| Year |
Citation |
Score |
| 2021 |
Fu X, Qi Q, Xu S, Negishi EI. Chemo- and Stereoselective Dearomative Coupling of Indoles and Bielectrophilic β-Imino Boronic Esters via Imine-Induced 1,2-Boronate Migration. Organic Letters. PMID 34734736 DOI: 10.1021/acs.orglett.1c03510 |
0.307 |
|
| 2018 |
Qi Q, Yang X, Fu X, Xu S, Negishi EI. Highly Enantiospecific Borylation for Chiral α-Amino Tertiary Boronic Esters. Angewandte Chemie (International Ed. in English). PMID 30291671 DOI: 10.1002/Anie.201809389 |
0.421 |
|
| 2017 |
Xu S, Wang C, Komiyama M, Tomonari Y, Negishi EI. Asymmetric Synthesis of Chiral Cyclopentanes Bearing an All-Carbon Quaternary Stereocenter via Zr-catalyzed Doubled Carboalumination. Angewandte Chemie (International Ed. in English). PMID 28726306 DOI: 10.1002/Anie.201706198 |
0.426 |
|
| 2016 |
Negishi EI, Xu S, Li H, Komiyama M, Oda A. One-step Homologation for the Catalytic Asymmetric Synthesis of Deoxypropionates. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27739117 DOI: 10.1002/Chem.201604478 |
0.472 |
|
| 2016 |
Xu S, Negishi EI. Zirconium-Catalyzed Asymmetric Carboalumination of Unactivated Terminal Alkenes. Accounts of Chemical Research. PMID 27685327 DOI: 10.1021/Acs.Accounts.6B00338 |
0.493 |
|
| 2015 |
Negishi E, Xu S. Catalytic enantioselective synthesis of chiral organic compounds of ultra-high purity of >99% ee. Proceedings of the Japan Academy. Series B, Physical and Biological Sciences. 91: 369-93. PMID 26460317 DOI: 10.2183/pjab.91.369 |
0.434 |
|
| 2015 |
Xu S, Oda A, Bobinski T, Li H, Matsueda Y, Negishi EI. Highly Efficient, Convergent, and Enantioselective Synthesis of Phthioceranic Acid. Angewandte Chemie (International Ed. in English). PMID 26088188 DOI: 10.1002/Anie.201503818 |
0.458 |
|
| 2015 |
Matsueda Y, Xu S, Negishi EI. A novel highly enantio- and diastereoselective synthesis of vitamin e side-chain Tetrahedron Letters. 56: 3346-3348. DOI: 10.1016/J.Tetlet.2014.12.081 |
0.424 |
|
| 2014 |
Xu S, Kim EH, Wei A, Negishi EI. Pd- and Ni-catalyzed cross-coupling reactions in the synthesis of organic electronic materials. Science and Technology of Advanced Materials. 15: 044201. PMID 27877696 DOI: 10.1088/1468-6996/15/4/044201 |
0.801 |
|
| 2014 |
Xu S, Oda A, Negishi E. Enantioselective synthesis of chiral isotopomers of 1-alkanols by a ZACA-Cu-catalyzed cross-coupling protocol. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 16060-4. PMID 25351794 DOI: 10.1002/Chem.201405053 |
0.484 |
|
| 2014 |
Xu S, Oda A, Kamada H, Negishi E. Highly enantioselective synthesis of γ-, δ-, and ε-chiral 1-alkanols via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA)-Cu- or Pd-catalyzed cross-coupling. Proceedings of the National Academy of Sciences of the United States of America. 111: 8368-73. PMID 24912191 DOI: 10.1073/Pnas.1401187111 |
0.528 |
|
| 2014 |
Xu S, Negishi EI. Syntheses of chiral heterocyclic compounds via zirconium-catalyzed asymmetric carboalumination of alkenes (ZACA reaction) Heterocycles. 88: 845-877. DOI: 10.3987/Rev-13-Sr(S)5 |
0.471 |
|
| 2014 |
Xu S, Kim EH, Wei A, Negishi EI. Pd- and Ni-catalyzed cross-coupling reactions in the synthesis of organic electronic materials Science and Technology of Advanced Materials. 15. DOI: 10.1088/1468-6996/15/4/044201 |
0.347 |
|
| 2014 |
Xu S, Oda A, Negishi E. Frontispiece: Enantioselective Synthesis of Chiral Isotopomers of 1‐Alkanols by a ZACA–Cu‐Catalyzed Cross‐Coupling Protocol Chemistry: a European Journal. 20. DOI: 10.1002/Chem.201484961 |
0.398 |
|
| 2013 |
Wang G, Xu S, Hu Q, Zeng F, Negishi E. Search for highly efficient, stereoselective, and practical synthesis of complex organic compounds of medicinal importance as exemplified by the synthesis of the C21-C37 fragment of amphotericin B. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 12938-42. PMID 24038187 DOI: 10.1002/Chem.201302383 |
0.721 |
|
| 2013 |
Xu S, Lee CT, Wang G, Negishi E. Widely applicable synthesis of enantiomerically pure tertiary alkyl-containing 1-alkanols by zirconium-catalyzed asymmetric carboalumination of alkenes and palladium- or copper-catalyzed cross-coupling. Chemistry, An Asian Journal. 8: 1829-35. PMID 23670801 DOI: 10.1002/Asia.201300311 |
0.704 |
|
| 2013 |
Xu S, Lee C, Wang G, Negishi E. Back Cover: Widely Applicable Synthesis of Enantiomerically Pure Tertiary Alkyl-Containing 1-Alkanols by Zirconium-Catalyzed Asymmetric Carboalumination of Alkenes and Palladium- or Copper-Catalyzed Cross-Coupling (Chem. Asian J. 8/2013) Chemistry - An Asian Journal. 8: 1602-1924. DOI: 10.1002/Asia.201390028 |
0.706 |
|
| 2012 |
Xu S, Truex NL, Mohan S, Negishi EI. Pd-catalyzed cross-coupling reactions exhibiting catalyst turnover numbers (TONs) exceeding one million Arkivoc. 2012: 242-252. DOI: 10.3998/Ark.5550190.0013.716 |
0.642 |
|
| 2011 |
Xu S, Lee CT, Rao H, Negishi EI. Highly(≥98%) Stereo- and Regioselective Trisubstituted Alkene Synthesis of Wide Applicability via 1-Halo-1-alkyne Hydroboration-Tandem Negishi-Suzuki Coupling or Organoborate Migratory Insertion Protocol. Advanced Synthesis & Catalysis. 353: 2981-2987. PMID 24072993 DOI: 10.1002/Adsc.201100420 |
0.517 |
|
| 2011 |
Wang G, Mohan S, Negishi E. Highly selective synthesis of conjugated dienoic and trienoic esters via alkyne elementometalation-Pd-catalyzed cross-coupling. Proceedings of the National Academy of Sciences of the United States of America. 108: 11344-9. PMID 21709262 DOI: 10.1073/Pnas.1105155108 |
0.747 |
|
| 2011 |
Wang G, Yin N, Negishi E. Highly stereoselective total synthesis of fully hydroxy-protected mycolactones A and B and their stereoisomerization upon deprotection. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 4118-30. PMID 21412860 DOI: 10.1002/Chem.201002627 |
0.704 |
|
| 2011 |
Negishi EI. Discovery of ZACA reaction: Zr-catalyzed asymmetric carboalumination of Alkenes Arkivoc. 2011: 34-53. DOI: 10.3998/Ark.5550190.0012.803 |
0.481 |
|
| 2010 |
Wang C, Xu Z, Tobrman T, Negishi EI. Arylethyne Bromoboration-Negishi Coupling Route to E- or Z-Aryl-Substituted Trisubstituted Alkenes of ≥98% IsomericPurity. New Horizon in the Highly Selective Synthesis of Trisubstituted Alkenes. Advanced Synthesis & Catalysis. 352: 627-631. PMID 24072992 DOI: 10.1002/Adsc.200900766 |
0.463 |
|
| 2010 |
Negishi EI, Tobrman T, Rao H, Xu S, Lee CT. Highly(≥98%) Selective Trisubstituted Alkene Synthesis of Wide Applicability via Fluoride-Promoted Pd-Catalyzed Cross-Coupling of Alkenylboranes. Israel Journal of Chemistry. 50: 696-701. PMID 23966749 DOI: 10.1002/Ijch.201000051 |
0.46 |
|
| 2010 |
Negishi E, Wang G, Rao H, Xu Z. Alkyne elementometalation-Pd-catalyzed cross-coupling. Toward synthesis of all conceivable types of acyclic alkenes in high yields, efficiently, selectively, economically, and safely: "green" way. The Journal of Organic Chemistry. 75: 3151-82. PMID 20465291 DOI: 10.1021/Jo1003218 |
0.68 |
|
| 2010 |
Pitsinos E, Athinaios N, Xu Z, Wang G, Negishi E. Total synthesis of (+)-scyphostatin featuring an enantioselective and highly efficient route to the side-chain via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA). Chemical Communications (Cambridge, England). 46: 2200-2. PMID 20234905 DOI: 10.1039/B920261G |
0.685 |
|
| 2009 |
Wang G, Negishi EI. AlCl3-Promoted Facile E-to-Z Isomerization Route to (Z)-2-Methyl-1-buten-1,4-ylidene Synthons for Highly Efficient and Selective (Z)-Isoprenoid Synthesis. European Journal of Organic Chemistry. 2009. PMID 24307863 DOI: 10.1002/Ejoc.200801188 |
0.643 |
|
| 2009 |
Wang C, Tobrman T, Xu Z, Negishi E. Highly regio- and stereoselective synthesis of (Z)-trisubstituted alkenes via propyne bromoboration and tandem Pd-catalyzed cross-coupling. Organic Letters. 11: 4092-5. PMID 19694459 DOI: 10.1021/Ol901566E |
0.487 |
|
| 2009 |
Wang G, Huang Z, Negishi Ei. Highly stereoselective and efficient synthesis of ω-heterofunctional di- and trienoic esters for Horner-Wadsworth-Emmons reaction via alkyne hydrozirconation and Pd-catalyzed alkenylation Tetrahedron Letters. 50: 3220-3223. DOI: 10.1016/J.Tetlet.2009.02.023 |
0.746 |
|
| 2009 |
Negishi E, Hu Q, Huang Z, Wang G, Yin N. Palladium‐ or Nickel‐Catalyzed Cross‐Coupling Reactions with Organozincs and Related Organometals Patai's Chemistry of Functional Groups. 457-553. DOI: 10.1002/9780470682531.Pat0374 |
0.766 |
|
| 2008 |
Negishi E, Huang Z, Wang G, Mohan S, Wang C, Hattori H. Recent advances in efficient and selective synthesis of di-, tri-, and tetrasubstituted alkenes via Pd-catalyzed alkenylation-carbonyl olefination synergy. Accounts of Chemical Research. 41: 1474-85. PMID 18783256 DOI: 10.1021/Ar800038E |
0.836 |
|
| 2008 |
Xu Z, Negishi E. Efficient and stereoselective synthesis of yellow scale pheromone via alkyne haloboration, Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction), and Pd-catalyzed tandem Negishi coupling. Organic Letters. 10: 4311-4. PMID 18763786 DOI: 10.1021/Ol8017566 |
0.512 |
|
| 2008 |
Wang G, Huang Z, Negishi E. Efficient and selective syntheses of (all-E)- and (6E,10Z)-2'-O-methylmyxalamides D via Pd-catalyzed alkenylation--carbonyl olefination synergy. Organic Letters. 10: 3223-6. PMID 18593171 DOI: 10.1021/Ol801115S |
0.75 |
|
| 2008 |
Zhu G, Liang B, Negishi E. Efficient and selective synthesis of (S,R,R,S,R,S)-4,6,8,10,16,18-hexamethyl-docosane via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction). Organic Letters. 10: 1099-101. PMID 18275210 DOI: 10.1021/Ol703056U |
0.347 |
|
| 2008 |
Liang B, Negishi E. Highly efficient asymmetric synthesis of fluvirucinine A1 via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA)-lipase-catalyzed acetylation tandem process. Organic Letters. 10: 193-5. PMID 18076181 DOI: 10.1021/Ol702272D |
0.391 |
|
| 2008 |
Zhu G, Negishi E. 1,4-Pentenyne as a five-carbon synthon for efficient and selective syntheses of natural products containing 2,4-dimethyl-1-penten-1,5-ylidene and related moieties by means of Zr-catalyzed carboalumination of alkynes and alkenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 311-8. PMID 17969219 DOI: 10.1002/Chem.200701512 |
0.493 |
|
| 2008 |
Negishi E, Liang B, Novak T, Tan Z. ChemInform Abstract: ZACA Reaction: Zr-Catalyzed Asymmetric Carboalumination of Alkenes Cheminform. 39. DOI: 10.1002/chin.200801257 |
0.579 |
|
| 2007 |
Wang G, Zhu G, Negishi EI. Zirconium-catalyzed methylalumination of heterosubstituted arylethynes. Factors affecting the regio-, stereo-, and chemoselectivities. Journal of Organometallic Chemistry. 692: 4731-4736. PMID 19746204 DOI: 10.1016/J.Jorganchem.2007.05.052 |
0.61 |
|
| 2007 |
Huang Z, Negishi E. Highly stereo- and regioselective synthesis of (Z)-trisubstituted alkenes via 1-bromo-1-alkyne hydroboration-migratory insertion-Zn-promoted iodinolysis and Pd-catalyzed organozinc cross-coupling. Journal of the American Chemical Society. 129: 14788-92. PMID 17985915 DOI: 10.1021/Ja0772039 |
0.64 |
|
| 2007 |
Zhu G, Negishi E. Fully reagent-controlled asymmetric synthesis of (-)-spongidepsin via the Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction). Organic Letters. 9: 2771-4. PMID 17583343 DOI: 10.1021/Ol0707259 |
0.5 |
|
| 2007 |
