GEOMETRY OF μ-CHLORO-μ-HYDRIDO-DECACARBONYLTRIOSMIUM, (μ-H)(μ-CL)OS3(CO)10, AND CHARACTERIZATION OF THE OS(μ-H)(μ-CL)OS BRIDGE Chemischer Informationsdienst. 10. DOI: 10.1002/chin.197942097  0.304
1979 CHURCHILL MR, YOUNGS WJ. ChemInform Abstract: CRYSTAL STRUCTURE AND MOLECULAR GEOMETRY OF (η2-BENZYNE)(η5-PENTAMETHYLCYCLOPENTADIENYL)DIMETHYLTANTALUM, A MONONUCLEAR TANTALUM-BENZYNE COMPLEX Chemischer Informationsdienst. 10. DOI: 10.1002/chin.197939062  0.409
1979 CHURCHILL MR, YOUNGS WJ. ChemInform Abstract: MOLECULES WITH AN M4X4 CORE. PART 11. THE UNEXPECTED ISOLATION OF THE CUBANE-LIKE ISOMER OF TETRAMERIC (TRIPHENYLARSINE)COPPER(I) IODIDE. CRYSTAL STRUCTURE OF ((ASPH3)CUI)4.C6H6 Chemischer Informationsdienst. 10. DOI: 10.1002/Chin.197929077  0.637
1979 Churchill MR, Lashewycz RA. Structural studies on polynuclear osmium carbonyl hydrides. 11. Crystal structure and molecular geometry of (.mu.-H)Os3(CO)10(CHCH:NEt2), a species containing a .mu.2-hydride ligand and a .mu.2-1,3-dipolar >C-HCH:N+Et2 ligand Cheminform. 10. DOI: 10.1002/Chin.197925066  0.809
1979 Churchill MR, Hollander FJ. Structural studies on polynuclear osmium carbonyl hydrides. 10. Molecular geometry and comments on the location of the .mu.2-hydride ligand in (.mu.-H)Os3W(CO)12(.eta.5-C5H5) Cheminform. 10. DOI: 10.1002/Chin.197925065  0.683
1979 McLain SJ, Schrock RR, Sharp PR, Churchill MR, Youngs WJ. SYNTHESIS OF MONOMERIC NIOBIUM- AND TANTALUM-BENZYNE COMPLEXES AND THE MOLECULAR STRUCTURE OF TA(η5-C5ME5)(C6H4)ME2 Cheminform. 10. DOI: 10.1002/Chin.197915308  0.625
1979 CHURCHILL MR, LASHEWYCZ RA. ChemInform Abstract: STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARONYL HYDRIDES. 8. ELUCIDATION OF THE GEOMETRY AND CONNECTIVITY OF (μ-H)OS3(CO)9-μ3-L, A MOLECULE WITH A 3-ETHYLIDENE-4-ETHYL-1-OXOCYCLOPENT-4-EN-2-YL LIGAND(L) BRIDGING THREE OSMIUM ATOMS Chemischer Informationsdienst. 10. DOI: 10.1002/Chin.197915078  0.773
1979 Davies G, El‐Shazly MF, Rupich MW, Churchill MR, Rotella FJ. Synthesis, X‐Ray Crystal Structure, And Properties Of A Tetranuclear Complex Formed By Oxidation Of Copper(I) Chloride With Molecular Dioxygen In N‐Methylpyrrolidin‐2‐One. Isolation Of A Catalyst For The Oxidative Coupling Of Phenols By Dioxygen Cheminform. 10. DOI: 10.1002/Chin.197914330  0.358
1979 CHURCHILL MR, HOLLANDER FJ. ChemInform Abstract: STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES. 7. CRYSTAL STRUCTURE AND MOLECULAR GEOMETRY OF DI-μ-HYDRIDO-EICOSACARBONYLTRIOSMIUMDIRHENIUM(3OS-OS,2OS-RE) Chemischer Informationsdienst. 10. DOI: 10.1002/chin.197909062  0.625
1978 Churchill MR, Youngs WJ. Evidence for an almost 'T-shaped' co-ordination geometry for carbon in the bis(alkylidene) complex Ta(=CH·CMe3)2(2,4,6-Me 3C6H2)(PMe3)2: X-ray crystal structure Journal of the Chemical Society, Chemical Communications. 1048-1049. DOI: 10.1039/C39780001048  0.644
1978 Davies G, El-Shazly MF, Rupich MW, Churchill MR, Rotella FJ. Synthesis, X-ray crystal structure, and properties of a tetranuclear complex formed by oxidation of copper(I) chloride with molecular dioxygen in N-methylpyrrolidin-2-one. Isolation of a catalyst for the oxidative coupling of phenols by dioxygen Journal of the Chemical Society, Chemical Communications. 1045-1046. DOI: 10.1039/C39780001045  0.389
1978 Churchill MR, Hollander FJ, Shapley JR, Foose DS. New mixed-metal clusters via metal hydride coupling. Synthesis and crystal structures of [(µ2-H)Os3W(CO)12(η5-C5H5)] and [(µ2-H)3Os3W(CO)11(η5-C5H5)] Journal of the Chemical Society, Chemical Communications. 534-535. DOI: 10.1039/C39780000534  0.682
1978 McLain SJ, Wood CD, Messerle LW, Schrock RR, Hollander FJ, Youngs WJ, Churchill MR. Multiple metal-carbon bonds. 10. Thermally stable tantalum alkylidyne complexes and the crystal structure of Ta(.eta.5-C5Me5)(CPh)(PMe3)2Cl Journal of the American Chemical Society. 100: 5962-5964. DOI: 10.1021/Ja00486A069  0.748
1978 Churchill MR, Hollander FJ, Schrock RR. Crystal structure of bis(.eta.5-cyclopentadienyl)chloro(neopentylidene)tantalum, Ta(.eta.5-C5H5)2(CHCMe3)Cl, a molecule containing a twisted neopentylidene ligand with a highly obtuse Ta-C(.alpha.)-C(.beta.) angle Journal of the American Chemical Society. 100: 647-648. DOI: 10.1021/Ja00470A058  0.674
1978 Churchill MR, Hollander FJ. Structural studies on polynuclear osmium carbonyl hydrides. 7. Crystal structure and molecular geometry of di-.mu.-hydrido-eicosacarbonyltriosmiumdirhenium(3Os-Os,2Os-Re) Inorganic Chemistry. 10: 3546-3552. DOI: 10.1021/Ic50190A043  0.657
