Selwyn Frank Mapolie, PhD - Publications

Affiliations: 
1991-2007 Chemistry University of the Western Cape 
 2008-2021 chemistry and polymer Science Stellenbosch University, Stellenbosch, Western Cape, South Africa 
Area:
Organometallics, catalysis, coordination chemistry
Website:
https://www0.sun.ac.za/chemistry/smapolie.php

74 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 van Niekerk A, Joseph MC, Kavanagh A, Dinh H, Swarts AJ, Mapolie SF, Zuegg J, Cain AK, Elliott AG, Blaskovich MAT, Frei A. The antimicrobial properties of Pd(II)- and Ru(II)-pyta complexes. Chembiochem : a European Journal of Chemical Biology. e202300247. PMID 37593808 DOI: 10.1002/cbic.202300247  0.788
2023 van Niekerk A, Blanckenberg A, Kimani S, Chakraborty S, Prince S, Chellan P, Mapolie S. DNA-binding affinity and molecular docking studies of the PEGylated binuclear palladacycle, BTC2, an efficient metallodrug against triple-negative breast cancer. Journal of Inorganic Biochemistry. 243: 112191. PMID 36996694 DOI: 10.1016/j.jinorgbio.2023.112191  0.644
2021 Kimani S, Chakraborty S, Irene I, de la Mare J, Edkins A, du Toit A, Loos B, Blanckenberg A, Van Niekerk A, Costa-Lotufo LV, ArulJothi KN, Mapolie S, Prince S. The palladacycle, BTC2, exhibits anti-breast cancer and breast cancer stem cell activity. Biochemical Pharmacology. 114598. PMID 33979647 DOI: 10.1016/j.bcp.2021.114598  0.606
2020 Williams C, Ferreira M, Tilloy S, Monflier E, Mapolie SF, Smith GS. Fréchet-type metallodendrons with N,P-iminophosphine Rh(I) complexes at the focal point: Synthesis and evaluation in the hydroformylation of 1-octene Inorganica Chimica Acta. 502: 119341. DOI: 10.1016/J.Ica.2019.119341  0.575
2020 October J, Mapolie SF. Alkylation of Amines Via Tandem Hydroaminomethylation Using Imino-Pyridine Complexes of Rhodium as Catalyst Precursors Catalysis Letters. 150: 998-1010. DOI: 10.1007/S10562-019-02998-Y  0.824
2020 Joseph MC, Swarts AJ, Mapolie SF. Palladium (II) complexes chelated by 1‐substituted‐4‐pyridyl‐ 1H ‐1,2,3‐triazole ligands as catalyst precursors for selective ethylene dimerization Applied Organometallic Chemistry. 34. DOI: 10.1002/Aoc.5595  0.827
2019 Leckie L, Mapolie SF. Triazole complexes of ruthenium immobilized on mesoporous silica as recyclable catalysts for octane oxidation Catalysis Communications. 131: 105803. DOI: 10.1016/J.Catcom.2019.105803  0.829
2019 Niekerk Av, Chellan P, Mapolie SF. Heterometallic Multinuclear Complexes as Anti‐Cancer Agents‐An Overview of Recent Developments European Journal of Inorganic Chemistry. 2019: 3432-3455. DOI: 10.1002/Ejic.201900375  0.391
2018 Joseph MC, Swarts AJ, Mapolie SF. Phenylacetylene polymerisation mediated by cationic cyclometallated palladium(ii) complexes bearing benzylidene 2,6-diisopropylphenylamine and its derivatives as ligands. Dalton Transactions (Cambridge, England : 2003). PMID 30046800 DOI: 10.1039/C8Dt02728E  0.808
2018 Williams C, Ferreira M, Monflier E, Mapolie SF, Smith GS. Synthesis and hydroformylation evaluation of Fréchet-type organometallic dendrons with N,O-salicylaldimine Rh(i) complexes at the focal point. Dalton Transactions (Cambridge, England : 2003). PMID 29953165 DOI: 10.1039/C8Dt01874J  0.585
