Polly L. Arnold - Publications

Affiliations: 
Chemistry University of Edinburgh, Edinburgh, Scotland, United Kingdom 
Area:
Inorganic chemistry
Website:
http://www.chem.ed.ac.uk/staff/academic/arnold.html

151 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Kynman AE, Christodoulou S, Ouellette ET, Peterson A, Kelly SN, Maron L, Arnold P. Photocatalytic dechlorination of unactivated chlorocarbons including PVC using organolanthanide complexes. Chemical Communications (Cambridge, England). PMID 37614167 DOI: 10.1039/d3cc02906a  0.381
2023 Price AN, Gupta AK, de Jong WA, Arnold PL. Tris(carbene)borates; alternatives to cyclopentadienyls in organolanthanide chemistry. Dalton Transactions (Cambridge, England : 2003). 52: 5433-5437. PMID 37070223 DOI: 10.1039/d3dt00718a  0.412
2022 Kynman AE, Elghanayan LK, Desnoyer AN, Yang Y, Sévery L, Di Giuseppe A, Tilley TD, Maron L, Arnold PL. Controlled monodefluorination and alkylation of C(sp)-F bonds by lanthanide photocatalysts: importance of metal-ligand cooperativity. Chemical Science. 13: 14090-14100. PMID 36540817 DOI: 10.1039/d2sc04192h  0.32
2022 Shephard JJ, Berryman VEJ, Ochiai T, Walter O, Price AN, Warren MR, Arnold PL, Kaltsoyannis N, Parsons S. Covalent bond shortening and distortion induced by pressurization of thorium, uranium, and neptunium tetrakis aryloxides. Nature Communications. 13: 5923. PMID 36207297 DOI: 10.1038/s41467-022-33459-7  0.326
2022 Lam FYT, Wells JAL, Ochiai T, Halliday CJV, McCabe KN, Maron L, Arnold PL. A Combined Experimental and Theoretical Investigation of Arene-Supported Actinide and Ytterbium Tetraphenolate Complexes. Inorganic Chemistry. 61: 4581-4591. PMID 35244386 DOI: 10.1021/acs.inorgchem.1c03365  0.432
2021 DeJesus JF, Kerr RWF, Penchoff DA, Carroll XB, Peterson CC, Arnold PL, Jenkins DM. Actinide tetra-N-heterocyclic carbene 'sandwiches'. Chemical Science. 12: 7882-7887. PMID 34168841 DOI: 10.1039/d1sc01007g  0.372
2021 Arnold PL, Halliday CJV, Puig-Urrea L, Nichol GS. Instantaneous and Phosphine-Catalyzed Arene Binding and Reduction by U(III) Complexes. Inorganic Chemistry. 60: 4162-4170. PMID 33662207 DOI: 10.1021/acs.inorgchem.1c00327  0.444
2020 Cowie BE, Douair I, Maron L, Love JB, Arnold PL. Selective oxo ligand functionalisation and substitution reactivity in an oxo/catecholate-bridged U/U Pacman complex. Chemical Science. 11: 7144-7157. PMID 33033607 DOI: 10.1039/D0Sc02297G  0.528
2020 Beach SA, Guillet JL, Lagueux SP, Perfetti M, Livesay BN, Shores MP, Bacon JW, Rheingold AL, Arnold PL, Doerrer LH. Heterotrimetallic {LnOVPt} complexes with antiferromagnetic Ln-V coupling and magnetic memory. Chemical Communications (Cambridge, England). PMID 32812571 DOI: 10.1039/D0Cc04334F  0.378
2020 Berryman VEJ, Shephard JJ, Ochiai T, Price AN, Arnold PL, Parsons S, Kaltsoyannis N. Quantum chemical topology and natural bond orbital analysis of M-O covalency in M(OCH) (M = Ti, Zr, Hf, Ce, Th, Pa, U, Np). Physical Chemistry Chemical Physics : Pccp. PMID 32662500 DOI: 10.1039/D0Cp02947E  0.356
2020 Arnold PL, Ochiai T, Lam FYT, Kelly RP, Seymour ML, Maron L. Metallacyclic actinide catalysts for dinitrogen conversion to ammonia and secondary amines. Nature Chemistry. PMID 32366961 DOI: 10.1038/S41557-020-0457-9  0.376
2019 Zegke M, Zhang X, Pidchenko I, Hlina JA, Lord RM, Purkis J, Nichol GS, Magnani N, Schreckenbach G, Vitova T, Love JB, Arnold PL. Differential uranyl(v) oxo-group bonding between the uranium and metal cations from groups 1, 2, 4, and 12; a high energy resolution X-ray absorption, computational, and synthetic study. Chemical Science. 10: 9740-9751. PMID 32055343 DOI: 10.1039/C8Sc05717F  0.765
2019 Arnold PL, Wang K, Gray SJ, Moreau LM, Booth CH, Curcio M, Wells JAL, Slawin AMZ. Dicerium letterbox-shaped tetraphenolates: f-block complexes designed for two-electron chemistry. Dalton Transactions (Cambridge, England : 2003). PMID 31859325 DOI: 10.1039/C9Dt03291F  0.487
2019 Cowie BE, Purkis JM, Austin J, Love JB, Arnold PL. Thermal and Photochemical Reduction and Functionalization Chemistry of the Uranyl Dication, [UO]. Chemical Reviews. PMID 31403292 DOI: 10.1021/Acs.Chemrev.9B00048  0.361
2019 Maron L, Castro L, So YM, Cho CW, Lotz R, Wong KH, Wang K, Arnold PL, Au-Yeung KC, Sung HH, Williams ID, Leung WH. A Combined Experimental and Theoretical Study of the Versatile Reactivity of an Oxocerium(IV) Complex: Concerted vs. Reductive Addition. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31287592 DOI: 10.1002/Chem.201903035  0.412
2019 Raman SK, Raja R, Arnold PL, Davidson MG, Williams CK. Waste not, want not: CO (re)cycling into block polymers. Chemical Communications (Cambridge, England). PMID 31172996 DOI: 10.1039/C9Cc02459J  0.303
