Jason Hartwig, Ph.D. - Publications

Affiliations: 
2007 University of Oregon, Eugene, OR, United States 
Area:
International Law and Relations

165 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2021 Sakamoto S, Butcher TW, Yang JL, Hartwig JF. gem-Difluoroallylation of Aryl Halides and Pseudo Halides with Difluoroallylboron Reagents in High Regioselectivity. Angewandte Chemie (International Ed. in English). PMID 34555220 DOI: 10.1002/anie.202111476  0.348
2021 Kalkman ED, Hartwig JF. Direct Observation of Diastereomeric α-C-Bound Enolates during Enantioselective α-Arylations: Synthesis, Characterization, and Reactivity of Arylpalladium Fluorooxindole Complexes. Journal of the American Chemical Society. 143: 11741-11750. PMID 34308646 DOI: 10.1021/jacs.1c05346  0.302
2021 Tlahuext-Aca A, Lee SY, Sakamoto S, Hartwig JF. Direct Arylation of Simple Arenes with Aryl Bromides by Synergistic Silver and Palladium Catalysis Acs Catalysis. 11: 1430-1434. DOI: 10.1021/ACSCATAL.0C05254  0.311
2020 Ray R, Hartwig JF. Oxalohydrazide Ligands for Copper-Catalyzed C-O Coupling Reactions with High Turnover Numbers. Angewandte Chemie (International Ed. in English). PMID 33377249 DOI: 10.1002/anie.202015654  0.322
2020 Ma S, Hill CK, Olen CL, Hartwig JF. Ruthenium-Catalyzed Hydroamination of Unactivated Terminal Alkenes with Stoichiometric Amounts of Alkene and an Ammonia Surrogate by Sequential Oxidation and Reduction. Journal of the American Chemical Society. PMID 33356181 DOI: 10.1021/jacs.0c11043  0.344
2020 Xi Y, Ma S, Hartwig JF. Catalytic asymmetric addition of an amine N-H bond across internal alkenes. Nature. PMID 33142305 DOI: 10.1038/s41586-020-2919-z  0.337
2020 Karmel C, Rubel CZ, Kharitonova EV, Hartwig JF. Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand. Angewandte Chemie (Weinheim An Der Bergstrasse, Germany). 132: 6130-6137. PMID 33071367 DOI: 10.1002/ange.201916015  0.355
2020 Wang JY, Choi K, Zuend SJ, Borate K, Shinde H, Goetz R, Hartwig JF. Cross-Coupling between Hydrazine and Aryl Halides with Hydroxide Base at Low Loadings of Palladium by Rate-Determining Deprotonation of Bound Hydrazine. Angewandte Chemie (International Ed. in English). PMID 32929852 DOI: 10.1002/Anie.202011161  0.311
2020 Karmel C, Hartwig JF. Mechanism of the Iridium-Catalyzed Silylation of Aromatic C-H Bonds. Journal of the American Chemical Society. 142: 10494-10505. PMID 32375477 DOI: 10.1021/Jacs.0C03301  0.305
2020 Saper NI, Ohgi A, Small DW, Semba K, Nakao Y, Hartwig JF. Nickel-catalysed anti-Markovnikov hydroarylation of unactivated alkenes with unactivated arenes facilitated by non-covalent interactions. Nature Chemistry. PMID 32042137 DOI: 10.1038/S41557-019-0409-4  0.314
2020 Karmel C, Rubel CZ, Kharitonova EV, Hartwig JF. Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand. Angewandte Chemie (International Ed. in English). PMID 31968139 DOI: 10.1002/Anie.201916015  0.355
2019 Oeschger RJ, Larsen MA, Bismuto A, Hartwig JF. Origin of the Difference in Reactivity between Ir Catalysts for the Borylation of C-H Bonds. Journal of the American Chemical Society. PMID 31539230 DOI: 10.1021/Jacs.9B08920  0.305
2019 He ZT, Jiang X, Hartwig JF. Stereodivergent Construction of Tertiary Fluorides in Vicinal Stereogenic Pairs by Allylic Substitution with Iridium and Copper Catalysts. Journal of the American Chemical Society. PMID 31343170 DOI: 10.1021/Jacs.9B04440  0.319
2019 Karmel C, Chen Z, Hartwig JF. Iridium-Catalyzed Silylation of C-H bonds in Unactivated Arenes: A Sterically-Encumbered Phenanthroline Ligand Accelerates Catalysis Enabling New Reactivity. Journal of the American Chemical Society. PMID 30971087 DOI: 10.1021/Jacs.9B01972  0.325
2019 Hanna S, Holder JC, Hartwig JF. Multicatalytic Approach to the Hydroaminomethylation of α-Olefins. Angewandte Chemie (International Ed. in English). PMID 30635956 DOI: 10.1002/Anie.201811297  0.301
2019 Hartwig JF, Shaughnessy KH, Shekhar S, Green RA. Palladium‐Catalyzed Amination of Aryl Halides Organic Reactions. 853-958. DOI: 10.1002/0471264180.Or100.14  0.33
2018 He ZT, Hartwig JF. Enantioselective α-functionalizations of ketones via allylic substitution of silyl enol ethers. Nature Chemistry. PMID 30455430 DOI: 10.1038/S41557-018-0165-X  0.31
2018 Su B, Lee T, Hartwig JF. Iridium-catalyzed, β-selective C(sp3)-H silylation of aliphatic amines to form silapyrrolidines and 1,2-amino alcohols. Journal of the American Chemical Society. PMID 30354144 DOI: 10.1021/Jacs.8B10428  0.32
2018 Butcher TW, Hartwig JF. Enantioselective Synthesis of Tertiary Allylic Fluorides by Iridium-Catalyzed Allylic Fluoroalkylation. Angewandte Chemie (International Ed. in English). PMID 30136379 DOI: 10.1002/Anie.201807474  0.328
