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Patrick S. Mariano - Publications

Affiliations: 
1970-1979 Texas A & M University, College Station, TX, United States 
 1979-1997 Chemistry University of Maryland, College Park, College Park, MD 
 1997- Chemistry University of New Mexico, Albuquerque, NM, United States 
Area:
Organic Chemistry, Biochemistry
Website:
https://chemistry.unm.edu/people/faculty/members/patrick-mariano.html

138 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2017 Huang H, Yu C, Zhang Y, Zhang Y, Mariano PS, Wang W. Chemo- and Regio-Selective Organo-Photoredox Catalyzed Hydro-formylation of Styrenes via a Radical Pathway. Journal of the American Chemical Society. PMID 28692260 DOI: 10.1021/Jacs.7B05082  0.31
2017 Huang H, Li X, Yu C, Zhang Y, Mariano PS, Wang W. Visible-Light-Promoted Nickel- and Organic-Dye-Cocatalyzed Formylation Reaction of Aryl Halides and Triflates and Vinyl Bromides with Diethoxyacetic Acid as a Formyl Equivalent. Angewandte Chemie (International Ed. in English). PMID 28066982 DOI: 10.1002/Anie.201610108  0.347
2016 Lim SH, Jeong HC, Sohn Y, Kim YI, Cho DW, Woo HJ, Shin IS, Yoon UC, Mariano PS. Single Electron Transfer Promoted Photochemical Reactions of Secondary N-Trimethylsilylmethyl-N-benzylamines Leading to Aminomethylation of Fullerene C60. The Journal of Organic Chemistry. PMID 26895035 DOI: 10.1021/Acs.Joc.6B00004  0.329
2015 Mariano PS, Cho DW, Moon GM, Lim SH, Kim SH, Lee IO, Yoon UC. Comparison Of Photochemical Reactions Of Aromatic Carbonyl Compounds With A Silyl Ketene Thioacetal And A Silyl Ketene Acetal Heterocycles. 90: 978. DOI: 10.3987/Com-14-S(K)69  0.383
2014 Lim SH, Yi J, Moon GM, Ra CS, Nahm K, Cho DW, Kim K, Hyung TG, Yoon UC, Lee GY, Kim S, Kim J, Mariano PS. Method for the synthesis of amine-functionalized fullerenes involving SET-promoted photoaddition reactions of α-silylamines. The Journal of Organic Chemistry. 79: 6946-58. PMID 24984113 DOI: 10.1021/Jo501034T  0.423
2014 Cho DW, Mariano PS, Yoon UC. Direct and indirect single electron transfer (SET)-photochemical approaches for the preparation of novel phthalimide and naphthalimide-based lariat-type crown ethers. Beilstein Journal of Organic Chemistry. 10: 514-27. PMID 24605169 DOI: 10.3762/bjoc.10.47  0.361
2013 Lim SH, Nahm K, Ra CS, Cho DW, Yoon UC, Latham JA, Dunaway-Mariano D, Mariano PS. Effects of alkoxy groups on arene rings of lignin β-O-4 model compounds on the efficiencies of single electron transfer-promoted photochemical and enzymatic C-C Bond Cleavage Reactions. The Journal of Organic Chemistry. 78: 9431-43. PMID 23992466 DOI: 10.1021/Jo401680Z  0.368
2013 Wu C, Dunaway-Mariano D, Mariano PS. Design, synthesis, and evaluation of inhibitors of pyruvate phosphate dikinase. The Journal of Organic Chemistry. 78: 1910-22. PMID 23094589 DOI: 10.1021/Jo3018473  0.32
2013 Park HJ, Ryu YJ, Kim KM, Yoon UC, Kim E, Sohn Y, Cho DW, Mariano PS. Comparison of Photocyclization Reactions of Fluoro- vs Nonfluoro-Substituted Polymethyleneoxy Donor Linked Phthalimides Bulletin of the Korean Chemical Society. 34: 1108-1114. DOI: 10.5012/Bkcs.2013.34.4.1108  0.441
2013 Park HJ, Sung NK, Kim SR, Ahn SH, Yoon UC, Cho DW, Mariano PS. Novel Naphthalene Based Lariat-Type Crown Ethers Using Direct Single Electron Transfer Photochemical Strategy Bulletin of the Korean Chemical Society. 34: 3681-3689. DOI: 10.5012/Bkcs.2013.34.12.3681  0.338
2012 Park HJ, Yoon UC, Lee HY, Cho DW, Cho DW, Mariano PS. Photoaddition reactions of acetylpyridines with silyl ketene acetals: SET vs [2 + 2]-cycloaddition pathways. The Journal of Organic Chemistry. 77: 10304-13. PMID 23092504 DOI: 10.1021/Jo301961N  0.462
2011 Cho DW, Lee CW, Park JG, Oh SW, Sung NK, Park HJ, Kim KM, Mariano PS, Yoon UC. Exploration of photochemical reactions of N-trimethylsilylmethyl-substituted uracil, pyridone, and pyrrolidone derivatives. Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society For Photobiology. 10: 1169-80. PMID 21472163 DOI: 10.1039/c0pp00372g  0.361
2011 Cho DW, Latham JA, Park HJ, Yoon UC, Langan P, Dunaway-Mariano D, Mariano PS. Regioselectivity of enzymatic and photochemical single electron transfer promoted carbon-carbon bond fragmentation reactions of tetrameric lignin model compounds. The Journal of Organic Chemistry. 76: 2840-52. PMID 21384857 DOI: 10.1021/Jo200253V  0.409
2011 Cho DW, Yoon UC, Mariano PS. Studies leading to the development of a single-electron transfer (SET) photochemical strategy for syntheses of macrocyclic polyethers, polythioethers, and polyamides. Accounts of Chemical Research. 44: 204-15. PMID 21197953 DOI: 10.1021/Ar100125J  0.461