2019 Arnold PL, Puig-Urrea L, Wells JAL, Yuan D, Cruickshank FL, Young RD. Applications of boroxide ligands in supporting small molecule activation by U(iii) and U(iv) complexes. Dalton Transactions (Cambridge, England : 2003). PMID 30924481 DOI: 10.1039/C8Dt05051A  0.734
2019 Berryman VEJ, Whalley ZJ, Shephard JJ, Ochiai T, Price AN, Arnold PL, Parsons S, Kaltsoyannis N. Computational analysis of M-O covalency in M(OCH) (M = Ti, Zr, Hf, Ce, Th, U). Dalton Transactions (Cambridge, England : 2003). PMID 30720806 DOI: 10.1039/C8Dt05094E  0.32
2019 Arnold PL, Purkis JM, Rutkauskaite R, Kovacs D, Love JB, Austin J. Controlled Photocatalytic Hydrocarbon Oxidation by Uranyl Complexes Chemcatchem. 11: 3786-3790. DOI: 10.1002/Cctc.201900037  0.372
2018 Arnold PL, Kerr RWF, Weetman C, Docherty SR, Rieb J, Cruickshank FL, Wang K, Jandl C, McMullon MW, Pöthig A, Kühn FE, Smith AD. Selective and catalytic carbon dioxide and heteroallene activation mediated by cerium N-heterocyclic carbene complexes. Chemical Science. 9: 8035-8045. PMID 30568765 DOI: 10.1039/C8Sc03312A  0.534
2018 Arnold PL, Green JC, Green MLH, Kilpatrick AFR, Layfield RA, Love JB, O'Hare D, Turner JFC. Geoff Cloke at 65: a pioneer in organometallic chemistry. Dalton Transactions (Cambridge, England : 2003). PMID 30003206 DOI: 10.1039/C8Dt90115E  0.415
2018 Cowie BE, Nichol GS, Love JB, Arnold PL. Double uranium oxo cations derived from uranyl by borane or silane reduction. Chemical Communications (Cambridge, England). PMID 29589007 DOI: 10.1039/C8Cc00341F  0.393
2018 Bell NL, Shaw B, Arnold PL, Love JB. Uranyl to Uranium(IV) Conversion through Manipulation of Axial and Equatorial Ligands. Journal of the American Chemical Society. PMID 29455528 DOI: 10.1021/Jacs.7B13474  0.473
2018 Weetman C, Notman S, Arnold PL. Destruction of chemical warfare agent simulants by air and moisture stable metal NHC complexes. Dalton Transactions (Cambridge, England : 2003). PMID 29384545 DOI: 10.1039/C7Dt04805J  0.396
2017 Arnold PL, Stevens CJ, Bell NL, Lord RM, Goldberg JM, Nichol GS, Love JB. Multi-electron reduction of sulfur and carbon disulfide using binuclear uranium(iii) borohydride complexes. Chemical Science. 8: 3609-3617. PMID 30155206 DOI: 10.1039/C7Sc00382J  0.784
2017 Pankhurst JR, Bell NL, Zegke M, Platts LN, Lamsfus CA, Maron L, Natrajan LS, Sproules S, Arnold PL, Love JB. Correction: Inner-sphere outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin. Chemical Science. 8: 806. PMID 30123470 DOI: 10.1039/c6sc90072k  0.56
2017 Arnold PL, Dutkiewicz MS, Walter O. Organometallic Neptunium Chemistry. Chemical Reviews. PMID 28853564 DOI: 10.1021/Acs.Chemrev.7B00192  0.407
2017 Sinclair F, Hlina JA, Wells JAL, Shaver MP, Arnold PL. Ring opening polymerisation of lactide with uranium(iv) and cerium(iv) phosphinoaryloxide complexes. Dalton Transactions (Cambridge, England : 2003). PMID 28765851 DOI: 10.1039/C7Dt02167D  0.504
2017 Arnold PL, Cowie B, Suvova M, Zegke M, Magnani N, Colineau E, Griveau JC, Caciuffo R, Love J. Axially Symmetric U-O-Ln and U-O-U containing molecules from the control of uranyl reduction with simple f-block halides. Angewandte Chemie (International Ed. in English). PMID 28686336 DOI: 10.1002/Anie.201705197  0.371
2017 Dutkiewicz MS, Apostolidis C, Walter O, Arnold PL. Reduction chemistry of neptunium cyclopentadienide complexes: from structure to understanding. Chemical Science. 8: 2553-2561. PMID 28553487 DOI: 10.1039/C7Sc00034K  0.367
2017 Pankhurst JR, Bell NL, Zegke M, Platts LN, Lamfsus CA, Maron L, Natrajan LS, Sproules S, Arnold PL, Love JB. Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin. Chemical Science. 8: 108-116. PMID 28451154 DOI: 10.1039/C6Sc02912D  0.723
2017 Hlina JA, Wells JA, Pankhurst JR, Love JB, Arnold PL. Uranium rhodium bonding in heterometallic complexes. Dalton Transactions (Cambridge, England : 2003). PMID 28154865 DOI: 10.1039/C6Dt04570G  0.455
2017 Arnold PL, Turner ZR. Carbon oxygenate transformations by actinide compounds and catalysts Nature Reviews Chemistry. 1. DOI: 10.1038/s41570-016-0002  0.531
2017 Suvova M, O’Brien KTP, Farnaby JH, Love JB, Kaltsoyannis N, Arnold PL. Thorium(IV) and Uranium(IV) trans-Calix[2]benzene[2]pyrrolide Alkyl and Alkynyl Complexes: Synthesis, Reactivity, and Electronic Structure Organometallics. 36: 4669-4681. DOI: 10.1021/Acs.Organomet.7B00633  0.542
2017 Kerr RW, Greenhalgh MD, Slawin AM, Arnold PL, Smith AD. Enantioselective N-heterocyclic carbene catalyzed formal [3+2] cycloaddition using α-aroyloxyaldehydes and oxaziridines Tetrahedron: Asymmetry. 28: 125-134. DOI: 10.1016/J.Tetasy.2016.10.012  0.333
