Robert Flowers - Publications

Affiliations: 
Lehigh University, Bethlehem, PA, United States 
Area:
organic, physical organic

106 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Boekell NG, Bartulovich CO, Maity S, Flowers RA. Accessing Unusual Reactivity through Chelation-Promoted Bond Weakening. Inorganic Chemistry. 62: 5040-5045. PMID 36912617 DOI: 10.1021/acs.inorgchem.3c00298  0.799
2022 Boekell NG, Flowers RA. Coordination-Induced Bond Weakening. Chemical Reviews. PMID 35900048 DOI: 10.1021/acs.chemrev.2c00254  0.795
2021 Ramírez-Solís A, Boekell NG, León-Pimentel CI, Saint-Martin H, Bartulovich CO, Flowers RA. Ammonia Solvation vs Aqueous Solvation of Samarium Diiodide. A Theoretical and Experimental Approach to Understanding Bond Activation Upon Coordination to Sm(II). The Journal of Organic Chemistry. PMID 34775764 DOI: 10.1021/acs.joc.1c01771  0.802
2020 Ramírez-Solís A, Bartulovich CO, León-Pimentel CI, Saint-Martin H, Boekell NG, Flowers RA. Proton donor effects on the reactivity of SmI. Experimental and theoretical studies on methanol solvation vs. aqueous solvation. Dalton Transactions (Cambridge, England : 2003). PMID 32483561 DOI: 10.1039/d0dt01221a  0.81
2019 Ramírez-Solís A, Bartulovich CO, León-Pimentel CI, Saint-Martin H, Anderson WR, Flowers RA. Experimental and Theoretical Studies on the Aqueous Solvation and Reactivity of SmCl and Comparison with SmBr and SmI. Inorganic Chemistry. PMID 31584813 DOI: 10.1021/acs.inorgchem.9b01818  0.808
2019 Bartulovich CO, Flowers RA. Coordination-induced O-H bond weakening in Sm(ii)-water complexes. Dalton Transactions (Cambridge, England : 2003). 48: 16142-16147. PMID 31549703 DOI: 10.1039/c9dt03352a  0.825
2019 Flowers RA, Maity S, Hoz S, Nimkar A. Contrasting Effect of Additives on Photoinduced Reactions of SmI2 Amey Nimkar,[a] Sandeepan Maity,[b] Robert A Flowers II*[b] and Shmaryahu Hoz*[a]. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31150561 DOI: 10.1002/Chem.201901997  0.799
2019 Maity S, Flowers RA. Mechanistic Study and Development of Catalytic Reactions of Sm(II). Journal of the American Chemical Society. PMID 30685971 DOI: 10.1021/Jacs.8B13119  0.756
2018 Ramirez-Solis A, Bartulovich C, Chciuk TV, Hernández-Cobos J, Saint-Martin H, Maron L, Anderson WR, Li AM, Flowers RA. Experimental and Theoretical Studies on the Implications of Halide Dependent Aqueous Solvation of Sm(II). Journal of the American Chemical Society. PMID 30412400 DOI: 10.1021/Jacs.8B09857  0.792
2018 Chciuk TV, Anderson WR, Flowers RA. Interplay between Substrate and Proton Donor Coordination in Reductions of Carbonyls by SmI-Water Through Proton-Coupled Electron-Transfer. Journal of the American Chemical Society. PMID 30379544 DOI: 10.1021/jacs.8b08890  0.829
2018 Chciuk TV, Maity S, Flowers RA. Kinetic solvent effects in the reduction of alkyl halides by {Sm[N(SiMe3)2]2(THF)2} Journal of Organometallic Chemistry. 857: 52-57. DOI: 10.1016/J.Jorganchem.2017.10.018  0.795
2018 Richrath RB, Olyschläger T, Hildebrandt S, Enny DG, Fianu GD, Flowers RA, Gansäuer A. Front Cover: Cp2 TiX Complexes for Sustainable Catalysis in Single-Electron Steps (Chem. Eur. J. 24/2018) Chemistry - a European Journal. 24: 6282-6282. DOI: 10.1002/Chem.201800784  0.787