Negishi EI. Transition metal-catalyzed organometallic reactions that have revolutionized organic synthesis Bulletin of the Chemical Society of Japan. 80: 233-257. DOI: 10.1246/Bcsj.80.233 |
0.464 |
|
| 2007 |
Huang Z, Tan Z, Novak T, Zhu G, Negishi E. ZACA-Lipase-Catalyzed Acetylation Synergy Synfacts. 2007: 608-608. DOI: 10.1055/S-2007-968494 |
0.571 |
|
| 2007 |
Zhang L, Huang Z, Chen WZ, Negishi EI, Fanwick PE, Updegraff JB, Protasiewicz JD, Ren T. Negishi coupling - Expedient formation of biphenyls on the periphery of inorganic/organometallic diruthenium species Organometallics. 26: 6526-6528. DOI: 10.1021/Om701083Q |
0.59 |
|
| 2007 |
Huang Z, Tan Z, Novak T, Zhu G, Negishi EI. Zirconium-catalyzed asymmetric carboalumination of alkenes: ZACA-lipase-catalyzed acetylation synergy Advanced Synthesis and Catalysis. 349: 539-545. DOI: 10.1002/Adsc.200600548 |
0.708 |
|
| 2006 |
Métay E, Hu Q, Negishi E. Highly efficient and selective synthesis of conjugated triynes and higher oligoynes of biological and materials chemical interest via palladium-catalyzed alkynyl-alkenyl coupling. Organic Letters. 8: 5773-6. PMID 17134269 DOI: 10.1021/Ol0623825 |
0.636 |
|
| 2006 |
Huang Z, Negishi E. A convenient and genuine equivalent to HZrCp2Cl generated in situ from ZrCp2Cl2-DIBAL-H. Organic Letters. 8: 3675-8. PMID 16898789 DOI: 10.1021/Ol061202O |
0.627 |
|
| 2006 |
Tan Z, Negishi E. Selective synthesis of epolactaene featuring efficient construction of methyl (Z)-2-iodo-2-butenoate and (2R,3S,4S)-2-trimethylsilyl-2,3-epoxy-4-methyl- gamma-butyrolactone. Organic Letters. 8: 2783-5. PMID 16774256 DOI: 10.1021/Ol060856U |
0.647 |
|
| 2006 |
Yin N, Wang G, Qian M, Negishi E. Stereoselective synthesis of the side chains of mycolactones A and B featuring stepwise double substitutions of 1,1-dibromo-1-alkenes. Angewandte Chemie (International Ed. in English). 45: 2916-20. PMID 16557634 DOI: 10.1002/Anie.200600012 |
0.635 |
|
| 2006 |
Liang B, Novak T, Tan Z, Negishi E. Catalytic, efficient, and syn-selective construction of deoxypolypropionates and other chiral compounds via Zr-catalyzed asymmetric carboalumination of allyl alcohol. Journal of the American Chemical Society. 128: 2770-1. PMID 16506734 DOI: 10.1021/Ja0530974 |
0.64 |
|
| 2006 |
Tan Z, Negishi E. Widely applicable Pd-catalyzed trans-selective monoalkylation of unactivated 1,1-dichloro-1-alkenes and Pd-catalyzed second substitution for the selective synthesis of E or Z trisubstituted alkenes. Angewandte Chemie (International Ed. in English). 45: 762-5. PMID 16365906 DOI: 10.1002/Anie.200503519 |
0.601 |
|
| 2006 |
Tan Z, Liang B, Huo S, Shi Jc, Negishi Ei. Zirconium-catalyzed asymmetric carboalumination (ZACA reaction) of 1,4-dienes Tetrahedron Asymmetry. 17: 512-515. DOI: 10.1016/J.Tetasy.2006.01.017 |
0.831 |
|
| 2006 |
Negishi EI, Wang G, Zhu G. Palladium-catalyzed cyclization via carbopalladation and acylpalladation Topics in Organometallic Chemistry. 19: 1-48. DOI: 10.1002/chin.200705243 |
0.709 |
|
| 2005 |
Novak T, Tan Z, Liang B, Negishi E. All-catalytic, efficient, and asymmetric synthesis of alpha,omega-diheterofunctional reduced polypropionates via "one-pot" Zr-catalyzed asymmetric carboalumination-Pd-catalyzed cross-coupling tandem process. Journal of the American Chemical Society. 127: 2838-9. PMID 15740104 DOI: 10.1021/Ja043534Z |
0.64 |
|
| 2005 |
Negishi E. A quarter of a century of explorations in organozirconium chemistry. Dalton Transactions (Cambridge, England : 2003). 827-48. PMID 15726133 DOI: 10.1039/B417134A |
0.497 |
|
| 2005 |
Qian M, Negishi EI. Palladium-catalyzed cross-coupling of alkynylzincs with allylic electrophiles: An efficient and selective synthesis of stereo- and regio-defined 1,4-enynes Synlett. 1789-1793. DOI: 10.1055/S-2005-871560 |
0.522 |
|
| 2005 |
Huang Z, Qian M, Babinski DJ, Negishi EI. Palladium-catalyzed cross-coupling reactions with zinc, boron, and indium exhibiting high turnover numbers (TONs): Use of bidentate phosphines and other critical factors in achieving high TONs Organometallics. 24: 475-478. DOI: 10.1021/Om049106J |
0.626 |
|
| 2005 |
Qian M, Negishi EI. Palladium-catalyzed cross-coupling reaction of alkynylzincs with benzylic electrophiles Tetrahedron Letters. 46: 2927-2930. DOI: 10.1016/J.Tetlet.2005.02.137 |
0.47 |
|
| 2005 |
Negishi EI, Shi JC, Zeng X. Palladium-catalyzed trans-selective alkynylation-alkylation tandem process for the synthesis of (E)-3-alkyl-1-trialkylsilyl-3-alken-1-ynes Tetrahedron. 61: 9886-9895. DOI: 10.1016/J.Tet.2005.07.100 |
0.606 |
|
| 2005 |
Negishi EI, Hu Q, Huang Z, Qian M, Wang G. Palladium-catalyzed alkenylation by the Negishi coupling Aldrichimica Acta. 38: 71-88. |
0.754 |
|
| 2004 |
Zeng X, Zeng F, Negishi E. Efficient and selective synthesis of 6,7-Dehydrostipiamide via Zr-catalyzed asymmetric carboalumination and Pd-catalyzed cross-coupling of organozincs. Organic Letters. 6: 3245-8. PMID 15355023 DOI: 10.1021/Ol048905V |
0.65 |
|
| 2004 |
Tan Z, Negishi E. An efficient and general method for the synthesis of alpha,omega-difunctional reduced polypropionates by Zr-catalyzed asymmetric carboalumination: synthesis of the scyphostatin side chain. Angewandte Chemie (International Ed. in English). 43: 2911-4. PMID 15170301 DOI: 10.1002/Anie.200353429 |
0.553 |
|
| 2004 |
Qian M, Huang Z, Negishi E. Use of InCl(3) as a cocatalyst and a Cl(2)Pd(DPEphos)-P(2-furyl)(3) catalyst system for one-pot hydrometalation-cross-coupling and carbometalation-cross-coupling tandem processes. Organic Letters. 6: 1531-4. PMID 15128228 DOI: 10.1021/Ol049716F |
0.62 |
|
| 2004 |
Zeng X, Qian M, Hu Q, Negishi E. Highly stereoselective synthesis of (1E)-2-methyl-1,3-dienes by palladium-catalyzed trans-selective cross-coupling of 1,1-dibromo-1-alkenes with alkenylzinc reagents. Angewandte Chemie (International Ed. in English). 43: 2259-63. PMID 15108138 DOI: 10.1002/Anie.200353022 |
0.7 |
|
| 2004 |
Magnin-Lachaux M, Tan Z, Liang B, Negishi E. Efficient and selective synthesis of siphonarienolone and related reduced polypropionates via Zr-catalyzed asymmetric carboalumination. Organic Letters. 6: 1425-7. PMID 15101758 DOI: 10.1021/Ol0497483 |
0.637 |
|
| 2004 |
Negishi E, Tan Z, Liang B, Novak T. An efficient and general route to reduced polypropionates via Zr-catalyzed asymmetric CC bond formation. Proceedings of the National Academy of Sciences of the United States of America. 101: 5782-7. PMID 15073327 DOI: 10.1073/Pnas.0307514101 |
0.61 |
|
| 2004 |
Dumond YR, Negishi EI. Zr-promoted 'pair'-selective and regioselective synthesis of penta-substituted benzene derivatives Tetrahedron. 60: 1345-1352. DOI: 10.1016/J.Tet.2003.09.102 |
0.822 |
|
| 2004 |
Negishi E, Idacavage MJ. Formation of Carbon ? Carbon and Carbon ? Heteroatom Bonds via Organoboranes and Organoborates Organic Reactions. 17: 1-246. DOI: 10.1002/0471264180.Or033.01 |
0.443 |
|
| 2003 |
Zeng X, Hu Q, Qian M, Negishi E. Clean inversion of configuration in the Pd-catalyzed cross-coupling of 2-bromo-1,3-dienes. Journal of the American Chemical Society. 125: 13636-7. PMID 14599182 DOI: 10.1021/Ja0304392 |
0.725 |
|
| 2003 |
Shi JC, Zeng X, Negishi E. Highly selective synthesis of (E)-3-methyl-1-trialkylsilyl-3-en-1-ynes via trans-selective alkynylation catalyzed by Cl2Pd(DPEphos) and stereospecific methylation with methylzincs catalyzed by Pd(tBu3P)2. Organic Letters. 5: 1825-8. PMID 12762662 DOI: 10.1021/Ol030017X |
0.631 |
|
| 2003 |
Negishi E, Anastasia L. Palladium-catalyzed alkynylation. Chemical Reviews. 103: 1979-2017. PMID 12744698 DOI: 10.1021/Cr020377I |
0.696 |
|
| 2003 |
Negishi E, Qian M, Zeng F, Anastasia L, Babinski D. Highly satisfactory alkynylation of alkenyl halides via Pd-catalyzed cross-coupling with alkynylzincs and its critical comparison with the sonogashira alkynylation. Organic Letters. 5: 1597-600. PMID 12735730 DOI: 10.1021/Ol030010F |
0.672 |
|
| 2003 |
Qian M, Negishi EI. Strictly "pair"-selective and economical synthesis of conjugated diynes via Pd-catalyzed reaction of terminal alkynes with 1,1-dichloroethylene, elimination with LDA, and subsequent transformations Organic Process Research and Development. 7: 412-417. DOI: 10.1021/op034029+ |
0.369 |
|
| 2003 |
Shi Jc, Negishi Ei. Pd-catalyzed selective tandem arylation-alkylation of 1,1-dihalo-1-alkenes with aryl- and alkylzinc derivatives to produce α-alkyl-substituted styrene derivatives Journal of Organometallic Chemistry. 687: 518-524. DOI: 10.1016/J.Jorganchem.2003.09.008 |
0.462 |
|
| 2003 |
Negishi E, Xu C. Palladium-Catalyzed Alkynylation with Alkynylmetals and Alkynyl Electrophiles Cheminform. 34. DOI: 10.1002/chin.200334245 |
0.617 |
|
| 2003 |
Negishi E, Zeng F. Reactions Between Homoallyl-, and Homopropargyl-, or Homobenzyl and Alkenyl or Aryl Electrophiles Cheminform. 34. DOI: 10.1002/chin.200333287 |
0.346 |
|
| 2003 |
Negishi E, Dumond Y. Palladium-Catalyzed Cross-Coupling Substitution Cheminform. 34. DOI: 10.1002/chin.200333280 |
0.329 |
|
| 2003 |
Negishi E, Takahashi T, King AO. Synthesis of Biaryls via Palladium‐Catalyzed Cross‐Coupling: 2‐Methyl‐4′‐Nitrobiphenyl Organic Syntheses. 67-67. DOI: 10.1002/0471264180.Os066.10 |
0.711 |
|
| 2003 |
Negishi E, Takahashi T, Baba S. Palladium‐Catalyzed Synthesis of Conjugated Dienes: (5Z,7E)‐5,7‐Hexadecadiene Organic Syntheses. 60-60. DOI: 10.1002/0471264180.Os066.09 |
0.701 |
|
| 2003 |
Negishi E, King AO, Tour JM. Conversion of Methyl Ketones into Terminal Alkynes: (E)‐Buten‐3‐ynyl‐2,6,6‐trimethyl‐1‐cyclohexene Organic Syntheses. 44-44. DOI: 10.1002/0471264180.Os064.06 |
0.514 |
|
| 2003 |
Negishi E, Matsushita H. Palladium‐Catalyzed Synthesis of 1,4‐Dienes by Allylation of Alkenylalanes:α‐Farnesene Organic Syntheses. 31-31. DOI: 10.1002/0471264180.Os062.05 |
0.467 |
|
| 2003 |
Negishi E, Brown HC. Perhydro‐9b‐Boraphenalene and Perhydro‐9b‐Phenalenol Organic Syntheses. 103-103. DOI: 10.1002/0471264180.Os061.23 |
0.365 |
|
| 2002 |
Huo S, Shi JC, Negishi E. A new protocol for the enantioselective synthesis of methyl-substituted alkanols and their derivatives through a hydroalumination/ zirconium-catalyzed alkylalumination tandem process. Angewandte Chemie (International Ed. in English). 41: 2141-3. PMID 19746622 DOI: 10.1002/1521-3773(20020617)41:12<2141::Aid-Anie2141>3.0.Co;2-W |
0.818 |
|
| 2002 |
Zeng F, Negishi EI. A highly efficient, selective, and general method for the synthesis of conjugated (all-E)-oligoenes of the (CH=CH)n type via iterative hydrozirconation-palladium-catalyzed cross-coupling Organic Letters. 4: 703-706. PMID 11869106 DOI: 10.1021/Ol0102794 |
0.372 |
|
| 2002 |
Negishi E, Liou SY, Xu C, Huo S. A novel, highly selective, and general methodology for the synthesis of 1,5-diene-containing oligoisoprenoids of all possible geometrical combinations exemplified by an iterative and convergent synthesis of coenzyme Q(10). Organic Letters. 4: 261-4. PMID 11796065 DOI: 10.1021/Ol010263D |
0.836 |
|
| 2002 |
Negishi Ei, Huo S. Zirconium-catalyzed enantioselective carboalumination of "unactivated" alkenes as a new synthetic tool for asymmetric carbon-carbon bond formation Pure and Applied Chemistry. 74: 151-157. DOI: 10.1351/Pac200274010151 |
