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Raghu Sivaramakrishnan - Publications

Affiliations: 
1999-2007 University of Illinois at Chicago, Chicago, IL, United States 
 2007- Chemical Sciences & Engineering Argonne National Laboratory, Lemont, IL, United States 
Area:
Gas Phase Chemical Kinetics, Flame Chemistry, Radical Reactions, Shock Tubes, Chemical Reactivity, Reaction Networks
Website:
https://www.anl.gov/profile/raghu-sivaramakrishnan
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52 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Cho J, Rösch D, Tao Y, Osborn DL, Klippenstein SJ, Sheps L, Sivaramakrishnan R. Modeling-Experiment-Theory Analysis of Reactions Initiated from Cl + Methyl Formate. The Journal of Physical Chemistry. A. PMID 37937747 DOI: 10.1021/acs.jpca.3c05085  0.365
2022 Cho J, Mulvihill CR, Klippenstein SJ, Sivaramakrishnan R. Bimolecular Peroxy Radical (RO) Reactions and Their Relevance in Radical Initiated Oxidation of Hydrocarbons. The Journal of Physical Chemistry. A. PMID 36562763 DOI: 10.1021/acs.jpca.2c06960  0.327
2022 Couch DE, Mulvihill CR, Sivaramakrishnan R, Au K, Taatjes CA, Sheps L. Quantification of Key Peroxy and Hydroperoxide Intermediates in the Low-Temperature Oxidation of Dimethyl Ether. The Journal of Physical Chemistry. A. PMID 36480708 DOI: 10.1021/acs.jpca.2c06959  0.346
2021 Sikes T, Banyon C, Schwind RA, Lynch PT, Comandini A, Sivaramakrishnan R, Tranter RS. Initiation reactions in the high temperature decomposition of styrene. Physical Chemistry Chemical Physics : Pccp. 23: 18432-18448. PMID 34612384 DOI: 10.1039/d1cp02437j  0.763
2021 Zaleski DP, Sivaramakrishnan R, Weller HR, Seifert NA, Bross DH, Ruscic B, Moore KB, Elliott SN, Copan AV, Harding LB, Klippenstein SJ, Field RW, Prozument K. Substitution Reactions in the Pyrolysis of Acetone Revealed through a Modeling, Experiment, Theory Paradigm. Journal of the American Chemical Society. PMID 33615780 DOI: 10.1021/jacs.0c11677  0.445
2020 Randazzo JB, Sivaramakrishnan R, Jasper AW, Sikes T, Lynch PT, Tranter RS. An experimental and theoretical study of the high temperature reactions of the four butyl radical isomers. Physical Chemistry Chemical Physics : Pccp. PMID 32785311 DOI: 10.1039/D0Cp02404J  0.613
2019 Jasper AW, Sivaramakrishnan R, Klippenstein SJ. Nonthermal rate constants for CH + X → CH + HX, X = H, O, OH, and O. The Journal of Chemical Physics. 150: 114112. PMID 30902010 DOI: 10.1063/1.5090394  0.518
2019 Bai S, Davis MJ, Sivaramakrishnan R, Skodje RT. A chemical pathway perspective on the kinetics of low-temperature ignition of propane Combustion and Flame. 202: 154-178. DOI: 10.1016/J.Combustflame.2019.01.006  0.47
2018 Magnotti GM, Wang Z, Liu W, Sivaramakrishnan R, Som S, Davis MJ. Sparsity Facilitates Chemical Reaction Selection for Engine Simulations. The Journal of Physical Chemistry. A. PMID 30102539 DOI: 10.1021/Acs.Jpca.8B05436  0.418
2016 Labbe NJ, Sivaramakrishnan R, Goldsmith CF, Georgievskii Y, Miller JA, Klippenstein SJ. Weakly Bound Free Radicals in Combustion: "Prompt" Dissociation of Formyl Radicals and Its Effect on Laminar Flame Speeds. The Journal of Physical Chemistry Letters. 7: 85-9. PMID 26655248 DOI: 10.1021/Acs.Jpclett.5B02418  0.764