1978 Churchill MR, Hutchinson JP. Crystal structure of tetrairidium dodecacarbonyl, Ir4(CO)12. An unpleasant case of disorder Inorganic Chemistry. 10: 3528-3535. DOI: 10.1021/Ic50190A040  0.38
1978 Churchill MR, Julis SA. Dimeric (pentamethylcyclopentadienyl)rhodium and iridium complex. 4. Crystal and molecular structure of di-.mu.-bromo-dibromobis(pentamethylcyclopentadienyl)dirhodium and partially halide-exchanged species [(.eta.5-C5Me5)RhX]2(.mu.-X')2 obtained by recrystallization of bromo complex from 1,2-dichloroethane Inorganic Chemistry. 17: 3011-3019. DOI: 10.1021/Ic50189A009  0.836
1978 Churchill MR, Julis SA. Crystal structure and molecular geometry of (3,5-dimethylaceheptylene)hexacarbonyldimanganese, (C14H8Me2)Mn2(CO)6 Inorganic Chemistry. 17: 2951-2955. DOI: 10.1021/Ic50188A052  0.833
1978 Churchill MR, Rotella FJ. Crystal structure and molecular configuration of Fe2(CO)6[C(CHO)P(Ph2C6H4)], a species with an ortho-dimetalated phenyl ring Inorganic Chemistry. 17: 2614-2621. DOI: 10.1021/Ic50187A051  0.395
1978 Churchill MR, Hollander FJ. Crystal and molecular structure of a tantalum-alkylidene complex, bis(.eta.5-cyclopentadienyl)chloro(neopentylidene)tantalum Inorganic Chemistry. 17: 1957-1962. DOI: 10.1021/Ic50185A052  0.714
1978 Churchill MR, Lashewycz RA. Crystallographic studies on ruthenium carbonyl hydrides. 3. Molecular geometry of tetra-.mu.-hydrido-[bis-1,2-(diphenylphosphino)ethane]decacarbonyltetraruthenium, including the direct location and refined positions of all four bridging hydride ligands Inorganic Chemistry. 17: 1950-1957. DOI: 10.1021/Ic50185A051  0.783
1978 Churchill MR, Julis SA. Crystal structure and molecular configuration of (3,5-dimethylaceheptylene)octacarbonyltriiron(Fe-Fe), (C14H8Me2)Fe3(CO)8 Inorganic Chemistry. 17: 1453-1458. DOI: 10.1021/Ic50184A012  0.79
1978 Churchill MR, Lashewycz RA. Structural studies on polynuclear osmium carbonyl hydrides. 6. (.mu.-H)Os3(CO)8[C(O-)C(CHMe-)CHCHCEt], a species with a trisubstituted .eta.5-cyclopentadienyl ring derived via extrusion of osmium from an osmiacyclohexadienone system Inorganic Chemistry. 17: 1291-1295. DOI: 10.1021/Ic50183A038  0.759
1978 Churchill MR, Rotella FJ. Crystal structure of [Mo(diphos)2(O)(OH)][BF4] Inorganic Chemistry. 17: 668-673. DOI: 10.1021/Ic50181A032  0.408
1978 Shapley JR, Tachikawa M, Churchill MR, Lashewycz RA. Triosmium-induced dehydrogenation of triethylamine. The crystal structure of HOs3 (CO)10 (-CHCH+NEt2) Journal of Organometallic Chemistry. 162: C39-C42. DOI: 10.1016/S0022-328X(00)81410-2  0.792
1978 Churchill MR, Julis SA. Crystal structure and molecular geometry of (3,5-dimethylaceheptylene)hexacarbonyldimanganese, (C14H8Me2)Mn2(CO)6 Cheminform. 10. DOI: 10.1002/Chin.197903071  0.833
1978 Mclain SJ, Wood CD, Messerle LW, Schrock RR, Hollander FJ, Youngs WJ, Churchill MR. MULTIPLE METAL-CARBON BONDS. 10. THERMALLY STABLE TANTALUM ALKYLIDYNE COMPLEXES AND THE CRYSTAL STRUCTURE OF TA(η5-C5ME5)(CPH)(PME3)2CL Cheminform. 9. DOI: 10.1002/Chin.197850273  0.628
1978 Churchill MR, Julis SA. Crystal Structure And Molecular Configuration Of (3,5-Dimethylaceheptylene)Octacarbonyltriiron(Fe-Fe), (C14H8Me2)Fe3(Co)8 Cheminform. 9. DOI: 10.1002/Chin.197837087  0.79
1978 Churchill MR, Rotella FJ. Crystal Structure Of (Mo(Diphos)2(O)(Oh))(Bf4) Cheminform. 9. DOI: 10.1002/Chin.197825074  0.408
1978 CHURCHILL MR, ROTELLA FJ. ChemInform Abstract: MOLECULES WITH AN M4X4 CORE. 9. CRYSTAL STRUCTURE AND MOLECULAR GEOMETRY OF TETRAMERIC (METHYLDIPHENYLPHOSPHINE)COPPER(I) IODIDE, ((PMEPH2)CUI)4 Chemischer Informationsdienst. 9. DOI: 10.1002/chin.197810080  0.303
1978 Churchill MR, Hollander FJ, Hutchinson JP. Structural studies on polynuclear osmium carbonyl hydrides. 5. Crystal structure and molecular geometry of di-.mu.-hydrido-decacarbonyltriosmium, (.mu.-H)2Os3(CO)10 Cheminform. 9. DOI: 10.1002/Chin.197805073  0.705
1977 Churchill MR, Lashewycz RA, Tachikawa M, Shapley JR. Synthesis and crystal structure of [(µ2-H)Os3(CO)8{C(O–)C(CHMe–)CHCHCEt}]: a cluster compound containing a µ3-trisubstituted-η5-cyclopentadienyl system Journal of the Chemical Society, Chemical Communications. 699-700. DOI: 10.1039/C39770000699  0.794
1977 Shapley JR, Pearson GA, Tachikawa M, Schmidt GE, Churchill MR, Hollander FJ. Mixed-metal clusters via metal hydride coupling. New rhenium-osmium clusters and the crystal structure of eicosacarbonyl(dihydrotriosmium)dirhenium Journal of the American Chemical Society. 99: 8064-8065. DOI: 10.1021/Ja00466A056  0.63
