| Year |
Citation |
Score |
| 2024 |
Marchese AD, Dorsheimer JR, Rovis T. Photoredox-Catalyzed Generation of Tertiary Anions from Primary Amines via a Radical Polar Crossover. Angewandte Chemie (International Ed. in English). e202317563. PMID 38189622 DOI: 10.1002/anie.202317563 |
0.362 |
|
| 2023 |
Treacy SM, Vaz DR, Noman S, Tard C, Rovis T. Coupling of α-bromoamides and unactivated alkenes to form γ-lactams through EDA and photocatalysis. Chemical Science. 14: 1569-1574. PMID 36794189 DOI: 10.1039/d2sc05973h |
0.348 |
|
| 2023 |
Zhang X, Shen Y, Rovis T. Photoinduced Nickel-Catalyzed Selective -Demethylation of Trialkylamines Using C(sp)-Bromides as HAT Reagents. Journal of the American Chemical Society. PMID 36724205 DOI: 10.1021/jacs.2c12767 |
0.307 |
|
| 2022 |
Burg F, Rovis T. Rh(III)-catalyzed Intra- and Intermolecular 3,4-Difunctionalization of 1,3-Dienes Rh(III)-π-allyl Amidation with 1,4,2-Dioxazolones. Acs Catalysis. 12: 9690-9697. PMID 37829170 DOI: 10.1021/acscatal.2c02537 |
0.368 |
|
| 2022 |
Wagner-Carlberg N, Rovis T. Rhodium(III)-Catalyzed Anti-Markovnikov Hydroamidation of Unactivated Alkenes Using Dioxazolones as Amidating Reagents. Journal of the American Chemical Society. PMID 36453859 DOI: 10.1021/jacs.2c10552 |
0.513 |
|
| 2021 |
Kang YC, Treacy SM, Rovis T. Iron-Catalyzed Photoinduced LMCT: a 1° C-H Abstraction Enables Skeletal Rearrangements and C(sp)-H Alkylation. Acs Catalysis. 11: 7442-7449. PMID 35669035 DOI: 10.1021/acscatal.1c02285 |
0.433 |
|
| 2021 |
Zhang X, Rovis T. Photocatalyzed Triplet Sensitization of Oximes Using Visible Light Provides a Route to Nonclassical Beckmann Rearrangement Products. Journal of the American Chemical Society. PMID 34905347 DOI: 10.1021/jacs.1c10148 |
0.502 |
|
| 2021 |
Dorsheimer JR, Ashley MA, Rovis T. Dual Nickel/Photoredox-Catalyzed Deaminative Cross-Coupling of Sterically Hindered Primary Amines. Journal of the American Chemical Society. 143: 19294-19299. PMID 34767360 DOI: 10.1021/jacs.1c10150 |
0.523 |
|
| 2021 |
Lee S, Rovis T. Rh(III)-Catalyzed Three-Component -Carboamination of Alkenes Using Arylboronic Acids and Dioxazolones. Acs Catalysis. 11: 8585-8590. PMID 34745710 DOI: 10.1021/acscatal.1c02406 |
0.501 |
|
| 2021 |
Shen Y, Rovis T. Late-Stage -Me Selective Arylation of Trialkylamines Enabled by Ni/Photoredox Dual Catalysis. Journal of the American Chemical Society. PMID 34590864 DOI: 10.1021/jacs.1c08157 |
0.435 |
|
| 2020 |
Lee S, Jang YJ, Phipps EJT, Lei H, Rovis T. Rhodium(III)-Catalyzed Three-Component 1,2-Diamination of Unactivated Terminal Alkenes. Synthesis. 52: 1247-1252. PMID 34290458 DOI: 10.1055/s-0039-1690756 |
0.547 |
|
| 2020 |
Ravetz BD, Tay NES, Joe CL, Sezen-Edmonds M, Schmidt MA, Tan Y, Janey JM, Eastgate MD, Rovis T. Development of a Platform for Near-Infrared Photoredox Catalysis. Acs Central Science. 6: 2053-2059. PMID 33274281 DOI: 10.1021/acscentsci.0c00948 |
0.679 |
|
| 2020 |
Ashley MA, Rovis T. Photoredox-Catalyzed Deaminative Alkylation via C-N Bond Activation of Primary Amines. Journal of the American Chemical Society. PMID 33058665 DOI: 10.1021/jacs.0c08595 |
0.421 |
|
| 2020 |
Lei H, Rovis T. A site-selective amination catalyst discriminates between nearly identical C-H bonds of unsymmetrical disubstituted alkenes. Nature Chemistry. PMID 32541949 DOI: 10.1038/S41557-020-0470-Z |
0.45 |
|
| 2020 |
Lee S, Semakul N, Rovis T. Direct Regio- and Diastereoselective Synthesis of δ-Lactams from Acrylamides and Unactivated Alkenes Initiated by Rh -Catalyzed C-H Activation. Angewandte Chemie (International Ed. in English). PMID 32045098 DOI: 10.1002/Anie.201916332 |
0.628 |
|
| 2020 |
Nicastri MC, Lehnherr D, Lam YH, DiRocco DA, Rovis T. Synthesis of Sterically Hindered Primary Amines by Concurrent Tandem Photoredox Catalysis. Journal of the American Chemical Society. PMID 31904228 DOI: 10.1021/Jacs.9B10871 |
0.8 |
|
| 2019 |
Phipps EJT, Piou T, Rovis T. Rh(III)-Catalyzed Cyclopropanation of Unactivated Olefins Initiated by C-H Activation. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 30: 1787-1790. PMID 32801480 DOI: 10.1055/S-0039-1690130 |
0.516 |
|
| 2019 |
Lehnherr D, Lam YH, Nicastri MC, Liu J, Newman JA, Regalado EL, DiRocco DA, Rovis T. Electrochemical Synthesis of Hindered Primary and Secondary Amines via Proton-Coupled Electron Transfer. Journal of the American Chemical Society. PMID 31849221 DOI: 10.1021/Jacs.9B10870 |
0.779 |
|
| 2019 |
Thullen SM, Treacy SM, Rovis T. Regioselective Alkylative Cross-Coupling of Remote Unactivated C()-H Bonds. Journal of the American Chemical Society. 141: 14062-14067. PMID 31478370 DOI: 10.1021/Jacs.9B07014 |
0.509 |
|
| 2019 |
Lee S, Lei H, Rovis T. A Rh(III)-Catalyzed Formal [4+1] Approach to Pyrrolidines from Unactivated Terminal Alkenes and Nitrene Sources. Journal of the American Chemical Society. PMID 31381308 DOI: 10.1021/Jacs.9B07012 |
0.604 |
|
| 2019 |
Lei H, Conway JH, Cook CC, Rovis T. Ligand Controlled Ir-Catalyzed Regiodivergent Oxyamination of Unactivated Alkenes. Journal of the American Chemical Society. PMID 31310537 DOI: 10.1021/Jacs.9B06366 |
0.541 |
|
| 2019 |
Theunissen C, Ashley MA, Rovis T. Visible-Light-Controlled Ruthenium-Catalyzed Olefin Metathesis. Journal of the American Chemical Society. PMID 31010292 DOI: 10.1021/Jacs.8B13663 |
0.744 |
|
| 2019 |
Phipps EJT, Rovis T. Rh(III)-Catalyzed C-H Activation-Initiated Directed Cyclopropanation of Allylic Alcohols. Journal of the American Chemical Society. PMID 30998324 DOI: 10.1021/Jacs.9B02156 |
0.491 |
|
| 2019 |
Hassan IS, Ta AN, Danneman MW, Semakul N, Burns M, Basch CH, Dippon VN, McNaughton BR, Rovis T. Asymmetric δ-Lactam Synthesis with a Monomeric Streptavidin Artificial Metalloenzyme. Journal of the American Chemical Society. PMID 30865436 DOI: 10.1021/Jacs.9B01596 |
0.6 |
|
| 2019 |
Ashley MA, Yamauchi C, Chu JCK, Otsuka S, Yorimitsu H, Rovis T. Photoredox-Catalyzed Site-Selective α-C(sp )-H Alkylation of Primary Amine Derivatives. Angewandte Chemie (International Ed. in English). PMID 30768740 DOI: 10.1002/Anie.201812227 |
0.512 |
|
| 2019 |
Lei H, Rovis T. Ir-Catalyzed Intermolecular Branch-Selective Allylic C-H Amidation of Unactivated Terminal Olefins. Journal of the American Chemical Society. PMID 30715868 DOI: 10.1021/Jacs.9B00237 |
0.575 |
|
| 2019 |
Ravetz BD, Pun AB, Churchill EM, Congreve DN, Rovis T, Campos LM. Photoredox catalysis using infrared light via triplet fusion upconversion. Nature. 565: 343-346. PMID 30651612 DOI: 10.1038/S41586-018-0835-2 |
0.412 |
|
| 2019 |
Otsuka S, Nogi K, Rovis T, Yorimitsu H. Photoredox-Catalyzed Alkenylation of Benzylsulfoniums. Chemistry, An Asian Journal. PMID 30644178 DOI: 10.1002/Asia.201801732 |
0.479 |
|
| 2019 |
Lee S, Jang YJ, Phipps EJT, Lei H, Rovis T. Rhodium(III)-Catalyzed Three-Component 1,2-Diamination of Unactivated Terminal Alkenes Synthesis. 52: 1247-1252. DOI: 10.1055/S-0039-1690756 |