2017 Flowers RA, Hoz S, Maity S. Aza vs. Oxophilicity of SmI2: A Break of a Paradigm. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29024166 DOI: 10.1002/Chem.201703394  0.789
2017 Chciuk TV, Anderson WR, Flowers RA. Reversibility of Ketone Reduction by SmI2–Water and Formation of Organosamarium Intermediates Organometallics. 36: 4579-4583. DOI: 10.1021/acs.organomet.7b00392  0.795
2016 Chciuk TV, Li AM, Vazquez-Lopez A, Anderson WR, Flowers RA. Secondary Amides as Hydrogen Atom Transfer Promoters for Reactions of Samarium Diiodide. Organic Letters. PMID 28001419 DOI: 10.1021/acs.orglett.6b03664  0.795
2016 Chciuk TV, Anderson WR, Flowers RA. Proton-Coupled Electron Transfer in the Reduction of Carbonyls by Samarium Diiodide-Water Complexes. Journal of the American Chemical Society. PMID 27367158 DOI: 10.1021/jacs.6b05879  0.815
2016 Chciuk TV, Anderson WR, Flowers RA. High-Affinity Proton Donors Promote Proton-Coupled Electron Transfer by Samarium Diiodide. Angewandte Chemie (International Ed. in English). PMID 27061351 DOI: 10.1002/anie.201601474  0.814
2015 Chciuk TV, Flowers RA. Proton-Coupled Electron Transfer in the Reduction of Arenes by SmI2-Water Complexes. Journal of the American Chemical Society. 137: 11526-31. PMID 26273964 DOI: 10.1021/jacs.5b07518  0.819
2015 Patel NR, Flowers RA. Mechanistic study of silver-catalyzed decarboxylative fluorination. The Journal of Organic Chemistry. 80: 5834-41. PMID 25927595 DOI: 10.1021/acs.joc.5b00826  0.547
2015 Gansäuer A, Hildebrandt S, Michelmann A, Dahmen T, von Laufenberg D, Kube C, Fianu GD, Flowers RA. Cationic Titanocene(III) Complexes for Catalysis in Single-Electron Steps. Angewandte Chemie (International Ed. in English). 54: 7003-6. PMID 25924582 DOI: 10.1002/Anie.201501955  0.809
2015 Gansäuer A, von Laufenberg D, Kube C, Dahmen T, Michelmann A, Behlendorf M, Sure R, Seddiqzai M, Grimme S, Sadasivam DV, Fianu GD, Flowers RA. Mechanistic study of the titanocene(III)-catalyzed radical arylation of epoxides. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 280-9. PMID 25351963 DOI: 10.1002/Chem.201404404  0.813
2015 Chciuk TV, Boland BP, Flowers RA. Mechanistic study of the samarium diiodide - N,N-dimethyl-2-aminoethanol reducing system Tetrahedron Letters. 56: 3212-3215. DOI: 10.1016/j.tetlet.2014.12.095  0.762
2015 Gerhart J, Haddad-Weiser G, Kussrow A, Bornhop D, Flowers R, Thévenin D. Backscattering Interferometry: Seeing Membrane Proteins in a New Light Biophysical Journal. 108: 253a. DOI: 10.1016/J.Bpj.2014.11.1398  0.736
2015 Gansäuer A, Von Laufenberg D, Kube C, Dahmen T, Michelmann A, Behlendorf M, Sure R, Seddiqzai M, Grimme S, Sadasivam DV, Fianu GD, Flowers RA. Mechanistic study of the titanocene(III)-catalyzed radical arylation of epoxides Chemistry - a European Journal. 21: 280-289. DOI: 10.1002/chem.201404404  0.81
2015 Gansäuer A, Hildebrandt S, Michelmann A, Dahmen T, Von laufenberg D, Kube C, Fianu GD, Flowers RA. Cationic Titanocene(III) Complexes for Catalysis in Single-Electron Steps Angewandte Chemie - International Edition. 54: 7003-7006. DOI: 10.1002/anie.201501955  0.8
