Stephen A. Koch - Publications

Affiliations: 
Chemistry Stony Brook University, Stony Brook, NY, United States 
Area:
Inorganic Chemistry, Biochemistry
Website:
https://www.stonybrook.edu/commcms/chemistry/faculty/koch.stephen.html

61 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2009 Jiang J, Maruani M, Solaimanzadeh J, Lo W, Koch SA, Millar M. Synthesis and structure of analogues for the Ni-Fe site in hydrogenase enzymes. Inorganic Chemistry. 48: 6359-61. PMID 20507106 DOI: 10.1021/Ic900929U  0.355
2007 Chang S, Koch SA. [FeIII(SR)4]1- complexes can be synthesized by the direct reaction of thiolates with FeCl3. Journal of Inorganic Biochemistry. 101: 1758-9. PMID 17723243 DOI: 10.1016/J.Jinorgbio.2007.07.004  0.378
2007 Conradie J, Quarless DA, Hsu HF, Harrop TC, Lippard SJ, Koch SA, Ghosh A. Electronic structure and FeNO conformation of nonheme iron-thiolate-NO complexes: an experimental and DFT study. Journal of the American Chemical Society. 129: 10446-56. PMID 17685516 DOI: 10.1021/Ja0719982  0.518
2006 Chiarella GM, Melgarejo DY, Koch SA. Further study of the reaction of Fe2+ with CN-: synthesis and characterization of cis and trans [FeII,III(CN)4L2]n- complexes. Journal of the American Chemical Society. 128: 1416-7. PMID 16448089 DOI: 10.1021/Ja0571951  0.346
2006 Pastor S, Rahni D, Khoury N, Koch S. The conformation of sterically congested seven-membered rings containing tetracoordinate germanium(IV): A first X-ray crystallographic structure determination Phosphorus, Sulfur and Silicon and the Related Elements. 181: 1951-1956. DOI: 10.1080/10426500500544139  0.3
2002 Jiang J, Koch SA. fac-[Fe(II)(CN)(3)(CO)(3)](-) and cis-[Fe(II)(CN)(4)(CO)(2)](2)(-): new members of the class of [Fe(II)(CN)(x)(CO)(y)] compounds. Inorganic Chemistry. 41: 158-60. PMID 11800601 DOI: 10.1021/Ic015604Y  0.376
2001 Jiang J, Koch SA. trans-[Fe(CN) (CO) ] , a 21st Century [Fe(CN)(CO)] Compound. Angewandte Chemie (International Ed. in English). 40: 2629-2631. PMID 29712327 DOI: 10.1002/1521-3773(20010716)40:14<2629::Aid-Anie2629>3.0.Co;2-Y  0.382
1998 Hwang JW, Govindaswamy K, Koch SA. The coordination chemistry of amine triphenolate tripod ligands with iron(III). Old organic compounds but new tripod ligands Chemical Communications. 1667-1668. DOI: 10.1039/A802725K  0.396
1998 Clark-Baldwin K, Tierney DL, Govindaswamy N, Gruff ES, Kim C, Berg J, Koch SA, Penner-Hahn JE. The limitations of X-ray absorption spectroscopy for determining the structure of zinc sites in proteins. When is a tetrathiolate not a tetrathiolate? Journal of the American Chemical Society. 120: 8401-8409. DOI: 10.1021/Ja980580O  0.549
1998 Motekaitis RJ, Martell AE, Koch SA, Hwang J, Quarless DA, Welch MJ. The Gallium(III) and Indium (III) Complexes of Tris(2-mercaptobenzyl)amine and Tris(2-hydroxybenzyl)amine Inorganic Chemistry. 37: 5902-5911. DOI: 10.1021/Ic980227J  0.323
1998 Bastos CM, Lee KS, Kjelsberg MA, Mayr A, Engen DV, Koch SA, Franolic JD, Klooster WT, Koetzle TF. Protonation of Fischer-type alkylidyne carbonyltungsten complexes. Structural comparison of alkylidyne and alkylidene metal complexes, including a neutron diffraction study of [W(CHCH3)Cl2(CO)(PMe3)2] Inorganica Chimica Acta. 279: 7-23. DOI: 10.1016/S0020-1693(98)00004-8  0.352
