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Frank A. Leibfarth, Ph.D. - Publications

Affiliations: 
2016- Chemistry University of North Carolina, Chapel Hill, Chapel Hill, NC 
Area:
synthetic polymer chemistry, nanotechnology and materials science
Website:
http://www.frankleibfarth.com/about
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47 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Sorensen CC, Bhat V, Bello AY, Leibfarth FA. Mechanistic Insights into the Stereoselective Cationic Polymerization of -Vinylcarbazole. Acs Catalysis. 13: 12163-12172. PMID 38469177 DOI: 10.1021/acscatal.3c02165  0.427
2022 Taylor NG, Reis MH, Varner TP, Rapp JL, Sarabia A, Leibfarth FA. A dual initiator approach for oxygen tolerant RAFT polymerization. Polymer Chemistry. 13: 4798-4808. PMID 37799166 DOI: 10.1039/D2PY00603K  0.794
2022 Zhang D, Vashahi F, Dashtimoghadam E, Hu X, Wang C, Garcia J, Bystrova AV, Vatankhah-Varnoosfaderani M, Leibfarth FA, Sheiko SS. Circular upcycling of bottlebrush thermosets. Angewandte Chemie (International Ed. in English). PMID 36583627 DOI: 10.1002/anie.202217941  0.35
2022 Sorensen CC, Leibfarth FA. Stereoselective Helix-Sense-Selective Cationic Polymerization of -Vinylcarbazole Using Chiral Lewis Acid Catalysis. Journal of the American Chemical Society. 144: 8487-8492. PMID 35510915 DOI: 10.1021/jacs.2c02738  0.381
2021 Reis M, Gusev F, Taylor NG, Chung SH, Verber MD, Lee YZ, Isayev O, Leibfarth FA. Machine-Learning-Guided Discovery of F MRI Agents Enabled by Automated Copolymer Synthesis. Journal of the American Chemical Society. PMID 34637304 DOI: 10.1021/jacs.1c08181  0.326
2021 Knutson PC, Teator AJ, Varner TP, Kozuszek CT, Jacky PE, Leibfarth FA. Brønsted Acid Catalyzed Stereoselective Polymerization of Vinyl Ethers. Journal of the American Chemical Society. 143: 16388-16393. PMID 34597508 DOI: 10.1021/jacs.1c08282  0.735
2020 Reis MH, Leibfarth FA, Pitet LM. Polymerizations in Continuous Flow: Recent Advances in the Synthesis of Diverse Polymeric Materials. Acs Macro Letters. 9: 123-133. PMID 35638663 DOI: 10.1021/acsmacrolett.9b00933  0.349
2020 Teator AJ, Varner TP, Knutson PC, Sorensen CC, Leibfarth FA. 100th Anniversary of Macromolecular Science Viewpoint: The Past, Present, and Future of Stereocontrolled Vinyl Polymerization. Acs Macro Letters. 9: 1638-1654. PMID 35617075 DOI: 10.1021/acsmacrolett.0c00664  0.673
2020 Varner TP, Teator AJ, Reddi Y, Jacky PE, Cramer CJ, Leibfarth FA. Mechanistic Insight into the Stereoselective Cationic Polymerization of Vinyl Ethers. Journal of the American Chemical Society. 142: 17175-17186. PMID 32986420 DOI: 10.1021/jacs.0c08254  0.789
2020 Taylor NG, Chung SH, Kwansa AL, Johnson RR, Teator AJ, Milliken NJB, Koshlap KM, Yingling YG, Lee YZ, Leibfarth F. Partially fluorinated copolymers as oxygen sensitive 19F MRI agents. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32468601 DOI: 10.1002/Chem.202001505  0.745
2020 Lewis SE, Wilhelmy BE, Leibfarth FA. Organocatalytic C–H fluoroalkylation of commodity polymers Polymer Chemistry. 11: 4914-4919. DOI: 10.1039/C9Py01884K  0.49
2020 Reis MH, Leibfarth FA, Pitet LM. Polymerizations in Continuous Flow: Recent Advances in the Synthesis of Diverse Polymeric Materials Acs Macro Letters. 9: 123-133. DOI: 10.1021/Acsmacrolett.9B00933  0.365