2011 Cho DW, Quan C, Park HJ, Yoon UC, Mariano PS. Photochemical Approach to the Preparation of Lariat Crown Ethers Containing Peptide Sidearms Bulletin of the Korean Chemical Society. 32: 503-509. DOI: 10.5012/Bkcs.2011.32.2.503  0.415
2011 Cho DW, Oh SW, Kim DU, Park HJ, Xue JY, Yoon UC, Mariano PS. ChemInform Abstract: Studies of Silyl-Transfer Photochemical Reactions of N-[(Trimethylsilyl)alkyl]saccharins. Cheminform. 42: no-no. DOI: 10.1002/CHIN.201107162  0.324
2010 Cho DW, Parthasarathi R, Pimentel AS, Maestas GD, Park HJ, Yoon UC, Dunaway-Mariano D, Gnanakaran S, Langan P, Mariano PS. Nature and kinetic analysis of carbon-carbon bond fragmentation reactions of cation radicals derived from SET-oxidation of lignin model compounds. The Journal of Organic Chemistry. 75: 6549-62. PMID 20831160 DOI: 10.1021/Jo1012509  0.368
2010 Cho DW, Oh SW, Kim DU, Park HJ, Xue JY, Yoon UC, Mariano PS. Studies of Silyl-Transfer Photochemical Reactions of N-[(Trimethylsilyl)alkyl]saccharins Bulletin of the Korean Chemical Society. 31: 2453-2458. DOI: 10.5012/Bkcs.2010.31.9.2453  0.416
2010 YOON UC, MARIANO PS, GIVENS RS, ATWATER BW. ChemInform Abstract: Photoinduced Electron Transfer Chemistry of Amines and Related Electron Donors Cheminform. 26: no-no. DOI: 10.1002/chin.199528277  0.531
2010 XU W, ZHANG X, MARIANO PS. ChemInform Abstract: Single Electron Transfer Promoted Photocyclization Reactions of ( Aminoalkyl)cyclohexenones. Mechanistic and Synthetic Features of Processes Involving the Generation and Reactions of Amine Cation and . alpha.-Amino Radicals. Cheminform. 23: no-no. DOI: 10.1002/chin.199209088  0.375
2009 Li Z, Kulakova L, Li L, Galkin A, Zhao Z, Nash TE, Mariano PS, Herzberg O, Dunaway-Mariano D. Mechanisms of catalysis and inhibition operative in the arginine deiminase from the human pathogen Giardia lamblia. Bioorganic Chemistry. 37: 149-61. PMID 19640561 DOI: 10.1016/J.Bioorg.2009.06.001  0.519
2008 Cho DW, Lee HY, Oh SW, Choi JH, Park HJ, Mariano PS, Yoon UC. Photoaddition reactions of 1,2-diketones with silyl ketene acetals. formation of beta-hydroxy-gamma-ketoesters. The Journal of Organic Chemistry. 73: 4539-47. PMID 18494523 DOI: 10.1021/Jo800473X  0.393
2008 Zou J, Mariano PS. The synthetic potential of pyridinium salt photochemistry. Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society For Photobiology. 7: 393-404. PMID 18385880 DOI: 10.1039/B801808C  0.396
2008 Li L, Li Z, Wang C, Xu D, Mariano PS, Guo H, Dunaway-Mariano D. The electrostatic driving force for nucleophilic catalysis in L-arginine deiminase: a combined experimental and theoretical study. Biochemistry. 47: 4721-32. PMID 18366187 DOI: 10.1021/Bi7023496  0.378
2008 Cho DW, Choi JH, Oh SW, Quan C, Yoon UC, Wang R, Yang S, Mariano PS. Single electron transfer-promoted photocyclization reactions of linked acceptor-polydonor systems: effects of chain length and type on the efficiencies of macrocyclic ring-forming photoreactions of tethered alpha-silyl ether phthalimide substrates. Journal of the American Chemical Society. 130: 2276-84. PMID 18225898 DOI: 10.1021/Ja076846L  0.776
2008 Li L, Li Z, Chen D, Lu X, Feng X, Wright EC, Solberg NO, Dunaway-Mariano D, Mariano PS, Galkin A, Kulakova L, Herzberg O, Green-Church KB, Zhang L. Inactivation of microbial arginine deiminases by L-canavanine. Journal of the American Chemical Society. 130: 1918-31. PMID 18205354 DOI: 10.1021/Ja0760877  0.65
2008 Narayanan BC, Niu W, Han Y, Zou J, Mariano PS, Dunaway-Mariano D, Herzberg O. Structure and function of PA4872 from Pseudomonas aeruginosa, a novel class of oxaloacetate decarboxylase from the PEP mutase/isocitrate lyase superfamily. Biochemistry. 47: 167-82. PMID 18081320 DOI: 10.1021/Bi701954P  0.332
2008 Zhou J, Gong M, Mariano PS, Yoon UC. Observations Made in Exploring a Pyridinium Salt Photochemical Approach to the Synthesis of (+)-Lactacystin Bulletin of the Korean Chemical Society. 29: 89-93. DOI: 10.5012/Bkcs.2008.29.1.089  0.405
2007 Sung NK, Cho DW, Choi JH, Choi KW, Yoon UC, Maeda H, Mariano PS. A facile approach to the preparation of bis-crown ethers based on SET-promoted photomacrocyclization reactions. The Journal of Organic Chemistry. 72: 8831-7. PMID 17927254 DOI: 10.1021/Jo701770X  0.443
2007 Han Y, Joosten HJ, Niu W, Zhao Z, Mariano PS, McCalman M, van Kan J, Schaap PJ, Dunaway-Mariano D. Oxaloacetate hydrolase, the C-C bond lyase of oxalate secreting fungi. The Journal of Biological Chemistry. 282: 9581-90. PMID 17244616 DOI: 10.1074/Jbc.M608961200  0.539
