| Year |
Citation |
Score |
| 2024 |
Gao Y, Jiang B, Friede NC, Hunter AC, Boucher DG, Minteer SD, Sigman MS, Reisman SE, Baran PS. Electrocatalytic Asymmetric Nozaki-Hiyama-Kishi Decarboxylative Coupling: Scope, Applications, and Mechanism. Journal of the American Chemical Society. PMID 38324710 DOI: 10.1021/jacs.3c13442 |
0.429 |
|
| 2024 |
Akana ME, Tcyrulnikov S, Akana-Schneider BD, Reyes GP, Monfette S, Sigman MS, Hansen EC, Weix DJ. Computational Methods Enable the Prediction of Improved Catalysts for Nickel-Catalyzed Cross-Electrophile Coupling. Journal of the American Chemical Society. PMID 38276910 DOI: 10.1021/jacs.3c09554 |
0.354 |
|
| 2023 |
Raghavan P, Haas BC, Ruos ME, Schleinitz J, Doyle AG, Reisman SE, Sigman MS, Coley CW. Dataset Design for Building Models of Chemical Reactivity. Acs Central Science. 9: 2196-2204. PMID 38161380 DOI: 10.1021/acscentsci.3c01163 |
0.67 |
|
| 2023 |
Morack T, Myers TE, Karas LJ, Hardy MA, Mercado BQ, Sigman MS, Miller SJ. An Asymmetric Aromatic Finkelstein Reaction: A Platform for Remote Diarylmethane Desymmetrization. Journal of the American Chemical Society. 145: 22322-22328. PMID 37788150 DOI: 10.1021/jacs.3c08727 |
0.389 |
|
| 2023 |
van Dijk L, Haas BC, Lim NK, Clagg K, Dotson JJ, Treacy SM, Piechowicz KA, Roytman VA, Zhang H, Toste FD, Miller SJ, Gosselin F, Sigman MS. Data Science-Enabled Palladium-Catalyzed Enantioselective Aryl-Carbonylation of Sulfonimidamides. Journal of the American Chemical Society. PMID 37656964 DOI: 10.1021/jacs.3c06674 |
0.55 |
|
| 2023 |
Liles JP, Rouget-Virbel C, Wahlman JLH, Rahimoff R, Crawford JM, Medlin A, O'Connor V, Li J, Roytman VA, Toste FD, Sigman MS. Data Science Enables the Development of a New Class of Chiral Phosphoric Acid Catalysts. Chem. 9: 1518-1537. PMID 37519827 DOI: 10.1016/j.chempr.2023.02.020 |
0.493 |
|
| 2023 |
Ortiz KG, Dotson JJ, Robinson DJ, Sigman MS, Karimov RR. Catalyst-Controlled Enantioselective and Regiodivergent Addition of Aryl Boron Nucleophiles to N-Alkyl Nicotinate Salts. Journal of the American Chemical Society. 145: 11781-11788. PMID 37205733 DOI: 10.1021/jacs.3c03048 |
0.313 |
|
| 2023 |
Rein J, Rozema SD, Langner OC, Zacate SB, Hardy MA, Siu JC, Mercado BQ, Sigman MS, Miller SJ, Lin S. Generality-oriented optimization of enantioselective aminoxyl radical catalysis. Science (New York, N.Y.). 380: 706-712. PMID 37200427 DOI: 10.1126/science.adf6177 |
0.517 |
|
| 2023 |
Tang T, Hazra A, Min DS, Williams WL, Jones E, Doyle AG, Sigman MS. Interrogating the Mechanistic Features of Ni(I)-Mediated Aryl Iodide Oxidative Addition Using Electroanalytical and Statistical Modeling Techniques. Journal of the American Chemical Society. PMID 37014945 DOI: 10.1021/jacs.3c01726 |
0.58 |
|
| 2023 |
Rein J, Meinhardt JM, Hofstra Wahlman JL, Sigman MS, Lin S. A Physical Organic Approach towards Statistical Modeling of Tetrazole and Azide Decomposition. Angewandte Chemie (International Ed. in English). e202218213. PMID 36823344 DOI: 10.1002/anie.202218213 |
0.418 |
|
| 2022 |
Samha MH, Wahlman JLH, Read JA, Werth J, Jacobsen EN, Sigman MS. Exploring Structure-Function Relationships of Aryl Pyrrolidine-Based Hydrogen-Bond Donors in Asymmetric Catalysis Using Data-Driven Techniques. Acs Catalysis. 12: 14836-14845. PMID 36816226 DOI: 10.1021/acscatal.2c04824 |
0.559 |
|
| 2022 |
Dotson JJ, van Dijk L, Timmerman JC, Grosslight S, Walroth RC, Gosselin F, Püntener K, Mack KA, Sigman MS. Data-Driven Multi-Objective Optimization Tactics for Catalytic Asymmetric Reactions Using Bisphosphine Ligands. Journal of the American Chemical Society. PMID 36574729 DOI: 10.1021/jacs.2c08513 |
0.338 |
|
| 2022 |
Nistanaki SK, Williams CG, Wigman B, Wong JJ, Haas BC, Popov S, Werth J, Sigman MS, Houk KN, Nelson HM. Catalytic asymmetric C-H insertion reactions of vinyl carbocations. Science (New York, N.Y.). 378: 1085-1091. PMID 36480623 DOI: 10.1126/science.ade5320 |
0.352 |
|
| 2022 |
Xu J, Grosslight S, Mack KA, Nguyen SC, Clagg K, Lim NK, Timmerman JC, Shen J, White NA, Sirois LE, Han C, Zhang H, Sigman MS, Gosselin F. Atroposelective Negishi Coupling Optimization Guided by Multivariate Linear Regression Analysis: Asymmetric Synthesis of KRAS G12C Covalent Inhibitor GDC-6036. Journal of the American Chemical Society. PMID 36326518 DOI: 10.1021/jacs.2c09917 |
0.362 |
|
| 2022 |
Tang T, Jones E, Wild T, Hazra A, Minteer SD, Sigman MS. Investigating Oxidative Addition Mechanisms of Allylic Electrophiles with Low-Valent Ni/Co Catalysts Using Electroanalytical and Data Science Techniques. Journal of the American Chemical Society. 144: 20056-20066. PMID 36265077 DOI: 10.1021/jacs.2c09120 |
0.387 |
|
| 2022 |
Xu EY, Werth J, Roos CB, Bendelsmith AJ, Sigman MS, Knowles RR. Noncovalent Stabilization of Radical Intermediates in the Enantioselective Hydroamination of Alkenes with Sulfonamides. Journal of the American Chemical Society. PMID 36197450 DOI: 10.1021/jacs.2c07099 |
0.624 |
|
| 2022 |
Gnaim S, Bauer A, Zhang HJ, Chen L, Gannett C, Malapit CA, Hill DE, Vogt D, Tang T, Daley RA, Hao W, Zeng R, Quertenmont M, Beck WD, Kandahari E, ... ... Sigman MS, et al. Cobalt-electrocatalytic HAT for functionalization of unsaturated C-C bonds. Nature. 605: 687-695. PMID 35614246 DOI: 10.1038/s41586-022-04595-3 |
0.587 |
|
| 2021 |
Zell D, Kingston C, Jermaks J, Smith SR, Seeger N, Wassmer J, Sirois LE, Han C, Zhang H, Sigman MS, Gosselin F. Stereoconvergent and -divergent Synthesis of Tetrasubstituted Alkenes by Nickel-Catalyzed Cross-Couplings. Journal of the American Chemical Society. 143: 19078-19090. PMID 34735129 DOI: 10.1021/jacs.1c08399 |
0.381 |
|
| 2021 |
Williams WL, Zeng L, Gensch T, Sigman MS, Doyle AG, Anslyn EV. The Evolution of Data-Driven Modeling in Organic Chemistry. Acs Central Science. 7: 1622-1637. PMID 34729406 DOI: 10.1021/acscentsci.1c00535 |
0.558 |
|
| 2021 |
Newman-Stonebraker SH, Smith SR, Borowski JE, Peters E, Gensch T, Johnson HC, Sigman MS, Doyle AG. Univariate classification of phosphine ligation state and reactivity in cross-coupling catalysis. Science (New York, N.Y.). 374: 301-308. PMID 34648340 DOI: 10.1126/science.abj4213 |
0.492 |
|
| 2021 |
Crawford JM, Kingston C, Toste FD, Sigman MS. Data Science Meets Physical Organic Chemistry. Accounts of Chemical Research. PMID 34351757 DOI: 10.1021/acs.accounts.1c00285 |
0.587 |
|
| 2021 |
Dherange BD, Kelly PQ, Liles JP, Sigman MS, Levin MD. Carbon Atom Insertion into Pyrroles and Indoles Promoted by Chlorodiazirines. Journal of the American Chemical Society. PMID 34286965 DOI: 10.1021/jacs.1c06287 |
0.666 |
|
| 2021 |
DeLano TJ, Dibrell SE, Lacker CR, Pancoast AR, Poremba KE, Cleary L, Sigman MS, Reisman SE. Nickel-catalyzed asymmetric reductive cross-coupling of α-chloroesters with (hetero)aryl iodides. Chemical Science. 12: 7758-7762. PMID 34168828 DOI: 10.1039/d1sc00822f |
0.642 |
|
| 2020 |
Reid JP, Hu M, Ito S, Huang B, Hong CM, Xiang H, Sigman MS, Toste FD. Strategies for remote enantiocontrol in chiral gold(iii) complexes applied to catalytic enantioselective γ,δ-Diels-Alder reactions. Chemical Science. 11: 6450-6456. PMID 34094110 DOI: 10.1039/d0sc00497a |
0.595 |
|
| 2020 |
Prater MB, Sigman MS. Enantioselective Synthesis of Alkyl Allyl Ethers via Palladium-Catalyzed Redox-Relay Heck Alkenylation of -Alkyl Enol Ethers. Israel Journal of Chemistry. 60: 452-460. PMID 33446940 DOI: 10.1002/ijch.201900077 |
0.374 |
|
| 2020 |