0.608 |
|
| 2019 |
Phipps EJT, Piou T, Rovis T. Rhodium(III)-Catalyzed Cyclopropanation of Unactivated Olefins Initiated by C–H Activation Synlett. 30: 1787-1790. DOI: 10.1055/s-0039-1690130 |
0.489 |
|
| 2018 |
Hyster TK, Dalton DM, Rovis T. Correction: Ligand design for Rh(iii)-catalyzed C-H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones. Chemical Science. 9: 8024. PMID 30542552 DOI: 10.1039/C8Sc90195C |
0.808 |
|
| 2018 |
Ye J, Kalvet I, Schoenebeck F, Rovis T. Direct α-alkylation of primary aliphatic amines enabled by CO and electrostatics. Nature Chemistry. PMID 30061617 DOI: 10.1038/S41557-018-0085-9 |
0.514 |
|
| 2018 |
Piou T, Romanov-Michailidis F, Ashley MA, Romanova-Michaelides M, Rovis T. Stereodivergent Rhodium(III)-Catalyzed cis-Cyclopropanation Enabled by Multivariate Optimization. Journal of the American Chemical Society. PMID 30033723 DOI: 10.1021/Jacs.8B04243 |
0.545 |
|
| 2018 |
Romanov-Michailidis F, Ravetz BD, Paley DW, Rovis T. Ir(III)-Catalyzed Carbocarbation of Alkynes through Undirected Double C-H Bond Activation of Anisoles. Journal of the American Chemical Society. PMID 29641190 DOI: 10.1021/Jacs.8B02716 |
0.484 |
|
| 2018 |
Rovis T, Oberg K, Cochran B, Cook M. The Catalytic Alkylative Desymmetrization of Anhydrides in a Formal Synthesis of Ionomycin Synthesis. 50: 4343-4350. DOI: 10.1055/S-0037-1610108 |
0.842 |
|
| 2018 |
Johnston J, Rovis T. Cluster Preface: Alkene Halofunctionalization Synlett. 29: 399-400. DOI: 10.1055/S-0037-1609319 |
0.65 |
|
| 2018 |
Ravetz BD, Wang JY, Ruhl KE, Rovis T. Photoinduced Ligand-to-Metal Charge Transfer Enables Photocatalyst-Independent Light-Gated Activation of Co(II) Acs Catalysis. 9: 200-204. DOI: 10.1021/Acscatal.8B04326 |
0.415 |
|
| 2018 |
Ravetz BD, Ruhl KE, Rovis T. External Regulation of Cobalt-Catalyzed Cycloaddition Polymerization with Visible Light Acs Catalysis. 8: 5323-5327. DOI: 10.1021/Acscatal.8B01431 |
0.409 |
|
| 2017 |
Hyster TK, Dalton DM, Rovis T. Correction: Ligand design for Rh(iii)-catalyzed C-H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones. Chemical Science. 8: 1666. PMID 30123475 DOI: 10.1039/c6sc90080a |
0.808 |
|
| 2017 |
Thullen SM, Rubush DM, Rovis T. A Photochemical Two-Step Formal [5+2] Cycloaddition: A Condensation/Ring-Expansion Approach to Substituted Azepanes. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 28: 2755-2758. PMID 29861552 DOI: 10.1055/S-0036-1589049 |
0.831 |
|
| 2017 |
Conway JH, Rovis T. Regiodivergent Iridium(III)-Catalyzed Diamination of Alkenyl Amides with Secondary Amines: Complementary Access to γ- or δ-Lactams. Journal of the American Chemical Society. PMID 29278330 DOI: 10.1021/Jacs.7B11455 |
0.571 |
|
| 2017 |
Piou T, Rovis T. Electronic and Steric Tuning of a Prototypical Piano Stool Complex: Rh(III) Catalysis for C-H Functionalization. Accounts of Chemical Research. PMID 29272106 DOI: 10.1021/Acs.Accounts.7B00444 |
0.546 |
|
| 2017 |
Chu JCK, Rovis T. Complementary Strategies for Directed C(sp3 )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer. Angewandte Chemie (International Ed. in English). PMID 29206316 DOI: 10.1002/Anie.201703743 |
0.448 |
|
| 2017 |
Thullen SM, Rovis T. A Mild Hydroaminoalkylation of Conjugated Dienes Using a Unified Cobalt and Photoredox Catalytic System. Journal of the American Chemical Society. PMID 29048886 DOI: 10.1021/Jacs.7B09252 |
0.479 |
|
| 2017 |
Niu Y, Wang N, Muñoz A, Xu J, Zeng H, Rovis T, Lee JK. Experimental and Computational Gas Phase Acidities of Conjugate Acids of Triazolylidene Carbenes: Rationalizing Subtle Electronic Effects. Journal of the American Chemical Society. PMID 29039669 DOI: 10.1021/Jacs.7B05229 |
0.386 |
|
| 2017 |
Chen DF, Chu JCK, Rovis T. Directed γ-C(sp(3))-H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox Catalysis. Journal of the American Chemical Society. PMID 29022709 DOI: 10.1021/Jacs.7B09306 |
0.405 |
|
| 2017 |
Flanigan DM, Rovis T. Enantioselective N-heterocyclic carbene-catalyzed nucleophilic dearomatization of alkyl pyridiniums. Chemical Science. 8: 6566-6569. PMID 28989683 DOI: 10.1039/C7Sc02648J |
0.546 |
|
| 2017 |
Chen DF, Rovis T. N-Heterocyclic Carbene and Chiral Brønsted Acid Cooperative Catalysis for a Highly Enantioselective [4+2] Annulation. Synthesis. 49: 293-298. PMID 28690345 DOI: 10.1055/S-0036-1588349 |
0.477 |
|
| 2017 |
Semakul N, Jackson KE, Paton RS, Rovis T. Heptamethylindenyl (Ind*) enables diastereoselective benzamidation of cyclopropenes via Rh(iii)-catalyzed C-H activation. Chemical Science. 8: 1015-1020. PMID 28451239 DOI: 10.1039/C6Sc02587K |
0.461 |
|
| 2017 |
Stache EE, Rovis T, Doyle AG. Dual Nickel- and Photoredox-Catalyzed Enantioselective Desymmetrization of Cyclic meso-Anhydrides. Angewandte Chemie (International Ed. in English). PMID 28230304 DOI: 10.1002/Anie.201700097 |
0.844 |
|
| 2017 |
Piou T, Romanov-Michailidis F, Romanova-Michaelides M, Jackson KE, Semakul N, Taggart TD, Newell BS, Rithner CD, Paton RS, Rovis T. Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand Properties in Rh(III)-Catalyzed C-H Activation Reactions: An Experimental and Computational Study. Journal of the American Chemical Society. PMID 28060499 DOI: 10.1021/Jacs.6B11670 |
0.477 |
|
| 2017 |
Rovis T, Cochran B, Henderson D, Thullen S. Rhodium-Catalyzed Desymmetrization of meso-Glutaric Anhydrides to Access Enantioenriched anti,anti-Polypropionates Synlett. 29: 306-309. DOI: 10.1055/S-0036-1591488 |
0.44 |
|
| 2016 |
Ruhl KE, Rovis T. Visible Light-Gated Cobalt Catalysis for a Spatially and Temporally Resolved [2+2+2] Cycloaddition. Journal of the American Chemical Society. 138: 15527-15530. PMID 27934027 DOI: 10.1021/Jacs.6B08792 |
0.352 |
|
| 2016 |
Chu JC, Rovis T. Amide-directed photoredox-catalysed C-C bond formation at unactivated sp(3) C-H bonds. Nature. PMID 27732580 DOI: 10.1038/Nature19810 |
0.319 |
|
| 2015 |
Davis TA, Wang C, Rovis T. Rhodium(III)-Catalyzed C-H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylic Acid. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 26: 1520-1524. PMID 27540274 DOI: 10.1055/S-0034-1381006 |
0.728 |
|
| 2015 |
Piou T, Rovis T. Rhodium-catalysed syn-carboamination of alkenes via a transient directing group. Nature. 527: 86-90. PMID 26503048 DOI: 10.1038/Nature15691 |
0.46 |
|
| 2015 |
White NA, Rovis T. Correction to "Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from Enals". Journal of the American Chemical Society. 137: 13210. PMID 26439476 DOI: 10.1021/Jacs.5B09675 |
0.675 |
|
| 2015 |
Archambeau A, Rovis T. Rhodium(III)-Catalyzed Allylic C(sp(3) )-H Activation of Alkenyl Sulfonamides: Unexpected Formation of Azabicycles. Angewandte Chemie (International Ed. in English). 54: 13337-40. PMID 26358769 DOI: 10.1002/Anie.201504150 |
0.465 |
|
| 2015 |
White NA, Rovis T. Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from Enals. Journal of the American Chemical Society. 137: 10112-5. PMID 26256839 DOI: 10.1021/Jacs.5B06390 |
