| Year |
Citation |
Score |
| 2020 |
Gray M, Hines MT, Parsutkar MM, Wahlstrom AJ, Brunelli NA, RajanBabu TV. Mechanism of Cobalt-Catalyzed Heterodimerization of Acrylates and 1,3-Dienes. A Potential Role of Cationic Cobalt(I) Intermediates. Acs Catalysis. 10: 4337-4348. PMID 32457820 DOI: 10.1021/Acscatal.9B05455 |
0.515 |
|
| 2019 |
Klare S, Gordon JP, Gansäuer A, RajanBabu TV, Nugent WA. The Reaction of β,γ-Epoxy Alcohols with Titanium(III) Reagents. A Proposed Role for Intramolecular Hydrogen Bonding. Tetrahedron. 75. PMID 32601512 DOI: 10.1016/J.Tet.2019.130662 |
0.43 |
|
| 2019 |
Parsutkar MM, Pagar VV, RajanBabu TV. Catalytic Enantioselective Synthesis of Cyclobutenes from Alkynes and Alkenyl Derivatives. Journal of the American Chemical Society. 141: 15367-15377. PMID 31476274 DOI: 10.1021/Jacs.9B07885 |
0.578 |
|
| 2019 |
Duvvuri K, Dewese KR, Parsutkar MM, Jing SM, Mehta MM, Gallucci JC, RajanBabu TV. Cationic Co(I)-Intermediates for Hydrofunctionalization Reactions: Regio- and Enantioselective Cobalt-Catalyzed 1,2-Hydroboration of 1,3-Dienes. Journal of the American Chemical Society. PMID 31020835 DOI: 10.1021/Jacs.8B13812 |
0.569 |
|
| 2018 |
Gordon J, Hildebrandt S, Dewese KR, Klare S, Gansäuer A, RajanBabu TV, Nugent WA. Demystifying CpTi(H)Cl and its Enigmatic Role in the Reactions of Epoxides with CpTiCl. Organometallics. 37: 4801-4809. PMID 30733623 DOI: 10.1021/Acs.Organomet.8B00793 |
0.443 |
|
| 2018 |
Tenneti S, Biswas S, Cox GA, Mans D, Lim HJ, RajanBabu TV. Broadly Applicable Stereoselective Syntheses of Serrulatane, Amphilectane Diterpenes and Their Diastereoisomeric Congeners using Asymmetric Hydrovinylation for Absolute Stereochemical Control. Journal of the American Chemical Society. PMID 30001133 DOI: 10.1021/Jacs.8B03549 |
0.511 |
|
| 2018 |
Pagar VV, RajanBabu TV. Tandem catalysis for asymmetric coupling of ethylene and enynes to functionalized cyclobutanes. Science (New York, N.Y.). 361: 68-72. PMID 29976822 DOI: 10.1126/Science.Aat6205 |
0.491 |
|
| 2018 |
Timsina YN, Biswas S, RajanBabu TV. Retraction of "Chemoselective Reactions of (E)-1,3-Dienes: Cobalt-Mediated Isomerization to (Z)-1,3-Dienes and Reactions with Ethylene". Journal of the American Chemical Society. PMID 29409319 DOI: 10.1021/Jacs.7B08973 |
0.461 |
|
| 2017 |
Jing SM, Balasanthiran V, Pagar V, Gallucci JC, RajanBabu TV. Catalytic Enantioselective Heterodimerization of Acrylates and 1,3-Dienes. Journal of the American Chemical Society. PMID 29120629 DOI: 10.1021/Jacs.7B10055 |
0.553 |
|
| 2017 |
Zhiquan L, Polen SM, Hadad CM, RajanBabu TV, Badjić JD. Examining the Scope and Thermodynamics of Assembly in Nesting Complexes Comprising Molecular Baskets and TPA Ligands. Organic Letters. PMID 28846424 DOI: 10.1021/Acs.Orglett.7B02391 |
0.329 |
|
| 2017 |
Raya B, Jing S, RajanBabu TV. Control of Selectivity through Synergy between Catalysts, Silanes and Reaction Conditions in Cobalt-Catalyzed Hydrosilylation of Dienes and Terminal Alkenes. Acs Catalysis. 7: 2275-2283. PMID 28593082 DOI: 10.1021/Acscatal.6B03373 |
0.53 |
|
| 2016 |
Raya B, Biswas S, RajanBabu TV. Selective Cobalt-Catalyzed Reduction of Terminal Alkenes and Alkynes Using (EtO)2Si(Me)H as a Stoichiometric Reductant. Acs Catalysis. 6: 6318-6323. PMID 28078166 DOI: 10.1021/Acscatal.6B02272 |
0.529 |
|
| 2016 |
Zhiquan L, Polen SM, Hadad CM, RajanBabu TV, Badjic JD. Russian Nesting Doll Complexes of Molecular Baskets and Zinc Containing TPA Ligands. Journal of the American Chemical Society. PMID 27305044 DOI: 10.1021/Jacs.6B04436 |
0.388 |
|
| 2016 |
Raya B, Biswas S, Rajanbabu TV. Selective Cobalt-Catalyzed Reduction of Terminal Alkenes and Alkynes Using (EtO)2Si(Me)H as a Stoichiometric Reductant Acs Catalysis. 6: 6318-6323. DOI: 10.1021/acscatal.6b02272 |
0.444 |
|
| 2015 |
Biswas S, Page JP, Dewese KR, RajanBabu TV. Asymmetric Catalysis with Ethylene. Synthesis of Functionalized Chiral Enolates. Journal of the American Chemical Society. PMID 26529467 DOI: 10.1021/Jacs.5B10364 |
0.578 |
|
| 2015 |
Timsina YN, Sharma RK, RajanBabu TV. Cobalt-Catalysed Asymmetric Hydrovinylation of 1,3-Dienes. Chemical Science (Royal Society of Chemistry : 2010). 6: 3994-4008. PMID 26430505 DOI: 10.1039/C5Sc00929D |
0.523 |
|
| 2014 |