2018 Leckie L, Mapolie SF. Mesoporous silica as phase transfer agent in the biphasic oxidative cleavage of alkenes using triazole complexes of ruthenium as catalyst precursors Applied Catalysis a-General. 565: 76-86. DOI: 10.1016/J.Apcata.2018.07.038  0.817
2017 Marais L, Burés J, Jordaan JHL, Mapolie S, Swarts AJ. A bis(pyridyl)-N-alkylamine/Cu(i) catalyst system for aerobic alcohol oxidation. Organic & Biomolecular Chemistry. PMID 28776055 DOI: 10.1039/C7Ob01383C  0.782
2017 October J, Mapolie SF. Synthesis and characterization of novel rhodium and ruthenium based iminopyridyl complexes and their application in 1-octene hydroformylation Journal of Organometallic Chemistry. 840: 1-10. DOI: 10.1016/J.Jorganchem.2017.03.049  0.819
2017 Kotzé H, Mapolie S. Cationic ruthenium(II) complexes supported on mesoporous silica as catalyst precursors in the selective oxidative cleavage of 1‐octene Applied Organometallic Chemistry. 31. DOI: 10.1002/Aoc.3643  0.805
2016 Bleloch J, Ballim R, Aliwaini S, Mapolie S, Prince S. Investigating a novel binuclear palladacycle complex for anti-cancer activity in rhabdomyosarcoma cells European Journal of Cancer. 61: S138. DOI: 10.1016/S0959-8049(16)61487-9  0.334
2016 Mketo N, Jordaan JHL, Jordaan A, Swarts AJ, Mapolie SF. Synthesis, Characterization, and Catalytic Application of Mononuclear and Dendritic Cationic CuI Iminopyridine‐Ligated Complexes in Aryl Iodide Hydroxylation European Journal of Inorganic Chemistry. 2016: 3781-3790. DOI: 10.1002/Ejic.201600417  0.808
2015 Zheng F, Hutton AT, van Sittert CG, Gerber WJ, Mapolie SF. Cyclometallated platinum(II) complexes of benzylidene-2,6-di-isopropylphenylamine containing bidentate phosphines: synthesis, structural properties and reactivity studies. Dalton Transactions (Cambridge, England : 2003). 44: 1969-81. PMID 25504380 DOI: 10.1039/C4Dt02375G  0.624
2015 Matsinha LC, Mapolie SF, Smith GS. Recoverable and recyclable water-soluble sulphonated salicylaldimine Rh(I) complexes for 1-octene hydroformylation in aqueous biphasic media. Dalton Transactions (Cambridge, England : 2003). 44: 1240-8. PMID 25415263 DOI: 10.1039/C4Dt02740J  0.627
2015 Cloete J, Mapolie SF, Malgas-Enus R. Facile synthesis and characterization of PTA stabilized hydrophilic Au55 nanoparticles via a DEN–MPC method Polyhedron. 102: 469-478. DOI: 10.1016/J.Poly.2015.09.043  0.747
2015 Malgas-Enus R, Mapolie SF. Corrigendum to “Nickel metallodendrimers as catalyst precursors in the tandem oligomerization of ethylene and Friedel–Crafts alkylation of its olefinic products” [Inorg. Chim. Acta 409 (2014) 96–105] Inorganica Chimica Acta. 428: 212. DOI: 10.1016/J.Ica.2015.02.015  0.826
2015 Matsinha LC, Mao J, Mapolie SF, Smith GS. Water-Soluble Palladium(II) Sulfonated Thiosemicarbazone Complexes: Facile Synthesis and Preliminary Catalytic Studies in the Suzuki-Miyaura Cross-Coupling Reaction in Water European Journal of Inorganic Chemistry. DOI: 10.1002/Ejic.201500588  0.552
2014 Swarts AJ, Mapolie SF. The synthesis and application of novel Ni(II) N-alkyl dipyridylaldiminato complexes as selective ethylene oligomerisation catalysts. Dalton Transactions (Cambridge, England : 2003). 43: 9892-900. PMID 24848302 DOI: 10.1039/C4Dt00537F  0.789