0.73 |
|
| 2015 |
Telitel S, Vallet AL, Flanigan DM, Graff B, Morlet-Savary F, Rovis T, Lalevée J, Lacôte E. Influence of Electronic Effects on the Reactivity of Triazolylidene-Boryl Radicals: Consequences for the use of N-Heterocyclic Carbene Boranes in Organic and Polymer Synthesis. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 13772-7. PMID 26239157 DOI: 10.1002/Chem.201500499 |
0.38 |
|
| 2015 |
Romanov-Michailidis F, Rovis T. Organic chemistry: Natural polarity inverted. Nature. 523: 417-8. PMID 26201594 DOI: 10.1038/523417A |
0.499 |
|
| 2015 |
Romanov-Michailidis F, Sedillo KF, Neely JM, Rovis T. Expedient Access to 2,3-Dihydropyridines from Unsaturated Oximes by Rh(III)-Catalyzed C-H Activation. Journal of the American Chemical Society. PMID 26154248 DOI: 10.1021/Jacs.5B04946 |
0.748 |
|
| 2015 |
Flanigan DM, Romanov-Michailidis F, White NA, Rovis T. Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes. Chemical Reviews. PMID 25992594 DOI: 10.1021/Acs.Chemrev.5B00060 |
0.672 |
|
| 2015 |
Chu JC, Dalton DM, Rovis T. Zn-catalyzed enantio- and diastereoselective formal [4 + 2] cycloaddition involving two electron-deficient partners: asymmetric synthesis of piperidines from 1-azadienes and nitro-alkenes. Journal of the American Chemical Society. 137: 4445-52. PMID 25821893 DOI: 10.1021/Jacs.5B00033 |
0.802 |
|
| 2015 |
Hyster TK, Rovis T. Correction: Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity. Chemical Communications (Cambridge, England). 51: 5778. PMID 25749239 DOI: 10.1039/c5cc90120k |
0.685 |
|
| 2015 |
Zhang WZ, Chu JC, Oberg KM, Rovis T. Enantioselective rhodium-catalyzed isomerization of 4-iminocrotonates: asymmetric synthesis of a unique chiral synthon. Journal of the American Chemical Society. 137: 553-5. PMID 25580807 DOI: 10.1021/Ja510348P |
0.85 |
|
| 2015 |
Filloux CM, Rovis T. Rh(I)-bisphosphine-catalyzed asymmetric, intermolecular hydroheteroarylation of α-substituted acrylate derivatives. Journal of the American Chemical Society. 137: 508-17. PMID 25545834 DOI: 10.1021/Ja511445X |
0.576 |
|
| 2015 |
Hyster TK, Dalton DM, Rovis T. Ligand Design for Rh(III)-Catalyzed C-H Activation: An Unsymmetrical Cyclopentadienyl Enables a Regioselective Synthesis of Dihydroisoquinolones. Chemical Science (Royal Society of Chemistry : 2010). 6: 254-258. PMID 25489470 DOI: 10.1039/C4Sc02590C |
0.838 |
|
| 2015 |
Davis TA, Wang C, Rovis T. Rhodium(III)-Catalyzed C-H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylate Synlett. 26: 1520-1524. DOI: 10.1055/s-0034-1381006 |
0.323 |
|
| 2015 |
Gaunt MJ, Chow HF, Rovis T. Cluster preface: Catalysis using sustainable metals - Part II Synlett. 26: 306. DOI: 10.1055/S-0034-1380054 |
0.319 |
|
| 2015 |
White NA, Rovis T. Oxidatively initiated NHC-catalyzed enantioselective synthesis of 3,4-disubstituted cyclopentanones from enals Journal of the American Chemical Society. 137: 10112-10115. DOI: 10.1021/jacs.5b06390 |
0.644 |
|
| 2014 |
Rubush DM, Rovis T. Stereoselective Synthesis of Dioxolanes and Oxazolidines via a Desymmetrization Acetalization/Michael Cascade. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 25: 713-717. PMID 25960607 DOI: 10.1055/S-0033-1340669 |
0.844 |
|
| 2014 |
Ozboya KE, Rovis T. A Late Stage Strategy for the Functionalization of Triazolium-based NHC catalysts. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 25: 2665-2668. PMID 25954060 DOI: 10.1055/S-0034-1379167 |
0.368 |
|
| 2014 |
White NA, Ozboya KE, Flanigan DM, Rovis T. Rapid Construction of (-)-Paroxetine and (-)-Femoxetine via N-Heterocyclic Carbene Catalyzed Homoenolate Addition to Nitroalkenes. Asian Journal of Organic Chemistry / Managing Editor, Richard Threlfall. 3: 442-444. PMID 25485210 DOI: 10.1002/Ajoc.201402031 |
0.708 |
|
| 2014 |
Oberg KM, Martin TJ, Oinen ME, Dalton DM, Friedman RK, Neely JM, Rovis T. Enantioselective Rhodium-Catalyzed [2+2+2] Cycloaddition of Pentenyl Isocyanate and 4-Ethynylanisole: Preparation and Use of Taddolpyrrolidine Phosphoramidite. Organic Syntheses; An Annual Publication of Satisfactory Methods For the Preparation of Organic Chemicals. 91: 150-161. PMID 25346554 DOI: 10.15227/Orgsyn.091.0150 |
0.796 |
|
| 2014 |
White NA, Rovis T. Enantioselective N-heterocyclic carbene-catalyzed β-hydroxylation of enals using nitroarenes: an atom transfer reaction that proceeds via single electron transfer. Journal of the American Chemical Society. 136: 14674-7. PMID 25302860 DOI: 10.1021/Ja5080739 |
0.653 |
|
| 2014 |
Piou T, Rovis T. Rh(III)-catalyzed cyclopropanation initiated by C-H activation: ligand development enables a diastereoselective [2 + 1] annulation of N-enoxyphthalimides and alkenes. Journal of the American Chemical Society. 136: 11292-5. PMID 25093811 DOI: 10.1021/Ja506579T |
0.456 |
|
| 2014 |
Hsieh SY, Wanner B, Wheeler P, Beauchemin AM, Rovis T, Bode JW. Stereoelectronic basis for the kinetic resolution of N-heterocycles with chiral acylating reagents. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 7228-31. PMID 24839065 DOI: 10.1002/Chem.201402818 |
0.763 |
|
| 2014 |
Neely JM, Rovis T. Rh(III)-catalyzed decarboxylative coupling of acrylic acids with unsaturated oxime esters: carboxylic acids serve as traceless activators. Journal of the American Chemical Society. 136: 2735-8. PMID 24512241 DOI: 10.1021/Ja412444D |
0.766 |
|
| 2014 |
Gaunt M, Rovis T, Chow HF. Catalysis using sustainable metals - Part i Synlett. 25: 2715-2716. DOI: 10.1055/S-0034-1379611 |
0.363 |
|
| 2014 |
Kohn BL, Rovis T. Cobaltate anion couples terminal dienes with trifluoroacetic anhydride: A direct fluoroacylation of 1,3-dienes Chemical Science. 5: 2889-2892. DOI: 10.1039/C4Sc00743C |
0.509 |
|
| 2014 |
Neely JM, Rovis T. Pyridine synthesis by [4 + 2] cycloadditions of 1-azadienes: Hetero-Diels Alder and transition metal-catalysed approaches Organic Chemistry Frontiers. 1: 1010-1015. DOI: 10.1039/C4Qo00187G |
0.767 |
|
| 2014 |
White NA, Ozboya KE, Flanigan DM, Rovis T. ChemInform Abstract: Rapid Construction of (-)-Paroxetine and (-)-Femoxetine via an N-Heterocyclic Carbene Catalyzed Homoenolate Addition to Nitroalkenes. Cheminform. 45: no-no. DOI: 10.1002/chin.201445160 |
0.616 |
|
| 2013 |
Perreault S, Rovis T. Enantioselective Synthesis of the Tricyclic Core of FR901483 Featuring a Rh-Catalyzed [2+2+2] Cycloaddition. Synthesis. 45: 719-728. PMID 25506094 DOI: 10.1055/S-0032-1316786 |
0.522 |
|
| 2013 |
Wheeler P, Vora HU, Rovis T. Asymmetric NHC-catalyzed synthesis of α-fluoroamides from readily accessible α-fluoroenals. Chemical Science (Royal Society of Chemistry : 2010). 4: 1674-1679. PMID 25346841 DOI: 10.1039/C3Sc00089C |
0.736 |
|
| 2013 |
Hyster TK, Rovis T. Rhodium(III)-Catalyzed C-H Activation Mediated Synthesis of Isoquinolones from Amides and Cyclopropenes. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 24: 1842-1844. PMID 25346576 DOI: 10.1055/S-0033-1339510 |