Biswas S, Zhang A, Raya B, RajanBabu TV. Triarylphosphine Ligands with Hemilabile Alkoxy Groups. Ligands for Nickel(II)-Catalyzed Olefin Dimerization Reactions. Hydrovinylation of Vi-nylarenes, 1,3-Dienes, and Cycloisomerization of 1,6-Dienes. Advanced Synthesis & Catalysis. 356: 2281-2292. PMID 25395919 DOI: 10.1002/Adsc.201400237 |
0.454 |
|
| 2014 |
Timsina YN, Biswas S, RajanBabu TV. Chemoselective reactions of (E)-1,3-dienes: cobalt-mediated isomerization to (Z)-1,3-dienes and reactions with ethylene. Journal of the American Chemical Society. 136: 6215-8. PMID 24712838 DOI: 10.1021/Ja501979G |
0.485 |
|
| 2014 |
Wu B, Gallucci JC, Parquette JR, Rajanbabu TV. Bimetallic catalysis in the highly enantioselective ring-opening reactions of aziridines Chemical Science. 5: 1102-1117. DOI: 10.1039/C3Sc52929K |
0.569 |
|
| 2014 |
RajanBabu TV. Hydrocyanation in Organic Synthesis Comprehensive Organic Synthesis: Second Edition. 5: 1772-1793. DOI: 10.1016/B978-0-08-097742-3.00537-1 |
0.473 |
|
| 2014 |
RajanBabu TV, Adam Cox G, Lim HJ, Nomura N, Sharma RK, Smith CR, Zhang A. Hydrovinylation Reactions in Organic Synthesis Comprehensive Organic Synthesis: Second Edition. 5: 1582-1620. DOI: 10.1016/B978-0-08-097742-3.00533-4 |
0.466 |
|
| 2013 |
Gong W, Rajanbabu TV. Conformation and reactivity in dibenzocyclooctadienes (DBCOD). A general approach to the total synthesis of fully substituted DBCOD lignans via borostannylative cyclization of α,ω-diynes Chemical Science. 4: 3979-3985. DOI: 10.1039/C3Sc51751A |
0.416 |
|
| 2013 |
Choi JH, Kwon JK, Rajanbabu TV, Lim HJ. Highly efficient catalytic dimerization of styrenes via cationic Palladium(II) complexes Advanced Synthesis and Catalysis. 355: 3633-3638. DOI: 10.1002/Adsc.201300864 |
0.453 |
|
| 2013 |
Rajanbabu TV. Asymmetric Hydrovinylation of Alkenes Asymmetric Synthesis Ii: More Methods and Applications. 293-301. DOI: 10.1002/9783527652235.ch37 |
0.39 |
|
| 2012 |
Page JP, RajanBabu TV. Asymmetric hydrovinylation of 1-vinylcycloalkenes. Reagent control of regio- and stereoselectivity. Journal of the American Chemical Society. 134: 6556-9. PMID 22452442 DOI: 10.1021/Ja301640E |
0.487 |
|
| 2012 |
Liu W, Lim HJ, RajanBabu TV. Asymmetric hydrovinylation of vinylindoles. A facile route to cyclopenta[g]indole natural products (+)-cis-trikentrin A and (+)-cis-trikentrin B. Journal of the American Chemical Society. 134: 5496-9. PMID 22394308 DOI: 10.1021/Ja3004733 |
0.473 |
|
| 2012 |
Gong W, Singidi RR, Gallucci JC, Rajanbabu TV. On the stereochemistry of acetylide additions to highly functionalized biphenylcarbaldehydes and multi-component cyclization of 1,n-diynes. Syntheses of dibenzocyclooctadiene lignans Chemical Science. 3: 1221-1230. DOI: 10.1039/C2Sc00920J |
0.535 |
|
| 2012 |
RajanBabu TV, Smith CR. 5.16 Reduction: Enantioselective Hydrovinylation of Alkenes Comprehensive Chirality. 5: 355-398. DOI: 10.1016/B978-0-08-095167-6.00518-8 |
0.477 |
|
| 2011 |
Lim HJ, RajanBabu TV. Ethylene in organic synthesis: a new route to anticholenergic pyrrolidinoindolines, and other molecules with all carbon-quaternary centers via asymmetric hydrovinylation. Organic Letters. 13: 6596-9. PMID 22103775 DOI: 10.1021/Ol203052Y |
0.403 |
|
| 2011 |
Mans DJ, Cox GA, RajanBabu TV. Ethylene in organic synthesis. Repetitive hydrovinylation of alkenes for highly enantioselective syntheses of pseudopterosins. Journal of the American Chemical Society. 133: 5776-9. PMID 21449569 DOI: 10.1021/Ja201321V |
0.527 |
|
| 2011 |
Rajanbabu TV. Hydrocyanation of alkenes and alkynes Organic Reactions. 75: 1-74. DOI: 10.1002/0471264180.Or075.01 |
0.504 |
|
| 2010 |
Liu W, RajanBabu TV. Reactivity and selectivity in hydrovinylation of strained alkenes. The Journal of Organic Chemistry. 75: 7636-43. PMID 20964350 DOI: 10.1021/Jo1015135 |
0.47 |
|
| 2010 |
Singidi RR, Kutney AM, Gallucci JC, RajanBabu TV. Stereoselective cyclization of functionalized 1,n-diynes mediated by [X-Y] reagents [X-Y = R3Si-SnR'3 or (R2N)2B-SnR'3]: synthesis and properties of atropisomeric 1,3-dienes. Journal of the American Chemical Society. 132: 13078-87. PMID 20806918 DOI: 10.1021/Ja105939V |
0.417 |
|
| 2010 |
Smith CR, Rajanbabu TV. Low Pressure Vinylation of Aryl and Vinyl Halides via Heck-Mizoroki Reactions Using Ethylene. Tetrahedron. 66: 1102-1110. PMID 20676383 DOI: 10.1016/J.Tet.2009.11.017 |