De Jesus Silva J, Ferreira MAB, Fedorov A, Sigman MS, Copéret C. Molecular-level insight in supported olefin metathesis catalysts by combining surface organometallic chemistry, high throughput experimentation, and data analysis. Chemical Science. 11: 6717-6723. PMID 33133485 DOI: 10.1039/D0Sc02594A |
0.407 |
|
| 2020 |
Robinson SG, Wu X, Jiang B, Sigman MS, Lin S. Mechanistic Studies Inform Design of Improved Ti(salen) Catalysts for Enantioselective [3 + 2] Cycloaddition. Journal of the American Chemical Society. PMID 33064948 DOI: 10.1021/jacs.0c07128 |
0.547 |
|
| 2020 |
Reisman SE, Sarpong R, Sigman MS, Yoon TP. Organic Chemistry: A Call to Action for Diversity and Inclusion. Acs Central Science. 6: 1241-1247. PMID 32875064 DOI: 10.1021/Acs.Organomet.0C00519 |
0.689 |
|
| 2020 |
Werth J, Sigman MS. Connecting and Analyzing Enantioselective Bifunctional Hydrogen Bond Donor Catalysis Using Data Science Tools. Journal of the American Chemical Society. PMID 32844647 DOI: 10.1021/Jacs.0C06905 |
0.411 |
|
| 2020 |
Reisman SE, Sarpong R, Sigman MS, Yoon TP. Organic Chemistry: A Call to Action for Diversity and Inclusion. Organic Letters. PMID 32806162 DOI: 10.1021/Acs.Orglett.0C02559 |
0.689 |
|
| 2020 |
Reisman SE, Sarpong R, Sigman MS, Yoon TP. Organic Chemistry: A Call to Action for Diversity and Inclusion. The Journal of Organic Chemistry. PMID 32806096 DOI: 10.1021/Acs.Joc.0C01607 |
0.697 |
|
| 2020 |
Levin MD, Ovian JM, Read JA, Sigman MS, Jacobsen EN. Catalytic Enantioselective Synthesis of Difluorinated Alkyl Bromides. Journal of the American Chemical Society. PMID 32799536 DOI: 10.1021/Jacs.0C07043 |
0.823 |
|
| 2020 |
Toste FD, Tsai CC, Sandford C, Wu T, Chen B, Sigman M. Enantioselective Intramolecular Allylic Substitution via Synergistic Palladium/Chiral Phosphoric Acid Catalysis: Insight into Stereoinduction through Statistical Modeling. Angewandte Chemie (International Ed. in English). PMID 32453890 DOI: 10.1002/Anie.202006237 |
0.612 |
|
| 2020 |
Robinson SG, Mack JBC, Alektiar SN, Du Bois J, Sigman MS. Electrochemical Ruthenium-Catalyzed C-H Hydroxylation of Amine Derivatives in Aqueous Acid. Organic Letters. PMID 32419465 DOI: 10.1021/Acs.Orglett.0C01313 |
0.44 |
|
| 2020 |
Ross SP, Rahman AA, Sigman MS. Development and Mechanistic Interrogation of Interrupted Chain-Walking in the Enantioselective Relay Heck Reaction. Journal of the American Chemical Society. PMID 32412759 DOI: 10.1021/Jacs.0C03589 |
0.448 |
|
| 2020 |
Rosales A, Ross SP, Helquist P, Norrby PO, Sigman MS, Wiest O. Transition State Force Field for the Asymmetric Redox Relay Heck Reaction. Journal of the American Chemical Society. PMID 32249569 DOI: 10.1021/Jacs.0C01979 |
0.576 |
|
| 2020 |
Miro J, Gensch T, Ellwart M, Han S, Lin HH, Sigman MS, Toste FD. Enantioselective Allenoate-Claisen Rearrangement using Chiral Phosphate Catalysts. Journal of the American Chemical Society. PMID 32182422 DOI: 10.1021/Jacs.0C01637 |
0.592 |
|
| 2020 |
Robinson SG, Sigman MS. Integrating Electrochemical and Statistical Analysis Tools for Molecular Design and Mechanistic Understanding. Accounts of Chemical Research. PMID 31920070 DOI: 10.1021/Acs.Accounts.9B00527 |
0.366 |
|
| 2020 |
Reid JP, Hu M, Ito S, Huang B, Hong CM, Xiang H, Sigman MS, Toste FD. Strategies for remote enantiocontrol in chiral gold( iii ) complexes applied to catalytic enantioselective γ,δ-Diels–Alder reactions Chemical Science. 11: 6450-6456. DOI: 10.1039/D0Sc00497A |
0.64 |
|
| 2019 |
Li J, Grosslight S, Miller SJ, Sigman MS, Toste FD. Site-selective acylation of natural products with BINOL-derived phosphoric acids. Acs Catalysis. 9: 9794-9799. PMID 31827975 DOI: 10.1021/Acscatal.9B03535 |
0.514 |
|
| 2019 |
Reid JP, Proctor RSJ, Sigman MS, Phipps RJ. Predictive Multivariate Linear Regression Analysis Guides Successful Catalytic Enantioselective Minisci Reactions of Diazines. Journal of the American Chemical Society. PMID 31710210 DOI: 10.1021/Jacs.9B11658 |
0.456 |
|
| 2019 |
Sandford C, Fries LR, Ball TE, Minteer SD, Sigman MS. Mechanistic Studies into the Oxidative Addition of Co(I) Complexes: Combining Electroanalytical Techniques with Parameterization. Journal of the American Chemical Society. PMID 31698896 DOI: 10.1021/Jacs.9B10771 |
0.459 |
|
| 2019 |
Chen ZM, Liu J, Guo JY, Loch M, DeLuca RJ, Sigman MS. Palladium-catalyzed enantioselective alkenylation of alkenylbenzene derivatives. Chemical Science. 10: 7246-7250. PMID 31588293 DOI: 10.1039/C9Sc02380A |
0.841 |
|
| 2019 |
Yan Y, Robinson SG, Sigman MS, Sanford MS. Mechanism-Based Design of a High-Potential Catholyte Enables a 3.2 V All-Organic Nonaqueous Redox Flow Battery. Journal of the American Chemical Society. PMID 31503480 DOI: 10.1021/Jacs.9B07345 |
0.336 |
|
| 2019 |
Sandford C, Edwards MA, Klunder KJ, Hickey DP, Li M, Barman K, Sigman MS, White HS, Minteer SD. A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms. Chemical Science. 10: 6404-6422. PMID 31367303 DOI: 10.1039/C9Sc01545K |
0.431 |
|
| 2019 |
Christian AH, Jia S, Cao W, Zhang P, Meza AT, Sigman MS, Chang CJ, Toste FD. A Physical Organic Approach to Tuning Reagents for Selective and Stable Methionine Bioconjugation. Journal of the American Chemical Society. PMID 31361488 DOI: 10.1021/Jacs.9B04744 |
0.605 |
|
| 2019 |
Allen JR, Bahamonde A, Furukawa Y, Sigman MS. Correction to "Enantioselective -Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction". Journal of the American Chemical Society. PMID 31347841 DOI: 10.1021/Jacs.9B07380 |
0.448 |
|
| 2019 |
Reid JP, Sigman MS. Holistic prediction of enantioselectivity in asymmetric catalysis. Nature. 571: 343-348. PMID 31316193 DOI: 10.1038/S41586-019-1384-Z |
0.482 |
|
| 2019 |
Liu J, Yuan Q, Toste FD, Sigman MS. Enantioselective construction of remote tertiary carbon-fluorine bonds. Nature Chemistry. PMID 31308495 DOI: 10.1038/S41557-019-0289-7 |
0.543 |
|
| 2019 |
Crawford JM, Sigman MS. Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element? Synthesis. 51: 1021-1036. PMID 31235980 DOI: 10.1055/S-0037-1611636 |
0.357 |
|
| 2019 |
Yuan Q, Sigman MS. Palladium-Catalyzed Enantioselective Alkenylation of Enelactams using a Relay Heck Strategy. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31216370 DOI: 10.1002/Chem.201902813 |
0.443 |
|
| 2019 |
Ferreira MAB, De Jesus Silva J, Grosslight S, Fedorov A, Sigman MS, Copéret C. Non-Covalent Interactions Drive the Efficiency of Molybdenum Imido Alkylidene Catalysts for Olefin Metathesis. Journal of the American Chemical Society. PMID 31180674 DOI: 10.1021/Jacs.9B04367 |
0.46 |
|
| 2019 |
Bahamonde A, Al Rifaie B, Martín-Heras V, Allen JR, Sigman MS. Enantioselective Markovnikov Addition of Carbamates to Allylic Alcohols for the Construction of α-Secondary and α-Tertiary Amines. Journal of the American Chemical Society. PMID 31124676 DOI: 10.1021/Jacs.9B03438 |
0.446 |
|
| 2019 |
Allen JR, Bahamonde A, Furukawa Y, Sigman MS. Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction. Journal of the American Chemical Society. PMID 31117643 DOI: 10.1021/Jacs.9B01476 |
0.48 |
|
| 2019 |
Kwon Y, Li J, Reid JP, Crawford JM, Jacob R, Sigman MS, Toste FD, Miller SJ. Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration. Journal of the American Chemical Society. PMID 30920223 DOI: 10.1021/Jacs.9B01911 |
0.57 |
|
| 2019 |
Mack JBC, Walker KL, Robinson SG, Zare RN, Sigman MS, Waymouth RM, Du Bois J. Mechanistic Study of Ruthenium-Catalyzed C-H Hydroxylation Reveals an Unexpected Pathway for Catalyst Arrest. Journal of the American Chemical Society. PMID 30601662 DOI: 10.1021/Jacs.8B10950 |