1997 Pastor SD, Huang V, NabiRahni D, Koch SA, Hsu HF. A Neutral Spirocyclic Hexacoordinated Germanium(IV) Complex: Hypervalent Germanium Compounds with Sulfur-Containing Eight-Membered Rings. Inorganic Chemistry. 36: 5966-5968. PMID 11670224 DOI: 10.1021/Ic9710263  0.371
1997 Hsu HF, Koch SA. Chemistry of iron thiolate complexes with CN- and CO. Models for the [Fe(CO)(CN)2 structural unit in Ni-Fe hydrogenase enzymes Journal of the American Chemical Society. 119: 8371-8372. DOI: 10.1021/Ja971139L  0.367
1996 Nguyen DH, Hsu HF, Millar M, Koch SA, Achim C, Bominaar EL, Münck E. Nickel(II) thiolate complex with carbon monoxide and its Fe(II) analog: Synthetic models for CO adducts of nickel-iron-containing enzymes Journal of the American Chemical Society. 118: 8963-8964. DOI: 10.1021/Ja961968R  0.583
1996 Millar M, Lee JF, O'Sullivan T, Koch SA, Fikar R. Models for the iron-sulfur protein rubredoxin: the use of sterically hindered thiolate ligands to stabilize [Fe(SR)4]1− complexes; some considerations of the structure of the [Fe(S-Cys)4] centers in oxidized rubredoxins Inorganica Chimica Acta. 243: 333-343. DOI: 10.1016/0020-1693(96)04924-9  0.398
1995 Govindaswamy N, Quarless DA, Koch SA. New amine trithiolate tripod ligand and its iron(II) and iron(III) complexes Journal of the American Chemical Society. 117: 8468-8469. DOI: 10.1021/Ja00137A024  0.378
1995 Franolic JD, Millar M, Koch SA. Synthesis, structure, and properties of a binuclear iron-thiolate complex with a trans-disulfur bridge: A structural isomer of the [Fe2S2] core of 2-Fe ferredoxins Inorganic Chemistry. 34: 1981-1982. DOI: 10.1021/Ic00112A005  0.396
1995 Corwin DT, Corning JF, Koch SA, Millar M. Synthesis and structure of titanium tetrathiolate and tantalum pentathiolate complexes. Metal-sulfur bonding in early transition metal compounds Inorganica Chimica Acta. 229: 335-342. DOI: 10.1016/0020-1693(94)04263-U  0.373
1994 Czernuszewicz RS, Kilpatrick LK, Koch SA, Spiro TG. Resonance Raman Spectroscopy of Iron(III) Tetrathiolate Complexes: Implications for the Conformation and Force Field of Rubredoxin Journal of the American Chemical Society. 116: 7134-7141. DOI: 10.1021/Ja00095A017  0.313
1993 Silver A, Koch SA, Millar M. X-ray crystal structures of a series of [MII(SR)4]2- complexes (MMn, Fe, Co, Ni, Zn, Cd and Hg) with S4 crystallographic symmetry Inorganica Chimica Acta. 205: 9-14. DOI: 10.1016/S0020-1693(00)87348-X  0.359
1992 Govindaswamy N, Moy J, Millar M, Koch SA. A distorted mercury [Hg(SR)4]2- complex with alkanethiolate ligands: the fictile coordination sphere of monomeric [Hg(SR)x] complexes Inorganic Chemistry. 31: 5343-5344. DOI: 10.1021/Ic00052A001  0.362
1992 Maelia LE, Millar M, Koch SA. General synthesis of iron(III) tetrathiolate complexes. Structural and spectroscopic models for the [Fe(Cys-S)4] center in oxidized rubredoxin Inorganic Chemistry. 31: 4594-4600. DOI: 10.1021/Ic00048A029  0.389
