| Year |
Citation |
Score |
| 2013 |
Spahn E, Albright A, Shevlin M, Pauli L, Pfaltz A, Gawley RE. Double-asymmetric hydrogenation strategy for the reduction of 1,1-diaryl olefins applied to an improved synthesis of CuIPhEt, a C2-symmetric N-heterocyclic carbenoid Journal of Organic Chemistry. 78: 2731-2735. PMID 23383707 DOI: 10.1021/Jo3026548 |
0.351 |
|
| 2012 |
Beng TK, Tyree WS, Parker T, Su C, Williard PG, Gawley RE. Dynamics of catalytic resolution of 2-lithio-N-Boc-piperidine by ligand exchange. Journal of the American Chemical Society. 134: 16845-55. PMID 22967289 DOI: 10.1021/Ja307796E |
0.693 |
|
| 2012 |
Beng TK, Woo JS, Gawley RE. Synthetic applications and inversion dynamics of configurationally stable 2-lithio-2-arylpyrrolidines and -piperidines. Journal of the American Chemical Society. 134: 14764-71. PMID 22881214 DOI: 10.1021/Ja306276W |
0.727 |
|
| 2012 |
Beng TK, Gawley RE. CATALYTIC DYNAMIC RESOLUTION APPLIED TO THE SYNTHESIS OF 2,6-DISUBSTITUTED PIPERIDINES: PREPARATION OF (+)-LUPETIDINE AND (-)-EPIDIHYDROPINIDINE. Heterocycles. 84: 697-718. PMID 22408286 DOI: 10.3987/Com-11-S(P)45 |
0.724 |
|
| 2011 |
Albright A, Gawley RE. Application of a C2-symmetric copper carbenoid in the enantioselective hydrosilylation of dialkyl and aryl-alkyl ketones. Journal of the American Chemical Society. 133: 19680-3. PMID 22074559 DOI: 10.1021/Ja209187A |
0.383 |
|
| 2011 |
Gawley RE, Smith GA. Formal synthesis of the bisbenzylisoquinoline alkaloid berbamunine by asymmetric substitution of chiral organolithium compounds. Arkivoc : Free Online Journal of Organic Chemistry / Arkat-Usa, Inc. 2011: 167-179. PMID 22003473 |
0.308 |
|
| 2011 |
Albright A, Eddings D, Black R, Welch CJ, Gerasimchuk NN, Gawley RE. Design and synthesis of C2-symmetric N-heterocyclic carbene precursors and metal carbenoids. The Journal of Organic Chemistry. 76: 7341-51. PMID 21823580 DOI: 10.1021/Jo2012434 |
0.388 |
|
| 2011 |
Beng TK, Gawley RE. Application of catalytic dynamic resolution of N-Boc-2-lithiopiperidine to the asymmetric synthesis of 2-aryl and 2-vinyl piperidines. Organic Letters. 13: 394-7. PMID 21174392 DOI: 10.1021/Ol102682R |
0.742 |
|
| 2010 |
Beng TK, Gawley RE. Highly enantioselective catalytic dynamic resolution of N-Boc-2-lithiopiperidine: synthesis of (R)-(+)-N-Boc-pipecolic acid, (S)-(-)-coniine, (S)-(+)-pelletierine, (+)-beta-conhydrine, and (S)-(-)-ropivacaine and formal synthesis of (-)-lasubine II and (+)-cermizine C. Journal of the American Chemical Society. 132: 12216-7. PMID 20806976 DOI: 10.1021/Ja105772Z |
0.717 |
|
| 2009 |
Coldham I, Leonori D, Beng TK, Gawley RE. The barrier to enantiomerization and dynamic resolution of N-Boc-2-lithiopiperidine and the effect of TMEDA. Chemical Communications (Cambridge, England). 5239-41. PMID 19707632 DOI: 10.1039/B911024K |
0.733 |
|
| 2009 |
Beng TK, Yousaf TI, Coldham I, Gawley RE. Enantiomerization dynamics and a catalytic dynamic resolution of N-trimethylallyl-2-lithiopyrrolidine. Journal of the American Chemical Society. 131: 6908-9. PMID 19405472 DOI: 10.1021/Ja900755A |