2006 Lu X, Li L, Wu R, Feng X, Li Z, Yang H, Wang C, Guo H, Galkin A, Herzberg O, Mariano PS, Martin BM, Dunaway-Mariano D. Kinetic analysis of Pseudomonas aeruginosa arginine deiminase mutants and alternate substrates provides insight into structural determinants of function. Biochemistry. 45: 1162-72. PMID 16430212 DOI: 10.1021/Bi051591E  0.675
2006 Yoon UC, Mariano PS. The Synthetic Potential of SET Photochemistry of Silicon-Substituted Polydonor-Linked Phthalimides Cheminform. 37. DOI: 10.5012/Bkcs.2006.27.8.1099  0.436
2005 Lu Z, Feng X, Song L, Han Y, Kim A, Herzberg O, Woodson WR, Martin BM, Mariano PS, Dunaway-Mariano D. Diversity of function in the isocitrate lyase enzyme superfamily: the Dianthus caryophyllus petal death protein cleaves alpha-keto and alpha-hydroxycarboxylic acids. Biochemistry. 44: 16365-76. PMID 16342929 DOI: 10.1021/Bi051776L  0.713
2005 Lu X, Li L, Feng X, Wu Y, Dunaway-Mariano D, Engen JR, Mariano PS. L-canavanine is a time-controlled mechanism-based inhibitor of Pseudomonas aeruginosa arginine deiminase. Journal of the American Chemical Society. 127: 16412-3. PMID 16305225 DOI: 10.1021/Ja056226P  0.649
2005 Zhao Z, Duesler E, Wang C, Guo H, Mariano PS. Photocyclization reactions of cyclohexa- and cyclopenta-fused pyridinium salts. Factors governing regioselectivity. The Journal of Organic Chemistry. 70: 8508-12. PMID 16209600 DOI: 10.1021/Jo051348L  0.609
2005 Feng X, Duesler EN, Mariano PS. Pyridinium salt photochemistry in a concise route for synthesis of the trehazolin aminocyclitol, trehazolamine. The Journal of Organic Chemistry. 70: 5618-23. PMID 15989345 DOI: 10.1021/Jo050589Q  0.714
2005 Zhao Z, Song L, Mariano PS. A concise sequential photochemical-metathesis approach for the synthesis of (+)-castanospermine and possible uniflorine-A stereoisomers Tetrahedron. 61: 8888-8894. DOI: 10.1016/J.Tet.2005.07.014  0.69
2004 Song L, Duesler EN, Mariano PS. Stereoselective synthesis of polyhydroxylated indolizidines based on pyridinium salt photochemistry and ring rearrangement metathesis. The Journal of Organic Chemistry. 69: 7284-93. PMID 15471482 DOI: 10.1021/Jo040226A  0.625
2004 Wang R, Chen C, Duesler E, Mariano PS, Yoon UC. Beta-lactam-forming photochemical reactions of N-trimethylsilylmethyl- and N-tributylstannylmethyl-substituted alpha-ketoamides. The Journal of Organic Chemistry. 69: 1215-20. PMID 14961673 DOI: 10.1021/Jo030343Q  0.782
2004 Yoon UC, Kwon HC, Hyung TG, Choi KH, Oh SW, Yang S, Zhao Z, Mariano PS. The photochemistry of polydonor-substituted phthalimides: Curtin-Hammett-type control of competing reactions of potentially interconverting zwitterionic biradical intermediates. Journal of the American Chemical Society. 126: 1110-24. PMID 14746480 DOI: 10.1021/Ja0305712  0.763
2003 Yoon UC, Jin YX, Oh SW, Park CH, Park JH, Campana CF, Cai X, Duesler EN, Mariano PS. A synthetic strategy for the preparation of cyclic peptide mimetics based on SET-promoted photocyclization processes. Journal of the American Chemical Society. 125: 10664-71. PMID 12940751 DOI: 10.1021/Ja030297B  0.735
2002 Lu H, Su Z, Song L, Mariano PS. A novel approach to the synthesis of amino-sugars. Routes to selectively protected 3-amino-3-deoxy-aldopentoses based on pyridinium salt photochemistry. The Journal of Organic Chemistry. 67: 3525-8. PMID 12003573 DOI: 10.1021/Jo020038P  0.574
2002 Yoon UC, Kim MJ, Moon JJ, Oh SW, Kim HJ, Mariano PS. Photoaddition Reactions of Silyl Ketene Acetals with Aromatic Carbonyl Compounds: A New Procedure for β-Hydroxyester Synthesis † Bulletin of the Korean Chemical Society. 23: 1218-1242. DOI: 10.5012/Bkcs.2002.23.9.1218  0.424
2001 Yoon UC, Mariano PS. The synthetic potential of phthalimide SET photochemistry. Accounts of Chemical Research. 34: 523-33. PMID 11456470 DOI: 10.1021/Ar010004O  0.488
2001 Yoon UC, Oh SW, Lee JH, Park JH, Kang KT, Mariano PS. Applications of phthalimide photochemistry to macrocyclic polyether, polythioether, and polyamide synthesis. The Journal of Organic Chemistry. 66: 939-43. PMID 11430116 DOI: 10.1021/Jo001457U  0.497
2001 Chen C, Chang V, Cai X, Duesler E, Mariano PS. A general strategy for absolute stereochemical control in enone-olefin [2+2] photocycloaddition reactions. Journal of the American Chemical Society. 123: 6433-4. PMID 11427077 DOI: 10.1021/Ja010883+  0.735
2000 Cai X, Chang V, Chen C, Kim H, Mariano PS. A potentially general method to control relative stereochemistry in enone–olefin 2+2-photocycloaddition reactions by using eniminium salt surrogates† Tetrahedron Letters. 41: 9445-9449. DOI: 10.1016/S0040-4039(00)01581-1  0.761