2015 Gansäuer A, Hildebrandt S, Michelmann A, Dahmen T, von Laufenberg D, Kube C, Fianu GD, Flowers RA. Kationische Titanocen(III)-Komplexe für die Katalyse in Ein-Elektronen-Schritten Angewandte Chemie. 127: 7109-7112. DOI: 10.1002/Ange.201501955  0.768
2014 Chciuk TV, Hilmersson G, Flowers RA. Solvent-dependent substrate reduction by {Sm[N(SiMe3)2]2(THF)2}. An alternative approach for accelerating the rate of substrate reduction by Sm(II). The Journal of Organic Chemistry. 79: 9441-3. PMID 25255468 DOI: 10.1021/jo501819z  0.812
2014 Gansäuer A, Kube C, Daasbjerg K, Sure R, Grimme S, Fianu GD, Sadasivam DV, Flowers RA. Substituent effects and supramolecular interactions of titanocene(III) chloride: implications for catalysis in single electron steps. Journal of the American Chemical Society. 136: 1663-71. PMID 24397383 DOI: 10.1021/Ja4121567  0.822
2014 Gansäuer A, Kube C, Daasbjerg K, Sure R, Grimme S, Fianu GD, Sadasivam DV, Flowers RA. Substituent effects and supramolecular interactions of titanocene(III) chloride: Implications for catalysis in single electron steps Journal of the American Chemical Society. 136: 1663-1671. DOI: 10.1021/ja4121567  0.798
2014 Choquette KA, Flowers RA. Samarium and Ytterbium Reagents Comprehensive Organic Synthesis: Second Edition. 1: 278-343. DOI: 10.1016/B978-0-08-097742-3.00111-7  0.727
2013 Szostak M, Spain M, Choquette KA, Flowers RA, Procter DJ. Substrate-directable electron transfer reactions. Dramatic rate enhancement in the chemoselective reduction of cyclic esters using SmI2-H 2O: Mechanism, scope, and synthetic utility Journal of the American Chemical Society. 135: 15702-15705. PMID 24079360 DOI: 10.1021/Ja4078864  0.773
2013 Patel NR, Flowers RA. Uncovering the mechanism of the Ag(I)/persulfate-catalyzed cross-coupling reaction of arylboronic acids and heteroarenes Journal of the American Chemical Society. 135: 4672-4675. PMID 23477364 DOI: 10.1021/ja400712g  0.544
2013 Sadasivam DV, Choquette KA, Flowers RA. Preparation and use of samarium diiodide (SmI(2)) in organic synthesis: the mechanistic role of HMPA and Ni(II) salts in the samarium Barbier reaction. Journal of Visualized Experiments : Jove. e4323. PMID 23407417 DOI: 10.3791/4323  0.781
2013 Patel NR, Flowers RA. Correction to “Uncovering the Mechanism of the Ag(I)/Persulfate-Catalyzed Cross-Coupling Reaction of Arylboronic Acids and Heteroarenes” Journal of the American Chemical Society. 135: 7788-7788. DOI: 10.1021/ja402937c  0.482
2013 Bornhop DJ, Kussrow A, Olmsted I, Baksh M, Finn MG, Marnett L, Windsor M, Pesciotta EN, Flowers RA, Massion P, Hassanein M. Using back-scattering interferometry to aid in probe development and drug efficacy monitoring Optical Molecular Probes, Imaging and Drug Delivery, Omp 2013. MM4C.6.  0.744
2012 Tu Y, Zhou L, Yin R, Lv X, Flowers RA, Choquette KA, Liu H, Niu Q, Wang X. Study on the coupling of acyclic esters with alkenes--the synthesis of 2-(2-hydroxyalkyl)cyclopropanols via cascade cyclization using allylsamarium bromide. Chemical Communications (Cambridge, England). 48: 11026-8. PMID 23038019 DOI: 10.1039/C2Cc34630C  0.741