2019 Teator AJ, Varner TP, Jacky PE, Sheyko KA, Leibfarth FA. Polar Thermoplastics with Tunable Physical Properties Enabled by the Stereoselective Copolymerization of Vinyl Ethers. Acs Macro Letters. 8: 1559-1563. PMID 35619395 DOI: 10.1021/acsmacrolett.9b00802  0.773
2019 Williamson JB, Na CG, Johnson RR, Daniel WFM, Alexanian EJ, Leibfarth FA. Chemo- and Regioselective Functionalization of Isotactic Polypropylene: A Mechanistic and Structure-Property Study. Journal of the American Chemical Society. PMID 31373806 DOI: 10.1021/Jacs.9B05799  0.428
2019 Lewis SE, Wilhelmy BE, Leibfarth FA. Upcycling aromatic polymers through C-H fluoroalkylation. Chemical Science. 10: 6270-6277. PMID 31341579 DOI: 10.1039/C9Sc01425J  0.486
2019 Teator AJ, Leibfarth FA. Catalyst-controlled stereoselective cationic polymerization of vinyl ethers. Science. 363: 1439-1443. PMID 30923220 DOI: 10.1126/Science.Aaw1703  0.515
2019 Reis MH, Varner TP, Leibfarth FA. The Influence of Residence Time Distribution on Continuous Flow Polymerization Chemrxiv. 52: 3551-3557. DOI: 10.26434/Chemrxiv.7726166.V1  0.788
2019 Teator AJ, Varner TP, Jacky PE, Sheyko KA, Leibfarth FA. Polar Thermoplastics with Tunable Physical Properties Enabled by the Stereoselective Copolymerization of Vinyl Ethers Acs Macro Letters. 8: 1559-1563. DOI: 10.1021/Acsmacrolett.9B00802  0.808
2018 Williamson JB, Lewis SE, Johnson Iii RR, Manning IM, Leibfarth F. C-H Functionalization of Commodity Polymers. Angewandte Chemie (International Ed. in English). PMID 30450640 DOI: 10.1002/Anie.201810970  0.442
2018 Williamson JB, Czaplyski WL, Alexanian EJ, Leibfarth F. Regioselective C-H Xanthylation as a Platform for Polyolefin Functionalization. Angewandte Chemie (International Ed. in English). PMID 29660850 DOI: 10.1002/Anie.201803020  0.411
2018 Reis MH, Davidson CLG, Leibfarth FA. Continuous-flow chemistry for the determination of comonomer reactivity ratios Polymer Chemistry. 9: 1728-1734. DOI: 10.1039/C7Py01938F  0.342
2018 Leibfarth FA, Russell MG, Langley DM, Seo H, Kelly LP, Carney DW, Sello JK, Jamison TF. Continuous-Flow Chemistry in Undergraduate Education: Sustainable Conversion of Reclaimed Vegetable Oil into Biodiesel Journal of Chemical Education. 95: 1371-1375. DOI: 10.1021/Acs.Jchemed.7B00719  0.526
2017 Wicker AC, Leibfarth FA, Jamison TF. Flow-IEG enables programmable thermodynamic properties in sequence-defined unimolecular macromolecules Polymer Chemistry. 8: 5786-5794. DOI: 10.1039/C7Py01204G  0.554
2015 Barnes JC, Ehrlich DJ, Gao AX, Leibfarth FA, Jiang Y, Zhou E, Jamison TF, Johnson JA. Iterative exponential growth of stereo- and sequence-controlled polymers. Nature Chemistry. 7: 810-5. PMID 26391080 DOI: 10.1038/Nchem.2346  0.629
2015 Leibfarth FA, Johnson JA, Jamison TF. Scalable synthesis of sequence-defined, unimolecular macromolecules by Flow-IEG. Proceedings of the National Academy of Sciences of the United States of America. 112: 10617-22. PMID 26269573 DOI: 10.1073/Pnas.1508599112  0.583
2015 Leibfarth FA, Johnson JA, Jamison TF. Scalable synthesis of sequence-defined, unimolecular macromolecules by Flow-IEG Proceedings of the National Academy of Sciences of the United States of America. 112: 10617-10622. DOI: 10.1073/pnas.1508599112  0.472
2014 Helmy S, Oh S, Leibfarth FA, Hawker CJ, Read de Alaniz J. Design and synthesis of donor-acceptor Stenhouse adducts: a visible light photoswitch derived from furfural. The Journal of Organic Chemistry. 79: 11316-29. PMID 25390619 DOI: 10.1021/Jo502206G  0.49