2018 Litman ZC, Wang Y, Zhao H, Hartwig JF. Cooperative asymmetric reactions combining photocatalysis and enzymatic catalysis. Nature. 560: 355-359. PMID 30111790 DOI: 10.1038/S41586-018-0413-7  0.318
2018 Wang JY, Strom AE, Hartwig JF. Mechanistic Studies of Palladium-Catalyzed Aminocarbonylation of Aryl Chlorides with Carbon Monoxide and Ammonia. Journal of the American Chemical Society. PMID 29852736 DOI: 10.1021/Jacs.8B04073  0.332
2018 Jiang X, Boehm P, Hartwig JF. Stereodivergent Allylation of Azaaryl Acetamides and Acetates by Synergistic Iridium and Copper Catalysis. Journal of the American Chemical Society. PMID 29319306 DOI: 10.1021/Jacs.7B12824  0.326
2017 Saper N, Hartwig JF. Mechanistic Investigations of the Hydrogenolysis of Diaryl Ethers Catalyzed by Nickel Complexes of N-Heterocyclic Carbene Ligands. Journal of the American Chemical Society. PMID 29116776 DOI: 10.1021/Jacs.7B10537  0.323
2017 Arlow SI, Hartwig JF. Synthesis, Characterization, and Reactivity of Palladium Fluoroenolate Complexes. Journal of the American Chemical Society. PMID 29077395 DOI: 10.1021/Jacs.7B09949  0.304
2017 Xi Y, Hartwig JF. Mechanistic Studies of Copper-Catalyzed Asymmetric Hydroboration of Alkenes. Journal of the American Chemical Society. PMID 28787137 DOI: 10.1021/Jacs.7B07124  0.315
2017 Wang Y, Bartlett MJ, Denard CA, Hartwig JF, Zhao H. Combining Rh-Catalyzed Diazocoupling and Enzymatic Reduction To Efficiently Synthesize Enantioenriched 2-Substituted Succinate Derivatives Acs Catalysis. 7: 2548-2552. DOI: 10.1021/Acscatal.7B00254  0.319
2016 Su B, Zhou TG, Li XW, Shao XR, Xu PL, Wu WL, Hartwig JF, Shi ZJ. A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C-H Bonds. Angewandte Chemie (International Ed. in English). PMID 27976482 DOI: 10.1002/Anie.201609939  0.324
2016 Zhang J, Shrestha R, Hartwig JF, Zhao P. A decarboxylative approach for regioselective hydroarylation of alkynes. Nature Chemistry. 8: 1144-1151. PMID 27874862 DOI: 10.1038/Nchem.2602  0.309
2016 Lee SY, Hartwig JF. Palladium-Catalyzed, Site-Selective Direct Allylation of Aryl C-H Bonds by Silver-Mediated C-H Activation: A Synthetic and Mechanistic Investigation. Journal of the American Chemical Society. PMID 27797512 DOI: 10.1021/Jacs.6B10220  0.352
2016 Peacock DM, Roos CB, Hartwig JF. Palladium-Catalyzed Cross Coupling of Secondary and Tertiary Alkyl Bromides with a Nitrogen Nucleophile. Acs Central Science. 2: 647-652. PMID 27725963 DOI: 10.1021/Acscentsci.6B00187  0.339
2016 Chen M, Hartwig JF. Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles. Angewandte Chemie (International Ed. in English). PMID 27531137 DOI: 10.1002/Anie.201607053  0.339
2016 Jiang X, Chen W, Hartwig JF. Iridium-Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic α-Alkoxy Ketones. Angewandte Chemie (International Ed. in English). PMID 27038004 DOI: 10.1002/Anie.201600235  0.301
2016 Yamamoto H, Samanta RC, Jiang X, Chen W, Hartwig JF. Catalytic Asymmetric Allylic Substitution Reactions Synfacts. 12: 717-717. DOI: 10.1055/S-0035-1562288  0.303
2016 Chen M, Hartwig JF. ChemInform Abstract: Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles. Cheminform. 47. DOI: 10.1002/CHIN.201652040  0.326
2015 Xi Y, Butcher TW, Zhang J, Hartwig JF. Regioselective, Asymmetric Formal Hydroamination of Unactivated Internal Alkenes. Angewandte Chemie (International Ed. in English). PMID 26592363 DOI: 10.1002/Anie.201509235  0.333
2015 Chen M, Hartwig JF. Iridium-Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides. Journal of the American Chemical Society. PMID 26441002 DOI: 10.1021/Jacs.5B09980  0.325
2015 Schramm Y, Takeuchi M, Semba K, Nakao Y, Hartwig JF. Anti-Markovnikov Hydroheteroarylation of Unactivated Alkenes with Indoles, Pyrroles, Benzofurans, and Furans Catalyzed by a Nickel-N-Heterocyclic Carbene System. Journal of the American Chemical Society. 137: 12215-8. PMID 26334367 DOI: 10.1021/Jacs.5B08039  0.354
2015 Larsen MA, Wilson CV, Hartwig JF. Iridium-Catalyzed Borylation of Primary Benzylic C-H Bonds without a Directing Group: Scope, Mechanism, and Origins of Selectivity. Journal of the American Chemical Society. PMID 26076367 DOI: 10.1021/Jacs.5B04899  0.318
2015 Brusoe AT, Hartwig JF. Palladium-Catalyzed Arylation of Fluoroalkylamines. Journal of the American Chemical Society. PMID 26065341 DOI: 10.1021/Jacs.5B02512  0.352
2015 Cheng C, Hartwig JF. Iridium-catalyzed silylation of aryl C-H bonds. Journal of the American Chemical Society. 137: 592-5. PMID 25514197 DOI: 10.1021/Ja511352U  0.323
2015 Denard CA, Bartlett MJ, Wang Y, Lu L, Hartwig JF, Zhao H. Development of a One-Pot tandem reaction combining ruthenium-catalyzed alkene metathesis and enantioselective enzymatic oxidation to produce Aryl epoxides Acs Catalysis. 5: 3817-3822. DOI: 10.1021/Acscatal.5B00533  0.311
