Munetaka Akita - Publications

Affiliations: 
Research Laboratory of Resources Utilization Tokyo Institute of Technology, Yokohama-shi, Kanagawa-ken, Japan 

268 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2020 Kishida N, Matsumoto K, Tanaka Y, Akita M, Sakurai H, Yoshizawa M. Anisotropic Contraction of a Polyaromatic Capsule and its Cavity-induced Compression Effect. Journal of the American Chemical Society. PMID 32369355 DOI: 10.1021/Jacs.0C02932  0.326
2020 Tanaka S, Nakayama Y, Konishi Y, Koike T, Akita M. Fluoroalkanesulfinate Salts as Dual Fluoroalkyl and SO Sources: Atom-Economical Fluoroalkyl-Sulfonylation of Alkenes and Alkynes by Photoredox Catalysis. Organic Letters. PMID 32207628 DOI: 10.1021/Acs.Orglett.0C00789  0.302
2020 Matsushita Y, Ochi R, Tanaka Y, Koike T, Akita M. Energy transfer-driven regioselective synthesis of functionalized phenanthridines by visible-light Ir photocatalysis Organic Chemistry Frontiers. 7: 1243-1248. DOI: 10.1039/D0Qo00271B  0.337
2019 Satoh Y, Catti L, Akita M, Yoshizawa M. A Redox-Active Heterocyclic Capsule: Radical Generation, Oxygenation, and Guest Uptake/Release. Journal of the American Chemical Society. PMID 31287679 DOI: 10.1021/Jacs.9B03419  0.343
2019 Osawa M, Yamayoshi H, Hoshino M, Tanaka Y, Akita M. Luminescence color alteration induced by trapped solvent molecules in crystals of tetrahedral gold(i) complexes: near-unity luminescence mixed with thermally activated delayed fluorescence and phosphorescence. Dalton Transactions (Cambridge, England : 2003). PMID 31086891 DOI: 10.1039/C9Dt01373C  0.328
2019 Koike T, Akita M. Recent progress in photochemical radical di- and mono-fluoromethylation. Organic & Biomolecular Chemistry. PMID 31086872 DOI: 10.1039/C9Ob00734B  0.313
2019 Oyama Y, Kawano R, Tanaka Y, Akita M. Dinuclear ruthenium acetylide complexes with diethynylated anthrahydroquinone and anthraquinone frameworks: a multi-stimuli-responsive organometallic switch. Dalton Transactions (Cambridge, England : 2003). PMID 31066424 DOI: 10.1039/C9Dt01255A  0.355
2019 Matsumoto K, Kusaba S, Tanaka Y, Sei Y, Akita M, Aritani K, Haga MA, Yoshizawa M. A Peanut-Shaped Polyaromatic Capsule: Solvent-Dependent Transformation and Electronic Properties of a Non-Contacted Fullerene Dimer. Angewandte Chemie (International Ed. in English). PMID 30993796 DOI: 10.1002/Anie.201903117  0.326
2019 Tsutsui T, Kusaba S, Yamashina M, Akita M, Yoshizawa M. Open vs. Closed Polyaromatic Nanocavity: Enhanced Host Abilities for Large Dyes and Pigments. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30667102 DOI: 10.1002/Chem.201806409  0.316
2019 Noto N, Koike T, Akita M. Visible-Light-Triggered Monofluoromethylation of Alkenes by Strongly Reducing 1,4-Bis(diphenylamino)naphthalene Photoredox Catalysis Acs Catalysis. 9: 4382-4387. DOI: 10.1021/Acscatal.9B00473  0.316
2019 Agake S, Komatsuzaki H, Satoh M, Agou T, Tanaka Y, Akita M, Nakazawa J, Hikichi S. A monomeric manganese(II) catecholato complex: Synthesis, crystal structure, and reactivity toward molecular oxygen Inorganica Chimica Acta. 484: 424-429. DOI: 10.1016/J.Ica.2018.09.013  0.416
2019 Tanaka Y, Akita M. Organometallic radicals of iron and ruthenium: Similarities and dissimilarities of radical reactivity and charge delocalization Coordination Chemistry Reviews. 388: 334-342. DOI: 10.1016/J.Ccr.2019.02.036  0.441
2018 Yamashina M, Kusaba S, Akita M, Kikuchi T, Yoshizawa M. Cramming versus threading of long amphiphilic oligomers into a polyaromatic capsule. Nature Communications. 9: 4227. PMID 30315217 DOI: 10.1038/S41467-018-06458-W  0.36
2018 Osawa M, Aino MA, Nagakura T, Hoshino M, Tanaka Y, Akita M. Near-unity thermally activated delayed fluorescence efficiency in three- and four-coordinate Au(i) complexes with diphosphine ligands. Dalton Transactions (Cambridge, England : 2003). PMID 29756141 DOI: 10.1039/C8Dt01097H  0.422
2018 Kai T, Kishimoto M, Akita M, Yoshizawa M. Encapsulation-induced emission enhancement (EIEE) of Eu(iii)-complexes by aromatic micelles in water. Chemical Communications (Cambridge, England). PMID 29319083 DOI: 10.1039/C7Cc09450G  0.314
2018 Tanaka Y, Ono M, Akita M. An Organometallic Molecular Wire Bearing a Manganese Porphyrin Linker: Coordination-driven Modulation of the Metal-Metal Interaction Chemistry Letters. 47: 1296-1299. DOI: 10.1246/Cl.180592  0.315
2018 Miyazawa K, Ochi R, Koike T, Akita M. Photoredox radical C–H oxygenation of aromatics with aroyloxylutidinium salts Organic Chemistry Frontiers. 5: 1406-1410. DOI: 10.1039/C8Qo00089A  0.347
2018 Noto N, Tanaka Y, Koike T, Akita M. Strongly Reducing (Diarylamino)anthracene Catalyst for Metal-Free Visible-Light Photocatalytic Fluoroalkylation Acs Catalysis. 8: 9408-9419. DOI: 10.1021/Acscatal.8B02885  0.326
2018 Tanaka Y, Akita M. Synthesis and intramolecular electronic interactions of hexaarylbenzene bearing redox-active Cp*(dppe)Fe-C≡C- termini Journal of Organometallic Chemistry. 878: 30-37. DOI: 10.1016/J.Jorganchem.2018.10.002  0.382
2017 Phungsripheng S, Akita M, Inagaki A. Substituent Effect of the Bridging Ligand in the Trinuclear Ru Complexes on Photocatalytic Oxygenation of a Sulfide and Alkenes. Inorganic Chemistry. PMID 29058883 DOI: 10.1021/Acs.Inorgchem.7B01764  0.406
2017 Noto N, Koike T, Akita M. Metal-free di- and tri-fluoromethylation of alkenes realized by visible-light-induced perylene photoredox catalysis. Chemical Science. 8: 6375-6379. PMID 28989669 DOI: 10.1039/C7Sc01703K  0.325
2017 Yamashina M, Akita M, Hasegawa T, Hayashi S, Yoshizawa M. A polyaromatic nanocapsule as a sucrose receptor in water. Science Advances. 3: e1701126. PMID 28875169 DOI: 10.1126/Sciadv.1701126  0.305
2017 Yazaki K, Akita M, Prusty S, Chand DK, Kikuchi T, Sato H, Yoshizawa M. Polyaromatic molecular peanuts. Nature Communications. 8: 15914. PMID 28656977 DOI: 10.1038/Ncomms15914  0.352
2017 Mishiba K, Ono M, Tanaka Y, Akita M. A Fully Charge-Delocalized Two-Dimensional Porphyrin System with Two Different Class III States. Chemistry (Weinheim An Der Bergstrasse, Germany). 23: 2067-2076. PMID 27785838 DOI: 10.1002/Chem.201604455  0.322
2017 Sugimoto K, Idei H, Tanaka Y, Akita M. Synthesis and charge delocalization property of multimetallic molecular wires with diethynylthiophene bridges Journal of Organometallic Chemistry. 847: 121-131. DOI: 10.1016/J.Jorganchem.2017.02.033  0.319
2017 Koike T, Akita M. New Horizons of Photocatalytic Fluoromethylative Difunctionalization of Alkenes Chem. 4: 409-437. DOI: 10.1016/J.Chempr.2017.11.004  0.325
2017 Li Y, Koike T, Akita M. Photocatalytic Trifluoromethylthiolation of Aromatic Alkenes Associated with Hydroxylation and Alkoxylation Asian Journal of Organic Chemistry. 6: 445-448. DOI: 10.1002/Ajoc.201600562  0.321
2016 Yazaki K, Noda S, Tanaka Y, Sei Y, Akita M, Yoshizawa M. An M2 L4 Molecular Capsule with a Redox Switchable Polyradical Shell. Angewandte Chemie (International Ed. in English). PMID 27791308 DOI: 10.1002/Anie.201608350  0.325
2016 Yazaki K, Sei Y, Akita M, Yoshizawa M. Polycationic-Shelled Capsular and Tubular Nanostructures and Their Anionic-Guest Binding Properties. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27685890 DOI: 10.1002/Chem.201604384  0.339
2016 Koike T, Akita M. Fine Design of Photoredox Systems for Catalytic Fluoromethylation of Carbon-Carbon Multiple Bonds. Accounts of Chemical Research. 49: 1937-45. PMID 27564676 DOI: 10.1021/Acs.Accounts.6B00268  0.344
2016 Ahmedova A, Mihaylova R, Momekova D, Shestakova P, Stoykova S, Zaharieva J, Yamashina M, Momekov G, Akita M, Yoshizawa M. M2L4 coordination capsules with tunable anticancer activity upon guest encapsulation. Dalton Transactions (Cambridge, England : 2003). PMID 27488015 DOI: 10.1039/C6Dt01801G  0.318
2016 Yamashina M, Matsuno S, Sei Y, Akita M, Yoshizawa M. Recognition of Multiple Methyl Groups on Aromatic Rings by a Polyaromatic Cavity. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27441895 DOI: 10.1002/Chem.201603032  0.322
2016 Phungsripheng S, Kozawa K, Akita M, Inagaki A. Photocatalytic Oxygenation of Sulfide and Alkenes by Trinuclear Ruthenium Clusters. Inorganic Chemistry. 55: 3750-8. PMID 27014848 DOI: 10.1021/Acs.Inorgchem.5B02518  0.398
2016 Sugimoto K, Tanaka Y, Fujii S, Tada T, Kiguchi M, Akita M. Organometallic molecular wires as versatile modules for energy-level alignment of the metal-molecule-metal junction. Chemical Communications (Cambridge, England). 52: 5796-9. PMID 26996138 DOI: 10.1039/C6Cc01705C  0.33
2016 Li Y, Koike T, Akita M. Radical Pentafluorosulfanylphenylation of Styrenes by Photoredox Catalysis Synlett. 27: 736-740. DOI: 10.1055/S-0035-1561304  0.341
2016 Koike T, Akita M. A versatile strategy for difunctionalization of carbon–carbon multiple bonds by photoredox catalysis Organic Chemistry Frontiers. 3: 1345-1349. DOI: 10.1039/C6Qo00139D  0.314
2016 Miyazawa K, Koike T, Akita M. Aminohydroxylation of olefins with iminopyridinium ylides by dual Ir photocatalysis and Sc(OTf)3 catalysis Tetrahedron. 72: 7813-7820. DOI: 10.1016/J.Tet.2016.05.045  0.329
2015 Omagari T, Suzuki A, Akita M, Yoshizawa M. Efficient Catalytic Epoxidation in Water by Axial N-Ligand-Free Mn-Porphyrins within a Micellar Capsule. Journal of the American Chemical Society. PMID 26709834 DOI: 10.1021/Jacs.5B11665  0.321
