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Erik R. Farquhar, Ph.D. - Publications

Affiliations: 
2010 Chemistry University of Minnesota, Twin Cities, Minneapolis, MN 
Area:
nonheme iron in biological systems
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59 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Doyle L, Magherusan A, Xu S, Murphy K, Farquhar ER, Molton F, Duboc C, Que L, McDonald AR. Class Ib Ribonucleotide Reductases: Activation of a Peroxido-MnMn to Generate a Reactive Oxo-MnMn Oxidant. Inorganic Chemistry. 63: 2194-2203. PMID 38231137 DOI: 10.1021/acs.inorgchem.3c04163  0.625
2023 Basak P, Cabelli DE, Chivers PT, Farquhar ER, Maroney MJ. In vitro maturation of NiSOD reveals a role for cytoplasmic histidine in processing and metalation. Metallomics : Integrated Biometal Science. 15. PMID 37723610 DOI: 10.1093/mtomcs/mfad054  0.555
2023 Heim P, Gericke R, Spedalotto G, Lovisari M, Farquhar ER, McDonald AR. Aromatic and aliphatic hydrocarbon hydroxylation a formally NiO oxidant. Dalton Transactions (Cambridge, England : 2003). PMID 36745393 DOI: 10.1039/d2dt03949d  0.699
2023 Heim P, Spedalotto G, Lovisari M, Gericke R, O'Brien J, Farquhar ER, McDonald AR. Synthesis and characterization of a masked terminal nickel-oxide complex. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 36696360 DOI: 10.1002/chem.202203840  0.741
2021 Malik DD, Chandra A, Seo MS, Lee YM, Farquhar ER, Mebs S, Dau H, Ray K, Nam W. Formation of cobalt-oxygen intermediates by dioxygen activation at a mononuclear nonheme cobalt(II) center. Dalton Transactions (Cambridge, England : 2003). PMID 34373886 DOI: 10.1039/d1dt01996a  0.738
2020 Gericke R, Doyle LM, Farquhar ER, McDonald AR. Oxo-Free Hydrocarbon Oxidation by an Iron(III)-Isoporphyrin Complex. Inorganic Chemistry. PMID 32955871 DOI: 10.1021/Acs.Inorgchem.0C01618  0.743
2019 Unjaroen D, Gericke R, Lovisari M, Nelis D, Mondal P, Pirovano P, Twamley B, Farquhar ER, McDonald AR. High-Valent d Ni versus d Cu Oxidants in PCET. Inorganic Chemistry. PMID 31804808 DOI: 10.1021/Acs.Inorgchem.9B03101  0.703
2019 Li Y, Handunneththige S, Farquhar ER, Guo Y, Talipov MR, Li F, Wang D. A Highly Reactive Co(μ-O) Diamond Core Complex that Cleaves C-H Bonds. Journal of the American Chemical Society. PMID 31794198 DOI: 10.1021/Jacs.9B09531  0.447
2019 Spedalotto G, Gericke R, Lovisari M, Farquhar E, Twamley B, McDonald AR. Preparation and characterization of a bis-μ-hydroxo-NiIII2 complex. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31237966 DOI: 10.1002/Chem.201902812  0.732
2019 Khadka N, Farquhar ER, Hill HE, Shi W, von Lintig J, Kiser PD. Evidence for distinct rate-limiting steps in the cleavage of alkenes by carotenoid cleavage dioxygenases. The Journal of Biological Chemistry. PMID 31138651 DOI: 10.1074/jbc.RA119.007535  0.413
2019 Singh N, Botcha NK, Jones TM, Ertem MZ, Niklas J, Farquhar ER, Poluektov OG, Mukherjee A. Reactivity of bio-inspired Cu(II) (N2/Py2) complexes with peroxide at room temperature. Journal of Inorganic Biochemistry. 197: 110674. PMID 31108242 DOI: 10.1016/J.Jinorgbio.2019.03.014  0.352
2019 Magherusan AM, Kal S, Nelis DN, Doyle LM, Farquhar ER, Que L, McDonald AR. A MnIIMnIII-peroxide complex capable of aldehyde deformylation. Angewandte Chemie (International Ed. in English). PMID 30830996 DOI: 10.1002/Anie.201900717  0.776