2014 Chen W, Chen M, Hartwig JF. Diastereo- and enantioselective iridium-catalyzed allylation of cyclic ketone enolates: synergetic effect of ligands and barium enolates. Journal of the American Chemical Society. 136: 15825-8. PMID 25337972 DOI: 10.1021/Ja506500U  0.327
2014 Chen M, Hartwig JF. Iridium-catalyzed regio- and enantioselective allylic substitution of silyl dienolates derived from dioxinones. Angewandte Chemie (International Ed. in English). 53: 12172-6. PMID 25223593 DOI: 10.1002/Anie.201406778  0.328
2014 Bair JS, Schramm Y, Sergeev AG, Clot E, Eisenstein O, Hartwig JF. Linear-selective hydroarylation of unactivated terminal and internal olefins with trifluoromethyl-substituted arenes. Journal of the American Chemical Society. 136: 13098-101. PMID 25171744 DOI: 10.1021/Ja505579F  0.324
2014 Green RA, Hartwig JF. Palladium-catalyzed amination of aryl chlorides and bromides with ammonium salts. Organic Letters. 16: 4388-91. PMID 25133675 DOI: 10.1021/Ol501739G  0.305
2014 Sevov CS, Hartwig JF. Iridium-catalyzed oxidative olefination of furans with unactivated alkenes. Journal of the American Chemical Society. 136: 10625-31. PMID 25032781 DOI: 10.1021/Ja504414C  0.324
2014 Cheng C, Hartwig JF. Rhodium-catalyzed intermolecular C-H silylation of arenes with high steric regiocontrol. Science (New York, N.Y.). 343: 853-7. PMID 24558154 DOI: 10.1126/Science.1248042  0.303
2014 Sevov CS, Zhou JS, Hartwig JF. Iridium-catalyzed, intermolecular hydroamination of unactivated alkenes with indoles. Journal of the American Chemical Society. 136: 3200-7. PMID 24483848 DOI: 10.1021/Ja412116D  0.314
2014 Cho SH, Hartwig JF. Iridium-catalyzed diborylation of benzylic C-H bonds directed by a hydrosilyl group: Synthesis of 1,1-benzyldiboronate esters Chemical Science. 5: 694-698. DOI: 10.1039/C3Sc52824C  0.301
2013 Fier PS, Hartwig JF. Selective C-H fluorination of pyridines and diazines inspired by a classic amination reaction. Science (New York, N.Y.). 342: 956-60. PMID 24264986 DOI: 10.1126/Science.1243759  0.309
2013 Hama T, Ge S, Hartwig JF. Palladium-catalyzed α-arylation of zinc enolates of esters: reaction conditions and substrate scope. The Journal of Organic Chemistry. 78: 8250-66. PMID 23931445 DOI: 10.1021/Jo401476F  0.353
2013 Shrestha R, Mukherjee P, Tan Y, Litman ZC, Hartwig JF. Sterically controlled, palladium-catalyzed intermolecular amination of arenes. Journal of the American Chemical Society. 135: 8480-3. PMID 23678959 DOI: 10.1021/Ja4032677  0.311
2013 Sevov CS, Hartwig JF. Iridium-catalyzed intermolecular asymmetric hydroheteroarylation of bicycloalkenes. Journal of the American Chemical Society. 135: 2116-9. PMID 23346874 DOI: 10.1021/Ja312360C  0.332
2013 Chen W, Hartwig JF. ChemInform Abstract: Iridium-Catalyzed Regioselective and Enantioselective Allylation of Trimethylsiloxyfuran. Cheminform. 44: no-no. DOI: 10.1002/CHIN.201309115  0.329
2012 Chen W, Hartwig JF. Iridium-catalyzed regioselective and enantioselective allylation of trimethylsiloxyfuran. Journal of the American Chemical Society. 134: 15249-52. PMID 22954355 DOI: 10.1021/Ja306850B  0.349
2012 Sevov CS, Zhou J, Hartwig JF. Iridium-catalyzed intermolecular hydroamination of unactivated aliphatic alkenes with amides and sulfonamides. Journal of the American Chemical Society. 134: 11960-3. PMID 22780090 DOI: 10.1021/Ja3052848  0.314
2012 Fier PS, Hartwig JF. Copper-mediated fluorination of aryl iodides. Journal of the American Chemical Society. 134: 10795-8. PMID 22709145 DOI: 10.1021/Ja304410X  0.311
2012 Madrahimov ST, Hartwig JF. Origins of enantioselectivity during allylic substitution reactions catalyzed by metallacyclic iridium complexes. Journal of the American Chemical Society. 134: 8136-47. PMID 22486270 DOI: 10.1021/Ja212217J  0.332
2012 Fier PS, Hartwig JF. Copper-mediated difluoromethylation of aryl and vinyl iodides. Journal of the American Chemical Society. 134: 5524-7. PMID 22397683 DOI: 10.1021/Ja301013H  0.304
2012 Hartwig JF. Borylation and silylation of C-H bonds: a platform for diverse C-H bond functionalizations. Accounts of Chemical Research. 45: 864-73. PMID 22075137 DOI: 10.1021/Ar200206A  0.33
2011 Robbins DW, Hartwig JF. A simple, multidimensional approach to high-throughput discovery of catalytic reactions. Science (New York, N.Y.). 333: 1423-7. PMID 21903809 DOI: 10.1126/Science.1207922  0.301
2011 Trost BM, Thaisrivongs DA, Hartwig J. Palladium-catalyzed asymmetric allylic alkylations of polynitrogen-containing aromatic heterocycles. Journal of the American Chemical Society. 133: 12439-41. PMID 21770467 DOI: 10.1021/Ja205523E  0.339
2011 Tan Y, Hartwig JF. Assessment of the intermediacy of arylpalladium carboxylate complexes in the direct arylation of benzene: evidence for C-H bond cleavage by "ligandless" species. Journal of the American Chemical Society. 133: 3308-11. PMID 21314146 DOI: 10.1021/Ja1113936  0.332