2014 Mahamo T, Moss JR, Mapolie SF, Smith GS, Slootweg JC, Lammertsma K. Platinacycloalkane complexes containing [P,N] bidentate ligands: synthesis and decomposition studies. Dalton Transactions (Cambridge, England : 2003). 43: 5546-57. PMID 24549177 DOI: 10.1039/C3Dt52798K  0.662
2014 Swarts AJ, Zheng F, Smith VJ, Nordlander E, Mapolie SF. Reactivity of bis(pyridyl)- N -alkylaminato methylpalladium complexes toward ethylene: insights from experiment and theory Organometallics. 33: 2247-2256. DOI: 10.1021/Om5001293  0.831
2014 Malgas-Enus R, Mapolie SF. Nickel metallodendrimers as catalyst precursors in the tandem oligomerization of ethylene and Friedel–Crafts alkylation of its olefinic products Inorganica Chimica Acta. 409: 96-105. DOI: 10.1016/J.Ica.2013.06.016  0.839
2013 Aliwaini S, Swarts AJ, Blanckenberg A, Mapolie S, Prince S. A novel binuclear palladacycle complex inhibits melanoma growth in vitro and in vivo through apoptosis and autophagy. Biochemical Pharmacology. 86: 1650-63. PMID 24099796 DOI: 10.1016/J.Bcp.2013.09.020  0.725
2013 Zheng F, Hutton AT, van Sittert CG, Moss JR, Mapolie SF. Synthesis, structural characterization and cis-trans isomerization of novel (salicylaldiminato)platinum(II) complexes. Dalton Transactions (Cambridge, England : 2003). 42: 11163-79. PMID 23807670 DOI: 10.1039/C3Dt51283E  0.681
2013 Matsinha LC, Mapolie SF, Smith GS. Synthesis and characterization of mono- and binuclear iminopyridyl and salicylaldimine Ru(II)–arene complexes Polyhedron. 53: 56-61. DOI: 10.1016/J.Poly.2013.01.014  0.464
2013 Mapolie SF, Wyk JLv. Synthesis and characterization of dendritic salicylaldimine complexes of copper and cobalt and their use as catalyst precursors in the aerobic hydroxylation of phenol Inorganica Chimica Acta. 394: 649-655. DOI: 10.1016/J.Ica.2012.09.006  0.508
2013 Matsinha LC, Malatji P, Hutton AT, Venter GA, Mapolie SF, Smith GS. Water-Soluble Half-Sandwich RuII-Arene Complexes: Synthesis, Structure, Electrochemistry, DFT Studies, and Aqueous Phase Hydroformylation of 1-Octene European Journal of Inorganic Chemistry. 2013: 4318-4328. DOI: 10.1002/Ejic.201300503  0.664
2012 Malinga SP, Arotiba OA, Krause RW, Mapolie SF, Mamba BB. Synthesis and characterisation of generation 2 and 3 poly(propylene imine) dendrimer capped NiFe nanoalloy Materials Letters. 68: 324-326. DOI: 10.1016/J.Matlet.2011.11.011  0.33
2012 Mahamo T, Mogorosi MM, Moss JR, Mapolie SF, Chris Slootweg J, Lammertsma K, Smith GS. Neutral palladium(II) complexes with P,N Schiff-base ligands: Synthesis, characterization and application as Suzuki-Miyaura coupling catalysts Journal of Organometallic Chemistry. 703: 34-42. DOI: 10.1016/J.Jorganchem.2011.12.021  0.745
2012 Sibanyoni JM, Bagihalli GB, Mapolie SF. Binuclear Pd-methyl complexes of N,N' -{1, n }-alkanediyl- bis (pyridinyl-2-methanimine) ligands ( n = 5, 8, 9, 10 and 12): Evaluation as catalysts precursors for phenylacetylene polymerization Journal of Organometallic Chemistry. 700: 93-102. DOI: 10.1016/J.Jorganchem.2011.11.019  0.555
2012 Ahamad T, Mapolie SF, Alshehri SM. Synthesis and characterization of polyamide metallodendrimers and their anti-bacterial and anti-tumor activities Medicinal Chemistry Research. 21: 2023-2031. DOI: 10.1007/S00044-011-9715-0  0.56
2011 Mungwe N, Swarts A, Mapolie S, Westman G. Cationic palladacycles as catalyst precursors for phenyl acetylene polymerization Journal of Organometallic Chemistry. 696: 3527-3535. DOI: 10.1016/J.Jorganchem.2011.07.044  0.821