1999 Yoon UC, Oh SW, Lee SM, Cho SJ, Gamlin aJ, Mariano PS. A Solvent Effect That Influences the Preparative Utility of N-(Silylalkyl)phthalimide and N-(Silylalkyl)maleimide Photochemistry Journal of Organic Chemistry. 64: 4411-4418. DOI: 10.1021/Jo990087A  0.384
1999 Takahashi Y, Miyashi T, Yoon UC, Oh SW, Mancheno M, Su Z, Falvey aDF, Mariano PS. Mechanistic Studies of the Azomethine Ylide-Forming Photoreactions of N-(Silylmethyl)phthalimides and N-Phthaloylglycine Journal of the American Chemical Society. 121: 3926-3932. DOI: 10.1021/Ja9841862  0.356
1998 Wu XD, Khim SK, Zhang X, Cederstrom EM, Mariano PS. An Oxidative Mannich Cyclization Methodology for the Stereocontrolled Synthesis of Highly Functionalized Piperidines. The Journal of Organic Chemistry. 63: 841-859. PMID 11672082 DOI: 10.1021/Jo971706N  0.418
1998 Su Z, Mariano PS, Falvey DE, Yoon UC, Oh SW. Dynamics of anilinium radical α-heterolytic fragmentation processes. Electrofugal group, substituent, and medium effects on desilylation, decarboxylation, and retro-aldol cleavage pathways Journal of the American Chemical Society. 120: 10676-10686. DOI: 10.1021/Ja981541F  0.366
1996 Lin X, Kavash RW, Mariano PS. Two Interrelated Strategies for Cephalotaxine Synthesis. The Journal of Organic Chemistry. 61: 7335-7347. PMID 11667659 DOI: 10.1021/Jo961179S  0.403
1996 Ling R, Yoshida M, Mariano PS. Exploratory Investigations Probing a Preparatively Versatile, Pyridinium Salt Photoelectrocyclization-Solvolytic Aziridine Ring Opening Sequence. The Journal of Organic Chemistry. 61: 4439-4449. PMID 11667350 DOI: 10.1021/Jo960316I  0.413
1996 Lee YJ, Ling R, Mariano PS, Yoon UC, Kim DU, Oh SW. Exploratory Studies of H-Atom Abstraction and Silyl-Transfer Photoreactions of Silylalkyl Ketones and (Silylalkyl)phthalimides Journal of Organic Chemistry. 61: 3304-3314. DOI: 10.1021/Jo9522623  0.398
1995 Xu Y, Yankie L, Shen L, Jung YS, Mariano PS, Dunaway-Mariano D, Martin BM. Location of the catalytic site for phosphoenolpyruvate formation within the primary structure of Clostridium symbiosum pyruvate phosphate dikinase. 1. Identification of an essential cysteine by chemical modification with [1-14C]bromopyruvate and site-directed mutagenesis Biochemistry. 34: 2181-2187. PMID 7857929 DOI: 10.1021/Bi00007A011  0.381
1994 Fasani E, d'Alessandro N, Albini A, Mariano PS. SET Photochemical Reactions between 1,4-Naphthalenedicarbonitrile and Benzylic Donors. Medium Effects Journal of Organic Chemistry. 59: 829-835. DOI: 10.1021/Jo00083A025  0.386
1994 Lin X, Kavash RW, Mariano PS. A Cephalotaxine Synthesis Founded On A Mechanistically Interesting, Quasi-Biomimetic Strategy Journal of the American Chemical Society. 116: 9791-9792. DOI: 10.1021/Ja00100A071  0.306
1993 D'Alessandro N, Albini A, Mariano PS. Methylbenzene cation radical .alpha.-fragmentation selectivities revealed in SET-photoadditions of p-xylene derivatives to 1,4-dicyanonaphthalene [SET = single electron transfer] Journal of Organic Chemistry. 58: 937-942. DOI: 10.1021/Jo00056A029  0.341
1993 Kim JM, Bogdan MA, Mariano PS. Mechanistic analysis of the 3-methyllumiflavin-promoted oxidative deamination of benzylamine. A potential model for monoamine oxidase catalysis Journal of the American Chemical Society. 115: 10591-10595. DOI: 10.1021/Ja00076A017  0.327
1992 Jung YS, Swartz WH, Xu W, Mariano PS, Green NJ, Schultz AG. Exploratory studies of .alpha.-silylamino- and .alpha.-silylamido-2,5-cyclohexadien-1-one SET photochemistry. Methodology for synthesis of functionalized hydroisoquinolines Journal of Organic Chemistry. 57: 6037-6047. DOI: 10.1021/Jo00048A046  0.399
1992 Yoon UC, Kim YC, Choi JJ, Kim DU, Mariano PS, Cho IS, Jeon YT. Photoaddition reactions of acenaphthylenedione with .alpha.-silyl n-electron donors via triplet single electron transfer desilylation and triplet hydrogen atom abstraction pathways Journal of Organic Chemistry. 57: 1422-1428. DOI: 10.1021/Jo00031A020  0.321
1992 Lee SL, Hepburn TW, Swartz WH, Ammon HL, Mariano PS, Dunaway-Mariano D. Stereochemical probe for the mechanism of phosphorus-carbon bond cleavage catalyzed by the Bacillus cereus phosphonoacetaldehyde hydrolase Journal of the American Chemical Society. 114: 7346-7354. DOI: 10.1021/Ja00045A003  0.354
1992 Yoon UC, Mariano PS. Mechanistic And Synthetic Aspects Of Amine-Enone Single Electron Transfer Photochemistry Accounts of Chemical Research. 25: 233-240. DOI: 10.1021/Ar00017A005  0.342