2012 Haddad GL, Young SC, Heindel ND, Bornhop DJ, Flowers RA. Back-scattering interferometry: an ultrasensitive method for the unperturbed detection of acetylcholinesterase-inhibitor interactions. Angewandte Chemie (International Ed. in English). 51: 11126-30. PMID 23037915 DOI: 10.1002/Anie.201203640  0.465
2012 Maity S, Choquette KA, Flowers RA, Prasad E. Effect of crown ethers on the ground and excited state reactivity of samarium diiodide in acetonitrile. The Journal of Physical Chemistry. A. 116: 2154-60. PMID 22313188 DOI: 10.1021/Jp212247A  0.795
2012 Kingsley NB, Kirschbaum K, Teprovich JA, Flowers RA, Mason MR. Synthesis and calorimetric, spectroscopic, and structural characterization of isocyanide complexes of trialkylaluminum and tri-tert-butylgallium. Inorganic Chemistry. 51: 2494-502. PMID 22296217 DOI: 10.1021/Ic202427Z  0.695
2012 Young SC, Fabio KM, Huang MT, Saxena J, Harman MP, Guillon CD, Vetrano AM, Heck DE, Flowers RA, Heindel ND, Laskin JD. Investigation of anticholinergic and non-steroidal anti-inflammatory prodrugs which reduce chemically induced skin inflammation. Journal of Applied Toxicology : Jat. 32: 135-41. PMID 21319177 DOI: 10.1002/Jat.1645  0.476
2012 Maity S, Choquette KA, Flowers RA, Prasad E. Effect of crown ethers on the ground and excited state reactivity of Samarium diiodide in acetonitrile Journal of Physical Chemistry A. 116: 2154-2160. DOI: 10.1021/jp212247a  0.76
2011 Casey BM, Flowers RA. On the nature of the oxidative heterocoupling of lithium enolates. Journal of the American Chemical Society. 133: 11492-5. PMID 21721524 DOI: 10.1021/Ja205017E  0.528
2011 Choquette KA, Sadasivam DV, Flowers RA. Catalytic Ni(II) in reactions of SmI2: Sm(II)- or Ni(0)-based chemistry? Journal of the American Chemical Society. 133: 10655-61. PMID 21619012 DOI: 10.1021/Ja204287N  0.757
2011 Pesciotta EN, Bornhop DJ, Flowers RA. Backscattering interferometry: an alternative approach for the study of hydrogen bonding interactions in organic solvents. Organic Letters. 13: 2654-7. PMID 21510617 DOI: 10.1021/Ol200757A  0.773
2011 Pesciotta EN, Bornhop DJ, Flowers RA. Back-scattering interferometry: a versatile platform for the study of free-solution versus surface-immobilized hybridization. Chemistry, An Asian Journal. 6: 70-3. PMID 21082726 DOI: 10.1002/Asia.201000614  0.75
2011 Choquette KA, Sadasivam DV, Flowers RA. Catalytic Ni(II) in reactions of SmI 2: Sm(II)-or Ni(0)-based chemistry? Journal of the American Chemical Society. 133: 10655-10661. DOI: 10.1021/ja204287n  0.742
2010 Choquette KA, Sadasivam DV, Flowers RA. Uncovering the mechanistic role of HMPA in the samarium Barbier reaction. Journal of the American Chemical Society. 132: 17396-8. PMID 21090625 DOI: 10.1021/Ja1088925  0.757
2010 Casey BM, Eakin CA, Jiao J, Sadasivam DV, Flowers RA. Corrigendum to Solvent-dependent oxidative coupling of 1-aryl-1,3-dicarbonyls and styrene. Tetrahedron. 66: 5720-5726. PMID 20806051 DOI: 10.1016/J.Tet.2010.05.063  0.68
2010 Sadasivam DV, Teprovich JA, Procter DJ, Flowers RA. Dynamic ligand exchange in reactions of samarium diiodide. Organic Letters. 12: 4140-3. PMID 20722385 DOI: 10.1021/Ol101722C  0.759