2011 Mogorosi MM, Mahamo T, Moss JR, Mapolie SF, Slootweg JC, Lammertsma K, Smith GS. Neutral palladium(II) complexes with P,N Schiff-base ligands: Synthesis, characterization and catalytic oligomerisation of ethylene Journal of Organometallic Chemistry. 696: 3585-3592. DOI: 10.1016/J.Jorganchem.2011.07.042  0.743
2011 Bhunora S, Mugo J, Bhaw-Luximon A, Mapolie S, Van Wyk J, Darkwa J, Nordlander E. The use of Cu and Zn salicylaldimine complexes as catalyst precursors in ring opening polymerization of lactides: Ligand effects on polymer characteristics Applied Organometallic Chemistry. 25: 133-145. DOI: 10.1002/Aoc.1728  0.806
2010 Mugo JN, Mapolie SF, Wyk JLv. Cu(II) and Ni(II) complexes based on monofunctional and dendrimeric pyrrole-imine ligands: Applications in catalytic liquid phase hydroxylation of phenol Inorganica Chimica Acta. 363: 2643-2651. DOI: 10.1016/J.Ica.2010.05.010  0.793
2010 Ahamad T, Alshehri SM, Mapolie SF. Synthesis characterization of polyamide metallodendrimers and their catalytic activities in ethylene oligomerization Catalysis Letters. 138: 171-179. DOI: 10.1007/S10562-010-0393-1  0.64
2009 Ojwach SO, Guzei IA, Benade LL, Mapolie SF, Darkwa J. (Pyrazol-1-ylmethyl)pyridine Nickel Complexes: Ethylene Oligomerization and Unusual Friedel−Crafts Alkylation Catalysts Organometallics. 28: 2127-2133. DOI: 10.1021/Om8006322  0.362
2009 Malumbazo N, Mapolie SF. Silica immobilized salicylaldimine Cu(II) and Co(II) complexes as catalysts in cyclohexene oxidation: A comparative study of support effects Journal of Molecular Catalysis a-Chemical. 312: 70-77. DOI: 10.1016/J.Molcata.2009.07.006  0.78
2008 Nelana SM, Cloete J, Lisensky GC, Nordlander E, Guzei IA, Mapolie SF, Darkwa J. Unconjugated diimine palladium complexes as Heck coupling catalysts Journal of Molecular Catalysis a: Chemical. 285: 72-78. DOI: 10.1016/J.Molcata.2008.01.009  0.814
2008 Malgas-Enus R, Mapolie SF, Smith GS. Norbornene polymerization using multinuclear nickel catalysts based on a polypropyleneimine dendrimer scaffold Journal of Organometallic Chemistry. 693: 2279-2286. DOI: 10.1016/J.Jorganchem.2008.03.029  0.833
2008 Wyk JLv, Mapolie SF, Lennartson A, Håkansson M, Jagner S. The catalytic oxidation of phenol in aqueous media using cobalt(II) complexes derived from N-(aryl) salicylaldimines Inorganica Chimica Acta. 361: 2094-2100. DOI: 10.1016/J.Ica.2007.10.031  0.517
2008 Martinovic J, Chiorcea-Paquim AM, Diculescu VC, Van Wyk J, Iwuoha E, Baker P, Mapolie S, Oliveira-Brett AM. Metallo-functionalized first-generation salicylaldimine poly(propylenimine) tetraamine dendrimers: Electrochemical study and atomic force microscopy imaging Electrochimica Acta. 53: 4907-4919. DOI: 10.1016/J.Electacta.2008.02.013  0.368
2008 Malgas R, Mapolie S, Ojwach S, Smith G, Darkwa J. The application of novel dendritic nickel catalysts in the oligomerization of ethylene Catalysis Communications. 9: 1612-1617. DOI: 10.1016/J.Catcom.2008.01.009  0.653
2007 van Wyk JL, Mapolie S, Lennartson A, Håkansson M, Jagner S. The Synthesis of Copper(II) Salicylaldiminato Complexes and their Catalytic Activity in the Hydroxylation of Phenol Zeitschrift FüR Naturforschung B. 62: 331-338. DOI: 10.1515/Znb-2007-0305  0.519