2015 Sivaramakrishnan R, Michael JV, Harding LB, Klippenstein SJ. Resolving Some Paradoxes in the Thermal Decomposition Mechanism of Acetaldehyde. The Journal of Physical Chemistry. A. PMID 25793559 DOI: 10.1021/Acs.Jpca.5B01032  0.667
2015 Peukert SL, Sivaramakrishnan R, Michael JV. High temperature rate constants for H/D + n-C4H10 and i-C4H10 Proceedings of the Combustion Institute. 35: 171-179. DOI: 10.1016/j.proci.2014.05.104  0.602
2013 Som S, Liu W, Zhou DD, Magnotti GM, Sivaramakrishnan R, Longman DE, Skodje RT, Davis MJ. Quantum Tunneling Affects Engine Performance. The Journal of Physical Chemistry Letters. 4: 2021-5. PMID 26283246 DOI: 10.1021/Jz400874S  0.409
2013 Peukert SL, Labbe NJ, Sivaramakrishnan R, Michael JV. Direct measurements of rate constants for the reactions of CH3 radicals with C2H6, C2H4, and C2H2 at high temperatures. The Journal of Physical Chemistry. A. 117: 10228-38. PMID 23968575 DOI: 10.1021/Jp4073153  0.792
2013 Peukert SL, Sivaramakrishnan R, Michael JV. High temperature shock tube and theoretical studies on the thermal decomposition of dimethyl carbonate and its bimolecular reactions with H and D-atoms. The Journal of Physical Chemistry. A. 117: 3718-28. PMID 23510116 DOI: 10.1021/Jp312643K  0.677
2013 Peukert SL, Sivaramakrishnan R, Michael JV. High temperature shock tube studies on the thermal decomposition of O3 and the reaction of dimethyl carbonate with O-atoms. The Journal of Physical Chemistry. A. 117: 3729-38. PMID 23510082 DOI: 10.1021/Jp400613P  0.658
2013 Peukert SL, Sivaramakrishnan R, Su MC, Michael JV. High temperature rate constants for H/D + methyl formate and methyl acetate Proceedings of the Combustion Institute. 34: 463-471. DOI: 10.1016/j.proci.2012.06.006  0.564
2013 Peukert S, Sivaramakrishnan R, Michael JV. Shock tube and modeling study of the pyrolysis of dimethyl carbonate and its reaction with D-and O-atoms 8th Us National Combustion Meeting 2013. 1: 12-21.  0.564
2012 Sivaramakrishnan R, Michael JV, Harding LB, Klippenstein SJ. Shock tube explorations of roaming radical mechanisms: the decompositions of isobutane and neopentane. The Journal of Physical Chemistry. A. 116: 5981-9. PMID 22394380 DOI: 10.1021/Jp210959J  0.643
2012 Peukert SL, Sivaramakrishnan R, Su MC, Michael JV. Experiment and theory on methylformate and methylacetate kinetics at high temperatures: Rate constants for H-atom abstraction and thermal decomposition Combustion and Flame. 159: 2312-2323. DOI: 10.1016/J.Combustflame.2012.03.007  0.659
2012 Sivaramakrishnan R, Michael JV, Ruscic B. High-temperature rate constants for H/D + C 2H 6 and C 3H 8 International Journal of Chemical Kinetics. 44: 194-205. DOI: 10.1002/Kin.20607  0.681
2011 Sivaramakrishnan R, Su MC, Michael JV, Klippenstein SJ, Harding LB, Ruscic B. Shock tube and theoretical studies on the thermal decomposition of propane: evidence for a roaming radical channel. The Journal of Physical Chemistry. A. 115: 3366-79. PMID 21446707 DOI: 10.1021/Jp2006205  0.69
2011 Sivaramakrishnan R, Su MC, Michael JV. H- and D-atom formation from the pyrolysis of C6H 5CH2Br and C6H5CD2Br: Implications for high-temperature benzyl decomposition Proceedings of the Combustion Institute. 33: 243-250. DOI: 10.1016/j.proci.2010.06.133  0.616
2011 Sivaramakrishnan R, Michael JV. Pyrolysis of C6D5CH3: Rate constants and branching ratios in the high-temperature thermal decomposition of toluene Proceedings of the Combustion Institute. 33: 225-232. DOI: 10.1016/j.proci.2010.05.077  0.583