2010 Pigga JM, Teprovich JA, Flowers RA, Antonio MR, Liu T. Selective monovalent cation association and exchange around Keplerate polyoxometalate macroanions in dilute aqueous solutions. Langmuir : the Acs Journal of Surfaces and Colloids. 26: 9449-56. PMID 20408519 DOI: 10.1021/La100467P  0.702
2010 Young S, Fabio K, Guillon C, Mohanta P, Halton TA, Heck DE, Flowers RA, Laskin JD, Heindel ND. Peripheral site acetylcholinesterase inhibitors targeting both inflammation and cholinergic dysfunction. Bioorganic & Medicinal Chemistry Letters. 20: 2987-90. PMID 20347302 DOI: 10.1016/J.Bmcl.2010.02.102  0.471
2010 Singh R, Flowers RA. Efficient protein renaturation using tunable hemifluorinated anionic surfactants as additives. Chemical Communications (Cambridge, England). 46: 276-8. PMID 20024350 DOI: 10.1039/B918984J  0.597
2010 Sadasivam DV, Teprovich JA, Procter DJ, Flowers RA. Dynamic ligand exchange in reactions of samarium diiodide Organic Letters. 12: 4140-4143. DOI: 10.1021/ol101722c  0.729
2010 Choquette KA, Sadasivam DV, Flowers RA. Uncovering the mechanistic role of HMPA in the samarium barbier reaction Journal of the American Chemical Society. 132: 17396-17398. DOI: 10.1021/ja1088925  0.732
2010 Casey BM, Eakin CA, Jiao J, Sadasivam DV, Flowers RA. Corrigendum to ‘Solvent-dependent oxidative coupling of 1-aryl-1,3-dicarbonyls and styrene’ [Tetrahedron 65 (52) (2009) 10762–10768] Tetrahedron. 66: 5719. DOI: 10.1016/J.Tet.2010.05.062  0.614
2010 Casey BM, Eakin CA, Jiao J, Sadasivam DV, Flowers RAI. ChemInform Abstract: Solvent-Dependent Oxidative Coupling of 1-Aryl-1,3-dicarbonyls and Styrene. Cheminform. 41. DOI: 10.1002/chin.201018033  0.52
2009 Devery JJ, Mohanta PK, Casey BM, Flowers RA. Facile Route to Tetrasubstituted Pyrazoles Utilizing Ceric Ammonium Nitrate. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 1490-1494. PMID 21151843 DOI: 10.1055/S-0029-1217163  0.514
2009 Casey BM, Eakin CA, Flowers RA. Synthesis of gamma-halogenated ketones via the Ce(IV)-mediated oxidative coupling of cyclobutanols and inorganic halides. Tetrahedron Letters. 50: 1264-1266. PMID 20676239 DOI: 10.1016/J.Tetlet.2008.12.114  0.54
2009 Casey BM, Eakin CA, Jiao J, Sadasivam DV, Flowers RA. Solvent-dependent oxidative coupling of 1-aryl-1,3-dicarbonyls and styrene. Tetrahedron. 65: 10762-10768. PMID 20625455 DOI: 10.1016/J.Tet.2009.06.118  0.675
2009 Sreenath K, Suneesh CV, Gopidas KR, Flowers RA. Generation of triarylamine radical cations through reaction of triarylamines with Cu(II) in acetonitrile. A kinetic investigation of the electron-transfer reaction. The Journal of Physical Chemistry. A. 113: 6477-83. PMID 19453121 DOI: 10.1021/Jp9027222  0.637
2009 Flowers RAI, Prasad E. ChemInform Abstract: Samarium(II)-Based Reductants Cheminform. 40. DOI: 10.1002/chin.200928253  0.726
2008 Sadasivam DV, Antharjanam PK, Prasad E, Flowers RA. Mechanistic study of samarium diiodide-HMPA initiated 5-exo-trig Ketyl-Olefin coupling: the role of HMPA in post-electron transfer steps. Journal of the American Chemical Society. 130: 7228-9. PMID 18479133 DOI: 10.1021/Ja802448X  0.768
2008 Teprovich JA, Antharjanam PKS, Prasad E, Pesciotta EN, Flowers RA. Generation of SmIIReductants Using High Intensity Ultrasound (Eur. J. Inorg. Chem. 32/2008) European Journal of Inorganic Chemistry. 2008: 4991-4991. DOI: 10.1002/Ejic.200890089  0.771