0.735 |
|
| 2013 |
Zhao X, Glover GS, Oberg KM, Dalton DM, Rovis T. SNAr-Derived Decomposition By-products Involving Pentafluorophenyl Triazolium Carbenes. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 24. PMID 24379522 DOI: 10.1055/S-0033-1338842 |
0.836 |
|
| 2013 |
Lathrop SP, Rovis T. A photoisomerization-coupled asymmetric Stetter reaction: application to the total synthesis of three diastereomers of (-)-cephalimysin A. Chemical Science (Royal Society of Chemistry : 2010). 4. PMID 24224080 DOI: 10.1039/C3Sc22292F |
0.745 |
|
| 2013 |
Davis TA, Hyster TK, Rovis T. Rhodium(III)-catalyzed intramolecular hydroarylation, amidoarylation, and Heck-type reaction: three distinct pathways determined by an amide directing group. Angewandte Chemie (International Ed. in English). 52: 14181-5. PMID 24214733 DOI: 10.1002/Anie.201307631 |
0.825 |
|
| 2013 |
White NA, DiRocco DA, Rovis T. Asymmetric N-heterocyclic carbene catalyzed addition of enals to nitroalkenes: controlling stereochemistry via the homoenolate reactivity pathway to access δ-lactams. Journal of the American Chemical Society. 135: 8504-7. PMID 23713683 DOI: 10.1021/Ja403847E |
0.85 |
|
| 2013 |
Dalton DM, Rappé AK, Rovis T. Perfluorinated Taddol Phosphoramidite as an L,Z-Ligand on Rh(I) and Co(-I): Evidence for Bidentate Coordination via Metal-C6F5 Interaction. Chemical Science (Royal Society of Chemistry : 2010). 4: 2062-2070. PMID 23671790 DOI: 10.1039/C3Sc50271F |
0.73 |
|
| 2013 |
Dalton DM, Rovis T. Catalytic, asymmetric indolizidinone aza-quaternary stereocenter synthesis: expedient synthesis of the cylindricine alkaloid core. Organic Letters. 15: 2346-9. PMID 23631448 DOI: 10.1021/Ol400529K |
0.804 |
|
| 2013 |
Martin TJ, Rovis T. A catalytic asymmetric synthesis of polysubstituted piperidines using a rhodium(I)-catalyzed [2+2+2] cycloaddition employing a cleavable tether. Angewandte Chemie (International Ed. in English). 52: 5368-71. PMID 23606664 DOI: 10.1002/Anie.201301741 |
0.608 |
|
| 2013 |
Hyster TK, Ruhl KE, Rovis T. A coupling of benzamides and donor/acceptor diazo compounds to form γ-lactams via Rh(III)-catalyzed C-H activation. Journal of the American Chemical Society. 135: 5364-7. PMID 23548055 DOI: 10.1021/Ja402274G |
0.709 |
|
| 2013 |
Neely JM, Rovis T. Rh(III)-catalyzed regioselective synthesis of pyridines from alkenes and α,β-unsaturated oxime esters. Journal of the American Chemical Society. 135: 66-9. PMID 23244023 DOI: 10.1021/Ja3104389 |
0.779 |
|
| 2013 |
Ferreira EM, Rovis T. 17th IUPAC Conference on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS 17), Fort Collins, CO, USA, July 28–August 1, 2013 Green Processing and Synthesis. 2. DOI: 10.1515/gps-2013-0014 |
0.537 |
|
| 2013 |
Rovis T, Dalton D. Rhodium-Catalyzed Enantioselective [2+2+2] Cycloaddition Synfacts. 9: 1030-1030. DOI: 10.1055/s-0033-1339688 |
0.803 |
|
| 2013 |
Rovis T, Nolan SP. Stable carbenes: From 'laboratory curiosities' to catalysis mainstays Synlett. 24: 1188-1189. DOI: 10.1055/S-0033-1339192 |
0.304 |
|
| 2013 |
DiRocco DA, Rovis T. ChemInform Abstract: Carbene-Catalyzed Stetter Reactions Cheminform. 44: no-no. DOI: 10.1002/chin.201307233 |
0.412 |
|
| 2013 |
Oberg KM, Rovis T. Heterocycle Construction via Asymmetric Rhodium-Catalyzed Cycloadditions Asymmetric Synthesis Ii: More Methods and Applications. 303-308. DOI: 10.1002/9783527652235.ch38 |
0.829 |
|
| 2012 |
Vora HU, Wheeler P, Rovis T. Exploiting Acyl and Enol Azolium Intermediates via NHeterocyclic Carbene Catalyzed Reactions of Alpha-Reducible Aldehydes. Advanced Synthesis & Catalysis. 354: 1617-1639. PMID 23538785 DOI: 10.1002/Adsc.201200031 |
0.801 |
|
| 2012 |
Zhao X, Ruhl KE, Rovis T. N-heterocyclic-carbene-catalyzed asymmetric oxidative hetero-Diels-Alder reactions with simple aliphatic aldehydes. Angewandte Chemie (International Ed. in English). 51: 12330-3. PMID 23124903 DOI: 10.1002/Anie.201206490 |
0.711 |
|
| 2012 |
Hyster TK, Knörr L, Ward TR, Rovis T. Biotinylated Rh(III) complexes in engineered streptavidin for accelerated asymmetric C-H activation. Science (New York, N.Y.). 338: 500-3. PMID 23112327 DOI: 10.1126/Science.1226132 |
0.708 |
|
| 2012 |
Rubush DM, Morges MA, Rose BJ, Thamm DH, Rovis T. An asymmetric synthesis of 1,2,4-trioxane anticancer agents via desymmetrization of peroxyquinols through a Brønsted acid catalysis cascade. Journal of the American Chemical Society. 134: 13554-7. PMID 22871165 DOI: 10.1021/Ja3052427 |
0.838 |
|
| 2012 |
DiRocco DA, Rovis T. Catalytic asymmetric cross-aza-benzoin reactions of aliphatic aldehydes with N-Boc-protected imines. Angewandte Chemie (International Ed. in English). 51: 5904-6. PMID 22566184 DOI: 10.1002/Anie.201202442 |
0.823 |
|
| 2012 |
DiRocco DA, Rovis T. Catalytic asymmetric α-acylation of tertiary amines mediated by a dual catalysis mode: N-heterocyclic carbene and photoredox catalysis. Journal of the American Chemical Society. 134: 8094-7. PMID 22548244 DOI: 10.1021/Ja3030164 |
0.765 |
|
| 2012 |
DiRocco DA, Oberg KM, Rovis T. Isolable analogues of the Breslow intermediate derived from chiral triazolylidene carbenes. Journal of the American Chemical Society. 134: 6143-5. PMID 22455368 DOI: 10.1021/Ja302031V |
0.813 |
|
| 2012 |
DiRocco DA, Noey EL, Houk KN, Rovis T. Catalytic asymmetric intermolecular Stetter reactions of enolizable aldehydes with nitrostyrenes: computational study provides insight into the success of the catalyst. Angewandte Chemie (International Ed. in English). 51: 2391-4. PMID 22282312 DOI: 10.1002/Anie.201107597 |
0.797 |
|
| 2012 |
Rovis T, Filloux C. 6.12 Benzoin and Stetter Reactions Comprehensive Chirality. 6: 318-344. DOI: 10.1016/B978-0-08-095167-6.00612-1 |
0.321 |
|
| 2012 |
Vora HU, Wheeler P, Rovis T. ChemInform Abstract: Exploiting Acyl and Enol Azolium Intermediates via N-Heterocyclic Carbene-Catalyzed Reactions of α-Reducible Aldehydes. Cheminform. 43: no-no. DOI: 10.1002/chin.201239239 |
0.661 |
|
| 2011 |
Hyster TK, Rovis T. An Improved Catalyst Architecture for Rhodium (III) Catalyzed C-H Activation and its Application to Pyridone Synthesis. Chemical Science (Royal Society of Chemistry : 2010). 2: 1606-1610. PMID 25580208 DOI: 10.1039/C1Sc00235J |
0.753 |
|
| 2011 |
Vora HU, Rovis T. Asymmetric N-Heterocyclic Carbene (NHC) Catalyzed Acyl Anion Reactivity. Aldrichimica Acta. 44: 3-11. PMID 25346540 |
0.621 |
|
| 2011 |
Du Y, Hyster TK, Rovis T. Rhodium(III)-catalyzed oxidative carbonylation of benzamides with carbon monoxide. Chemical Communications (Cambridge, England). 47: 12074-6. PMID 22006288 DOI: 10.1039/C1Cc15843K |
0.727 |
|
| 2011 |
Hyster TK, Rovis T. Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity. Chemical Communications (Cambridge, England). 47: 11846-8. PMID 21986995 DOI: 10.1039/C1Cc15248C |
0.741 |
|
| 2011 |