0.488 |
|
| 2010 |
Singidi RR, RajanBabu TV. Borostannylation of alkynes and enynes. Scope and limitations of the reaction and utility of the adducts. Organic Letters. 12: 2622-5. PMID 20459076 DOI: 10.1021/Ol100824F |
0.509 |
|
| 2010 |
Lim HJ, Gallucci JC, RajanBabu TV. Annulated diketopiperazines from dipeptides or Schöllkopf reagents via tandem cyclization-intramolecular N-arylation. Organic Letters. 12: 2162-5. PMID 20387855 DOI: 10.1021/Ol100663Y |
0.437 |
|
| 2010 |
Sanan TT, Rajanbabu TV, Hadad CM. Mechanism and stereoselection in a Y-catalyzed transacylation reaction. A computational modeling study. The Journal of Organic Chemistry. 75: 2369-81. PMID 20222696 DOI: 10.1021/Jo100206D |
0.499 |
|
| 2010 |
Sharma RK, RajanBabu TV. Asymmetric hydrovinylation of unactivated linear 1,3-dienes. Journal of the American Chemical Society. 132: 3295-7. PMID 20163120 DOI: 10.1021/Ja1004703 |
0.522 |
|
| 2010 |
Sharma RK, RajanBabu TV. Asymmetric Hydrovinylation of 1,3-Dienes Synfacts. 2010: 672-672. DOI: 10.1055/S-0029-1219871 |
0.467 |
|
| 2010 |
Ayers TA, RajanBabu TV. ChemInform Abstract: Practical Catalysts for Asymmetric Synthesis: Ligands from Natural Sugars for Rh-Catalyzed Asymmetric Synthesis of D- and L-Amino Acids Cheminform. 31: no-no. DOI: 10.1002/chin.200020277 |
0.345 |
|
| 2010 |
RAJANBABU TV, CASALNUOVO AL, AYERS TA. ChemInform Abstract: Ligand Tuning in Asymmetric Catalysis: Hydrocyanation and Hydrogenation Reactions Cheminform. 29: no-no. DOI: 10.1002/chin.199829356 |
0.391 |
|
| 2010 |
Rajanbabu TV. Exocyclic and acyclic stereocontrol in catalyzed reactions of ethylene: Asymmetric hydrovinylation reactions in natural product synthesis Acs National Meeting Book of Abstracts. |
0.449 |
|
| 2009 |
Joseph J, Rajanbabu TV, Jemmis ED. A Theoretical Investigation of the Ni(II)-Catalyzed Hydrovinylation of Styrene. Organometallics. 28: 3552-3566. PMID 21532981 DOI: 10.1021/Om900045P |
0.37 |
|
| 2009 |
Wu B, Parquette JR, RajanBabu TV. Regiodivergent ring opening of chiral aziridines. Science (New York, N.Y.). 326: 1662. PMID 20019280 DOI: 10.1126/Science.1180739 |
0.448 |
|
| 2009 |
Smith CR, Lim HJ, Zhang A, Rajanbabu TV. Tunable Phosphoramidite Ligands for Asymmetric Hydrovinylation: Ligands par excellence for Generation of All-Carbon Quaternary Centers. Synthesis. 12: 2089-2100. PMID 19763244 DOI: 10.1055/S-0029-1216826 |
0.488 |
|
| 2009 |
Rajanbabu TV. In Pursuit of an Ideal C-C Bond-Forming Reaction: Development and Applications of the Hydrovinylation of Olefins. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 2009: 853-885. PMID 19606231 DOI: 10.1055/s-0028-1088213 |
0.396 |
|
| 2009 |
Lim HJ, RajanBabu TV. Seleniranium ion-triggered reactions: new aspects of Friedel-Crafts and N-detosylative cyclizations. Organic Letters. 11: 2924-7. PMID 19507847 DOI: 10.1021/Ol900961M |
0.398 |
|
| 2009 |
Lim HJ, Smith CR, RajanBabu TV. Facile Pd(II)- and Ni(II)-catalyzed isomerization of terminal alkenes into 2-alkenes. The Journal of Organic Chemistry. 74: 4565-72. PMID 19441793 DOI: 10.1021/Jo900180P |
0.466 |
|
| 2009 |
Smith CR, RajanBabu TV. Catalytic asymmetric synthesis using feedstocks: an enantioselective route to 2-arylpropionic acids and 1-arylethyl amines via hydrovinylation of vinyl arenes. The Journal of Organic Chemistry. 74: 3066-72. PMID 19317393 DOI: 10.1021/Jo900198B |
0.519 |
|
| 2009 |
Wu B, Gallucci JC, Parquette JR, RajanBabu TV. Enantioselective desymmetrization of meso-aziridines with TMSN3 or TMSCN catalyzed by discrete yttrium complexes. Angewandte Chemie (International Ed. in English). 48: 1126-9. PMID 19021173 DOI: 10.1002/Anie.200804415 |
0.449 |
|
| 2009 |
Wu B, Gallucci JC, Parquette JR, RajanBabu TV. Yttrium-Catalyzed Desymmetrization of Aziridines Synfacts. 2009: 424-424. DOI: 10.1055/S-0028-1087896 |
0.509 |
|
| 2009 |
Smith CR, RajanBabu TV. Catalytic asymmetric synthesis using feedstocks: An enantioselective route to 2-arylpropionic acids and 1-arylethyl amines via hydrovinylation of vinyl arenes (Journal of Organic Chemistry (2009) 74 (3069)) Journal of Organic Chemistry. 74: 4896. DOI: 10.1021/jo900973h |
0.357 |
|
| 2009 |