0.725 |
|
| 2007 |
Gawley RE, Moon K. Stereoselective [2,3]-sigmatropic rearrangements of unstabilized nitrogen ylides. Organic Letters. 9: 3093-6. PMID 17628071 DOI: 10.1021/Ol071188V |
0.376 |
|
| 2007 |
Klein R, Gawley RE. Configurational and conformational effects on tin-lithium exchange in alpha-aminoorganostannanes by rapid-injection NMR. Journal of the American Chemical Society. 129: 4126-7. PMID 17362012 DOI: 10.1021/Ja0692377 |
0.755 |
|
| 2005 |
Gawley RE, Narayan S. Stannyl cyclopropanes by diastereoselective cyclopropanations with (tributylstannyl)-diazoacetate esters catalyzed by Cu(I) N-heterocyclic carbene. Chemical Communications (Cambridge, England). 5109-11. PMID 16220187 DOI: 10.1039/B509958G |
0.386 |
|
| 2005 |
Madan S, Milano P, Eddings DB, Gawley RE. Conversion of five-, six-, and seven-membered lactams to racemic or scalemic 2-substituted heterocycles by amidoalkylation. The Journal of Organic Chemistry. 70: 3066-71. PMID 15822965 DOI: 10.1021/Jo048484V |
0.414 |
|
| 2005 |
Ashweek NJ, Brandt P, Coldham I, Dufour S, Gawley RE, Haeffner F, Klein R, Sanchez-Jimenez G. Barrier to enantiomerization of unstabilized, chelated, and dipole-stabilized 2-lithiopyrrolidines. Journal of the American Chemical Society. 127: 449-57. PMID 15631496 DOI: 10.1021/Ja048090L |
0.747 |
|
| 2005 |
Gawley RE, Klein R, Ashweek NJ, Coldham I. Structural studies of {6Li} 2-lithiopyrrolidines using NMR spectroscopy Tetrahedron. 61: 3271-3280. DOI: 10.1016/J.Tet.2005.01.098 |
0.429 |
|
| 2004 |
Gawley RE, Barolli G, Madan S, Saverin M, O'Connor S. Nucleophilic synthesis of enantiopure 2-(tributylstannyl)pyrrolidines and piperidines Tetrahedron Letters. 45: 1759-1761. DOI: 10.1016/J.Tetlet.2003.12.080 |
0.405 |
|
| 2004 |
Narayan S, Seelhammer T, Gawley RE. Microwave assisted solvent free amination of halo-(pyridine or pyrimidine) without transition metal catalyst Tetrahedron Letters. 45: 757-759. DOI: 10.1016/J.Tetlet.2003.11.030 |
0.32 |
|
| 2004 |
Gawley RE. The Beckmann Reactions: Rearrangements, Elimination–Additions, Fragmentations, and Rearrangement–Cyclizations Organic Reactions. DOI: 10.1002/0471264180.Or035.01 |
0.314 |
|
| 2003 |
Santiago M, Low E, Chambournier G, Gawley RE. Modeling and experiment reveal an unexpected stereoelectronic effect on conformation and scalar couplings of alpha-aminoorganostannanes, with possible relevance to the tin-lithium exchange reaction. The Journal of Organic Chemistry. 68: 8480-4. PMID 14575474 DOI: 10.1021/Jo034948Y |
0.383 |
|
| 2002 |
Haeffner F, Brandt P, Gawley RE. A theoretical investigation into the inversion barrier of dipole-stabilized alpha-aminoorganolithiums. Organic Letters. 4: 2101-4. PMID 12049528 DOI: 10.1021/Ol026041C |
0.328 |
|
| 2002 |
Cardona CM, Gawley RE. An improved synthesis of a trifurcated newkome-type monomer and orthogonally protected two-generation dendrons. The Journal of Organic Chemistry. 67: 1411-3. PMID 11846699 DOI: 10.1021/Jo0161678 |
0.367 |
|
| 2002 |