1991 Santos RA, Gruff ES, Koch SA, Harbison GS. Solid-state mercury-199 and cadmium-113 NMR studies of mercury- and cadmium-thiolate complexes. Spectroscopic models for [Hg(SCys)n] centers in the bacterial mercury resistance proteins Journal of the American Chemical Society. 113: 469-475. DOI: 10.1021/Ja00002A014  0.303
1990 Santos RA, Gruff ES, Koch SA, Harbison GS. Single-crystal, solid-state, and solution cadmium-113 NMR studies of [Cd(SR)2(N-donor)2] complexes. Structural and spectroscopic analog for biologically occurring [M(S-Cys)2(His)2] centers Journal of the American Chemical Society. 112: 9257-9263. DOI: 10.1021/Ja00181A031  0.306
1990 Gebhard MS, Deaton JC, Koch SA, Millar M, Solomon EI. Single-crystal spectral studies of Fe(SR)4- [R = 2,3,5,6-(Me)4C6H]: The electronic structure of the ferric tetrathiolate active site Journal of the American Chemical Society. 112: 2217-2231. DOI: 10.1021/Ja00162A023  0.363
1990 Gruff ES, Koch SA. Trigonal-planar [M(SR)3]1- complexes of cadmium and mercury. Structural similarities between mercury-cysteine and cadmium-cysteine coordination centers Journal of the American Chemical Society. 112: 1245-1247. DOI: 10.1021/Ja00159A054  0.359
1989 Gruff ES, Koch SA. A trigonal planar [Zn(SR)3]1- complex. A possible new coordination mode for zinc-cysteine centers Journal of the American Chemical Society. 111: 8762-8763. DOI: 10.1021/Ja00205A052  0.308
1988 Deaton JC, Gebhard MS, Koch SA, Millar M, Solomon EI. Ligand field transitions and the origin of zero field splitting in [PPh4][FeCl4] and [NEt4][Fe(SR)4] (R = 2,3,5,6-Me4C6H): a model for the high-spin Fe(III) site in rubredoxin. Journal of the American Chemical Society. 110: 6241-3. PMID 22148807 DOI: 10.1021/Ja00226A047  0.306
1988 Corwin DT, Koch SA. Crystal structures of Zn(SR)2 complexes: Structural models for the proposed [Zn(cys-S)2(his)2] center in transcription factor IIIA and related nucleic acid binding proteins Inorganic Chemistry. 27: 493-496. DOI: 10.1021/Ic00276A011  0.331
1988 Corwin DT, Gruff ES, Koch SA. Zinc, cobalt and cadmium thiolate complexes: Models for the Zn(S-cys)3(his) center in the gene 32 protein Inorganica Chimica Acta. 151: 5-6. DOI: 10.1016/S0020-1693(00)83473-8  0.308
1987 Corwin DT, Gruff ES, Koch SA. Zinc, cobalt, and cadmium thiolate complexes: Models for the zinc (S-cys)2(his)2 centre in transcription factor IIIA (cys = cysteine; his = histidine) Journal of the Chemical Society, Chemical Communications. 966-967. DOI: 10.1039/C39870000966  0.339
1987 Corwin DT, Fikar R, Koch SA. Four- and five-coordinate cobalt(II) thiolate complexes: Models for the catalytic site of alcohol dehydrogenase [1] Inorganic Chemistry. 26: 3079-3080. DOI: 10.1021/Ic00266A001  0.307
1986 Maelia LE, Koch SA. Gallium analogues of iron-sulfide-thiolate compounds. Analysis of the structural parameters in gallium(III) and iron(III) chalcogenide compounds Inorganic Chemistry. 25: 1896-1904. DOI: 10.1021/Ic00231A037  0.394
1986 Lincoln S, Koch SA. Synthesis, structure, and interconversion of polypyrazolylborate complexes of molybdenum(V) Inorganic Chemistry. 25: 1594-1602. DOI: 10.1002/Chin.198637261  0.322