Smith CR, RajanBabu TV. ChemInform Abstract: Catalytic Asymmetric Synthesis Using Feedstocks: An Enantioselective Route to 2-Arylpropionic Acids and 1-Arylethyl Amines via Hydrovinylation of Vinyl Arenes Cheminform. 40. DOI: 10.1002/CHIN.200935056 |
0.373 |
|
| 2009 |
Wu B, Gallucci J, Parquette J, RajanBabu T. Inside Cover: Enantioselective Desymmetrization ofmeso-Aziridines with TMSN3or TMSCN Catalyzed by Discrete Yttrium Complexes (Angew. Chem. Int. Ed. 6/2009) Angewandte Chemie International Edition. 48: 994-994. DOI: 10.1002/Anie.200990017 |
0.413 |
|
| 2009 |
Wu B, Gallucci J, Parquette J, RajanBabu T. Innentitelbild: Enantioselective Desymmetrization ofmeso-Aziridines with TMSN3or TMSCN Catalyzed by Discrete Yttrium Complexes (Angew. Chem. 6/2009) Angewandte Chemie. 121: 1012-1012. DOI: 10.1002/Ange.200990014 |
0.436 |
|
| 2008 |
Smith CR, Zhang A, Mans DJ, Rajanbabu TV, Denmark SE, Xie M. (R)-3-METHYL-3-PHENYL-1-PENTENE VIA CATALYTIC ASYMMETRIC HYDROVINYLATION. Organic Syntheses; An Annual Publication of Satisfactory Methods For the Preparation of Organic Chemicals. 85: 248-266. PMID 19672483 DOI: 10.15227/Orgsyn.085.0248 |
0.465 |
|
| 2008 |
Smith CR, Mans DJ, Rajanbabu TV, Denmark SE, Nguyen ST. (R)-2,2'-BINAPHTHOYL-(S,S)-DI(1-PHENYLETHYL) AMINOPHOSPHINE. SCALABLE PROTOCOLS FOR THE SYNTHESES OF PHOSPHORAMIDITE (FERINGA) LIGANDS. Organic Syntheses; An Annual Publication of Satisfactory Methods For the Preparation of Organic Chemicals. 85: 238-247. PMID 19655040 DOI: 10.15227/Orgsyn.085.0238 |
0.324 |
|
| 2008 |
Singidi RR, RajanBabu TV. Catalyzed cyclizations leading to enrichment of functionality and chirality. A general approach to dibenzocyclooctadiene lignans from alpha,omega-diynes. Organic Letters. 10: 3351-4. PMID 18610976 DOI: 10.1021/Ol8013792 |
0.357 |
|
| 2008 |
Saha B, Smith CR, RajanBabu TV. Ligand tuning in asymmetric hydrovinylation of 1,3-dienes: a stereoselective route to either steroid-C20 (S) or -C20 (R) derivatives. Journal of the American Chemical Society. 130: 9000-5. PMID 18570419 DOI: 10.1021/Ja711475F |
0.462 |
|
| 2008 |
Yu J, RajanBabu TV, Parquette JR. Conformationally driven asymmetric induction of a catalytic dendrimer. Journal of the American Chemical Society. 130: 7845-7. PMID 18507460 DOI: 10.1021/Ja802308A |
0.405 |
|
| 2008 |
Smith CR, RajanBabu TV. Efficient, selective, and green: catalyst tuning for highly enantioselective reactions of ethylene. Organic Letters. 10: 1657-9. PMID 18351772 DOI: 10.1021/Ol800395M |
0.535 |
|
| 2007 |
Saha B, Lin MH, RajanBabu TV. Exceptionally active yttrium-salen complexes for the catalyzed ring opening of epoxides by TMSCN and TMSN(3). The Journal of Organic Chemistry. 72: 8648-55. PMID 17929974 DOI: 10.1021/Jo071076H |
0.7 |
|
| 2007 |
Saha B, RajanBabu TV. Syntheses and applications of 2-phosphino-2'-alkoxy-1,1'-binaphthyl ligands. Development of a working model for asymmetric induction in hydrovinylation reactions. The Journal of Organic Chemistry. 72: 2357-63. PMID 17335230 DOI: 10.1021/Jo062044H |
0.509 |
|
| 2007 |
Saha B, RajanBabu TV. A Working Model for Asymmetric Induction in Hydrovinylation Reactions Synfacts. 2007: 611-611. DOI: 10.1055/S-2007-968493 |
0.401 |
|
| 2007 |
Rajanbabu TV, Shin S. Catalyzed Reductions in Aqueous Media Organic Reactions in Water: Principles, Strategies and Applications. 185-214. DOI: 10.1002/9780470988817.ch6 |
0.611 |
|
| 2006 |
Saha B, Rajanbabu TV. Nickel(0)-catalyzed asymmetric hydrocyanation of 1,3-dienes. Organic Letters. 8: 4657-9. PMID 16986974 DOI: 10.1021/Ol062002F |
0.499 |
|
| 2006 |
Zhang A, RajanBabu TV. All-carbon quaternary centers via catalytic asymmetric hydrovinylation. New approaches to the exocyclic side chain stereochemistry problem. Journal of the American Chemical Society. 128: 5620-1. PMID 16637613 DOI: 10.1021/Ja060999B |
0.496 |
|
| 2006 |
Zhang A, RajanBabu TV. Hydrovinylation of 1,3-dienes: a new protocol, an asymmetric variation, and a potential solution to the exocyclic side chain stereochemistry problem. Journal of the American Chemical Society. 128: 54-5. PMID 16390118 DOI: 10.1021/Ja0561338 |
0.54 |
|
| 2006 |
Zhang A, RajanBabu TV. Hydrovinylation of 1,3-Dienes Synfacts. 2006: 344-344. DOI: 10.1055/S-2006-934335 |
0.447 |
|
| 2005 |