2011 Liu Z, Yamamichi H, Madrahimov ST, Hartwig JF. Rhodium phosphine-π-arene intermediates in the hydroamination of alkenes. Journal of the American Chemical Society. 133: 2772-82. PMID 21309512 DOI: 10.1021/Ja1057949  0.367
2011 Liao X, Stanley LM, Hartwig JF. Enantioselective total syntheses of (-)-taiwaniaquinone H and (-)-taiwaniaquinol B by iridium-catalyzed borylation and palladium-catalyzed asymmetric α-arylation. Journal of the American Chemical Society. 133: 2088-91. PMID 21268578 DOI: 10.1021/Ja110215B  0.316
2011 Klinkenberg JL, Hartwig JF. Catalytic organometallic reactions of ammonia. Angewandte Chemie (International Ed. in English). 50: 86-95. PMID 20857466 DOI: 10.1002/Anie.201002354  0.306
2011 Hartwig JF, Pouy MJ. Iridium-catalyzed allylic substitution Topics in Organometallic Chemistry. 34: 169-208. DOI: 10.1007/978-3-642-15334-1_7  0.318
2011 Trost BM, Thaisrivongs DA, Hartwig J. ChemInform Abstract: Palladium-Catalyzed Asymmetric Allylic Alkylations of Polynitrogen-Containing Aromatic Heterocycles. Cheminform. 43: no-no. DOI: 10.1002/chin.201204150  0.346
2011 Hartwig JF, Pouy MJ. ChemInform Abstract: Iridium-Catalyzed Allylic Substitution Cheminform. 42: no-no. DOI: 10.1002/chin.201152252  0.311
2010 Hartwig JF, Stanley LM. Mechanistically driven development of iridium catalysts for asymmetric allylic substitution. Accounts of Chemical Research. 43: 1461-75. PMID 20873839 DOI: 10.1021/Ar100047X  0.347
2010 Julian LD, Hartwig JF. Intramolecular hydroamination of unbiased and functionalized primary aminoalkenes catalyzed by a rhodium aminophosphine complex. Journal of the American Chemical Society. 132: 13813-22. PMID 20839807 DOI: 10.1021/Ja1052126  0.341
2010 Stanley LM, Bai C, Ueda M, Hartwig JF. Iridium-catalyzed kinetic asymmetric transformations of racemic allylic benzoates. Journal of the American Chemical Society. 132: 8918-20. PMID 20552969 DOI: 10.1021/Ja103779E  0.345
2010 Hanley PS, Markovi? D, Hartwig JF. Intermolecular insertion of ethylene and octene into a palladium-amide bond. Spectroscopic evidence for an ethylene amido intermediate. Journal of the American Chemical Society. 132: 6302-3. PMID 20408534 DOI: 10.1021/Ja102172M  0.301
2010 Ueda M, Hartwig JF. Iridium-catalyzed, regio- and enantioselective allylic substitution with aromatic and aliphatic sulfinates. Organic Letters. 12: 92-4. PMID 19954200 DOI: 10.1021/Ol9023248  0.333
2010 Liskey CW, Liao X, Hartwig JF. ChemInform Abstract: Cyanation of Arenes via Iridium-Catalyzed Borylation. Cheminform. 42: no-no. DOI: 10.1002/CHIN.201104045  0.314
2010 Ueda M, Hartwig JF. ChemInform Abstract: Iridium-Catalyzed, Regio- and Enantioselective Allylic Substitution with Aromatic and Aliphatic Sulfinates. Cheminform. 41: no-no. DOI: 10.1002/CHIN.201022071  0.327
2010 Pouy MJ, Stanley LM, Hartwig JF. ChemInform Abstract: Enantioselective, Iridium-Catalyzed Monoallylation of Ammonia. Cheminform. 41. DOI: 10.1002/CHIN.201002074  0.301
2010 Lee S, Joergensen M, Hartwig JF. ChemInform Abstract: Palladium-Catalyzed Synthesis of Arylamines from Aryl Halides and Lithium Bis(trimethylsilyl)amide as an Ammonia Equivalent. Cheminform. 32: no-no. DOI: 10.1002/CHIN.200151097  0.323
2010 Loeber O, Kawatsura M, Hartwig JF. ChemInform Abstract: Palladium-Catalyzed Hydroamination of 1,3-Dienes: A Colorimetric Assay and Enantioselective Additions. Cheminform. 32: no-no. DOI: 10.1002/CHIN.200137094  0.312
2010 HARTWIG JF. ChemInform Abstract: Synthesis, Structure, and Reactivity of a Palladium Hydrazonato Complex: A New Type of Reductive Elimination Reaction to Form C-N Bonds and Catalytic Arylation of Benzophenone Hydrazone. Cheminform. 29: no-no. DOI: 10.1002/CHIN.199849112  0.321
2010 HAMANN BC, HARTWIG JF. ChemInform Abstract: Sterically Hindered Chelating Alkyl Phosphines Provide Large Rate Accelerations in Palladium-Catalyzed Amination of Aryl Iodides, Bromides, and Chlorides, and the First Amination of Aryl Tosylates. Cheminform. 29: no-no. DOI: 10.1002/CHIN.199847091  0.336
2010 MANN G, HARTWIG JF. ChemInform Abstract: Palladium-Catalyzed Formation of Diaryl Ethers from Aryl Bromides. Electron Poor Phosphines Enhance Reaction Yields. Cheminform. 29: no-no. DOI: 10.1002/CHIN.199807121  0.304
2010 MANN G, HARTWIG JF. ChemInform Abstract: Nickel- vs Palladium-Catalyzed Synthesis of Protected Phenols from Aryl Halides. Cheminform. 28: no-no. DOI: 10.1002/CHIN.199752100  0.31
2010 DRIVER MS, HARTWIG JF. ChemInform Abstract: A Second-Generation Catalyst for Aryl Halide Amination: Mixed Secondary Amines from Aryl Halides and Primary Amines Catalyzed by ( dppf)PdCl2 Cheminform. 27: no-no. DOI: 10.1002/CHIN.199645087  0.305