Ozboya KE, Rovis T. Enamine/Carbene Cascade Catalysis in the Diastereo- and Enantioselective Synthesis of Functionalized Cyclopentanones. Chemical Science (Royal Society of Chemistry : 2010). 2: 1835-1838. PMID 21927711 DOI: 10.1039/C1Sc00175B |
0.516 |
|
| 2011 |
Zhao X, DiRocco DA, Rovis T. N-heterocyclic carbene and Brønsted acid cooperative catalysis: asymmetric synthesis of trans-γ-lactams. Journal of the American Chemical Society. 133: 12466-9. PMID 21780842 DOI: 10.1021/Ja205714G |
0.811 |
|
| 2011 |
DiRocco DA, Rovis T. Organocatalytic hydroacylation of unactivated alkenes. Angewandte Chemie (International Ed. in English). 50: 7982-3. PMID 21721090 DOI: 10.1002/Anie.201102920 |
0.772 |
|
| 2011 |
DiRocco DA, Rovis T. Catalytic asymmetric intermolecular Stetter reaction of enals with nitroalkenes: enhancement of catalytic efficiency through bifunctional additives. Journal of the American Chemical Society. 133: 10402-5. PMID 21678918 DOI: 10.1021/Ja203810B |
0.806 |
|
| 2011 |
Um JM, DiRocco DA, Noey EL, Rovis T, Houk KN. Quantum mechanical investigation of the effect of catalyst fluorination in the intermolecular asymmetric Stetter reaction. Journal of the American Chemical Society. 133: 11249-54. PMID 21675770 DOI: 10.1021/Ja202444G |
0.763 |
|
| 2011 |
Oberg KM, Rovis T. Enantioselective rhodium-catalyzed [4+2] cycloaddition of α,β-unsaturated imines and isocyanates. Journal of the American Chemical Society. 133: 4785-7. PMID 21401131 DOI: 10.1021/Ja200766K |
0.822 |
|
| 2011 |
Moore JL, Silvestri AP, de Alaniz JR, DiRocco DA, Rovis T. Mechanistic investigation of the enantioselective intramolecular stetter reaction: proton transfer is the first irreversible step. Organic Letters. 13: 1742-5. PMID 21355598 DOI: 10.1021/Ol200256A |
0.773 |
|
| 2011 |
DiRocco DA, Rovis T. ChemInform Abstract: Asymmetric Benzoin and Stetter Reactions Cheminform. 42: no-no. DOI: 10.1002/chin.201140200 |
0.382 |
|
| 2011 |
DiRocco DA, Rovis T. Organokatalytische Hydroacylierung nichtaktivierter Alkene Angewandte Chemie. 123: 8130-8132. DOI: 10.1002/Ange.201102920 |
0.793 |
|
| 2011 |
Du Y, Hyster TK, Rovis T. Rhodium-catalyzed oxidative carbonylation of benzamides with CO under mild conditions Acs National Meeting Book of Abstracts. |
0.657 |
|
| 2011 |
Vora HU, Rovis T. Asymmetric N-Heterocyclic carbene (NHC) catalyzed acyl anion reactions Aldrichimica Acta. 44: 3-11. |
0.664 |
|
| 2010 |
Moore JL, Rovis T. Carbene catalysts. Topics in Current Chemistry. 291: 77-144. PMID 21494949 DOI: 10.1007/978-3-642-02815-1_18 |
0.43 |
|
| 2010 |
Dalton DM, Rovis T. Organometallic chemistry: C-H carboxylation takes gold. Nature Chemistry. 2: 710-1. PMID 20729887 DOI: 10.1038/Nchem.815 |
0.756 |
|
| 2010 |
Hyster TK, Rovis T. Rhodium-catalyzed oxidative cycloaddition of benzamides and alkynes via C-H/N-H activation. Journal of the American Chemical Society. 132: 10565-9. PMID 20662529 DOI: 10.1021/Ja103776U |
0.755 |
|
| 2010 |
Filloux CM, Lathrop SP, Rovis T. Multicatalytic, asymmetric Michael/Stetter reaction of salicylaldehydes and activated alkynes. Proceedings of the National Academy of Sciences of the United States of America. 107: 20666-71. PMID 20639467 DOI: 10.1073/Pnas.1002830107 |
0.749 |
|
| 2010 |
Vora HU, Rovis T. N-Heterocyclic carbene catalyzed asymmetric hydration: direct synthesis of alpha-protio and alpha-deuterio alpha-chloro and alpha-fluoro carboxylic acids. Journal of the American Chemical Society. 132: 2860-1. PMID 20151675 DOI: 10.1021/Ja910281S |
0.559 |
|
| 2010 |
Miyake GM, DiRocco DA, Liu Q, Oberg KM, Bayram E, Finke RG, Rovis T, Chen EYX. Stereospecific polymerization of chiral oxazolidinone-functionalized alkenes Macromolecules. 43: 7504-7514. DOI: 10.1021/Ma101310N |
0.794 |
|
| 2010 |
Vora HU, Rovis T. ChemInform Abstract: N-Heterocyclic Carbene Catalyzed Asymmetric Hydration: Direct Synthesis of α-Protio and α-Deuterio α-Chloro and α-Fluoro Carboxylic Acids. Cheminform. 41: no-no. DOI: 10.1002/chin.201031028 |
0.561 |
|
| 2010 |
Evans DA, Sweeney ZK, Rovis T, Tedrow JS. ChemInform Abstract: Highly Enantioselective Syntheses of Homopropargylic Alcohols and Dihydrofurans Catalyzed by a Bis(oxazolinyl)pyridine-Scandium Triflate Complex. Cheminform. 33: no-no. DOI: 10.1002/chin.200218032 |
0.746 |
|
| 2010 |
Lautens M, Fagnou K, Taylor M, Rovis T. ChemInform Abstract: Rhodium-Catalyzed Asymmetric Ring Opening of Oxabicyclic Alkenes with Heteroatom Nucleophiles. Cheminform. 32: no-no. DOI: 10.1002/chin.200134120 |
0.737 |
|
| 2010 |
Evans DA, Rovis T, Johnson JS. ChemInform Abstract: Chiral Copper(II) Complexes as Lewis Acids for Catalyzed Cycloaddition, Carbonyl Addition, and Conjugate Addition Reactions Cheminform. 31: no-no. DOI: 10.1002/chin.200031287 |
0.716 |
|
| 2010 |
Lautens M, Rovis T. ChemInform Abstract: Hydroalumination of Carbon-Carbon Double Bonds Cheminform. 31: no-no. DOI: 10.1002/chin.200018249 |
0.379 |
|
| 2010 |
Lautens M, Rovis T. ChemInform Abstract: Selective Functionalization of 1,2-Dihydronaphthalenols Leads to a Concise, Stereoselective Synthesis of Sertraline. Cheminform. 30: no-no. DOI: 10.1002/chin.199946235 |
0.518 |
|
| 2010 |
LAUTENS M, ROVIS T. ChemInform Abstract: Scope of the Nickel Catalyzed Asymmetric Reductive Ring Opening Reaction. Synthesis of Enantiomerically Enriched Cyclohexenols. Cheminform. 29: no-no. DOI: 10.1002/chin.199823035 |
0.644 |
|
| 2010 |
LAUTENS M, ROVIS T. ChemInform Abstract: A New Route to the Enantioselective Synthesis of Cycloheptenols. Temperature Effects in the Asymmetric Reductive Ring Opening of [3.2.1] Oxabicycloalkenes. Cheminform. 29: no-no. DOI: 10.1002/chin.199810093 |
0.536 |
|
| 2010 |
LAUTENS M, ROVIS T. ChemInform Abstract: General Strategy Toward the Tetrahydronaphthalene Skeleton. An Expedient Total Synthesis of Sertraline. Cheminform. 28: no-no. DOI: 10.1002/chin.199752115 |
0.499 |
|
| 2010 |
LAUTENS M, CHIU P, MA S, ROVIS T. ChemInform Abstract: Nickel-Catalyzed Hydroalumination of Oxabicyclic Alkenes. Ligand Effects on the Regio- and Enantioselectivity. Cheminform. 26: no-no. DOI: 10.1002/chin.199527076 |
0.546 |
|
| 2010 |
Vora HU, Lathrop SP, Reynolds NT, Kerr MS, De Alaniz JR, Rovis T, Chennamadhavuni S, Davies HML. Preparation of chiral and achiral triazolium salts: Carbene precursors with demonstrated synthetic utility Organic Syntheses. 87: 350-361. DOI: 10.1002/0471264229.Os087.37 |
0.808 |
|
| 2009 |
Oberg KM, Lee EE, Rovis T. Regioselective rhodium-catalyzed intermolecular [2+2+2] cycloaddition of alkynes and isocyanates to form pyridones. Tetrahedron. 65: 5056-5061. PMID 21927511 DOI: 10.1016/J.Tet.2009.02.021 |
0.845 |
|
| 2009 |
Friedman RK, Oberg KM, Dalton DM, Rovis T. Phosphoramidite-Rhodium Complexes as Catalysts for the Asymmetric [2+2+2] Cycloaddition of Alkenyl Isocyanates and Alkynes. Pure and Applied Chemistry. Chimie Pure Et Appliquee. 82: 1353-1364. PMID 20622923 DOI: 10.1351/Pac-Con-09-12-09 |