0.481 |
|
| 2019 |
Hickey DP, Sandford C, Rhodes Z, Gensch T, Fries LR, Sigman MS, Minteer SD. Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low Valent Co(I) Intermediates. Journal of the American Chemical Society. PMID 30599130 DOI: 10.1021/Jacs.8B12634 |
0.367 |
|
| 2019 |
Prater MB, Sigman MS. Enantioselective Synthesis of Alkyl Allyl Ethers via Palladium‐Catalyzed Redox‐Relay Heck Alkenylation of
O
‐Alkyl Enol Ethers Israel Journal of Chemistry. 60: 452-460. DOI: 10.1002/Ijch.201900077 |
0.382 |
|
| 2019 |
Yuan Q, Prater MB, Sigman MS. Enantioselective Synthesis of γ‐Functionalized Cyclopentenones and δ‐Functionalized Cycloheptenones Utilizing a Redox‐Relay Heck Strategy Advanced Synthesis & Catalysis. 362: 326-330. DOI: 10.1002/Adsc.201901239 |
0.365 |
|
| 2018 |
Albright H, Riehl PS, McAtee CC, Reid JP, Ludwig JR, Karp L, Zimmerman PM, Sigman MS, Schindler CS. Catalytic Carbonyl-Olefin Metathesis of Aliphatic Ketones: Iron(III) Homo-Dimers as Lewis Acidic Superelectrophiles. Journal of the American Chemical Society. PMID 30596414 DOI: 10.1021/Jacs.8B11840 |
0.659 |
|
| 2018 |
Race N, Yuan Q, Sigman MS. Enantioselective C2-alkylation of indoles via a redox-relay Heck reaction of 2-indole triflates. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30402891 DOI: 10.1002/Chem.201805416 |
0.504 |
|
| 2018 |
Coelho JAS, Matsumoto A, Orlandi M, Hilton MJ, Sigman MS, Toste FD. Enantioselective fluorination of homoallylic alcohols enabled by the tuning of non-covalent interactions. Chemical Science. 9: 7153-7158. PMID 30310638 DOI: 10.1039/C8Sc02223B |
0.591 |
|
| 2018 |
Zhao S, Gensch T, Murray B, Niemeyer ZL, Sigman MS, Biscoe MR. Enantiodivergent Pd-catalyzed C-C bond formation enabled through ligand parameterization. Science (New York, N.Y.). PMID 30237245 DOI: 10.1126/Science.Aat2299 |
0.486 |
|
| 2018 |
Metsänen TT, Lexa KW, Santiago CB, Chung CK, Xu Y, Liu Z, Humphrey GR, Ruck RT, Sherer EC, Sigman MS. Combining traditional 2D and modern physical organic-derived descriptors to predict enhanced enantioselectivity for the key aza-Michael conjugate addition in the synthesis of Prevymis™ (letermovir). Chemical Science. 9: 6922-6927. PMID 30210766 DOI: 10.1039/C8Sc02089B |
0.728 |
|
| 2018 |
Woods BP, Orlandi M, Huang CD, Sigman MS, Doyle AG. Correction to "Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of Styrenyl Aziridines". Journal of the American Chemical Society. PMID 29889505 DOI: 10.1021/Jacs.8B05650 |
0.593 |
|
| 2018 |
Yuan Q, Sigman MS. Palladium-Catalyzed Enantioselective Relay Heck Arylation of Enelac-tams: Accessing α,β-Unsaturated δ-Lactams. Journal of the American Chemical Society. PMID 29746119 DOI: 10.1021/Jacs.8B02752 |
0.382 |
|
| 2018 |
Santiago CB, Guo JY, Sigman MS. Predictive and mechanistic multivariate linear regression models for reaction development. Chemical Science. 9: 2398-2412. PMID 29719711 DOI: 10.1039/C7Sc04679K |
0.351 |
|
| 2018 |
Patel HH, Prater MB, Squire SO, Sigman MS. Formation of Chiral Allylic Ethers via an Enantioselective Palladium-Catalyzed Alkenylation of Acyclic Enol Ethers. Journal of the American Chemical Society. PMID 29665329 DOI: 10.1021/Jacs.8B02751 |
0.475 |
|
| 2018 |
Crawford JM, Stone E, Metrano AJ, Miller SJ, Sigman MS. Parameterization and Analysis of Peptide-Based Catalysts for the At-roposelective Bromination of 3-Arylquinazolin-4(3H)-ones. Journal of the American Chemical Society. PMID 29300461 DOI: 10.1021/Jacs.7B11303 |
0.313 |
|
| 2017 |
Christian AH, Niemeyer ZL, Sigman MS, Toste FD. Uncovering Subtle Ligand Effects of Phosphines Using Gold(I) Catalysis. Acs Catalysis. 7: 3973-3978. PMID 29686935 DOI: 10.1021/Acscatal.7B00757 |
0.557 |
|
| 2017 |
Lancaster L, Hickey DP, Sigman MS, Minteer SD, Wheeldon I. Bioinspired design of a hybrid bifunctional enzymatic/organic electrocatalyst for site selective alcohol oxidation. Chemical Communications (Cambridge, England). PMID 29260808 DOI: 10.1039/C7Cc08548F |
0.376 |
|
| 2017 |
Toste FD, Biswas S, Kubota K, Sigman MS, Orlandi M, Turberg M, Miles D. Enantioselective Synthesis of N,S-Acetals by an Oxidative Pummerer Type Transformation Using Anionic Phase-Transfer Catalysis. Angewandte Chemie (International Ed. in English). PMID 29171138 DOI: 10.1002/Anie.201711277 |
0.593 |
|
| 2017 |
Toste FD, Biswas S, Kubota K, Sigman MS, Orlandi M, Turberg M, Miles D. Enantioselective Synthesis of N,S-Acetals by an Oxidative Pummerer Type Transformation Using Anionic Phase-Transfer Catalysis. Angewandte Chemie (International Ed. in English). PMID 29171138 DOI: 10.1002/Anie.201711277 |
0.593 |
|
| 2017 |
Bischoff AJ, Nelson BM, Niemeyer ZL, Sigman MS, Movassaghi M. Quantitative Modeling of Bis(pyridine)silver (I) Permanganate Oxidation of Hydantoin Derivatives: Guidelines for Predicting the Site of Oxidation in Complex Substrates. Journal of the American Chemical Society. PMID 28975782 DOI: 10.1021/Jacs.7B09541 |
0.635 |
|
| 2017 |
Toste FD, Sigman MS, Miller SJ. Pursuit of Noncovalent Interactions for Strategic Site-Selective Catalysis. Accounts of Chemical Research. 50: 609-615. PMID 28945415 DOI: 10.1021/Acs.Accounts.6B00613 |
0.559 |
|
| 2017 |
Orlandi M, Toste FD, Sigman MS. Multidimensional Correlations in Asymmetric Catalysis via Parameterization of Uncatalyzed Transition States. Angewandte Chemie (International Ed. in English). PMID 28902441 DOI: 10.1002/Anie.201707644 |
0.593 |
|
| 2017 |
Niemeyer ZL, Pindi S, Khrakovsky DA, Kuzniewski CN, Hong CM, Joyce LA, Sigman MS, Toste FD. Parameterization of Acyclic Diaminocarbene Ligands Applied to a Gold(I)-Catalyzed Enantioselective Tandem Rearrangement/Cyclization. Journal of the American Chemical Society. PMID 28885017 DOI: 10.1021/Jacs.7B08791 |
0.586 |
|
| 2017 |
Macazo FC, Hickey DP, Abdellaoui S, Sigman MS, Minteer SD. Polymer-immobilized, hybrid multi-catalyst architecture for enhanced electrochemical oxidation of glycerol. Chemical Communications (Cambridge, England). PMID 28871300 DOI: 10.1039/C7Cc05724E |
0.334 |
|
| 2017 |
Engl PS, Santiago CB, Gordon CP, Liao WC, Fedorov A, Copéret C, Sigman MS, Togni A. Exploiting and Understanding the Selectivity in NHC-Based Ru Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes. Journal of the American Chemical Society. PMID 28820588 DOI: 10.1021/Jacs.7B06947 |
0.418 |
|
| 2017 |
Orlandi M, Hilton MJ, Yamamoto E, Toste FD, Sigman MS. Mechanistic Investigations of the Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Benzyl Acrylates. Journal of the American Chemical Society. PMID 28800230 DOI: 10.1021/Jacs.7B06917 |
0.628 |
|
| 2017 |
Keylor MH, Niemeyer ZL, Sigman MS, Tan KL. Inverting Conventional Chemoselectivity in Pd-Catalyzed Amine Arylations with Multiply Halogenated Pyridines. Journal of the American Chemical Society. PMID 28715180 DOI: 10.1021/Jacs.7B05409 |
0.481 |
|
| 2017 |
Mack JBC, Gipson JD, Du Bois J, Sigman MS. Ruthenium-Catalyzed C-H Hydroxylation in Aqueous Acid Enables Selective Functionalization of Amine Derivatives. Journal of the American Chemical Society. PMID 28660763 DOI: 10.1021/Jacs.7B05469 |
0.489 |
|
| 2017 |
Plata RE, Hill DE, Haines BE, Musaev DG, Chu L, Hickey DP, Sigman MS, Yu JQ, Blackmond DG. A Role for Pd(IV) in Catalytic Enantioselective C-H Functionalization With Monoprotected Amino Acid Ligands Under Mild Conditions. Journal of the American Chemical Society. PMID 28605190 DOI: 10.1021/Jacs.7B03716 |
0.643 |
|
| 2017 |