1977 Shapley JR, Richter SI, Churchill MR, Lashewycz RA. Synthesis and crystal structure of tetrahydro(decacarbonyl)-1,2-ethanediylbis(diphenylphosphine)tetraruthenium. Evidence for an edge-terminal-edge hydride scrambling pathway Journal of the American Chemical Society. 99: 7384-7387. DOI: 10.1021/Ja00464A063  0.782
1977 Churchill MR, Rotella FJ, Abel EW, Mucklejohn SA. Synthesis, characterization, and crystal structure of Fe2(CO)6[C(CHO)P(Ph2C6H4)], a species containing an o-dimetalated phenyl ring resembling a Meisenheimer complex Journal of the American Chemical Society. 99: 5820-5821. DOI: 10.1021/Ja00459A059  0.415
1977 Churchill MR, Rotella FJ. Molecules with an M4X4 core. 9. Crystal structure and molecular geometry of tetrameric (methyldiphenylphosphine)copper(I) iodide, [(PMePh2)CuI]4 Inorganic Chemistry. 16: 3267-3273. DOI: 10.1021/Ic50178A056  0.418
1977 Churchill MR, Hollander FJ, Hutchinson JP. Structural studies on polynuclear osmium carbonyl hydrides. 5. Crystal structure and molecular geometry of di-.mu.-hydrido-decacarbonyltriosmium, (.mu.-H)2Os3(CO)10 Inorganic Chemistry. 16: 2697-2700. DOI: 10.1021/Ic50177A006  0.705
1977 Churchill MR, Hollander FJ, Hutchinson JP. An accurate redetermination of the structure of triruthenium dodecacarbonyl, Ru3(CO)12 Inorganic Chemistry. 16: 2655-2659. DOI: 10.1021/Ic50176A051  0.656
1977 Churchill MR, Hollander FJ. Structural studies on polynuclear osmium carbonyl hydrides. 4. Crystal structure and molecular geometry of HOs3Re(CO)15, a rhomboidal metal cluster species Inorganic Chemistry. 16: 2493-2497. DOI: 10.1021/Ic50176A013  0.68
1977 Churchill MR, DeBoer BG. Structural studies on polynuclear osmium carbonyl hydrides. 3. Crystal structure and molecular geometry of decacarbonyldihydro(triphenylphosphine)triosmium including direct location of both terminal and .mu.2-bridging hydride ligands Inorganic Chemistry. 16: 2397-2403. DOI: 10.1021/Ic50175A047  0.773
1977 Churchill MR, Julis SA. Crystal structure and molecular geometry of homogeneous hydrogenation catalyst .mu.-chloro-.mu.-hydrido-dichlorobis(pentamethylcyclopentadienyl)diiridium(III) and of its di-.mu.-chloro-dichlorobis- precursor. Direct comparison of .mu.-hydrido-.mu.-chloro-diiridium and di-.mu.-chloro-diiridium bridging systems Inorganic Chemistry. 16: 1488-1494. DOI: 10.1021/Ic50172A050  0.812
1977 Churchill MR, DeBoer BG. Structural studies on polynuclear osmium carbonyl hydrides. 2. Direct location of the .mu.2-hydride ligand and characterization of the 1,3-dipolar :C-HCH2P+Me2Ph ligand in the .mu.-hydrido-decacarbonyl(dimethylphenylphosphine)-.mu.-vinyl-triosmium molecule Inorganic Chemistry. 16: 1141-1146. DOI: 10.1021/Ic50171A033  0.729
1977 Churchill MR, Julis SA, Rotella FJ. Comparative geometry of di-.mu.-chloro-dirhodium and .mu.-hydrido-.mu.-chloro-dirhodium bridges. Crystal structure of di-.mu.-chloro-dichlorobis(.eta.5-pentamethylcyclopentadienyl)dirhodium and its relation to .mu.-hydrido-.mu.-chloro-dichlorobis(.eta.5-pentamethylcyclopentadienyl)dirhodium Inorganic Chemistry. 16: 1137-1141. DOI: 10.1021/Ic50171A032  0.817
1977 Churchill MR, DeBoer BG. Structural studies on polynuclear osmium carbonyl hydrides. 1. Crystal structures of the isomorphous species undecacarbonyldihydrotriosmium and dodecacarbonyltriosmium. Role of an equatorial .mu.2-bridging hydride ligand in perturbing the arrangement of carbonyl ligands in a triangular cluster Inorganic Chemistry. 16: 878-884. DOI: 10.1021/Ic50170A032  0.758
1977 Churchill MR, Lashewycz RA, Rotella FJ. Crystal structure and molecular geometry of dimeric azulenemanganese tricarbonyl, [(C10H8)Mn(CO)3]2 Inorganic Chemistry. 16: 265-271. DOI: 10.1021/Ic50168A009  0.81
1977 Churchill MR, Julis SA, King RB, Harmon CA. Metal carbonyl complexes of 3,5-dimethylaceheptylene. Synthesis and molecular structures of (C14H8Me2)Mn2(CO)6 and (C14H8Me2)Fe3(CO)8 Journal of Organometallic Chemistry. 142: C52-C54. DOI: 10.1016/S0022-328X(00)88359-X  0.797
1977 CHURCHILL MR, HOLLANDER FJ. ChemInform Abstract: STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES. 4. CRYSTAL STRUCTURE AND MOLECULAR GEOMETRY OF HOS3RE(CO)15, A RHOMBOIDAL METAL CLUSTER SPECIES Chemischer Informationsdienst. 8. DOI: 10.1002/chin.197752087  0.648
1977 Churchill MR, Julis SA, Rotella FJ. COMPARATIVE GEOMETRY OF DI-μ-CHLO Cheminform. 8. DOI: 10.1002/Chin.197730065  0.803
1977 CHURCHILL MR, LASHEWYCZ RA, ROTELLA FJ. ChemInform Abstract: CRYSTAL STRUCTURE AND MOLECULAR GEOMETRY OF DIMERIC AZULENEMANGANESE TRICARBONYL, ((C10H8)MN(CO)3)2 Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/Chin.197716069  0.811