Gawley RE, Campagna SA, Santiago M, Ren T. Lithiated camphor-derived oxazolidinone S,N-acetals as chiral formyl anion synthons in additions to aldehydes. Asymmetric synthesis of α-hydroxy aldehydes and α-hydroxy acids Tetrahedron Asymmetry. 13: 29-36. DOI: 10.1016/S0957-4166(02)00043-5 |
0.406 |
|
| 2001 |
Gaul C, Arvidsson PI, Bauer W, Gawley RE, Seebach D. Computational, ReactIR-, and NMR-spectroscopic investigations on the chiral formyl anion equivalent N-(alpha-lithiomethylthiomethyl)-4-isopropyl-5,5-diphenyloxazolidin-2-one and related compounds. Chemistry (Weinheim An Der Bergstrasse, Germany). 7: 4117-25. PMID 11686589 DOI: 10.1002/1521-3765(20011001)7:19<4117::Aid-Chem4117>3.0.Co;2-I |
0.337 |
|
| 2000 |
Iula DM, Gawley RE. Synthesis and reactivity of dipole-stabilized but unchelated alpha-aminoorganolithiums. The Journal of Organic Chemistry. 65: 6196-201. PMID 10987959 DOI: 10.1021/Jo000786J |
0.343 |
|
| 2000 |
Chambournier G, Gawley RE. Synthesis and Reactivity of Conformationally Locked α-Aminoorganostannanes and α-Aminoorganolithiums. Discovery of a Surprising Configurational Requirement for Transmetalation Organic Letters. 2: 1561-1564. PMID 10841479 DOI: 10.1021/Ol005770U |
0.362 |
|
| 2000 |
Low E, Gawley RE. Solution structure of unstabilized cyclic α-aminoorganolithiums by 13C, 15N, and 6Li NMR spectroscopy [13] Journal of the American Chemical Society. 122: 9562-9563. DOI: 10.1021/Ja002308W |
0.345 |
|
| 2000 |
Gawley RE, Zhang Q, McPhail AT. 2-Lithio-N-BOC-thiazolidines as chiral acyl anion synthons: Evaluation of facial stereoselectivity in the addition of chiral organolithiums to aldehydes Tetrahedron Asymmetry. 11: 2093-2106. DOI: 10.1016/S0957-4166(00)00154-3 |
0.447 |
|
| 1999 |
Gawley RE, Low E, Chambournier G. Unusual conformational effect in α-aminoorganostannanes Organic Letters. 1: 653-655. PMID 10823196 DOI: 10.1021/Ol990737X |
0.371 |
|
| 1996 |
Gawley RE, Zhang P. 1-Magnesiotetrahydroisoquinolyloxazolines as Chiral Nucleophiles in Stereoselective Additions to Aldehydes: Auxiliary Optimization, Asymmetric Synthesis of (+)-Corlumine, (+)-Bicuculline, (+)-Egenine, and (+)-Corytensine, and Preliminary (13)C NMR Studies of 1-Lithio- and 1-Magnesiotetrahydroisoquinolyloxazolines. The Journal of Organic Chemistry. 61: 8103-8112. PMID 11667797 DOI: 10.1021/Jo961164U |
0.404 |
|
| 1995 |
Gawley RE, Zhang Q. Alkylation of 2-lithio-N-methylpiperidines and -pyrrolidines: Scope, limitations, and stereochemistry Journal of Organic Chemistry. 60: 5763-5769. DOI: 10.1021/Jo00123A008 |
0.373 |
|
| 1994 |
Gawley RE, Zhang Q. Search for configurationally stable, aracemic α-amino organolithiums Tetrahedron. 50: 6077-6088. DOI: 10.1016/S0040-4020(01)90459-4 |
0.359 |
|
| 1994 |
Ito YN, Ariza X, Beck AK, Boháč A, Ganter C, Gawley RE, Kühnle FNM, Tuleja J, Wang YM, Seebach D. Preparation and Structural Analysis of Several New α,α,α′,α′-Tetraaryl-1,3-dioxolane-4,5-dimethanols (TADDOL's) and TADDOL analogs, their evaluation as titanium ligands in the enantioselective addition of methyltitanium and diethylzinc reagents to benzald Helvetica Chimica Acta. 77: 2071-2110. DOI: 10.1002/Hlca.19940770802 |