0.844 |
|
| 2009 |
de Alaniz JR, Rovis T. The Catalytic Asymmetric Intramolecular Stetter Reaction. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 8: 1189-1207. PMID 20585467 DOI: 10.1055/S-0029-1216654 |
0.503 |
|
| 2009 |
Perreault S, Rovis T. Multi-component cycloaddition approaches in the catalytic asymmetric synthesis of alkaloid targets. Chemical Society Reviews. 38: 3149-59. PMID 19847348 DOI: 10.1039/B816702H |
0.513 |
|
| 2009 |
Dalton DM, Oberg KM, Yu RT, Lee EE, Perreault S, Oinen ME, Pease ML, Malik G, Rovis T. Enantioselective rhodium-catalyzed [2 + 2 + 2] cycloadditions of terminal alkynes and alkenyl isocyanates: mechanistic insights lead to a unified model that rationalizes product selectivity. Journal of the American Chemical Society. 131: 15717-28. PMID 19817441 DOI: 10.1021/Ja905065J |
0.828 |
|
| 2009 |
Oinen ME, Yu RT, Rovis T. Excess substrate is a spectator ligand in a rhodium-catalyzed asymmetric [2 + 2 + 2] cycloaddition of alkenyl isocyanates with tolanes. Organic Letters. 11: 4934-7. PMID 19803471 DOI: 10.1021/Ol9020805 |
0.72 |
|
| 2009 |
Lathrop SP, Rovis T. Asymmetric synthesis of functionalized cyclopentanones via a multicatalytic secondary amine/N-heterocyclic carbene catalyzed cascade sequence. Journal of the American Chemical Society. 131: 13628-30. PMID 19731910 DOI: 10.1021/Ja905342E |
0.735 |
|
| 2009 |
DiRocco DA, Oberg KM, Dalton DM, Rovis T. Catalytic asymmetric intermolecular stetter reaction of heterocyclic aldehydes with nitroalkenes: backbone fluorination improves selectivity. Journal of the American Chemical Society. 131: 10872-4. PMID 19722669 DOI: 10.1021/Ja904375Q |
0.843 |
|
| 2009 |
Yu RT, Friedman RK, Rovis T. Enantioselective rhodium-catalyzed [4+2+2] cycloaddition of dienyl isocyanates for the synthesis of bicyclic azocine rings. Journal of the American Chemical Society. 131: 13250-1. PMID 19711950 DOI: 10.1021/Ja906641D |
0.742 |
|
| 2009 |
Friedman RK, Rovis T. Predictable and regioselective insertion of internal unsymmetrical alkynes in rhodium-catalyzed cycloadditions with alkenyl isocyanates. Journal of the American Chemical Society. 131: 10775-82. PMID 19569692 DOI: 10.1021/Ja903899C |
0.531 |
|
| 2009 |
Liu Q, Rovis T. Enantio- and diastereoselective intermolecular Stetter reaction of glyoxamide and alkylidene ketoamides. Organic Letters. 11: 2856-9. PMID 19507841 DOI: 10.1021/Ol901081A |
0.555 |
|
| 2009 |
Galan BR, Rovis T. Beyond Reppe: building substituted arenes by [2+2+2] cycloadditions of alkynes. Angewandte Chemie (International Ed. in English). 48: 2830-4. PMID 19229917 DOI: 10.1002/Anie.200804651 |
0.409 |
|
| 2009 |
Yu RT, Lee EE, Malik G, Rovis T. Total synthesis of indolizidine alkaloid (-)-209D: overriding substrate bias in the asymmetric rhodium-catalyzed [2+2+2] cycloaddition. Angewandte Chemie (International Ed. in English). 48: 2379-82. PMID 19229912 DOI: 10.1002/Anie.200805455 |
0.704 |
|
| 2009 |
Rovis T, Yu R, Friedman R. Synthesis of Bicyclic Azocine Rings via Rh-Catalyzed [4+2+2] Cycloaddition Synfacts. 2009: 1355-1355. DOI: 10.1055/s-0029-1218313 |
0.671 |
|
| 2009 |
Cook MJ, Rovis T. Enantioselective rhodium-catalyzed alkylative desymmetrization of 3,5-dimethylglutaric anhydride Synthesis. 335-338. DOI: 10.1055/S-0028-1083275 |
0.764 |
|
| 2009 |
Johnson JB, Cook MJ, Rovis T. Ligand differentiated complementary Rh-catalyst systems for the enantioselective desymmetrization of meso-cyclic anhydrides Tetrahedron. 65: 3202-3210. DOI: 10.1016/J.Tet.2008.10.075 |
0.732 |
|
| 2008 |
Vora HU, Moncecchi JR, Epstein O, Rovis T. Nucleophilic carbene catalyzed synthesis of 1,2 amino alcohols via azidation of epoxy aldehydes. The Journal of Organic Chemistry. 73: 9727-31. PMID 18989930 DOI: 10.1021/Jo8020055 |
0.699 |
|
| 2008 |
Williams CM, Johnson JB, Rovis T. Nickel-catalyzed reductive carboxylation of styrenes using CO2. Journal of the American Chemical Society. 130: 14936-7. PMID 18928253 DOI: 10.1021/Ja8062925 |
0.764 |
|
| 2008 |
Liu Q, Perreault S, Rovis T. Catalytic asymmetric intermolecular Stetter reaction of glyoxamides with alkylidenemalonates. Journal of the American Chemical Society. 130: 14066-7. PMID 18834123 DOI: 10.1021/Ja805680Z |
0.568 |
|
| 2008 |
Cullen SC, Rovis T. Catalytic asymmetric stetter reaction onto vinylphosphine oxides and vinylphosphonates. Organic Letters. 10: 3141-4. PMID 18549233 DOI: 10.1021/Ol801047K |
0.473 |
|
| 2008 |
Orellana A, Rovis T. Towards the total synthesis of FD-838: modular enantioselective assembly of the core. Chemical Communications (Cambridge, England). 730-2. PMID 18478705 DOI: 10.1039/B716445A |
0.743 |
|
| 2008 |
de Alaniz JR, Kerr MS, Moore JL, Rovis T. Scope of the asymmetric intramolecular stetter reaction catalyzed by chiral nucleophilic triazolinylidene carbenes. The Journal of Organic Chemistry. 73: 2033-40. PMID 18302407 DOI: 10.1021/Jo702313F |
0.791 |
|
| 2008 |
Yu RT, Rovis T. Asymmetric synthesis of bicyclic amidines via rhodium-catalyzed [2+2+2] cycloaddition of carbodiimides. Journal of the American Chemical Society. 130: 3262-3. PMID 18302377 DOI: 10.1021/Ja710065H |
0.747 |
|
| 2008 |
Lee EE, Rovis T. Enantioselective synthesis of indolizidines bearing quaternary substituted stereocenters via rhodium-catalyzed [2+2+2] cycloaddition of alkenyl isocyanates and terminal alkynes. Organic Letters. 10: 1231-4. PMID 18284249 DOI: 10.1021/Ol800086S |
0.561 |
|
| 2008 |
Johnson JB, Rovis T. Enantioselective cross-coupling of anhydrides with organozinc reagents: the controlled formation of carbon-carbon bonds through the nucleophilic interception of metalacycles. Accounts of Chemical Research. 41: 327-38. PMID 18232665 DOI: 10.1021/Ar700176T |
0.534 |
|
| 2008 |
Nasveschuk CG, Rovis T. The [1, 3] O-to-C rearrangement: opportunities for stereoselective synthesis. Organic & Biomolecular Chemistry. 6: 240-54. PMID 18174990 DOI: 10.1039/B714881J |
0.733 |
|
| 2008 |
Nasveschuk CG, Rovis T. A diastereoselective ring contraction of 1,3-dioxepins to 2,3,4-trisubstituted and tetrasubstituted tetrahydrofurans. The Journal of Organic Chemistry. 73: 612-7. PMID 18088144 DOI: 10.1021/Jo702071V |
0.791 |
|
| 2008 |
Johnson JB, Rovis T. More than bystanders: the effect of olefins on transition-metal-catalyzed cross-coupling reactions. Angewandte Chemie (International Ed. in English). 47: 840-71. PMID 18081111 DOI: 10.1002/Anie.200700278 |
0.444 |
|
| 2008 |
Rovis T. Development of chiral bicyclic triazolium salt organic catalysts: The importance of the N-aryl substituent Chemistry Letters. 37: 2-7. DOI: 10.1246/Cl.2008.2 |
0.441 |
|
| 2008 |
Nasveschuk CG, Rovis T. A rapid total synthesis of (±)-sylvone Synlett. 0126-0128. DOI: 10.1055/S-2007-990926 |
0.712 |
|
| 2008 |
Yu RT, Rovis T. ChemInform Abstract: Asymmetric Synthesis of Bicyclic Amidines via Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition of Carbodiimides. Cheminform. 39. DOI: 10.1002/chin.200831169 |