2016 Wells JA, Seymour ML, Suvova M, Arnold PL. Dinuclear uranium complexation and manipulation using robust tetraaryloxides. Dalton Transactions (Cambridge, England : 2003). 45: 16026-16032. PMID 27727351 DOI: 10.1039/C6Dt02630C  0.423
2016 Arnold PL, Dutkiewicz MS, Zegke M, Walter O, Apostolidis C, Hollis E, Pécharman AF, Magnani N, Griveau JC, Colineau E, Caciuffo R, Zhang X, Schreckenbach G, Love JB. Subtle Interactions and Electron Transfer between U(III) , Np(III) , or Pu(III) and Uranyl Mediated by the Oxo Group. Angewandte Chemie (International Ed. in English). PMID 27628291 DOI: 10.1002/Anie.201607022  0.369
2016 Dutkiewicz MS, Farnaby JH, Apostolidis C, Colineau E, Walter O, Magnani N, Gardiner MG, Love JB, Kaltsoyannis N, Caciuffo R, Arnold PL. Organometallic neptunium(III) complexes. Nature Chemistry. 8: 797-802. PMID 27442286 DOI: 10.1038/Nchem.2520  0.398
2016 Zheng XJ, Bell NL, Stevens CJ, Zhong YX, Schreckenbach G, Arnold PL, Love JB, Pan QJ. Relativistic DFT and experimental studies of mono- and bis-actinyl complexes of an expanded Schiff-base polypyrrole macrocycle. Dalton Transactions (Cambridge, England : 2003). PMID 27373562 DOI: 10.1039/C6Dt01625A  0.469
2016 Bell NL, Arnold PL, Love JB. Controlling uranyl oxo group interactions to group 14 elements using polypyrrolic Schiff-base macrocyclic ligands. Dalton Transactions (Cambridge, England : 2003). PMID 27356021 DOI: 10.1039/C6Dt01948J  0.524
2016 So YM, Li Y, Au-Yeung KC, Wang GC, Wong KL, Sung HH, Arnold PL, Williams ID, Lin Z, Leung WH. Probing the Reactivity of the Ce═O Multiple Bond in a Cerium(IV) Oxo Complex. Inorganic Chemistry. PMID 27196506 DOI: 10.1021/Acs.Inorgchem.6B00480  0.467
2016 Hlina JA, Pankhurst JR, Kaltsoyannis N, Arnold PL. Metal-Metal Bonding in Uranium-Group 10 Complexes. Journal of the American Chemical Society. PMID 26942560 DOI: 10.1021/Jacs.5B10698  0.404
2016 Prescimone A, Parsons S, Arnold PL. Pressure-induced C-H agostic interactions in a uranium complex Acta Crystallographica Section a Foundations and Advances. 72: s235-s235. DOI: 10.1107/S2053273316096431  0.325
2016 Mansell SM, Arnold PL. Coordination of isocyanide and reduction of cyclooctatetraene by a homoleptic uranium(III) aryloxide, and characterisation of the heteroleptic uranium(III) dimer [(U(N″)2(thf)(μ-I))2] Polyhedron. DOI: 10.1016/J.Poly.2016.03.048  0.471
2015 Stevens CJ, Prescimone A, Tuna F, McInnes EJ, Parsons S, Morrison CA, Arnold PL, Love JB. Inter- versus Intramolecular Structural Manipulation of a Dichromium(II) Pacman Complex through Pressure Variation. Inorganic Chemistry. PMID 26683991 DOI: 10.1021/Acs.Inorgchem.5B02151  0.352
2015 Bell NL, Maron L, Arnold PL. Thorium Mono- and Bis(imido) Complexes Made by Reprotonation of cyclo-Metalated Amides. Journal of the American Chemical Society. PMID 26244991 DOI: 10.1021/Jacs.5B06630  0.448
2015 Arnold PL, Prescimone A, Farnaby JH, Mansell SM, Parsons S, Kaltsoyannis N. Characterizing pressure-induced uranium ch agostic bonds. Angewandte Chemie (International Ed. in English). 54: 6735-9. PMID 25882329 DOI: 10.1002/Anie.201411250  0.415
2015 Arnold PL, Pécharman AF, Lord RM, Jones GM, Hollis E, Nichol GS, Maron L, Fang J, Davin T, Love JB. Control of oxo-group functionalization and reduction of the uranyl ion. Inorganic Chemistry. 54: 3702-10. PMID 25799215 DOI: 10.1021/Acs.Inorgchem.5B00420  0.771
2015 Zegke M, Nichol GS, Arnold PL, Love JB. Catalytic one-electron reduction of uranyl(VI) to Group 1 uranyl(V) complexes via Al(III) coordination. Chemical Communications (Cambridge, England). 51: 5876-9. PMID 25727815 DOI: 10.1039/C5Cc00867K  0.502
2015 Arnold PL, McMullon MW, Rieb J, Kühn FE. C-H bond activation by f-block complexes. Angewandte Chemie (International Ed. in English). 54: 82-100. PMID 25384554 DOI: 10.1002/Anie.201404613  0.45
2015 Cadenbach T, Pankhurst JR, Hofmann TA, Curcio M, Arnold PL, Love JB. Macrocyclic Platforms for the Construction of Tetranuclear Oxo and Hydroxo Zinc Clusters Organometallics. 34: 2608-2613. DOI: 10.1021/Om501244N  0.478
2015 Arnold PL, Farnaby JH, Gardiner MG, Love JB. Uranium(III) Coordination Chemistry and Oxidation in a Flexible Small-Cavity Macrocycle Organometallics. 34: 2114-2117. DOI: 10.1021/Om5012193  0.486
2015 Batrice RJ, McKinven J, Arnold PL, Eisen MS. Selective Oligomerization and [2 + 2 + 2] Cycloaddition of Terminal Alkynes from Simple Actinide Precatalysts Organometallics. 34: 4039-4050. DOI: 10.1021/Acs.Organomet.5B00455  0.459
2014 McKinven J, Nichol GS, Arnold PL. Arene-ligated heteroleptic terphenolate complexes of thorium. Dalton Transactions (Cambridge, England : 2003). 43: 17416-21. PMID 25338260 DOI: 10.1039/C4Dt02995J  0.488