2015 Arai Y, Tomita R, Ando G, Koike T, Akita M. Oxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF2H-Containing Alcohols. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26639021 DOI: 10.1002/Chem.201504838  0.31
2015 Tomita R, Koike T, Akita M. Photoredox-Catalyzed Stereoselective Conversion of Alkynes into Tetrasubstituted Trifluoromethylated Alkenes. Angewandte Chemie (International Ed. in English). 54: 12923-7. PMID 26360134 DOI: 10.1002/Anie.201505550  0.32
2015 Noto N, Miyazawa K, Koike T, Akita M. Anti-Diastereoselective Synthesis of CF3-Containing Spirooxazolines and Spirooxazines via Regiospecific Trifluoromethylative Spirocyclization by Photoredox Catalysis. Organic Letters. 17: 3710-3. PMID 26181341 DOI: 10.1021/Acs.Orglett.5B01694  0.314
2015 Miyazawa K, Koike T, Akita M. Regiospecific Intermolecular Aminohydroxylation of Olefins by Photoredox Catalysis. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 11677-80. PMID 26179746 DOI: 10.1002/Chem.201501590  0.375
2015 Yamashina M, Sartin MM, Sei Y, Akita M, Takeuchi S, Tahara T, Yoshizawa M. Preparation of Highly Fluorescent Host-Guest Complexes with Tunable Color upon Encapsulation. Journal of the American Chemical Society. 137: 9266-9. PMID 26166243 DOI: 10.1021/Jacs.5B06195  0.332
2015 Yamashina M, Yuki T, Sei Y, Akita M, Yoshizawa M. Anisotropic expansion of an M2L4 coordination capsule: host capability and frame rearrangement. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 4200-4. PMID 25677602 DOI: 10.1002/Chem.201406445  0.325
2015 Tanaka Y, Ono M, Akita M. Synthesis and wire-like performance of diruthenium molecular wire with a C≡C-porphyrin-C≡C linker Journal of Porphyrins and Phthalocyanines. 19: 442-450. DOI: 10.1142/S1088424615500352  0.381
2015 Chinzei T, Miyazawa K, Yasu Y, Koike T, Akita M. Redox-economical radical generation from organoborates and carboxylic acids by organic photoredox catalysis Rsc Advances. 5: 21297-21300. DOI: 10.1039/C5Ra01826A  0.321
2015 Li Y, Miyazawa K, Koike T, Akita M. Alkyl- and aryl-thioalkylation of olefins with organotrifluoroborates by photoredox catalysis Organic Chemistry Frontiers. 2: 319-323. DOI: 10.1039/C4Qo00352G  0.355
2015 Shiba Y, Inagaki A, Akita M. C-C Bond Forming Reductive Elimination from Diarylplatinum Complexes Driven by Visible-Light-Mediated Photoredox Reactions Organometallics. 34: 4844-4853. DOI: 10.1021/Om501080V  0.418
2015 Tanaka Y, Ishisaka T, Koike T, Akita M. Synthesis and properties of diiron complexes with heteroaromatic linkers: An approach for modulation of organometallic molecular wire Polyhedron. 86: 105-110. DOI: 10.1016/J.Poly.2014.05.080  0.421
2015 Asano M, Tomita R, Koike T, Akita M. Trifluoromethylation of aromatic alkenes by visible-light-driven photoredox catalysis: Direct conversion of alkenes to 3-trifluoromethyl-1-propenyl and 1,3-bis(trifluoromethyl)-1-propenyl derivatives Journal of Fluorine Chemistry. DOI: 10.1016/J.Jfluchem.2015.07.020  0.345
2014 Tomita R, Yasu Y, Koike T, Akita M. Direct C-H trifluoromethylation of di- and trisubstituted alkenes by photoredox catalysis. Beilstein Journal of Organic Chemistry. 10: 1099-106. PMID 24991259 DOI: 10.3762/Bjoc.10.108  0.327
2014 Kishi N, Akita M, Yoshizawa M. Selective host-guest interactions of a transformable coordination capsule/tube with fullerenes. Angewandte Chemie (International Ed. in English). 53: 3604-7. PMID 24590625 DOI: 10.1002/Anie.201311251  0.355
2014 Mukuta T, Fukazawa N, Murata K, Inagaki A, Akita M, Tanaka S, Koshihara SY, Onda K. Infrared vibrational spectroscopy of [Ru(bpy)2(bpm)]2+ and [Ru(bpy)3]2+ in the excited triplet state. Inorganic Chemistry. 53: 2481-90. PMID 24528148 DOI: 10.1021/Ic402474T  0.329
2014 Kozawa K, Inagaki A, Akita M. Synthesis of Highly Conjugated Dinuclear Ru Complexes Bridged by a Novel N2–N3 Ligand and Their Application in Photocatalytic Oxygenation of Sulfides Chemistry Letters. 43: 290-292. DOI: 10.1246/Cl.130966  0.415
2014 Koike T, Akita M. Visible-light radical reaction designed by Ru- and Ir-based photoredox catalysis Inorganic Chemistry Frontiers. 1: 562-576. DOI: 10.1039/C4Qi00053F  0.363
2014 Cai Z, Su H, Nakayama Y, Shiono T, Akita M. Synthesis of C1symmetrical ansa-cyclopentadienylamidotitanium complexes and their application for living polymerization of propylene Journal of Organometallic Chemistry. 770: 136-141. DOI: 10.1016/J.Jorganchem.2014.08.019  0.335
2014 Yasu Y, Inagaki A, Akita M. Synthesis of trinuclear Pd–Ru–Pd porphyrin complexes with axially ligated Pd centers. Prominent metal-to-ligand charge transfer band in the visible region Journal of Organometallic Chemistry. 753: 48-54. DOI: 10.1016/J.Jorganchem.2013.12.008  0.376
2014 Koike T, Akita M. Recent progress in transition-metal-catalyzed trifluoromethylation of olefins using electrophilic CF3 reagents Journal of Fluorine Chemistry. 167: 30-36. DOI: 10.1016/J.Jfluchem.2014.06.025  0.318
2014 Miyazawa K, Koike T, Akita M. Hydroaminomethylation of Olefins with Aminomethyltrifluoroborate by Photoredox Catalysis Advanced Synthesis and Catalysis. 342. DOI: 10.1002/Adsc.201400556  0.316
2013 Murai M, Sugimoto M, Akita M. Zinc-porphyrins functionalized with redox-active metal peripherals: enhancement of dπ-pπ interaction leading to unique assembly and redox-triggered remote switching of fluorescence. Dalton Transactions (Cambridge, England : 2003). 42: 16108-20. PMID 24008592 DOI: 10.1039/C3Dt51675J  0.371
2013 Kishi N, Akita M, Kamiya M, Hayashi S, Hsu HF, Yoshizawa M. Facile catch and release of fullerenes using a photoresponsive molecular tube. Journal of the American Chemical Society. 135: 12976-9. PMID 23957216 DOI: 10.1021/Ja406893Y  0.527
2013 Murata K, Inagaki A, Akita M, Halet JF, Costuas K. Revelation of the photoactive species in the photocatalytic dimerization of α-methylstyrene by a dinuclear ruthenium-palladium complex. Inorganic Chemistry. 52: 8030-9. PMID 23790155 DOI: 10.1021/Ic400666V  0.363
2013 Komatsuzaki H, Shiota A, Hazawa S, Itoh M, Miyamura N, Miki N, Takano Y, Nakazawa J, Inagaki A, Akita M, Hikichi S. Manganese(II) semiquinonato and manganese(III) catecholato complexes with tridentate ligand: modeling the substrate-binding state of manganese-dependent catechol dioxygenase and reactivity with molecular oxygen. Chemistry, An Asian Journal. 8: 1115-9. PMID 23512755 DOI: 10.1002/Asia.201300029  0.384
2013 Murata K, Araki M, Inagaki A, Akita M. Syntheses, photophysical properties, and reactivities of novel bichromophoric Pd complexes composed of Ru(II)-polypyridyl and naphthyl moieties. Dalton Transactions (Cambridge, England : 2003). 42: 6989-7001. PMID 23512115 DOI: 10.1039/C3Dt50266J  0.397
2013 Kishi N, Li Z, Sei Y, Akita M, Yoza K, Siegel JS, Yoshizawa M. Wide-ranging host capability of a Pd(II)-linked M2L4 molecular capsule with an anthracene shell. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 6313-20. PMID 23508693 DOI: 10.1002/Chem.201204010  0.326
2013 Yasu Y, Koike T, Akita M. Visible-light-induced synthesis of a variety of trifluoromethylated alkenes from potassium vinyltrifluoroborates by photoredox catalysis. Chemical Communications (Cambridge, England). 49: 2037-9. PMID 23380942 DOI: 10.1039/C3Cc39235J  0.32
2013 Hikichi S, Hanaue K, Fujimura T, Okuda H, Nakazawa J, Ohzu Y, Kobayashi C, Akita M. Characterization of nickel(II)-acylperoxo species relevant to catalytic alkane hydroxylation by nickel complex with mCPBA. Dalton Transactions (Cambridge, England : 2003). 42: 3346-56. PMID 23223606 DOI: 10.1039/C2Dt32419A  0.486
2013 Koike T, Akita M. Visible-Light-Induced Photoredox Catalysis: An Easy Access to Green Radical Chemistry Synlett. 24: 2492-2505. DOI: 10.1055/S-0033-1339874  0.361
2012 Li Z, Kishi N, Yoza K, Akita M, Yoshizawa M. Isostructural M2L4 molecular capsules with anthracene shells: synthesis, crystal structures, and fluorescent properties. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 8358-65. PMID 22639389 DOI: 10.1002/Chem.201200155  0.304
2012 Ordronneau L, Nitadori H, Ledoux I, Singh A, Williams JA, Akita M, Guerchais V, Le Bozec H. Photochromic metal complexes: photoregulation of both the nonlinear optical and luminescent properties. Inorganic Chemistry. 51: 5627-36. PMID 22545780 DOI: 10.1021/Ic2025457  0.379
2012 Yasu Y, Koike T, Akita M. Sunlight-driven synthesis of γ-diketones via oxidative coupling of enamines with silyl enol ethers catalyzed by [Ru(bpy)3]2+. Chemical Communications (Cambridge, England). 48: 5355-7. PMID 22510814 DOI: 10.1039/C2Cc31748F  0.335
2012 Nitadori H, Takahashi T, Inagaki A, Akita M. Enhanced photocatalytic activity of α-methylstyrene oligomerization through effective metal-to-ligand charge-transfer localization on the bridging ligand. Inorganic Chemistry. 51: 51-62. PMID 22142429 DOI: 10.1021/Ic200291T  0.395
2012 Li H, Koike T, Akita M. Color change of redox-active organometallic dithienylethene complexes by photochemical and redox processes Dyes and Pigments. 92: 854-860. DOI: 10.1016/J.Dyepig.2011.03.029  0.453
2011 Motoyama K, Li H, Koike T, Hatakeyama M, Yokojima S, Nakamura S, Akita M. Photo- and electro-chromic organometallics with dithienylethene (DTE) linker, L2CpM-DTE-MCpL2: dually stimuli-responsive molecular switch. Dalton Transactions (Cambridge, England : 2003). 40: 10643-57. PMID 21927723 DOI: 10.1039/C1Dt10727E  0.455