2011 Sivaramakrishnan R, Michael JV, Wagner AF, Dawes R, Jasper AW, Harding LB, Georgievskii Y, Klippenstein SJ. Roaming radicals in the thermal decomposition of dimethyl ether: Experiment and theory Combustion and Flame. 158: 618-632. DOI: 10.1016/J.Combustflame.2010.12.017  0.638
2010 Sivaramakrishnan R, Su MC, Michael JV, Klippenstein SJ, Harding LB, Ruscic B. Rate constants for the thermal decomposition of ethanol and its bimolecular reactions with OH and D: reflected shock tube and theoretical studies. The Journal of Physical Chemistry. A. 114: 9425-39. PMID 20715882 DOI: 10.1021/Jp104759D  0.698
2010 Sivaramakrishnan R, Michael JV, Klippenstein SJ. Direct observation of roaming radicals in the thermal decomposition of acetaldehyde. The Journal of Physical Chemistry. A. 114: 755-64. PMID 20017515 DOI: 10.1021/Jp906918Z  0.686
2010 Sivaramakrishnan R, Michael JV, Klippenstein SJ. Direct observation of roaming radicals in the thermal decomposition of acetaldehyde Journal of Physical Chemistry A. 114: 755-764. DOI: 10.1021/jp906918z  0.543
2009 Klippenstein SJ, Harding LB, Ruscic B, Sivaramakrishnan R, Srinivasan NK, Su MC, Michael JV. Thermal decomposition of NH2OH and subsequent reactions: ab initio transition state theory and reflected shock tube experiments. The Journal of Physical Chemistry. A. 113: 10241-59. PMID 19722533 DOI: 10.1021/Jp905454K  0.674
2009 Sivaramakrishnan R, Michael JV. Rate constants for OH with selected large alkanes: Shock-tube measurements and an improved group scheme Journal of Physical Chemistry A. 113: 5047-5060. PMID 19348456 DOI: 10.1021/Jp810987U  0.633
2009 Garner S, Sivaramakrishnan R, Brezinsky K. The high-pressure pyrolysis of saturated and unsaturated C7 hydrocarbons Proceedings of the Combustion Institute. 32: 461-467. DOI: 10.1016/j.proci.2008.06.217  0.739
2009 Sivaramakrishnan R, Srinivasan NK, Su MC, Michael JV. High temperature rate constants for OH+ alkanes Proceedings of the Combustion Institute. 32: 107-114. DOI: 10.1016/j.proci.2008.05.018  0.588
2009 Sivaramakrishnan R, Michael JV. Shock tube measurements of high temperature rate constants for OH with cycloalkanes and methylcycloalkanes Combustion and Flame. 156: 1126-1134. DOI: 10.1016/J.Combustflame.2008.10.010  0.597
2008 Culbertson B, Sivaramakrishnan R, Brezinsky K. Elevated pressure thermal experiments and modeling studies on the water-gas shift reaction Journal of Propulsion and Power. 24: 1085-1092. DOI: 10.2514/1.31897  0.797
2007 Sivaramakrishnan R, Brezinsky K, Dayma G, Dagaut P. High pressure effects on the mutual sensitization of the oxidation of NO and CH4-C2H6 blends. Physical Chemistry Chemical Physics : Pccp. 9: 4230-44. PMID 17687472 DOI: 10.1039/B703379F  0.784
2007 Xu H, Kiefer JH, Sivaramakrishnan R, Giri BR, Tranter RS. Shock tube study of dissociation and relaxation in 1,1-difluoroethane and vinyl fluoride. Physical Chemistry Chemical Physics : Pccp. 9: 4164-76. PMID 17687466 DOI: 10.1039/B703124F  0.478
2007 Sivaramakrishnan R, Comandini A, Tranter RS, Brezinsky K, Davis SG, Wang H. Combustion of CO/H2 mixtures at elevated pressures Proceedings of the Combustion Institute. 31: 429-437. DOI: 10.1016/j.proci.2006.08.057  0.789