2014 Arnold PL, Bell NL, Marr IH, She S, Hamilton J, Fraser C, Wang K. Protonolysis and thermolysis reactions of functionalised NHC-carbene boranes and borates. Dalton Transactions (Cambridge, England : 2003). 43: 15419-28. PMID 25188908 DOI: 10.1039/C4Dt01464B  0.728
2014 Arnold PL, Stevens CJ, Farnaby JH, Gardiner MG, Nichol GS, Love JB. New chemistry from an old reagent: mono- and dinuclear macrocyclic uranium(III) complexes from [U(BH4)3(THF)2]. Journal of the American Chemical Society. 136: 10218-21. PMID 25003979 DOI: 10.1021/Ja504835A  0.495
2014 Arnold PL, Cadenbach T, Marr IH, Fyfe AA, Bell NL, Bellabarba R, Tooze RP, Love JB. Homo- and heteroleptic alkoxycarbene f-element complexes and their reactivity towards acidic N-H and C-H bonds. Dalton Transactions (Cambridge, England : 2003). 43: 14346-58. PMID 24920060 DOI: 10.1039/C4Dt01442A  0.48
2014 Arnold PL, Marr IA, Zlatogorsky S, Bellabarba R, Tooze RP. Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex. Dalton Transactions (Cambridge, England : 2003). 43: 34-7. PMID 24162511 DOI: 10.1039/C3Dt52762J  0.413
2014 Arnold PL, Farnaby JH, White RC, Kaltsoyannis N, Gardiner MG, Love JB. Switchable π-coordination and C-H metallation in small-cavity macrocyclic uranium and thorium complexes Chemical Science. 5: 756-765. DOI: 10.1039/C3Sc52072B  0.451
2013 Stevens CJ, Nichol GS, Arnold PL, Love JB. Isocyanide and Phosphine Oxide Coordination in Binuclear Chromium Pacman Complexes. Organometallics. 32: 6879-6882. PMID 24489428 DOI: 10.1021/Om4009313  0.408
2013 Arnold PL. Inorganic chemistry: A reducing role for boron. Nature. 502: 458-9. PMID 24153296 DOI: 10.1038/502458A  0.326
2013 Jones GM, Arnold PL, Love JB. Oxo-group-14-element bond formation in binuclear uranium(V) Pacman complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 10287-94. PMID 23794441 DOI: 10.1002/Chem.201301067  0.541
2013 Mansell SM, Bonnet F, Visseaux M, Arnold PL. Uranium(IV) amido-borohydrides as highly active diene polymerisation catalysts. Dalton Transactions (Cambridge, England : 2003). 42: 9033-9. PMID 23571673 DOI: 10.1039/C3Dt50131K  0.349
2013 Arnold PL, Hollis E, Nichol GS, Love JB, Griveau JC, Caciuffo R, Magnani N, Maron L, Castro L, Yahia A, Odoh SO, Schreckenbach G. Oxo-functionalization and reduction of the uranyl ion through lanthanide-element bond homolysis: synthetic, structural, and bonding analysis of a series of singly reduced uranyl-rare earth 5f1-4f(n) complexes. Journal of the American Chemical Society. 135: 3841-54. PMID 23451865 DOI: 10.1021/Ja308993G  0.517
2013 Bonnet F, Jones CE, Semlali S, Bria M, Roussel P, Visseaux M, Arnold PL. Tuning the catalytic properties of rare earth borohydrides for the polymerisation of isoprene. Dalton Transactions (Cambridge, England : 2003). 42: 790-801. PMID 23202137 DOI: 10.1039/C2Dt31624B  0.459
2013 Arnold PL, Turner ZR, Germeroth AI, Casely IJ, Nichol GS, Bellabarba R, Tooze RP. Carbon monoxide and carbon dioxide insertion chemistry of f-block N-heterocyclic carbene complexes. Dalton Transactions (Cambridge, England : 2003). 42: 1333-7. PMID 23188410 DOI: 10.1039/C2Dt31698F  0.696
2013 Mansell SM, Farnaby JH, Germeroth AI, Arnold PL. Thermally stable uranium dinitrogen complex with siloxide supporting ligands Organometallics. 32: 4214-4222. DOI: 10.1021/Om4003957  0.458
2012 Jones GM, Arnold PL, Love JB. Controlled deprotection and reorganization of uranyl oxo groups in a binuclear macrocyclic environment. Angewandte Chemie (International Ed. in English). 51: 12584-7. PMID 23132703 DOI: 10.1002/Anie.201207609  0.399
2012 Arnold PL, Mansell SM, Maron L, McKay D. Spontaneous reduction and C-H borylation of arenes mediated by uranium(III) disproportionation. Nature Chemistry. 4: 668-74. PMID 22824900 DOI: 10.1038/Nchem.1392  0.461
2012 Pan QJ, Odoh SO, Schreckenbach G, Arnold PL, Love JB. Theoretical exploration of uranyl complexes of a designed polypyrrolic macrocycle: structure/property effects of hinge size on Pacman-shaped complexes. Dalton Transactions (Cambridge, England : 2003). 41: 8878-85. PMID 22714056 DOI: 10.1039/C2Dt31055D  0.471
2012 Arnold PL, Jones GM, Pan QJ, Schreckenbach G, Love JB. Co-linear, double-uranyl coordination by an expanded Schiff-base polypyrrole macrocycle. Dalton Transactions (Cambridge, England : 2003). 41: 6595-7. PMID 22543562 DOI: 10.1039/C2Dt30658A  0.386
2012 Arnold PL, Jones GM, Odoh SO, Schreckenbach G, Magnani N, Love JB. Strongly coupled binuclear uranium-oxo complexes from uranyl oxo rearrangement and reductive silylation. Nature Chemistry. 4: 221-7. PMID 22354437 DOI: 10.1038/Nchem.1270  0.407