2019 Engelmann X, Malik DD, Corona T, Warm K, Farquhar ER, Swart M, Nam W, Ray K. Trapping of a Highly Reactive Oxoiron(IV) Complex in the Catalytic Epoxidation of Olefins by Hydrogen Peroxide. Angewandte Chemie (International Ed. in English). PMID 30663826 DOI: 10.1002/Anie.201812758  0.72
2019 Gerschel P, Warm K, Farquhar ER, Englert U, Reback ML, Siegmund D, Ray K, Apfel UP. Sulfur substitution in a Ni(cyclam) derivative results in lower overpotential for CO reduction and enhanced proton reduction. Dalton Transactions (Cambridge, England : 2003). PMID 30624449 DOI: 10.1039/C8Dt04740E  0.665
2018 Panda C, Chandra A, Corona T, Andris E, Pandey B, Garai S, Lindenmaier N, Kuenstner S, Farquhar ER, Roithova J, Rajaraman G, Driess M, Ray K. Nucleophilic vs Electrophilic Reactivity of Bioinspired Super-oxido Nickel(II) Complexes. Angewandte Chemie (International Ed. in English). PMID 30204293 DOI: 10.1002/Anie.201808085  0.699
2018 Sui X, Farquhar ER, Hill HE, von Lintig J, Shi W, Kiser PD. Preparation and characterization of metal-substituted carotenoid cleavage oxygenases. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. PMID 29946976 DOI: 10.1007/s00775-018-1586-0  0.4
2018 Mondal P, Pirovano P, Das A, Farquhar ER, McDonald AR. Hydrogen atom transfer by a high-valent nickel-chloride complex. Journal of the American Chemical Society. PMID 29293330 DOI: 10.1021/Jacs.7B11953  0.712
2018 Le CN, Phan H, Tran-Le DP, Tran DH, Farquhar ER, Vu VV. Solution structure of the reduced active site of a starch-active polysaccharide monooxygenase from Neurospora crassa Vietnam Journal of Science and Technology. 60: 9-12. DOI: 10.31276/Vjste.60(3).09  0.582
2018 Engelmann X, Farquhar ER, England J, Ray K. Four-electron reduction of dioxygen to water by a trinuclear copper complex Inorganica Chimica Acta. 481: 159-165. DOI: 10.1016/J.Ica.2017.11.014  0.684
2017 Magherusan A, Zhou A, Farquhar E, Garcia Melchor M, Twamley B, Que L, McDonald AR. Mimicking class Ib Mn2 ribonucleotide reductase: a MnII2 complex and its reaction with superoxide. Angewandte Chemie (International Ed. in English). PMID 29165865 DOI: 10.1002/Anie.201709806  0.774
2017 Snider VG, Farquhar ER, Allen M, Abu-Spetani A, Mukherjee A. Design and reactivity of Ni-complexes using pentadentate neutral-polypyridyl ligands: Possible mimics of NiSOD. Journal of Inorganic Biochemistry. 175: 110-117. PMID 28750282 DOI: 10.1016/j.jinorgbio.2017.07.005  0.363
2017 Sui X, Weitz AC, Farquhar ER, Badiee M, Banerjee S, von Lintig J, Tochtrop G, Palczewski K, Hendrich MP, Kiser PD. Structure and spectroscopy of alkene-cleaving dioxygenases containing an atypically coordinated non-heme iron center. Biochemistry. PMID 28493664 DOI: 10.1021/Acs.Biochem.7B00251  0.511
2017 Bigelow JO, England J, Klein JE, Farquhar ER, Frisch JR, Martinho M, Mandal D, Münck E, Shaik S, Que L. Oxoiron(IV) Tetramethylcyclam Complexes with Axial Carboxylate Ligands: Effect of Tethering the Carboxylate on Reactivity. Inorganic Chemistry. PMID 28257190 DOI: 10.1021/Acs.Inorgchem.6B02659  0.819