0.811 |
|
| 2002 |
NEGISHI E, KATZ J, BROWN H. Applications of Thexylmonoalkylboranes to the Stereoselective Synthesis of trans Disubstituted Olefins Synthesis. 1972: 555-556. DOI: 10.1055/S-1972-21922 |
0.529 |
|
| 2002 |
Anastasia L, Xu C, Negishi EI. Catalytic and selective conversion of (Z)-2-en-4-ynoic acids to either 2H-pyran-2-ones in the presence of ZnBr2 or (Z)-5-alkylidenefuran-2(5H)-ones in the presence of Ag2CO3 Tetrahedron Letters. 43: 5673-5676. DOI: 10.1016/S0040-4039(02)01128-0 |
0.683 |
|
| 2002 |
Negishi EI. A genealogy of Pd-catalyzed cross-coupling Journal of Organometallic Chemistry. 653: 34-40. DOI: 10.1016/S0022-328X(02)01273-1 |
0.408 |
|
| 2002 |
Negishi E, Matsushita H, Chatterjee S, John RA. Selective carbon-carbon bond formation via transition metal catalysis. 29. A highly regio- and stereospecific palladium-catalyzed allylation of enolates derived from ketones Cheminform. 14. DOI: 10.1002/Chin.198301170 |
0.387 |
|
| 2002 |
Negishi E, Lew G, Yoshida T. A Novel Stereoselective Synthesis Of (E)‐ And (Z)‐Alpha,Beta‐Unsaturated Carboxylic Esters Via Hydroboration Cheminform. 5. DOI: 10.1002/Chin.197447199 |
0.432 |
|
| 2002 |
Huo S, Shi J, Negishi E. A New Protocol for the Enantioselective Synthesis of Methyl-Substituted Alkanols and Their Derivatives through a Hydroalumination/Zirconium-Catalyzed Alkylalumination Tandem Process We thank the National Science Foundation (CHE-0080795), the National Institutes of Health (GM36792), and Purdue University for support of this research. We also thank Albemarle and Boulder Chemical for assistance in the procurement of Al and Zr compounds, respectively. Angewandte Chemie. 114: 2245. DOI: 10.1002/1521-3757(20020617)114:12<2245::Aid-Ange2245>3.0.Co;2-2 |
0.795 |
|
| 2001 |
Huo S, Negishi E. A convenient and asymmetric protocol for the synthesis of natural products containing chiral alkyl chains via Zr-catalyzed asymmetric carboalumination of alkenes. Synthesis of phytol and vitamins E and K. Organic Letters. 3: 3253-6. PMID 11594807 DOI: 10.1021/Ol010142D |
0.817 |
|
| 2001 |
Zeng F, Negishi E. A novel, selective, and efficient route to carotenoids and related natural products via Zr-catalyzed carboalumination and Pd- and Zn-catalyzed cross coupling. Organic Letters. 3: 719-22. PMID 11259045 DOI: 10.1021/Ol000384Y |
0.481 |
|
| 2001 |
Negishi Ei. Some newer aspects of organozirconium chemistry of relevance to organic synthesis. Zr-catalyzed enantioselective carbometallation Pure and Applied Chemistry. 73: 239-242. DOI: 10.1351/Pac200173020239 |
0.484 |
|
| 2001 |
Gagneur S, Makabe H, Negishi EI. A novel hydrogen transfer hydroalumination of alkenes with triisobutylaluminum catalyzed by Pd and other late transition metal complexes Tetrahedron Letters. 42: 785-787. DOI: 10.1016/S0040-4039(00)02142-0 |
0.783 |
|
| 2001 |
Anastasia L, Dumond YR, Negishi EI. Stereoselective synthesis of exocyclic alkenes by Cu-catalyzed allylmagnesiation, Pd-catalyzed alkylation, and Ru-catalyzed ring-closing metathesis: Highly stereoselective synthesis of (Z)- and (E)-γ-bisabolenes European Journal of Organic Chemistry. 3039-3043. DOI: 10.1002/1099-0690(200108)2001:16<3039::Aid-Ejoc3039>3.0.Co;2-V |
0.839 |
|
| 2000 |
Negishi EI, Hata M, Xu C. A strictly "pair"-selective synthesis of conjugated diynes via Pd-catalyzed cross coupling of 1,3-diynylzincs: a superior alternative to the Cadiot-Chodkiewicz reaction. Organic Letters. 2: 3687-9. PMID 11073676 DOI: 10.1021/Ol000270M |
0.622 |
|
| 2000 |
Negishi E, Alimardanov A, Xu C. An efficient and stereoselective synthesis of xerulin via Pd-catalyzed cross coupling and lactonization featuring (E)-lodobromoethylene as a novel two-carbon synthon. Organic Letters. 2: 65-7. PMID 10814247 DOI: 10.1021/Ol990336H |
0.573 |
|
| 2000 |
Negishi E, Liao B. Development of a Method for the Synthesis of a-Substituted a,b-Unsaturated Lactones Based on Stille-Type Pd-catalyzed Carbonylation of (Z)-w-Iodoalkenols. An Efficient and Selective Synthesis of (+)-Hamabiwa-lactone B Heterocycles. 52: 1241-1249. DOI: 10.3987/Com-99-S138 |
0.442 |
|
| 2000 |
Gagneur S, Montchamp aJ, Negishi E. Ethylzincation of Monosubstituted Alkenes Catalyzed by EtMgBr−Cl2ZrCp2 and Palladium-Catalyzed Cross Coupling of the Resultant Diisoalkylzinc Derivatives Organometallics. 19: 2417-2419. DOI: 10.1021/Om991004J |
0.822 |
|
| 2000 |
Negishi Ei, Liou SY, Xu C, Huo S. A general method for the synthesis of E and/or Z oligoisoprenoids based on Pd-catalyzed homoallyl-alkenyl and homopropargyl-alkenyl cross coupling and Zr-catalyzed carboalumination Polyhedron. 19: 591-592. DOI: 10.1016/S0277-5387(99)00415-5 |
0.839 |
|
| 2000 |
Negishi EI, Tan Z, Liou SY, Liao B. Strictly regiocontrolled α-monosubstitution of cyclic carbonyl compounds with alkynyl and alkyl groups via Pd-catalyzed coupling of cyclic α-iodoenones with organozincs Tetrahedron. 56: 10197-10207. DOI: 10.1016/S0040-4020(00)00864-4 |
0.605 |
|
| 2000 |
Liao B, Negishi EI. Development of a method for the synthesis of α-substituted α,β- unsaturated lactones based on stille-type Pd-catalyzed carbonylation of (Z)- ω-iodoalkenols. An efficient and selective synthesis of (+)-hamabiwalactone B Heterocycles. 52: 1241-1249. |
0.302 |
|
| 1999 |
Copéret C, Negishi E. Palladium-catalyzed highly diastereoselective cyclic carbopalladation-carbonylative esterification tandem reaction of iododienes and iodoarylalkenes. Organic Letters. 1: 165-7. PMID 10822554 DOI: 10.1021/Ol9900663 |
0.625 |
|
| 1999 |
Dumond Y, Negishi EI. Highly chemo-, regio-, and stereoselective carbon-carbon bond formation via migratory insertion reaction of zirconacyclopentene derivatives and alkynyl metals containing Li and Mg. Novel synthesis of 1,5-dienes and 1,5- enynes [1] Journal of the American Chemical Society. 121: 11223-11224. DOI: 10.1021/Ja990266+ |
0.81 |
|
| 1999 |
Negishi EI, Liou SY, Xu C, Shimoyama I, Makabe H. Intermolecular trapping of acylpalladium and related acylmetal derivatives with active C-H compounds Journal of Molecular Catalysis a: Chemical. 143: 279-286. DOI: 10.1016/S1381-1169(98)00395-1 |
0.588 |
|
| 1999 |
Alimardanov A, Negishi Ei. Synthesis of α-iodo-α,β-unsaturated ketones by the reaction of α- silyl-α,β-unsaturated ketones with ICl or ICIl-AlCl3 Tetrahedron Letters. 40: 3839-3842. DOI: 10.1016/S0040-4039(99)00635-8 |
0.305 |
|
| 1999 |
Xu C, Negishi Ei. A highly efficient and selective synthesis of lissoclinolide featuring hydrogen transfer hydrozirconation, trans-selective Pd-catalyzed cross coupling of alkenylzirconiums with 1,1-dibromoalkenes and Ag-catalyzed lactonization providing (Z)-γ-alkylidenebutenolides Tetrahedron Letters. 40: 431-434. DOI: 10.1016/S0040-4039(98)02394-6 |
0.605 |
|
| 1999 |
Negishi EI. Novel and selective α-substitution of ketones and other carbonyl compounds based on Pd-catalyzed cross coupling of α,β-unsaturated carbonyl derivatives containing α-halogen or α-metal groups Journal of Organometallic Chemistry. 576: 179-194. DOI: 10.1016/S0022-328X(98)01057-2 |
0.439 |
|
| 1999 |
Makabe H, Negishi EI. Hydrogen transfer hydrozirconation of alkenes with iBuZrCp2Cl catalyzed by Lewis-acidic metal compounds containing Al, Zn, Si, Ag, and Pd European Journal of Organic Chemistry. 969-971. DOI: 10.1002/(Sici)1099-0690(199905)1999:5<969::Aid-Ejoc969>3.0.Co;2-G |
0.398 |
|
| 1998 |
Negishi EI, Takahashi T. Alkene and Alkyne Complexes of Zirconocene. Their Preparation, Structure, and Novel Transformations Bulletin of the Chemical Society of Japan. 71: 755-769. DOI: 10.1246/Bcsj.71.755 |
0.645 |
|
| 1998 |
Montchamp JL, Negishi EI. Carbozincation of enynes catalyzed by titanium(IV) alkoxides and alkylmagnesium Derivatives [16] Journal of the American Chemical Society. 120: 5345-5346. DOI: 10.1021/Ja973841N |
0.44 |
|
| 1998 |
Negishi EI, Montchamp JL, Anastasia L, Elizarov A, Choueiry D. Zirconium-catalyzed carboalumination of alkynes and enynes as a route to aluminacycles and their conversion to cyclic organic compounds Tetrahedron Letters. 39: 2503-2506. DOI: 10.1016/S0040-4039(98)00349-9 |
0.611 |
|
| 1998 |
Negishi Ei, Pour M, Cederbaum FE, Kotora M. Strictly regio- and stereo-controlled α-alkenylation of bicyclic enone derivatives via palladium-catalyzed cross coupling and its application to a formal synthesis of (±)-carbacyclin Tetrahedron. 54: 7057-7074. DOI: 10.1016/S0040-4020(98)00347-0 |
0.757 |
|
| 1998 |
Negishi Ei, Makabe H, Shimoyama I, Wu G, Zhang Y. Catalytic generation and trapping of acylmetals containing Ni and Cu with enolates Tetrahedron. 54: 1095-1106. DOI: 10.1016/S0040-4020(97)10210-1 |
0.457 |
|
| 1998 |
Negishi EI, Rousset CJ, Choueiry D, Maye JP, Suzuki N, Takahashi T. Zirconium-catalyzed and zirconium-promoted cyclization reactions of non-conjugated dienes with alkylmagnesium halides to give cycloalkylmethylmagnesium derivatives Inorganica Chimica Acta. 280: 8-20. DOI: 10.1016/S0020-1693(98)00064-4 |
0.725 |
|
| 1997 |
Negishi EI, Xu C, Tan Z, Kotora M. Direct synthesis of heteroarylethynes via palladiumcatalyzed coupling of heteroaryl halides with ethynylzinc halides. Its application to an efficient synthesis of a thiophenelactone from chamaemelum nobile Heterocycles. 46: 209-214. DOI: 10.3987/Com-97-S79 |
0.798 |
|
| 1997 |
Kotora M, Negishi EI. Highly efficient and selective procedures for the synthesis of γ-alkylidenebutenolides via palladium-catalyzed ene-yne coupling and palladium- or silver-catalyzed lactonization of (Z)-2-en-4-ynoic acids. Synthesis of rubrolides A, C, D, and E Synthesis. 121-128. DOI: 10.1055/S-1997-1513 |
0.748 |
|
| 1997 |
Negishi EI, Kondakov DY, Van Horn DE. Carbometalation reactions of diphenylacetylene and other alkynes with methylalanes and titanocene derivatives Organometallics. 16: 951-957. DOI: 10.1021/Om960879K |
0.428 |
|
| 1997 |
Negishi E, Kotora M, Xu C. Direct Synthesis of Terminal Alkynes via Pd-Catalyzed Cross Coupling of Aryl and Alkenyl Halides with Ethynylmetals Containing Zn, Mg, and Sn. Critical Comparison of Countercations Journal of Organic Chemistry. 62: 8957-8960. DOI: 10.1021/Jo971552B |
0.742 |
|
| 1997 |
Liu F, Negishi EI. Efficient and Stereoselective Synthesis of Freelingyne via Pd-Catalyzed Cross Coupling and Lactonization Journal of Organic Chemistry. 62: 8591-8594. DOI: 10.1021/Jo971360G |
0.463 |
|
| 1997 |
Negishi EI, Ma S, Sugihara T, Noda Y. Synthesis of hydrazulenes via Zr-promoted bicyclization of enynes and transition metal-catalyzed or radical cyclization of alkenyl iodides. Efficient synthesis of (±)-7-epi-β-bulnesene Journal of Organic Chemistry. 62: 1922-1923. DOI: 10.1021/Jo970009S |
0.526 |
|
| 1997 |
Rousset CJ, Iyer S, Negishi EI. Enantiomerically pure zirconium and hafnium complexes containing a chiral cyclopentadiene derivative prepared from (-)-β-pinene Tetrahedron Asymmetry. 8: 3921-3926. DOI: 10.1016/S0957-4166(97)00588-0 |
0.371 |
|
| 1997 |
Ma S, Liu F, Negishi EI. Anti-hydroalumination of homo- and bishomopropargyl alcohols Tetrahedron Letters. 38: 3829-3832. DOI: 10.1016/S0040-4039(97)00764-8 |
0.386 |
|
| 1997 |
Pour M, Negishi EI. An efficient and selective synthesis of nakienone a involving a novel protocol for α-alkenylation of ketones via palladium-catalyzed alkenyl-alkenyl coupling Tetrahedron Letters. 38: 525-528. DOI: 10.1016/S0040-4039(96)02409-4 |