Orlandi M, Coelho JAS, Hilton MJ, Toste FD, Sigman MS. Parameterization of Noncovalent Interactions for Transition State In-terrogation Applied to Asymmetric Catalysis. Journal of the American Chemical Society. PMID 28475315 DOI: 10.1021/Jacs.7B02311 |
0.477 |
|
| 2017 |
Chen ZM, Nervig CS, DeLuca RJ, Sigman MS. Palladium-Catalyzed Enantioselective Redox-Relay Heck Alkynylation of Alkenols to Access Propargylic Stereocenters. Angewandte Chemie (International Ed. in English). PMID 28467031 DOI: 10.1002/Anie.201703089 |
0.82 |
|
| 2017 |
Thornbury RT, Saini V, Fernandes TA, Santiago CB, Talbot EPA, Sigman MS, McKenna JM, Toste FD. The development and mechanistic investigation of a palladium-catalyzed 1,3-arylfluorination of chromenes. Chemical Science. 8: 2890-2897. PMID 28451354 DOI: 10.1039/C6Sc05102B |
0.607 |
|
| 2017 |
Zhang C, Tutkowski B, DeLuca RJ, Joyce LA, Wiest O, Sigman MS. Palladium-Catalyzed Enantioselective Heck Alkenylation of Trisubstituted Allylic Alkenols: A Redox-Relay Strategy to Construct Vicinal Stereocenters. Chemical Science. 8: 2277-2282. PMID 28435657 DOI: 10.1039/C6Sc04585E |
0.837 |
|
| 2017 |
Avila CM, Patel JS, Reddi Y, Saito M, Nelson HM, Shunatona HP, Sigman MS, Sunoj RB, Toste FD. Enantioselective Heck-Matsuda Arylations through Chiral Anion Phase-Transfer of Aryl Diazonium Salts. Angewandte Chemie (International Ed. in English). PMID 28418118 DOI: 10.1002/Anie.201702107 |
0.626 |
|
| 2017 |
Woods BP, Orlandi M, Huang CY, Sigman MS, Doyle AG. Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of Styrenyl Aziridines. Journal of the American Chemical Society. PMID 28406622 DOI: 10.1021/Jacs.7B03448 |
0.637 |
|
| 2017 |
Neel AJ, Hilton MJ, Sigman MS, Toste FD. Exploiting non-covalent π interactions for catalyst design. Nature. 543: 637-646. PMID 28358089 DOI: 10.1038/Nature21701 |
0.521 |
|
| 2017 |
Liao K, Liu W, Niemeyer ZL, Ren Z, Bacsa J, Musaev DG, Sigman MS, Davies HML. Site-Selective Carbene-Induced C–H Functionalization Catalyzed by Dirhodium Tetrakis(triarylcyclopropanecarboxylate) Complexes Acs Catalysis. 8: 678-682. DOI: 10.1021/Acscatal.7B03421 |
0.377 |
|
| 2017 |
Guo J, Minko Y, Santiago CB, Sigman MS. Developing Comprehensive Computational Parameter Sets To Describe the Performance of Pyridine-Oxazoline and Related Ligands Acs Catalysis. 7: 4144-4151. DOI: 10.1021/Acscatal.7B00739 |
0.387 |
|
| 2017 |
Park Y, Niemeyer ZL, Yu J, Sigman MS. Quantifying Structural Effects of Amino Acid Ligands in Pd(II)-Catalyzed Enantioselective C–H Functionalization Reactions Organometallics. 37: 203-210. DOI: 10.1021/Acs.Organomet.7B00751 |
0.624 |
|
| 2016 |
Race NJ, Schwalm CS, Nakamuro T, Sigman MS. Palladium-Catalyzed Enantioselective Intermolecular Coupling of Phenols and Allylic Alcohols. Journal of the American Chemical Society. 138: 15881-15884. PMID 27960316 DOI: 10.1021/Jacs.6B11486 |
0.426 |
|
| 2016 |
Yamamoto E, Hilton MJ, Orlandi M, Saini V, Toste FD, Sigman MS. Development and Analysis of a Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Acrylates Enabled by Chiral Anion Phase Transfer. Journal of the American Chemical Society. 138: 15877-15880. PMID 27960315 DOI: 10.1021/Jacs.6B11367 |
0.628 |
|
| 2016 |
Patel HH, Sigman MS. Enantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols to form Allylic Quaternary Centers. Journal of the American Chemical Society. PMID 27768842 DOI: 10.1021/Jacs.6B09649 |
0.463 |
|
| 2016 |
Santiago CB, Milo A, Sigman MS. Developing a Modern Approach to Account for Steric Effects in Hammett-type Correlations. Journal of the American Chemical Society. PMID 27652906 DOI: 10.1021/Jacs.6B08799 |
0.766 |
|
| 2016 |
Chen ZM, Hilton MJ, Sigman MS. Palladium-Catalyzed Enantioselective Redox-Relay Heck Arylation of 1,1-Disubstituted Homoallylic Alcohols. Journal of the American Chemical Society. PMID 27571167 DOI: 10.1021/Jacs.6B06994 |
0.502 |
|
| 2016 |
Xu L, Zhang X, McCammant MS, Sigman MS, Wu YD, Wiest O. Mechanism and Selectivity in the Pd-Catalyzed Difunctionalization of Isoprene. The Journal of Organic Chemistry. PMID 27486829 DOI: 10.1021/Acs.Joc.6B01317 |
0.45 |
|
| 2016 |
Sigman MS, Harper KC, Bess EN, Milo A. The Development of Multidimensional Analysis Tools for Asymmetric Catalysis and Beyond. Accounts of Chemical Research. PMID 27220055 DOI: 10.1021/Acs.Accounts.6B00194 |
0.824 |
|
| 2016 |
Niemeyer ZL, Milo A, Hickey DP, Sigman MS. Parameterization of phosphine ligands reveals mechanistic pathways and predicts reaction outcomes. Nature Chemistry. 8: 610-7. PMID 27219707 DOI: 10.1038/Nchem.2501 |
0.741 |
|
| 2016 |
McCammant MS, Shigeta T, Sigman MS. Palladium-Catalyzed 1,3-Difunctionalization Using Terminal Alkenes with Alkenyl Nonaflates and Aryl Boronic Acids. Organic Letters. PMID 27019228 DOI: 10.1021/Acs.Orglett.6B00517 |
0.466 |
|
| 2016 |
Wheeldon I, Minteer SD, Banta S, Barton SC, Atanassov P, Sigman M. Substrate channelling as an approach to cascade reactions. Nature Chemistry. 8: 299-309. PMID 27001725 DOI: 10.1038/Nchem.2459 |
0.363 |
|
| 2016 |
Neel AJ, Milo A, Sigman MS, Toste FD. Enantiodivergent Fluorination of Allylic Alcohols: Data Set Design Reveals Structural Interplay between Achiral Directing Group and Chiral Anion. Journal of the American Chemical Society. PMID 26967114 DOI: 10.1021/Jacs.6B00356 |
0.764 |
|
| 2016 |
Lautens M, Yoon H, McCammant MS, Shigeta T, Sigman MS. Regio- and Stereoselective Pd-Catalyzed 1,3-Difunctionalization of Alkenyl Nonaflates Synfacts. 12: 599-599. DOI: 10.1055/S-0035-1562199 |
0.378 |
|
| 2016 |
Weldy NME, Schafer AG, Owens CP, Herting CJ, Varela-Alvarez A, Chen S, Niemeyer Z, Musaev DG, Sigman MS, Davies HML, Blakey SB. Iridium(III)-bis(imidazolinyl)phenyl catalysts for enantioselective C-H functionalization with ethyl diazoacetate Chemical Science. 7: 3142-3146. DOI: 10.1039/C6Sc00190D |
0.443 |
|
| 2015 |
Bess EN, Guptill DM, Davies HML, Sigman MS. Using IR vibrations to quantitatively describe and predict site-selectivity in multivariate Rh-catalyzed C-H functionalization. Chemical Science. 6: 3057-3062. PMID 29403640 DOI: 10.1039/C5Sc00357A |
0.332 |
|
| 2015 |
Hickey DP, Schiedler DA, Matanovic I, Doan PV, Atanassov P, Minteer SD, Sigman MS. Predicting Electrocatalytic Properties: Modeling Structure-Activity Relationships of Nitroxyl Radicals. Journal of the American Chemical Society. PMID 26635089 DOI: 10.1021/Jacs.5B11252 |
0.343 |
|
| 2015 |
Zhang C, Santiago CB, Crawford JM, Sigman MS. Enantioselective Dehydrogenative Heck Arylations of Trisubstituted Alkenes with Indoles to Construct Quaternary Stereocenters. Journal of the American Chemical Society. PMID 26624236 DOI: 10.1021/Jacs.5B11335 |
0.444 |
|
| 2015 |
Hilton MJ, Cheng B, Buckley BR, Xu L, Wiest O, Sigman MS. Relative reactivity of alkenyl alcohols in the palladium-catalyzed redox-relay Heck reaction. Tetrahedron. 71: 6513-6518. PMID 26392640 DOI: 10.1016/J.Tet.2015.05.020 |
0.417 |
|
| 2015 |
Zhang C, Santiago CB, Kou L, Sigman MS. Alkenyl carbonyl derivatives in enantioselective redox relay Heck reactions: accessing α,β-unsaturated systems. Journal of the American Chemical Society. 137: 7290-3. PMID 26030059 DOI: 10.1021/Jacs.5B04289 |
0.443 |
|
| 2015 |
Mougel V, Santiago CB, Zhizhko PA, Bess EN, Varga J, Frater G, Sigman MS, Copéret C. Quantitatively analyzing metathesis catalyst activity and structural features in silica-supported tungsten imido-alkylidene complexes. Journal of the American Chemical Society. 137: 6699-704. PMID 25938259 DOI: 10.1021/Jacs.5B03344 |
0.345 |
|