2011 Johno K, Tanaka Y, Koike T, Akita M. Making organometallic molecular wires via oxidative ligand coupling. Dalton Transactions (Cambridge, England : 2003). 40: 8089-91. PMID 21766133 DOI: 10.1039/C1Dt11077B  0.341
2011 Kishi N, Li Z, Yoza K, Akita M, Yoshizawa M. An M2L4 molecular capsule with an anthracene shell: encapsulation of large guests up to 1 nm. Journal of the American Chemical Society. 133: 11438-41. PMID 21707060 DOI: 10.1021/Ja2037029  0.301
2011 Gondoh A, Koike T, Akita M. 3,5-Bis(diphenylphosphinoethyl)pyrazolate ligand (PNNPC2) and its dirhodium complexes: Comparison with related quadridentate dinucleating diphenylphosphinomethyl (PNNPPy) and phthalazine derivatives (PNNPPh) Inorganica Chimica Acta. 374: 489-498. DOI: 10.1016/J.Ica.2011.02.040  0.459
2010 Hikichi S, Kobayashi C, Yoshizawa M, Akita M. Tuning the stability and reactivity of metal-bound alkylperoxide by remote site substitution of the ligand. Chemistry, An Asian Journal. 5: 2086-92. PMID 20589827 DOI: 10.1002/Asia.201000183  0.419
2010 Tanaka Y, Ishisaka T, Inagaki A, Koike T, Lapinte C, Akita M. Photochromic organometallics with a dithienylethene (DTE) Bridge, [Y-C[triple bond]C-DTE-C[triple bond]C-Y] (Y={MCp*(dppe)}): photoswitchable molecular wire (M=Fe) versus dual photo- and electrochromism (M=Ru). Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 4762-76. PMID 20391579 DOI: 10.1002/Chem.200903583  0.39
2010 Murata K, Ito M, Inagaki A, Akita M. Photocatalytic Styrene Polymerization by Novel Bichromophoric Pd Catalyst Having Long Excited-state Lifetime Chemistry Letters. 39: 915-917. DOI: 10.1246/Cl.2010.915  0.336
2010 Yamaguchi T, Koike T, Akita M. Dirhodium Complexes Bridged by Bis(diphenylphosphino)phthalazine (PNNPPh): Central Ring Size and Charge Effects As Compared with the Pyrazolate Derivative (PNNPPy) Organometallics. 29: 6493-6502. DOI: 10.1021/Om100832Z  0.423
2010 Inagaki A, Akita M. Visible-light promoted bimetallic catalysis Coordination Chemistry Reviews. 254: 1220-1239. DOI: 10.1016/J.Ccr.2009.11.003  0.328
2010 Tanaka Y, Koike T, Akita M. Reversible, Fine Performance Tuning of an Organometallic Molecular Wire by Addition, Ligand Replacement and Removal of Dicobalt Fragments European Journal of Inorganic Chemistry. 2010: 3571-3575. DOI: 10.1002/Ejic.201000661  0.342
2010 Hikichi S, Fujita K, Manabe Y, Akita M, Nakazawa J, Komatsuzaki H. Coordination Properties of Organoborate Ligands – Steric Hindrance Around the Distal Boron Center Directs the Conformation of the Dialkylbis(imidazolyl)borate Scaffold European Journal of Inorganic Chemistry. 2010: 5529-5537. DOI: 10.1002/Ejic.201000629  0.433
2009 Kuwabara J, Mori H, Teratani T, Akita M, Kanbara T. Regioregulated Syntheses of Poly(aminopyridine)s by Pd-catalyzed Amination Reaction. Macromolecular Rapid Communications. 30: 997-1001. PMID 21706561 DOI: 10.1002/Marc.200900033  0.315
2009 Hikichi S, Okuda H, Ohzu Y, Akita M. Structural characterization and oxidation activity of a nickel(II) alkylperoxo complex. Angewandte Chemie (International Ed. in English). 48: 188-91. PMID 19040236 DOI: 10.1002/Anie.200804402  0.343
2009 Koike T, Akita M. Photoinduced Oxyamination of Enamines and Aldehydes with TEMPO Catalyzed by [Ru(bpy)3]2+ Chemistry Letters. 38: 166-167. DOI: 10.1246/Cl.2009.166  0.322
2009 Sugie A, Furukawa H, Suzaki Y, Osakada K, Akita M, Monguchi D, Mori A. Electrophilic substitution of thiophenes with arylpalladium(II) and platinum(II) complexes: Mechanistic studies on palladium-catalyzed CH arylation of thiophenes Bulletin of the Chemical Society of Japan. 82: 555-562. DOI: 10.1246/Bcsj.82.555  0.443
2009 Tanaka Y, Shaw-Taberlet JA, Justaud F, Cador O, Roisnel T, Akita M, Hamon J, Lapinte C. Electronic and Magnetic Couplings in Free and π-Coordinated 1,4-Diethynylnaphthalene-Bridged [Cp*(dppe)Fe]n+ (n = 0, 1) Units Organometallics. 28: 4656-4669. DOI: 10.1021/Om900352Q  0.433
2009 Okamoto K, Yamamoto T, Akita M, Wada A, Kanbara T. Chemical Stimuli Induced Phosphorescence Modulation of Secondary Thioamide-Based Pincer Platinum Complexes Organometallics. 28: 3307-3310. DOI: 10.1021/Om800894J  0.402
2009 Saita T, Nitadori H, Inagaki A, Akita M. Syntheses and photophysical properties of visible-light-absorbing Ru(II) polypyridyl complexes possessing (pyridylpyrazolyl)metal tethers Journal of Organometallic Chemistry. 694: 3125-3133. DOI: 10.1016/J.Jorganchem.2009.05.024  0.424
2009 Matsuura Y, Tanaka Y, Akita M. p-Diethynylbenzene-based molecular wires, Fe–CC-p-C6H2X2–CC–Fe [Fe = Fe(η5-C5Me5)(dppe)]: Synthesis, substituent effects and unexpected formation of benzodifuran complex Journal of Organometallic Chemistry. 694: 1840-1847. DOI: 10.1016/J.Jorganchem.2009.01.019  0.355
2009 Fujita K, Akita M, Hikichi S. Acetoxybis(imidazolyl)methylborate [B(ImN-Me)2(OC(O)Me)Me]−: Carboxylation of borane moiety of imidazolyl-based scorpionate Inorganica Chimica Acta. 362: 4472-4479. DOI: 10.1016/J.Ica.2009.05.007  0.335
2009 Hikichi S, Kaneko M, Miyoshi Y, Mizuno N, Fujita K, Akita M. Design, Synthesis, and Catalysis of Bio-inspired Immobilized Metallocomplex Catalyst Topics in Catalysis. 52: 845-851. DOI: 10.1007/S11244-009-9232-2  0.375
2008 Inagaki A, Nakagawa H, Akita M, Inoue K, Sakai M, Fujii M. Synthesis of Pd complexes directly linked to the light-absorbing [(bpy)(3)Ru](2+) unit and their photochemical reactions toward styrenes. Dalton Transactions (Cambridge, England : 2003). 6709-23. PMID 19153619 DOI: 10.1039/B809020C  0.456
2008 Akita M, Koike T. Chemistry of polycarbon species: from clusters to molecular devices. Dalton Transactions (Cambridge, England : 2003). 3523-30. PMID 18594697 DOI: 10.1039/B802069H  0.327
2008 Higashihara G, Inagaki A, Akita M. Syntheses of novel di- and trinucleating ligands having a triethylbenzene core with N,N-bidentate tethers: their complexation toward Pd and Rh organometallic fragments. Dalton Transactions (Cambridge, England : 2003). 1888-98. PMID 18369496 DOI: 10.1039/B713503C  0.429
2008 Mori A, Sugie A, Furukawa H, Suzaki Y, Osakada K, Akita M. Electrophilic substitution of platinum(II) complexes with thiophene derivatives Chemistry Letters. 37: 542-543. DOI: 10.1246/Cl.2008.542  0.401
2007 Tanaka Y, Inagaki A, Akita M. A photoswitchable molecular wire with the dithienylethene (DTE) linker, (dppe)(eta(5)-C(5)Me(5))Fe-C[triple bond, length as m-dash]C-DTE-C[triple bond, length as m-dash]C-Fe(eta(5)-C(5)Me(5))(dppe). Chemical Communications (Cambridge, England). 1169-71. PMID 17347728 DOI: 10.1039/B614748H  0.326
2007 Inagaki A, Yatsuda S, Edure S, Suzuki A, Takahashi T, Akita M. Synthesis of Pd complexes combined with photosensitizing of a ruthenium(II) polypyridyl moiety through a series of substituted bipyrimidine bridges. Substituent effect of the bridging ligand on the photocatalytic dimerization of alpha-methylstyrene. Inorganic Chemistry. 46: 2432-45. PMID 17328538 DOI: 10.1021/Ic0612909  0.394
2007 Tanaka Y, Ozawa T, Inagaki A, Akita M. Redox-active polyiron complexes with tetra(ethynylphenyl)ethene and [2,2]paracyclophane spacers containing ethynylphenyl units: extension to higher dimensional molecular wire. Dalton Transactions (Cambridge, England : 2003). 928-33. PMID 17308672 DOI: 10.1039/B614803D  0.383
2007 Osawa M, Nagai H, Akita M. Photo-activation of Pd-catalyzed Sonogashira coupling using a Ru/bipyridine complex as energy transfer agent. Dalton Transactions (Cambridge, England : 2003). 827-9. PMID 17297509 DOI: 10.1039/B618007H  0.329
2007 Uchida K, Inagaki aA, Akita M. Preparation and Photochemical Behavior of Organoruthenium Derivatives of Photochromic Dithienylethene (DTE): DTE−(RRuLm)n (RRuLm = (η6-C6H5)Ru(η5-C5Me5), (η6-C6H5)RuCl2(PPh3), (η5-C5Me4)Ru(CO)2; n = 1, 2)† Organometallics. 26: 5030-5041. DOI: 10.1021/Om700537S  0.442
2007 Higashihara G, Terada M, Inagaki aA, Akita M. C−C Coupling of a Permetalated Ethene, (μ4-CC)Ru2(FeCp*)2(CO)10, with Alkynes, and Isolation of a Labile MeCN Adduct, (μ4-CC)Ru2(FeCp*)2(CO)8(NCMe)2 Organometallics. 26: 439-444. DOI: 10.1021/Om0609160  0.469
2007 Hirasa M, Inagaki A, Akita M. Ruthenium and chromium complexes bearing pH-indicators as the η6-arene ligand: Synthesis, characterization, and protonation behavior Journal of Organometallic Chemistry. 692: 93-110. DOI: 10.1016/J.Jorganchem.2006.07.046  0.39
2006 Chung MC, Ahn HG, Kwak CH, Akita M. Electronic coupling in dimetallic complexes with pi-conjugated bridge. Journal of Nanoscience and Nanotechnology. 6: 3347-50. PMID 17252762 DOI: 10.1166/jnn.2006.007  0.308
2006 Dubs C, Yamamoto T, Inagaki A, Akita M. A new method for the conversion of allyl alcohol into pi-allyl species promoted by nucleophilic interaction with a CO ligand. Chemical Communications (Cambridge, England). 1962-4. PMID 16767250 DOI: 10.1039/B601143H  0.358
2006 Takano K, Inagaki A, Akita M. Chelation-assisted Facile C–N Bond Oxidative Addition of Spironaphthoxazines by Ru(η4-cycloocta-1,5-diene)(η6-naphthalene) Chemistry Letters. 35: 434-435. DOI: 10.1246/Cl.2006.434  0.437
2006 Akita M, Tanaka Y, Naitoh C, Ozawa T, Hayashi N, Takeshita M, Inagaki aA, Chung‡ M. Synthesis of a series of diiron complexes based on a tetraethynylethene skeleton and related C6-enediyne spacers, (dppe)Cp*Fe-C≡CC(R)=C(R)C≡C-FeCp*(dppe ) : Tunable molecular wires Organometallics. 25: 5261-5275. DOI: 10.1021/Om060403T  0.388