Park H, Kumareswaran R, RajanBabu TV. Tunable phosphinite, phosphite and phosphoramidite ligands for the asymmetric hydrovinylation reactions Tetrahedron. 61: 6352-6367. DOI: 10.1016/J.Tet.2005.03.120 |
0.545 |
|
| 2004 |
Kumareswaran R, Gallucci J, Rajanbabu TV. Tuning the acceptors in catalyzed cyclizations initiated by allenes. Silylstannylation/cyclization of allene-aldehydes for synthesis of polyalkylated indolizidines including 223A congeners. The Journal of Organic Chemistry. 69: 9151-8. PMID 15609949 DOI: 10.1021/Jo048580W |
0.453 |
|
| 2004 |
Apte S, Radetich B, Shin S, RajanBabu TV. Silylstannylation of highly functionalized acetylenes. synthesis of precursors for annulations via radical or Heck reactions. Organic Letters. 6: 4053-6. PMID 15496097 DOI: 10.1021/Ol048265W |
0.711 |
|
| 2004 |
Kumareswaran R, Shin S, Gallou I, RajanBabu TV. Silylstannylation of allenes and silylstannylation-cyclization of allenynes. Synthesis of highly functionalized allylstannanes and carbocyclic and heterocyclic compounds. The Journal of Organic Chemistry. 69: 7157-70. PMID 15471465 DOI: 10.1021/Jo049010Z |
0.712 |
|
| 2004 |
Zhang A, RajanBabu TV. Chiral benzyl centers through asymmetric catalysis. a three-step synthesis of (R)-(-)-alpha-curcumene via asymmetric hydrovinylation. Organic Letters. 6: 3159-61. PMID 15330612 DOI: 10.1021/ol048790v |
0.425 |
|
| 2004 |
Nomura N, Tsurugi K, RajanBabu TV, Kondo T. Homogeneous two-component polycondensation without strict stoichiometric balance via the Tsuji-Trost reaction: remote control of two reaction sites by catalysis. Journal of the American Chemical Society. 126: 5354-5. PMID 15113195 DOI: 10.1021/Ja0492743 |
0.434 |
|
| 2004 |
Zhang A, RajanBabu TV. Fine-tuning monophosphine ligands for enhanced enantioselectivity. Influence of chiral hemilabile pendant groups. Organic Letters. 6: 1515-7. PMID 15101781 DOI: 10.1021/Ol0495063 |
0.443 |
|
| 2003 |
Kumareswaran R, Nandi M, RajanBabu TV. Hydrovinylation of norbornene. Ligand-dependent selectivity and asymmetric variations. Organic Letters. 5: 4345-8. PMID 14601996 DOI: 10.1021/Ol0356284 |
0.508 |
|
| 2003 |
RajanBabu TV, Nomura N, Jin J, Nandi M, Park H, Sun X. Heterodimerization of olefins. 1. Hydrovinylation reactions of olefins that are amenable to asymmetric catalysis. The Journal of Organic Chemistry. 68: 8431-46. PMID 14575468 DOI: 10.1021/Jo035171B |
0.589 |
|
| 2003 |
RajanBabu TV. Asymmetric hydrovinylation reaction. Chemical Reviews. 103: 2845-60. PMID 12914483 DOI: 10.1021/Cr020040G |
0.475 |
|
| 2003 |
Rhee JU, Bliss BI, RajanBabu TV. A new reaction manifold for the Barton radical intermediates: synthesis of N-heterocyclic furanosides and pyranosides via the formation of the C(1)-C(2) bond. Journal of the American Chemical Society. 125: 1492-3. PMID 12568605 DOI: 10.1021/Ja028617Z |
0.459 |
|
| 2003 |
RajanBabu TV, Yan YY, Shin S. Asymmetric catalysis in water: Prospects and problems of using hydorxyphosphines and hydroxyphosphinites as ligands Current Organic Chemistry. 7: 1759-1773. DOI: 10.2174/1385272033486189 |
0.68 |
|
| 2003 |
RajanBabu TV, Casalnuovo AL, Ayers TA, Nomura N, Jin J, Park H, Nandi M. Ligand tuning as a tool for the discovery of new catalytic asymmetric processes Current Organic Chemistry. 7: 301-316. DOI: 10.2174/1385272033372824 |
0.547 |
|
| 2003 |
Rhee JU, Bliss BI, RajanBabu TV. Stereochemical control in radical cyclization routes to N-glycosides: Role of protecting groups and of the configuration (E versus Z) of the acceptors Tetrahedron Asymmetry. 14: 2939-2959. DOI: 10.1016/j.tetasy.2003.07.013 |
0.332 |
|
| 2002 |
Lin MH, RajanBabu TV. Ligand-assisted rate acceleration in transacylation by a yttrium-salen complex. Demonstration of a conceptually new strategy for metal-catalyzed kinetic resolution of alcohols. Organic Letters. 4: 1607-10. PMID 11975640 DOI: 10.1021/Ol025809Q |
0.651 |
|
| 2002 |
Park H, RajanBabu TV. Tunable ligands for asymmetric catalysis: readily available carbohydrate-derived diarylphosphinites induce high selectivity in the hydrovinylation of styrene derivatives. Journal of the American Chemical Society. 124: 734-5. PMID 11817932 DOI: 10.1021/Ja0172013 |
0.506 |
|
| 2001 |