| 2015 |
Patel HH, Sigman MS. Palladium-catalyzed enantioselective Heck alkenylation of acyclic alkenols using a redox-relay strategy. Journal of the American Chemical Society. 137: 3462-5. PMID 25738548 DOI: 10.1021/Ja5130836 |
0.495 |
|
| 2015 |
McCammant MS, Sigman MS. Development and Investigation of a Site Selective Palladium-Catalyzed 1,4-Difunctionalization of Isoprene using Pyridine-Oxazoline Ligands. Chemical Science (Royal Society of Chemistry : 2010). 6: 1355-1361. PMID 25705367 DOI: 10.1039/C4Sc03074E |
0.416 |
|
| 2015 |
Milo A, Neel AJ, Toste FD, Sigman MS. Organic chemistry. A data-intensive approach to mechanistic elucidation applied to chiral anion catalysis. Science (New York, N.Y.). 347: 737-43. PMID 25678656 DOI: 10.1126/Science.1261043 |
0.79 |
|
| 2015 |
Saini V, O'Dair M, Sigman MS. Synthesis of highly functionalized tri- and tetrasubstituted alkenes via Pd-catalyzed 1,2-hydrovinylation of terminal 1,3-dienes. Journal of the American Chemical Society. 137: 608-11. PMID 25555197 DOI: 10.1021/Ja511640G |
0.44 |
|
| 2015 |
Hilton MJ, Cheng B, Buckley BR, Xu L, Wiest O, Sigman MS. Relative reactivity of alkenyl alcohols in the palladium-catalyzed redox-relay Heck reaction Tetrahedron. DOI: 10.1016/j.tet.2015.05.020 |
0.328 |
|
| 2014 |
Vaden RM, Gligorich KM, Jana R, Sigman MS, Welm BE. The small molecule C-6 is selectively cytotoxic against breast cancer cells and its biological action is characterized by mitochondrial defects and endoplasmic reticulum stress. Breast Cancer Research : Bcr. 16: 472. PMID 25425314 DOI: 10.1186/S13058-014-0472-0 |
0.587 |
|
| 2014 |
Hickey DP, McCammant MS, Giroud F, Sigman MS, Minteer SD. Hybrid enzymatic and organic electrocatalytic cascade for the complete oxidation of glycerol. Journal of the American Chemical Society. 136: 15917-20. PMID 25350383 DOI: 10.1021/Ja5098379 |
0.356 |
|
| 2014 |
Bess EN, Bischoff AJ, Sigman MS. Designer substrate library for quantitative, predictive modeling of reaction performance. Proceedings of the National Academy of Sciences of the United States of America. 111: 14698-703. PMID 25267648 DOI: 10.1073/Pnas.1409522111 |
0.428 |
|
| 2014 |
Hilton MJ, Xu LP, Norrby PO, Wu YD, Wiest O, Sigman MS. Investigating the nature of palladium chain-walking in the enantioselective redox-relay Heck reaction of alkenyl alcohols. The Journal of Organic Chemistry. 79: 11841-50. PMID 25186804 DOI: 10.1021/Jo501813D |
0.623 |
|
| 2014 |
Stokes BJ, Liao L, de Andrade AM, Wang Q, Sigman MS. A palladium-catalyzed three-component-coupling strategy for the differential vicinal diarylation of terminal 1,3-dienes. Organic Letters. 16: 4666-9. PMID 25162125 DOI: 10.1021/Ol502279U |
0.777 |
|
| 2014 |
Stokes BJ, Bischoff AJ, Sigman MS. Pd(Quinox)-Catalyzed Allylic Relay Suzuki Reactions of Secondary Homostyrenyl Tosylates via Alkene-Assisted Oxidative Addition. Chemical Science (Royal Society of Chemistry : 2010). 5: 2336-2339. PMID 24910768 DOI: 10.1039/C4Sc00602J |
0.756 |
|
| 2014 |
Mei TS, Patel HH, Sigman MS. Enantioselective construction of remote quaternary stereocentres. Nature. 508: 340-4. PMID 24717439 DOI: 10.1038/Nature13231 |
0.614 |
|
| 2014 |
Bess EN, DeLuca RJ, Tindall DJ, Oderinde MS, Roizen JL, Du Bois J, Sigman MS. Analyzing site selectivity in Rh2(esp)2-catalyzed intermolecular C-H amination reactions. Journal of the American Chemical Society. 136: 5783-9. PMID 24673332 DOI: 10.1021/Ja5015508 |
0.81 |
|
| 2014 |
Milo A, Bess EN, Sigman MS. Interrogating selectivity in catalysis using molecular vibrations. Nature. 507: 210-4. PMID 24622199 DOI: 10.1038/Nature13019 |
0.702 |
|
| 2014 |
Xu L, Hilton MJ, Zhang X, Norrby PO, Wu YD, Sigman MS, Wiest O. Mechanism, reactivity, and selectivity in palladium-catalyzed redox-relay Heck arylations of alkenyl alcohols. Journal of the American Chemical Society. 136: 1960-7. PMID 24410393 DOI: 10.1021/Ja4109616 |
0.646 |
|
| 2014 |
Deluca RJ, Stokes BJ, Sigman MS. The strategic generation and interception of palladium-hydrides for use in alkene functionalization reactions Pure and Applied Chemistry. 86: 395-408. DOI: 10.1515/Pac-2014-5041 |
0.82 |
|
| 2014 |
Saini V, Stokes BJ, Sigman MS. ChemInform Abstract: Transition-Metal-Catalyzed Laboratory-Scale Carbon-Carbon Bond-Forming Reactions of Ethylene Cheminform. 45: no-no. DOI: 10.1002/chin.201406242 |
0.642 |
|
| 2013 |
Saini V, Stokes BJ, Sigman MS. Transition-metal-catalyzed laboratory-scale carbon-carbon bond-forming reactions of ethylene. Angewandte Chemie (International Ed. in English). 52: 11206-20. PMID 24105881 DOI: 10.1002/Anie.201303916 |
0.687 |
|
| 2013 |
Saini V, Liao L, Wang Q, Jana R, Sigman MS. Pd(0)-catalyzed 1,1-diarylation of ethylene and allylic carbonates. Organic Letters. 15: 5008-11. PMID 24047468 DOI: 10.1021/Ol4023358 |
0.79 |
|
| 2013 |
Mei TS, Werner EW, Burckle AJ, Sigman MS. Enantioselective redox-relay oxidative heck arylations of acyclic alkenyl alcohols using boronic acids. Journal of the American Chemical Society. 135: 6830-3. PMID 23607624 DOI: 10.1021/Ja402916Z |
0.835 |
|
| 2013 |
Harper KC, Sigman MS. Using physical organic parameters to correlate asymmetric catalyst performance. The Journal of Organic Chemistry. 78: 2813-8. PMID 23510194 DOI: 10.1021/Jo4002239 |
0.772 |
|
| 2013 |
McCammant MS, Liao L, Sigman MS. Palladium-catalyzed 1,4-difunctionalization of butadiene to form skipped polyenes. Journal of the American Chemical Society. 135: 4167-70. PMID 23473452 DOI: 10.1021/Ja3110544 |
0.658 |
|
| 2013 |
Harper KC, Vilardi SC, Sigman MS. Prediction of catalyst and substrate performance in the enantioselective propargylation of aliphatic ketones by a multidimensional model of steric effects. Journal of the American Chemical Society. 135: 2482-5. PMID 23387331 DOI: 10.1021/Ja4001807 |
0.777 |
|
| 2013 |
DeLuca RJ, Edwards JL, Steffens LD, Michel BW, Qiao X, Zhu C, Cook SP, Sigman MS. Wacker-type oxidation of internal alkenes using Pd(Quinox) and TBHP. The Journal of Organic Chemistry. 78: 1682-6. PMID 23363387 DOI: 10.1021/Jo302638V |
0.823 |
|
| 2013 |
Bess EN, Sigman MS. Distinctive meta-directing group effect for iridium-catalyzed 1,1-diarylalkene enantioselective hydrogenation. Organic Letters. 15: 646-9. PMID 23311924 DOI: 10.1021/Ol303465C |
0.384 |
|
| 2013 |
DeLuca RJ, Sigman MS. The palladium-catalyzed anti-Markovnikov hydroalkylation of allylic alcohol derivatives. Organic Letters. 15: 92-5. PMID 23252845 DOI: 10.1021/Ol303129P |
0.814 |
|
| 2013 |
Saini V, Stokes BJ, Sigman MS. Übergangsmetallkatalysierte C-C-Kupplungen mit Ethylen im Labormaßstab Angewandte Chemie. 125: 11414-11429. DOI: 10.1002/Ange.201303916 |
0.608 |
|
| 2012 |
Werner EW, Mei TS, Burckle AJ, Sigman MS. Enantioselective Heck arylations of acyclic alkenyl alcohols using a redox-relay strategy. Science (New York, N.Y.). 338: 1455-8. PMID 23239733 DOI: 10.1126/Science.1229208 |
0.842 |
|
| 2012 |
Jana R, Pathak TP, Jensen KH, Sigman MS. Palladium(II)-catalyzed enantio- and diastereoselective synthesis of pyrrolidine derivatives. Organic Letters. 14: 4074-7. PMID 22873944 DOI: 10.1021/Ol3016989 |
0.822 |
|
| 2012 |
Pathak TP, Osiak JG, Vaden RM, Welm BE, Sigman MS. Synthesis and Preliminary Biological Study of Bisindolylmethanes Accessed by an Acid-Catalyzed Hydroarylation of Vinylindoles. Tetrahedron. 68: 5203-5208. PMID 22778488 DOI: 10.1016/J.Tet.2012.03.075 |
0.811 |
|
| 2012 |
Saini V, Sigman MS. Palladium-catalyzed 1,1-difunctionalization of ethylene. Journal of the American Chemical Society. 134: 11372-5. PMID 22765909 DOI: 10.1021/Ja304344H |