1991 Cho I, Chang SSS, Ho C, Lee C-, Ammon HL, Mariano PS. Stereochemical Characteristics of Set-promoted Photochemical Reactions of Dihydroisoquinolinium Salts Heterocycles. 32: 2161-2192. DOI: 10.3987/Com-91-5841  0.439
1991 McQueney MS, Lee SL, Swartz WH, Ammon HL, Mariano PS, Dunaway-Mariano D. Evidence for an intramolecular, stepwise reaction pathway for PEP phosphomutase catalyzed phosphorus-carbon bond formation The Journal of Organic Chemistry. 56: 7121-7130. DOI: 10.1021/Jo00025A031  0.372
1991 Kim JM, Cho IS, Mariano PS. Amine-flavin electron transfer photochemistry. Potential models for monoamine oxidase catalysis and inhibition Journal of Organic Chemistry. 56: 4943-4955. DOI: 10.1021/Jo00016A026  0.324
1991 Zhang XM, Mariano PS. Mechanistic details for SET-promoted photoadditions of amines to conjugated enones arising from studies of aniline-cyclohexenone photoreactions Journal of Organic Chemistry. 56: 1655-1660. DOI: 10.1021/Jo00004A055  0.328
1991 Xu W, Zhang XM, Mariano PS. Single electron transfer promoted photocyclization reactions of (aminoalkyl)cyclohexenones. Mechanistic and synthetic features of processes involving the generation and reactions of amine cation and .alpha.-amino radicals Journal of the American Chemical Society. 113: 8863-8878. DOI: 10.1021/Ja00023A039  0.47
1991 Jeon YT, Lee CP, Mariano PS. Radical cyclization reactions of .alpha.-silyl amine .alpha.,.beta.-unsaturated ketone and ester systems promoted by single electron transfer photosensitization Journal of the American Chemical Society. 113: 8847-8863. DOI: 10.1021/Ja00023A038  0.422
1990 Lee SL, Hepburn TW, Mariano PS, Dunaway-Mariano D. A method for chiral thiophosphonate synthesis and its use in elucidating the phosphorus stereochemistry of the hydrolytic carbon-phosphorus bond cleavage reaction of thiophosphonoacetaldehyde Journal of Organic Chemistry. 55: 5435-5437. DOI: 10.1021/Jo00307A007  0.364
1990 Baxter EW, Labaree D, Ammon HL, Mariano PS. Formal total synthesis of deserpidine demonstrating a versatile amino-claisen rearrangement/Wenkert cyclization strategy for the preparation of functionalized yohimbane ring systems Journal of the American Chemical Society. 112: 7682-7692. DOI: 10.1021/Ja00177A032  0.336
1990 Cho IS, Tu CL, Mariano PS. Electron-transfer-induced photochemical reactions of (silylallyl)iminium and benzylpyrrolinium salts by dual diradical and diradical cation cyclization pathways Journal of the American Chemical Society. 112: 3594-3607. DOI: 10.1021/Ja00165A052  0.457
1990 CHO I, TU C, MARIANO PS. ChemInform Abstract: Electron Transfer Induced Photochemical Reactions of (Silylallyl)iminium and Benzylpyrrolinium Salts by Dual Diradical and Diradical Cation Cyclization Pathways. Cheminform. 21. DOI: 10.1002/chin.199034063  0.322
1989 Yoon UC, Kim H, Mariano PS. Electron Transfer - Induced Photochemical Reactions in Imide- RXCH2 TMS Systems. Photoaddition of a-Trimethylsilyl Substituted Heteroatom Containing Compounds to Phthalimides Heterocycles. 29: 1041-1064. DOI: 10.3987/Com-89-4762  0.379
1989 Baxter EW, Labaree D, Chao S, Mariano PS. Model studies probing the amino-Claisen rearrangement approach to hydroisoquinoline synthesis. Development of methods for stereocontrolled introduction of reserpine E ring type functionality Journal of Organic Chemistry. 54: 2893-2904. DOI: 10.1021/Jo00273A024  0.305
1989 Xu W, Jeon YT, Hasegawa E, Yoon UC, Mariano PS. Novel electron-transfer photocyclization reactions of .alpha.-silyl amine .alpha.,.beta.-unsaturated ketone and ester systems Journal of the American Chemical Society. 111: 406-408. DOI: 10.1021/Ja00183A081  0.404
1988 Olsen DB, Hepburn TW, Moos M, Mariano PS, Dunaway-Mariano D. Investigation of the Bacillus cereus phosphonoacetaldehyde hydrolase. Evidence for a schiff base mechanism and sequence analysis of an active-site peptide containing the catalytic lysine residue Biochemistry. 27: 2229-2234. PMID 3132206 DOI: 10.1021/Bi00406A063  0.326
1988 Hasegawa E, Brumfield MA, Mariano PS, Yoon UC. Photoadditions of ethers, thioethers, and amines to 9,10-dicyanoanthracene by electron transfer pathways Journal of Organic Chemistry. 53: 5435-5442. DOI: 10.1021/Jo00258A007  0.336
1988 Dai-Ho G, Mariano PS. Exploratory, mechanistic, and synthetic aspects of silylarene-iminium salt SET photochemistry: studies of diradical cyclization processes and applications to protoberberine alkaloid synthesis Journal of Organic Chemistry. 53: 5113-5127. DOI: 10.1021/Jo00256A038  0.328