2009 Pouy MJ, Stanley LM, Hartwig JF. Enantioselective, iridium-catalyzed monoallylation of ammonia. Journal of the American Chemical Society. 131: 11312-3. PMID 19722644 DOI: 10.1021/Ja905059R  0.325
2009 Vo GD, Hartwig JF. Palladium-catalyzed coupling of ammonia with aryl chlorides, bromides, iodides, and sulfonates: a general method for the preparation of primary arylamines. Journal of the American Chemical Society. 131: 11049-61. PMID 19591470 DOI: 10.1021/Ja903049Z  0.308
2009 Weix DJ, Marković D, Ueda M, Hartwig JF. Direct, intermolecular, enantioselective, iridium-catalyzed allylation of carbamates to form carbamate-protected, branched allylic amines. Organic Letters. 11: 2944-7. PMID 19552468 DOI: 10.1021/Ol901151U  0.348
2009 Stanley LM, Hartwig JF. Regio- and enantioselective N-allylations of imidazole, benzimidazole, and purine heterocycles catalyzed by single-component metallacyclic iridium complexes. Journal of the American Chemical Society. 131: 8971-83. PMID 19480431 DOI: 10.1021/Ja902243S  0.316
2009 Madrahimov ST, Markovic D, Hartwig JF. The allyl intermediate in regioselective and enantioselective iridium-catalyzed asymmetric allylic substitution reactions. Journal of the American Chemical Society. 131: 7228-9. PMID 19432473 DOI: 10.1021/Ja902609G  0.303
2009 Fernández-Rodríguez MA, Hartwig JF. A general, efficient, and functional-group-tolerant catalyst system for the palladium-catalyzed thioetherification of aryl bromides and iodides. The Journal of Organic Chemistry. 74: 1663-72. PMID 19154131 DOI: 10.1021/Jo802594D  0.331
2009 Weix DJ, Marković D, Ueda M, Hartwig JF. Iridium-Catalyzed Allylation of Carbamates Synfacts. 2009: 1113-1113. DOI: 10.1055/S-0029-1217913  0.329
2009 Weix DJ, Markovic D, Ueda M, Hartwig JF. ChemInform Abstract: Direct, Intermolecular, Enantioselective, Iridium-Catalyzed Allylation of Carbamates to Form Carbamate-Protected, Branched Allylic Amines. Cheminform. 40. DOI: 10.1002/CHIN.200946064  0.317
2008 Herzon SB, Hartwig JF. Hydroaminoalkylation of unactivated olefins with dialkylamines. Journal of the American Chemical Society. 130: 14940-1. PMID 18937477 DOI: 10.1021/Ja806367E  0.35
2008 Ogata T, Hartwig JF. Palladium-catalyzed amination of aryl and heteroaryl tosylates at room temperature. Journal of the American Chemical Society. 130: 13848-9. PMID 18811161 DOI: 10.1021/Ja805810P  0.338
2008 Zhou JS, Hartwig JF. Intermolecular, catalytic asymmetric hydroamination of bicyclic alkenes and dienes in high yield and enantioselectivity. Journal of the American Chemical Society. 130: 12220-1. PMID 18715004 DOI: 10.1021/Ja803523Z  0.34
2008 Hartwig JF. Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides. Accounts of Chemical Research. 41: 1534-44. PMID 18681463 DOI: 10.1021/Ar800098P  0.334
2008 Boebel TA, Hartwig JF. Silyl-directed, iridium-catalyzed ortho-borylation of arenes. A one-pot ortho-borylation of phenols, arylamines, and alkylarenes. Journal of the American Chemical Society. 130: 7534-5. PMID 18494474 DOI: 10.1021/Ja8015878  0.319
2008 Liu Z, Hartwig JF. Mild, rhodium-catalyzed intramolecular hydroamination of unactivated terminal and internal alkenes with primary and secondary amines. Journal of the American Chemical Society. 130: 1570-1. PMID 18183986 DOI: 10.1021/Ja710126X  0.316
2008 Liao X, Weng Z, Hartwig JF. Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel. Journal of the American Chemical Society. 130: 195-200. PMID 18076166 DOI: 10.1021/Ja074453G  0.319
2008 Ueno S, Hartwig JF. Iridium-Catalyzed Asymmetric Allylic Etherification Synfacts. 2008: 500-500. DOI: 10.1055/S-2008-1072667  0.33
2008 Boebel TA, Hartwig JF. Iridium-catalyzed preparation of silylboranes by silane borylation and their use in the catalytic borylation of arenes Organometallics. 27: 6013-6019. DOI: 10.1021/Om800696D  0.365
2008 Boebel TA, Hartwig JF. ChemInform Abstract: Silyl-Directed, Iridium-Catalyzed ortho-Borylation of Arenes. A One-Pot ortho-Borylation of Phenols, Arylamines, and Alkylarenes. Cheminform. 39. DOI: 10.1002/CHIN.200843174  0.323
2008 Liao X, Weng Z, Hartwig JF. ChemInform Abstract: Enantioselective α-Arylation of Ketones with Aryl Triflates Catalyzed by Difluorphos Complexes of Palladium and Nickel. Cheminform. 39. DOI: 10.1002/CHIN.200822032  0.304
2008 Pouy MJ, Leitner A, Weix DJ, Ueno S, Hartwig JF. ChemInform Abstract: Enantioselecitve Iridium-Catalyzed Allylic Amination of Ammonia and Convenient Ammonia Surrogates. Cheminform. 39. DOI: 10.1002/CHIN.200812069  0.313
2007 Murphy JM, Liao X, Hartwig JF. Meta halogenation of 1,3-disubstituted arenes via iridium-catalyzed arene borylation. Journal of the American Chemical Society. 129: 15434-5. PMID 18027947 DOI: 10.1021/Ja076498N  0.318