2008 Teprovich JA, Antharjanam PKS, Prasad E, Pesciotta EN, Flowers RA. Generation of SmII reductants using high intensity ultrasound European Journal of Inorganic Chemistry. 5015-5019. DOI: 10.1002/Ejic.200800876  0.783
2007 Teprovich JA, Balili MN, Pintauer T, Flowers RA. Mechanistic studies of proton-donor coordination to samarium diiodide. Angewandte Chemie (International Ed. in English). 46: 8160-3. PMID 17828725 DOI: 10.1002/Anie.200702571  0.713
2007 Jiao J, Zhang Y, Devery JJ, Xu L, Deng J, Flowers RA. Mechanistic studies of Ce(IV)-mediated oxidation of beta-dicarbonyls: solvent-dependent behavior of radical cation intermediates. The Journal of Organic Chemistry. 72: 5486-92. PMID 17602587 DOI: 10.1021/Jo0625406  0.52
2007 Jiao J, Nguyen LX, Patterson DR, Flowers RA. An efficient and general approach to beta-functionalized ketones. Organic Letters. 9: 1323-6. PMID 17335227 DOI: 10.1021/Ol070159H  0.494
2007 Teprovich JA, Prasad E, Flowers RA. Solvation-controlled luminescence of SmII complexes. Angewandte Chemie (International Ed. in English). 46: 1145-8. PMID 17177223 DOI: 10.1002/Anie.200604100  0.769
2006 Zhang Y, Jiao J, Flowers RA. Mild conversion of beta-diketones and beta-ketoesters to carboxylic acids. The Journal of Organic Chemistry. 71: 4516-20. PMID 16749782 DOI: 10.1021/Jo0602975  0.496
2006 Sadasivam DV, Prasad E, Flowers RA, Birney DM. Stopped-flow kinetics of tetrazine cycloadditions; experimental and computational studies toward sequential transition states. The Journal of Physical Chemistry. A. 110: 1288-94. PMID 16435789 DOI: 10.1021/Jp0534075  0.712
2006 Jiao J, Zhang Y, Flowers RA. A convenient one-pot synthesis of spirocyclic pyrido[1,2-a]indole derivatives from 3-(2-bromoethyl)indole Synlett. 3355-3357. DOI: 10.1055/S-2006-950252  0.491
2006 Flowers RA, Prasad E. Chapter 230 Samarium (II) based reductants Handbook On the Physics and Chemistry of Rare Earths. 36: 393-473. DOI: 10.1016/S0168-1273(06)36004-7  0.744
2005 Prasad E, Flowers RA. Mechanistic impact of water addition to SmI2: consequences in the ground and transition state. Journal of the American Chemical Society. 127: 18093-9. PMID 16366561 DOI: 10.1021/Ja056352T  0.736
2005 Mohanta PK, Davis TA, Gooch JR, Flowers RA. Chelation-controlled diastereoselective reduction of alpha-fluoroketones. Journal of the American Chemical Society. 127: 11896-7. PMID 16117501 DOI: 10.1021/Ja052546X  0.468
2005 Dahlén A, Prasad E, Flowers RA, Hilmersson G. Exploring SmBr2-, SmI2-, and YbI2-mediated reactions assisted by microwave irradiation. Chemistry (Weinheim An Der Bergstrasse, Germany). 11: 3279-84. PMID 15786498 DOI: 10.1002/Chem.200401320  0.754
2005 Prasad E, Knettle BW, Flowers RA. Photoinduced electron transfer reactions by SmI2 in THF: luminescence quenching studies and mechanistic investigations. Chemistry (Weinheim An Der Bergstrasse, Germany). 11: 3105-12. PMID 15761842 DOI: 10.1002/Chem.200401163  0.8
2005 Davis TA, Chopade PR, Hilmersson G, Flowers RA. Reduction of beta-hydroxyketones by SmI2/H2O/Et3N. Organic Letters. 7: 119-22. PMID 15624992 DOI: 10.1021/ol047835p  0.748