2006 Dubs C, Yamamoto T, Inagaki aA, Akita M. Synthesis of a Library of Iridium-Containing Dinuclear Complexes with Bridging PNNN and PNNP Ligands (BL), [LM(μ-BL)M‘L‘]BF4. 2. Preparation, Basic Coordination Properties, and Reactivity of the Carbonyl Complexes Organometallics. 25: 1359-1367. DOI: 10.1021/Om050897E  0.444
2006 Dubs C, Yamamoto T, Inagaki aA, Akita M. Synthesis of a Library of Iridium-Containing Dinuclear Complexes with Bridging PNNN and PNNP Ligands (BL), [LM(μ-BL)M‘L‘]BF4. 1. Specific Synthesis of Isomeric Heterodinuclear Complexes with Switched Metal Arrangements Organometallics. 25: 1344-1358. DOI: 10.1021/Om050896M  0.432
2006 Chung M-, Ahn H-, Akita M. Reaction of Butadiynediyl dimetal Complexes with Fe2(CO)9: Formation of Various Complexes with the C4 bridge Studies in Surface Science and Catalysis. 159: 341-344. DOI: 10.1016/S0167-2991(06)81603-4  0.433
2006 Nishii K, Hagihara H, Ikeda T, Akita M, Shiono T. Stereospecific polymerization of propylene with group 4 ansa-fluorenylamidodimethyl complexes Journal of Organometallic Chemistry. 691: 193-201. DOI: 10.1016/J.Jorganchem.2005.08.027  0.373
2006 Singh UP, Sharma AK, Hikichi S, Komatsuzaki H, Moro-oka Y, Akita M. Hydrogen bonding interaction between imidazolyl N-H group and peroxide : Stabilization of Mn(III)-peroxo complex TpiPr2Mn(η2-O2)(imMeH) (imMeH = 2-methylimidazole) Inorganica Chimica Acta. 359: 4407-4411. DOI: 10.1016/J.Ica.2006.06.033  0.603
2005 Inagaki A, Edure S, Yatsuda S, Akita M. Highly selective photo-catalytic dimerization of alpha-methylstyrene by a novel palladium complex with photosensitizing ruthenium(II) polypyridyl moiety. Chemical Communications (Cambridge, England). 5468-70. PMID 16261249 DOI: 10.1039/B508013D  0.347
2005 Uehara K, Hikichi S, Inagaki A, Akita M. Xenophilic complexes bearing a Tp(R) Ligand, [Tp(R)M--M'Ln] [Tp(R) = Tp(iPr2), Tp(#) (Tp(Me2,4-Br)); M=Ni, Co, Fe, Mn; M'Ln = Co(CO)4, Co(CO)3(PPh3), RuCp(CO)2]: the two metal centers are held together not by covalent interaction but by electrostatic attraction. Chemistry (Weinheim An Der Bergstrasse, Germany). 11: 2788-809. PMID 15736146 DOI: 10.1002/Chem.200401016  0.404
2005 Osawa M, Hoshino M, Akita M, Wada T. Synthesis and characterization of phenanthrylphosphine gold complex: observation of Au-induced blue-green phosphorescence at room temperature. Inorganic Chemistry. 44: 1157-9. PMID 15732943 DOI: 10.1021/Ic048538J  0.354
2005 Moriuchi A, Uchida K, Inagaki A, Akita M. Photochromic Behavior and Diastereomeric Isomerism in [(η6-spirobenzopyran)RuCp*]PF6 Organometallics. 24: 6382-6392. DOI: 10.1021/Om0506771  0.419
2005 Tanaka S, Dubs C, Inagaki aA, Akita M. Polynuclear Rhodium Complexes with Dinucleating PNNP Ligand: Dynamic and Diverse M···M Interactions in [(μ-X)Rh2(PNNP)(CO)2]n+ and [(μ4-X)Rh4(PNNP)2(CO)4]n+ [X = H, O, C⋮C−R, R−C⋮C−R, C⋮C, CHCH2, SMe2; n = 0, 1: PNNP = 3,5-bis(diphenylphosphinomethyl)pyrazolato] Organometallics. 24: 163-184. DOI: 10.1021/Om049427V  0.445
2005 Cai Z, Ikeda T, Akita M, Shiono T. Substituent Effects of tert-Butyl Groups on Fluorenyl Ligand in Syndiospecific Living Polymerization of Propylene with ansa-Fluorenylamidodimethyltitanium Complex Macromolecules. 38: 8135-8139. DOI: 10.1021/Ma050898I  0.323
2005 Nishii K, Ikeda T, Akita M, Shiono T. Polymerization of propylene with [t-BuNSiMe2Ind]TiMe2–MAO catalyst systems Journal of Molecular Catalysis a-Chemical. 231: 241-246. DOI: 10.1016/J.Molcata.2004.12.035  0.313
2004 Dubs C, Inagaki A, Akita M. Selective synthesis of isomeric heterodinuclear complexes with switched metal arrangements via proton-induced reversible metal migration. Chemical Communications (Cambridge, England). 2760-1. PMID 15568104 DOI: 10.1039/B409514F  0.349
2004 Chung M, Akita M. A Study on Electronic Interaction in Dimetallic Complexes with Conjugated Chain Journal of the Korean Institute of Electrical and Electronic Material Engineers. 17: 652-660. DOI: 10.4313/Jkem.2004.17.6.652  0.315
2004 Tanaka S, Dubs C, Inagaki aA, Akita M. Tetranuclear Complexes Based on a Dynamic Metal−Metal Linkage, [(μ4-X)Rh4(CO)4(PNNP)2]n+ (X/n = RC⋮C/1 (Acetylide), C2/0 (Dicarbide)) Organometallics. 23: 317-319. DOI: 10.1021/Om034315+  0.353
2004 Takahashi Y, Hikichi S, Moro-oka Y, Akita M. Oxygenation of a series of cationic aquoruthenium complexes, TpiPr2Ru(OH2)nL3–n · CF3SO3 · (THF)x, leading to mono- and dinuclear aquo-hydroxo complexes supported by unique hydrogen bonding networks Polyhedron. 23: 225-234. DOI: 10.1016/J.Poly.2003.11.009  0.619
2004 Akita M. Coordinatively unsaturated organometallic system based on Tp ligand: tetrahedral TpRM-R' and TpRM-M'Ln species Journal of Organometallic Chemistry. 689: 4540-4551. DOI: 10.1016/J.Jorganchem.2004.08.007  0.427
2004 Takahashi Y, Hashimoto M, Hikichi S, Moro-oka Y, Akita M. Oxygenation of a low valent rhodium complex, TpiPr2Rh(dppe): sequential conversion of molecular oxygen into peroxo and hydroperoxo complexes and characterization of the peroxo species Inorganica Chimica Acta. 357: 1711-1724. DOI: 10.1016/J.Ica.2003.12.022  0.596
2003 Terada M, Higashihara G, Inagaki A, Akita M. mu4-Dicarbyne complex with a dimetallacyclobutatriene core: a new binding mode of C2 species. Chemical Communications (Cambridge, England). 2984-5. PMID 14703819 DOI: 10.1039/B310484B  0.331
2003 Kujime M, Hikichi S, Akita M. Conversion of a Hydroperoxo Complex, (TpiPr2)(py)Pd-OOH, into a Cyclic Alkylperoxo Complex, [HB(pziPr2)2(pz-3-CMe2-5-i-Pr)](py)Pd-OO, Catalyzed by Cu(II) Species [TpiPr2: Hydrotris(3,5-diisopropylpyrazolyl)borato] Chemistry Letters. 32: 486-487. DOI: 10.1246/Cl.2003.486  0.347
2003 Sugawara K, Hikichi S, Akita M. A peroxochromium complex, TpiPr2Cr(O2)2, obtained by oxidative dehydrative condensation between a dihydroxochromium complex and H2O2[TpiPr2= hydrotris(3,5-diisopropylpyrazolyl)borato] Dalton Transactions. 4346-4355. DOI: 10.1039/B309762E  0.418
2003 Kujime M, Hikichi S, Akita M. Interaction of hydroperoxopalladium complexes, (TpR)(py)Pd–OOH, with hydroxo-nickel and -cobalt complexes, [(μ-OH)(MTpR′)]2(M = Ni, Co), leading to oxidative dehydrogenation of the saturated hydrocarbyl moiety in the ancillary ligand (TpiPr2) Dalton Transactions. 3506-3515. DOI: 10.1039/B307262M  0.477
2003 Terada M, Akita M. Formal hydrogenation of a permetalated ethene, (μ4-C=C)Fe2Ru2(η5-C5 Me5)2(CO)8(dppm), via successive protonation-hydride reduction leading to C2Hn cluster compounds Organometallics. 22: 355-364. DOI: 10.1021/Om020722U  0.445
2003 Akita M, Sakurai A, Chung M, Moro-oka Y. Cluster compounds containing a linear carbon chain derived from polyynediyl and polyynyl complexes, Fp*(CC)nX [X=Fp*, H; Fp*=Fe(η5-C5Me5)(CO)2] Journal of Organometallic Chemistry. 670: 2-10. DOI: 10.1016/S0022-328X(02)02067-3  0.578
2003 Kujime M, Hikichi S, Akita M. Synthesis and characterization of enolato-cobalt and -nickel complexes bearing TpiPr2 ligand, [TpiPr2M(XCHY)]n [TpiPr2=hydrotris(3,5-diisopropylpyrazolyl)borato; n=1, 2], obtained from hydroxometal complexes, (μ-OH)2(MTpiPr2)2, and active methylene compounds, CH2XY Inorganica Chimica Acta. 350: 163-174. DOI: 10.1016/S0020-1693(02)01547-5  0.456
2002 Miyaji T, Kujime M, Hikichi S, Moro-oka Y, Akita M. Synthesis and characterization of a series of (hydroperoxo)-, (alkylperoxo)-, and (mu-peroxo)palladium complexes containing the hydrotris(3,5-diisopropylpyrazolyl)borato ligand (Tp(iPr2)): (Tp(iPr2))(py)Pd-OO-X [X = H, t-Bu, Pd(Tp(iPr2))(py)] and (Tp(iPr2))(py)Pd-(mu-kappa(1):kappa(2)-OO)-PdTp(iPr2). Inorganic Chemistry. 41: 5286-95. PMID 12354063 DOI: 10.1021/Ic020355E  0.564
2002 Uehara K, Hikichi S, Akita M. Reactivity Control of a Dinuclear Xenophilic Species, Tp#Ni–RuCp(CO)2, via Spin Crossover across a Metal-metal Bond [Tp#: Hydrotris(4-bromo-3,5-dimethylpyrazolyl)borato] Chemistry Letters. 31: 1198-1199. DOI: 10.1246/Cl.2002.1198  0.31
2002 Akita M, Hikichi S. Inorganic chemistry based on Tp ligands: From dioxygen complexes to organometallic systems Bulletin of the Chemical Society of Japan. 75: 1657-1679. DOI: 10.1246/Bcsj.75.1657  0.438
2002 Hikichi S, Sasakura Y, Yoshizawa M, Ohzu Y, Moro-Oka Y, Akita M. Selective Synthesis, Characterization, and Configurational Flexibility of the Coordinatively Unsaturated Metal Center of Half-Sandwich Type Complexes with the Less-Hindered Hydrotris(3, 5-dimethyl-4-X-1-pyrazolyl)borate Ligands [TpMe2,XMII(κ2-O,O′-L)] (M = Ni, Co; L = NO3, OAc; X = Me, H, Br) Bulletin of the Chemical Society of Japan. 75: 1255-1262. DOI: 10.1246/Bcsj.75.1255  0.609
2002 Sugawara K, Hikichi S, Akita M. Di- and tri-valent chlorochromium complexes bearing hydrotris(3,5-diisopropylpyrazolyl)borato ligand (TpiPr2), TpiPr2CrCln(L) (n = 1, 2) and [TpiPr2Cr(μ-Cl)]2: flexible coordination behavior of the TpiPr2 ligand and reduction features of Cr(II) species Journal of the Chemical Society-Dalton Transactions. 4514-4524. DOI: 10.1039/B207326A  0.446
2002 Uehara K, Hikichi S, Akita M. Highly labile cationic tris-acetonitrile complexes, [TpRM(NCMe)3]OTf (M = Ni, Co; TpR: hydrotrispyrazolylborato, R = Ph, Me and iPr2): versatile precursors for TpR-containing nickel and cobalt complexes Journal of the Chemical Society-Dalton Transactions. 3529-3538. DOI: 10.1039/B203377C  0.445
2002 Yoshimitsu S, Hikichi S, Akita M. Synthesis and Characterization of Coordinatively Unsaturated Alkynyl- and Aryl-Cobalt Complexes with 15 Valence Electrons, TpiPr2Co−R, Bearing the Hydrotris(3,5-diisopropylpyrazolyl)borato Ligand (TpiPr2) Organometallics. 21: 3762-3773. DOI: 10.1021/Om020268U  0.474