0.374 |
|
| 1993 |
Gawley RE, Zhang Q. 2-Lithio-N-methylpiperidine and 2-lithio-N-methylpyrrolidine: configurationally and chemically stable unchelated .alpha.-aminoorganolithiums Journal of the American Chemical Society. 115: 7515-7516. DOI: 10.1021/Ja00069A066 |
0.369 |
|
| 1992 |
Zhang P, Gawley RE. Second-generation auxiliary for the asymmetric addition of metalated tetrahydroisoquinolines to aldehydes Tetrahedron Letters. 33: 2945-2948. DOI: 10.1016/S0040-4039(00)79567-0 |
0.338 |
|
| 1991 |
Rein KS, Gawley RE. Synthesis of the phthalide isoquinoline alkaloids (-)-egenine, (-)-corytensine, and (-)-bicuculline by asymmetric carbonyl addition of chiral dipole-stabilized organometallics Journal of Organic Chemistry. 56: 1564-1569. DOI: 10.1021/Jo00004A041 |
0.395 |
|
| 1991 |
Rein KS, Chen ZH, Perumal PT, Echegoyen L, Gawley RE. Single electron transfer in the addition of chiral dipole-stabilized organolithiums to carbonyls. Stereochemistry of a chiral nucleophile as a mechanistic probe Tetrahedron Letters. 32: 1941-1944. DOI: 10.1016/0040-4039(91)85007-R |
0.316 |
|
| 1990 |
Rein KS, Gawley RE. Synthesis of (-)-egenine (decumbensine) by asymmetric carbonyl addition Tetrahedron Letters. 31: 3711-3714. DOI: 10.1016/S0040-4039(00)97451-3 |
0.387 |
|
| 1989 |
Gawley RE, Chemburkar SR. Generation and cyclization of nitrilium ions from amides Heterocycles. 29: 1283-1292. DOI: 10.3987/Com-89-4964 |
0.313 |
|
| 1989 |
Gawley RE, Rein K, Chemburkar S. Acyclic stereoselection in the alkylation of chiral dipole-stabilized organolithiums: a self-immolative chirality transfer process for the synthesis of primary amines The Journal of Organic Chemistry. 54: 3002-3004. DOI: 10.1021/Jo00274A004 |
0.355 |
|
| 1989 |
Bartolotti LJ, Gawley RE. On the relative energies of ab initio structures of N-methylformamide anions and their lithium derivatives. An estimate of the magnitude of chelate stabilization Journal of Organic Chemistry. 54: 2980-2982. DOI: 10.1021/Jo00273A042 |
0.341 |
|
| 1989 |
Rein K, Goicoechea-Pappas M, Anklekar TV, Hart GC, Smith GA, Gawley RE. Chiral dipole-stabilized anions: experiment and theory in benzylic and allylic systems. Stereoselective deprotonations, pyramidal inversions, and stereoselective alkylations of lithiated (tetrahydroisoquinolyl)oxazolines Journal of the American Chemical Society. 111: 2211-2217. DOI: 10.1021/Ja00188A040 |
0.347 |
|
| 1989 |
Gawley RE, Rein K, Chemburkar S. Acyclic stereoselection in the alkylation of chiral dipole-stabilized organolithiums: A self-immolative chirality transfer process for the synthesis of primary amines Journal of Organic Chemistry. 54: 3002-3004. |
0.333 |
|
| 1988 |
Gawley RE, Chemburkar SR, Smith AL, Anklekar TV. (R,R)-1,3-Dibenzylisoindoline: a new C2-symmetric secondary amine, by stereoselective and regioselective .alpha.,.alpha.'-dialkylation of isoindoline, and an improved procedure for the preparation of isoindoline Journal of Organic Chemistry. 53: 5381-5383. DOI: 10.1021/Jo00257A041 |
