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C. Wade Downey - Publications

Affiliations: 
University of Richmond, Richmond, VA, United States 
Area:
organic synthesis
Website:
http://chemistry.richmond.edu/faculty/wdowney/
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40 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2022 Dixon GJ, Rodriguez MR, Chong TG, Kim KY, Downey CW. Synthesis of β,β-Disubstituted Styrenes via Trimethylsilyl Trifluoromethanesulfonate-Promoted Aldehyde-Aldehyde Aldol Coupling-Elimination. The Journal of Organic Chemistry. PMID 36239694 DOI: 10.1021/acs.joc.2c01458  0.337
2021 Oracheff ZZ, Xia HL, Poff CD, Isaacson SE, Downey CW. Friedel-Crafts Addition of Indoles to Nitrones Promoted by Trimethylsilyl Trifluoromethanesulfonate. The Journal of Organic Chemistry. PMID 34780184 DOI: 10.1021/acs.joc.1c01551  0.85
2020 Downey CW, Glist HM, Takashima A, Bottum SR, Dixon GJ. Corrigendum to “Chalcone and cinnamate synthesis via one-pot enol silane formation-Mukaiyama aldol reactions of ketones and acetate esters” [Tetrahedron Lett. 59(32) (2018) 3080–3083] Tetrahedron Letters. 61: 152669. DOI: 10.1016/j.tetlet.2020.152669  0.62
2020 Downey CW, Robertson GAL, Santa J, Flicker KR, Stith WM. One-pot silyl ketene imine formation-nucleophilic addition reactions of acetonitrile with acetals and nitrones Tetrahedron Letters. 61: 151537. DOI: 10.1016/j.tetlet.2019.151537  0.841
2019 Downey CW, Dixon GJ, Ingersoll JA, Fuller CN, MacCormac KW, Takashima A, Sediqui R. One-pot enol silane formation-Mukaiyama aldol reactions: Crossed aldehyde-aldehyde coupling, thioester substrates, and reactions in ester solvents Tetrahedron Letters. 60: 151192. DOI: 10.1016/j.tetlet.2019.151192  0.824
2018 Downey CW, Confair DN, Liu Y, Heafner ED. One-Pot Enol Silane Formation-Alkylation of Ketones with Propargyl Carboxylates Promoted by Trimethylsilyl Trifluoromethanesulfonate. The Journal of Organic Chemistry. PMID 30248260 DOI: 10.1021/acs.joc.8b01997  0.832
2018 Downey CW, Glist HM, Takashima A, Bottum SR, Dixon GJ. Chalcone and cinnamate synthesis via one-pot enol silane formation-Mukaiyama aldol reactions of ketones and acetate esters Tetrahedron Letters. 59: 3080-3083. DOI: 10.1016/j.tetlet.2018.06.066  0.852
2018 Downey CW, Johnson MW. Corrigendum to “A tandem enol silane Formation-Mukaiyama aldol reaction mediated by TMSOTf” [Tetrahedron Lett. 48 (2007) 3559–3562] Tetrahedron Letters. 59: 1268. DOI: 10.1016/J.Tetlet.2018.01.088  0.845
2017 Downey CW, Lee AY, Goodin JR, Botelho CJ, Stith WM. Mukaiyama addition of (trimethylsilyl)acetonitrile to dimethyl acetals mediated by trimethylsilyl trifluoromethanesulfonate Tetrahedron Letters. 58: 3496-3499. DOI: 10.1016/j.tetlet.2017.07.082  0.762
2016 Downey CW, Ingersoll JA, Glist HM, Dombrowski CM, Barnett AT. ChemInform Abstract: One-Pot Silyl Ketene Acetal-Formation Mukaiyama-Mannich Additions to Imines Mediated by Trimethylsilyl Trifluoromethanesulfonate. Cheminform. 47: no-no. DOI: 10.1002/chin.201615079  0.797
2015 Downey CW, Poff CD, Nizinski AN. Friedel-Crafts Hydroxyalkylation of Indoles Mediated by Trimethylsilyl Trifluoromethanesulfonate. The Journal of Organic Chemistry. 80: 10364-9. PMID 26393376 DOI: 10.1021/acs.joc.5b01681  0.808
2014 van Loon AA, Holton MK, Downey CR, White TM, Rolph CE, Bruening SR, Li G, Delaney KM, Pelkey SJ, Pelkey ET. Preparation of dibenzo[e,g]isoindol-1-ones via Scholl-type oxidative cyclization reactions. The Journal of Organic Chemistry. 79: 8049-58. PMID 25138638 DOI: 10.1021/jo501185f  0.335