2001 Tanaka S, Akita M. [(μ -H)Rh (PNNP) (CO) ] : A Novel Hydride Bridging Mode. Angewandte Chemie (International Ed. in English). 40: 2865-2867. PMID 29711970 DOI: 10.1002/1521-3773(20010803)40:15<2865::Aid-Anie2865>3.0.Co;2-5  0.4
2001 Hikichi S, Yoshizawa M, Sasakura Y, Komatsuzaki H, Moro-oka Y, Akita M. Structural characterization and intramolecular aliphatic C-H oxidation ability of M(III)(mu-O)2M(III) complexes of Ni and Co with the hydrotris-(3,5-dialkyl-4-X-pyrazolyl)borate ligands TpMe2,X (X = Me, H, Br) and TpiPr2. Chemistry (Weinheim An Der Bergstrasse, Germany). 7: 5011-28. PMID 11775675 DOI: 10.1002/1521-3765(20011203)7:23<5011::Aid-Chem5011>3.0.Co;2-C  0.608
2001 Akita M, Takahashi Y, Hikichi S, Moro-oka Y. Synthesis and dehydrative condensation of monomeric hydroxoruthenium complexes with hydrotris(3,5-diisopropylpyrazolyl)borate ligand, TpiPr2Ru(L2)-OH (L2 = dppe, bipy). Inorganic Chemistry. 40: 169-72. PMID 11195376 DOI: 10.1021/Ic000520V  0.593
2001 Sugawara K, Hikichi S, Akita M. Dichloromethane Activation by Chlorochromium(II) Complexes with TpiPr2: Generation of an Electrophilic Cr–Methylene Species without the Action of an External Cl-Abstraction Reagent Chemistry Letters. 2001: 1094-1095. DOI: 10.1246/Cl.2001.1094  0.394
2001 Uehara K, Hikichi aS, Akita M. Rational Synthesis and Reversible Metal−Metal Bond Scission of Heterobimetallic Xenophilic Complexes Containing an Unsupported, Polar Metal−Metal Bond, TpiPr2M−Co(CO)3L (M = Ni, Co, Fe, Mn; L = CO, PPh3) Organometallics. 20: 5002-5004. DOI: 10.1021/Om010651J  0.369
2001 Kujime M, Hikichi aS, Akita M. N/O- and C-Bound (Enolato)palladium Complexes with Hydrotris(pyrazolyl)borato Ligands (TpR: R = iPr2, Me2) Obtained via Dehydrative Condensation between the Hydroxo Complexes TpRPd(Py)OH and Active Methylene Compounds: Factors Determining the Isomer Distribution and Dimerization of Cyano Compounds Organometallics. 20: 4049-4060. DOI: 10.1021/Om010448O  0.449
2001 Shirasawa N, Nguyet TT, Hikichi S, Moro-oka aY, Akita M. Tetrahedral, Highly Coordinatively Unsaturated 14e (Fe) and 15e (Co) Hydrocarbyl Complexes Bearing Hydrotris(pyrazolyl)borato Ligands (TpR‘), TpR‘M−R (M = Fe, Co, Ni) Organometallics. 20: 3582-3598. DOI: 10.1021/Om0103106  0.393
2001 Akita M, Kakuta S, Sugimoto S, Terada M, Tanaka aM, Moro-oka Y. Nucleophilic Addition to the η2-Alkyne Ligand in [CpFe(CO)2(η2-R−C⋮C−R)]+. Dependence of the Alkenyl Product Stereochemistry on the Basicity of the Nucleophile Organometallics. 20: 2736-2750. DOI: 10.1021/Om010095T  0.621
2001 Akita M, Sugimoto S, Hirakawa H, Kato S, Terada M, Tanaka aM, Moro-oka Y. Higher Nuclearity Fe,Ru Mixed-Metal Dicarbide Cluster Compounds Derived from Ethynediyldiiron Complex (η5-C5Me5)(CO)2Fe−C⋮C−Fe(η5-C5Me5)(CO)2 Organometallics. 20: 1555-1568. DOI: 10.1021/Om001009C  0.649
2001 Akita M, Musashi H, Nakanishi S, Moro-oka Y. Photochemical C–H bond activation of diruthenium bridging alkylidene complexes: Interligand H-exchange on Cp2Ru2(μ-CH2)(μ-CHR)(CO)2 (R=H, Me) Journal of Organometallic Chemistry. 617: 254-260. DOI: 10.1016/S0022-328X(00)00538-6  0.631
2001 Tanaka S, Akita M. [(μ4‐H)Rh4(PNNP)2(CO)4]+: eine neuartige Hydrid‐Verbrückung Angewandte Chemie. 113: 2951-2953. DOI: 10.1002/1521-3757(20010803)113:15<2951::Aid-Ange2951>3.0.Co;2-T  0.306
2000 Akita M, Miyaji T, Muroga N, Mock-Knoblauch C, Adam W, Hikichi S, Moro-oka Y. Synthesis and dehydrative condensation of square-planar mono- and dinuclear hydroxopalladium complexes with the hydrotris(3,5-diisopropylpyrazolyl)borato ligand (TpiPr2), TpiPr2(Py)Pd-OH, and (mu-OH)2[PdTpiPr2(H2O)]2. Inorganic Chemistry. 39: 2096-102. PMID 12526518 DOI: 10.1021/Ic991034E  0.577
2000 Akita M, Chung M, Sakurai A, Moro-oka Y. Formation of novel conjugated polycarbon–metal systems via metal migration on a M–CC–CC–M linkage Chemical Communications. 1285-1286. DOI: 10.1039/B003722M  0.631
2000 Fujita K, Hikichi S, Akita M, Moro-oka Y. Synthesis and structural characterization of a new class of organoborato ligands containing imidazolyl functional groups [MeB(ImN-Me)2(X)]− Journal of the Chemical Society-Dalton Transactions. 1255-1260. DOI: 10.1039/B000467G  0.58
2000 Ma D, Hikichi S, Akita M, Moro-oka Y. An entry to half-sandwich complexes of first row transition metals (Ni, Co, Mn) containing the Kläui tripodal ligand, LOMe: synthesis and crystal structures of oligomeric, [LOMeM(μ-X)(L)]n (n = 2, 4), and monomeric complexes, LOMeM(L2)(X) Journal of the Chemical Society-Dalton Transactions. 1123-1134. DOI: 10.1039/A909580B  0.634
2000 Fujita K, Hikichi S, Akita M, Moro-oka Y. Novel monoanionic tripodal ligands: methylbis(1-methylimidazol-2-yl)(pyrazol-1-yl)borate (= [MeB(ImN-Me)2(PzR)]−). Synthesis and structural characterization of their nickel complexes and carboxylate shift from nickel to boron Journal of the Chemical Society-Dalton Transactions. 117-119. DOI: 10.1039/A908181J  0.597
2000 Akita M, Hashimoto M, Hikichi aS, Moro-oka Y. Synthesis and Structural Comparison of TpiPr2Rh[cis-1,2-bis(diphenylphosphino)ethene]: Factors Determining Hapticity (κ2 vs κ3) of the TpiPr2 Ligand in TpiPr2Rh(diphosphine) Complexes Organometallics. 19: 3744-3747. DOI: 10.1021/Om0003640  0.604
2000 Akita M. Deoxygenative reduction of organometallic compounds by hydrosilanes — an organometallic approach to reaction mechanisms of catalytic CO hydrogenation Applied Catalysis a-General. 200: 153-165. DOI: 10.1016/S0926-860X(00)00632-3  0.337
2000 Ogihara T, Hikichi S, Akita M, Uchida T, Kitagawa T, Moro-oka Y. An approach to the O2 activating mononuclear non-heme Fe enzymes: structural characterization of Fe(II)–acetato complex and formation of alkylperoxoiron(III) species with the highly hindered hydrotris(3-tert-butyl-5-isopropyl-1-pyrazolyl)borate Inorganica Chimica Acta. 297: 162-170. DOI: 10.1016/S0020-1693(99)00337-0  0.602
2000 Singh UP, Singh R, Hikichi S, Akita M, Moro-oka Y. Characterization of a dinuclear Mn(II) tri(μ-carboxylato) complex with the hindered hydrotris(3,5-diisopropyl-1-pyrazolyl)borate (=TpiPr2) ligand: intramolecular hydrogen bonding interaction between the protonated TpiPr2 and Mn-coordinating carboxylate ligands Inorganica Chimica Acta. 310: 273-278. DOI: 10.1016/S0020-1693(00)00296-6  0.618
2000 Hikichi S, Akita M, Moro-oka Y. New aspects of the cobalt-dioxygen complex chemistry opened by hydrotris(pyrazoly)borate ligands (TpR): unique properties of TpRCo-dioxygen complexes Coordination Chemistry Reviews. 198: 61-87. DOI: 10.1016/S0010-8545(99)00232-5  0.632
1999 Takahashi Y, Hashimoto M, Hikichi S, Akita M, Moro-Oka Y. Conversion of Molecular Oxygen into a Hydroperoxo Species by Ring-Opening Protonation of a Cyclic eta(2)-Peroxo Intermediate: Characterization of the eta(2)-Peroxo and Hydroperoxo Complexes. Angewandte Chemie (International Ed. in English). 38: 3074-3077. PMID 10540427 DOI: 10.1002/(Sici)1521-3773(19991018)38:20<3074::Aid-Anie3074>3.0.Co;2-R  0.56
1999 Akita M, Hikichi S, Moro-Oka Y. Chemistry of Transition Metal Complexes Supported by Hydrotris (pyrazolyl) -borates : Their Characteristic Properties and the Chemistry of Dioxygen Complexes Based on the Ligands Journal of Synthetic Organic Chemistry Japan. 57: 619-628. DOI: 10.5059/Yukigoseikyokaishi.57.619  0.607
1999 Hikichi S, Yoshizawa M, Sasakura Y, Komatsuzaki H, Akita M, Moro-oka Y. Oxygenation of Saturated Hydrocarbyl Groups in the Dinuclear Ni(III) Bis(μ-oxo) Complexes with the Hydrotris(pyrazolyl)borate Ligands TpR (R = Me3 and Pri2) Chemistry Letters. 1999: 979-980. DOI: 10.1246/Cl.1999.979  0.612
1999 Akita M, Miyaji T, Hikichi S, Moro-oka Y. A Transition Metal-Hydroperoxo Complex Stabilized by Hydrogen-Bonding Interaction: The First Example of a Hydroperoxopalladium Species Characterized by X-Ray Crystallography, (κ2-TpiPr)Pd(PPh3)(OOH) [TpiPr = hydrotris(3,5-diisopropylpyrazolyl)borato] Chemistry Letters. 1999: 813-814. DOI: 10.1246/Cl.1999.813  0.548
1999 Punniyamurthy T, Irie R, Katsuki T, Akita M, Moro-oka Y. Why Do (R, R)- And (R, S)-(Salen)Manganese(Iii) Complexes Show Different Substrate-Specificity? The Role Of An Apical Aqua Ligand Synlett. 1999: 1049-1052. DOI: 10.1055/S-1999-2785  0.537
1999 Takahashi Y, Hikichi S, Akita M, Moro-oka Y. Oxidative C(sp3)–C(sp3) bond cleavage reaction of an isopropyl group to give an acetyl group upon O2-treatment of a labile cationic ruthenium species, [TpiPrRu(dppene)(OH2)]+† Chemical Communications. 1491-1492. DOI: 10.1039/A904218K  0.572
1999 Kosugi M, Hikichi S, Akita M, Moro-oka Y. The first evidence for activation of exogenous O2 on a vanadium(IV) center: synthesis and characterization of a peroxo vanadium(V) complex with hydrotris(3,5-diisopropylpyrazol-1-yl)borate Journal of the Chemical Society-Dalton Transactions. 1369-1372. DOI: 10.1039/A901054H  0.558
1999 Shirasawa N, Akita M, Hikichi S, Moro-oka Y. Thermally stable coordinatively unsaturated alkyl complexes resistant to β-hydride elimination: TpiPrM–CH2CH3 (M = Co, Fe) Chemical Communications. 417-418. DOI: 10.1039/A809441A  0.549
1999 Akita M, Sakurai A, Moro-oka Y. Facile CC bond cleavage of polyynediyldiiron complexes, Fp*–(CC)n–Fp* [Fp* = Fe(η5-C5Me5)(CO)2; n = 3, 4], with Fe2(CO)9 leading to bis(µ3-alkylidyne) complexes, Fp*–CC-µ3-C–Fe3(CO)9–µ3-C–(CC)n–2–Fp* Chemical Communications. 101-102. DOI: 10.1039/A808712A  0.603