2007 Stambuli JP, Weng Z, Incarvito CD, Hartwig JF. Reductive elimination of ether from T-shaped, monomeric arylpalladium alkoxides. Angewandte Chemie (International Ed. in English). 46: 7674-7. PMID 17786903 DOI: 10.1002/Anie.200702809  0.336
2007 Pouy MJ, Leitner A, Weix DJ, Ueno S, Hartwig JF. Enantioselective iridium-catalyzed allylic amination of ammonia and convenient ammonia surrogates. Organic Letters. 9: 3949-52. PMID 17725361 DOI: 10.1021/Ol701562P  0.32
2007 Johns AM, Liu Z, Hartwig JF. Primary tert- and sec-allylamines via palladium-catalyzed hydroamination and allylic substitution with hydrazine and hydroxylamine derivatives. Angewandte Chemie (International Ed. in English). 46: 7259-61. PMID 17594679 DOI: 10.1002/Anie.200701899  0.371
2007 Weix DJ, Hartwig JF. Regioselective and enantioselective iridium-catalyzed allylation of enamines. Journal of the American Chemical Society. 129: 7720-1. PMID 17542586 DOI: 10.1021/Ja071455S  0.309
2007 Herzon SB, Hartwig JF. Direct, catalytic hydroaminoalkylation of unactivated olefins with N-alkyl arylamines. Journal of the American Chemical Society. 129: 6690-1. PMID 17474747 DOI: 10.1021/Ja0718366  0.336
2007 Weix DJ, Hartwig JF. Regioselective and Enantioselective Iridium-Catalyzed Allylation of Enamines. Cheminform. 38. DOI: 10.1002/CHIN.200744074  0.33
2007 Hartwig JF, Shekhar S, Shen Q, Barrios-Landeros F. Synthesis of Anilines Cheminform. 38. DOI: 10.1002/9780470682531.Pat0391  0.321
2006 Takemiya A, Hartwig JF. Palladium-catalyzed synthesis of aryl ketones by coupling of aryl bromides with an acyl anion equivalent. Journal of the American Chemical Society. 128: 14800-1. PMID 17105278 DOI: 10.1021/Ja064782T  0.316
2006 Murphy JM, Lawrence JD, Kawamura K, Incarvito C, Hartwig JF. Ruthenium-catalyzed regiospecific borylation of methyl C-H bonds. Journal of the American Chemical Society. 128: 13684-5. PMID 17044685 DOI: 10.1021/Ja064092P  0.326
2006 Fernández-Rodríguez MA, Shen Q, Hartwig JF. Highly efficient and functional-group-tolerant catalysts for the palladium-catalyzed coupling of aryl chlorides with thiols. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 7782-96. PMID 17009367 DOI: 10.1002/Chem.200600949  0.33
2006 Shekhar S, Trantow B, Leitner A, Hartwig JF. Sequential catalytic isomerization and allylic substitution. Conversion of racemic branched allylic carbonates to enantioenriched allylic substitution products. Journal of the American Chemical Society. 128: 11770-1. PMID 16953612 DOI: 10.1021/Ja0644273  0.313
2006 Shen Q, Hartwig JF. Palladium-catalyzed coupling of ammonia and lithium amide with aryl halides. Journal of the American Chemical Society. 128: 10028-9. PMID 16881628 DOI: 10.1021/Ja064005T  0.328
2006 Sakai N, Ridder A, Hartwig JF. Tropene derivatives by sequential intermolecular and transannular, intramolecular palladium-catalyzed hydroamination of cycloheptatriene. Journal of the American Chemical Society. 128: 8134-5. PMID 16787067 DOI: 10.1021/Ja061349A  0.314
2006 Takemiya A, Hartwig JF. Rhodium-catalyzed intramolecular, anti-Markovnikov hydroamination. Synthesis of 3-arylpiperidines. Journal of the American Chemical Society. 128: 6042-3. PMID 16669666 DOI: 10.1021/Ja058299E  0.341
2006 Hama T, Culkin DA, Hartwig JF. Palladium-catalyzed intermolecular alpha-arylation of zinc amide enolates under mild conditions. Journal of the American Chemical Society. 128: 4976-85. PMID 16608331 DOI: 10.1021/Ja056076I  0.324
2006 Fernández-Rodríguez MA, Shen Q, Hartwig JF. A general and long-lived catalyst for the palladium-catalyzed coupling of aryl halides with thiols. Journal of the American Chemical Society. 128: 2180-1. PMID 16478149 DOI: 10.1021/Ja0580340  0.358
2006 Johns AM, Utsunomiya M, Incarvito CD, Hartwig JF. A highly active palladium catalyst for intermolecular hydroamination. Factors that control reactivity and additions of functionalized anilines to dienes and vinylarenes. Journal of the American Chemical Society. 128: 1828-39. PMID 16464081 DOI: 10.1021/Ja056003Z  0.311
2006 Sakai N, Ridder A, Hartwig JF. Tropene Derivatives by Sequential Intermolecular and Transannular, Intramolecular Palladium-Catalyzed Hydroamination of Cycloheptatriene. Cheminform. 37. DOI: 10.1002/CHIN.200644160  0.325
2006 Graening T, Hartwig JF. Iridium-Catalyzed Regio- and Enantioselective Allylation of Ketone Enolates. Cheminform. 37. DOI: 10.1002/CHIN.200621026  0.333
2005 Graening T, Hartwig JF. Iridium-catalyzed regio- and enantioselective allylation of ketone enolates. Journal of the American Chemical Society. 127: 17192-3. PMID 16332060 DOI: 10.1021/JA0566275  0.355
2005 Wu L, Hartwig JF. Mild palladium-catalyzed selective monoarylation of nitriles. Journal of the American Chemical Society. 127: 15824-32. PMID 16277525 DOI: 10.1021/Ja053027X  0.313