1985 Fikar R, Koch SA, Millar MM. A square-planar cobalt(III) tetrathiolate complex Inorganic Chemistry. 24: 3311-3312. DOI: 10.1021/Ic00215A001  0.377
1985 Lincoln S, Soong SL, Koch SA, Sato M, Enemark JH. Polypyrazolylborate complexes containing the [MoSMo]2+ and [MoSeMo]2+ units Inorganic Chemistry. 24: 1355-1359. DOI: 10.1021/Ic00203A018  0.336
1985 LINCOLN S, SOONG S, KOCH SA, SATO M, ENEMARK JH. ChemInform Abstract: POLYPYRAZOLYLBORATE COMPLEXES CONTAINING THE (MOSMO)2+ AND (MOSEMO)2+ UNITS Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198536267  0.302
1984 Millar M, Koch SA, Fikar R. The reactions of Fe(III) with sterically hindered thiolate ligands Inorganica Chimica Acta. 88. DOI: 10.1016/S0020-1693(00)83582-3  0.352
1984 Koch SA, Fikar R, Millar M, O'Sullivan T. Steric control of metal-thiolate coordination: Synthesis and structure of monomeric cobalt(II) and copper(I) thiolate complexes [1] Inorganic Chemistry. 23: 121-122. DOI: 10.1002/Chin.198417318  0.391
1983 Koch SA, Maelia LE, Millar M. Syntheses and structures of the tetrakis(benzenethiolato)ferrate(1-) ([FeIII(SPh)4]-) and tetrakis(ethanethiolato)ferrate(1-) ([FeIII(SEt)4]-) anions. A general route to iron(III) tetrathiolate complexes Journal of the American Chemical Society. 105: 5944-5945. DOI: 10.1021/Ja00356A053  0.334
1982 Koch SA, Millar M. Iron(III) phenoxide complexes: Models for iron(III)-tyrosine coordination Journal of the American Chemical Society. 104: 5255-5257. DOI: 10.1021/Ja00383A057  0.363
1982 Millar M, Lincoln S, Koch SA. Stable monomeric complexes of molybdenum(III) and tungsten(III) Journal of the American Chemical Society. 104: 288-289. DOI: 10.1021/Ja00365A052  0.368
1982 Millar M, Lee JF, Koch SA, Fikar R. Synthetic models for the iron-sulfur protein rubredoxin: Synthesis, structure, and properties of a highly symmetric iron(III) tetrathiolate anion [1] Inorganic Chemistry. 21: 4105-4106. DOI: 10.1021/Ic00141A048  0.342
1978 Cotton FA, Koch SA, Schultz AJ, Williams JM. Preparation and structures of the homologous quadruply bonded tris(cyclooctatetraene)dimolybdenum and -ditungsten Inorganic Chemistry. 17: 2093-2098. DOI: 10.1021/Ic50186A012  0.49
1978 Cotton FA, Koch SA, Millar M. Dichromium and dimolybdenum compounds of 2,6-dimethoxyphenyl and 2,4,6-trimethoxyphenyl ligands Inorganic Chemistry. 17: 2087-2093. DOI: 10.1021/Ic50186A011  0.335
1978 Cotton FA, Koch SA, Millar M. Tetrakis(2-methoxy-5-methylphenyl)dichromium Inorganic Chemistry. 17: 2084-2086. DOI: 10.1021/Ic50186A010  0.48
1978 Cotton FA, Koch S. Rational preparation and structural study of a dichromium o-oxophenyl compound: the shortest metal-to-metal bond yet observed Inorganic Chemistry. 17: 2021-2024. DOI: 10.1021/Ic50185A067  0.502
1978 Collins DM, Cotton FA, Koch SA, Millar M, Murillo CA. X-ray crystallographic structural studies of the quadruply bonded octamethylditungsten anion and a related species containing a mixture of chloro and methyl ligands Inorganic Chemistry. 17: 2017-2020. DOI: 10.1021/Ic50185A066  0.505