0.338 |
|
| 1987 |
Gawley RE. Thermodynamic control in the asymmetric alkylation of the dipole-stabilized anions of chiral aminooxazolines Journal of the American Chemical Society. 109: 1265-1266. DOI: 10.1021/Ja00238A057 |
0.385 |
|
| 1986 |
Gawley RE, Hart G, Goicoechea-Pappas M, Smith AL. Oxazoline-mediated asymmetric alkylation of amines Journal of Organic Chemistry. 51: 3076-3078. DOI: 10.1021/Jo00365A049 |
0.394 |
|
| 1986 |
Gawley RE, Chemburkar S. Generation and cyclization of nitrilium ions from amides. Asymmetric synthesis of fused azabicyclics Tetrahedron Letters. 27: 2071-2074. DOI: 10.1016/S0040-4039(00)84451-2 |
0.324 |
|
| 1984 |
Gawley RE, Termine EJ. The oxime rearrangement cyclization. Synthesis of alkylidene-.DELTA.1-pyrrolines Journal of Organic Chemistry. 49: 1946-1951. DOI: 10.1021/Jo00185A022 |
0.381 |
|
| 1984 |
Gawley RE, Nagy T. Alkylation of aldehyde oxime dianions Tetrahedron Letters. 25: 263-264. DOI: 10.1016/S0040-4039(00)99856-3 |
0.37 |
|
| 1982 |
Gawley RE, Termine EJ. The oxime rearrangement cyclization. Alkenyl, styryl and vinyl chloride terminators in the synthesis of Δ1-pyrrolines Tetrahedron Letters. 23: 307-308. DOI: 10.1016/S0040-4039(00)86816-1 |
0.386 |
|
| 1981 |
Gawley RE, Termine EJ, Onan KD. Cationic cyclization reactions of 6-methylhept-5-en-2-one oxime; x-ray crystal structure of 3-isopropylidene-2-methyl-Δ<sup>1</sup>-pyrroline Journal of the Chemical Society, Chemical Communications. 568-569. DOI: 10.1039/C39810000568 |
0.329 |
|
| 1979 |
Boggs NT, Goldsmith B, Gawley RE, Koehler KA, Hiskey RG. Studies on the synthesis and resolution of .gamma.-carboxyglutamic acid derivatives The Journal of Organic Chemistry. 44: 2262-2269. DOI: 10.1021/Jo01327A048 |
0.575 |
|
| 1979 |
Boggs NT, Goldsmith B, Gawley RE, Koehler KA, Hiskey RG. Studies on the synthesis and resolution of γ-carboxyglutamic acid derivatives Journal of Organic Chemistry. 44: 2262-2269. |
0.542 |
|
| 1975 |
Boggs NT, Gawley RE, Koehler KA, Hiskey RG. Synthesis of DL-gamma-carboxyglutamic acid derivatives. The Journal of Organic Chemistry. 40: 2850-2. PMID 1177071 DOI: 10.1002/Chin.197552365 |
0.559 |
|
| 1975 |
Baldwin SW, Gawley RE, Doll RJ, Leung KH. Photoannelations with .alpha.-formyl ketones. Enol specificity in the reaction of acyclic .alpha.-formyl ketones with alkenes Journal of Organic Chemistry. 40: 1865-1867. DOI: 10.1021/Jo00900A052 |
0.624 |
|
| 1975 |
Baldwin SW, Gawley RE. Photoannelations with α-formyl ketones. A facile synthesis of the cis-9,10-dimethyldecalin ring system of the valerane sesquiterpenes Tetrahedron Letters. 16: 3969-3972. DOI: 10.1016/S0040-4039(00)91211-5 |
0.606 |
|
| 1975 |
Baldwin SW, Gawley RE, Doll RJ, Leung KH. Photoannelations with α-formyl ketones. Enol specificity in the reaction of acyclic α-formyl ketones with alkenes Journal of Organic Chemistry. 40: 1865-1867. |
0.594 |
|
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