0.541 |
|
| 1997 |
Takahashi T, Xi Z, Nishihara Y, Huo S, Kasai K, Aoyagi K, Denisov V, Negishi EI. Convenient preparative method of α,β-disubstituted cyclopentenone by zirconium promoted intermolecular coupling of an alkyne, EtMgBr (or ethylene) and CO Tetrahedron. 53: 9123-9134. DOI: 10.1016/S0040-4020(97)00612-1 |
0.608 |
|
| 1997 |
Negishi EI, Kotora M. Regio- and stereoselective synthesis of γ-Alkylidenebutenolides and related compounds Tetrahedron. 53: 6707-6738. DOI: 10.1016/S0040-4020(97)00199-3 |
0.697 |
|
| 1996 |
Negishi EI, Kondakov DY. An odyssey from stoichiometric carbotitanation of alkynes to zirconium-catalysed enantioselective carboalumination of alkenes Chemical Society Reviews. 25: 417-426. DOI: 10.1039/Cs9962500417 |
0.5 |
|
| 1996 |
Negishi EI, Kondakov DY, Choueiry D, Kasai K, Takahashi T. Multiple mechanistic pathways for zirconium-catalyzed carboalumination of alkynes. Requirements for cyclic carbometalation processes involving C-H activation Journal of the American Chemical Society. 118: 9577-9588. DOI: 10.1021/Ja9538039 |
0.681 |
|
| 1996 |
Kondakov DY, Negishi EI. Zirconium-catalyzed enantioselective alkylalumination of monosubstituted alkenes proceeding via noncyclic mechanism Journal of the American Chemical Society. 118: 1577-1578. DOI: 10.1021/Ja953655M |
0.426 |
|
| 1996 |
Negishi E, Ma S, Amanfu J, Coperet C, Miller JA, Tour JM. Palladium-catalyzed cyclization of 1-iodo-substituted 1,4-, 1,5-, and 1,6-dienes as well as 5-iodo-1,5-dienes in the presence of carbon monoxide Journal of the American Chemical Society. 118: 5919-5931. DOI: 10.1021/Ja9533205 |
0.688 |
|
| 1996 |
Negishi EI, Copéret C, Ma S, Mita T, Sugihara T, Tour JM. Palladium-catalyzed carbonylative cyclization of 1-iodo-2-alkenylbenzenes Journal of the American Chemical Society. 118: 5904-5918. DOI: 10.1021/Ja9533196 |
0.689 |
|
| 1996 |
Kotora M, Negishi EI. Efficient and diastereoselective synthesis of (+)-goniobutenolide A via palladium-catalyzed ene-yne cross coupling-lactonization cascade Tetrahedron Letters. 37: 9041-9042. DOI: 10.1016/S0040-4039(96)01972-7 |
0.759 |
|
| 1996 |
Pour M, Negishi EI. A selective procedure for α-alkenylation of enones involving Pd-catalyzed alkenyl-alkenyl coupling and its application to a convergent and efficient synthesis of nakienone B Tetrahedron Letters. 37: 4679-4682. DOI: 10.1016/0040-4039(96)00962-8 |
0.465 |
|
| 1996 |
Kondakov DY, Wang S, Negishi EI. Titanium-catalyzed cascade carboalumination of 2-alkyl-substituted dienes and related trienes Tetrahedron Letters. 37: 3803-3806. DOI: 10.1016/0040-4039(96)00693-4 |
0.447 |
|
| 1996 |
Copéret C, Ma S, Sugihara T, Negishi EI. Cyclic carbopalladation of alkynes terminated by carbonylative amidation Tetrahedron. 52: 11529-11544. DOI: 10.1016/0040-4020(96)00640-0 |
0.558 |
|
| 1996 |
Copéret C, Ma S, Negishi E. Palladium‐Catalyzed Carbonylative Cyclization Cascades with Iododienes and ‐trienes Angewandte Chemie. 35: 2125-2126. DOI: 10.1002/Anie.199621251 |
0.626 |
|
| 1996 |
Copéret C, Ma S, Negishi E. Palladiumkatalysierte Kaskadencyclisierung von Ioddienen und -trienen unter Carbonylierung Angewandte Chemie. 108: 2255-2257. DOI: 10.1002/Ange.19961081818 |
0.406 |
|
| 1996 |
Copéret C, Ma S, Negishi EI. Palladium-Catalyzed Carbonylative Cyclization Cascades with lododienes and trienes Bis(guanidinium) Angewandte Chemie (International Edition in English). 35: 2125-2126. |
0.467 |
|
| 1995 |
Kondakov DY, Negishi EI. Zirconium-catalyzed enantioselective methylalumination of monosubstituted alkenes Journal of the American Chemical Society. 117: 10771-10772. DOI: 10.1021/Ja00148A031 |
0.512 |
|
| 1995 |
Ma S, Negishi E. Palladium-Catalyzed Cyclization of .omega.-Haloallenes. A New General Route to Common, Medium, and Large Ring Compounds via Cyclic Carbopalladation Journal of the American Chemical Society. 117: 6345-6357. DOI: 10.1021/Ja00128A025 |
0.408 |
|
| 1995 |
Copéret C, Sugihara T, Wu G, Shimoyama I, Negishi EI. Acylpalladation of internal alkynes and palladium-catalyzed carbonylation of (Z)-β-iodoenones and related derivatives producing γ-lactones and γ-lactams Journal of the American Chemical Society. 117: 3422-3431. DOI: 10.1021/Ja00117A011 |
0.546 |
|
| 1995 |
Copéret C, Sugihara T, Negishi E. Termination of carbopalladation of alkynes via carbonylative amidation producing lactams Tetrahedron Letters. 36: 1771-1774. DOI: 10.1016/0040-4039(95)00120-2 |
0.569 |
|
| 1995 |
Negishi Ei, Maye JP, Choueiry D. Stoichiometric reactions of nonconjugated dienes with zirconocene derivatives. Further delineation of the scope of bicyclization and observation of novel multipositional alkene regioisomerization Tetrahedron. 51: 4447-4462. DOI: 10.1016/0040-4020(94)01132-J |
0.476 |
|
| 1994 |
Ma S, Negishi E. Facile Formation of Seven- and Eight-Membered Cycloalkenes via Catalytic and Cyclic Carbopalladation of Allenes Journal of Organic Chemistry. 59: 4730-4732. DOI: 10.1021/Jo00096A011 |
0.424 |
|
| 1994 |
Negishi E, Choueiry D, Nguyen TB, Swanson DR, Suzuki N, Takahashi T. Nonconcerted Paths for Reactions of Alkene-Zirconocene Complexes Journal of the American Chemical Society. 116: 9751-9752. DOI: 10.1021/Ja00100A051 |
0.651 |
|
| 1994 |
Negishi E, Jensen MD, Kondakov DY, Wang S. Titanium-Catalyzed Cascade Carboalumination of Dienes and Trienes Journal of the American Chemical Society. 116: 8404-8405. DOI: 10.1021/Ja00097A073 |
0.499 |
|
| 1994 |
Sugihara T, Coperet C, Owczarczyk Z, Harring LS, Negishi E. Deferred Carbonylative Esterification in the Pd-Catalyzed Cyclic Carbometalation-Carbonylation Cascade Journal of the American Chemical Society. 116: 7923-7924. DOI: 10.1021/Ja00096A070 |
0.561 |
|
| 1994 |
Negishi E, Takahashi T. Patterns of Stoichiometric and Catalytic Reactions of Organozirconium and Related Complexes of Synthetic Interest Accounts of Chemical Research. 27: 124-130. DOI: 10.1021/Ar00041A002 |
0.667 |
|
| 1994 |
Copéret C, Negishi E, Xi Z, Takahashi T. Reaction of 3-zircona-1-cyclopentenes and zirconacyclopentanes with aldehydes. A selective and convenient synthesis of 4-penten-1-ols, (Z)-5-iodo-4-penten-1-ols, and related alkanols Tetrahedron Letters. 35: 695-698. DOI: 10.1016/S0040-4039(00)75793-5 |
0.807 |
|
| 1994 |
Negishi E, Copéret C, Sugihara T, Shimoyama I, Zhang Y, Wu G, Tour JM. Palladium-catalyzed carbonylative cyclization via trapping of acylpalladium derivatives with internal enolates. Its scope and factors affecting the C-to-O ratio Tetrahedron. 50: 425-436. DOI: 10.1016/S0040-4020(01)80765-1 |
0.651 |
|
| 1993 |
Maye JP, Negishi EI. Convenient synthesis of diene-zirconocenes and regioselective partial reduction of the more highly substituted double bonds of conjugated dienes via complexation with zirconocenes and protonolysis Journal of the Chemical Society, Chemical Communications. 1830-1831. DOI: 10.1039/C39930001830 |
0.413 |
|
| 1993 |
Maye JP, Negishi Ei. Conversion of non-conjugated dienes into conjugated diene-zirconocenes via multipositional regioisomerization Tetrahedron Letters. 34: 3359-3362. DOI: 10.1016/S0040-4039(00)79155-6 |
0.449 |
|
| 1993 |
Takahashi T, Kageyama M, Denisov V, Hara R, Negishi E. Facile cleavage of the CβCβ′ bond of zirconacyclopentenes. Convenient method for selectively coupling alkynes with alkynes, nitriles, and aldehydes Tetrahedron Letters. 34: 687-690. DOI: 10.1016/S0040-4039(00)61653-2 |
0.681 |
|
| 1993 |
Takahashi T, Aoyagi K, Denisov V, Suzuki N, Choueiry D, Negishi E. Zirconium catalyzed CC bond formation reaction of conjugated diynes with EtMgBr Tetrahedron Letters. 34: 8301-8304. DOI: 10.1016/S0040-4039(00)61416-8 |
0.694 |
|
| 1993 |
Negishi E, Ay M, Gulevich YV, Noda Y. Highly stereoselective and general synthesis of (z)-3-methyl-2-alken-1-ols via palladium-catalyzed cross coupling of (z)-3-iodo-2-buten-1-ol with organozincs and other organometals Tetrahedron Letters. 34: 1437-1440. DOI: 10.1016/S0040-4039(00)60312-X |
0.51 |
|
| 1993 |
Negishi E, Ay M, Sugihara T. Selective synthesis of benzene derivatives via palladium-catalyzed cascade carbometallation of alkynes Tetrahedron. 49: 5471-5482. DOI: 10.1016/S0040-4020(01)87263-X |
0.5 |
|
| 1992 |
Negishi E. Zipper-mode cascade carbometallation for construction of polycyclic structures Pure and Applied Chemistry. 64: 323-334. DOI: 10.1351/Pac199264030323 |
0.478 |
|
| 1992 |
Negishi E, Nguyen T, Maye JP, Choueiri D, Suzuki N, Takahashi T. Factors Affecting the Unusual Reactivity Order in the β-Hydrogen Abstraction of Dialkylzirconocenes Chemistry Letters. 21: 2367-2370. DOI: 10.1246/Cl.1992.2367 |
0.605 |
|
| 1992 |
Owczarczyk Z, Lamaty F, Vawter EJ, Negishi E. Apparent endo-mode cyclic carbopalladation with inversion of alkene configuration via exo-mode cyclization-cyclopropanation rearrangement Journal of the American Chemical Society. 114: 10091-10092. DOI: 10.1021/Ja00051A069 |
0.549 |
|
| 1992 |
Negishi E, Harring LS, Owczarczyk Z, Mohamud MM, Ay M. Cyclic cascade carbopalladation reactions as a route to benzene and fulvene derivatives Tetrahedron Letters. 33: 3253-3256. DOI: 10.1016/S0040-4039(00)92060-4 |
0.535 |
|
| 1992 |
Agnel G, Owczarczyk Z, Negishi E. Diastereoselective zirconocene-promoted bicyclization-carbonylation of allylically methyl-substituted enynes. Synthesis of (+)-iridomyrmecin Tetrahedron Letters. 33: 1543-1546. DOI: 10.1016/S0040-4039(00)91669-1 |
0.439 |
|
| 1992 |
Rousset CJ, Negishi E, Suzuki N, Takahashi T. Novel head-to-tail alkyl-alkene or alkene-alkene coupling via zirconium-catalyzed reaction of alkylmagnesium derivatives with monosubstituted alkenes Tetrahedron Letters. 33: 1965-1968. DOI: 10.1016/0040-4039(92)88115-L |
0.731 |
|
| 1992 |
Negishi E, Nguyen T, Boardman LD, Sawada H, Morrison JA. Cyclization reactions of ω-tosyloxy-1-alkynyl- and ω-tosyloxy-1-alkenylborates and their ω-halo analogues† Heteroatom Chemistry. 3: 293-302. DOI: 10.1002/Hc.520030315 |
0.457 |
|
| 1991 |
Takahashi T, Suzuki N, Kageyama M, Nitto Y, Sabur M, Negishi E. Catalytic Hydrogenation of Alkenes Using Zirconocene–Alkene Complexes Chemistry Letters. 20: 1579-1582. DOI: 10.1246/Cl.1991.1579 |
0.647 |
|
| 1991 |
Swanson DR, Negishi E. A general and convenient procedure for the preparation of zirconocene complexes of alkenes and conjugated dienes Organometallics. 10: 825-826. DOI: 10.1021/Om00050A001 |
0.341 |
|
| 1991 |
Wu G, Shimoyama I, Negishi E. Palladium-catalyzed carbonylative cyclization of o-allylbenzyl halides to produce benzo-annulated enol lactones and/or bicyclo[3.3.0]hept-3-en-6-ones. An efficient route to U-68,215 Journal of Organic Chemistry. 56: 6506-6507. DOI: 10.1021/Jo00023A011 |
0.407 |
|
| 1991 |
Takahashi T, Hasegawa M, Suzuki N, Saburi M, Rousset CJ, Fanwick PE, Negishi E. Zirconium-catalyzed highly regioselective hydrosilation reaction of alkenes and x-ray structures of silyl(hydrido)zirconocene derivatives Journal of the American Chemical Society. 113: 8564-8566. DOI: 10.1021/Ja00022A077 |
0.657 |
|
| 1991 |