2007 Sivaramakrishnan R, Dayma G, Dagaut P, Brezinsky K. High pressure experiments and detailed modeling of the mutual sensitization of the oxidation of NO and CH4-C2H6 blends 5th Us Combustion Meeting 2007. 3: 1532-1537.  0.739
2007 Sivaramakrishnan R, Som S, Brezinsky K, Aggarwal SK. Validation of a detailed chemical kinetic modeling for the high pressure combustion of methane - Flame and ignition characteristics 5th Us Combustion Meeting 2007. 1: 348-355.  0.755
2007 Culbertson B, Sivaramakrishnan R, Brezinsky K. The high-pressure water-gas shift reaction 5th Us Combustion Meeting 2007. 3: 1341-1346.  0.735
2007 Raman A, Sivaramakrishnan R, Brezinsky K. Experimental and modeling study of the pyrolysis of diacetylene at high temperatures and pressures 5th Us Combustion Meeting 2007. 4: 2383-2389.  0.758
2007 Culbertson B, Sivaramakrishnan R, Brezinsky K. High pressure shock tube studies on C(s)+CO2 Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2007 "Chemical and Physical Processes in Combustion". 570-575.  0.728
2007 Garner S, Sivaramakrishnan R, Brezinsky K, Dagaut P. The high pressure combustion of saturated and unsaturated C7 hydrocarbons Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2007 "Chemical and Physical Processes in Combustion". 105-113.  0.744
2006 Sivaramakrishnan R, Tranter RS, Brezinsky K. High pressure pyrolysis of toluene. 2. Modeling benzyl decomposition and formation of soot precursors. The Journal of Physical Chemistry. A. 110: 9400-4. PMID 16869689 DOI: 10.1021/Jp0608224  0.767
2006 Sivaramakrishnan R, Tranter RS, Brezinsky K. High pressure pyrolysis of toluene. 1. Experiments and modeling of toluene decomposition. The Journal of Physical Chemistry. A. 110: 9388-99. PMID 16869688 DOI: 10.1021/Jp060820J  0.801
2006 Sivaramakrishnan R, Brezinsky K, Vasudevan H, Tranter RS. A shock-tube study of the high-pressure thermal decomposition of benzene Combustion Science and Technology. 178: 285-305. DOI: 10.1080/00102200500292340  0.789
2005 Sivaramakrishnan R, Tranter RS, Brezinsky K. Ring conserved isodesmic reactions: A new method for estimating the heats of formation of aromatics and PAHs. The Journal of Physical Chemistry. A. 109: 1621-8. PMID 16833486 DOI: 10.1021/Jp045076M  0.704
2005 Sivaramakrishnan R, Tranter RS, Brezinsky K. A high pressure model for the oxidation of toluene Proceedings of the Combustion Institute. 30: 1165-1173. DOI: 10.1016/j.proci.2004.08.128  0.737
2005 Tranter RS, Raman A, Sivaramakrishnan R, Brezinsky K. Ethane oxidation and pyrolysis from 5 bar to 1000 bar: Experiments and simulation International Journal of Chemical Kinetics. 37: 306-331. DOI: 10.1002/Kin.20067  0.699
2004 Sivaramakrishnan R, Tranter RS, Brezinsky K. High-pressure, high-temperature oxidation of toluene Combustion and Flame. 139: 340-350. DOI: 10.1016/J.Combustflame.2004.09.006  0.789
2002 Tranter RS, Sivaramakrishnan R, Brezinsky K, Allendorf MD. High pressure, high temperature shock tube studies of ethane pyrolysis and oxidation Physical Chemistry Chemical Physics. 4: 2001-2010. DOI: 10.1039/B110702J  0.784
2001 Tranter RS, Sivaramakrishnan R, Srinivasan N, Brezinsky K. Calibration of reaction temperatures in a very high pressure shock tube using chemical thermometers International Journal of Chemical Kinetics. 33: 722-731. DOI: 10.1002/Kin.1069  0.78
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