2011 Arnold PL, Pécharman AF, Love JB. Oxo group protonation and silylation of pentavalent uranyl Pacman complexes. Angewandte Chemie (International Ed. in English). 50: 9456-8. PMID 21948445 DOI: 10.1002/Anie.201104359  0.411
2011 Arnold PL, Turner ZR, Bellabarba R, Tooze RP. Carbon-silicon and carbon-carbon bond formation by elimination reactions at metal N-heterocyclic carbene complexes. Journal of the American Chemical Society. 133: 11744-56. PMID 21657266 DOI: 10.1021/Ja204209T  0.699
2011 Arnold PL. Uranium-mediated activation of small molecules. Chemical Communications (Cambridge, England). 47: 9005-10. PMID 21614341 DOI: 10.1039/C1Cc10834D  0.324
2011 Mansell SM, Kaltsoyannis N, Arnold PL. Small molecule activation by uranium tris(aryloxides): experimental and computational studies of binding of N2, coupling of CO, and deoxygenation insertion of CO2 under ambient conditions. Journal of the American Chemical Society. 133: 9036-51. PMID 21591662 DOI: 10.1021/Ja2019492  0.482
2011 Pan QJ, Schreckenbach G, Arnold PL, Love JB. Theoretical predictions of cofacial bis(actinyl) complexes of a stretched Schiff-base calixpyrrole ligand. Chemical Communications (Cambridge, England). 47: 5720-2. PMID 21487592 DOI: 10.1039/C1Cc10979K  0.478
2011 Arnold PL, Turner ZR, Bellabarba RM, Tooze RP. Carbon monoxide coupling and functionalisation at a simple uranium coordination complex Chemical Science. 2: 77-79. DOI: 10.1039/C0Sc00452A  0.68
2010 Arnold PL, Pécharman AF, Hollis E, Yahia A, Maron L, Parsons S, Love JB. Uranyl oxo activation and functionalization by metal cation coordination. Nature Chemistry. 2: 1056-61. PMID 21107370 DOI: 10.1038/Nchem.904  0.383
2010 Arnold PL, Turner ZR, Kaltsoyannis N, Pelekanaki P, Bellabarba RM, Tooze RP. Covalency in Ce(IV) and U(IV) halide and N-heterocyclic carbene bonds. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 9623-9. PMID 20658507 DOI: 10.1002/Chem.201001471  0.706
2010 Arnold PL, Turner ZR, Germeroth AI, Casely IJ, Bellabarba R, Tooze RP. Lanthanide/actinide differentiation with sterically encumbered N-heterocyclic carbene ligands. Dalton Transactions (Cambridge, England : 2003). 39: 6808-14. PMID 20526485 DOI: 10.1039/C001584A  0.686
2010 Arnold PL, Potter NA, Magnani N, Apostolidis C, Griveau JC, Colineau E, Morgenstern A, Caciuffo R, Love JB. Synthesis of bimetallic uranium and neptunium complexes of a binucleating macrocycle and determination of the solid-state structure by magnetic analysis. Inorganic Chemistry. 49: 5341-3. PMID 20503974 DOI: 10.1021/Ic100374J  0.384
2010 Arnold PL, Patel D, Pécharman AF, Wilson C, Love JB. Equatorial ligand substitution by hydroxide in uranyl Pacman complexes of a Schiff-base pyrrole macrocycle. Dalton Transactions (Cambridge, England : 2003). 39: 3501-8. PMID 20333339 DOI: 10.1039/B922115H  0.425
2010 Yahia A, Arnold PL, Love JB, Maron L. The effect of the equatorial environment on oxo-group silylation of the uranyl dication: a computational study. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 4881-8. PMID 20301143 DOI: 10.1002/Chem.200902991  0.403
2010 Turner ZR, Bellabarba R, Tooze RP, Arnold PL. Addition-elimination reactions across the M-C bond of metal N-heterocyclic carbenes. Journal of the American Chemical Society. 132: 4050-1. PMID 20201572 DOI: 10.1021/Ja910673Q  0.676
2010 Arnold PL, Potter NA, Carmichael CD, Slawin AM, Roussel P, Love JB. Constructing cerium supramolecular wheels and encapsulating uranium with a Schiff-base calixpyrrole ligand. Chemical Communications (Cambridge, England). 46: 1833-5. PMID 20198224 DOI: 10.1039/B921132B  0.434
2010 Fox AR, Arnold PL, Cummins CC. Uranium-nitrogen multiple bonding: isostructural anionic, neutral, and cationic uranium nitride complexes featuring a linear U=N=U core. Journal of the American Chemical Society. 132: 3250-1. PMID 20178384 DOI: 10.1021/Ja910364U  0.79
2010 Buffet JC, Okuda J, Arnold PL. Chiral indium alkoxide complexes as initiators for the stereoselective ring-opening polymerization of rac-lactide. Inorganic Chemistry. 49: 419-26. PMID 20000658 DOI: 10.1021/Ic900740N  0.773
2010 Mansell SM, Perandones BF, Arnold PL. New UIII and UIV silylamides and an improved synthesis of NaN(SiMe2R)2 (R = Me, Ph) Journal of Organometallic Chemistry. 695: 2814-2821. DOI: 10.1016/J.Jorganchem.2010.08.019  0.365
2009 Arnold PL. Organometallic actinides: Now U=C it. Nature Chemistry. 1: 29-30. PMID 21378797 DOI: 10.1038/Nchem.153  0.429
2009 Arnold PL, Casely IJ, Turner ZR, Bellabarba R, Tooze RB. Magnesium and zinc complexes of functionalised, saturated N-heterocyclic carbene ligands: carbene lability and functionalisation, and lactide polymerisation catalysis. Dalton Transactions (Cambridge, England : 2003). 7236-47. PMID 20449168 DOI: 10.1039/B907034F  0.715