Agnel G, Negishi E. Highly stereo- and regiocontrolled cyclopentannulation via allylphosphonate conjugate addition and hydroboration-oxidation-elimination. Synthesis of pentalenic acid with virtually complete stereo- and regiocontrol Journal of the American Chemical Society. 113: 7424-7426. DOI: 10.1021/Ja00019A051 |
0.324 |
|
| 1991 |
Takahashi T, Seki T, Nitto Y, Saburi M, Rousset CJ, Negishi E. Remarkably pair- and regioselective carbon-carbon bond-forming reaction of zirconacyclopentane derivatives with Grignard reagents Journal of the American Chemical Society. 113: 6266-6268. DOI: 10.1021/Ja00016A051 |
0.642 |
|
| 1991 |
Takagi K, Rousset CJ, Negishi E. Novel zirconocene-promoted carbon-carbon bond formation via a 1,2-migration reaction of alkynylzirconium derivatives Journal of the American Chemical Society. 113: 1440-1442. DOI: 10.1021/Ja00004A070 |
0.351 |
|
| 1991 |
Negishi E, Owczarczyk Z. Highly selective synthesis of vitamin A and its derivatives. Critical comparison of some known palladium-catalyzed alkenyl-alkenyl coupling reactions Tetrahedron Letters. 32: 6683-6686. DOI: 10.1016/S0040-4039(00)93574-3 |
0.484 |
|
| 1991 |
Nguyen T, Negishi E. Carbon-carbon bond formation by the reaction of organolithiums with α-lithiated cyclic enol ethers. Stereoselective synthesis of β- and γ-hydroxy DI- and tri-substituted alkenes Tetrahedron Letters. 32: 5903-5906. DOI: 10.1016/S0040-4039(00)79422-6 |
0.425 |
|
| 1991 |
Negishi Ei, Yoshida T, Abramovitch A, Lew G, Williams RM. Highly stereoselective syntheses of conjugated E,E- and E,Z-dienes, E-enynes and E-1,2,3-butatriened via alkenylborane derivatives Tetrahedron. 47: 343-356. DOI: 10.1016/S0040-4020(01)90494-6 |
0.309 |
|
| 1991 |
Negishi E, Owczarczyk ZR, Swanson DR. Strictly regio-controlled method for α-alkenylation of cyclic ketones via palladium-catalyzed cross coupling Tetrahedron Letters. 32: 4453-4456. DOI: 10.1016/0040-4039(91)80010-4 |
0.383 |
|
| 1990 |
Takahashi T, Nitto Y, Seki T, Saburi M, Negishi E. Reaction of Dimethylzirconocene with Alkylmagnesium Halides as a Potentially General Method for Preparing Zirconocene-Alkene Complexes Chemistry Letters. 19: 2259-2262. DOI: 10.1246/Cl.1990.2259 |
0.651 |
|
| 1990 |
Negishi E, Swanson DR, Takahashi T. Nondissociative mechanism for decomposition of dialkylzirconocenes to produce alkene–zirconocene–phosphine complexes Journal of the Chemical Society, Chemical Communications. 1254-1255. DOI: 10.1039/C39900001254 |
0.613 |
|
| 1990 |
Takahashi T, Fujimori T, Seki T, Saburi M, Uchida Y, Rousset CJ, Negishi E. Selective skeletal rearrangement by carbon–carbon bond activation Journal of the Chemical Society, Chemical Communications. 182-183. DOI: 10.1039/C39900000182 |
0.641 |
|
| 1990 |
Negishi E, Noda Y, Lamaty F, Vawter EJ. Effects of organometals on the palladium-catalyzed tandem carbopalladation-cross coupling for preparing stereodefined exocyclic alkenes Tetrahedron Letters. 31: 4393-4396. DOI: 10.1016/S0040-4039(00)97630-5 |
0.684 |
|
| 1990 |
Wu G, Cederbaum FE, Negishi E. Stereoselective cyclic carbolithiation of alkyne derivatives. A stereoselective synthesis of exocyclic alkenes Tetrahedron Letters. 31: 493-496. DOI: 10.1016/0040-4039(90)87016-S |
0.494 |
|
| 1990 |
Shimoyama I, Zhang Y, Wu G, Negishi E. Synthesis of enol esters and enol lactones via palladium-catalyzed carbonyiation of ary land alkenyl halides Tetrahedron Letters. 31: 2841-2844. DOI: 10.1016/0040-4039(90)80162-F |
0.498 |
|
| 1989 |
NEGISHI E, TAKAHASHI T. Organic syntheses using zirconium compounds - Recent developments. Journal of Synthetic Organic Chemistry, Japan. 47: 2-10. DOI: 10.5059/Yukigoseikyokaishi.47.2 |
0.717 |
|
| 1989 |
Negishi E, Nguyen T, O'Connor B, Evans JM, Silveira A. Synthesis of benzofurans, tetrahydrobenzopyrans, and related cyclic ethers via cyclic carbopalladation Heterocycles. 28: 55-58. DOI: 10.3987/Com-88-S21 |
0.407 |
|
| 1989 |
Takahashi T, Murakami M, Kunishige M, Saburi M, Uchida Y, Kozawa K, Uchida T, Swanson DR, Negishi E. Zirconocene–Alkene Complexes. An X-Ray Structure and a Novel Preparative Method Chemistry Letters. 18: 761-764. DOI: 10.1246/Cl.1989.761 |
0.604 |
|
| 1989 |
Takahashi T, Tamura M, Saburi M, Uchida Y, Negishi E. Preparation of a hafnocene–ethylene complex from bis(η5-cyclopentadienyl)hafnacyclopentane and its characterization Journal of the Chemical Society, Chemical Communications. 852-853. DOI: 10.1039/C39890000852 |
0.615 |
|
| 1989 |
Negishi E, Miller SR. Stereoselective synthesis of exocyclic alkenes via zirconium-promoted alkyl-diene coupling The Journal of Organic Chemistry. 54: 6014-6016. DOI: 10.1021/Jo00287A008 |
0.482 |
|
| 1989 |
Swanson DR, Rousset CJ, Negishi E, Takahashi T, Seki T, Saburi M, Uchida Y. Metal-promoted cyclization. 28. Regioselective and diastereoselective alkyl-alkene and alkene-alkene coupling promoted by zirconocene and hafnocene The Journal of Organic Chemistry. 54: 3521-3523. DOI: 10.1021/Jo00276A006 |
0.682 |
|
| 1989 |
Wu GZ, Lamaty F, Negishi E. Metal-promoted cyclization. 26. Palladium-catalyzed cyclization of benzyl halides and related electrophiles containing alkenes and alkynes as a novel route to carbocycles The Journal of Organic Chemistry. 54: 2507-2508. DOI: 10.1021/Jo00272A006 |
0.673 |
|
| 1989 |
Negishi E, Zhang Y, Shimoyama I, Wu G. Carbonylative cyclization via intramolecular trapping of acylmetal derivatives by carbon nucleophiles catalyzed by late transition metals Journal of the American Chemical Society. 111: 8018-8020. DOI: 10.1021/Ja00202A055 |
0.379 |
|
| 1989 |
Zhang Y, Negishi E. Metal-promoted cyclization. 25. Palladium-catalyzed cascade carbometalation of alkynes and alkenes as an efficient route to cyclic and polycyclic structures Journal of the American Chemical Society. 111: 3454-3456. DOI: 10.1021/Ja00191A066 |
0.428 |
|
| 1989 |
Negishi E, Holmes SJ, Tour JM, Miller JA, Cederbaum FE, Swanson DR, Takahashi T. Metal-promoted cyclization. 19. Novel bicyclization of enynes and diynes promoted by zirconocene derivatives and conversion of zirconabicycles into bicyclic enones via carbonylation Journal of the American Chemical Society. 111: 3336-3346. DOI: 10.1021/Ja00191A035 |
0.698 |
|
| 1989 |
Negishi E, Akiyoshi K, O'Connor B, Takagi K, Wu G. Migratory insertion reactions of organometallics. 3. Carbon-carbon bond forming reactions of organotransition metals with .alpha.- or .gamma.-haloorganolithium reagents Journal of the American Chemical Society. 111: 3089-3091. DOI: 10.1021/Ja00190A067 |
0.367 |
|
| 1989 |
Rousset CJ, Swanson DR, Lamaty F, Negishi E. Zirconocene-promoted stereoselective bicyclization of 1,6- and 1,7-dienes to produce trans-zirconabicyclo[3.3.0]octanes and cis-zirconabicyclo[4.3.0]nonanes Tetrahedron Letters. 30: 5105-5108. DOI: 10.1016/S0040-4039(01)93459-8 |
0.58 |
|
| 1989 |
Negishi E, Iyer S, Rousset CJ. Synthesis of cyclopentanol derivatives via palladium-catalyzed cyclic allylmetallation-dehydrometallation Tetrahedron Letters. 30: 291-294. DOI: 10.1016/S0040-4039(00)95182-7 |
0.487 |
|
| 1988 |
Negishi E, Takahashi T. Organozirconium Compounds in Organic Synthesis Synthesis. 1988: 1-19. DOI: 10.1055/S-1988-27453 |
0.615 |
|
| 1988 |
Zhang Y, O'Connor B, Negishi E. Metal-promoted cyclization. 21. Palladium-catalyzed procedures for [3 + 2] annulation via intramolecular alkenylpalladation and arylpalladation The Journal of Organic Chemistry. 53: 5588-5590. DOI: 10.1021/Jo00258A050 |
0.39 |
|
| 1988 |
Negishi E, Sawada H, Tour JM, Wei Y. Metal-promoted cyclization. 17. A novel bicyclization methodology via cyclialkylation of .omega.-halo-1-metallo-1-alkynes containing aluminum and zinc The Journal of Organic Chemistry. 53: 913-915. DOI: 10.1021/Jo00239A054 |
0.484 |
|
| 1988 |
Negishi E, Boardman LD, Sawada H, Bagheri V, Stoll AT, Tour JM, Rand CL. Metal promoted cyclization. 18. Novel cyclialkylation reactions of (.omega.-halo-1-alkenyl)metal derivatives. Synthetic scope and mechanism Journal of the American Chemical Society. 110: 5383-5396. DOI: 10.1021/Ja00224A025 |
0.463 |
|
| 1988 |
Negishi E, Akiyoshi K. Novel 1,2-migration reactions of organometals containing aluminum, zinc, and other main-group metals with .alpha.-haloorganolithiums Journal of the American Chemical Society. 110: 646-647. DOI: 10.1021/Ja00210A081 |
0.323 |
|
| 1988 |
Negishi E, Wu G, Tour JM. Palladium-catalyzed cyclic acylmetalation of allylic electrophiles as a route to cyclopentenone derivatives Tetrahedron Letters. 29: 6745-6748. DOI: 10.1016/S0040-4039(00)82444-2 |
0.58 |
|
| 1988 |
Negishi E, Swanson DR, Miller SR. One-pot conversion of alkynes and alkenes into one-carbon homologated aldehydes via hydrozirconation-isocyanide insertion-hydrolysis Tetrahedron Letters. 29: 1631-1634. DOI: 10.1016/S0040-4039(00)82003-1 |
0.471 |
|
| 1988 |
O'Connor B, Zhang Y, Negishi E, Luo F, Cheng J. Palladium-catalyzed cyclization of alkenyl and aryl halides containing α, β-Unsaturated carbonyl groups via intramolecular carbopalladation Tetrahedron Letters. 29: 3903-3906. DOI: 10.1016/S0040-4039(00)80376-7 |
0.439 |
|
| 1988 |
Negishi E, Zhang Y, O'Connor B. Efficient synthesis of carbobicyclic and carbopolycyclic compounds via intramolecular carbopalladation catalyzed by palladium-phosphine complexes Tetrahedron Letters. 29: 2915-2918. DOI: 10.1016/0040-4039(88)85046-9 |
0.514 |
|
| 1987 |
Takahashi T, Swanson DR, Negishi E. Zirconacyclopropanes and Zirconacyclopropenes. Their Synthesis, Characterization, and Reactions Chemistry Letters. 16: 623-626. DOI: 10.1246/Cl.1987.623 |
0.689 |
|
| 1987 |
Negishi E, Akiyoshi K. Highly Selective Methods for α-Alkenylation and α-Arylation of Ketones via Palladium- or Nickel-Catalyzed Cross Coupling Chemistry Letters. 16: 1007-1010. DOI: 10.1246/Cl.1987.1007 |
0.388 |
|
| 1987 |
Negishi E, Akiyoshi K, Takahashi T. Inhibition of reductive elimination of diorganopalladium species by formation of tetraorganopalladates Journal of the Chemical Society, Chemical Communications. 477-478. DOI: 10.1039/C39870000477 |
0.671 |
|
| 1987 |
Negishi E, Zhang Y, Bagheri V. Highly stereoselective synthesis of exocyclic alkenes via cyclialkylation Tetrahedron Letters. 28: 5793-5796. DOI: 10.1016/S0040-4039(01)81055-8 |
0.472 |
|
| 1987 |
Negishi E, Swanson DR, Cederbaum FE, Takahashi T. Zirconium-promoted bicyclization of enynes. Effects of enyne structure Tetrahedron Letters. 28: 917-920. DOI: 10.1016/S0040-4039(00)95873-8 |
0.628 |
|
| 1987 |
Negishi E, Takahashi T, Akiyoshi K. Palladium-catalyzed or -promoted reductive carbon-carbon coupling. Effects of phosphines and carbon ligands Journal of Organometallic Chemistry. 334: 181-194. DOI: 10.1016/0022-328X(87)80048-7 |
0.657 |
|
| 1986 |
Negishi E, Takahashi T, Akiyoshi K. ‘Bis(triphenylphosphine)palladium:’ its generation, characterization, and reactions Journal of the Chemical Society, Chemical Communications. 1338-1339. DOI: 10.1039/C39860001338 |
0.664 |
|
| 1986 |
Brown HC, Basavaiah D, Kulkarni SU, Lee HD, Negishi E, Katz JJ. Vinylic organoboranes. 6. A general synthesis of (E)-disubstituted-alkenes or ketones via the (E)-(1-substituted-1-alkenyl)boronic esters The Journal of Organic Chemistry. 51: 5270-5276. DOI: 10.1021/Jo00376A041 |
0.672 |
|
| 1986 |