2007 Ojwach SO, Guzei IA, Darkwa J, Mapolie SF. Palladium complexes of multidentate pyrazolylmethyl pyridine ligands: Synthesis, structures and phenylacetylene polymerization Polyhedron. 26: 851-861. DOI: 10.1016/J.Poly.2006.09.007  0.32
2007 Ray S, Mapolie SF, Darkwa J. Catalytic hydroxylation of phenol using immobilized late transition metal salicylaldimine complexes Journal of Molecular Catalysis a-Chemical. 267: 143-148. DOI: 10.1016/J.Molcata.2006.11.031  0.75
2007 Abbo HS, Mapolie SF, Darkwa J, Titinchi SJJ. Bis(pyrazolyl)pyridine vanadium(III) complexes as highly active ethylene polymerization catalysts Journal of Organometallic Chemistry. 692: 5327-5330. DOI: 10.1016/J.Jorganchem.2007.08.035  0.562
2006 Cloete J, Mapolie SF. Functionalized pyridinyl???imine complexes of palladium as catalyst precursors for ethylene polymerization Journal of Molecular Catalysis a-Chemical. 243: 221-225. DOI: 10.1016/J.Molcata.2005.08.002  0.836
2005 Ojwach SO, Tshivhase MG, Guzei IA, Darkwa J, Mapolie SF. Furoyl and thiophene carbonyl linker pyrazolyl palladium(II) complexes — Synthesis, characterization, and evaluation as ethylene oligomerization catalysts Canadian Journal of Chemistry. 83: 843-853. DOI: 10.1139/V05-092  0.349
2005 Mohlala MS, Guzei IA, Darkwa J, Mapolie SF. Pyridine linker pyrazolyl palladium complexes: Synthesis, characterization and ethylene polymerization activity Journal of Molecular Catalysis a: Chemical. 241: 93-100. DOI: 10.1016/J.Molcata.2005.06.040  0.493
2004 Smith GS, Mapolie SF. Iminopyridyl-palladium dendritic catalyst precursors: evaluation in Heck reactions Journal of Molecular Catalysis a: Chemical. 213: 187-192. DOI: 10.1016/J.Molcata.2003.12.010  0.562
2004 Meijboom R, Moss JR, Hutton AT, Makaluza TA, Mapolie SF, Waggie F, Domingo MR. Hydrozirconation of first-generation allyl-functionalized dendrimers and dendrimer model compounds Journal of Organometallic Chemistry. 689: 1876-1881. DOI: 10.1016/J.Jorganchem.2004.03.010  0.72
2004 Nelana SM, Darkwa J, Guzei IA, Mapolie SF. Ethylene polymerization catalyzed by substituted pyrazole nickel complexes Journal of Organometallic Chemistry. 689: 1835-1842. DOI: 10.1016/J.Jorganchem.2004.03.005  0.487
2003 Guzei IA, Li K, Bikzhanova GA, Darkwa J, Mapolie SF. Benzenedicarbonyl and benzenetricarbonyl linker pyrazolyl complexes of palladium(II): Synthesis, X-ray structures and evaluation as ethylene polymerisation catalysts Journal of the Chemical Society. Dalton Transactions. 715-722. DOI: 10.1039/B208376K  0.493
2003 Chen R, Mapolie SF. Catalyst precursors for ethylene polymerization based on novel mono- and bi-nuclear pyridylimine-type palladium(II) complexes with long straight chain alkyl substituents at the imino nitrogen Journal of Molecular Catalysis a-Chemical. 193: 33-40. DOI: 10.1016/S1381-1169(02)00456-9  0.602
2003 Chen R, Bacsa J, Mapolie SF. {N-alkyl-N-[pyridin-2-ylmethylene] amine}dichloro palladium(II) complexes: synthesis, crystal structures and evaluation of their catalytic activities for ethylene polymerization Polyhedron. 22: 2855-2861. DOI: 10.1016/S0277-5387(03)00410-8  0.575