2017 Monte Pérez I, Engelmann X, Lee Y, Yoo M, Kumaran E, Farquhar ER, Bill E, England J, Nam W, Swart M, Ray K. Frontispiece: A Highly Reactive Oxoiron(IV) Complex Supported by a Bioinspired N3 O Macrocyclic Ligand Angewandte Chemie International Edition. 56. DOI: 10.1002/Anie.201784661  0.69
2016 Engelmann X, Yao S, Farquhar ER, Szilvási T, Kuhlmann U, Hildebrandt P, Driess M, Ray K. A New Domain of Reactivity for High-Valent Dinuclear [M(μ-O)2 M'] Complexes in Oxidation Reactions. Angewandte Chemie (International Ed. in English). PMID 27906528 DOI: 10.1002/Anie.201607611  0.685
2016 Pirovano P, Farquhar ER, Swart M, McDonald AR. Tuning the reactivity of terminal nickel(III)-oxygen adducts for C-H bond activation. Journal of the American Chemical Society. PMID 27739688 DOI: 10.1021/Jacs.6B08406  0.698
2016 Corona T, Ribas L, Rovira M, Farquhar ER, Ribas X, Ray K, Company A. Characterization and Reactivity Studies of a Terminal Copper-Nitrene Species. Angewandte Chemie (International Ed. in English). PMID 27723252 DOI: 10.1002/Anie.201607238  0.654
2016 Schwalenstocker K, Paudel J, Kohn AW, Dong C, Van Heuvelen KM, Farquhar ER, Li F. Cobalt Kβ valence-to-core X-ray emission spectroscopy: a study of low-spin octahedral cobalt(iii) complexes. Dalton Transactions (Cambridge, England : 2003). PMID 27533922 DOI: 10.1039/C6Dt02413K  0.438
2015 Nettles WL, Song H, Farquhar ER, Fitzkee NC, Emerson JP. Characterization of the Copper(II) Binding Sites in Human Carbonic Anhydrase II. Inorganic Chemistry. 54: 5671-80. PMID 26010488 DOI: 10.1021/Acs.Inorgchem.5B00057  0.569
2015 Pirovano P, Farquhar ER, Swart M, Fitzpatrick AJ, Morgan GG, McDonald AR. Characterization and reactivity of a terminal nickel(III)-oxygen adduct. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 3785-90. PMID 25612563 DOI: 10.1002/Chem.201406485  0.714
2015 Pirovano P, Farquhar ER, Swart M, Fitzpatrick AJ, Morgan GG, McDonald AR. Characterization and reactivity of a terminal nickel(III)-oxygen adduct Chemistry - a European Journal. 21: 3785-3790. DOI: 10.1002/chem.201406485  0.675
2014 Vu VV, Beeson WT, Span EA, Farquhar ER, Marletta MA. A family of starch-active polysaccharide monooxygenases. Proceedings of the National Academy of Sciences of the United States of America. 111: 13822-7. PMID 25201969 DOI: 10.1073/Pnas.1408090111  0.665
2014 Abram SL, Monte-Pérez I, Pfaff FF, Farquhar ER, Ray K. Evidence of two-state reactivity in alkane hydroxylation by Lewis-acid bound copper-nitrene complexes. Chemical Communications (Cambridge, England). 50: 9852-4. PMID 25025824 DOI: 10.1039/c4cc03754e  0.607
2014 England J, Bigelow JO, Van Heuvelen KM, Farquhar ER, Martinho M, Meier KK, Frisch JR, Münck E, Que L. An Ultra-Stable Oxoiron(IV) Complex and Its Blue Conjugate Base. Chemical Science (Royal Society of Chemistry : 2010). 5: 1204-1215. PMID 24660055 DOI: 10.1039/C3Sc52755G  0.825
2014 Heims F, Pfaff FF, Abram SL, Farquhar ER, Bruschi M, Greco C, Ray K. Redox non-innocence of a N-heterocyclic nitrenium cation bound to a nickel-cyclam core. Journal of the American Chemical Society. 136: 582-5. PMID 24380589 DOI: 10.1021/Ja4099559  0.668
2014 Kundu S, Miceli E, Farquhar ER, Ray K. Mechanism of phenol oxidation by heterodinuclear Ni Cu bis(μ-oxo) complexes involving nucleophilic oxo groups. Dalton Transactions (Cambridge, England : 2003). 43: 4264-7. PMID 24362244 DOI: 10.1039/C3Dt52644E  0.662