Negishi E, Zhang Y, Cederbaum FE, Webb MB. A selective method for the synthesis of stereodefined exocyclic alkenes via allylmetalation of propargyl alcohols The Journal of Organic Chemistry. 51: 4080-4082. DOI: 10.1021/Jo00371A036 |
0.31 |
|
| 1986 |
Negishi E, Takahashi T. The origin of the configurational instability of 1-silyl-1-alkenyllithiums and related alkenylmetals Journal of the American Chemical Society. 108: 3402-3408. DOI: 10.1021/Ja00272A040 |
0.578 |
|
| 1986 |
Negishi E, Tour JM. Complete reversal of regiochemistry in cyclic acylpalladation. Novel synthesis of quinones. Tetrahedron Letters. 27: 4869-4872. DOI: 10.1016/S0040-4039(00)85084-4 |
0.558 |
|
| 1986 |
Negishi E, Cederbaum FE, Takahashi T. Reaction of zirconocene dichloride with alkyllithiums or alkyl grignard reagents as a convenient method for generating a “zirconocene” equivalant and its use in zirconium-promoted cyclization of alkenes, alkynes, dienes, enynes, and diynes Tetrahedron Letters. 27: 2829-2832. DOI: 10.1016/S0040-4039(00)84653-5 |
0.677 |
|
| 1986 |
Sawada H, Webb M, Stoll A, Negishi E. A novel synthesis of cyclopentenones and cyclohexenones via cycliacylation of lithioalkenylcarboxamides Tetrahedron Letters. 27: 775-778. DOI: 10.1016/S0040-4039(00)84098-8 |
0.447 |
|
| 1986 |
SAWADA H, WEBB M, STOLL AT, NEGISHI E. ChemInform Abstract: Metal Promoted Cyclization. Part 10. A Novel Synthesis of Cyclopentenones and Cyclohexenones via Cycliacylation of Lithioalkenylcarboxamides. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198624106 |
0.362 |
|
| 1986 |
Negishi E, Takahashi T. Organozirconium Compounds as New Reagents and Intermediates Cheminform. 17. DOI: 10.1002/Chin.198611392 |
0.601 |
|
| 1985 |
Luo FT, Negishi E. Nickel- or palladium-catalyzed cross coupling. 28. A selective synthesis of a mixture of C-15 epimers of (.+-.)-11-deoxyprostaglandin E2 methyl ester The Journal of Organic Chemistry. 50: 4762-4766. DOI: 10.1021/Jo00224A021 |
0.457 |
|
| 1985 |
Chatterjee S, Negishi E. Palladium-catalyzed reaction of organoalanes and organozincs with .alpha.,.beta.-unsaturated acetals and orthoesters as conjugate addition equivalents The Journal of Organic Chemistry. 50: 3406-3408. DOI: 10.1021/Jo00218A033 |
0.313 |
|
| 1985 |
Tour JM, Negishi E. Metal promoted cyclization. 9. Controlled and catalytic acylpalladation. A novel route to cyclopentenone and cyclohexenone derivatives Journal of the American Chemical Society. 107: 8289-8291. DOI: 10.1021/Ja00312A095 |
0.499 |
|
| 1985 |
Negishi E, Van Horn DE, Yoshida T. Controlled carbometalation. 20. Carbometalation reaction of alkynes with organoalene-zirconocene derivatives as a route to stereo-and regiodefined trisubstituted alkenes Journal of the American Chemical Society. 107: 6639-6647. DOI: 10.1021/Ja00309A036 |
0.44 |
|
| 1985 |
Negishi E, Holmes SJ, Tour JM, Miller JA. Metal promoted cyclization. 7. Zirconium-promoted bicyclization of enynes Journal of the American Chemical Society. 107: 2568-2569. DOI: 10.1021/Ja00294A071 |
0.454 |
|
| 1985 |
Stoll AT, Negishi E. A mild and selective synthesis of cyclopropene and cyclopropane derivatives via cycliallylation of alkenyllithiums Tetrahedron Letters. 26: 5671-5674. DOI: 10.1016/S0040-4039(01)80915-1 |
0.432 |
|
| 1985 |
Luo F, Negishi E. Palladium-catalyzed allylation of lithium 3-alkenyl-1-cyclopentenolates-triethylborane and its application to a selective synthesis of methyl (z)-jasmonate1 Tetrahedron Letters. 26: 2177-2180. DOI: 10.1016/S0040-4039(00)98955-X |
0.494 |
|
| 1985 |
Chatterjee S, Negishi E. Metal-promoted cyclization Journal of Organometallic Chemistry. 285: C1-C4. DOI: 10.1016/0022-328X(85)87390-3 |
0.467 |
|
| 1985 |
Brown HC, Negishi E, Dickason WC. Hydroboration. 70. The polycyclic hydroboration of acyclic and cyclic trienes with borane in tetrahydrofuran and triethylamine-borane. Reexamination of the stereochemistry of isomeric perhydro-9b-boraphenalenes The Journal of Organic Chemistry. 50: 520-527. DOI: 10.1002/Chin.198530090 |
0.428 |
|
| 1984 |
Boardman LD, Bagheri V, Sawada H, Negishi E. Metal promoted cyclization. 5. Mechanistic duality in cyclialkylation of alkenylmetal derivatives Journal of the American Chemical Society. 106: 6105-6107. DOI: 10.1021/Ja00332A072 |
0.325 |
|
| 1984 |
Negishi E, Miller JA, Yoshida T. Reaction of alkenes and dienes with t-butylmagnesium halides and zirconocene dihalides. A convenient procedure for hydrozirconation and a novel t-butylzirconation of conjugated alkenes Tetrahedron Letters. 25: 3407-3410. DOI: 10.1016/S0040-4039(01)91032-9 |
0.378 |
|
| 1984 |
Miller JA, Negishi E. Zirconium-catalyzed allylalumination and benzylalumination of alkynes Tetrahedron Letters. 25: 5863-5866. DOI: 10.1016/S0040-4039(01)81705-6 |
0.412 |
|
| 1984 |
Miller JA, Negishi E. Cyclic Carboalumination of Alkynylsilanes Forming Exocyclic Alkenes Israel Journal of Chemistry. 24: 76-81. DOI: 10.1002/Ijch.198400013 |
0.438 |
|
| 1984 |
Negishi E, Okukado N, Lovich SF, Luo FT. A method for the preparation of terminal and internal conjugated diynes via palladium-catalyzed cross-coupling The Journal of Organic Chemistry. 49: 2629-2632. DOI: 10.1002/Chin.198450156 |
0.408 |
|
| 1984 |
Negishi E, Bagheri V, Chatterjee S, Luo F-, Miller JA, Stoll AT. Selective Carbon-Carbon Bond Formation Via Transition Metal Catalysis. 36. Palladium-Catalyzed Acylation Of Organozincs And Other Organometallics As A Convenient Route To Ketones Cheminform. 15. DOI: 10.1002/Chin.198414156 |
0.363 |
|
| 1983 |
Negishi E, John RA. Selective carbon-carbon bond formation via transition-metal catalysis. 34. Countercation effects on the palladium-catalyzed allylation of enolates The Journal of Organic Chemistry. 48: 4098-4102. DOI: 10.1021/Jo00170A045 |
0.349 |
|
| 1983 |
Negishi E, Luo FT, Pecora AJ, Silveira A. 1,4- and 1,5-Diketones via palladium-catalyzed allylation of potassium enoxyborates Journal of Organic Chemistry. 48: 2427-2430. DOI: 10.1021/Jo00162A030 |
0.527 |
|
| 1983 |
Negishi E, Luo F. Selective carbon-carbon bond formation via transition-metal catalysis. 33. Palladium-catalyzed cross-coupling reaction of .alpha.-heterosubstituted alkenylmetals. A stereoselective route to heterosubstituted dienes suitable for the Diels-Alder reaction The Journal of Organic Chemistry. 48: 1560-1562. DOI: 10.1021/Jo00157A044 |
0.448 |
|
| 1983 |
Negishi E, Miller JA. Selective carbon-carbon bond formation via transition metal catalysis. 37. Controlled carbometalation. 16. Novel syntheses of .alpha.,.beta.-unsaturated cyclopentenones via allylzincation of alkynes Journal of the American Chemical Society. 105: 6761-6763. DOI: 10.1021/Ja00360A060 |
0.305 |
|
| 1983 |
Negishi E, Matsushita H, Kobayashi M, Rand CL. A convenient synthesis of unsymmetrical bibenzyls homoallylarenes, and homopropargylarenes via palladium-catalyzed cross coupling☆ Tetrahedron Letters. 24: 3823-3824. DOI: 10.1016/S0040-4039(00)94284-9 |
0.515 |
|
| 1983 |
Negishi E, Bagheri V, Chatterjee S, Luo F, Miller JA, Stoll A. Palladium-catalyzed acylation of organozincs and other organometallics as a convenient route to ketones Tetrahedron Letters. 24: 5181-5184. DOI: 10.1016/S0040-4039(00)88391-4 |
0.521 |
|
| 1983 |
Negishi E, Boardman LD, Tour JM, Sawada H, Rand CL. Novel silicon-promoted cycloalkylation of alkenylmetal derivatives Journal of the American Chemical Society. 105: 6344-6346. DOI: 10.1002/Chin.198402126 |
0.431 |
|
| 1983 |
Negishi E, Luo FT, Pecora AJ, Silveira A. 1,4- and 1,5-Diketones via palladium-catalyzed allylation of potassium enoxyborates Cheminform. 14. DOI: 10.1002/Chin.198348155 |
0.527 |
|
| 1982 |
Negishi E, Luo F, Frisbee R, Matsushita H. A Regiospecific Synthesis of Carbosubstituted Heteroaromatic Derivatives via Pd-Catalyzed Cross Coupling Heterocycles. 18: 117. DOI: 10.3987/S(B)-1982-01-0117 |
0.455 |
|
| 1982 |
Matsushita H, Negishi E. anti-Stereospecificity in the palladium-catalysed reactions of alkenyl- or aryl-metal derivatives with allylic electrophiles Journal of the Chemical Society, Chemical Communications. 160-161. DOI: 10.1039/C39820000160 |
0.5 |
|
| 1982 |
Negishi E. Asymmetric Reactions and Processes in Chemistry Organometallics. 1: 1556-1556. DOI: 10.1021/Om00071A904 |
0.391 |
|
| 1982 |
Matsushita H, Negishi E. Palladium-catalyzed reactions of allylic electrophiles with organometallic reagents. A regioselective 1,4-elimination and a regio- and stereoselective reduction of allylic derivatives The Journal of Organic Chemistry. 47: 4161-4165. DOI: 10.1021/Jo00142A031 |
0.54 |
|
| 1982 |
Negishi E, Matsushita H, Chatterjee S, John RA. Selective carbon-carbon bond formation via transition metal catalysis. 29. A highly regio- and stereospecific palladium-catalyzed allylation of enolates derived from ketones Journal of Organic Chemistry. 47: 3188-3190. DOI: 10.1021/Jo00137A038 |
0.387 |
|
| 1982 |
Negishi E. Palladium- or nickel-catalyzed cross coupling. A new selective method for carbon-carbon bond formation Accounts of Chemical Research. 15: 340-348. DOI: 10.1021/Ar00083A001 |
0.363 |
|
| 1982 |
Negishi E, Luo F, Rand CL. Stereo- and regioselective routes to allylic silanes Tetrahedron Letters. 23: 27-30. DOI: 10.1016/S0040-4039(00)97523-3 |
0.509 |
|
| 1982 |
Negishi E, Boardman LD. A selective and convenient synthesis of β, β-dialkyl-substituted alkenylbroanes and alkenylzirconiums via carboalumination of alkynes1 Tetrahedron Letters. 23: 3327-3330. DOI: 10.1016/S0040-4039(00)87606-6 |
0.41 |
|
| 1982 |
Negishi E, Jadhav KP, Daotien N. A selective synthesis of alkenylmercuric chlorides via alkenylalanes Tetrahedron Letters. 23: 2085-2086. DOI: 10.1016/S0040-4039(00)87267-6 |
0.484 |
|
| 1982 |
Negishi E, Jadhav KP, Daotien N. Carbometalation. 13. Selective Carbon-Carbon Bond Formation Via Transition-Metal Catalysis. 28. A Selective Synthesis Of Alkenylmercuric Chlorides Via Alkenylalanes Cheminform. 13. DOI: 10.1002/Chin.198243285 |
0.33 |
|
| 1982 |
Negishi E, Luo F-, Frisbee R, Matsushita H. A Regiospecific Synthesis of Carbosubstituted Heteroaromatic Derivatives via Pd-Catalyzed Cross Coupling. Selective Carbon-Carbon Bond Formation via Transition Metal Catalysis. Part 26. Cheminform. 13. DOI: 10.1002/Chin.198236176 |
0.435 |
|
| 1981 |
Negishi E. Bimetallic catalytic systems containing Ti, Zr, Ni, and Pd. Their applications to selective organic syntheses Pure and Applied Chemistry. 53: 2333-2356. DOI: 10.1351/Pac198153122333 |
0.346 |
|
| 1981 |
Negishi E, Rand CL, Jadhav KP. Selective carbon-carbon bond formation via transition metal catalysis. 23. Highly selective and convenient method for the synthesis of 1,5-enynes and 1,5-dienes by the reaction of 1,3-dilithiopropargyl phenyl sulfide with allylic halides Journal of Organic Chemistry. 13: 5041-5044. DOI: 10.1021/Jo00337A057 |
0.417 |
|
| 1981 |
Rand CL, Horn DEV, Moore MW, Negishi E. A versatile and selective route to difunctional trisubstituted (E)-alkene synthons via zirconium-catalyzed carboalumination of alkynes Journal of Organic Chemistry. 46: 4093-4096. DOI: 10.1021/Jo00333A041 |
0.414 |
|
| 1981 |
Yoshida T, Negishi E. Mechanism of the zirconium-catalyzed carboalumination of alkynes. Evidence for direct carboalumination Journal of the American Chemical Society. 103: 4985-4987. DOI: 10.1021/Ja00406A071 |