2003 Smith G, Chen R, Mapolie S. The synthesis and catalytic activity of a first-generation poly(propylene imine) pyridylimine palladium metallodendrimer Journal of Organometallic Chemistry. 673: 111-115. DOI: 10.1016/S0022-328X(03)00173-6  0.649
2003 Iovu MC, Maithufi NG, Mapolie SF. Evaluation of bis(2‐pyridinal)ethylenediimine as ligand for atom transfer radical polymerization of methyl methacrylate: influence of polar solvents Polymer International. 52: 899-907. DOI: 10.1002/Pi.1124  0.454
2003 Iovu M, Maithufi N, Mapolie S. Copper‐mediated ATRP of methyl methacrylate in polar solvents using a bifunctional pyridinal diimine ligand Macromolecular Symposia. 193: 209-226. DOI: 10.1002/Masy.200390054  0.335
2002 Li K, Darkwa J, Guzei IA, Mapolie SF. Synthesis and evaluation of substituted pyrazoles palladium(II) complexes as ethylene polymerization catalysts Journal of Organometallic Chemistry. 660: 108-115. DOI: 10.1016/S0022-328X(02)01799-0  0.503
2002 Mapolie SF, Mavunkal IJ, Moss JR, Smith GS. The synthesis, characterization and polycondensation of metal-containing diols: Crystal structure of [(η5-C5H5) (CO)2Fe(CH2)3O- {2,6-(CH2OH)2-4- CH3-C6H2}] Applied Organometallic Chemistry. 16: 307-314. DOI: 10.1002/Aoc.301  0.643
2001 Dooling D, Joorst G, Mapolie SF. The synthesis, characterization and some reactions of cationic η2-(α,ω-diene) complexes of iron Polyhedron. 20: 467-476. DOI: 10.1016/S0277-5387(00)00649-5  0.74
2001 Iovu M, Mapolie S, Britchi AG. Styrene‐butadiene rubber synthesized by anionic polymerization Macromolecular Symposia. 165: 55-62. DOI: 10.1002/1521-3900(200103)165:1<55::Aid-Masy55>3.0.Co;2-N  0.322
1999 Joorst G, Karlie R, Mapolie S. The synthesis and characterisation of a new series of ω-hydroxy-alkyl complexes of iron Polyhedron. 18: 3377-3381. DOI: 10.1016/S0277-5387(99)00252-1  0.349
1998 Mapolie SF, Moss JR, Smith GS. The synthesis and characterization of metal-containing vinylic monomers of iron and tungsten Applied Organometallic Chemistry. 12: 801-807. DOI: 10.1002/(Sici)1099-0739(199812)12:12<801::Aid-Aoc751>3.0.Co;2-T  0.64
1997 Hermans L, Mapolie SF. Reactivity studies on some η1-alkenyl complexes of iron Polyhedron. 16: 869-875. DOI: 10.1016/S0277-5387(96)00295-1  0.383
1991 Finch KP, Gafoor MA, Mapolie SF, Moss JR. A comparative study of the reactivity of some dinuclear alkanediyl complexes of the type [L(CO)2M(CH2)nM(CO)2L] (where M = Fe and L = η5-C5H5, η-C5H4Me or η5-C5Me5 and n = 4-6 or M = Ru and L = η5-C5H5 and n = 5) Polyhedron. 10: 963-972. DOI: 10.1016/S0277-5387(00)86916-8  0.557
1991 Mapolie SF, Moss JR. The synthesis and reactivity of some μ-phthaloyl and μ-phenylene complexes Polyhedron. 10: 717-723. DOI: 10.1016/S0277-5387(00)83759-6  0.615
1990 Mapolie SF, Moss JR. Synthesis and reactivity of the μ(1,n)-alkanediyl complexes [(OC)5M(CH2)nM(CO)5] (M = Mn, n = 4-6; M = Re, n = 3 or 4) Journal of the Chemical Society, Dalton Transactions. 299-305. DOI: 10.1039/Dt9900000299  0.573
1988 Mapolie SF, Moss JR. Alkanediyl Complexes of Iron and Other Transition Metals Organometallic Syntheses. 198-204. DOI: 10.1016/B978-0-444-42956-8.50054-2  0.533
1985 Mapolie SF, Moss JR, Scott LG. The synthesis and reactivity of μ(1,4)-butanediylbis(manganese pentacarbonyl) Journal of Organometallic Chemistry. 297: c1-c4. DOI: 10.1016/0022-328X(85)80403-4  0.566
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