1999 Akita M, Nakanishi S, Musashi H, Moro-oka Y. Photochemical C–H bond activation of the diruthenium bridging methylene complex, Cp2Ru2(μ-CH2)2(CO)2: insertion of norbornadienes into the methylene C–H bond and unprecedented intramolecular H–D exchange between the two methylene units Chemical Communications. 145-146. DOI: 10.1039/A808411D  0.621
1999 Akita M, Ma D, Hikichi S, Moro-oka Y. Synthesis and crystal structures of mononuclear half-sandwich complexes of Ni and Co containing Kläui’s tripodal ligand, [M{κ3-(η5-C5H5)Co[P(O)(OCH3)2]3}(κ2-NO3)(L)] (M = Ni or Co) Journal of the Chemical Society-Dalton Transactions. 987-996. DOI: 10.1039/A807816E  0.629
1999 Takahashi Y, Hikichi S, Akita M, Moro-oka Y. A Coordinatively Unsaturated Species with an Agostic C−H Interaction, [(κ4-TpiPr)Ru(dppe)]OSO2CF3, and Its Addition Reaction Organometallics. 18: 2571-2573. DOI: 10.1021/Om990250S  0.637
1999 Kosugi M, Hikichi S, Akita M, Moro-oka Y. Inter- and Intramolecular Hydrogen-Bonding Interaction of Hydroxo Groups and Steric Effect of Alkyl Substituents on Pyrazolyl Rings in TpR Ligands: Synthesis and Structural Characterization of Chloro-, Acetylacetonato-, and Hydroxo Complexes of VO2+ with TpPri2 and TpMe2 Ligands† Inorganic Chemistry. 38: 2567-2578. DOI: 10.1021/Ic9806028  0.64
1999 Hashihayata T, Punniyamurthy T, Irie R, Katsuki T, Akita M, Moro-oka Y. Conformational analysis of cationic (R,S)- and (R,R)-(salen)manganese complexes possessing axial chirality as a chiral element based on x-ray crystallography: an explanation of the effect of apical ligand on enantioselection by (salen)manganese catalyst Tetrahedron. 55: 14599-14610. DOI: 10.1016/S0040-4020(99)00952-7  0.567
1999 Takahashi Y, Hashimoto M, Hikichi S, Akita M, Moro-oka Y. Umwandlung von molekularem Sauerstoff in eine Hydroperoxoverbindung über eine Protonierungs‐induzierte Ringöffnung eines cyclischen η2‐Peroxo‐Intermediats: Charakterisierung der η2‐Peroxo‐ und Hydroperoxokomplexe Angewandte Chemie. 111: 3259-3262. DOI: 10.1002/(Sici)1521-3757(19991018)111:20<3259::Aid-Ange3259>3.0.Co;2-E  0.484
1998 Komatsuzaki H, Sakamoto N, Satoh M, Hikichi S, Akita M, Moro-Oka Y. The First Synthesis and Structural Characterization of Alkylperoxo Complex of Manganese(II). Inorganic Chemistry. 37: 6554-6555. PMID 11670782 DOI: 10.1021/Ic980509J  0.623
1998 Komatsuzaki H, Ichikawa S, Hikichi S, Akita M, Moro-Oka Y. Characterization of a Dinuclear (&mgr;-Hydroxo)(&mgr;-pyrazolato)dimanganese(II) Complex and Hydrolytic Equilibrium of the Bridging Pyrazolate Ligand. Inorganic Chemistry. 37: 3652-3656. PMID 11670460 DOI: 10.1021/Ic971622X  0.629
1998 Ogihara T, Hikichi S, Akita M, Moro-Oka Y. Synthesis, Structural Characterization, and Extradiol Oxygenation of Iron-Catecholato Complexes with Hydrotris(pyrazolyl)borate Ligands(,). Inorganic Chemistry. 37: 2614-2615. PMID 11670392 DOI: 10.1021/Ic9716215  0.622
1998 Irie R, Hashihayata T, Katsuki T, Akita M, Moro-Oka Y. X-Ray Structures of Chiral(Salen)manganese(III) Complexes: Proof of Pliability of the Salen Ligand Chemistry Letters. 1998: 1041-1042. DOI: 10.1246/Cl.1998.1041  0.592
1998 Akita M, Fujisawa K, Hikichi S, Moro-Oka Y. Chemistry of μ-η2:η2-peroxo dimetal complexes: A bioinorganic model triggers a new trend of transition metal peroxo species Research On Chemical Intermediates. 24: 291-307. DOI: 10.1163/156856798X00258  0.573
1998 Akita M, Shirasawa N. 14e η1-Hydrocarbyliron complexes supported by hydrotris(3,5-diisopropyl-pyrazolyl)borate: the allyl complex prefers a highly coordinatively unsaturated 14e η1-structure to a 16e η3-structure‡ Chemical Communications. 973-974. DOI: 10.1039/A801460D  0.454
1998 Akita M, Miyaji T, Moro-oka Y. Systematic synthesis of a series of hydroperoxo-, alkylperoxo- and µ-peroxo-palladium complexes supported by the hydrotris(3,5-diisopropylpyrazolyl)borate ligand (TpiPr), TpiPrPd(py)–OOX [X = PdTpiPr(py), H, But], via dehydrative condensation of a hydroxo complex, TpiPrPd(py)–OH Chemical Communications. 1005-1006. DOI: 10.1039/A801111G  0.623
1998 Komatsuzaki H, Nagasu Y, Suzuki K, Shibasaki T, Satoh M, Ebina F, Hikichi S, Akita M, Moro-oka Y. Dioxygen activation by a novel manganese(II) thiolate complex with hydrotris(3,5-diisopropylpyrazol-1-yl)borate ligand Journal of the Chemical Society-Dalton Transactions. 511-512. DOI: 10.1039/A708210J  0.635
1998 Takahashi Y, Akita M, Hikichi S, Moro-oka Y. Two Isomeric Structures of Hydridoruthenium Complexes Supported by Hydrotrispyrazolylborates, TpRRu(H)(1,5-cyclooctadiene): An Octahedral Structure with Additional 3-Center-2-Electron Ru−H−B Interaction Is More Stable than a Square-Pyramidal Structure with a κ2-TpR Ligand Organometallics. 17: 4884-4888. DOI: 10.1021/Om980363W  0.595
1998 Takahashi Y, Akita M, Hikichi S, Moro-oka Y. Synthesis of Various Cationic Ruthenium−Aqua Complexes with Hydrotris(3,5-diisopropylpyrazolyl)borate Ligand, TpiPrRu(OH2)n(L)3-n·(CF3SO3)(THF)x, and Their Structures Supported by Hydrogen-Bonding Networks1 Inorganic Chemistry. 37: 3186-3194. DOI: 10.1021/Ic9801802  0.633
1998 Akita M, Moro-oka Y. Reductive activation of dioxygen: A new concept for the catalytic oxidation Catalysis Today. 44: 183-188. DOI: 10.1016/S0920-5861(98)00189-8  0.584
1998 Moro-oka Y, Akita M. Bio-inorganic approach to hydrocarbon oxidation Catalysis Today. 41: 327-338. DOI: 10.1016/S0920-5861(98)00023-6  0.536
1998 Akita M, Hua R, Knox SAR, Moro-oka Y, Nakanishi S, Yates MI. Specific C–C coupling of the labile diruthenium bridging methylene complex, Cp2Ru2(μ-CH2)(CO)2(MeCN), with diazoalkanes (R2C=N2) leading to alkenyl complexes, Cp2Ru2(μ-CH=CR2)(μ-H)(CO)2, and alkenes, CH2=CR2 Journal of Organometallic Chemistry. 569: 71-83. DOI: 10.1016/S0022-328X(98)00775-X  0.633
1998 Akita M, Chung M, Terada M, Miyauti M, Tanaka M, Moro-oka Y. Reaction of ethynediyl, butadiynediyl and ethynyl iron complexes, (η5-C5R5)(CO)2Fe–(CC)n–X [X=Fe(η5-C5R5)(CO)2, H; R5=Me5, Me4Et; n=1, 2], with Fe2(CO)9 leading to polynuclear C2 and C4 complexes Journal of Organometallic Chemistry. 565: 49-62. DOI: 10.1016/S0022-328X(98)00442-2  0.616
1997 Hikichi S, Ogihara T, Fujisawa K, Kitajima N, Akita M, Moro-Oka Y. Synthesis and Characterization of the Benzoylformato Ferrous Complexes with the Hindered Tris(pyrazolyl)borate Ligand as a Structural Model for Mononuclear Non-Heme Iron Enzymes. Inorganic Chemistry. 36: 4539-4547. PMID 11670119 DOI: 10.1021/Ic960903M  0.623
1997 Takahashi Y, Akita M, Moro-oka Y. Synthesis And Structural Characterization Of A Tetrahedral Sp3 Carbide Cluster Compound Chemical Communications. 1557-1558. DOI: 10.1039/A702806G  0.573
1997 Akita M, Terada M, Moro-oka Y. Photochemical C–C coupling reaction of an iron acetylidecomplex[Fe(η5-C5Me5)(CO)2(CCPh)] with alk-1-ynes (RCCH) leading to cyclic compoundsincluding paramagnetic iron(i) cyclopentadienone complexes[Fe(η5-C5Me5)(η4-2-Ph-5-R-C5H2O)] Chemical Communications. 265-266. DOI: 10.1039/A606836G  0.591
1997 Akita M, Hua R, Knox SAR, Moro-oka Y, Nakanishi S, Yates MI. Specific alkylidene coupling of the labile diruthenium bridging methylene complex [(η-C5H5)2Ru2(μ-CH 2)(CO)2(MeCN)] with diazoalkanes (N2=CR2) giving alkenic products Chemical Communications. 51-52. DOI: 10.1039/A606525B  0.724
1997 Akita M, Hua R, Nakanishi S, Tanaka M, Moro-Oka Y. Synthesis and Reactivity of Labile MeCN Adducts of Diruthenium Bis(μ-methylene) Species, Cp2Ru2(μ-CH2)2(CO)n(MeCN)2-n (n = 1, 2): Reaction with H Sources, H−X (X = SiR3, SnR3, H), and C−C Coupling with Alkynes and Diazoalkanes Organometallics. 16: 5572-5584. DOI: 10.1021/Om9706727  0.737
1997 Akita M, Chung M, Sakurai A, Sugimoto S, Terada M, Tanaka M, Moro-oka Y. Synthesis and Structure Determination of the Linear Conjugated Polyynyl and Polyynediyl Iron Complexes Fp*−(C⋮C)n−X (X = H (n = 1, 2); X = Fp* (n = 1, 2, 4); Fp* = (η5-C5Me5)Fe(CO)2)1 Organometallics. 16: 4882-4888. DOI: 10.1021/Om970538M  0.551
1997 Akita M, Ohta K, Takahashi Y, Hikichi S, Moro-oka Y. Synthesis and Structure Determination of Rh−diene Complexes with the Hydridotris(3,5-diisopropylpyrazolyl)borate Ligand, TpiPrRh(diene) (diene = cod, nbd): Dependence of the ν(B−H) Values on the Hapticity of the TpiPr Ligand (κ2 vs κ3)1 Organometallics. 16: 4121-4128. DOI: 10.1021/Om970352N  0.612
1997 Akita M, Kato S, Terada M, Masaki Y, Tanaka M, Moro-oka Y. Synthesis of Diiron Bridging Allenylidene Complexes Cp*2Fe2(μ-CCCR1R2)(μ-CO)(CO)2 (Cp* = η5-C5Me5) via Nucleophilic Addition to the Diiron Ethynediyl Complex (μ-C⋮C)[FeCp*(CO)2]2 and Their Conversion to Cationic μ-Vinylcarbyne and μ-Vinylidene Complexes Organometallics. 16: 2392-2412. DOI: 10.1021/Om961104E  0.635
1997 Hikichi S, Komatsuzaki H, Kitajima N, Akita M, Mukai M, Kitagawa aT, Moro-oka †Y. Characterization of a μ-η2:η2-Peroxo Dinuclear Cobalt(II) Complex Inorganic Chemistry. 36: 266-267. DOI: 10.1021/Ic950723X  0.63
1997 Akita M, Hua R, Moro-oka Y. Interconversion Between Methylene And Methylidyne-Hydride Species On A Tetraruthenium System Journal of Organometallic Chemistry. 539: 205-207. DOI: 10.1016/S0022-328X(97)00023-5  0.747
1997 Kamisuki T, Akita M, Moro-oka Y, Hirose C. Raman spectroscopic study of bis(4‐biphenylyl)acetylene in the S0, S1 and T1 states Journal of Raman Spectroscopy. 28: 791-796. DOI: 10.1002/(Sici)1097-4555(199710)28:10<791::Aid-Jrs149>3.0.Co;2-L  0.467