RajanBabu TV, Yan YY, Shin S. Synthesis, characterization, and applicability of neutral polyhydroxy phospholane derivatives and their rhodium(I) complexes for reactions in organic and aqueous media. Journal of the American Chemical Society. 123: 10207-13. PMID 11603970 DOI: 10.1021/Ja011500A |
0.706 |
|
| 2001 |
Shin S, RajanBabu TV. Regio- and stereochemical control in bis-functionalization-cyclization: use of alleneyne precursors for carbocyclic and heterocyclic synthesis. Journal of the American Chemical Society. 123: 8416-7. PMID 11516299 DOI: 10.1021/Ja011281T |
0.658 |
|
| 2001 |
Gallou-Dagommer I, Gastaud P, RajanBabu TV. Asymmetric synthesis of functionalized 1,2,3,4-tetrahydroquinolines. Organic Letters. 3: 2053-6. PMID 11418047 DOI: 10.1021/Ol016018B |
0.495 |
|
| 2001 |
Yan YY, RajanBabu TV. Water-soluble organometallic catalysts from carbohydrates. 2. A strategy for the preparation of catalysts with pendant quaternary ammonium groups using D-salicin. The Journal of Organic Chemistry. 66: 3277-83. PMID 11348107 DOI: 10.1021/Jo001686G |
0.523 |
|
| 2000 |
Yan YY, RajanBabu TV. Ligand substituent effects on asymmetric induction. Effect Of structural variations of the DIOP ligand on the Rh-catalyzed asymmetric hydrogenation of enamides Organic Letters. 2: 4137-40. PMID 11150183 DOI: 10.1021/Ol006591F |
0.383 |
|
| 2000 |
Yan YY, RajanBabu TV. Ligand tuning in asymmetric catalysis: mono- and bis-phospholanes for a prototypical Pd-catalyzed asymmetric allylation reaction Organic Letters. 2: 199-202. PMID 10814281 DOI: 10.1021/Ol991285R |
0.469 |
|
| 2000 |
Clyne DS, Jin J, Genest E, Gallucci JC, RajanBabu TV. First chelated chiral N-heterocyclic bis-carbene complexes Organic Letters. 2: 1125-8. PMID 10804570 DOI: 10.1021/Ol005694V |
0.428 |
|
| 2000 |
Lin MH, RajanBabu TV. Metal-catalyzed acyl transfer reactions of enol esters: role of Y5(OiPr)13O and (thd)2Y(OiPr) as transesterification catalysts Organic Letters. 2: 997-1000. PMID 10768206 DOI: 10.1021/Ol0057131 |
0.635 |
|
| 2000 |
Yan YY, RajanBabu TV. Highly flexible synthetic routes to functionalized phospholanes from carbohydrates Journal of Organic Chemistry. 65: 900-906. DOI: 10.1021/Jo991762J |
0.442 |
|
| 2000 |
Gréau S, Radetich B, Rajanbabu TV. First demonstration of helical chirality in 1,4-disubstituted (Z,Z)-1,3-dienes: R3Si-SnR'3-mediated cyclization of 1,6-diynes [11] Journal of the American Chemical Society. 122: 8579-8580. DOI: 10.1021/Ja0015500 |
0.386 |
|
| 2000 |
Jin J, Rajanbabu TV. Heterodimerization of propylene and vinylarenes: Functional group compatibility in a highly efficient Ni-catalyzed carbon-carbon bond-forming reaction Tetrahedron. 56: 2145-2151. DOI: 10.1016/S0040-4020(99)01097-2 |
0.535 |
|
| 2000 |
Clyne DS, Jin J, Genest E, Gallucci JC, RajanBabu TV. First chelated chiral N-heterocyclic bis-carbene complexes Organic Letters. 2: 1125-1128. |
0.32 |
|
| 2000 |
Lin MH, RajanBabu TV. Metal-catalyzed acyl transfer reactions of enol esters: Role of Y5(OiPr)13O and (thd)2Y(OiPr) as transesterification catalysts Organic Letters. 2: 997-1000. |
0.322 |
|
| 2000 |
RajanBabu TV. Controlling asymmetric catalyzed reactions through ligand effects Chimica Oggi. 18: 26-31. |
0.496 |
|
| 2000 |
Yan YY, RajanBabu TV. Ligand tuning in asymmetric catalysis: Mono- and bis-phospholanes for a prototypical Pd-catalyzed asymmetric allylation reaction Organic Letters. 2: 199-202. |
0.336 |
|
| 1999 |
RajanBabu TV, Radetich B, You KK, Ayers TA, Casalnuovo AL, Calabrese JC. Electronic Effects in Asymmetric Catalysis: Structural Studies of Precatalysts and Intermediates in Rh-Catalyzed Hydrogenation of Dimethyl Itaconate and Acetamidocinnamic Acid Derivatives Using C(2)-Symmetric Diarylphosphinite Ligands. The Journal of Organic Chemistry. 64: 3429-3447. PMID 11674463 DOI: 10.1021/Jo9901182 |
0.444 |
|
| 1999 |
Shin S, RajanBabu TV. Water-soluble organometallic catalysts from carbohydrates. 1. Diphosphinite-Rh complexes Organic Letters. 1: 1229-1232. DOI: 10.1021/Ol9908979 |
0.407 |
|
| 1999 |
Clyne DS, Mermet-Bouvier YC, Nomura N, RajanBabu TV. Substituent effects of ligands on asymmetric induction in a prototypical palladium-catalyzed allylation reaction: Making both enantiomers of a product in high optical purity using the same source of chirality Journal of Organic Chemistry. 64: 7601-7611. DOI: 10.1021/Jo9911387 |