0.453 |
|
| 2012 |
Stokes BJ, Opra SM, Sigman MS. Palladium-catalyzed allylic cross-coupling reactions of primary and secondary homoallylic electrophiles. Journal of the American Chemical Society. 134: 11408-11. PMID 22742056 DOI: 10.1021/Ja305403S |
0.819 |
|
| 2012 |
Harper KC, Bess EN, Sigman MS. Multidimensional steric parameters in the analysis of asymmetric catalytic reactions. Nature Chemistry. 4: 366-74. PMID 22522256 DOI: 10.1038/Nchem.1297 |
0.744 |
|
| 2012 |
Sigman MS, Werner EW. Imparting catalyst control upon classical palladium-catalyzed alkenyl C-H bond functionalization reactions. Accounts of Chemical Research. 45: 874-84. PMID 22111756 DOI: 10.1021/Ar200236V |
0.839 |
|
| 2012 |
Jana R, Pathak TP, Jensen KH, Sigman MS. A Palladium-Catalyzed Enantioselective Hydroamination Route to Pyrrolidines Synfacts. 8: 1068-1068. DOI: 10.1055/S-0032-1317290 |
0.729 |
|
| 2011 |
Michel BW, Sigman MS. Peroxide-Mediated Wacker Oxidations for Organic Synthesis. Aldrichimica Acta. 44: 55-62. PMID 27746479 |
0.758 |
|
| 2011 |
Pathak TP, Sigman MS. Applications of ortho-quinone methide intermediates in catalysis and asymmetric synthesis. The Journal of Organic Chemistry. 76: 9210-5. PMID 21999240 DOI: 10.1021/Jo201789K |
0.831 |
|
| 2011 |
Harper KC, Sigman MS. Three-dimensional correlation of steric and electronic free energy relationships guides asymmetric propargylation. Science (New York, N.Y.). 333: 1875-8. PMID 21960632 DOI: 10.1126/Science.1206997 |
0.729 |
|
| 2011 |
Podhajsky SM, Iwai Y, Cook-Sneathen A, Sigman MS. Asymmetric palladium-catalyzed hydroarylation of styrenes and dienes. Tetrahedron. 67: 4435-4441. PMID 21743752 DOI: 10.1016/J.Tet.2011.02.027 |
0.491 |
|
| 2011 |
DeLuca RJ, Sigman MS. Anti-Markovnikov hydroalkylation of allylic amine derivatives via a palladium-catalyzed reductive cross-coupling reaction. Journal of the American Chemical Society. 133: 11454-7. PMID 21728336 DOI: 10.1021/Ja204080S |
0.838 |
|
| 2011 |
Werner EW, Sigman MS. Operationally simple and highly (E)-styrenyl-selective Heck reactions of electronically nonbiased olefins. Journal of the American Chemical Society. 133: 9692-5. PMID 21627305 DOI: 10.1021/Ja203164P |
0.822 |
|
| 2011 |
Michel BW, Steffens LD, Sigman MS. On the mechanism of the palladium-catalyzed tert-butylhydroperoxide-mediated Wacker-type oxidation of alkenes using quinoline-2-oxazoline ligands. Journal of the American Chemical Society. 133: 8317-25. PMID 21553838 DOI: 10.1021/Ja2017043 |
0.797 |
|
| 2011 |
Pathak TP, Sigman MS. Palladium-catalyzed hydrofunctionalization of vinyl phenol derivatives with heteroaromatics. Organic Letters. 13: 2774-7. PMID 21510631 DOI: 10.1021/Ol200913R |
0.83 |
|
| 2011 |
Liao L, Jana R, Urkalan KB, Sigman MS. A palladium-catalyzed three-component cross-coupling of conjugated dienes or terminal alkenes with vinyl triflates and boronic acids. Journal of the American Chemical Society. 133: 5784-7. PMID 21449562 DOI: 10.1021/Ja201358B |
0.825 |
|
| 2011 |
McCombs JR, Michel BW, Sigman MS. Catalyst-controlled Wacker-type oxidation of homoallylic alcohols in the absence of protecting groups. The Journal of Organic Chemistry. 76: 3609-13. PMID 21446720 DOI: 10.1021/Jo200462A |
0.803 |
|
| 2011 |
Jana R, Pathak TP, Sigman MS. Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partners. Chemical Reviews. 111: 1417-92. PMID 21319862 DOI: 10.1021/Cr100327P |
0.815 |
|
| 2011 |
Harper KC, Sigman MS. Predicting and optimizing asymmetric catalyst performance using the principles of experimental design and steric parameters. Proceedings of the National Academy of Sciences of the United States of America. 108: 2179-83. PMID 21262844 DOI: 10.1073/Pnas.1013331108 |
0.751 |
|
| 2011 |
Michel BW, Sigman MS. Peroxide-Mediated wacker oxidations for Organic Synthesis Aldrichimica Acta. 44: 55-62. |
0.758 |
|
| 2010 |
Jensen KH, Webb JD, Sigman MS. Advancing the mechanistic understanding of an enantioselective palladium-catalyzed alkene difunctionalization reaction. Journal of the American Chemical Society. 132: 17471-82. PMID 21082845 DOI: 10.1021/Ja108106H |
0.471 |
|
| 2010 |
Jensen KH, Sigman MS. Evaluation of catalyst acidity and substrate electronic effects in a hydrogen bond-catalyzed enantioselective reaction. The Journal of Organic Chemistry. 75: 7194-201. PMID 20919686 DOI: 10.1021/Jo1013806 |
0.413 |
|
| 2010 |
Werner EW, Sigman MS. A highly selective and general palladium catalyst for the oxidative Heck reaction of electronically nonbiased olefins. Journal of the American Chemical Society. 132: 13981-3. PMID 20858011 DOI: 10.1021/Ja1060998 |
0.81 |
|
| 2010 |
Michel BW, McCombs JR, Winkler A, Sigman MS. Catalyst-controlled Wacker-type oxidation of protected allylic amines. Angewandte Chemie (International Ed. in English). 49: 7312-5. PMID 20799310 DOI: 10.1002/Anie.201004156 |
0.832 |
|
| 2010 |
Anderson BJ, Keith JA, Sigman MS. Experimental and computational study of a direct O2-coupled Wacker oxidation: water dependence in the absence of Cu salts. Journal of the American Chemical Society. 132: 11872-4. PMID 20687555 DOI: 10.1021/Ja1057218 |
0.366 |
|
| 2010 |
Liao L, Sigman MS. Palladium-catalyzed hydroarylation of 1,3-dienes with boronic esters via reductive formation of pi-allyl palladium intermediates under oxidative conditions. Journal of the American Chemical Society. 132: 10209-11. PMID 20608751 DOI: 10.1021/Ja105010T |
0.696 |
|
| 2010 |
Pathak TP, Gligorich KM, Welm BE, Sigman MS. Synthesis and preliminary biological studies of 3-substituted indoles accessed by a palladium-catalyzed enantioselective alkene difunctionalization reaction. Journal of the American Chemical Society. 132: 7870-1. PMID 20486685 DOI: 10.1021/Ja103472A |
0.835 |
|
| 2010 |
Gustafson JL, Sigman MS, Miller SJ. Linear free-energy relationship analysis of a catalytic desymmetrization reaction of a diarylmethane-bis(phenol). Organic Letters. 12: 2794-7. PMID 20486656 DOI: 10.1021/Ol100927M |
0.35 |
|
| 2010 |
Werner EW, Urkalan KB, Sigman MS. Pd(II)-catalyzed oxidative 1,1-diarylation of terminal olefins. Organic Letters. 12: 2848-51. PMID 20481606 DOI: 10.1021/Ol1009575 |
0.831 |
|
| 2010 |
Sigman M, Werner E. A Selective and General Palladium Catalyst for the Oxidative Heck Reaction Synfacts. 2011: 0079-0079. DOI: 10.1055/s-0030-1259116 |
0.798 |
|
| 2010 |
Sigman M, Liao L. Palladium-Catalyzed Oxidative Hydro-arylation of 1,3-Dienes with Boronic Esters Synfacts. 2010: 1286-1286. DOI: 10.1055/s-0030-1258724 |
0.377 |
|
| 2010 |
Jensen KH, Pathak TP, Zhang Y, Sigman MS. Enantioselective Difunctionalization of Alkenes Catalyzedby Palladium(II) Synfacts. 2010: 320-320. DOI: 10.1055/S-0029-1219318 |
0.344 |
|
| 2010 |
Werner EW, Urkalan KB, Sigman MS. ChemInform Abstract: PdII-Catalyzed Oxidative 1,1-Diarylation of Terminal Olefins. Cheminform. 41: no-no. DOI: 10.1002/chin.201045077 |
0.798 |
|
| 2009 |
Gligorich KM, Iwai Y, Cummings SA, Sigman MS. A new approach to carbon-carbon bond formation: Development of aerobic Pd-catalyzed reductive coupling reactions of organometallic reagents and styrenes. Tetrahedron. 65: 5074-5083. PMID 20161306 DOI: 10.1016/J.Tet.2009.03.096 |
0.513 |
|
| 2009 |
Urkalan KB, Sigman MS. Palladium-catalyzed hydroalkylation of styrenes with organozinc reagents to form carbon-carbon sp3-sp3 bonds under oxidative conditions. Journal of the American Chemical Society. 131: 18042-3. PMID 19929001 DOI: 10.1021/Ja908545B |