2009 Arnold PL, Sanford MS, Pearson SM. Chelating N-heterocyclic carbene alkoxide as a supporting ligand for Pd(II/IV) C-H bond functionalization catalysis. Journal of the American Chemical Society. 131: 13912-3. PMID 19788324 DOI: 10.1021/Ja905713T  0.328
2009 Arnold PL, Buffet JC, Blaudeck R, Sujecki S, Wilson C. Ligand recognition processes in the formation of homochiral C3-symmetric LnL3 complexes of a chiral alkoxide. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 8241-50. PMID 19609985 DOI: 10.1002/Chem.200900522  0.712
2009 Yahia A, Arnold PL, Love JB, Maron L. A DFT study of the single electron reduction and silylation of the U-O bond of the uranyl dication in a macrocyclic environment. Chemical Communications (Cambridge, England). 2402-4. PMID 19377700 DOI: 10.1039/B900571D  0.404
2009 Arnold PL, Casely IJ. F-block N-heterocyclic carbene complexes. Chemical Reviews. 109: 3599-611. PMID 19358527 DOI: 10.1021/Cr8005203  0.413
2009 Arnold PL, McMaster J, Liddle ST. An unsupported transition metal--lanthanide bond; synthesis and crystal structure of an Nd--Fe amido N-heterocyclic carbene complex. Chemical Communications (Cambridge, England). 818-20. PMID 19322452 DOI: 10.1039/B819072K  0.483
2009 Arnold PL, Love JB, Patel D. Pentavalent uranyl complexes Coordination Chemistry Reviews. 253: 1973-1978. DOI: 10.1016/J.Ccr.2009.03.014  0.443
2009 Arnold PL, Casely IJ, Zlatogorsky S, Wilson C. Organometallic cerium complexes from tetravalent coordination complexes Helvetica Chimica Acta. 92: 2291-2303. DOI: 10.1002/Hlca.200900152  0.507
2008 Berard JJ, Schreckenbach G, Arnold PL, Patel D, Love JB. Computational density functional study of polypyrrolic macrocycles: analysis of actinyl-oxo to 3d transition metal bonding. Inorganic Chemistry. 47: 11583-92. PMID 19006299 DOI: 10.1021/Ic8010772  0.355
2008 Arnold PL, Casely IJ, Turner ZR, Carmichael CD. Functionalised saturated-backbone carbene ligands: yttrium and uranyl alkoxy-carbene complexes and bicyclic carbene-alcohol adducts. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 10415-22. PMID 18830988 DOI: 10.1002/Chem.200801321  0.706
2008 Arnold PL, Zlatogorsky S, Jones NA, Carmichael CD, Liddle ST, Blake AJ, Wilson C. Comparisons between yttrium and titanium N-heterocyclic carbene complexes in the search for early transition metal NHC backbonding interactions. Inorganic Chemistry. 47: 9042-9. PMID 18767795 DOI: 10.1021/Ic801046U  0.478
2008 Arnold PL, Buffet JC, Blaudeck RP, Sujecki S, Blake AJ, Wilson C. C3-symmetric lanthanide tris(alkoxide) complexes formed by preferential complexation and their stereoselective polymerization of rac-lactide. Angewandte Chemie (International Ed. in English). 47: 6033-6. PMID 18649297 DOI: 10.1002/Anie.200801279  0.727
2008 Arnold PL, Edworthy IS, Carmichael CD, Blake AJ, Wilson C. Magnesium amido N-heterocyclic carbene complexes. Dalton Transactions (Cambridge, England : 2003). 3739-46. PMID 18615221 DOI: 10.1039/B803253J  0.446
2008 Liddle ST, McMaster J, Green JC, Arnold PL. Synthesis and structural characterisation of an yttrium-alkyl-alkylidene. Chemical Communications (Cambridge, England). 1747-9. PMID 18379680 DOI: 10.1039/B719633D  0.327
2008 Arnold PL, Patel D, Wilson C, Love JB. Reduction and selective oxo group silylation of the uranyl dication. Nature. 451: 315-7. PMID 18202653 DOI: 10.1038/Nature06467  0.381
2008 Arnold PL, Liddle ST. Synthesis and reactivity of neodymium(III) amido-tethered N-heterocyclic carbene complexes Comptes Rendus Chimie. 11: 603-611. DOI: 10.1016/J.Crci.2008.01.012  0.428
2007 Liddle ST, Edworthy IS, Arnold PL. Anionic tethered N-heterocyclic carbene chemistry. Chemical Society Reviews. 36: 1732-44. PMID 18213982 DOI: 10.1039/B611548A  0.461
2007 Casely IJ, Liddle ST, Blake AJ, Wilson C, Arnold PL. Tetravalent cerium carbene complexes. Chemical Communications (Cambridge, England). 5037-9. PMID 18049745 DOI: 10.1039/B713041D  0.518
2007 Liddle ST, Arnold PL. Synthesis and characterisation of yttrium complexes supported by the beta-diketiminate ligand {ArNC(CH3)CHC(CH3)NAr}- (Ar = 2,6-Pr(i)2C6H3). Dalton Transactions (Cambridge, England : 2003). 3305-13. PMID 17893777 DOI: 10.1039/B706971E  0.402
2007 Arnold PL, Liddle ST, McMaster J, Jones C, Mills DP. A lanthanide-gallium complex stabilized by the N-heterocyclic carbene group. Journal of the American Chemical Society. 129: 5360-1. PMID 17411055 DOI: 10.1021/Ja0710858  0.47
2007 Edworthy IS, Blake AJ, Wilson C, Arnold PL. Synthesis and NHC lability of d0 lithium, yttrium, titanium, and zirconium amido bis(N-heterocyclic carbene) complexes Organometallics. 26: 3684-3689. DOI: 10.1021/Om0701874  0.535