1996 Hua R, Akita M, Moro-oka Y. C–H and Si–C bond activation on diruthenium bridging methylene complexes: evidence for reversible oxidative addition of Si–C(sp3) bonds Chemical Communications. 541-542. DOI: 10.1039/Cc9960000541  0.715
1996 Akita M, Hua R, Oku T, Tanaka M, Moro-oka Y. Conversion of a Diruthenium μ-Methylene Complex, Cp2Ru2(μ-CH2)(μ-CO)(CO)2, into Methane through Reduction with Hydrosilane: Reactivity of Silyl−μ-Methylene Intermediates Cp2Ru2(μ-CH2)(SiR3)(X)(CO)2 (X = H, SiR3) Relevant to Catalytic CO Hydrogenation and Activation of Si−H, C−H, and C−Si Bonds Organometallics. 15: 4162-4177. DOI: 10.1021/Om960258R  0.731
1996 Akita M, Hua R, Oku T, Moro-oka Y. Deoxygenative Reduction of Diruthenium Carbonyl Complexes (η5-C5H4R)2Ru2(μ-CO)2(CO)2 with Hydrosilanes Leading to Bridging Methylene Complexes (η5-C5H4R)2Ru2(μ-CH2)n(μ-CO)2-n(CO)2 (n = 1, 2; R = H, CH3) Organometallics. 15: 2548-2553. DOI: 10.1021/Om950893H  0.75
1996 Hua R, Akita M, Moro-oka Y. Reduction of a diruthenium bridging vinylidene species Cp2Ru2(μ-C = CH2)(CO)(μ-CO)(MeCN) by hydrosilane leading to a vinyl complex Cp2Ru2(μ-CH = CH2)(CO)2(SiR3) and vinylsilane: a model system for production of an olefinic product from a vinylidene intermediate Inorganica Chimica Acta. 250: 177-183. DOI: 10.1016/S0020-1693(96)05225-5  0.719
1996 Akita M, Terada M, Tanaka M, Morooka Y. Some additional aspects of versatile starting compounds for cationic organoiron complexes: molecular structure of the aqua complex [(η5-C5Me4Et)Fe(CO)2(OH2)]BF4 and solution behavior of the THF complex [(η5C5R5)Fe(CO)2(THF)]BF4 Journal of Organometallic Chemistry. 510: 255-261. DOI: 10.1016/0022-328X(95)05918-F  0.425
1995 Akita M, Moro-oka Y. Structure and Reactivity of C2 Species on Polymetallic Systems Bulletin of the Chemical Society of Japan. 68: 420-432. DOI: 10.1246/Bcsj.68.420  0.622
1995 Terada M, Masaki Y, Tanaka M, Akita M, Moro-Oka Y. A versatile synthetic method for diiron bridging allenylidene complexes (η5-C5Me5)2Fe2(µ-CO)(CO)2(µ-η1-CCCR1R2)via nucleophilic addition to the ethynediyldiiron complex (µ-CC)[Fe(η5-C5Me5)(CO)2]2 Journal of the Chemical Society, Chemical Communications. 1611-1612. DOI: 10.1039/C39950001611  0.594
1995 Akita M, Noda K, Takahashi Y, Moro-oka Y. Deoxygenative Reduction of Dimolybdenum Carbonyl Complexes Mo2(.eta.5-C5H4R')2(CO)4 by Hydrosilane Giving Trinuclear .mu.3-Methylidyne and .mu.3-Ethylidyne Complexes, (.mu.3-CR)[Mo(.eta.5-C5H4R')(CO)2]3 (R, R' = H, CH3), and Analysis of the Rotational Processes of the Mo(.eta.5-C5H4R')(CO)2 Moieties Organometallics. 14: 5209-5220. DOI: 10.1021/Om00011A044  0.606
1995 Akita M, Hirakawa H, Sakaki K, Moro-oka Y. 1,2-H Shift on Tetranuclear Ethynyl Complexes (.mu.4-C2H)(.eta.5-C5R5)FeMCo2(CO)n (M = Fe, Ru; n = 10, 11; R = H, Me) Organometallics. 14: 2775-2780. DOI: 10.1021/Om00006A025  0.587
1995 Akita M, Hirakawa H, Tanaka M, Moro-oka Y. Structure expansion of the mixed-metal dicarbide cluster core in [(μ3-C≡C-Fp)Ru3(μ-H)(CO9)] via direct radical and thermal coupling reactions leading to higher-nuclearity (μ-C2Hx)My cluster compounds (x = 0, 1; y = 7, 8),CpFeRu6(μ5-C2)(μ5-C2H)(CO)16,Cp2Fe2Ru5(μ5-C2)2(CO)17and Cp2Fe2Ru6(μ6-C2)2(CO)17 Journal of Organometallic Chemistry. 485. DOI: 10.1016/0022-328X(94)05044-C  0.601
1994 Akita M, Noda K, Moro-oka Y. Formation of a Trinuclear .mu.3-Methylidyne Complex, (.mu.3-CH)[MoCp(CO)2]3, through Reduction of a CO Ligand in Cp2Mo2(CO)4 by a Hydrosilane Organometallics. 13: 4145-4147. DOI: 10.1021/Om00023A008  0.615
1994 Akita M, Ishii N, Takabuchi A, Tanaka M, Moro-oka Y. Transformation of the C2H ligand in Fp*C.tplbond.CH [Fp* = (.eta.5-C5Me5)Fe(CO)2] into various C2 functional groups via an iron-substituted vinylidene complex, (.eta.5-C5H4Me)Mn(CO)2[:C:C(H)Fp*]: its amphoteric reactivities, structural comparisons relevant to 1-alkyne-to-vinylidene rearrangements, and electronic influences on structures of heterobimetallic bridging alkynyl complexes [(.eta.5-C5R5)M(CO)2]2(.mu.-C2R) Organometallics. 13: 258-268. DOI: 10.1021/Om00013A039  0.621
1994 Akita M, Terada M, Ishii N, Hirakawa H, Moro-oka Y. Unusual reactivities of (μ-η2:η2-FPCCH)Co2(CO)6, the adducts of FPCCH to Co2(CO)8: photolysis, thermolysis and reduction with hydrosilanes giving polynuclear complexes, (CP)2Fe2Co3(μ5-CCH)(CO)10, (μ-CHCH)[(−μ3-C)Co3(CO)9]2 and CpFeCo3(μ-CCH2)(CO)9 Journal of Organometallic Chemistry. 473: 175-186. DOI: 10.1016/0022-328X(94)80118-5  0.605
1993 Akada M, Nakano S, Sugiyama T, Ichitoh K, Nakao H, Akita M, Moro-oka Y. A Practical O2-Oxidation of Functionalized Alcohols Producing Carboxylic Acids Catalyzed by the Pd–C/Pb(OAc)2 System Bulletin of the Chemical Society of Japan. 66: 1511-1515. DOI: 10.1246/Bcsj.66.1511  0.517
1993 Akita M, Oku T, Hua R, Moro-oka Y. Reduction of ruthenium and iron µ-methylene complexes with hydrosilanes producing alkane: a model system for methanation via the Fischer–Tropsch mechanism Journal of the Chemical Society, Chemical Communications. 1670-1672. DOI: 10.1039/C39930001670  0.724
1993 Akita M, Sugimoto S, Takabuchi A, Tanaka M, Morooka Y. Synthesis and characterization of (CP)2Mo2(CO)4(.mu.-.eta.2:.eta.2-FP-C.tplbond.C-H), adducts of ethynyliron complexes to (CP)2Mo2(CO)4: their fluxional behavior via reversible 1-alkyne-vinylidene ligand interconversion on a dinuclear system and photochemical decarbonylation leading to the .mu.3-vinylidenyl complexes (CP)FeCp2Mo2(CO)4(.mu.-CO)(.mu.3-:C:CH) Organometallics. 12: 2925-2932. DOI: 10.1021/Om00032A013  0.451
1993 Akita M, Sugimoto S, Terada M, Moro-oka Y. Photochemical head-to-head (R H) vs. head-to-tail dimerization (R Ph) of iron acetylide complexes (η5-C5Me5)Fe(CO)2CCR leading to a dimetallacyclopentenone and a μ-vinylidene complex Journal of Organometallic Chemistry. 447: 103-106. DOI: 10.1016/0022-328X(93)80278-J  0.576
1992 Akita M, Moro-Oka Y. Elucidation of Mechanisms of Syngas Reactions by Employing Organometallic Model Compounds Journal of Synthetic Organic Chemistry Japan. 50: 726-736. DOI: 10.5059/Yukigoseikyokaishi.50.726  0.535
1992 Akita M, Oku T, Moro-Oka Y. One-step transformation of coordinated CO into CH2 on diruthenium complexes by the action of hydrosilanes: a model system for the Fischer–Tropsch mechanism Journal of the Chemical Society, Chemical Communications. 1031-1032. DOI: 10.1039/C39920001031  0.586
1992 Kawahara T, Suzuki K, Iwasaki Y, Shimoi H, Akita M, Moro-Oka Y, Nishikawa Y. Stereochemistry of the peptide α-amidation reaction involving two enzymes, peptidylglycine α-hydroxylating monooxygenase (PHM) and peptidylhydroxyglycine N–C lyase (PHL) Journal of the Chemical Society, Chemical Communications. 625-626. DOI: 10.1039/C39920000625  0.476
1992 Akita M, Kakuta S, Sugimoto S, Terada M, Moro-oka Y. cis-Stereochemistry on nucleophilic addition to a cationic η2-alkyne complex, [(η5-C5H5)Fe(CO)2(Ph–CC–Ph)]BF4 Journal of the Chemical Society, Chemical Communications. 451-453. DOI: 10.1039/C39920000451  0.611
1992 Akita M, Terada M, Tanaka M, Morooka Y. Interaction of iron ethynyl and ethynediyl complexes with Cp2Ni2(CO)2 : formation of tri- and tetranuclear adducts with a multiply bridging C2H ligand Organometallics. 11: 3468-3472. DOI: 10.1021/Om00046A058  0.376
1992 Akita M, Terada M, Morooka Y. Interaction of ethynyliron (FpC.tplbond.CH and Fp*C.tplbond.CH) and ethynediyldiiron complexes (Fp*C.tplbond.CFp*) with Co2(CO)8: formation of a cluster compound which is fluxional via a metal-metal bond scission and recombination process Organometallics. 11: 1825-1830. DOI: 10.1021/Om00041A016  0.393
1992 Akita M, Sugimoto S, Tanaka M, Morooka Y. Preparation, characterization, and sequential transformation of dicarbide cluster compounds with permetalated ethyne, ethene, and ethane structures Journal of the American Chemical Society. 114: 7581-7582. DOI: 10.1021/Ja00045A051  0.305
1991 Akita M, Mitani O, Sayama M, Morooka Y. Reduction of acyl ligand in transition-metal complexes by catalytic hydrosilylation [Erratum to document cited in CA114(23):229097g] Organometallics. 10: 3411-3411. DOI: 10.1021/Om00055A072  0.341
1991 Akita M, Terada M, Oyama S, Sugimoto S, Morooka Y. Reaction of the cationic diiron .mu.-(.eta.1:.eta.2)acetylide complexes [(FP)2(C.tplbond.CR)]BF4 (R = H, Ph) with NaOMe [Erratum to document cited in CA115(3):29548p] Organometallics. 10: 3411-3411. DOI: 10.1021/Om00055A071  0.373
1991 Akita M, Oku T, Tanaka M, Morooka Y. Oxymethylation of alkyliron complex CpFe(CO)2-R with hydrostannane and -silane, leading to R-CH2OH derivatives: related reactions of CpFe(CO)(L)-R and CpFe(CO)(L)-C(O)R type organoiron complexes and the molecular structure of trans-CpFe(H)(CO)(SnPh3)2 Organometallics. 10: 3080-3089. DOI: 10.1021/Om00055A021  0.354
1991 Akita M, Terada M, Moro-oka Y. Reaction of cationic diiron μ-η1:η2-acetylide complexes [(FP)2(C≡Cr)]BF4 (R=H, Ph) with carbon nucleophiles and hydride. Formation of μ-vinylidene complexes Organometallics. 10: 2961-2965. DOI: 10.1021/Om00054A077  0.62
1991 Akita M, Terada M, Oyama S, Sugimoto S, Morooka Y. Reaction of the cationic diiron .mu.-(.eta.1:.eta.2)acetylide complexes [(FP)2(C.tplbond.CR)]BF4 (R = H, Ph) with NaOMe Organometallics. 10: 1561-1568. DOI: 10.1021/Om00051A055  0.402