2013 Hayden JA, Farquhar ER, Que L, Lipscomb JD, Hendrich MP. NO binding to Mn-substituted homoprotocatechuate 2,3-dioxygenase: relationship to O₂ reactivity. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 18: 717-28. PMID 23824380 DOI: 10.1007/S00775-013-1016-2  0.697
2013 Kundu S, Pfaff FF, Miceli E, Zaharieva I, Herwig C, Yao S, Farquhar ER, Kuhlmann U, Bill E, Hildebrandt P, Dau H, Driess M, Limberg C, Ray K. A high-valent heterobimetallic [Cu(III)(μ-O)2Ni(III)]2+ core with nucleophilic oxo groups. Angewandte Chemie (International Ed. in English). 52: 5622-6. PMID 23589478 DOI: 10.1002/Anie.201300861  0.641
2013 Wang D, Ray K, Collins MJ, Farquhar ER, Frisch JR, Gómez L, Jackson TA, Kerscher M, Waleska A, Comba P, Costas M, Que L. Nonheme Oxoiron(IV) Complexes of Pentadentate N5 Ligands: Spectroscopy, Electrochemistry, and Oxidative Reactivity. Chemical Science (Royal Society of Chemistry : 2010). 4: 282-291. PMID 23227304 DOI: 10.1039/C2Sc21318D  0.832
2013 Kundu S, Pfaff FF, Miceli E, Zaharieva I, Herwig C, Yao S, Farquhar ER, Kuhlmann U, Bill E, Hildebrandt P, Dau H, Driess M, Limberg C, Ray K. Cover Picture: A High-Valent Heterobimetallic [CuIII(μ-O)2NiIII]2+Core with Nucleophilic Oxo Groups (Angew. Chem. Int. Ed. 21/2013) Angewandte Chemie International Edition. 52: 5409-5409. DOI: 10.1002/Anie.201303268  0.609
2013 Kundu S, Pfaff FF, Miceli E, Zaharieva I, Herwig C, Yao S, Farquhar ER, Kuhlmann U, Bill E, Hildebrandt P, Dau H, Driess M, Limberg C, Ray K. Titelbild: A High-Valent Heterobimetallic [CuIII(μ-O)2NiIII]2+Core with Nucleophilic Oxo Groups (Angew. Chem. 21/2013) Angewandte Chemie. 125: 5519-5519. DOI: 10.1002/Ange.201303268  0.613
2012 Song H, Wilson DL, Farquhar ER, Lewis EA, Emerson JP. Revisiting zinc coordination in human carbonic anhydrase II. Inorganic Chemistry. 51: 11098-105. PMID 23030313 DOI: 10.1021/Ic301645J  0.609
2012 Kundu S, Miceli E, Farquhar E, Pfaff FF, Kuhlmann U, Hildebrandt P, Braun B, Greco C, Ray K. Lewis acid trapping of an elusive copper-tosylnitrene intermediate using scandium triflate Journal of the American Chemical Society. 134: 14710-14713. PMID 22928636 DOI: 10.1021/Ja306674H  0.639
2012 Dai Z, Farquhar ER, Arora DP, Boon EM. Is histidine dissociation a critical component of the NO/H-NOX signaling mechanism? Insights from X-ray absorption spectroscopy. Dalton Transactions (Cambridge, England : 2003). 41: 7984-93. PMID 22430114 DOI: 10.1039/C2Dt30147D  0.357
2011 England J, Farquhar ER, Guo Y, Cranswick MA, Ray K, Münck E, Que L. Characterization of a tricationic trigonal bipyramidal iron(IV) cyanide complex, with a very high reduction potential, and its iron(II) and iron(III) congeners. Inorganic Chemistry. 50: 2885-96. PMID 21381646 DOI: 10.1021/Ic102094D  0.829
2011 Farquhar ER, Emerson JP, Koehntop KD, Reynolds MF, Trmčić M, Que L. In vivo self-hydroxylation of an iron-substituted manganese-dependent extradiol cleaving catechol dioxygenase. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 16: 589-97. PMID 21279661 DOI: 10.1007/S00775-011-0760-4  0.795
2011 Fielding AJ, Kovaleva EG, Farquhar ER, Lipscomb JD, Que L. A hyperactive cobalt-substituted extradiol-cleaving catechol dioxygenase. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 16: 341-55. PMID 21153851 DOI: 10.1007/S00775-010-0732-0  0.784
