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Christian R. Goldsmith, Ph.D. - Publications

Affiliations: 
1998-2004 Chemistry Stanford University, Palo Alto, CA 
 2004-2007 Chemistry Massachusetts Institute of Technology, Cambridge, MA, United States 
 2007- Chemistry and Biochemistry Auburn University, Auburn, AL, United States 
Area:
synthetic inorganic and organic chemistry
Website:
http://www.auburn.edu/academic/cosam/faculty/chemistry/goldsmith/research/
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45 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Karbalaei S, Franke A, Oppelt J, Aziz T, Jordan A, Pokkuluri PR, Schwartz DD, Ivanović-Burmazović I, Goldsmith CR. A macrocyclic quinol-containing ligand enables high catalase activity even with a redox-inactive metal at the expense of the ability to mimic superoxide dismutase. Chemical Science. 14: 9910-9922. PMID 37736643 DOI: 10.1039/d3sc02398b  0.526
2022 Obisesan SV, Rose C, Farnum BH, Goldsmith CR. Co(II) Complex with a Covalently Attached Pendent Quinol Selectively Reduces O to HO. Journal of the American Chemical Society. PMID 36493464 DOI: 10.1021/jacs.2c08315  0.411
2022 Moore JL, Oppelt J, Senft L, Franke A, Scheitler A, Dukes MW, Alix HB, Saunders AC, Karbalaei S, Schwartz DD, Ivanović-Burmazović I, Goldsmith CR. Diquinol Functionality Boosts the Superoxide Dismutase Mimicry of a Zn(II) Complex with a Redox-Active Ligand while Maintaining Catalyst Stability and Enhanced Activity in Phosphate Solution. Inorganic Chemistry. PMID 36445832 DOI: 10.1021/acs.inorgchem.2c03256  0.518
2022 Karbalaei S, Franke A, Jordan A, Rose C, Pokkuluri PR, Beyers RJ, Zahl A, Ivanović-Burmazović I, Goldsmith CR. A Highly Water- and Air-Stable Iron-Containing MRI Contrast Agent Sensor for H O. Chemistry (Weinheim An Der Bergstrasse, Germany). e202201179. PMID 35666136 DOI: 10.1002/chem.202201179  0.399
2021 Senft L, Moore JL, Franke A, Fisher KR, Scheitler A, Zahl A, Puchta R, Fehn D, Ison S, Sader S, Ivanović-Burmazović I, Goldsmith CR. Quinol-containing ligands enable high superoxide dismutase activity by modulating coordination number, charge, oxidation states and stability of manganese complexes throughout redox cycling. Chemical Science. 12: 10483-10500. PMID 34447541 DOI: 10.1039/d1sc02465e  0.47
2021 Karbalaei S, Knecht E, Franke A, Zahl A, Saunders AC, Pokkuluri PR, Beyers RJ, Ivanović-Burmazović I, Goldsmith CR. A Macrocyclic Ligand Framework That Improves Both the Stability and -Weighted MRI Response of Quinol-Containing HO Sensors. Inorganic Chemistry. PMID 34042423 DOI: 10.1021/acs.inorgchem.1c00896  0.441
2019 Hutchinson TE, Bashir A, Yu M, Beyers RJ, Goldsmith CR. An overly anionic metal coordination environment eliminates the T-weighted response of quinol-containing MRI contrast agent sensors to H2O2 Inorganica Chimica Acta. 496: 119045. DOI: 10.1016/J.Ica.2019.119045  0.518
2018 Ward MB, Scheitler A, Yu M, Senft L, Zillmann AS, Gorden JD, Schwartz DD, Ivanović-Burmazović I, Goldsmith CR. Superoxide dismutase activity enabled by a redox-active ligand rather than metal. Nature Chemistry. PMID 30275506 DOI: 10.1038/S41557-018-0137-1  0.511