2005 Boller TM, Murphy JM, Hapke M, Ishiyama T, Miyaura N, Hartwig JF. Mechanism of the mild functionalization of arenes by diboron reagents catalyzed by iridium complexes. Intermediacy and chemistry of bipyridine-ligated iridium trisboryl complexes. Journal of the American Chemical Society. 127: 14263-78. PMID 16218621 DOI: 10.1021/Ja053433G  0.33
2005 Leitner A, Shu C, Hartwig JF. Effects of catalyst activation and ligand steric properties on the enantioselective allylation of amines and phenoxides. Organic Letters. 7: 1093-6. PMID 15760147 DOI: 10.1021/Ol050029D  0.302
2004 Leitner A, Larsen J, Steffens C, Hartwig JF. Palladium-catalyzed addition of mono- and dicarbonyl compounds to conjugated dienes. The Journal of Organic Chemistry. 69: 7552-7. PMID 15497981 DOI: 10.1021/Jo0490999  0.337
2004 Shu C, Hartwig JF. Iridium-catalyzed intermolecular allylic etherification with aliphatic alkoxides: asymmetric synthesis of dihydropyrans and dihydrofurans. Angewandte Chemie (International Ed. in English). 43: 4794-7. PMID 15366090 DOI: 10.1002/Anie.200460214  0.303
2004 Utsunomiya M, Hartwig JF. Ruthenium-catalyzed anti-Markovnikov hydroamination of vinylarenes. Journal of the American Chemical Society. 126: 2702-3. PMID 14995178 DOI: 10.1021/Ja031542U  0.331
2004 Utsunomiya M, Hartwig JF. Intermolecular, markovnikov hydroamination of vinylarenes with alkylamines. Journal of the American Chemical Society. 125: 14286-7. PMID 14624571 DOI: 10.1021/Ja0375535  0.336
2004 Orbell J, Morikawa T, Hartwig J, Hanley J, Allen N. "Machiavellian" intelligence as a basis for the evolution of cooperative dispositions American Political Science Review. 98: 1-15. DOI: 10.1017/S0003055404000966  0.522
2004 Shu C, Hartwig JF. Iridium-Catalyzed Intermolecular Allylic Etherification with Aliphatic Alkoxides: Asymmetric Synthesis of Dihydropyrans and Dihydrofurans. Cheminform. 35. DOI: 10.1002/CHIN.200452047  0.303
2003 Hama T, Liu X, Culkin DA, Hartwig JF. Palladium-catalyzed alpha-arylation of esters and amides under more neutral conditions. Journal of the American Chemical Society. 125: 11176-7. PMID 16220921 DOI: 10.1021/Ja036792P  0.311
2003 Kiener CA, Shu C, Incarvito C, Hartwig JF. Identification of an activated catalyst in the iridium-catalyzed allylic amination and etherification. Increased rates, scope, and selectivity. Journal of the American Chemical Society. 125: 14272-3. PMID 14624564 DOI: 10.1021/Ja038319H  0.324
2003 Culkin DA, Hartwig JF. Palladium-catalyzed alpha-arylation of carbonyl compounds and nitriles. Accounts of Chemical Research. 36: 234-45. PMID 12693921 DOI: 10.1021/Ar0201106  0.338
2003 López F, Ohmura T, Hartwig JF. Regio- and enantioselective iridium-catalyzed intermolecular allylic etherification of achiral allylic carbonates with phenoxides. Journal of the American Chemical Society. 125: 3426-7. PMID 12643693 DOI: 10.1021/Ja029790Y  0.325
2003 Ohmura T, Hartwig JF. Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex. Journal of the American Chemical Society. 124: 15164-5. PMID 12487578 DOI: 10.1021/Ja028614M  0.313
2003 Ohmura T, Hartwig JF. Regio- and Enantioselective Allylic Amination of Achiral Allylic Esters Catalyzed by an Iridium—Phosphoramidite Complex. Cheminform. 34. DOI: 10.1002/CHIN.200319051  0.322
2003 Kuwano R, Utsunomiya M, Hartwig JF. Aqueous Hydroxide as a Base for Palladium-Catalyzed Amination of Aryl Chlorides and Bromides. Cheminform. 34. DOI: 10.1002/CHIN.200306053  0.322
2002 Stambuli JP, Bühl M, Hartwig JF. Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand. Journal of the American Chemical Society. 124: 9346-7. PMID 12167009 DOI: 10.1021/Ja0264394  0.308
2002 Kataoka N, Shelby Q, Stambuli JP, Hartwig JF. Air stable, sterically hindered ferrocenyl dialkylphosphines for palladium-catalyzed C[bond]C, C[bond]N, and C[bond]O bond-forming cross-couplings. The Journal of Organic Chemistry. 67: 5553-66. PMID 12153253 DOI: 10.1021/Jo025732J  0.347
2002 Pawlas J, Nakao Y, Kawatsura M, Hartwig JF. A general nickel-catalyzed hydroamination of 1,3-dienes by alkylamines: catalyst selection, scope, and mechanism. Journal of the American Chemical Society. 124: 3669-79. PMID 11929257 DOI: 10.1021/Ja017575W  0.369
2002 Beare NA, Hartwig JF. Palladium-catalyzed arylation of malonates and cyanoesters using sterically hindered trialkyl- and ferrocenyldialkylphosphine ligands. The Journal of Organic Chemistry. 67: 541-55. PMID 11798329 DOI: 10.1021/Jo016226H  0.313
2002 Ishiyama T, Takagi J, Ishida K, Miyaura N, Anastasi NR, Hartwig JF. Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate. Journal of the American Chemical Society. 124: 390-1. PMID 11792205 DOI: 10.1021/Ja0173019  0.317