0.712 |
|
| 2008 |
Nasveschuk CG, Rovis T. ChemInform Abstract: A Rapid Total Synthesis of (.+-.)-Sylvone. Cheminform. 39. DOI: 10.1002/chin.200822206 |
0.735 |
|
| 2007 |
Liu Q, Rovis T. Enantioselective Synthesis of Hydrobenzofuranones Using an Asymmetric Desymmetrizing Intramolecular Stetter Reaction of Cyclohexadienones. Organic Process Research & Development. 11: 598-604. PMID 19603085 DOI: 10.1021/op600278f |
0.46 |
|
| 2007 |
Rogers RL, Moore JL, Rovis T. Alkene-directed regioselective nickel-catalyzed cross-coupling of cyclic anhydrides with diorganozinc reagents. Angewandte Chemie (International Ed. in English). 46: 9301-4. PMID 17985335 DOI: 10.1002/Anie.200703124 |
0.425 |
|
| 2007 |
Nasveschuk CG, Frein JD, Jui NT, Rovis T. A diastereoselective intermolecular heck reaction of 1,3-dioxepins. Organic Letters. 9: 5099-102. PMID 17958436 DOI: 10.1021/Ol702294U |
0.829 |
|
| 2007 |
Vora HU, Rovis T. Nucleophilic carbene and HOAt relay catalysis in an amide bond coupling: an orthogonal peptide bond forming reaction. Journal of the American Chemical Society. 129: 13796-7. PMID 17929821 DOI: 10.1021/Ja0764052 |
0.687 |
|
| 2007 |
Cook MJ, Rovis T. Rhodium-catalyzed enantioselective desymmetrization of meso-3,5-dimethyl glutaric anhydride: a general strategy to syn-deoxypolypropionate synthons. Journal of the American Chemical Society. 129: 9302-3. PMID 17622150 DOI: 10.1021/Ja073269S |
0.726 |
|
| 2007 |
Johnson JB, Bercot EA, Williams CM, Rovis T. A concise synthesis of eupomatilones 4, 6, and 7 by rhodium-catalyzed enantioselective desymmetrization of cyclic meso anhydrides with organozinc reagents generated in situ. Angewandte Chemie (International Ed. in English). 46: 4514-8. PMID 17492814 DOI: 10.1002/Anie.200700816 |
0.857 |
|
| 2007 |
Johnson JB, Bercot EA, Rowley JM, Coates GW, Rovis T. Ligand-dependent catalytic cycle and role of styrene in nickel-catalyzed anhydride cross-coupling: evidence for turnover-limiting reductive elimination. Journal of the American Chemical Society. 129: 2718-25. PMID 17295486 DOI: 10.1021/Ja067845G |
0.827 |
|
| 2006 |
Frein JD, Rovis T. Surveying approaches to the formation of carbon-carbon bonds between a pyran and an adjacent ring. Tetrahedron. 62: 4573-4583. PMID 17710219 DOI: 10.1016/J.Tet.2006.02.042 |
0.797 |
|
| 2006 |
Epstein OL, Rovis T. A Sakurai-Prins-Ritter sequence for the three-component diastereoselective synthesis of 4-amino tetrahydropyrans. Journal of the American Chemical Society. 128: 16480-1. PMID 17177379 DOI: 10.1021/Ja066794K |
0.423 |
|
| 2006 |
Yu RT, Rovis T. Enantioselective rhodium-catalyzed [2+2+2] cycloaddition of alkenyl isocyanates and terminal alkynes: application to the total synthesis of (+)-lasubine II. Journal of the American Chemical Society. 128: 12370-1. PMID 16984159 DOI: 10.1021/Ja064868M |
0.709 |
|
| 2006 |
Johnson JB, Yu RT, Fink P, Bercot EA, Rovis T. Selective substituent transfer from mixed zinc reagents in Ni-catalyzed anhydride alkylation. Organic Letters. 8: 4307-10. PMID 16956213 DOI: 10.1021/Ol0616337 |
0.804 |
|
| 2006 |
Nasveschuk CG, Jui NT, Rovis T. A modular approach to the synthesis of 2,3,4-trisubstituted tetrahydrofurans. Chemical Communications (Cambridge, England). 3119-21. PMID 16855705 DOI: 10.1039/B605438B |
0.827 |
|
| 2006 |
Yu RT, Rovis T. Rhodium-catalyzed [2 + 2 + 2] cycloaddition of alkenyl isocyanates and alkynes. Journal of the American Chemical Society. 128: 2782-3. PMID 16506740 DOI: 10.1021/Ja057803C |
0.683 |
|
| 2006 |
Liu Q, Rovis T. Asymmetric synthesis of hydrobenzofuranones via desymmetrization of cyclohexadienones using the intramolecular Stetter reaction. Journal of the American Chemical Society. 128: 2552-3. PMID 16492036 DOI: 10.1021/Ja058337U |
0.568 |
|
| 2006 |
Rovis T, Yu R. Indolizinone and Quinolizinone via Asymmetric [2+2+2] Cycloaddition Synfacts. 2006: 1209-1209. DOI: 10.1055/s-2006-955576 |
0.687 |
|
| 2006 |
Rovis T, Liu Q. Asymmetric Synthesis of Hydrobenzofuranones via Enantioselective Stetter Reaction Synfacts. 2006: 0508-0508. DOI: 10.1055/s-2006-934454 |
0.483 |
|
| 2006 |
Rovis T. Quaternary Stereocenters: Challenges and Solutions for Organic Synthesis Edited by Jens Christoffers and Angelika Baro (Universität Stuttgart). Wiley-VCH Verlag GmbH & Co. KGA: Weinheim. 2005. xxiv + 336 pp. $170. ISBN 3-527-31107-6. Journal of the American Chemical Society. 128: 8095-8095. DOI: 10.1021/Ja0598917 |
0.329 |
|
| 2006 |
Moore JL, Kerr MS, Rovis T. Enantioselective formation of quaternary stereocenters using the catalytic intramolecular Stetter reaction Tetrahedron. 62: 11477-11482. DOI: 10.1016/J.Tet.2006.06.042 |
0.789 |
|
| 2006 |
Rovis T. Recent Advances in Catalytic Asymmetric Desymmetrization Reactions New Frontiers in Asymmetric Catalysis. 275-311. DOI: 10.1002/0470098007.ch10 |
0.381 |
|
| 2005 |
Reynolds NT, Rovis T. Enantioselective protonation of catalytically generated chiral enolates as an approach to the synthesis of alpha-chloroesters. Journal of the American Chemical Society. 127: 16406-7. PMID 16305222 DOI: 10.1021/Ja055918A |
0.819 |
|
| 2005 |
Kerr MS, Read de Alaniz J, Rovis T. An efficient synthesis of achiral and chiral 1,2,4-triazolium salts: bench stable precursors for N-heterocyclic carbenes. The Journal of Organic Chemistry. 70: 5725-8. PMID 15989360 DOI: 10.1021/Jo050645N |
0.836 |
|
| 2005 |
Nasveschuk CG, Rovis T. Regioselective Lewis acid-mediated [1,3] rearrangement of allylvinyl ethers. Organic Letters. 7: 2173-6. PMID 15901162 DOI: 10.1021/Ol0505151 |
0.767 |
|
| 2005 |
Read de Alaniz J, Rovis T. A highly enantio- and diastereoselective catalytic intramolecular Stetter reaction. Journal of the American Chemical Society. 127: 6284-9. PMID 15853335 DOI: 10.1021/Ja0425132 |
0.734 |
|
| 2005 |
Nasveschuk CG, Rovis T. Stereoselective Lewis acid mediated [1,3] ring contraction of 2,5-dihydrooxepins as a route to polysubstituted cyclopentenes. Angewandte Chemie (International Ed. in English). 44: 3264-7. PMID 15844118 DOI: 10.1002/Anie.200500088 |
0.735 |
|
| 2005 |
Bercot EA, Rovis T. Highly efficient nickel-catalyzed cross-coupling of succinic and glutaric anhydrides with organozinc reagents. Journal of the American Chemical Society. 127: 247-54. PMID 15631474 DOI: 10.1021/Ja044588B |
0.83 |
|
| 2005 |
Bercot EA, Kindrachuk DE, Rovis T. Complementary diastereoselective reduction of cyclic gamma-keto acids: efficient access to trisubsituted gamma-lactones. Organic Letters. 7: 107-10. PMID 15624989 DOI: 10.1021/Ol047821J |
0.785 |
|
| 2005 |
Rovis T, Reynolds N. Organocatalytic Asymmetric Synthesis of α-Chloroesters Synfacts. 2006: 0078-0078. DOI: 10.1055/s-2005-921718 |
0.788 |
|
| 2005 |
Reynolds NT, Rovis T. The effect of pre-existing stereocenters in the intramolecular asymmetric Stetter reaction Tetrahedron. 61: 6368-6378. DOI: 10.1016/J.Tet.2005.03.121 |