2005 Davis TA, Chopade PR, Hilmersson G, Flowers RAI. Reduction of ?-Hydroxyketones by SmI2/H2O/Et3N. Cheminform. 36. DOI: 10.1002/chin.200520042  0.738
2005 Prasad E, Knettle BW, Flowers RA. Photoinduced electron transfer reactions by SmI2 in THF: Luminescence quenching studies and mechanistic investigations Chemistry - a European Journal. 11: 3105-3112. DOI: 10.1002/chem.200401163  0.795
2004 Chopade PR, Davis TA, Prasad E, Flowers RA. Solvent-dependent diastereoselectivities in reductions of beta-hydroxyketones by SmI2. Organic Letters. 6: 2685-8. PMID 15281744 DOI: 10.1021/Ol049129U  0.783
2004 Prasad E, Knettle BW, Flowers RA. The role of ligand displacement in SmII-HMPA-based reductions. Journal of the American Chemical Society. 126: 6891-4. PMID 15174857 DOI: 10.1021/Ja049161J  0.802
2004 Chopade PR, Prasad E, Flowers RA. The role of proton donors in SmI2-mediated ketone reduction: new mechanistic insights. Journal of the American Chemical Society. 126: 44-5. PMID 14709051 DOI: 10.1021/Ja038363X  0.797
2004 Prasad E, Knettle BW, Flowers RA. The role of ligand displacement in Sm(II)-HMPA-based reductions Journal of the American Chemical Society. 126: 6891-6894. DOI: 10.1021/ja049161j  0.789
2003 Zhang Y, Raines AJ, Flowers RA. Solvent-dependent chemoselectivities in Ce(IV)-mediated oxidative coupling reactions. Organic Letters. 5: 2363-5. PMID 12816449 DOI: 10.1021/Ol034763D  0.303
2003 Dahlén A, Hilmersson G, Knettle BW, Flowers RA. Rapid SmI2-mediated reductions of alkyl halides and electrochemical properties of SmI2/H2O/amine. The Journal of Organic Chemistry. 68: 4870-5. PMID 12790593 DOI: 10.1021/Jo034173T  0.817
2003 Kim M, Knettle BW, Dahlén A, Hilmersson G, Flowers RA. Reduction and reductive coupling of imines by Sm(II)-based reagents Tetrahedron. 59: 10397-10402. DOI: 10.1016/J.Tet.2003.06.004  0.802
2002 Prasad E, Knettle BW, Flowers RA. Investigation of the [Sm{N(SiMe3)2}2] reducing system in THF. Rate and mechanistic studies Journal of the American Chemical Society. 124: 14663-14667. PMID 12465977 DOI: 10.1021/Ja028111G  0.791
2002 Prasad E, Flowers RA. Reduction of ketones and alkyl iodides by SmI(2) and Sm(II)-HMPA complexes. Rate and mechanistic studies. Journal of the American Chemical Society. 124: 6895-9. PMID 12059211 DOI: 10.1021/Ja026074N  0.751
2002 Prasad E, Flowers RA. Mechanistic study of beta-substituent effects on the mechanism of ketone reduction by SmI(2). Journal of the American Chemical Society. 124: 6357-61. PMID 12033865 DOI: 10.1021/Ja020051R  0.758
2001 Knettle BW, Flowers RA. Influence of HMPA on reducing power and reactivity of SmBr(2). Organic Letters. 3: 2321-4. PMID 11463306  0.788
2001 Knettle BW, Flowers RA. Influence of HMPA on reducing power and reactivity of SmBr2 Organic Letters. 3: 2321-2324. DOI: 10.1021/ol0160957  0.765
2000 Summers CA, Flowers RA. Protein renaturation by the liquid organic salt ethylammonium nitrate. Protein Science : a Publication of the Protein Society. 9: 2001-8. PMID 11106174 DOI: 10.1110/ps.9.10.2001  0.51