0.348 |
|
| 1981 |
Matsushita H, Negishi E. Selective carbon-carbon bond formation via transition-metal catalysis. Part 18. Palladium-catalyzed stereo- and regiospecific coupling of allylic derivatives with alkenyl- and arylmetals. A highly selective synthesis and 1,4-dienes Journal of the American Chemical Society. 103: 2882-2884. DOI: 10.1021/Ja00400A074 |
0.426 |
|
| 1981 |
Negishi E, Matsushita H, Okukado N. Highly selective synthesis of allylated arenes and diarylmethanes via palladium-catalyzed cross coupling involving benzylic derivatives Tetrahedron Letters. 22: 2715-2718. DOI: 10.1016/S0040-4039(01)90533-7 |
0.512 |
|
| 1981 |
Negishi E, Chatterjee S, Matsushita H. Scope of the palladium-catalyzed coupling reaction of organometallics with allylic electrophiles. Effect of the leaving group Tetrahedron Letters. 22: 3737-3740. DOI: 10.1016/S0040-4039(01)82007-4 |
0.498 |
|
| 1980 |
Kobayashi M, Valente LF, Negishi E, Patterson W, Silveira A. A Selective and Efficient Synthesis of (E)-4-Methyl-3-alken-1-ols via Zirconium-Catalyzed Carboalumination of Terminal Alkynes Synthesis. 1980: 1034-1035. DOI: 10.1055/S-1980-29313 |
0.438 |
|
| 1980 |
Kobayashi M, Negishi E. A palladium-catalyzed stereospecific substitution reaction of homoallylzincs with .beta.-bromo-substituted .alpha.,.beta.-unsaturated carbonyl derivatives. A highly selective synthesis of mokupalide The Journal of Organic Chemistry. 45: 5223-5225. DOI: 10.1021/Jo01313A048 |
0.39 |
|
| 1980 |
Negishi E, King AO, Klima WL, Patterson W, Silveira A. Conversion of methyl ketones into terminal acetylenes and (E)-trisubstituted olefins of terpenoid origin The Journal of Organic Chemistry. 45: 2526-2528. DOI: 10.1021/Jo01300A060 |
0.36 |
|
| 1980 |
Negishi E, Valente LF, Kobayashi M. Palladium-catalyzed cross-coupling reaction of homoallylic or homopropargylic organozincs with alkenyl halides as a new selective route to 1,5-dienes and 1,5-enynes Journal of the American Chemical Society. 102: 3298-3299. DOI: 10.1021/Ja00529A091 |
0.49 |
|
| 1980 |
Negishi E, Yoshida T. A novel zirconium-catalyzed hydroalumination of olefins Tetrahedron Letters. 21: 1501-1504. DOI: 10.1016/S0040-4039(00)92757-6 |
0.427 |
|
| 1980 |
Negishi E. Catalysis in Organic Synthesis Journal of Organometallic Chemistry. 199: C50. DOI: 10.1016/S0022-328X(00)83869-3 |
0.342 |
|
| 1979 |
Negishi E, Horn DEV, King AO, Okukado N. A Selective Synthesis of (E)-2-Methyl-1-alkenyl Iodides via Zirconium-Catalyzed Carboalumination Synthesis. 1979: 501-502. DOI: 10.1055/S-1979-28729 |
0.416 |
|
| 1978 |
Negishi E, Idacavage MJ, Chiu K, Yoshida T, Abramovitch A, Goettel ME, Silveira A, Bretherick HD. Scope of the reaction of organoboranes with organolithiums as a method of preparation of lithium organoborates. Stability of lithium organoborates Journal of the Chemical Society-Perkin Transactions 1. 10: 1225-1232. DOI: 10.1039/P29780001225 |
0.401 |
|
| 1978 |
King AO, Negishi E, Villani FJ, Silveira A. A general synthesis of terminal and internal arylalkynes by the palladium-catalyzed reaction of alkynylzinc reagents with aryl halides The Journal of Organic Chemistry. 43: 358-360. DOI: 10.1021/Jo00396A046 |
0.524 |
|
| 1978 |
Negishi E, Okukado N, King AO, Van Horn DE, Spiegel BI. Selective carbon-carbon bond formation via transition metal catalysts. 9. Double metal catalysis in the cross-coupling reaction and its application to the stereo- and regioselective synthesis of trisubstituted olefins Journal of the American Chemical Society. 100: 2254-2256. DOI: 10.1021/Ja00475A059 |
0.42 |
|
| 1978 |
Horn DEV, Negishi E. Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins Journal of the American Chemical Society. 100: 2252-2254. DOI: 10.1021/Ja00475A058 |
0.382 |
|
| 1978 |
Okukado N, Van Horn DE, Klima WL, Negishi E. A highly stereo- , regio- , and chemoselective synthesis of conjugated dienes by the palladium-catalyzed reaction of ()-1-alkenylzirconium derivatives with alkenyl halides Tetrahedron Letters. 19: 1027-1030. DOI: 10.1016/S0040-4039(01)85443-5 |
0.456 |
|
| 1977 |
Hughes RJ, Ncube S, Pelter A, Smith K, Negishi E, Yoshida T. Synthesis of secondary or tertiary alcohols by reactions of trialkylboranes with acyl carbanion equivalents Journal of the Chemical Society-Perkin Transactions 1. 8: 1172-1176. DOI: 10.1039/P19770001172 |
0.338 |
|
| 1977 |
King AO, Okukado N, Negishi E. Highly general stereo-, regio-, and chemo-selective synthesis of terminal and internal conjugated enynes by the Pd-catalysed reaction of alkynylzinc reagents with alkenyl halides Journal of the Chemical Society, Chemical Communications. 683-684. DOI: 10.1039/C39770000683 |
0.528 |
|
| 1977 |
Brown CA, Negishi E. Novel synthesis of an ω-alkynylorganometallic reagent via triple bond isomerization with potassium 3-aminopropylamide: ω-(9-borabicyclo[3.3.1]nonan-9-yl)alkl-1-ynes Journal of the Chemical Society, Chemical Communications. 318-319. DOI: 10.1039/C39770000318 |
0.469 |
|
| 1977 |
Negishi E, King AO, Okukado N. Selective carbon-carbon bond formation via transition metal catalysis. 3. A highly selective synthesis of unsymmetrical biaryls and diarylmethanes by the nickel- or palladium-catalyzed reaction of aryl- and benzylzinc derivatives with aryl halides The Journal of Organic Chemistry. 42: 1821-1823. DOI: 10.1021/Jo00430A041 |
0.468 |
|
| 1977 |
Negishi E, Horn DEV. Selective carbon-carbon bond formation via transition metal catalysis. 4. A novel approach to cross-coupling exemplified by the nickel-catalyzed reaction of alkenylzirconium derivatives with aryl halides Journal of the American Chemical Society. 99: 3168-3170. DOI: 10.1021/Ja00451A055 |
0.413 |
|
| 1976 |
Negishi E, Baba S. Novel stereoselective alkenyl–aryl coupling via nickel-catalysed reaction of alkenylanes with aryl halides Journal of the Chemical Society, Chemical Communications. DOI: 10.1039/C3976000596B |
0.522 |
|
| 1976 |
Negishi E, Baba S, King AO. Stereoselective synthesis of β-hydroxy substituted trans-alkenes by the reaction of trans-alkenyltrialkylaluminates with epoxides Journal of the Chemical Society, Chemical Communications. 17-18. DOI: 10.1039/C39760000017 |
0.448 |
|
| 1976 |
Negishi E, Chiu K. A novel intermolecular transfer reaction of alkenyltrialkylborates with aqueous bases and its application to the protonolysis of alkenylboron derivatives Journal of Organic Chemistry. 41: 3484-3486. DOI: 10.1021/Jo00883A040 |
0.372 |
|
| 1976 |
Baba S, Negishi E. A novel stereospecific alkenyl-alkenyl cross-coupling by a palladium- or nickel-catalyzed reaction of alkenylalanes with alkenyl halides Journal of the American Chemical Society. 98: 6729-6731. DOI: 10.1021/Ja00437A067 |
0.488 |
|
| 1976 |
Baba S, Van Horn DE, Negishi E. A stereoselective synthesis of disubstituted trans-alkenes by the reaction of trans-alkenyl trialkylaluminates with alkyl halides and sulfonates Tetrahedron Letters. 17: 1927-1930. DOI: 10.1016/S0040-4039(00)78081-6 |
0.42 |
|
| 1976 |
Hughes RJ, Pelter A, Smith K, Negishi E, Yoshida T. Preparation of secondary alcohols by reaction of trialkylboranes with bis(phenylthio)methyl-lithium Tetrahedron Letters. 17: 87-88. DOI: 10.1016/S0040-4039(00)71332-3 |
0.371 |
|
| 1976 |
Negishi EI, Sabanski M, Katz JJ, Brown HC. An efficient synthesis of juvabione and todomatuic acid via hydroboration-carbonylation Tetrahedron. 32: 925-926. DOI: 10.1016/0040-4020(76)85050-8 |
0.373 |
|
| 1976 |
C. Brown H, Negishi E, U. Kulkarni S. Organoborane Heterocycles via Cyclic Hydroboration of Dienes Heterocycles. 5: 883. DOI: 10.1002/Chin.197717236 |
0.456 |
|
| 1976 |
Negishi E, Baba S, King AO. STEREOSELECTIVE SYNTHESIS OF β-HYDROXY SUBSTITUTED TRANS-ALKENES BY THE REACTION OF TRANS-ALKENYLTRIALKYLALUMINATES WITH EPOXIDES Cheminform. 7. DOI: 10.1002/Chin.197615153 |
0.461 |
|
| 1975 |
Negishi E, Chiu K, Yoshida T. Intermolecular alkyl-transfer reaction of tetraorganoborate anions with acyl halides. Novel method for moderating the carbanion reactivity The Journal of Organic Chemistry. 40: 1676-1677. DOI: 10.1021/Jo00899A046 |
0.397 |
|
| 1975 |
Negishi E, Baba S. Convenient method for the tertiary alkyl-alkynyl coupling via organoalanes Journal of the American Chemical Society. 97: 7385-7387. DOI: 10.1021/Ja00858A035 |
0.361 |
|
| 1975 |
Brown HC, Katz JJ, Lane CF, Negishi E. Hydroboration. XXXVIII. Structural study of the hydroboration of olefins with thexylmonoalkylboranes. Convenient route to thexyldialkylboranes, mixed dialkylboranes, and mixed trialkylboranes Journal of the American Chemical Society. 97: 2799-2804. DOI: 10.1021/Ja00843A031 |
0.383 |
|
| 1975 |
Brown HC, Negishi E, Katz JJ. Hydroboration. XXXVII. Structural study of the hydroboration of olefins with thexylborane in the molar ratio of 1:1. Convenient synthesis of thexylmonoalkylboranes and their ready conversion to monoalkylboranes Journal of the American Chemical Society. 97: 2791-2798. DOI: 10.1021/Ja00843A030 |
0.48 |
|
| 1975 |
BROWN HC, KATZ J, LANE CF, NEGISHI E. ChemInform Abstract: HYDROBORATION PART 38, STRUCTURAL STUDY OF THE HYDROBORATION OF OLEFINS WITH THEXYLMONOALKYLBORANES, A CONVENIENT ROUTE TO THEXYLDIALKYLBORANES, MIXED DIALKYLBORANES, AND MIXED TRIALKYLBORANES Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/Chin.197531296 |
0.406 |
|
| 1975 |
Negishi Ei, Abramovitch A, Merrill RE. A novel regiospecific aryl ketone synthesis by the reaction of arylborate anions with acyl chlorides Journal of the Chemical Society, Chemical Communications. 138-139. DOI: 10.1002/Chin.197523269 |
0.515 |
|
| 1975 |
Negishi E, Merrill RE. Novel And Regioselective Aromatic Double Substitution Involving Borate Anions And A Regio- And Stereo-Selective Route To Dihydroaromatic Derivatives Cheminform. 6. DOI: 10.1002/Chin.197506228 |
0.412 |
|
| 1974 |
NEGISHI E, BROWN HC. Thexylborane-A Highly Versatile Reagent for Organic Synthesis via Hydroboration Synthesis. 1974: 77-89. DOI: 10.1055/S-1974-23248 |
0.473 |
|
| 1974 |
Negishi E, Merrill RE. Novel and regioselective aromatic double substitution involving borate anions and a regio- and stereo-selective route to dihydroaromatic derivatives Journal of the Chemical Society, Chemical Communications. 860-861. DOI: 10.1039/C39740000860 |
0.432 |
|
| 1974 |
Merrill RE, Negishi E. Tetrahydrofuran-promoted aryl-alkyl coupling involving organolithium reagents The Journal of Organic Chemistry. 39: 3452-3453. DOI: 10.1021/Jo00937A048 |
0.443 |
|
| 1974 |
Negishi E, Lew G, Yoshida T. Novel stereoselective synthesis of (E)- and (Z)-.alpha.,.beta.-unsaturated carboxylic esters via hydroboration Journal of Organic Chemistry. 39: 2321-2322. DOI: 10.1021/Jo00929A056 |
0.339 |
|
| 1974 |
Yoshida T, Williams RM, Negishi E. Stereoselective synthesis of partially substituted 1,2,3-butatriene derivatives via hydroboration Journal of the American Chemical Society. 96: 3688-3690. DOI: 10.1021/Ja00818A073 |
0.467 |
|
| 1974 |
Negishi E, Lew G, Yoshida T. Stereoselective Synthesis Of Conjugated Trans-Enynes Readily Convertible Into Conjugated Cis,Trans-Dienes And Its Application To The Synthesis Of The Pheromone Bombykol Cheminform. 5. DOI: 10.1002/Chin.197408180 |