1988 Hasegawa E, Xu W, Mariano PS, Yoon UC, Kim JU. Electron-transfer-induced photoadditions of the silyl amine, Et2NCH2SiMe3, to .alpha.,.beta.-unsaturated cyclohexenones. Dual reaction pathways based on ion pair-selective cation-radical chemistry Journal of the American Chemical Society. 110: 8099-8111. DOI: 10.1021/Ja00232A023  0.414
1988 Ho E, Cheng Y, Mariano PS. Acid catalyzed intramolecular 2-aza-1,3-diene Diels-Alder cyclization processes Tetrahedron Letters. 29: 4799-4802. DOI: 10.1016/S0040-4039(00)80612-7  0.371
1988 Chen S, Ho E, Mariano PS. A protodesilylation route for 2-Aza-1,3-diene synthesis Tetrahedron. 44: 7013-7026. DOI: 10.1016/S0040-4020(01)86070-1  0.438
1988 CHO I, MARIANO PS. ChemInform Abstract: Photocyclization Reactions of 1-Benzyl-1-pyrrolinium Salts by Diradical and Diradical Cation Pathways. Novel Photochemical Pictet-Spengler Cyclizations. Cheminform. 19. DOI: 10.1002/chin.198839181  0.321
1987 Haddaway K, Somekawa K, Fleming P, Tossell JA, Mariano PS. Chemistry of allene cation radicals probed by the use of theoretical and electron-transfer photochemical methods Journal of Organic Chemistry. 52: 4239-4253. DOI: 10.1021/Jo00228A017  0.331
1987 Tu CL, Mariano PS. Dual diradical and cation diradical cyclization mechanisms for silylalkenyl iminium salt. Electron-transfer induced photocyclization reactions Journal of the American Chemical Society. 109: 5287-5288. DOI: 10.1021/Ja00251A048  0.421
1987 Yoon UC, Kim JU, Hasegawa E, Mariano PS. Electron-transfer photochemistry of. cap alpha. -silylamine-cyclohexenone systems. Medium effects on reaction pathways followed Journal of the American Chemical Society. 109: 4421-4423. DOI: 10.1021/Ja00248A063  0.4
1987 TU C, MARIANO PS. ChemInform Abstract: Dual Diradical and Cation Diradical Cyclization Mechanisms for Silylalkenyl Iminium Salt. Electron-Transfer-Induced Photocyclization Reactions. Cheminform. 18. DOI: 10.1002/chin.198749106  0.32
1986 Ahmed-Schofield R, Mariano PS. Sequential Electron-Transfer-Desilylation Methods for Diradical Photogeneration as Part of Synthetic Routes for Erythrina Alkaloid Synthesis. Cheminform. 17. DOI: 10.1002/Chin.198627315  0.347
1986 CHENG Y, HO E, MARIANO PS, AMMON HL. ChemInform Abstract: Mechanistic Aspects of the Boron Trifluoride Catalyzed, Intermolecular Diels-Alder Cycloaddition of an Unactivated 2-Aza 1,3-Diene with Electron-Donating-Substituted Dienophiles. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198627098  0.419
1985 Cheng YS, Ho E, Mariano PS, Ammon HL. Mechanistic aspects of the boron trifluoride catalyzed, intermolecular Diels-Alder cycloaddition of an unactivated 2-aza 1,3-diene with electron-donating-substituted dienophiles Journal of Organic Chemistry. 50: 5678-5686. DOI: 10.1021/Jo00350A049  0.303
1985 Ahmed-Schofield R, Mariano PS. Sequential electron-transfer-desilylation methods for diradical photogeneration as part of synthetic routes for erythrina alkaloid synthesis Journal of Organic Chemistry. 50: 5667-5677. DOI: 10.1021/Jo00350A048  0.347
1984 Chao S, Kunng FA, Gu JM, Ammon HL, Mariano PS. Rauwolfia alkaloid synthesis approach employing the zwitterionic amino-Claisen rearrangement. Improvements in the efficiency for yohimbane ring construction and unambiguous de-ring-fusion stereochemical assignments Journal of Organic Chemistry. 49: 2708-2711. DOI: 10.1021/Jo00189A011  0.318
1984 Chiu FT, Ullrich JW, Mariano PS. Model studies examining the application of allyliminium salt photospirocyclization methodologies in synthetic approaches to the harringtonine alkaloids Journal of Organic Chemistry. 49: 228-236. DOI: 10.1021/Jo00176A003  0.307
1984 Ullrich JW, Chiu FT, Tiner-Harding T, Mariano PS. Electron-transfer-initiated photospirocyclization reactions of .beta.-enaminone-derived allyliminium salts Journal of Organic Chemistry. 49: 220-228. DOI: 10.1021/Jo00176A002  0.373
1984 Ohga K, Yoon UC, Mariano PS. Exploratory and mechanistic studies of the electron-transfer-initiated photoaddition reactions of allylsilane-iminium salt systems Journal of Organic Chemistry. 49: 213-219. DOI: 10.1021/Jo00176A001  0.417
1984 Brumfield MA, Quillen SL, Yoon UC, Mariano PS. A novel method for heteroatom-substituted free radical generation by photochemical electron transfer induced desilylation of RXCH2SiMe3 systems Journal of the American Chemical Society. 106: 6855-6856. DOI: 10.1021/Ja00334A072  0.325
1984 Somekawa K, Haddaway K, Mariano PS, Tossell JA. Electron-transfer photochemistry of allene-iminium salt systems. Probes for allene cation radical structure by theoretical and chemical techniques Journal of the American Chemical Society. 106: 3060-3062. DOI: 10.1021/Ja00322A067  0.361