0.495 |
|
| 1999 |
RajanBabu TV, Radetich B, You KK, Ayers TA, Casalnuovo AL, Calabrese JC. Electronic effects in asymmetric catalysis: Structural studies of precatalysts and intermediates in Rh-catalyzed hydrogenation of dimethyl itaconate and acetamidocinnamic acid derivatives using C2-symmetric diarylphosphinite ligands Journal of Organic Chemistry. 64: 3429-3447. DOI: 10.1021/jo9901182 |
0.322 |
|
| 1999 |
Nandi M, Jin J, RajanBabu TV. Synergistic effects of hemilabile coordination and counterions in homogeneous catalysis: New tunable monophosphine ligands for hydrovinylation reactions [15] Journal of the American Chemical Society. 121: 9899-9900. DOI: 10.1021/Ja992493H |
0.565 |
|
| 1999 |
Valluri M, Nomura N, Avery MA, Jin J, Park H, Rajanbabu TV. The hydrovinylation reaction: A new highly selective protocol amenable to asymmetric catalysis Chemtracts. 12: 52-56. DOI: 10.1021/Ja973548N |
0.489 |
|
| 1999 |
RajanBabu TV, Nomura N, Jin J, Radetich B, Park H, Nandi M. Hydrovinylation and related reactions: New protocols and control elements in search of greater synthetic efficiency and selectivity Chemistry - a European Journal. 5: 1963-1968. DOI: 10.1002/(Sici)1521-3765(19990702)5:7<1963::Aid-Chem1963>3.0.Co;2-4 |
0.456 |
|
| 1998 |
Radetich B, RajanBabu TV. Catalyzed cyclization of α,ω-dienes: A versatile protocol for the synthesis of functionalized carbocyclic and heterocyclic compounds [18] Journal of the American Chemical Society. 120: 8007-8008. DOI: 10.1021/Ja9738788 |
0.409 |
|
| 1997 |
RajanBabu TV, Ayers TA, Halliday GA, You KK, Calabrese JC. Carbohydrate Phosphinites as Practical Ligands in Asymmetric Catalysis: Electronic Effects and Dependence of Backbone Chirality in Rh-Catalyzed Asymmetric Hydrogenations. Synthesis of R- or S-Amino Acids Using Natural Sugars as Ligand Precursors Journal of Organic Chemistry. 62: 6012-6025. DOI: 10.1021/Jo970884D |
0.475 |
|
| 1997 |
Nomura N, RajanBabu TV. Nickel-catalyzed asymmetric allylation of alkyl Grignard reagents, effect of ligands, leaving groups and a kinetic resolution with a hard nucleophile Tetrahedron Letters. 38: 1713-1716. DOI: 10.1016/S0040-4039(97)00178-0 |
0.564 |
|
| 1996 |
Nomura N, Mermet-Bouvier YC, RajanBabu TV. Unprecedented Electronic and Steric Effects in Palladium-Catalyzed Asymmetric Allylation: Switching of Enantioselectivity with a Single Chiral Backbone Synlett. 1996: 745-746. DOI: 10.1055/S-1996-5534 |
0.434 |
|
| 1996 |
RajanBabu TV, Casalnuovo AL. Role of electronic asymmetry in the design of new ligands: The asymmetric hydrocyanation reaction Journal of the American Chemical Society. 118: 6325-6326. DOI: 10.1021/Ja9609112 |
0.55 |
|
| 1994 |
Casalnuovo AL, RajanBabu TV, Ayers TA, Warren TH. Ligand Electronic Effects in Asymmetric Catalysis: Enhanced Enantioselectivity in the Asymmetric Hydrocyanation of Vinylarenes Journal of the American Chemical Society. 116: 9869-9882. DOI: 10.1021/Ja00101A007 |
0.451 |
|
| 1994 |
RajanBabu TV, Ayers TA, Casalnuovo AL. Electronic amplification of selectivity in Rh-catalyzed hydrogenations: D-glucose-derived ligands for the synthesis of D- or L-amino acids Journal of the American Chemical Society. 116: 4101-4102. DOI: 10.1021/Ja00088A065 |
0.445 |
|
| 1994 |
RajanBabu TV, Nugent WA. Selective generation of free radicals from epoxides using a transition-metal radical. A powerful new tool for organic synthesis Journal of the American Chemical Society. 116: 986-997. DOI: 10.1021/Ja00082A021 |
0.434 |
|
| 1994 |
RajanBabu TV, Ayers TA. Electronic effects in asymmetric catalysis: Hydroformylation of olefins Tetrahedron Letters. 35: 4295-4298. DOI: 10.1016/S0040-4039(00)73337-5 |
0.461 |
|
| 1993 |
Nugent WA, Rajanbabu TV, Burk MJ. Beyond Nature's Chiral Pool: Enantioselective Catalysis in Industry. Science (New York, N.Y.). 259: 479-83. PMID 17734166 DOI: 10.1126/Science.259.5094.479 |
0.473 |
|
| 1993 |
Nugent WA, RajanBabu TV, Burk MJ. Beyond nature's chiral pool: Enantioselective catalysis in industry Science. 259: 479-483. |
0.375 |
|
| 1992 |
RajanBabu TV, Casalnuovo AL. Tailored ligands for asymmetric catalysis: the hydrocyanation of vinyl arenes Journal of the American Chemical Society. 114: 6265-6266. DOI: 10.1021/Ja00041A066 |
0.412 |
|
| 1991 |