1978 COLLINS DM, COTTON FA, KOCH SA, MILLAR M, MURILLO CA. ChemInform Abstract: X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDIES OF THE QUADRUPLY BONDED OCTAMETHYLDITUNGSTEN ANION AND A RELATED SPECIES CONTAINING A MIXTURE OF CHLORO AND METHYL LIGANDS Chemischer Informationsdienst. 9. DOI: 10.1002/Chin.197841076  0.449
1977 Cotton FA, Koch S, Millar M. Exceedingly short metal-to-metal multiple bonds Journal of the American Chemical Society. 99: 7372-7374. DOI: 10.1021/Ja00464A056  0.465
1977 Cotton FA, Koch SA. A quadruple bond between tungsten atoms in an air-stable compound Journal of the American Chemical Society. 99: 7371-7372. DOI: 10.1021/Ja00464A055  0.477
1977 Cotton FA, Koch S, Mertis K, Millar M, Wilkinson G. Preparation and characterization of compounds containing the octamethylditungsten(II) anion and partially chlorinated analogs Journal of the American Chemical Society. 99: 4989-4992. DOI: 10.1021/Ja00457A016  0.592
1977 Collins DM, Cotton FA, Koch S, Millar M, Murillo CA. Crystallographic proof of the stability of a quadruple bond between tungsten atoms Journal of the American Chemical Society. 99: 1259-1261. DOI: 10.1021/Ja00446A045  0.458
1977 Cotton FA, Koch S, Mertis K, Millar M, Wilkinson G. Preparation and characterization of compounds containing the octamethylditungsten(II) anion and partially chlorinated analogs Cheminform. 8. DOI: 10.1002/Chin.197744303  0.502
1977 COLLINS DM, COTTON FA, KOCH S, MILLAR M, MURILLO CA. ChemInform Abstract: CRYSTALLOGRAPHIC PROOF OF THE STABILITY OF A QUADRUPLE BOND BETWEEN TUNGSTEN ATOMS Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/Chin.197719293  0.399
1975 Koch S, Holm RH, Frankel RB. Synthesis and ground state electronic properties of tetraaza macrocyclic iron(II, III) complexes containing [14]-, [15]-, and [16]-membered rings Journal of the American Chemical Society. 97: 6714-6723. DOI: 10.1021/Ja00856A020  0.608
1975 Koch S, Tang SC, Holm RH, Frankel RB. [FeIIIN4SR] coordination unit. Synthesis and ground state electronic properties of macrocyclic ferric thilates Journal of the American Chemical Society. 97: 914-916. DOI: 10.1021/Ja00837A051  0.544
1975 KOCH S, TANG SC, HOLM RH, FRANKEL RB, IBERS JA. ChemInform Abstract: FERRIC PORPHYRIN THIOLATES, POSSIBLE RELATIONSHIP TO CYTOCHROME P-450 ENZYMES AND THE STRUCTURE OF (P-NITROBENZENETHIOLATO)IRON(III) PROTOPORPHYRIN IX DIMETHYL ESTER Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/Chin.197518394  0.55
1975 KOCH S, TANG SC, HOLM RH, FRANKEL RB. ChemInform Abstract: THE (FE(III)N4SR) COORDINATION UNIT, SYNTHESIS AND GROUND STATE ELECTRONIC PROPERTIES OF MACROCYCLIC FERRIC THIOLATES Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/chin.197518393  0.549
1974 TANG SC, KOCH S, WEINSTEIN GN, LANE RW, HOLM RH. ChemInform Abstract: SYNTHETIC APPROACHES TO 14-, 15-, AND 16-MEMBERED TETRAAZA MACROCYCLES AND THEIR METAL COMPLEXES Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/chin.197402329  0.523
1973 Tang SC, Koch S, Weinstein GN, Lane RW, Holm RH. Synthetic approaches to 14-, 15-, and 16-membered tetraaza macrocycles and their metal complexes Inorganic Chemistry. 12: 2589-2595. DOI: 10.1021/Ic50129A020  0.519
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