2000 Miller RS, Sealy JM, Shabangi M, Kuhlman ML, Fuchs JR, Flowers RA. Reactions of SmI2 with alkyl halides and ketones: Inner-sphere vs outer-sphere electron transfer in reactions of Sm(II) reductants Journal of the American Chemical Society. 122: 7718-7722. DOI: 10.1021/Ja001260J  0.81
1999 Garlitz JA, Summers CA, Flowers RA, Borgstahl GE. Ethylammonium nitrate: a protein crystallization reagent. Acta Crystallographica. Section D, Biological Crystallography. 55: 2037-8. PMID 10666583 DOI: 10.1107/S0907444999011774  0.513
1999 Shabangi M, Kuhlman ML, Flowers RA. Mechanism of reduction of primary alkyl radicals by SmI2-HMPA Organic Letters. 1: 2133-2135.  0.785
1998 Shabangi M, Sealy JM, Fuchs JR, Flowers RA. The effect of cosolvent on the reducing power of SmI2 in tetrahydrofuran Tetrahedron Letters. 39: 4429-4432. DOI: 10.1016/S0040-4039(98)00839-9  0.802
1997 Larsen JW, Flowers RA, Hall PJ, Carlson G. Structural rearrangement of strained coals Energy and Fuels. 11: 998-1002. DOI: 10.1021/Ef970014Z  0.429
1997 Fuchs JR, Mitchell ML, Shabangi M, Flowers RA. The effect of lithium bromide and lithium chloride on the reactivity of SmI2 in THF Tetrahedron Letters. 38: 8157-8158. DOI: 10.1016/S0040-4039(97)10222-2  0.786
1997 Shabangi M, Flowers RA. Electrochemical investigation of the reducing power of SmI2 in THF and the effect of HMPA cosolvent Tetrahedron Letters. 38: 1137-1140. DOI: 10.1016/S0040-4039(97)00008-7  0.783
1997 Arnett EM, Flowers RA, Ludwig RT, Meekhof AE, Walek SA. Triarylmethanes and 9-arylxanthenes as prototypes amphihydric compounds for relating the stabilities of cations, anions and radicals by C-H bond cleavage and electron transfer Journal of Physical Organic Chemistry. 10: 499-513. DOI: 10.1002/(Sici)1099-1395(199707)10:7<499::Aid-Poc896>3.0.Co;2-2  0.522
1995 Arnett EM, Flowers RA, Ludwig RT, Meekhof A, Walek S. Thermodynamics for C-H bond-breaking of some amphihydric compounds by transfer of protons, hydride ions, H-atoms and electrons Pure and Applied Chemistry. 67: 729-734. DOI: 10.1351/Pac199567050729  0.475
1994 Arnett EM, Flowers RA, Meekhof AE, Pourjavadi A, Walek SA. Stabilities of some 2-(para-substituted-phenyl)-4,4,5,5-tetramethyl-1,3-dioxolanes relative to their conjugate dioxolenium ions, radicals and carbanions as determined by thermodynamics for hydride and electron transfer in solution Journal of Physical Organic Chemistry. 7: 663-671. DOI: 10.1002/Poc.610071204  0.509
1994 Seebach D, Bossler HG, Flowers R, Arnett EM. Calorimetric Measurements of the Complexation of Cyclosporin A, Ascomycin, Fujimycin, and Rapamycin with Lithium Chloride and with an Immunophilin Helvetica Chimica Acta. 77: 291-305. DOI: 10.1002/Hlca.19940770129  0.457
1994 Flowers RA, Gebhard L, Larsen JW, Sanada Y, Sasaki M, Silbernagel B. Unusual electronic properties of complexes between coals and the oxidants TCNQ and TCNE Energy & Fuels. 8: 1524-1525.  0.466
1993 Arnett EM, Flowers RA. Bond cleavage energies for molecules and their associated radical ions Chemical Society Reviews. 22: 9-15. DOI: 10.1039/Cs9932200009  0.453
1992 Arnett EM, Dowd P, Flowers RA, Ham SK, Naganathan S. Thermochemical confirmation of the mechanism of action of vitamin K Journal of the American Chemical Society. 114: 9209-9210. DOI: 10.1021/Ja00049A075  0.396
Show low-probability matches.