0.794 |
|
| 2009 |
Jensen KH, Pathak TP, Zhang Y, Sigman MS. Palladium-catalyzed enantioselective addition of two distinct nucleophiles across alkenes capable of quinone methide formation. Journal of the American Chemical Society. 131: 17074-5. PMID 19902942 DOI: 10.1021/Ja909030C |
0.842 |
|
| 2009 |
Sigman MS, Miller JJ. Examination of the role of Taft-type steric parameters in asymmetric catalysis. The Journal of Organic Chemistry. 74: 7633-43. PMID 19813764 DOI: 10.1021/Jo901698T |
0.467 |
|
| 2009 |
Gligorich KM, Sigman MS. Recent advancements and challenges of palladium(II)-catalyzed oxidation reactions with molecular oxygen as the sole oxidant. Chemical Communications (Cambridge, England). 3854-67. PMID 19662234 DOI: 10.1039/B902868D |
0.492 |
|
| 2009 |
Michel BW, Camelio AM, Cornell CN, Sigman MS. A general and efficient catalyst system for a Wacker-type oxidation using TBHP as the terminal oxidant: application to classically challenging substrates. Journal of the American Chemical Society. 131: 6076-7. PMID 19364100 DOI: 10.1021/Ja901212H |
0.83 |
|
| 2009 |
Urkalan KB, Sigman MS. Palladium-catalyzed oxidative intermolecular difunctionalization of terminal alkenes with organostannanes and molecular oxygen. Angewandte Chemie (International Ed. in English). 48: 3146-9. PMID 19308939 DOI: 10.1002/Anie.200900218 |
0.825 |
|
| 2009 |
Michel BW, Camelio AM, Cornell CN, Sigman MS. Palladium/Quinox-Catalyzed Wacker-Type Oxidationof Terminal Olefins Synfacts. 2009: 872-872. DOI: 10.1055/S-0029-1217416 |
0.392 |
|
| 2009 |
Miller JJ, Rajaram S, Pfaffenroth C, Sigman MS. Synthesis of amine functionalized oxazolines with applications in asymmetric catalysis Tetrahedron. 65: 3110-3119. DOI: 10.1016/J.Tet.2008.11.046 |
0.433 |
|
| 2008 |
Jensen KH, Sigman MS. Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions. Organic & Biomolecular Chemistry. 6: 4083-8. PMID 18972034 DOI: 10.1039/B813246A |
0.483 |
|
| 2008 |
Iwai Y, Gligorich KM, Sigman MS. Aerobic alcohol oxidation coupled to palladium-catalyzed alkene hydroarylation with boronic esters. Angewandte Chemie (International Ed. in English). 47: 3219-22. PMID 18348123 DOI: 10.1002/Anie.200705317 |
0.519 |
|
| 2008 |
Gligorich KM, Cummings SA, Sigman MS. Palladium-Catalyzed Hydroarylation of Styrenes under Aerobic Conditions Synfacts. 2008: 184-184. DOI: 10.1055/S-2007-992474 |
0.392 |
|
| 2007 |
Podhajsky SM, Sigman MS. Coupling Pd-Catalyzed Alcohol Oxidation to Olefin Functionalization: Hydrohalogenation/Hydroalkoxylation of Styrenes. Organometallics. 26: 5680-5686. PMID 19779575 DOI: 10.1021/Om700675Z |
0.431 |
|
| 2007 |
Gligorich KM, Cummings SA, Sigman MS. Palladium-catalyzed reductive coupling of styrenes and organostannanes under aerobic conditions. Journal of the American Chemical Society. 129: 14193-5. PMID 17963397 DOI: 10.1021/Ja076746F |
0.441 |
|
| 2007 |
Jensen KH, Sigman MS. Systematically probing the effect of catalyst acidity in a hydrogen-bond-catalyzed enantioselective reaction. Angewandte Chemie (International Ed. in English). 46: 4748-50. PMID 17503406 DOI: 10.1002/Anie.200700298 |
0.421 |
|
| 2007 |
Cornell CN, Sigman MS. Recent progress in Wacker oxidations: moving toward molecular oxygen as the sole oxidant. Inorganic Chemistry. 46: 1903-9. PMID 17348721 DOI: 10.1021/Ic061858D |
0.669 |
|
| 2007 |
Miller JJ, Sigman MS. Design and synthesis of modular oxazoline ligands for the enantioselective chromium-catalyzed addition of allyl bromide to ketones. Journal of the American Chemical Society. 129: 2752-3. PMID 17309263 DOI: 10.1021/Ja068915M |
0.427 |
|
| 2007 |
Zhang Y, Sigman MS. Palladium(II)-catalyzed enantioselective aerobic dialkoxylation of 2-propenyl phenols: a pronounced effect of copper additives on enantioselectivity. Journal of the American Chemical Society. 129: 3076-7. PMID 17298071 DOI: 10.1021/Ja070263U |
0.42 |
|
| 2007 |
Sigman M, Miller J. Enantioselective Addition of Allyl Bromides to Ketones Synfacts. 2007: 0499-0499. DOI: 10.1055/s-2007-968441 |
0.39 |
|
| 2006 |
Zhang Y, Sigman MS. Development of a general Pd(II)-catalyzed intermolecular hydroalkoxylation reaction of vinylphenols by using a sacrificial alcohol as the hydride source. Organic Letters. 8: 5557-60. PMID 17107071 DOI: 10.1021/Ol062222T |
0.406 |
|
| 2006 |
Dible BR, Sigman MS. Steric effects in the aerobic oxidation of pi-allylnickel(II) complexes with N-heterocyclic carbenes. Inorganic Chemistry. 45: 8430-41. PMID 16999444 DOI: 10.1021/Ic0612451 |
0.799 |
|
| 2006 |
Gligorich KM, Sigman MS. Mechanistic questions about the reaction of molecular oxygen with palladium in oxidase catalysis. Angewandte Chemie (International Ed. in English). 45: 6612-5. PMID 16986187 DOI: 10.1002/Anie.200602138 |
0.404 |
|
| 2006 |
Cornell CN, Sigman MS. Discovery of a practical direct O2-coupled Wacker oxidation with Pd[(-)-sparteine]Cl2. Organic Letters. 8: 4117-20. PMID 16928088 DOI: 10.1021/Ol061662H |
0.687 |
|
| 2006 |
Sigman MS, Jensen DR. Ligand-modulated palladium-catalyzed aerobic alcohol oxidations. Accounts of Chemical Research. 39: 221-9. PMID 16548511 DOI: 10.1021/Ar040243M |
0.459 |
|
| 2006 |
Balija AM, Stowers KJ, Schultz MJ, Sigman MS. Pd(II)-catalyzed conversion of styrene derivatives to acetals: impact of (-)-sparteine on regioselectivity. Organic Letters. 8: 1121-4. PMID 16524283 DOI: 10.1021/Ol053110P |
0.829 |
|
| 2006 |
Gligorich KM, Schultz MJ, Sigman MS. Palladium(II)-catalyzed aerobic hydroalkoxylation of styrenes containing a phenol. Journal of the American Chemical Society. 128: 2794-5. PMID 16506746 DOI: 10.1021/Ja0585533 |
0.649 |
|
| 2006 |
Schultz MJ, Sigman MS. Palladium(II)-catalyzed aerobic dialkoxylation of styrenes: a profound influence of an o-phenol. Journal of the American Chemical Society. 128: 1460-1. PMID 16448111 DOI: 10.1021/Ja0579053 |
0.586 |
|
| 2006 |
Schultz MJ, Sigman MS. Aerobic Dialkoxylation of Styrenes: A Profound Influence of an o-Phenol Synfacts. 2006: 353-353. DOI: 10.1055/S-2006-934343 |
0.501 |
|
| 2006 |
Schultz MJ, Sigman MS. Recent advances in homogeneous transition metal-catalyzed aerobic alcohol oxidations Tetrahedron. 62: 8227-8241. DOI: 10.1016/J.Tet.2006.06.065 |
0.575 |
|
| 2006 |
Gligorich KM, Sigman MS. Zum Mechanismus der Reaktion von molekularem Sauerstoff mit Palladium in der Oxidase-Katalyse Angewandte Chemie. 118: 6764-6767. DOI: 10.1002/Ange.200602138 |
0.335 |
|
| 2006 |
Schultz MJ, Sigman MS. Metal-mediated and -catalyzed Oxidations Using N-Heterocyclic Carbene Ligands N-Heterocyclic Carbenes in Synthesis. 103-118. DOI: 10.1002/9783527609451.ch5 |
0.55 |
|
| 2006 |
Cornell CN, Sigman MS. Molecular Oxygen Binding and Activation: Oxidation Catalysis Activation of Small Molecules: Organometallic and Bioinorganic Perspectives. 159-186. DOI: 10.1002/9783527609352.ch5 |
0.56 |
|
| 2005 |
Rajaram S, Sigman MS. Design of hydrogen bond catalysts based on a modular oxazoline template: application to an enantioselective hetero Diels-Alder reaction. Organic Letters. 7: 5473-5. PMID 16288534 DOI: 10.1021/Ol052300X |
0.405 |
|
| 2005 |
Mueller JA, Cowell A, Chandler BD, Sigman MS. Origin of enantioselection in chiral alcohol oxidation catalyzed by Pd[(-)-sparteine]Cl2. Journal of the American Chemical Society. 127: 14817-24. PMID 16231935 DOI: 10.1021/Ja053195P |
0.624 |
|
| 2005 |