2002 Lee S, Hartwig JF. Improved catalysts for the palladium-catalyzed synthesis of oxindoles by amide alpha-arylation. Rate acceleration, use of aryl chloride substrates, and a new carbene ligand for asymmetric transformations. The Journal of Organic Chemistry. 66: 3402-15. PMID 11348123 DOI: 10.1021/Jo005761Z  0.309
2002 Takagi J, Sato K, Hartwig JF, Ishiyama T, Miyaura N. Iridium-catalyzed C–H coupling reaction of heteroaromatic compounds with bis(pinacolato)diboron: regioselective synthesis of heteroarylboronates Tetrahedron Letters. 43: 5649-5651. DOI: 10.1016/S0040-4039(02)01135-8  0.331
2001 Lee S, Jørgensen M, Hartwig JF. Palladium-catalyzed synthesis of arylamines from aryl halides and lithium bis(trimethylsilyl)amide as an ammonia equivalent. Organic Letters. 3: 2729-32. PMID 11506620 DOI: 10.1021/Ol016333Y  0.328
2001 Löber O, Kawatsura M, Hartwig JF. Palladium-catalyzed hydroamination of 1,3-dienes: a colorimetric assay and enantioselective additions. Journal of the American Chemical Society. 123: 4366-7. PMID 11457216 DOI: 10.1021/Ja005881O  0.308
2001 Kawatsura M, Hartwig JF. ChemInform Abstract: Palladium-Catalyzed Intermolecular Hydroamination of Vinylarenes Using Arylamines. Cheminform. 32: no-no. DOI: 10.1002/CHIN.200104101  0.334
2000 Kawatsura M, Hartwig JF. Palladium-Catalyzed Intermolecular Hydroamination of Vinylarenes Using Arylamines Journal of the American Chemical Society. 122: 9546-9547. DOI: 10.1021/Ja002284T  0.352
1999 Hartwig JF. Approaches to catalyst discovery. New carbon–heteroatom and carbon–carbon bond formation Pure and Applied Chemistry. 71: 1417-1423. DOI: 10.1351/Pac199971081417  0.33
1999 Mann G, Incarvito C, Rheingold AL, Hartwig JF. Palladium-Catalyzed C−O Coupling Involving Unactivated Aryl Halides. Sterically Induced Reductive Elimination To Form the C−O Bond in Diaryl Ethers Journal of the American Chemical Society. 121: 3224-3225. DOI: 10.1021/Ja984321A  0.339
1999 Kawatsura M, Hartwig JF. Simple, Highly Active Palladium Catalysts for Ketone and Malonate Arylation:  Dissecting the Importance of Chelation and Steric Hindrance Journal of the American Chemical Society. 121: 1473-1478. DOI: 10.1021/Ja983378U  0.342
1998 Hartwig JF. Synthesis, Structure, and Reactivity of a Palladium Hydrazonato Complex: A New Type of Reductive Elimination Reaction To Form C-N Bonds and Catalytic Arylation of Benzophenone Hydrazone. Angewandte Chemie (International Ed. in English). 37: 2090-2093. PMID 29711062 DOI: 10.1002/(Sici)1521-3773(19980817)37:15<2090::Aid-Anie2090>3.0.Co;2-A  0.319
1998 Hartwig JF. Transition Metal Catalyzed Synthesis of Arylamines and Aryl Ethers from Aryl Halides and Triflates: Scope and Mechanism. Angewandte Chemie (International Ed. in English). 37: 2046-2067. PMID 29711045 DOI: 10.1002/(Sici)1521-3773(19980817)37:15<2046::Aid-Anie2046>3.0.Co;2-L  0.313
1998 Shaughnessy KH, Hamann BC, Hartwig JF. Palladium-Catalyzed Inter- and Intramolecular α-Arylation of Amides. Application of Intramolecular Amide Arylation to the Synthesis of Oxindoles The Journal of Organic Chemistry. 63: 6546-6553. DOI: 10.1021/Jo980611Y  0.327
1998 Hamann BC, Hartwig JF. Sterically Hindered Chelating Alkyl Phosphines Provide Large Rate Accelerations in Palladium-Catalyzed Amination of Aryl Iodides, Bromides, and Chlorides, and the First Amination of Aryl TosylatesJ. Am. Chem. Soc.1998,120, 7369−7370 Journal of the American Chemical Society. 120: 12706-12706. DOI: 10.1021/Ja985527E  0.308
1998 Hamann BC, Hartwig JF. Sterically hindered chelating alkyl phosphines provide large rate accelerations in palladium-catalyzed amination of aryl iodides, bromides, and chlorides, and the first amination of aryl tosylates [12] Journal of the American Chemical Society. 120: 7369-7370. DOI: 10.1021/Ja981318I  0.334
1997 Hartwig J. Palladium-Catalyzed Amination of Aryl Halides: Mechanism and Rational Catalyst Design Synlett. 1997: 329-340. DOI: 10.1055/S-1997-789  0.374
1997 Mann G, Hartwig JF. Nickel- vs Palladium-Catalyzed Synthesis of Protected Phenols from Aryl Halides The Journal of Organic Chemistry. 62: 5413-5418. DOI: 10.1021/Jo970453V  0.362
1997 Louie J, Driver MS, Hamann BC, Hartwig JF. Palladium-Catalyzed Amination of Aryl Triflates and Importance of Triflate Addition Rate The Journal of Organic Chemistry. 62: 1268-1273. DOI: 10.1021/Jo961930X  0.308
1995 Louie J, Hartwig JF. Palladium-catalyzed synthesis of arylamines from aryl halides. Mechanistic studies lead to coupling in the absence of tin reagents Tetrahedron Letters. 36: 3609-3612. DOI: 10.1016/0040-4039(95)00605-C  0.316
1994 Paul F, Patt J, Hartwig JF. Palladium-catalyzed formation of carbon-nitrogen bonds. Reaction intermediates and catalyst improvements in the hetero cross-coupling of aryl halides and tin amides Journal of the American Chemical Society. 116: 5969-5970. DOI: 10.1021/Ja00092A058  0.311
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