2010 McDonald AR, Bukowski MR, Farquhar ER, Jackson TA, Koehntop KD, Seo MS, De Hont RF, Stubna A, Halfen JA, Münck E, Nam W, Que L. Sulfur versus iron oxidation in an iron-thiolate model complex. Journal of the American Chemical Society. 132: 17118-29. PMID 21070030 DOI: 10.1021/Ja1045428  0.791
2010 England J, Guo Y, Farquhar ER, Young VG, Münck E, Que L. The crystal structure of a high-spin oxoiron(IV) complex and characterization of its self-decay pathway. Journal of the American Chemical Society. 132: 8635-44. PMID 20568768 DOI: 10.1021/Ja100366C  0.739
2010 Torres Martin De Rosales R, Faiella M, Farquhar E, Que L, Andreozzi C, Pavone V, Maglio O, Nastri F, Lombardi A. Spectroscopic and metal-binding properties of DF3: An artificial protein able to accommodate different metal ions Journal of Biological Inorganic Chemistry. 15: 717-728. PMID 20225070 DOI: 10.1007/S00775-010-0639-9  0.63
2009 Wang D, Farquhar ER, Stubna A, Münck E, Que L. A diiron(IV) complex that cleaves strong C-H and O-H bonds. Nature Chemistry. 1: 145-50. PMID 19885382 DOI: 10.1038/Nchem.162  0.739
2009 England J, Martinho M, Farquhar ER, Frisch JR, Bominaar EL, Münck E, Que L. A synthetic high-spin oxoiron(IV) complex: generation, spectroscopic characterization, and reactivity. Angewandte Chemie (International Ed. in English). 48: 3622-6. PMID 19373820 DOI: 10.1002/Anie.200900863  0.811
2008 Gunderson WA, Zatsman AI, Emerson JP, Farquhar ER, Que L, Lipscomb JD, Hendrich MP. Electron paramagnetic resonance detection of intermediates in the enzymatic cycle of an extradiol dioxygenase. Journal of the American Chemical Society. 130: 14465-7. PMID 18839948 DOI: 10.1021/Ja8052255  0.756
2008 Emerson JP, Kovaleva EG, Farquhar ER, Lipscomb JD, Que L. Swapping metals in Fe- and Mn-dependent dioxygenases: evidence for oxygen activation without a change in metal redox state. Proceedings of the National Academy of Sciences of the United States of America. 105: 7347-52. PMID 18492808 DOI: 10.1073/Pnas.0711179105  0.762
2008 Emerson JP, Farquhar ER, Que LJ. ChemInform Abstract: Structural “Snapshots” along Reaction Pathways of Non-Heme Iron Enzymes Cheminform. 39. DOI: 10.1002/chin.200807276  0.607
2007 Emerson JP, Farquhar ER, Que L. Structural "snapshots" along reaction pathways of non-heme iron enzymes. Angewandte Chemie (International Ed. in English). 46: 8553-6. PMID 17924385 DOI: 10.1002/Anie.200703057  0.691
2007 Farquhar ER, Richard JP, Morrow JR. Formation and stability of mononuclear and dinuclear Eu(III) complexes and their catalytic reactivity toward cleavage of an RNA analog. Inorganic Chemistry. 46: 7169-77. PMID 17655292 DOI: 10.1021/Ic7005666  0.337
2007 Emerson J, Farquhar E, Que L. “Schnappschüsse” von Strukturen entlang der Reaktionswege von Nicht-Häm-Eisenenzymen Angewandte Chemie. 119: 8705-8708. DOI: 10.1002/Ange.200703057  0.514
2005 Farquhar ER, Koehntop KD, Emerson JP, Que L. Post-translational self-hydroxylation: a probe for oxygen activation mechanisms in non-heme iron enzymes. Biochemical and Biophysical Research Communications. 338: 230-9. PMID 16165090 DOI: 10.1016/J.Bbrc.2005.08.191  0.791
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