2007 Jones NA, Liddle ST, Wilson C, Arnold PL. Titanium(III) alkoxy-N-heterocyclic carbenes and a safe, low-cost route to TiCl3(THF)3 Organometallics. 26: 755-757. DOI: 10.1021/Om060486D  0.413
2007 Arnold PL, Wilson C. Sterically demanding bi- and tridentate alkoxy-N-heterocyclic carbenes Inorganica Chimica Acta. 360: 190-196. DOI: 10.1016/J.Ica.2006.07.075  0.487
2007 Arnold PL, Pearson S. Abnormal N-heterocyclic carbenes Coordination Chemistry Reviews. 251: 596-609. DOI: 10.1016/J.Ccr.2006.08.006  0.446
2006 Arnold PL, Liddle ST. F-block N-heterocyclic carbene complexes. Chemical Communications (Cambridge, England). 3959-71. PMID 17003868 DOI: 10.1039/B606829D  0.457
2006 Natrajan LS, Blake AJ, Wilson C, Weinstein JA, Arnold PL. Group I cation templated formation of luminescent mono- and bis-substituted thionaphthol heterobimetallic complexes of Pr, Nd, Eu and Tb. Dalton Transactions (Cambridge, England : 2003). 4465-73. PMID 16981021 DOI: 10.1039/B602242A  0.712
2006 Arnold PL, Patel D, Blake AJ, Wilson C, Love JB. Selective oxo functionalization of the uranyl ion with 3d metal cations. Journal of the American Chemical Society. 128: 9610-1. PMID 16866497 DOI: 10.1021/Ja0634167  0.377
2006 Patel D, Liddle ST, Mungur SA, Rodden M, Blake AJ, Arnold PL. Bifunctional yttrium(III) and titanium(IV) NHC catalysts for lactide polymerisation. Chemical Communications (Cambridge, England). 1124-6. PMID 16514460 DOI: 10.1039/B514406J  0.345
2006 Arnold PL, Liddle ST. Deprotonation of N-heterocyclic carbenes to afford heterobimetallic organolanthanide complexes Organometallics. 25: 1485-1491. DOI: 10.1021/Om050895U  0.527
2006 Mungur SA, Blake AJ, Wilson C, McMaster J, Arnold PL. Titanium(IV) alkoxy-N-heterocyclic carbenes: Structural preferences of alkoxide and bromide adducts Organometallics. 25: 1861-1867. DOI: 10.1021/Om0508839  0.516
2005 Arnold PL, Liddle ST. Regioselective C-H activation of lanthanide-bound N-heterocyclic carbenes. Chemical Communications (Cambridge, England). 5638-40. PMID 16292374 DOI: 10.1039/B511265F  0.409
2005 Arnold PL, Blake AJ, Wilson C. Synthesis and small molecule reactivity of uranium(IV) alkoxide complexes with both bound and pendant N-heterocyclic carbene ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). 11: 6095-9. PMID 16052659 DOI: 10.1002/Chem.200500481  0.519
2005 Arnold PL, Rodden M, Wilson C. Thermally stable potassium N-heterocyclic carbene complexes with alkoxide ligands, and a polymeric crystal structure with distorted, bridging carbenes. Chemical Communications (Cambridge, England). 1743-5. PMID 15791318 DOI: 10.1039/B418302A  0.51
2005 Liddle ST, Arnold PL. Synthesis of heteroleptic cerium(III) anionic amido-tethered N-heterocyclic carbene complexes Organometallics. 24: 2597-2605. DOI: 10.1021/Om050061B  0.44
2005 Edworthy IS, Rodden M, Mungur SA, Davis KM, Blake AJ, Wilson C, Schröder M, Arnold PL. Silver alkoxide and amino N-heterocyclic carbenes; Syntheses and crystal structures Journal of Organometallic Chemistry. 690: 5710-5719. DOI: 10.1016/J.Jorganchem.2005.07.063  0.473
2004 Arnold PL, Blake AJ, Wilson C, Love JB. Uranyl complexation by a schiff-base, polypyrrolic macrocycle. Inorganic Chemistry. 43: 8206-8. PMID 15606157 DOI: 10.1021/Ic0487070  0.475
2004 Mungur SA, Liddle ST, Wilson C, Sarsfield MJ, Arnold PL. Bent metal carbene geometries in amido N-heterocyclic carbene complexes. Chemical Communications (Cambridge, England). 2738-9. PMID 15568093 DOI: 10.1039/B410074C  0.508
2004 Natrajan LS, Blake AJ, Wilson C, Weinstein JA, Arnold PL. Synthesis and luminescence studies of mono- and C3-symmetric, tris(ligand) complexes of Sm(III), Y(III) and Eu(III) with sulfur-bridged binaphtholate ligands. Dalton Transactions (Cambridge, England : 2003). 3748-55. PMID 15510302 DOI: 10.1039/B409989C  0.753
2004 Arnold PL, Rodden M, Davis KM, Scarisbrick AC, Blake AJ, Wilson C. Asymmetric lithium(I) and copper(II) alkoxy-N-heterocyclic carbene complexes; crystallographic characterisation and Lewis acid catalysis. Chemical Communications (Cambridge, England). 1612-3. PMID 15263943 DOI: 10.1039/B404614E  0.461
2004 Arnold PL, Scarisbrick AC. Di- and trivalent ruthenium complexes of chelating, anionic N-heterocyclic carbenes Organometallics. 23: 2519-2521. DOI: 10.1021/Om0498091  0.47
2004 Arnold PL. Perspectives in organometallic chemistry Journal of Organometallic Chemistry. 689: 1866. DOI: 10.1016/J.Jorganchem.2004.02.029  0.302
2004 Natrajan LS, Wilson C, Okuda J, Arnold PL. Group 4 complexes of chelating dianionic [OSO] binaphtholate ligands; synthesis and alkene polymerisation catalysis European Journal of Inorganic Chemistry. 3724-3732. DOI: 10.1002/Ejic.200400174  0.766