1977 Churchill MR, Donahue J, Rotella FJ. Molecules With An M4X4 Core. 8. Crystal Structures Of Tetrameric Triethylphosphinesilver(I) Chloride And Triethylphosphinesilver(I) Bromide Cheminform. 8. DOI: 10.1002/Chin.197704061  0.428
1976 Churchill MR, Donahue J, Rotella FJ. Molecules with an M4X4 core. 8. Crystal structures of tetrameric triethylphosphinesilver(I) chloride and triethylphosphinesilver(I) bromide Inorganic Chemistry. 15: 2752-2758. DOI: 10.1021/Ic50165A037  0.428
1976 Churchill MR, DeBoer BG, Rotella FJ. Crystal structure and molecular geometry of HRu3(CO)10(C = NMe2), including the direct location of the .mu.2-bridging hydride ligand Inorganic Chemistry. 15: 1843-1853. DOI: 10.1021/Ic50162A022  0.768
1976 Churchill MR, Chen K. Transition metal .sigma.-acyls and related species. IV. Crystal structure and molecular geometry of MeCH.VIN...VIN...VIN..CH.VIN...VIN...VIN..CHCHMeOC(:O)Fe(CO)3, a molecule containing an iron-carbon(carboxylate) linkage in a ferrelactone ring Inorganic Chemistry. 15: 788-792. DOI: 10.1021/Ic50158A009  0.408
1976 CHURCHILL MR, DEBOER BG, ROTELLA FJ. ChemInform Abstract: CRYSTAL STRUCTURE AND MOLECULAR GEOMETRY OF HRU3(CO)10(C = NME2), INCLUDING THE DIRECT LOCATION OF THE μ2-BRIDGING HYDRIDE LIGAND Chemischer Informationsdienst. 7: no-no. DOI: 10.1002/chin.197644055  0.384
1976 Churchill MR, DeBoer BG, Shapley JR, Keister JB. Attack by phosphorus nucleophiles on a cluster-bound vinyl group. The crystal structure of HOs3(CO)10(CHCH2PMe2Ph) Journal of the American Chemical Society. 98: 2357-2358. DOI: 10.1002/Chin.197627312  0.734
1976 CHURCHILL MR, ROTELLA FJ, KING RB, ACKERMANN MN. ChemInform Abstract: CYCLOOCTATETRAENEHEXACARBONYLDIMANGANESE. CORRECTED STRUCTURAL FORMULATION, BASED ON AN X-RAY, CRYSTALLOGRAPHIC STUDY Chemischer Informationsdienst. 7: no-no. DOI: 10.1002/Chin.197604060  0.793
1976 Churchill MR, Deboer BG. Crystal And Molecular Structure Of Tris(Triphenylphosphine)Pentakis(Pentafluorophenylethynyl)Rhodiumdisilver Cheminform. 7. DOI: 10.1002/Chin.197602318  0.755
1975 Churchill MR, DeBoer BG, Rotella FJ, Abel EW, Rowley RJ. Fission of organotin bases at transition metal centers. Synthesis , characterization, and crystal structure of hydrido(decacarbonyl)dimethylaminomethylene triruthenium Journal of the American Chemical Society. 97: 7158-7159. DOI: 10.1021/Ja00857A031  0.73
1975 Chen K, Moriarty RM, DeBoer BG, Churchill MR, Yeh HJC. Stereochemical course of the reaction of iron carbonyl with diastereomeric vinyloxiranes Journal of the American Chemical Society. 97: 5602-5603. DOI: 10.1021/Ja00852A058  0.653
1975 Shapley JR, Keister JB, Churchill MR, DeBoer BG. Synthesis and characterization of the fluxional species H2Os3(CO)10L. Crystal structure of dihydroundecacarbonyltriosmium Journal of the American Chemical Society. 97: 4145-4146. DOI: 10.1021/Ja00847A055  0.726
1975 Churchill MR, DeBoer BG. Crystal and molecular structure of tris(triphenylphosphine)pentakis(pentafluorophenylethynyl)rhodiumdisilver Inorganic Chemistry. 14: 2630-2639. DOI: 10.1021/Ic50153A008  0.755
1975 Churchill MR, DeBoer BG. Molecules with an M4X4 core. VII. Crystal and molecular structure of tetrameric triethylphosphinesilver(I) iodide Inorganic Chemistry. 14: 2502-2507. DOI: 10.1021/Ic50152A042  0.739
1975 Churchill MR, DeBoer BG, Mendak SJ. Molecules with an M4X4 core. VI. Crystallographic characterization of .mu.4-oxo-hexa-.mu.2-chloro-tetrakis(triethylphosphine oxide)tetracopper(II), a product from the aerobic oxidation of tetrameric triethylphosphine copper(I) chloride Inorganic Chemistry. 14: 2496-2501. DOI: 10.1021/Ic50152A041  0.673
1975 Churchill MR, Hackbarth JJ. Crystal structure and molecular geometry of dibromobis(trimethylphosphine)(2-pentaboranyl)carbonyliridium(III), a product from the oxidative addition of bromopentaborane to chlorobis(trimethylphosphine)carbonyliridium, and comments on the structural trans influence of .sigma.-bonded boron Inorganic Chemistry. 14: 2047-2051. DOI: 10.1021/Ic50151A006  0.431
1975 Churchill MR, DeBoer BG, Mendak SJ. Molecules with an M4X4 core. V. Crystallographic characterization of the tetrameric cubane-like species triethylphosphinecopper(I) chloride and triethylphosphinecopper(I) bromide. Systematics in the [PEt3CuX]4 series Inorganic Chemistry. 14: 2041-2047. DOI: 10.1021/Ic50151A005  0.671