2018 Bell-Taylor A, Gorden JD, Hardy EE, Goldsmith CR. A spin-crossover Co(II) complex catalyzes the activation of sp3 C–H bonds by two-electron oxidants Inorganica Chimica Acta. 482: 206-212. DOI: 10.1016/J.Ica.2018.06.012  0.498
2018 Goldsmith CR. Aluminum and gallium complexes as homogeneous catalysts for reduction/oxidation reactions Coordination Chemistry Reviews. 377: 209-224. DOI: 10.1016/J.Ccr.2018.08.025  0.545
2017 Yu M, Ward MB, Franke A, Ambrose SL, Whaley ZL, Bradford TM, Gorden JD, Beyers RJ, Cattley RC, Ivanović-Burmazović I, Schwartz DD, Goldsmith CR. Adding a Second Quinol to a Redox-Responsive MRI Contrast Agent Improves Its Relaxivity Response to H2O2. Inorganic Chemistry. PMID 28191846 DOI: 10.1021/Acs.Inorgchem.6B02964  0.543
2017 Kenkel I, Franke A, Dürr M, Zahl A, Dücker-Benfer C, Langer J, Filipović MR, Yu M, Puchta R, Fiedler SR, Shores MP, Goldsmith CR, Ivanović-Burmazović I. Switching between Inner- and Outer-Sphere PCET Mechanisms of Small-Molecule Activation: Superoxide Dismutation and Oxygen/Superoxide Reduction Reactivity Deriving from the Same Manganese Complex. Journal of the American Chemical Society. PMID 28111938 DOI: 10.1021/Jacs.6B08394  0.509
2016 Zhang Q, Bell-Taylor A, Bronston FM, Gorden JD, Goldsmith CR. Aldehyde Deformylation and Catalytic C-H Activation Resulting from a Shared Cobalt(II) Precursor. Inorganic Chemistry. PMID 28004924 DOI: 10.1021/Acs.Inorgchem.6B02127  0.536
2016 Bronston F, Ting S, Zhang Q, Goldsmith CR. Expanding the scope of gallium-catalyzed olefin epoxidation Polyhedron. 114: 268-272. DOI: 10.1016/J.Poly.2015.12.040  0.414
2015 Koellner CA, Piro NA, Kassel WS, Goldsmith CR, Graves CR. Synthesis and Characterization of α-Diimine Complexes of Group 13 Metals and Their Catalytic Activity toward the Epoxidation of Alkenes. Inorganic Chemistry. 54: 7139-41. PMID 26192441 DOI: 10.1021/Acs.Inorgchem.5B01136  0.491
2015 Yu M, Ambrose SL, Whaley ZL, Fan S, Gorden JD, Beyers RJ, Schwartz DD, Goldsmith CR. Correction to "A Mononuclear Manganese(II) Complex Demonstrates a Strategy To Simultaneously Image and Treat Oxidative Stress". Journal of the American Chemical Society. 137: 9195. PMID 26151197 DOI: 10.1021/Jacs.5B06259  0.396
2014 Yu M, Ambrose SL, Whaley ZL, Fan S, Gorden JD, Beyers RJ, Schwartz DD, Goldsmith CR. A mononuclear manganese(II) complex demonstrates a strategy to simultaneously image and treat oxidative stress. Journal of the American Chemical Society. 136: 12836-9. PMID 25187295 DOI: 10.1021/Ja507034D  0.467
2014 Zhang Q, Goldsmith CR. Kinetic analysis of the formation and decay of a non-heme ferric hydroperoxide species susceptible to O-O bond homolysis. Inorganic Chemistry. 53: 5206-11. PMID 24783960 DOI: 10.1021/Ic5003786  0.391
2014 Khan M, Goldsmith CR, Huang Z, Georgiou J, Luyben TT, Roder JC, Lippard SJ, Okamoto K. Two-photon imaging of Zn2+ dynamics in mossy fiber boutons of adult hippocampal slices. Proceedings of the National Academy of Sciences of the United States of America. 111: 6786-91. PMID 24757053 DOI: 10.1073/Pnas.1405154111  0.384