2003 Arnold PL, Mungur SA, Blake AJ, Wilson C. Anionic amido N-heterocyclic carbenes: synthesis of covalently tethered lanthanide-carbene complexes. Angewandte Chemie (International Ed. in English). 42: 5981-4. PMID 14679548 DOI: 10.1002/Anie.200352710  0.534
2003 Clarke PA, Arnold PL, Smith MA, Natrajan LS, Wilson C, Chan C. Mechanistic insight into the lanthanide(III) salt catalysed monoacylation of symmetrical diols from structural models. Chemical Communications (Cambridge, England). 2588-9. PMID 14594294 DOI: 10.1039/B308171K  0.651
2003 Arnold PL, Hall JJ, Natrajan LS, Blake AJ, Wilson C. Synthesis of mono- and di-potassium salts and methoxy adducts of sulfur-bridged biphenols by selective deprotonation Dalton Transactions. 1053-1055. DOI: 10.1039/B301015E  0.679
2003 Natrajan LS, Hall JJ, Blake AJ, Wilson C, Arnold PL. Sulfur-bridged phenoxide and naphthyloxide-based ligands for lanthanide chemistry and catalysis Journal of Solid State Chemistry. 171: 90-100. DOI: 10.1016/S0022-4596(02)00197-4  0.708
2003 Arnold PL, Petrukhina MA, Bochenkov VE, Shabatina TI, Zagorskii VV, Sergeev GB, Cloke FGN. Arene complexation of Sm, Eu, Tm and Yb atoms: A variable temperature spectroscopic investigation Journal of Organometallic Chemistry. 688: 49-55. DOI: 10.1016/J.Jorganchem.2003.08.028  0.45
2003 Clarke PA, Arnold PL, Smith MA, Natrajan LS, Wilson C, Chan C. Mechanistic insight into the lanthanide (III) salt catalysed monoacylation of symmetrical diols from structural models Chemical Communications. 9: 2588-2589.  0.604
2002 Arnold PL, Natrajan LS, Hall JJ, Bird SJ, Wilson C. Symmetric and asymmetric samarium alkoxide derivatives of bridging sulfur biphenolate and binaphtholate ligands; synthetic, structural, and catalytic studies Journal of Organometalic Chemistry. 647: 205-215. DOI: 10.1016/S0022-328X(01)01425-5  0.702
2002 Arnold PL. Organometallic chemistry of silver and copper N-heterocyclic carbene complexes Heteroatom Chemistry. 13: 534-539. DOI: 10.1002/Hc.10098  0.487
2001 Arnold PL, Scarisbrick AC, Blake AJ, Wilson C. Chelating alkoxy-N-heterocyclic carbene complexes of silver and copper. Chemical Communications (Cambridge, England). 2340-1. PMID 12240065 DOI: 10.1039/B107855K  0.468
2001 Arnold PL, Blake AJ. Selective reduction in ring size of silsesquioxane oligomers mediated by potassium metal Acta Crystallographica Section E Structure Reports Online. 57: o131-o133. DOI: 10.1107/S1600536801000745  0.351
2001 Arnold PL, Blake AJ, Hall SN, Ward BD, Wilson C. A functional model for lanthanide doped silicate materials: Synthesis of an apically substituted samarium silsesquioxane complex Journal of the Chemical Society, Dalton Transactions. 488-491. DOI: 10.1039/B009123P  0.48
2000 Diaconescu PL, Arnold PL, Baker TA, Mindiola DJ, Cummins CC. Arene-bridged diuranium complexes: Inverted sandwiches supported by δ backbonding [2] Journal of the American Chemical Society. 122: 6108-6109. DOI: 10.1021/Ja994484E  0.774
1999 Arnold PL, Geoffrey F, Cloke N, Geldbach T, Hitchcock PB. Metal vapor synthesis as a straightforward route to group 10 homoleptic carbene complexes Organometallics. 18: 3228-3233. DOI: 10.1021/Om990224U  0.527
1998 Arnold PL, Cloke FGN, Nixon JF. The first stable scandocene: Synthesis and characterisation of bis(η-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)scandium(II) Chemical Communications. 797-798. DOI: 10.1039/A800089A  0.381
1998 Odom AL, Arnold PL, Cummins CC. Heterodinuclear uranium/molybdenum dinitrogen complexes [16] Journal of the American Chemical Society. 120: 5836-5837. DOI: 10.1021/Ja980095T  0.729
1997 Green JC, Scurr RG, Arnold PL, Cloke FGN. An experimental and theoretical investigation of the electronic structure of Pd and Pt bis(carbene) complexes Chemical Communications. 1963-1964. DOI: 10.1039/A705157C  0.392
1997 Arnold PL, Cloke FGN, Hitchcock PB. The first structurally authenticated zerovalent heteroarene complex of a lanthanide; synthesis and X-ray structure of bis(2,4,6-tri-tert-butyl-phosphorin)holmium(o) Chemical Communications. 481-482. DOI: 10.1039/A607827C  0.445
1996 Arnold PL, Cloke FGN, Hitchcock PB, Nixon JF. The first example of a formal scandium(I) complex: Synthesis and molecular structure of the 22-electron scandium triple decker incorporating the novel 1,3,5-triphosphabenzene ring Journal of the American Chemical Society. 118: 7630-7631. DOI: 10.1021/Ja961253O  0.366
1994 O'Hare D, Murphy V, Diamond GM, Arnold P, Mountford P. Synthesis of Permethylindenyl Complexes of the Early Transition Metals. Crystal Structures of Ti(.eta.5-C9Me7)Cl3 and Zr(.eta.5-C9Me7)2Cl2 Organometallics. 13: 4689-4694. DOI: 10.1021/Om00024A014  0.556
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