0.39 |
|
| 1973 |
Negishi EI, Yoshida T. An intramolecular Michael reaction involving borate complexes. A novel synthesis of -hydroxycarboxylic acids. Journal of the American Chemical Society. 95: 6837-8. PMID 4746280 DOI: 10.1021/Ja00801A056 |
0.442 |
|
| 1973 |
Negishi E, Lew G, Yoshida T. Stereoselective synthesis of conjugated trans-enynes readily convertible into conjugated cis,trans-dienes and its application to the synthesis of the pheromone bombykol Journal of the Chemical Society, Chemical Communications. 874-875. DOI: 10.1039/C39730000874 |
0.392 |
|
| 1973 |
Negishi E, Yoshida T. A highly stereoselective and general synthesis of conjugated trans,trans-dienes and trans-alkyl ketones via hydroboration Journal of the Chemical Society, Chemical Communications. 606-607. DOI: 10.1039/C39730000606 |
0.447 |
|
| 1973 |
Negishi E, Brown HC. Hydroboration. XXXV. Cyclic hydroboration of 2,4-dimethyl-1,4-pentadiene and 2,5-dimethyl-1,5-hexadiene. Simple synthesis of bis(3,5-dimethyl)borinane and bis(3,6-dimethyl)borepane and their application to the 1,4-addition reaction of organoboranes Journal of the American Chemical Society. 95: 6757-6763. DOI: 10.1021/Ja00801A038 |
0.583 |
|
| 1973 |
Burke PL, Negishi E, Brown HC. Hydroboration. XXXIV. Cyclic hydroboration of 1,5-hexadiene with borane in tetrahydrofuran and 9-borabicyclo[3.3.1]nonane. New convenient route to the borepane ring system utilizing 9-borabicyclo[3.3.1]nonane Journal of the American Chemical Society. 95: 3654-3662. DOI: 10.1021/Ja00792A032 |
0.466 |
|
| 1973 |
Negishi E, Yoshida T. An Intramolecular Michael Reaction Involving Borate Complexes, A Novel Synthesis Of Beta-Hydroxycarboxylic Acids Cheminform. 4. DOI: 10.1002/Chin.197350218 |
0.387 |
|
| 1973 |
NEGISHI E, BROWN HC. ChemInform Abstract: HYDROBORATION PART 35, CYCLIC HYDROBORATION OF 2,4-DIMETHYL-1,4-PENTADIENE AND 2,5-DIMETHYL-1,5-HEXADIENE, A SIMPLE SYNTHESIS OF BIS(3,5-DIMETHYL)BORINANE AND BIS(3,6-DIMETHYL)BOREPANE AND THEIR APPLICATION TO THE 1,4-ADDITION REACTIO Chemischer Informationsdienst. 4: no-no. DOI: 10.1002/Chin.197349368 |
0.544 |
|
| 1973 |
NEGISHI E, KATZ J, BROWN HC. ChemInform Abstract: ANWENDUNG VON THEXYLMONOALKYLBORANEN ZUR STEREOSELEKTIVEN SYNTH. VON TRANS-DISUBSTITUIERTEN OLEFINEN Chemischer Informationsdienst. 4: no-no. DOI: 10.1002/Chin.197304166 |
0.316 |
|
| 1972 |
Brown HC, Negishi E. The cyclic hydroboration of dienes. A simple convenient route to heterocyclic organoboranes Pure and Applied Chemistry. 29: 527-546. DOI: 10.1351/Pac197229040527 |
0.491 |
|
| 1972 |
NEGISHI E, BROWN HC. The Reaction of Organoboranes Containing a Tertiary Alkyl Group with Carbon Monoxide. A New Approach to the Synthesis of Highly Branched Trialkylcarbinols Synthesis. 1972: 197-199. DOI: 10.1055/S-1972-21851 |
0.517 |
|
| 1972 |
NEGISHI E, BROWN HC. A General Multi-Carbon Homologation of OlefinsviaHydroboration-Carbonylation Synthesis. 1972: 196-197. DOI: 10.1055/S-1972-21850 |
0.375 |
|
| 1972 |
Negishi E, Burke PL, Brown HC. Hydroboration. XXXIII. Cyclic hydroboration of 1,4-pentadiene with borane in tetrahydrofuran. Thermal behavior of the organoborane derivatives and a simple synthesis of bisborinane and .beta.-alkylborinanes Journal of the American Chemical Society. 94: 7431-7437. DOI: 10.1021/Ja00776A028 |
0.407 |
|
| 1972 |
Brown HC, Negishi E, Katz JJ. Remarkably facile and selective dehydroboration of tetramethylethylene from thexylmonoalkylboranes under the influence of triethylamine. Novel, convenient synthesis of monoalkylboranes as triethylaminates Journal of the American Chemical Society. 94: 5893-5894. DOI: 10.1021/Ja00771A059 |
0.474 |
|
| 1972 |
Brown HC, Negishi E. Hydroboration. XXXII. Cyclic hydroboration of dienes with thexylborane Journal of the American Chemical Society. 94: 3567-3572. DOI: 10.1021/Ja00765A051 |
0.5 |
|
| 1972 |
Brown HC, Negishi E, Burke PL. Hydroboration. XXXI. Cyclic hydroboration of dienes with borane in tetrahydrofuran in the molar ratio of 1:1 Journal of the American Chemical Society. 94: 3561-3567. DOI: 10.1021/Ja00765A050 |
0.445 |
|
| 1972 |
NEGISHI E, BURKE PL, BROWN HC. ChemInform Abstract: HYDROBORIERUNG 33. MITT. CYCLISCHE HYDROBORIERUNG VON PENTADIEN-(1,4) MIT BORAN IN TETRAHYDROFURAN, THERMISCHES VERH. VON ORGANOBORDERIVATEN UND EINFACHE SYNTH. VON BISBORINAN UND B-ALKYLBORINANEN Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197252320 |
0.368 |
|
| 1972 |
BROWN HC, NEGISHI E, KATZ J. ChemInform Abstract: BEMERKENSWERT LEICHTE UND SELEKTIVE DEHYDROBORIERUNG VON TETRAMETHYLAETHYLEN AUS THEXYLMONOALKYLBORANEN UNTER DEM EINFLUSS VON TRIAETHYLAMIN, NEUE, BEQUEME SYNTH. VON MONOALKYLBORANEN ALS TRIAETHYLAMINATE Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197244377 |
0.346 |
|
| 1972 |
BROWN HC, NEGISHI E. ChemInform Abstract: HYDROBORIERUNG 32. MITT. CYCLISCHE HYDROBORIERUNG VON DIENEN MIT THEXYLBORAN Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197232328 |
0.393 |
|
| 1972 |
BROWN HC, NEGISHI E, BURKE PL. ChemInform Abstract: HYDROBORIERUNG 31. MITT. CYCLISCHE HYDROBORIERUNG VON DIENEN MIT BORAN IN TETRAHYDROFURAN IM MOLVERHAELTNIS 1 ZU 1 Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197232327 |
0.415 |
|
| 1972 |
BROWN HC, NEGISHI E. ChemInform Abstract: BIS-(BOROLAN), EIN SCHWER FASSBARES BIS-(BORACYCLAN) Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197206313 |
0.451 |
|
| 1971 |
Brown HC, Negishi E. Bisborolane. Highly elusive bisboracyclane Journal of the American Chemical Society. 93: 6682-6683. DOI: 10.1021/Ja00753A063 |
0.416 |
|
| 1971 |
Brown HC, Negishi E. Facile reaction of B-alkylboracyclanes with .alpha.,.beta.-unsaturated carbonyl derivatives. Extension of the 1,4-addition reaction via organoboranes to highly branched secondary and tertiary alkyl groups Journal of the American Chemical Society. 93: 3777-3779. DOI: 10.1021/Ja00744A043 |
0.491 |
|
| 1971 |
Brown HC, Negishi E, Burke PL. Organoboranes. XII. Hydroboration of 1,3-butadiene with borane in tetrahydrofuran in a ratio equal to or smaller than 1:1. Interconversion between .beta.-alkylborolanes and 1,2-tetramethylenediboranes Journal of the American Chemical Society. 93: 3400-3409. DOI: 10.1021/Ja00743A017 |
0.328 |
|
| 1971 |
Brown HC, Negishi E. A simple synthesis of bisborinane and its applicability in hydroboration for the preparation ofB-alkylborinanes Journal of Organometallic Chemistry. 26: C67-C69. DOI: 10.1016/S0022-328X(00)82607-8 |
0.492 |
|
| 1971 |
Brown HC, Negishi E. A simple synthesis of bis(3,5-dimethyl)borinane and bis(3,6-dimethyl)borepane as new valuable reagents via cyclic hydroboration Journal of Organometallic Chemistry. 28: C1-C4. DOI: 10.1016/S0022-328X(00)81562-4 |
0.535 |
|
| 1971 |
BROWN HC, NEGISHI E. ChemInform Abstract: EINFACHE RK. VON B-ALKYLBORACYCLANEN MIT ALPHA,BETA-UNGESAETTIGTEN CARBONYLDERIVATEN, ERWEITERUNG DER 1,4-ADDITIONSRK. UEBER ORGANOBORANE AUF HOCHVERZWEIGTE SEKUNDAERE UND TERTIAERE ALKYLGRUPPEN Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197141003 |
0.342 |
|
| 1971 |
BROWN HC, NEGISHI E, BURKE PL. ChemInform Abstract: ORGANOBORANE 12. MITT. HYDROBORIERUNG VON BUTADIEN-(1,3) MIT BORAN IN THF, GEGENSEITIGE UMWANDLUNG VON B-ALKYL-BOROLANEN UND 1,2-TETRAMETHYLEN-DIBORANEN Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197140002 |
0.419 |
|
| 1971 |
SUZUKI A, MIYAURA N, ITOH M, BROWN HC, HOLLAND GW, NEGISHI E. ChemInform Abstract: NEUE VIER-KOHLENSTOFFATOM-HOMOLOGISIERUNG DURCH RADIKALKETTENRK. VON BUTADIEN-(1,3)-MONOXID MIT ORGANOBORANEN, SYNTH. VON 4-ALKYL-BUTEN-(2)-OLEN-(1) AUS OLEFINEN DURCH HYDROBORIERUNG Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197135252 |
0.538 |
|
| 1971 |
BROWN HC, NEGISHI E, BURKE PL. ChemInform Abstract: LEICHTE OEFFNUNG DES BOROLANRINGES DURCH BORAN, EINFACHER ZUGANG ZU 1,2-TETRAMETHYLENDIBORANEN Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197103003 |
0.378 |
|
| 1971 |
BROWN HC, NEGISHI E, GUPTA SK. ChemInform Abstract: RK. VON B-METHOXY-DIALKYLBORANEN MIT LI-AL-HYDRID IN GEGENWART VON OLEFINEN, SYNTH. VON GEMISCHTEN ACYCLISCHEN UND CYCLISCHEN TRIALKYLBORANEN UND UMWANDLUNG IN TRIALKYLCARBINOLE Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197103001 |
0.369 |
|
| 1970 |
Brown HC, Negishi E, Burke PL. Facile opening of the borolane ring with borane. A simple entry into 1,2-tetramethylenediboranes Journal of the American Chemical Society. 92: 6649-6651. DOI: 10.1021/Ja00725A051 |
0.427 |
|
| 1970 |
Brown HC, Negishi E, Gupta SK. Reaction of B-methoxydialkylboranes with lithium aluminum hydride in the presence of olefins. A new and general synthesis of acyclic and cyclic mixed trialkylboranes and their conversion into the corresponding trialkylcarbinols via carbonylation-oxidation Journal of the American Chemical Society. 92: 6648-6649. DOI: 10.1021/Ja00725A050 |
0.533 |
|
| 1970 |
Brown HC, Negishi E, Gupta SK. Organoboranes. IX. Structure of the organoboranes formed in the reaction of 1,3-butadiene and diborane in the stoichiometric ratio. An unusual thermal isomerization of these organoboranes Journal of the American Chemical Society. 92: 2460-2467. DOI: 10.1021/Ja00711A042 |
0.445 |
|
| 1970 |
BROWN HC, NEGISHI E, GUPTA SK. ChemInform Abstract: ORGANOBORANE 9. MITT. STRUKTUR DER BEI DER RK. 1,3-BUTADIEN UND DIBORAN UNTER STOECHIOMETRISCHEM VERHAELTNIS GEBILDETEN ORGANOBORANE. UNGEWOEHNLICHE THERMISCHE ISOMERISIERUNG DIESER ORGANOBORANE Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197028001 |
0.385 |
|
| 1969 |
Suzuki A, Nozawa S, Itoh M, Brown HC, Negishi E, Gupta SK. Reaction of the cyclic organoboranes from dienes with methyl vinyl ketone. A convenient synthesis of ω-hydroxy-ketones from dienes via hydroboration Journal of the Chemical Society D: Chemical Communications. 1009-1010. DOI: 10.1039/C29690001009 |
0.632 |
|
| 1969 |
Brown HC, Negishi E. Conversion of linear trienes into bicyclic boranes via hydroboration-isomerization and their carbonylation. A simple synthesis of angularly substituted bicyclic alcohols Journal of the American Chemical Society. 91: 1224-1226. DOI: 10.1021/Ja01033A037 |
0.474 |
|
| 1968 |
Brown HC, Negishi E. A general stereospecific annelation for the synthesis of trans-fused polycyclic ketones via hydroboration–carbonylation Chemical Communications (London). 594-595. DOI: 10.1039/C19680000594 |
0.544 |
|
| 1967 |
Brown HC, Negishi E. Carbonylation of perhydro-9b-boraphenalene to form perhydro-9b-phenalenol. New general synthesis of polycyclic derivatives Journal of the American Chemical Society. 89: 5478-5480. DOI: 10.1021/Ja00997A046 |
0.432 |
|
| 1967 |
Brown HC, Negishi E. Carbonylation of the organoboranes from the cyclic hydroboration of dienes with thexylborane. Simple procedure for the conversion of dienes into cyclic ketones Journal of the American Chemical Society. 89: 5477-5478. DOI: 10.1021/Ja00997A045 |
0.49 |
|
| 1967 |
Brown HC, Negishi E. Carbonylation of thexyldialkylboranes. New general synthesis of ketones Journal of the American Chemical Society. 89: 5285-5287. DOI: 10.1021/Ja00996A037 |
0.52 |
|
| Show low-probability matches. |