0.85 |
|
| 2005 |
Bercot EA, Kindrachuk DE, Rovis T. Complementary Diastereoselective Reduction of Cyclic ?-Keto Acids: Efficient Access to Trisubstituted ?-Lactones. Cheminform. 36. DOI: 10.1002/chin.200517114 |
0.782 |
|
| 2004 |
Zhang Y, Rovis T. A unique catalyst effects the rapid room-temperature cross-coupling of organozinc reagents with carboxylic acid fluorides, chlorides, anhydrides, and thioesters. Journal of the American Chemical Society. 126: 15964-5. PMID 15584721 DOI: 10.1021/Ja044113K |
0.458 |
|
| 2004 |
Bercot EA, Rovis T. A palladium-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides. Journal of the American Chemical Society. 126: 10248-9. PMID 15315429 DOI: 10.1021/Ja046528B |
0.825 |
|
| 2004 |
Reynolds NT, Read de Alaniz J, Rovis T. Conversion of alpha-haloaldehydes into acylating agents by an internal redox reaction catalyzed by nucleophilic carbenes. Journal of the American Chemical Society. 126: 9518-9. PMID 15291537 DOI: 10.1021/Ja046991O |
0.834 |
|
| 2004 |
Kerr MS, Rovis T. Enantioselective synthesis of quaternary stereocenters via a catalytic asymmetric Stetter reaction. Journal of the American Chemical Society. 126: 8876-7. PMID 15264801 DOI: 10.1021/Ja047644H |
0.791 |
|
| 2004 |
Zhang Y, Rovis T. Use of acid fluorides increases the scope of the reductive acylation of esters. Organic Letters. 6: 1877-9. PMID 15151437 DOI: 10.1021/Ol049333H |
0.421 |
|
| 2003 |
O'Brien EM, Bercot EA, Rovis T. Decarbonylative cross-coupling of cyclic anhydrides: introducing stereochemistry at an sp3 carbon in the cross-coupling event. Journal of the American Chemical Society. 125: 10498-9. PMID 12940714 DOI: 10.1021/Ja036290B |
0.767 |
|
| 2003 |
Kerr MS, Rovis T. Effect of the Michael Acceptor in the Asymmetric Intramolecular Stetter Reaction Synlett. 1934-1936. DOI: 10.1055/S-2003-41458 |
0.763 |
|
| 2003 |
Zhang Y, Rovis T. 1,3-Polyol arrays via the stereoselective rearrangement of vinyl acetals Tetrahedron. 59: 8979-8987. DOI: 10.1016/J.Tet.2003.03.004 |
0.431 |
|
| 2002 |
Kerr MS, Read de Alaniz J, Rovis T. A highly enantioselective catalytic intramolecular Stetter reaction. Journal of the American Chemical Society. 124: 10298-9. PMID 12197730 DOI: 10.1021/Ja027411V |
0.844 |
|
| 2002 |
Zhang Y, Reynolds NT, Manju K, Rovis T. Stereoretentive O-to-C rearrangement of vinyl acetals: solvent cage effects as a stereocontrol element. Journal of the American Chemical Society. 124: 9720-1. PMID 12175226 DOI: 10.1021/Ja026972J |
0.812 |
|
| 2002 |
Bercot EA, Rovis T. A mild and efficient catalytic alkylative monofunctionalization of cyclic anhydrides. Journal of the American Chemical Society. 124: 174-5. PMID 11782160 DOI: 10.1021/Ja017086W |
0.85 |
|
| 2001 |
Evans DA, Sweeney ZK, Rovis T, Tedrow JS. Highly enantioselective syntheses of homopropargylic alcohols and dihydrofurans catalyzed by a bis(oxazolinyl)pyridine-scandium triflate complex. Journal of the American Chemical Society. 123: 12095-6. PMID 11724622 DOI: 10.1021/Ja011983I |
0.757 |
|
| 2001 |
Lautens M, Fagnou K, Taylor M, Rovis T. Rhodium-catalysed asymmetric ring opening of oxabicyclic alkenes with heteroatom nucleophiles Journal of Organometallic Chemistry. 624: 259-270. DOI: 10.1016/S0022-328X(00)00904-9 |
0.767 |
|
| 2001 |
Evans DA, Rovis T, Kozlowski MC, Downey CW, Tedrow JS. ChemInform Abstract: Enantioselective Lewis Acid Catalyzed Michael Reactions of Alkylidene Malonates. Catalysis by C2-Symmetric Bis(oxazoline) Copper(II) Complexes in the Synthesis of Chiral, Differentiated Glutarate Esters. Cheminform. 32: no-no. DOI: 10.1002/chin.200103030 |
0.852 |
|
| 2001 |
Rovis T, Evans DA. Structural and mechanistic investigations in asymmetric copper(I) and copper(II) catalyzed reactions Progress in Inorganic Chemistry. 50: 1-150. |
0.55 |
|
| 2000 |
Evans DA, Rovis T, Kozlowski MC, Downey CW, Tedrow JS. Enantioselective Lewis acid catalyzed Michael reactions of alkylidene malonates. Catalysis by C2-symmetric bis(oxazoline) copper(II) complexes in the synthesis of chiral, differentiated glutarate esters Journal of the American Chemical Society. 122: 9134-9142. DOI: 10.1021/Ja002246+ |
0.854 |
|
| 2000 |
Lautens M, Fagnou K, Rovis T. Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene: A new enantioselective carbon-heteroatom bond forming process [8] Journal of the American Chemical Society. 122: 5650-5651. DOI: 10.1021/Ja000134C |
0.715 |
|
| 2000 |
Lautens M, Fagnou K, Rovis T. ChemInform Abstract: Rhodium-Catalyzed Asymmetric Alcoholysis and Aminolysis of Oxabenzonorbornadiene: A New Enantioselective Carbon-Heteroatom Bond Forming Process. Cheminform. 31: no-no. DOI: 10.1002/chin.200040088 |
0.697 |
|
| 1999 |
Evans DA, Rovis T, Johnson JS. Chiral copper(∥) complexes as Lewis acids for catalyzed cycloaddition, carbonyl addition, and conjugate addition reactions Pure and Applied Chemistry. 71: 1407-1415. DOI: 10.1351/Pac199971081407 |
0.699 |
|
| 1999 |
Evans DA, Rovis T, Kozlowski MC, Tedrow JS. C2-symmetric Cu(II) complexes as chiral Lewis acids. Catalytic enantioselective Michael addition of silylketene acetals to alkylidene malonates [21] Journal of the American Chemical Society. 121: 1994-1995. DOI: 10.1021/Ja983864H |
0.77 |
|
| 1999 |
Lautens M, Rovis T. Selective functionalization of 1,2-dihydronaphthalenols leads to a concise, stereoselective synthesis of sertraline Tetrahedron. 55: 8967-8976. DOI: 10.1016/S0040-4020(99)00456-1 |
0.564 |
|
| 1998 |
Lautens M, Rovis T, Smith ND, Ostrovsky D. Metal catalyzed hydrometalations and their applications in synthesis Pure and Applied Chemistry. 70: 1059-1064. DOI: 10.1351/Pac199870051059 |
0.627 |
|
| 1998 |
Lautens M, Rovis T. Scope of the nickel catalyzed asymmetric reductive ring opening reaction. Synthesis of enantiomerically enriched cyclohexenols Tetrahedron. 54: 1107-1116. DOI: 10.1016/S0040-4020(97)10211-3 |
0.612 |
|
| 1997 |
Lautens M, Rovis T. General strategy toward the tetrahydronaphthalene skeleton. An expedient total synthesis of sertraline Journal of Organic Chemistry. 62: 5246-5247. DOI: 10.1021/Jo971115X |
0.55 |
|
| 1997 |
Lautens M, Rovis T. A new route to the enantioselective synthesis of cycloheptenols. Temperature effects in the asymmetric reductive ring opening [3.2.1] oxabicycloalkenes Journal of the American Chemical Society. 119: 11090-11091. DOI: 10.1021/Ja971770M |
0.586 |
|
| 1995 |
Lautens M, Chiu P, Ma S, Rovis T. Nickel-Catalyzed Hydroalumination of Oxabicyclic Alkenes. Ligand Effects on the Regio- and Enantioselectivity Journal of the American Chemical Society. 117: 532-533. DOI: 10.1021/Ja00106A062 |
0.689 |
|
| 1995 |
Lautens M, Chiu P, Ma S, Rovis T. Nickel-catalyzed hydroalumination of oxabicyclic alkenes. Ligand effects on the regio- and enantioselectivity Journal of the American Chemical Society. 117: 532-533. |
0.33 |
|
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