2014 Downey CW, Covington SE, Obenschain DC, Halliday E, Rague JT, Confair DN. Silyl trifluoromethanesulfonate-activated para-methoxybenzyl methyl ether as an alkylating agent for thiols and aryl ketones Tetrahedron Letters. 55: 5213-5215. DOI: 10.1016/j.tetlet.2014.07.068  0.736
2014 Downey CW, Maxwell EN, Confair DN. Silyl triflate-accelerated additions of catalytically generated zinc acetylides to N-phenyl nitrones Tetrahedron Letters. 4959-4961. DOI: 10.1016/j.tetlet.2014.07.015  0.736
2013 Downey CW, Dombrowski CM, Maxwell EN, Safran CL, Akomah OA. One-pot enol silane formation/mukaiyama-mannich addition of ketones, amides, and thioesters to nitrones in the presence of trialkylsilyl trifluoromethanesulfonates European Journal of Organic Chemistry. 5716-5720. DOI: 10.1002/ejoc.201300691  0.808
2013 Downey CW, Craciun S, Neferu AM, Vivelo CA, Mueller CJ, Southall BC, Corsi S, Etchill EW, Sault R. ChemInform Abstract: One-Pot Synthesis of (Z)-β-Sulfonyl Enoates from Ethyl Propiolate. Cheminform. 44: no-no. DOI: 10.1002/chin.201304053  0.716
2013 Downey CW, Craciun S, Vivelo CA, Neferu AM, Mueller CJ, Corsi S. ChemInform Abstract: One-Pot Three-Step Thioconjugate Addition-Oxidation-Diels-Alder Reactions of Ethyl Propiolate. Cheminform. 44: no-no. DOI: 10.1002/chin.201303073  0.799
2012 Downey CW, Craciun S, Vivelo CA, Neferu AM, Mueller CJ, Corsi S. One-pot three-step thioconjugate addition-oxidation-Diels-Alder reactions of ethyl propiolate Tetrahedron Letters. 53: 5766-5768. DOI: 10.1016/j.tetlet.2012.08.054  0.792
2012 Downey CW, Craciun S, Neferu AM, Vivelo CA, Mueller CJ, Southall BC, Corsi S, Etchill EW, Sault RJ. One-pot synthesis of (Z)-β-sulfonyl enoates from ethyl propiolate Tetrahedron Letters. 53: 5763-5765. DOI: 10.1016/j.tetlet.2012.08.051  0.707
2011 Greger JG, Yoon-Miller SJ, Bechtold NR, Flewelling SA, MacDonald JP, Downey CR, Cohen EA, Pelkey ET. Synthesis of unsymmetrical 3,4-diaryl-3-pyrrolin-2-ones utilizing pyrrole Weinreb amides. The Journal of Organic Chemistry. 76: 8203-14. PMID 21913662 DOI: 10.1021/jo2013516  0.547
2011 Greger JG, Yoon-Miller SJ, Bechtold NR, Flewelling SA, MacDonald JP, Downey CR, Cohen EA, Pelkey ET. Synthesis of unsymmetrical 3,4-diaryl-3-pyrrolin-2-ones utilizing pyrrole Weinreb amides. The Journal of Organic Chemistry. 76: 8203-14. PMID 21913662 DOI: 10.1021/jo2013516  0.547
2011 Downey CW, Fleisher AS, Rague JT, Safran CL, Venable ME, Pike RD. Synthesis of N-acyl-N,O-acetals from N-aryl amides and acetals in the presence of TMSOTf Tetrahedron Letters. 52: 4756-4759. DOI: 10.1016/J.Tetlet.2011.07.023  0.795
2010 Downey CW, Johnson MW, Lawrence DH, Fleisher AS, Tracy KJ. Acetic acid aldol reactions in the presence of trimethylsilyl trifluoromethanesulfonate. The Journal of Organic Chemistry. 75: 5351-4. PMID 20590083 DOI: 10.1021/Jo100828C  0.837
2010 Evans DA, Tedrow JS, Shaw JT, Downey CW. ChemInform Abstract: Diastereoselective Magnesium Halide-Catalyzed anti-Aldol Reactions of Chiral N-Acyloxazolidinones. Cheminform. 33: no-no. DOI: 10.1002/chin.200226034  0.846
2010 Evans DA, Scheidt KA, Downey CW. ChemInform Abstract: Synthesis of (-)-Epibatidine Cheminform. 33: no-no. DOI: 10.1002/chin.200204220  0.803
2009 Downey CW, Mahoney BD, Lipari VR. Trimethylsilyl trifluoromethanesulfonate-accelerated addition of catalytically generated zinc acetylides to aldehydes. The Journal of Organic Chemistry. 74: 2904-6. PMID 19260695 DOI: 10.1021/jo900102w  0.804