1975 Churchill MR, Chang SWY. Transition metal .sigma.-acyls. III. Crystal structure and molecular geometry of (carbonyl-3,5-cyclohexadiene-1,2-diyl-cyclopentadienediyl)pentacarbonyldiiron, including the location and refinement of all hydrogen atoms Inorganic Chemistry. 14: 1680-1685. DOI: 10.1021/Ic50149A050  0.403
1975 Churchill MR, Lin KG. Crystal structure and molecular geometry of .mu.-carbonyl-bis(.mu.-hexafluoroisopropylidenimino)hexacarbonyldimanganese(Mn-Mn), [CF3)2C=N]2Mn2(CO)7, a complex with bridging alkylidenimino ligands Inorganic Chemistry. 14: 1675-1680. DOI: 10.1021/Ic50149A049  0.465
1975 Churchill MR, Lin KG. Phenyldiazo group as a bridging ligand. Crystal structure and molecular configuration of bis(tetracarbonylphenyldiazomanganese), [PhN:NMn(CO)4]2, including the location and refinement of the hydrogen atoms Inorganic Chemistry. 14: 1133-1138. DOI: 10.1021/Ic50147A035  0.44
1975 Churchill MR, DeBoer BG, Donovan DJ. Molecules with an M4X4 core. IV. Crystallographic detection of a step configuration for the tetracopper tetraiodide core in tetrameric triphenylphosphinecopper(I) iodine, [PPh3CuI]4 Inorganic Chemistry. 14: 617-623. DOI: 10.1021/Ic50145A036  0.667
1975 Churchill MR, Chang SW-. Crystal and molecular structure of dicarbonyl(.eta.5-cyclopentadienyl)triphenylphosphine(1-.eta.-1,1,2,2-tetracyanopropyl)molybdenum, the product of insertion of tetracyanoethylene into a molybdenum-methyl linkage Inorganic Chemistry. 14: 98-105. DOI: 10.1021/Ic50143A020  0.418
1975 Churchill MR, Rotella FJ, King RB, Ackermann MN. Cyclooctatetraenehexacarbonyldimanganese, (C8H8)Mn2(CO)6. A corrected structural formulation, based on an x-ray crystallographic study Journal of Organometallic Chemistry. 99. DOI: 10.1016/S0022-328X(00)86377-9  0.836
1975 Churchill MR, Deboer BG. Molecules With An M4X4 Core Part 7, Crystal And Molecular Structure Of Tetrameric Triethylphosphinesilver(I) Iodide Cheminform. 6. DOI: 10.1002/Chin.197550399  0.738
1975 Churchill MR, Deboer BG, Mendak SJ. Molecules With An M4X4 Core Part 6, Crystallographic Characterization Of Cu4Ocl6(Opet3)4 - A Product From The Aerobic Oxidation Of (Pet3Cucl)4 Cheminform. 6. DOI: 10.1002/Chin.197550395  0.658
1975 CHURCHILL MR, HACKBARTH JJ. ChemInform Abstract: CRYSTAL STRUCTURE AND MOLECULAR GEOMETRY OF IR(B5H8)BR2(CO)(PME3)2, A PRODUCT FROM THE OXIDATIVE ADDITION OF BROMOPENTABORANE TO IRCL(CO)(PME3)2, AND SOME COMMENTS ON THE STRUCTURAL TRANS INFLUENCE OF SIGMA-BONDED BORON Chemischer Informationsdienst. 6. DOI: 10.1002/Chin.197546424  0.444
1975 Churchill MR, DeBoer BG, Rotella FJ, Abu Salah OM, Bruce MI. Determination of the crystal structure and molecular geometry of [hydrotris(1-pyrazolyl)borato]copper(I) carbonyl. Unique structural investigation of a copper-carbonyl linkage Inorganic Chemistry. 14: 2051-2056. DOI: 10.1002/Chin.197546411  0.745
1975 CHURCHILL MR, DEBOER BG, ROTELLA FJ, ABU SALAH OM, BRUCE MI. ChemInform Abstract: DETERMINATION OF THE CRYSTAL STRUCTURE AND MOLECULAR GEOMETRY OF (HYDROTRIS(1-PYRAZOLYL)BORATO)COPPER(I) CARBONYL, A UNIQUE STRUCTURAL INVESTIGATION OF A COPPER-CARBONYL LINKAGE Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/chin.197546411  0.315
1975 Churchill MR, Deboer BG, Mendak SJ. Molecules With An M4X4 Core Part 5, Crystallographic Characterization Of The Tetrameric ′Cubane-Like′ Species Triethylphosphinecopper(I), Chloride And Triethylphosphinecopper(I) Bromide, Systematics In The (Pet3Cux)4 Series Cheminform. 6. DOI: 10.1002/Chin.197546410  0.673
1975 SHAPLEY JR, KEISTER JB, CHURCHILL MR, DEBOER BG. ChemInform Abstract: SYNTHESIS AND CHARACTERIZATION OF THE FLUXIONAL SPECIES H2OS3(CO)10L. THE CRYSTAL STRUCTURE OF H2OS3(CO)11 Chemischer Informationsdienst. 6. DOI: 10.1002/Chin.197539368  0.727
1975 Churchill MR, Chang SW-. Transition Metal Sigma-Acyls Part 3, Crystal Structure And Molecular Geometry Of (C5H4C6H6Co)Fe2(Co)5, Including The Location And Refinement Of All Hydrogen Atoms Cheminform. 6. DOI: 10.1002/Chin.197537359  0.392
1975 Churchill MR, Lin KG. Crystal Structure And Molecular Geometry Of Mu-Carbonyl-Bis(Mu-Hexafluoroisopropylidenimino)-Hexacarbonyldimanganese (Mn-Mn), ((Cf3)2 C = N)2 Mn2(Co)7, A Complex With Bridging Alkylidenimino Ligands Cheminform. 6. DOI: 10.1002/Chin.197537355  0.465
1975 Churchill MR, Deboer BG, Donovan DJ. Molecules With An M4X4 Core Part 4, Crystallographic Detection Of A ′Step′ Configuration For The Cu4I4 Core In Tetrameric Triphenylphosphinecopper(I) Iodide, (Pph3Cuj)4 Cheminform. 6. DOI: 10.1002/Chin.197520419  0.663