2014 McKee ML, Goldsmith CR. Computational examination of the mechanism of alkene epoxidation catalyzed by gallium(III) complexes with N-donor ligands. Inorganic Chemistry. 53: 318-26. PMID 24308455 DOI: 10.1021/Ic402261V  0.528
2013 Zhang Q, Gorden JD, Goldsmith CR. C-H oxidation by H2O2 and O2 catalyzed by a non-heme iron complex with a sterically encumbered tetradentate N-donor ligand. Inorganic Chemistry. 52: 13546-54. PMID 24252099 DOI: 10.1021/Ic402501K  0.512
2013 Jiang W, Gorden JD, Goldsmith CR. Catalysis of alkene epoxidation by a series of gallium(III) complexes with neutral N-donor ligands. Inorganic Chemistry. 52: 5814-23. PMID 23621448 DOI: 10.1021/Ic400570H  0.528
2013 Zhang Q, Goldsmith CR. Hydrocarbon oxidation catalyzed by manganese and iron complexes with the hexadentate ligand N,N′-di(ethylacetate)-N,N′-bis(2-pyridyl-methyl)- 1, 2-ethanediamine Inorganica Chimica Acta. 406: 301-306. DOI: 10.1016/J.Ica.2013.06.009  0.562
2012 He Y, Goldsmith CR. Observation of a ferric hydroperoxide complex during the non-heme iron catalysed oxidation of alkenes and alkanes by O2. Chemical Communications (Cambridge, England). 48: 10532-4. PMID 22992783 DOI: 10.1039/C2Cc34634F  0.455
2012 Yu M, Beyers RJ, Gorden JD, Cross JN, Goldsmith CR. A magnetic resonance imaging contrast agent capable of detecting hydrogen peroxide. Inorganic Chemistry. 51: 9153-5. PMID 22889331 DOI: 10.1021/Ic3012603  0.542
2012 Jiang W, Gorden JD, Goldsmith CR. A homogeneous gallium(III) compound selectively catalyzes the epoxidation of alkenes. Inorganic Chemistry. 51: 2725-7. PMID 22356230 DOI: 10.1021/Ic300159A  0.404
2012 Goldsmith CR, Jiang W. Alkene epoxidation catalyzed by manganese complexes with electronically modified 1,10-phenanthroline ligands Inorganica Chimica Acta. 384: 340-344. DOI: 10.1016/J.Ica.2011.12.029  0.486
2011 He Y, Gorden JD, Goldsmith CR. Steric modifications tune the regioselectivity of the alkane oxidation catalyzed by non-heme iron complexes. Inorganic Chemistry. 50: 12651-60. PMID 22070163 DOI: 10.1021/Ic201695A  0.454
2011 Zhang Q, Gorden JD, Beyers RJ, Goldsmith CR. Manganese(II)-containing MRI contrast agent employing a neutral and non-macrocyclic ligand. Inorganic Chemistry. 50: 9365-73. PMID 21888331 DOI: 10.1021/Ic2009495  0.509
2011 Coates CM, Hagan K, Mitchell CA, Gorden JD, Goldsmith CR. Structural characterization of manganese and iron complexes with methylated derivatives of bis(2-pyridylmethyl)-1,2-ethanediamine reveals unanticipated conformational flexibility. Dalton Transactions (Cambridge, England : 2003). 40: 4048-58. PMID 21373666 DOI: 10.1039/C0Dt01556C  0.503
2011 Goldsmith CR, Coates CM, Hagan K, Mitchell CA. Hydrocarbon chlorination promoted by manganese and iron complexes with methylated derivatives of bis(2-pyridylmethyl)-1,2-ethanediamine Journal of Molecular Catalysis a: Chemical. 335: 24-30. DOI: 10.1016/J.Molcata.2010.11.006  0.45
2010 Coates CM, Fiedler SR, McCullough TL, Albrecht-Schmitt TE, Shores MP, Goldsmith CR. Synthesis and characterization of an asymmetric, linear, trinuclear manganese(II) complex. Inorganic Chemistry. 49: 1481-6. PMID 20073502 DOI: 10.1021/Ic901758S  0.493