1991 Akita M, Mitani O, Sayama M, Morooka Y. Reduction of acyl ligand in transition-metal complexes by catalytic hydrosilylation Organometallics. 10: 1394-1399. DOI: 10.1021/Om00051A034  0.444
1991 Akita M, Yasuda H, Yamamoto H, Nakamura A. Template synthesis of substituted cyclopentanones by zirconocene/olefin/CO systems☆ Polyhedron. 10: 1-9. DOI: 10.1016/S0277-5387(00)83539-1  0.545
1990 Akita M, Shapley JR. Selective synthesis of functionalized alkylidynetriosmium compounds via silicon and tin reagents Organometallics. 9: 2209-2211. DOI: 10.1021/Om00158A016  0.544
1990 Akita M, Terada M, Oyama S, Morooka Y. Preparation, structure, and divergent fluxional behavior of cationic dinuclear iron acetylides [Fp*2(C.tplbond.CR)]BF4 (R = H, Ph) Organometallics. 9: 816-825. DOI: 10.1021/Om00117A043  0.329
1990 Nagashima H, Mukai K, Shiota Y, Yamaguchi K, Ara K, Fukahori T, Suzuki H, Akita M, Morooka Y, Itoh K. Oxidative addition of allylic halides to ruthenium(II) compounds. Preparation, reactions, and x-ray crystallographic structure of ruthenium(IV)-allyl complexes Organometallics. 9: 799-807. DOI: 10.1021/Om00117A041  0.315
1989 Akita M, Kondoh A, Moro-oka Y. Molecular structure of heterobimetallic µ-η2-(C,C)-ketene complexes Journal of the Chemical Society-Dalton Transactions. 1627-1630. DOI: 10.1039/Dt9890001627  0.609
1989 Akita M, Kondoh A, Moro-Oka Y. Crystal structures of di-iron µ-η2-(C,C)-ketene complexes, [{Fe(η5-C5H5)(CO)2}2(µ-CH2CO)] and [{Fe(η5-C5Me5)(CO)2}2(µ-CH2CO)]. Synergistic metal-to-ligand back donation as revealed by comparison with [{Fe(η5-C5H5)(CO)2}2(µ-CH2CH2CO)] Journal of the Chemical Society-Dalton Transactions. 1083-1087. DOI: 10.1039/Dt9890001083  0.631
1989 Akita M, Oku T, Moro-Oka Y. Oxymethylation of iron complexes [(cp)Fe(CO)2(R)] with HMMe3(M = Sn, Si; cp = C5H5) leading to R–CH2OH via a formylation–hydrometallation sequence Journal of the Chemical Society, Chemical Communications. 1790-1792. DOI: 10.1039/C39890001790  0.575
1989 Akita M, Mitani O, Moro-oka Y. Modelling the Pichler–Schulz mechanism by catalytic hydrosilylation of acyl metal complexes Journal of the Chemical Society, Chemical Communications. 527-529. DOI: 10.1039/C39890000527  0.593
1989 Akita M, Kawahara T, Terada M, Kakinuma N, Moro-oka Y. Metal-exchange reaction on cationic polyiron .mu.3-.eta.3-(C,C,O)-ketene and .mu.-.eta.2-(C,O)-enolate complexes Organometallics. 8: 687-693. DOI: 10.1021/Om00105A017  0.565
1989 Akita M, Andoh H, Mitani O, Oku T, Moro-Oka Y. Reactivities of ketene ligands on polymetallic systems Journal of Molecular Catalysis. 56: 107-116. DOI: 10.1016/0304-5102(89)80176-2  0.599
1988 Akita M, Kondoh A, Kawahara T, Takagi T, Morooka Y. Preparation of homo- and heterobimetallic .mu.-.eta.2-(C,C)-ketene complexes, FpCH2COMLn, and transformation of the bridging ketene ligand into various C2 functional groups Organometallics. 7: 366-374. DOI: 10.1021/Om00092A019  0.374
1988 Tamao K, Akita M, Kato H, Kumada M. Electrophilic cleavage reations of carbonsilicon bonds in neutral hexacoordinate silicon compounds: diorgano(phthalocyaninato)silicon Journal of Organometallic Chemistry. 341: 165-179. DOI: 10.1016/0022-328X(88)89072-7  0.634
1988 Akita M, Kakinuma N, Moro-oka Y. One-pot synthesis of transition metal-substituted carboxylic acids Journal of Organometallic Chemistry. 348: 91-94. DOI: 10.1016/0022-328X(88)80342-5  0.567
1988 Akita M, Terada M, Moro-oka Y. Metal-exchange reaction on cationic diiron μ-η2-(C,O)-enolate complexes Journal of Organometallic Chemistry. 345. DOI: 10.1016/0022-328X(88)80256-0  0.647
1987 Akita M, Kawahara T, Moro-oka Y. Preparation and intramolecular metal-exchange reaction of cationic trinuclear µ3-η3-(C,C,O)-ketene complexes Journal of the Chemical Society, Chemical Communications. 1356-1357. DOI: 10.1039/C39870001356  0.619
1987 Tamao K, Akita M, Maeda K, Kumada M. Silafunctional compounds in organic synthesis. 32. Stereoselective halogenolysis of alkenylsilanes: stereochemical dependence on the coordination state of the leaving silyl groups The Journal of Organic Chemistry. 52: 1100-1106. DOI: 10.1021/Jo00382A023  0.585
1987 Akita M, Kondoh A, Kawahara T, Moro-Oka Y. Conversion of a diiron μ-keten complex, FpCH2COFP (Fp = (η5-C5H5)Fe(CO)2), into binuclear cationic oxycarbene complexes and their bimodal reactivities Journal of Organometallic Chemistry. 323. DOI: 10.1016/0022-328X(87)80437-0  0.648
1987 Akita M, Matsuoka K, Asami K, Yasuda H, Nakamura A. Selective carbometallation of α,β-unsaturated carbonyl compounds and substituted oxacyclopropanes with zirconium-diene complexes Journal of Organometallic Chemistry. 327: 193-209. DOI: 10.1016/0022-328X(87)80204-8  0.51
1986 Akita M, Kondoh A, Moro-oka Y. A novel preparative method for heterobimetallic µ-η2-(C,C)-ketene complexes, Fp–CH2CO–MLn[Fp =(η5-C5H5)Fe(CO)2] Journal of the Chemical Society, Chemical Communications. 1296-1298. DOI: 10.1039/C39860001296  0.611
1986 Akita M, Kondoh A. Selective generation of ferraenolates, Li[CpFe(CO)2COCR1R2], and their reactions with electrophiles Journal of Organometallic Chemistry. 299: 369-376. DOI: 10.1016/0022-328X(86)84012-8  0.304
1984 Akita M, Yasuda H, Nakamura A. Regioselective Homo- and Codimerization of 1-Alkynes Leading to 2,4-Disubstituted 1-Buten-3-ynes by Catalysis of a (η5-C5Me5)2TiCl2/RMgX System Bulletin of the Chemical Society of Japan. 57: 480-487. DOI: 10.1246/Bcsj.57.480  0.503
1984 Yasuda H, Nagasuna K, Akita M, Lee K, Nakamura A. Zirconocene-.eta.4-1,3-pentadiene complex and its higher homologs. A new synthetic method involving .sigma.-.pi. rearrangement of the hydrido-2,4-pentadienylzirconium species Organometallics. 3: 1470-1478. DOI: 10.1021/Om00088A004  0.492
1984 Akita M, Yasuda H, Nakamura A. REGIOSELECTIVE HOMO- AND CODIMERIZATION OF 1-ALKYNES LEADING TO 2,4-DISUBSTITUTED 1-BUTEN-3-YNES BY CATALYSIS OF A (η5-C5ME5)2TICL2/RMGX SYSTEM Cheminform. 15. DOI: 10.1002/Chin.198429088  0.537
1984 Nakamura A, Yasuda H, Tatsumi K, Noda I, Mashima K, Akita M, Nagasuna K. Chemistry Of Novel Transition Metal-Diene Complexes And Their Application To Organic Synthesis Cheminform. 15. DOI: 10.1002/Chin.198416347  0.479
1984 TAMAO K, AKITA M, KUMADA M. ChemInform Abstract: SILAFUNCTIONAL COMPOUNDS IN ORGANIC SYNTHESIS. XVIII. OXIDATIVE CLEAVAGE OF THE SILICON-CARBON BOND IN ALKENYLFLUOROSILANES TO CARBONYL COMPOUNDS: SYNTHETIC AND MECHANISTIC ASPECTS Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198403155  0.602
1983 Akita M, Yasuda H, Nakamura A. ZIRCONIUM ASSISTED REGIOSELECTIVE ACYLATION OF DIENES WITH SATURATED OR UNSATURATED ESTERS TO LEAD TO β,γ-UNSATURATED CARBONYL COMPOUNDS Chemistry Letters. 12: 217-218. DOI: 10.1246/Cl.1983.217  0.481
1983 Akita M, Yasuda H, Nagasuna K, Nakamura A. Highly Stereoselective Isomerization of Monosubstituted 1-Alkenes to (E)-2-Alkenes by Catalysis of (C5Me5)2TiCl2/NaC10H8 Bulletin of the Chemical Society of Japan. 56: 554-558. DOI: 10.1246/Bcsj.56.554  0.508
1983 Kai Y, Kanehisa N, Miki K, Kasai N, Akita M, Yasuda H, Nakamura A. The X-Ray and NMR Studies on the Regio- and Stereoselective Courses for Insertion of Ketones into thes-cis- ands-trans-Diene Complexes of Zirconium Leading to (Z)-1,2-Oxazirconacyclohept-4-enes Bulletin of the Chemical Society of Japan. 56: 3735-3743. DOI: 10.1246/Bcsj.56.3735  0.507
1983 Tamao K, Kakui T, Akita M, Iwahara T, Kanatani R, Yoshida J, Kumada M. Oxidative cleavage of silicon-carbon bonds in organosilicon fluorides to alcohols Tetrahedron. 39: 983-990. DOI: 10.1016/S0040-4020(01)88597-5  0.511
1983 Tamao K, Akita M, Kumada M. Silafunctional compounds in organic synthesis Journal of Organometallic Chemistry. 254: 13-22. DOI: 10.1016/0022-328X(83)85112-2  0.561
1983 Akita M, Yasuda H, Nakamura A. ZIRCONIUM ASSISTED REGIOSELECTIVE ACYLATION OF DIENES WITH SATURATED OR UNSATURATED ESTERS TO LEAD TO β,Γ‐UNSATURATED CARBONYL COMPOUNDS Cheminform. 14. DOI: 10.1002/Chin.198336153  0.421
1983 TAMAO K, KAKUI T, AKITA M, IWAHARA T, KANATANI R, YOSHIDA J, KUMADA M. ChemInform Abstract: ORGANOFLUOROSILICATES IN ORGANIC SYNTHESIS. PART 17. OXIDATIVE CLEAVAGE OF SILICON-CARBON BONDS IN ORGANOSILICON FLUORIDES TO ALCOHOLS Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198331270  0.569
1983 Akita M, Yasuda H, Nagasuna K, Nakamura A. Highly Stereoselective Isomerization Of Monosubstituted 1-Alkenes To (E)-2-Alkenes By Catalysis Of (C5Me5)2Ticl2/Nac10H8 Cheminform. 14. DOI: 10.1002/Chin.198323110  0.435
1982 Tamao K, Yoshida J, Akita M, Sugihara Y, Iwahara T, Kumada M. Organofluorosilicates in Organic Synthesis. XVI. Synthesis of Organopentafluorosilicatesviathe Diels-Alder, Ene, and Friedel-Crafts Reaction. Their Transformations to Organic Halides and Alcohols Bulletin of the Chemical Society of Japan. 55: 255-260. DOI: 10.1246/Bcsj.55.255  0.614
1982 Tamao K, Akita M, Kanatani R, Ishida N, Kumada M. Silyl-titanation of acetylenes and 1,3-dienes Journal of Organometallic Chemistry. 226: C9-C13. DOI: 10.1016/S0022-328X(00)83399-9  0.616
1982 TAMAO K, YOSHIDA J, AKITA M, SUGIHARA Y, IWAHARA T, KUMADA M. ChemInform Abstract: ORGANOFLUOROSILICATES IN ORGANIC SYNTHESIS. XVI. SYNTHESIS OF ORGANOPENTAFLUOROSILICATES VIA THE DIELS-ALDER, ENE, AND FRIEDEL-CRAFTS REACTION. THEIR TRANSFORMATIONS TO ORGANIC HALIDES AND ALCOHOLS Chemischer Informationsdienst. 13. DOI: 10.1002/Chin.198218257  0.575
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