1975 CHURCHILL MR, WORMALD J. ChemInform Abstract: CRYSTAL AND MOLECULAR STRUCTURE OF TETRAMETHYLAMMONIUM CARBIDOHEXADECACARBONYLHEXAFERRATE(2-), A HEXANUCLEAR IRON CLUSTER COMPLEX WITH AN ENCAPSULATED SIX-CO-ORDINATE CARBON ATOM Chemischer Informationsdienst. 6. DOI: 10.1002/Chin.197509377  0.732
1975 Abel EW, Burton CA, Churchill MR, Lin K-G. Synthesis And X-Ray Structure Of Mu-Carbonyl-Bis-Mu-Hexafluoroisopropylidenamidohexacarbonyldimanganese, An Analogue Of Enneacarbonyldi-Iron Having Unsymmetrically Bridging Ligands Cheminform. 6. DOI: 10.1002/Chin.197507390  0.385
1974 Churchill MR, Wormald J. Crystal and molecular structure of tetramethylammonium carbidohexadecacarbonylhexaferrate(2–), [Me4N]2[Fe6(CO)16C], a hexanuclear iron cluster complex with an encapsulated six-co-ordinate carbon atom Journal of the Chemical Society-Dalton Transactions. 2410-2415. DOI: 10.1039/Dt9740002410  0.723
1974 Abel EW, Burton CA, Churchill MR, Lin KG. Synthesis and X-ray structure of µ-carbonyl-bis-µ-hexafluoroisopropylidenamido-hexacarbonyldimanganese. An analogue of enneacarbonyldi-iron having unsymmetrically bridging ligands Journal of the Chemical Society, Chemical Communications. 917-918. DOI: 10.1039/C39740000917  0.384
1974 Salah OMA, Bruce MI, Churchill MR, DeBoer BG. Preparation and X-ray crystallographic characterisation of an unusual heteronuclear complex, RhAg2(CCC6F5)5(PPh3)3 Journal of the Chemical Society, Chemical Communications. 688-689. DOI: 10.1039/C39740000688  0.723
1974 Churchill MR, Chang SW-. X-Ray crystallographic evidence for a trinuclear formulation for the ‘non-oxidized’ hexamethylbenzene–niobium chloride cluster complex, [(Me6C6)3Nb3Cl6]Cl Journal of the Chemical Society, Chemical Communications. 248-249. DOI: 10.1039/C39740000248  0.451
1974 Churchill MR, DeBoer BG. Example of a facial hydrogen atom attempting to bridge all five atoms of an open pentagonal B3C2 face. Crystal and molecular structure of (.pi.-cyclopentadienyl)[.pi.-1-(undecahydro-1,2-dicarboundecaboranyl)cyclopentadienyl]cobalt, including the location and refinement of all hydrogen atoms Journal of the American Chemical Society. 96: 6310-6318. DOI: 10.1021/Ja00827A011  0.701
1974 Churchill MR, Hackbarth JJ, Davison A, Traficante DD, Wreford SS. Oxidative addition of pentaborane(9) and bromopentaborane(9). Crystal structure of 2-[dibromobis(trimethylphosphine)carbonyliridium]pentaborane(9) Journal of the American Chemical Society. 96: 4041-4042. DOI: 10.1021/Ja00819A067  0.58
1974 Churchill MR, Lin KG. X-ray crystallographic studies on fluxional pentacoordinate transition metal complexes. IV. Structure of (norbornadiene)bis(dimethylphenylphosphine)(trichlorostannato)iridium(I), including the location and refinement of all hydrogen atoms Journal of the American Chemical Society. 96: 76-84. DOI: 10.1021/Ja00808A012  0.381
1974 Churchill MR, Chang SWY. X-ray crystallographic determination of the molecular structure of bis(tetraethylammonium)di-.mu.-hydrido-octacarbonylditungstate(2-), [Et4N+]2[H2W2(CO)82-]. Unique example of the successful location and refinement of hydride ligands in positions bridging third-row transition metal atoms Inorganic Chemistry. 13: 2413-2419. DOI: 10.1021/Ic50140A023  0.4
1974 Churchill MR, DeBoer BG, Hackbarth JJ. Transition metal .sigma.- acyls. II. Crystallographic determination of the molecular structure of (pentahaptocyclopentadienyl)-1,3',4'-trihapto{2-methyl-2-(6'6'-dimethylbicyclo[3.2.0]hept-3'-en-7'-on-2'-yl)propionyl}nickel(II), including the location and refinement of all hydrogen atoms Inorganic Chemistry. 13: 2098-2105. DOI: 10.1021/Ic50139A011  0.699
1974 Churchill MR, Kalra KL. Molecules with an M4X4 core. III. Comparison of the x-ray crystallographically determined molecular structures of tetrameric triethylphosphinecopper(I) iodide and triethylarsinecopper(I) iodide Inorganic Chemistry. 13: 1899-1904. DOI: 10.1021/Ic50138A022  0.361
1974 Churchill MR, Kalra KL. Molecules with an M4X4 core. II. X-ray crystallographic determination of the molecular structure of tetrameric triphenylphosphinecopper(I) bromide in crystalline [PPH3CuBr]4.2CHCl3 Inorganic Chemistry. 13: 1427-1434. DOI: 10.1021/Ic50136A034  0.364
1974 Churchill MR, Bezman SA. Crystal and molecular structure of bis(triphenylphosphine)octakis(phenylethynyl)tetracopperdiiridium(4 Cu-Cu) (8 Cu-Ir), novel heteronuclear octahedral metal cluster complex Inorganic Chemistry. 13: 1418-1427. DOI: 10.1021/Ic50136A033  0.776