1984 Somekawa K, Haddaway K, Mariano PS, Tossell JA. Electron-Transfer Photochemistry Of Allene-Iminium Salt Systems. Probes For Allene Cation Radical Structure By Theoretical And Chemical Techniques Cheminform. 15. DOI: 10.1002/Chin.198435124  0.328
1984 Ullrich JW, Chiu F-, Tiner-Harding T, Mariano PS. ELECTRON-TRANSFER-INITIATED PHOTOSPIROCYCLIZATION REACTIONS OF β-ENAMINONE-DERIVED ALLYLIMINIUM SALTS Cheminform. 15. DOI: 10.1002/Chin.198425183  0.387
1983 Chen SF, Ullrich JW, Mariano PS. Sequential electron-transfer-desilylation pathways for C-vinylazomethine ylide formation in the photochemistry of [1-(triethylsilyl)allyl]iminium salts Journal of the American Chemical Society. 105: 6160-6162. DOI: 10.1021/Ja00357A037  0.356
1983 Yoon UC, Quillen SL, Mariano PS, Swanson R, Stavinoha JL, Bay E. Exploratory and mechanistic aspects of the electron-transfer photochemistry of olefin-N-heteroaromatic cation systems Journal of the American Chemical Society. 105: 1204-1218. DOI: 10.1021/Ja00343A022  0.338
1983 Mariano PS. Electron-transfer mechanisms in photochemical transformations of iminium salts Accounts of Chemical Research. 16: 130-137. DOI: 10.1021/Ar00088A003  0.302
1982 Tiner-Harding T, Ullrich JW, Chiu FT, Chen SF, Mariano PS. Electron Transfer Initiated Iminium Salt Photospirocyclization Methodologies. Model Studies For Harringtonine Alkaloid Synthesis Journal of Organic Chemistry. 14: 3360-3362. DOI: 10.1021/Jo00138A042  0.352
1982 Ohga K, Mariano PS. Electron-transfer initiated photoaddition of allylsilanes to 1-methyl-2-phenylpyrrolinium perchlorate. A novel allylation methodology Journal of the American Chemical Society. 104: 617-619. DOI: 10.1021/Ja00366A043  0.332
1982 Yerino LV, Osborn ME, Mariano PS. The hydroazocine route to highly functionalized pyrrolizidines Tetrahedron. 38: 1579-1591. DOI: 10.1016/0040-4020(82)80133-6  0.402
1981 Stavinoha JL, Mariano PS, Leone-Bay A, Swanson R, Bracken C. Photocyclizations of N-allyliminium salts leading to the production of substituted pyrrolidines Journal of the American Chemical Society. 103: 3148-3160. DOI: 10.1021/Ja00401A037  0.318
1981 Stavinoha JL, Mariano PS. Electron-transfer photochemistry of iminium salts. Olefin photoadditions to 2-phenyl-1-pyrrolinium perchlorate Journal of the American Chemical Society. 103: 3136-3148. DOI: 10.1021/Ja00401A036  0.336
1981 Mariano PS, Stavinoha J, Bay E. Photochemistry of iminium salts Tetrahedron. 37: 3385-3395. DOI: 10.1016/S0040-4020(01)92387-7  0.327
1981 Leone AA, Mariano PS. The photochemistry of 3-heteroatom substituted 1,4-dienes Reviews of Chemical Intermediates. 4: 81-119. DOI: 10.1007/Bf03052413  0.377
1980 Mariano PS, Bay E. Substituent control of cyclopropylcarbinyl radical ring opening reactions Journal of Organic Chemistry. 45: 1763-1769. DOI: 10.1021/Jo01298A005  0.41
1980 Stavinoha J, Bay E, Leone A, Mariano PS. Photochemistry of iminium salts in the presence of N-electron donating alcohols and ethers Tetrahedron Letters. 21: 3455-3458. DOI: 10.1016/S0040-4039(00)78713-2  0.32
1980 MARIANO PS, BAY E. ChemInform Abstract: SUBSTITUENT CONTROL OF CYCLOPROPYLCARBINYL RADICAL RING OPENING REACTIONS Chemischer Informationsdienst. 11. DOI: 10.1002/Chin.198042086  0.419
1979 Mariano PS, Dunaway-Mariano D, Huesmann PL. Amino-Claisen rearrangements of N-vinylisoquinuclidenes in novel approaches to the synthesis of hydroisoquinolines and hydrophenanthridines Journal of Organic Chemistry. 44: 124-133. DOI: 10.1021/Jo01315A028  0.367
1979 Mariano PS, Leone AA. Excited-State Chemistry Of 1-Alkenyl-2-Pyridones. Exploratory And Mechanistic Investigations And Kinetic Analysis Of Photocyclization Reactions Involving Conversion Of The N-Vinylamide To Oxazolium Ylide Function Journal of the American Chemical Society. 101: 3607-3617. DOI: 10.1021/Ja00507A029  0.403
1979 MARIANO PS, STAVINOHA JL, PEPE G, MEYER EFJ. ChemInform Abstract: NOVEL PHOTOCHEMICAL ADDITION REACTIONS OF IMINIUM SALTS. ELECTRON TRANSFER INITIATED ADDITIONS OF OLEFINS TO 2-PHENYL-1-PYRROLINIUM PERCHLORATE Chemischer Informationsdienst. 10. DOI: 10.1002/chin.197905097  0.347
1978 Mariano PS, Glover GI, Petersen JR. Evidence for a pH-dependent irreversible formation of a stable conformation of phenacyl-alpha-chymotrypsin. The Biochemical Journal. 171: 115-22. PMID 25656 DOI: 10.1042/Bj1710115  0.34