2010 He Y, Goldsmith CR. The halogenation of aliphatic C-H bonds with peracetic acid and halide salts Synlett. 1377-1380. DOI: 10.1055/S-0029-1219832  0.376
2010 Coates CM, Nelson AGD, Goldsmith CR. Assessing the impact of inductive electronic effects on the metrical parameters and reactivity of a series of ferrous complexes Inorganica Chimica Acta. 363: 199-204. DOI: 10.1016/J.Ica.2009.08.033  0.471
2009 Coates CM, Nelson AGD, Goldsmith CR. The influence of inductive ligand electronics on the metrical parameters and redox potentials of a series of manganese(II) compounds Inorganica Chimica Acta. 362: 4797-4803. DOI: 10.1016/J.Ica.2009.07.006  0.487
2006 Goldsmith CR, Lippard SJ. Analogues of Zinpyr-1 provide insight into the mechanism of zinc sensing. Inorganic Chemistry. 45: 6474-8. PMID 16878961 DOI: 10.1021/Ic060378J  0.47
2006 Goldsmith CR, Stack TD. Hydrogen atom abstraction by a mononuclear ferric hydroxide complex: insights into the reactivity of lipoxygenase. Inorganic Chemistry. 45: 6048-55. PMID 16842013 DOI: 10.1021/Ic060621E  0.64
2006 Goldsmith CR, Lippard SJ. 6-methylpyridyl for pyridyl substitution tunes the properties of fluorescent zinc sensors of the Zinpyr family. Inorganic Chemistry. 45: 555-61. PMID 16411690 DOI: 10.1021/Ic051113S  0.481
2006 Goldsmith CR, Jaworski J, Sheng M, Lippard SJ. Selective labeling of extracellular proteins containing polyhistidine sequences by a fluorescein-nitrilotriacetic acid conjugate. Journal of the American Chemical Society. 128: 418-9. PMID 16402822 DOI: 10.1021/Ja0559754  0.481
2005 Goldsmith CR, Cole AP, Stack TDP. C-H activation by a mononuclear manganese(III) hydroxide complex: Synthesis and characterization of a manganese-lipoxygenase mimic? Journal of the American Chemical Society. 127: 9904-9912. PMID 15998097 DOI: 10.1021/Ja039283W  0.688
2005 Rudd DJ, Goldsmith CR, Cole AP, Stack TDP, Hodgson KO, Hedman B. X-ray absorption spectroscopic investigation of the spin-transition character in a of series of single-site perturbed iron(II) complexes Inorganic Chemistry. 44: 1221-1229. PMID 15732962 DOI: 10.1021/Ic048765L  0.601
2002 Goldsmith CR, Jonas RT, Cole AP, Stack TDP. A spectrochemical walk: Single-site perturbation within a series of six-coordinate ferrous complexes Inorganic Chemistry. 41: 4642-4652. PMID 12206687 DOI: 10.1021/Ic025616Z  0.661
2002 Klein Gebbink RJ, Jonas RT, Goldsmith CR, Stack TD. A periodic walk: a series of first-row transition metal complexes with the pentadentate ligand PY5. Inorganic Chemistry. 41: 4633-41. PMID 12206686 DOI: 10.1021/Ic025617R  0.716
2002 Goldsmith CR, Jonas RT, Stack TDP. C-H bond activation by a ferric methoxide complex: Modeling the rate-determining step in the mechanism of lipoxygenase Journal of the American Chemical Society. 124: 83-96. PMID 11772065 DOI: 10.1021/Ja016451G  0.656
1998 Donahue JP, Goldsmith CR, Nadiminti U, Holm RH. Synthesis, structures, and reactivity of bis(dithiolene)molybdenum(IV,VI) complexes related to the active sites of molybdoenzymes Journal of the American Chemical Society. 120: 12869-12881. DOI: 10.1021/Ja982914F  0.654
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