1974 Churchill MR, Deboer BG. X-ray crystallographic elucidation of the structure of (pentahaptocyclopentadienyl) (7,8,9,10,11,12-hexahaptododecahydro-7,9-dicarba-nido-dodecaborato)cobalt(III), a fluxional molecule containing a triangulated 13-vertex (1,5,6,1) docosahedral cage Inorganic Chemistry. 13: 1411-1418. DOI: 10.1021/Ic50136A032  0.716
1974 Churchill MR, Kalra KL. Molecules with an M4X4 core. I. Crystal and molecular structure of tetrameric triphenylphosphinecopper(I) chloride, a cubane-like molecule, including the location and refinement of all hydrogen atoms Inorganic Chemistry. 13: 1065-1071. DOI: 10.1021/Ic50135A011  0.371
1974 Churchill MR, Deboer BG. An Example Of A Facial Hydrogen Atom Attempting To Bridge All Five Atoms Of An Open Pentagonal B3C2 Face, The Crystal And Molecular Structure Of (Pi-C5H5)Co(Pi-C5H4B9C2H11), Including The Location And Refinement Of All Hydrogen Atoms Cheminform. 5. DOI: 10.1002/Chin.197450429  0.715
1974 Churchill MR, Chang SW-. X-Ray Crystallographic Determination Of The Molecular Structure Of Bis(Tetraethylammonium) Di-Mu-Hydrido-Octacarbonylditungstate(2-1), (Et(4)N)2(H2W2(Co)8), A Unique Example Of The Successful Location And Refinement Of Hydride Ligands Cheminform. 5. DOI: 10.1002/Chin.197450396  0.401
1974 SALAH OMA, BRUCE MI, CHURCHILL MR, DEBOER BG. ChemInform Abstract: PREPARATION AND X-RAY CRYSTALLOGRAPHIC CHARACTERISATION OF AN UNUSUAL HETERONUCLEAR COMPLEX, RHAG2(C-CC6F5)5(PPH3)3 Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/Chin.197449438  0.708
1974 Churchill MR, Deboer BG, Hackbarth JJ. Transition Metal Sigma‐Acyls Part 2, Crystallographic Determination Of The Molecular Structure Of (Pi‐C5H5)Ni(C5H5(Me2C2O)2), Including The Location And Refinement Of All Hydrogen Atoms Cheminform. 5. DOI: 10.1002/Chin.197445402  0.72
1974 CHURCHILL MR, HACKBARTH JJ, DAVISON A, TRAFICANTE DD, WREFORD SS. ChemInform Abstract: OXIDATIVE ADDITION OF PENTABORANE(9) AND BROMOPENTABORANE(9), THE CRYSTAL STRUCTURE OF 2-(IRBR2(CO)(P(CH3)3)2).B5H8 Chemischer Informationsdienst. 5. DOI: 10.1002/Chin.197434414  0.603
1974 Churchill MR, Kalra KL. Molecules With An M4X4 Core Part 2, X-Ray Crystallographic Determination Of The Molecular Structure Of Tetrameric Triphenylphosphinecopper(I) Bromide In Crystalline (Pph3Cubr)4.2Chcl3 Cheminform. 5. DOI: 10.1002/Chin.197433420  0.359
1974 Churchill MR, Bezman SA. Crystal And Molecular Structure Of Cu4Ir2(Pph3)2(C=Cph)8, A Novel Heteronuclear Octahedral Metal Cluster Complex Cheminform. 5. DOI: 10.1002/Chin.197433419  0.816
1974 Abel EW, Burton CA, Churchill MR, Lin KKG. Synthesis And Crystallographic Characterization Of Bis(Tetracarbonylphenyldiazomanganes), An Unique Complex With Bridging Aryldiazo-Ligands Cheminform. 5. DOI: 10.1002/Chin.197427358  0.384
1974 CHURCHILL MR, CHANG SW. ChemInform Abstract: X-RAY CRYSTALLOGRAPHIC EVIDENCE FOR A TRINUCLEAR FORMULATION FOR THE ′NON-OXIDIZED′ HEXAMETHYLBENZENE-NIOBIUM CHLORIDE CLUSTER COMPLEX ((ME6C6)3NB3CL6)CL Chemischer Informationsdienst. 5. DOI: 10.1002/Chin.197427070  0.355
1974 Churchill MR, Lin KG. X-Ray Crystallographic Studies On Fluxional Pentacoordinate Transition Metal Complexes Part 4, The Structure Of (Norbornadiene)Bis(Dimethylphenylphosphine)-(Trichlorostannato)Iridium(I), (C7H8)(Pme2Ph)2Ir(Sncl3), Including The Locatio Cheminform. 5. DOI: 10.1002/Chin.197412451  0.42
1974 Churchill MR, Deboer BG. Crystal Structure And Molecular Geometry Of (Me4N(+))(Me2B10C2H11(-)), Including The Refinement Of Positional And Anisotropic Thermal Parameters For All Hydrogen Atoms Cheminform. 5. DOI: 10.1002/Chin.197401267  0.718
1973 Churchill MR, Reis AH. Structural studies on clathro-chelate complexes. Part III. Trigonal prismatic co-ordination of d7 cobalt(II) in orthorhombic crystalline [{FB(ONCHC5H3N)3P}CoII+][BF4–],MeCN and a single-crystal transformation of unsolvated monoclinic [{FB(ONCHC5H3N)3P}CoII+][BF4–] Journal of the Chemical Society-Dalton Transactions. 1570-1576. DOI: 10.1039/Dt9730001570  0.413
1973 Churchill MR, Chang SW-N, Berch ML, Davison A. Synthesis and X-ray crystallographic characterization of [Et4N]2[W2(CO)8H2] including the direct location and the refinement of the two bridging hydride ligands Journal of the Chemical Society, Chemical Communications. 691-692. DOI: 10.1039/C39730000691  0.594
1973 Churchill MR, Chang SWYN. Crystal and molecular structure of dicarbonyl-pentahapto-cyclopentadienyl(1-monohapto-3,3,4,4-tetracyano-1-methylcyclopentyl)iron(II), the product of a [3+2] cycloaddition of tetracyanoethylene and a transition metal .sigma.-allyl Journal of the American Chemical Society. 95: 5931-5938. DOI: 10.1021/Ja00799A017  0.382