1978 Glover GI, Mariano PS, Hildreth RA. AFFINITY-CONTROLLED TRIPLET ENERGY TRANSFER FROM p-BENZOYLBENZYL-BOVINE SERUM ALBUMIN TO LOW MOLECULAR WEIGHT QUENCHERS Photochemistry and Photobiology. 28: 7-21. DOI: 10.1111/J.1751-1097.1978.Tb06924.X  0.354
1978 Mariano PS, Leone AA. Kinetic analysis and solvent polarity effects on the ylide-forming photocyclization reaction of 1-vinyl-2-pyridones Journal of the American Chemical Society. 100: 3947-3949. DOI: 10.1021/Ja00480A059  0.356
1978 Mariano PS, Huesmann PL, Beamer RL, Dunaway-Mariano D. The diels-alder chemistry of 1-vinyl-2-pyridones Tetrahedron. 34: 2617-2626. DOI: 10.1016/0040-4020(78)88396-3  0.443
1978 Mariano PS, Krochmal E, Beamer R, Huesmann PL, Dunaway-Mariano D. General synthetic methods for the preparation of 1-substituted-vinyl-2-pyridones Tetrahedron. 34: 2609-2616. DOI: 10.1016/0040-4020(78)88395-1  0.421
1978 Mariano PS, Stavinoha JL, Pèpe G, Meyer EF. Novel photochemical addition reactions of iminium salts. Electron transfer initiated additions of olefins to 2-phenyl-1-pyrrolinium perchlorate [32] Journal of the American Chemical Society. 100: 7114-7116. DOI: 10.1002/Chin.197905097  0.446
1978 MARIANO PS, LEONE AA. ChemInform Abstract: KINETIC ANALYSIS AND SOLVENT POLARITY EFFECTS ON THE YLIDE-FORMING PHOTOCYCLIZATION REACTION OF 1-VINYL-2-PYRIDONES Chemischer Informationsdienst. 9. DOI: 10.1002/Chin.197837132  0.364
1977 Mariano PS, Osborn ME, Dunaway-Mariano D, Gunn BC, Pettersen RC. The chemistry of azocines. Intermediates for the synthesis of pyrrolizidines Journal of Organic Chemistry. 42: 2903-2910. DOI: 10.1021/Jo00437A027  0.441
1977 Mariano PS, Stavinoha JL, Swanson R. Photochemistry of N-allyliminium salts. A novel photocyclization reaction leading to pyrrolidines Journal of the American Chemical Society. 99: 6781-6782. DOI: 10.1021/Ja00462A063  0.403
1977 Mariano PS, Leone AA, Krochmal E. Novel photocyclization reactions of 1-vinyl-2-pyridones leading to oxazolo[3,2-a]pyridinium salts. Tetrahedron Letters. 18: 2227-2229. DOI: 10.1016/S0040-4039(01)83727-8  0.413
1977 Mariano PS, Watson DG, Bay E. The di-π-methane rearrangement : The effect of 1,4-diene structure and conformation on the reaction efficiency and stereochemistry Tetrahedron. 33: 11-17. DOI: 10.1016/0040-4020(77)80425-0  0.354
1977 MARIANO PS, LEONE AA, KROCHMAL EJ. ChemInform Abstract: NOVEL PHOTOCYCLIZATION REACTIONS OF 1-VINYL-2-PYRIDONES LEADING TO OXAZOLO(3,2-A)PYRIDINIUM SALTS Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/chin.197746241  0.31
1976 Glover GI, Mariano PS, Petersen JR. Reinvestigation of the Phenacyl Bromide Modification of α-Chymotrypsin Biochemistry. 15: 3754-3760. PMID 8093 DOI: 10.1021/Bi00662A018  0.351
1975 Mariano PS, Osborn ME, Krochmal E. Reaction of N-styryl-1,2-dihydropyridine with dimethyl acettylenedicarboxylate. Preparation of an N-vinyldihydroazocine. Tetrahedron Letters. 16: 2741-2744. DOI: 10.1016/S0040-4039(00)75228-2  0.356
1974 Mariano PS, Peters M. Novel reactions in the preparation of alkylidene-2,3-dihydrofurans Tetrahedron Letters. 15: 2607-2610. DOI: 10.1016/S0040-4039(01)92305-6  0.406
1974 MARIANO PS, KO J. ChemInform Abstract: THE DI-PI-METHANE REARRANGEMENT, STEREOCHEMISTRY Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/Chin.197411160  0.32
1974 HIXSON SS, MARIANO PS, ZIMMERMAN HE. ChemInform Abstract: THE DI-PI-METHANE AND OXA-DI-PI-METHANE REARRANGEMENTS Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/chin.197402118  0.431
1973 Mariano PS, Ko J. Di-.pi.-methane rearrangement. Stereochemistry Journal of the American Chemical Society. 95: 8670-8678. DOI: 10.1021/Ja00807A028  0.311
1973 Hixson SS, Mariano PS, Zimmerman HE. Di-.pi.-methane and oxa-di-.pi.-methane rearrangements Chemical Reviews. 73: 531-551. DOI: 10.1021/Cr60285A005  0.48
1971 Wasserman HH, Mariano PS, Keehn PM. Photooxidation of hexamethylbenzene and related aromatic systems The Journal of Organic Chemistry. 36: 1765-1769. DOI: 10.1021/Jo00812A009  0.466
1971 WASSERMAN HH, MARIANO PS, KEEHN PM. ChemInform Abstract: PHOTOOX. VON HEXAMETHYLBENZOL UND AEHNLICHEN AROMATISCHEN VERBINDUNGEN Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197140213  0.472
1969 Zimmerman HE, Mariano PS. Mechanistic and exploratory organic photochemistry. XLI. Di-.pi.-methane rearrangement. Interaction of electronically excited vinyl chromophores Journal of the American Chemical Society. 91: 1718-1727. DOI: 10.1021/Ja01035A021  0.491
1968 Zimmerman HE, Mariano PS. The stereochemistry of protonation. XI Journal of the American Chemical Society. 90: 6091-6096. DOI: 10.1021/Ja01024A028  0.463
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