RajanBabu TV. Stereochemistry of intramolecular free-radical cyclization reactions Accounts of Chemical Research. 24: 139-145. DOI: 10.1021/Ar00005A003 |
0.443 |
|
| 1990 |
Rajanbabu TV, Nugent WA, Beattie MS. Free radical mediated reduction and deoxygenation of epoxides Journal of the American Chemical Society. 112: 6408-6409. DOI: 10.1021/Ja00173A045 |
0.42 |
|
| 1989 |
RajanBabu TV, Nugent WA. Intermolecular addition of epoxides to activated olefins: A new reaction Journal of the American Chemical Society. 111: 4525-4527. DOI: 10.1021/Ja00194A073 |
0.459 |
|
| 1989 |
RajanBabu TV, Fukunaga T, Reddy GS. Stereochemical control in hex-5-enyl radical cyclizations: From carbohydrates to carbocycles. 3 Journal of the American Chemical Society. 111: 1759-1769. DOI: 10.1021/Ja00187A031 |
0.452 |
|
| 1989 |
RajanBabu TV, Fukunaga T. Stereochemical control in hex-5-enyl radical cyclizations: Axial vs equatorial 2-(1-but-3-enyl)cyclohexyl radicals Journal of the American Chemical Society. 111: 296-300. DOI: 10.1021/Ja00183A045 |
0.35 |
|
| 1988 |
Nugent WA, RajanBabu TV. Transition-metal-centered radicals in organic synthesis. Titanium(III)-induced cyclization of epoxyolefins Journal of the American Chemical Society. 110: 8561-8562. DOI: 10.1021/Ja00233A051 |
0.421 |
|
| 1988 |
RajanBabu TV, Nugent WA, Taber DF, Fagan PJ. Stereoselective cyclization of enynes mediated by metallocene reagents Journal of the American Chemical Society. 110: 7128-7135. DOI: 10.1021/Ja00229A028 |
0.316 |
|
| 1988 |
Hertler WR, Rajanbabu TV, Ovenall DW, Reddy GS, Sogah DY. Group transfer polymerization with polyunsaturated esters and silyl polyenolates Journal of the American Chemical Society. 110: 5841-5853. DOI: 10.1021/Ja00225A040 |
0.432 |
|
| 1988 |
RajanBabu TV. From carbohydrates to carbocycles. 2. A free radical route to Corey lactone and other prostanoid intermediates Journal of Organic Chemistry. 53: 4522-4530. |
0.304 |
|
| 1986 |
RajanBabu TV, Chenard BL, Petti MA. α-Nitroarylation of ketones and esters: An exceptionally facile synthesis of indoles, 2-indolinones, and arylacetic acids Journal of Organic Chemistry. 51: 1704-1712. DOI: 10.1021/Jo00360A014 |
0.464 |
|
| 1985 |
Chenard BL, Laganis ED, Davidson F, RajanBabu TV. Silylstannanes: Useful reagents for bis functionalization of α,β-unsaturated ketones and acetylenes Journal of Organic Chemistry. 50: 3666-3667. DOI: 10.1021/Jo00219A058 |
0.309 |
|
| 1985 |
RajanBabu TV, Reddy GS, Fukunaga T. Nucleophilic addition of silyl enol ethers to aromatic nitro compounds: Scope and mechanism of reaction Journal of the American Chemical Society. 107: 5473-5483. DOI: 10.1002/Chin.198601079 |
0.479 |
|
| 1984 |
RajanBabu TV, Fukunaga T. Nucleophilic addition of silyl enol ethers to aromatic nitro compounds: a facile synthesis of .alpha.-nitroaryl carbonyl compounds Journal of Organic Chemistry. 49: 4571-4572. DOI: 10.1021/Jo00197A062 |
0.367 |
|
| 1984 |
RajanBabu TV. Addition of ketene trimethylsilyl acetals to α,β-unsaturated ketones: A new strategy for Michael Addition of ester enolates Journal of Organic Chemistry. 49: 2083-2089. |
0.394 |
|
| 1983 |
Webster OW, Hertler WR, Sogah DY, Farnham WB, RajanBabu TV. SYNTHESIS OF REACTIVE-ENDED ACRYLIC POLYMERS BY GROUP TRANSFER POLYMERIZATION. INITIATION WITH SILYL KETENE ACETALS. Journal of Macromolecular Science. Chemistry. 943-960. DOI: 10.1080/00222338408056584 |
0.304 |
|
| 1983 |
Rajanbabu TV, Eaton DF, Fukunaga T. Chemistry of bridged aromatics. A study of the substituent effect on the course of bond cleavage of 9,10-dihydro-9,10-ethanoanthracenes and an oxyanion-assisted retro-diels-alder reaction Journal of Organic Chemistry. 48: 652-657. DOI: 10.1021/Jo00153A006 |
0.454 |
|
| 1983 |
Webster OW, Hertler WR, Sogah DY, Farnham WB, RajanBabu TV. Group-transfer polymerization. 1. A new concept for addition polymerization with organosilicon initiators Journal of the American Chemical Society. 105: 5706-5708. DOI: 10.1021/Ja00355A039 |
0.343 |
|
| 1977 |
RajanBabu TV, Sanders DC, Shechter H. Surprises in base-catalyzed decompositions of bicyclo[4.2.1]nona-2,4,7-trien-9-one hydrazone Journal of the American Chemical Society. 99: 6449-6451. DOI: 10.1021/Ja00461A051 |
0.422 |
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