2008 Downey CW, Johnson MW, Tracy KJ. One-pot enol silane formation-Mukaiyama aldol-type addition to dimethyl acetals mediated by TMSOTf. The Journal of Organic Chemistry. 73: 3299-302. PMID 18335962 DOI: 10.1021/Jo8001084  0.875
2008 O'Halloran N, James JP, Downey CA, O'Malley P, Duff T, Bertrand S. Inter-and intra-molecular cyclisation reactions of azoacetates derived from aryl hydrazones of ethyl acetoacetate and acetoacetanilides Heterocycles. 75: 2681-2701. DOI: 10.3987/COM-08-11433  0.528
2007 Downey CW, Johnson MW. A tandem enol silane formation-Mukaiyama aldol reaction mediated by TMSOTf Tetrahedron Letters. 48: 3559-3562. DOI: 10.1016/J.Tetlet.2007.03.088  0.87
2007 Downey CW, Johnson MW. A Tandem Enol Silane Formation—Mukaiyama Aldol Reaction Mediated by TMSOTf. Cheminform. 38. DOI: 10.1002/chin.200735102  0.747
2005 Suárez A, Downey CW, Fu GC. Kinetic resolutions of azomethine imines via copper-catalyzed [3 + 2] cycloadditions. Journal of the American Chemical Society. 127: 11244-5. PMID 16089444 DOI: 10.1021/Ja052876H  0.822
2004 Smith TE, Djang M, Velander AJ, Downey CW, Carroll KA, Van Alphen S. Versatile asymmetric synthesis of the kavalactones: first synthesis of (+)-kavain. Organic Letters. 6: 2317-20. PMID 15228268 DOI: 10.1021/ol0493960  0.853
2003 Evans DA, Seidel D, Rueping M, Lam HW, Shaw JT, Downey CW. A new copper acetate-bis(oxazoline)-catalyzed, enantioselective Henry reaction. Journal of the American Chemical Society. 125: 12692-3. PMID 14558801 DOI: 10.1021/Ja0373871  0.84
2003 Evans DA, Downey CW, Hubbs JL. Ni(II) bis(oxazoline)-catalyzed enantioselective syn aldol reactions of N-propionylthiazolidinethiones in the presence of silyl triflates. Journal of the American Chemical Society. 125: 8706-7. PMID 12862448 DOI: 10.1021/Ja035509J  0.849
2003 Kosmrlj J, Weigel LO, Evans DA, Downey CW, Wu J. Unfunctionalized, alpha-epimerizable nonracemic ketones and aldehydes can be accessed by crystallization-induced dynamic resolution of imines. Journal of the American Chemical Society. 125: 3208-9. PMID 12630864 DOI: 10.1021/Ja029715N  0.794
2002 Evans DA, Downey CW, Shaw JT, Tedrow JS. Magnesium halide-catalyzed anti-aldol reactions of chiral N-acylthiazolidinethiones. Organic Letters. 4: 1127-30. PMID 11922799 DOI: 10.1021/Ol025553O  0.856
2002 Evans DA, Tedrow JS, Shaw JT, Downey CW. Diastereoselective magnesium halide-catalyzed anti-aldol reactions of chiral N-acyloxazolidinones. Journal of the American Chemical Society. 124: 392-3. PMID 11792206 DOI: 10.1021/Ja0119548  0.848
2001 Evans DA, Scheidt KA, Downey CW. Synthesis of (-)-epibatidine. Organic Letters. 3: 3009-12. PMID 11554830 DOI: 10.1021/Ol016420Q  0.86
2001 Evans DA, Rovis T, Kozlowski MC, Downey CW, Tedrow JS. ChemInform Abstract: Enantioselective Lewis Acid Catalyzed Michael Reactions of Alkylidene Malonates. Catalysis by C2-Symmetric Bis(oxazoline) Copper(II) Complexes in the Synthesis of Chiral, Differentiated Glutarate Esters. Cheminform. 32: no-no. DOI: 10.1002/chin.200103030  0.839
2000 Evans DA, Rovis T, Kozlowski MC, Downey CW, Tedrow JS. Enantioselective Lewis acid catalyzed Michael reactions of alkylidene malonates. Catalysis by C2-symmetric bis(oxazoline) copper(II) complexes in the synthesis of chiral, differentiated glutarate esters Journal of the American Chemical Society. 122: 9134-9142. DOI: 10.1021/Ja002246+  0.826
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