1973 Churchill MR, Kalra KL. Tetrameric phosphinecopper(I) halides. X-ray crystallographic evidence for a cubane structure for the CU4Cl4 core of tetra-.mu.-chlorotetrakis(triphenylphosphine copper(I) and a step structure for the CU4Br4 core in crystalline tetra-.mu.-bromotetrakis(triphenylphosphine copper(I)-2-chloroform Journal of the American Chemical Society. 95: 5772-5773. DOI: 10.1021/Ja00798A061  0.369
1973 Churchill MR, Ni SWY. Crystal structure and location of the bridging hydride ligand in .mu.-chloro-.mu.-hydrido-bis[chloro(pentamethylcyclopentadienyl)rhodium(III)], a monogeneous hydrogenation catalyst Journal of the American Chemical Society. 95: 2150-2155. DOI: 10.1021/Ja00788A012  0.428
1973 Churchill MR, DeBoer BG. Crystal structure and molecular geometry of tetramethylammonium C,C'-dimethylundecahydrodicarba-nido-dodecaborate, including the refinement of positional and anisotropic thermal parameters for all hydrogen atoms Inorganic Chemistry. 12: 2674-2682. DOI: 10.1021/Ic50129A036  0.72
1973 Churchill MR, Kalra KL, Veidis MV. Crystal structures of transition metal aryls. VI. Molecular geometry of trans-bromodis(methyldiphenylphosphine) (.sigma.-pentafluorophenyl)nickel(II), including the location and refinement of hydrogen atoms Inorganic Chemistry. 12: 1656-1662. DOI: 10.1021/Ic50125A036  0.406
1973 Churchill MR, Kalra KL. Crystallographic studies on sulfur dioxide insertion compounds. V. 1Elucidation of the molecular geometry of cis-.mu.-carbonyl-.mu.-(sulfur dioxide)-bis (.pi.-cyclopentadienylcarbonyliron), cis-(.pi.-C5H5)2Fe2(CO)3(SO2) Inorganic Chemistry. 12: 1650-1656. DOI: 10.1021/Ic50125A035  0.344
1973 Churchill MR, DeBoer BG, Kalra KL. Crystallographic studies on sulfur dioxide insertion compounds. IV. Structure of .mu.-(sulfur dioxide)-bis(.pi.-cyclopentadienyldicarbonyliron), including the location and refinement of hydrogen atoms Inorganic Chemistry. 12: 1646-1650. DOI: 10.1021/Ic50125A034  0.709
1973 Churchill MR. Carbon-hydrogen and nitrogen-hydrogen distances assumed in, and determined from, recent x-ray diffraction studies on inorganic complexes Inorganic Chemistry. 12: 1213-1214. DOI: 10.1021/Ic50123A054  0.302
1973 Churchill MR, Gold K. Crystal and molecular structure of the asymmetric metallocarborane complex tetraethylammonium {(3,11')-commo-[undecahydro-1,2-dicarba-3-cobalta-closo-dodecaborato][decahydro-9'-pyridyl-7',8'-dicarba-11'-cobalta-nido-undecarborate]}, [(C2H5)4N+][(B9C2H11)Co((B8C2H10)(C5H5N))-] Inorganic Chemistry. 12: 1157-1165. DOI: 10.1021/Ic50123A038  0.784
1973 Churchill MR, Bezman SA. X-ray crystallographic studies on fluxional pentacoordinate transition metal complexes. III. (Cycloocta-1,5-diene)[bis(1,3-diphenylphosphino)propane]methyliridium(I) Inorganic Chemistry. 12: 531-536. DOI: 10.1021/Ic50121A006  0.779
1973 Churchill MR, DeBoer BG. Crystal and molecular structure of 1,6,7,8-tetrahaptoheptafulveneiron tricarbonyl, a heptafulvene complex of iron(II) containing a trimethylenemethane-iron linkage Inorganic Chemistry. 12: 525-531. DOI: 10.1021/Ic50121A005  0.717
1973 Churchill MR, Bezman SA. X-ray crystallographic studies on fluxional pentacoordinate transition metal complexes. II. (Cycloocta-1,5-diene)[1,2-bis(diphenylphosphino)ethane]methyliridium(I), (C8H12)(diphos)Ir(CH3) Inorganic Chemistry. 12: 260-265. DOI: 10.1021/Ic50120A003  0.794
1973 Churchill MR, Wormald J. Crystallographic identification of azulenetriruthenium heptacarbonyl Inorganic Chemistry. 12: 191-198. DOI: 10.1021/Ic50119A043  0.669
1973 Churchill MR, Chang W-N, Berch ML, Davison A. Synthesis And X-Ray Crystallographic Characterization Of (Et4N)2(W2(Co)8H2) Including The Direct Location And The Refinement Of The Two Bridging Hydride Ligands Cheminform. 4. DOI: 10.1002/Chin.197351360  0.564
1973 Churchill MR, Reis AHJ. Structural Studies On Clathro Chelate Complexes Part 4, Trigonal-Prismatic Coordination Of D(10) Zinc(Ii) In Crystalline ((Fb(Onchc5H3N)3P)Zn(+))(Bf4(-)) Cheminform. 4. DOI: 10.1002/Chin.197348324  0.359
1973 CHURCHILL MR, CHANG SWN. ChemInform Abstract: CRYSTAL AND MOLECULAR STRUCTURE OF DICARBONYLPENTAHAPTOCYCLOPENTADIENYL(1-MONOHAPTO-3,3,4,4-TETRACYANO-1-METHYLCYCLOPENTYL)IRON(II), THE PRODUCT OF A (3+2)CYCLOADDITION OF TETRACYANOETHYLENE AND A TRANSITION METAL SIGMA-ALLYL Chemischer Informationsdienst. 4: no-no. DOI: 10.1002/Chin.197345446  0.381
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