Schultz MJ, Adler RS, Zierkiewicz W, Privalov T, Sigman MS. Using mechanistic and computational studies to explain ligand effects in the palladium-catalyzed aerobic oxidation of alcohols. Journal of the American Chemical Society. 127: 8499-507. PMID 15941285 DOI: 10.1021/Ja050949R |
0.625 |
|
| 2005 |
Dible BR, Sigman MS, Arif AM. Oxygen-induced ligand dehydrogenation of a planar bis-mu-chloronickel(I) dimer featuring an NHC ligand. Inorganic Chemistry. 44: 3774-6. PMID 15907100 DOI: 10.1021/Ic050445U |
0.788 |
|
| 2005 |
Schultz MJ, Hamilton SS, Jensen DR, Sigman MS. Development and comparison of the substrate scope of Pd-catalysts for the aerobic oxidation of alcohols. The Journal of Organic Chemistry. 70: 3343-52. PMID 15844968 DOI: 10.1021/Jo0482211 |
0.648 |
|
| 2005 |
Lee JY, Miller JJ, Hamilton SS, Sigman MS. Stereochemical diversity in chiral ligand design: discovery and optimization of catalysts for the enantioselective addition of allylic halides to aldehydes. Organic Letters. 7: 1837-9. PMID 15844919 DOI: 10.1021/Ol050528E |
0.475 |
|
| 2005 |
Cornell CN, Sigman MS. Discovery of and mechanistic insight into a ligand-modulated palladium-catalyzed wacker oxidation of styrenes using TBHP Journal of the American Chemical Society. 127: 2796-2797. PMID 15740083 DOI: 10.1021/Ja043203M |
0.699 |
|
| 2005 |
Lee J-, Miller JJ, Hamilton SS, Sigman MS. Modular Catalysts for the Enantioselective Allylation of Aldehydes Synfacts. 2005: 65-65. DOI: 10.1055/S-2005-869927 |
0.395 |
|
| 2005 |
Mercer GJ, Sturdy M, Jensen DR, Sigman MS. Intermolecular reductive coupling of hindered N-aryl imines towards the modular synthesis of chiral N-heterocyclic carbenes Tetrahedron. 61: 6418-6424. DOI: 10.1016/J.Tet.2005.03.124 |
0.355 |
|
| 2004 |
Sigman MS, Schultz MJ. The renaissance of palladium(II)-catalyzed oxidation chemistry. Organic & Biomolecular Chemistry. 2: 2551-4. PMID 15351815 DOI: 10.1039/B409127M |
0.628 |
|
| 2004 |
Mueller JA, Goller CP, Sigman MS. Elucidating the significance of β-hydride elimination and the dynamic role of acid/base chemistry in a palladium-catalyzed aerobic oxidation of alcohols Journal of the American Chemical Society. 126: 9724-9734. PMID 15291576 DOI: 10.1021/Ja047794S |
0.64 |
|
| 2004 |
Sigman MS, Schultz MJ. The renaissance of palladium(II)-catalyzed oxidation chemistry Organic and Biomolecular Chemistry. 2: 2551-2554. DOI: 10.1039/b409127m |
0.569 |
|
| 2003 |
Mandal SK, Sigman MS. Palladium-catalyzed aerobic oxidative kinetic resolution of alcohols with an achiral exogenous base Journal of Organic Chemistry. 68: 7535-7537. PMID 12968915 DOI: 10.1021/Jo034717R |
0.396 |
|
| 2003 |
Jensen DR, Schultz MJ, Mueller JA, Sigman MS. A well-defined complex for palladium-catalyzed aerobic oxidation of alcohols: Design, synthesis, and mechanistic considerations Angewandte Chemie - International Edition. 42: 3810-3813. PMID 12923852 DOI: 10.1002/Anie.200351997 |
0.726 |
|
| 2003 |
Mueller JA, Sigman MS. Mechanistic investigations of the palladium-catalyzed aerobic oxidative kinetic resolution of secondary alcohols using (-)-Sparteine Journal of the American Chemical Society. 125: 7005-7013. PMID 12783555 DOI: 10.1021/Ja034262N |
0.637 |
|
| 2003 |
Mandal SK, Jensen DR, Pugsley JS, Sigman MS. Scope of enantioselective Palladium(II)-catalyzed aerobic alcohol oxidations with (-)-sparteine Journal of Organic Chemistry. 68: 4600-4603. PMID 12762783 DOI: 10.1021/Jo0269161 |
0.391 |
|
| 2003 |
Mercer GJ, Sigman MS. Diastereoselective synthesis of piperazines by manganese-mediated reductive cyclization. Organic Letters. 5: 1591-4. PMID 12713331 DOI: 10.1021/Ol034469L |
0.456 |
|
| 2003 |
Dible BR, Sigman MS. Unusual reactivity of molecular oxygen with pi-allylnickel(N-heterocyclic carbene) chloride complexes. Journal of the American Chemical Society. 125: 872-3. PMID 12537477 DOI: 10.1021/Ja0286876 |
0.791 |
|
| 2003 |
Jensen DR, Sigman MS. Palladium catalysts for aerobic oxidative kinetic resolution of secondary alcohols based on mechanistic insight. Organic Letters. 5: 63-5. PMID 12509891 DOI: 10.1021/Ol027190Y |
0.491 |
|
| 2002 |
Schultz MJ, Park CC, Sigman MS. A convenient palladium-catalyzed aerobic oxidation of alcohols at room temperature. Chemical Communications (Cambridge, England). 3034-5. PMID 12536803 DOI: 10.1039/B209344H |
0.622 |
|
| 2002 |
Rajaram S, Sigman MS. Modular synthesis of amine-functionalized oxazolines. Organic Letters. 4: 3399-401. PMID 12323028 DOI: 10.1021/Ol0264758 |
0.395 |
|
| 2002 |
Mueller JA, Jensen DR, Sigman MS. Dual role of (-)-sparteine in the palladium-catalyzed aerobic oxidative kinetic resolution of secondary alcohols. Journal of the American Chemical Society. 124: 8202-3. PMID 12105896 DOI: 10.1021/Ja026553M |
0.629 |
|
| 2001 |
Jensen DR, Pugsley JS, Sigman MS. Palladium-catalyzed enantioselective oxidations of alcohols using molecular oxygen. Journal of the American Chemical Society. 123: 7475-6. PMID 11472200 DOI: 10.1021/Ja015827N |
0.377 |
|
| 2000 |
Sigman MS, Vachal P, Jacobsen EN. A General Catalyst for the Asymmetric Strecker Reaction This work was supported by the NIH (GM-43214). A postdoctoral fellowship to M.S.S. (NIH), and a predoctoral fellowship to P.V. sponsored by Alfred Bader are gratefully acknowledged. Angewandte Chemie (International Ed. in English). 39: 1279-1281. PMID 10767031 DOI: 10.1002/(Sici)1521-3773(20000403)39:7<1279::Aid-Anie1279>3.0.Co;2-U |
0.764 |
|
| 1998 |
Sigman MS, Fatland AW, Eaton BE. Cobalt-catalyzed cyclotrimerization of alkynes in aqueous solution [10] Journal of the American Chemical Society. 120: 5130-5131. DOI: 10.1021/Ja9807284 |
0.783 |
|
| 1998 |
Sigman MS, Jacobsen EN. Enantioselective addition of hydrogen cyanide to imines catalyzed by a chiral (salen)Al(III) complex [1] Journal of the American Chemical Society. 120: 5315-5316. DOI: 10.1021/Ja980299+ |
0.545 |
|
| 1998 |
Sigman MS, Jacobsen EN. Schiff base catalysts for the asymmetric strecker reaction identified and optimized from parallel synthetic libraries Journal of the American Chemical Society. 120: 4901-4902. DOI: 10.1021/Ja980139Y |
0.586 |
|
| 1996 |
Sigman MS, Eaton BE, Heise JD, Kubiak CP. Low-temperature study of the iron-mediated [4 + 1] cyclization of allenyl ketones with carbon monoxide Organometallics. 15: 2829-2832. DOI: 10.1021/Om9601716 |
0.616 |
|
| 1996 |
Sigman MS, Eaton BE. Catalytic iron-mediated [4 + 1] cycloaddition of diallenes with carbon monoxide Journal of the American Chemical Society. 118: 11783-11788. DOI: 10.1021/Ja962908O |
0.671 |
|
| 1995 |
Netzel TL, Zhao M, Nafisi K, Headrick J, Sigman MS, Eaton BE. Photophysics of 2′-deoxyuridine (dU) nucleosides covalently substituted with either 1-pyrenyl or 1-pyrenoyl: Observation of pyrene-to-nucleoside charge-transfer emission in 5-(1-pyrenyl)-dU Journal of the American Chemical Society. 117: 9119-9128. DOI: 10.1021/Ja00141A002 |
0.591 |
|
| 1994 |
Sigman MS, Eaton BE. The first iron-mediated catalytic carbon-nitrogen bond formation: [4 + 1] Cycloaddition of allenyl imines and carbon monoxide Journal of Organic Chemistry. 59: 7488-7491. DOI: 10.1021/Jo00103A050 |
0.627 |
|
| 1993 |
Sigman MS, Kerr CE, Eaton BE. Catalytic iron-mediated carbon-oxygen and carbon-carbon bond formation in [4 + 1] assembly of alkylidenebutenolides Journal of the American Chemical Society. 115: 7545-7546. DOI: 10.1021/Ja00069A081 |
0.614 |
|
| 1993 |
Sigman MS, Eaton BE. Addition of primary amines to conjugated allenyl aldehydes and ketones Tetrahedron Letters. 34: 5367-5368. DOI: 10.1016/S0040-4039(00)73910-4 |
0.682 |
|
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