2014 Oh SS, Lee BF, Leibfarth FA, Eisenstein M, Robb MJ, Lynd NA, Hawker CJ, Soh HT. Synthetic aptamer-polymer hybrid constructs for programmed drug delivery into specific target cells. Journal of the American Chemical Society. 136: 15010-5. PMID 25290917 DOI: 10.1021/Ja5079464  0.77
2014 Helmy S, Leibfarth FA, Oh S, Poelma JE, Hawker CJ, Read de Alaniz J. Photoswitching using visible light: a new class of organic photochromic molecules. Journal of the American Chemical Society. 136: 8169-72. PMID 24848124 DOI: 10.1021/Ja503016B  0.452
2014 Groote R, Szyja BM, Leibfarth FA, Hawker CJ, Doltsinis NL, Sijbesma RP. Strain-induced strengthening of the weakest link: The importance of intermediate geometry for the outcome of mechanochemical reactions Macromolecules. 47: 1187-1192. DOI: 10.1021/Ma4022339  0.485
2013 Leibfarth FA, Mattson KM, Fors BP, Collins HA, Hawker CJ. External regulation of controlled polymerizations. Angewandte Chemie (International Ed. in English). 52: 199-210. PMID 23166046 DOI: 10.1002/Anie.201206476  0.793
2013 Leibfarth FA, Hawker CJ. The emerging utility of ketenes in polymer chemistry Journal of Polymer Science, Part a: Polymer Chemistry. 51: 3769-3782. DOI: 10.1002/Pola.26797  0.608
2013 Jung H, Leibfarth FA, Woo S, Lee S, Kang M, Moon B, Hawker CJ, Bang J. Efficient surface neutralization and enhanced substrate adhesion through ketene mediated crosslinking and functionalization Advanced Functional Materials. 23: 1597-1602. DOI: 10.1002/Adfm.201201352  0.565
2012 Burke DJ, Kawauchi T, Kade MJ, Leibfarth FA, McDearmon B, Wolffs M, Kierstead PH, Moon B, Hawker CJ. Ketene-Based Route to rigid Cyclobutanediol Monomers for the Replacement of BPA in High Performance Polyesters. Acs Macro Letters. 1: 1228-1232. PMID 35607146 DOI: 10.1021/mz300497m  0.814
2012 Lee BF, Wolffs M, Delaney KT, Sprafke JK, Leibfarth FA, Hawker CJ, Lynd NA. Reactivity ratios, and mechanistic insight for anionic ring-opening copolymerization of epoxides. Macromolecules. 45: 3722-3731. PMID 23226879 DOI: 10.1021/Ma300634D  0.767
2012 Leibfarth FA, Wolffs M, Campos LM, Delany K, Treat N, Kade MJ, Moon B, Hawker CJ. Low-temperature ketene formation in materials chemistry through molecular engineering Chemical Science. 3: 766-771. DOI: 10.1039/C2Sc00841F  0.784
2012 Burke DJ, Kawauchi T, Kade MJ, Leibfarth FA, McDearmon B, Wolffs M, Kierstead PH, Moon B, Hawker CJ. Ketene-based route to rigid cyclobutanediol monomers for the replacement of BPA in high performance polyesters Acs Macro Letters. 1: 1228-1232. DOI: 10.1021/Mz300497M  0.811
2012 Leibfarth FA, Moreno N, Hawker AP, Shand JD. Transforming polylactide into value-added materials Journal of Polymer Science, Part a: Polymer Chemistry. 50: 4814-4822. DOI: 10.1002/Pola.26303  0.45
2012 Leibfarth FA, Mattson KM, Fors BP, Collins HA, Hawker CJ. Externe Regulation kontrollierter Polymerisationen Angewandte Chemie. 125: 210-222. DOI: 10.1002/Ange.201206476  0.74
2011 Leibfarth FA, Hawker CJ. Chemistry. Mechanically throwing a reaction into reverse. Science (New York, N.Y.). 333: 1582-3. PMID 21921184 DOI: 10.1126/Science.1210892  0.485
2011 Spruell JM, Wolffs M, Leibfarth FA, Stahl BC, Heo J, Connal LA, Hu J, Hawker CJ. Reactive, multifunctional polymer films through thermal cross-linking of orthogonal click groups. Journal of the American Chemical Society. 133: 16698-706. PMID 21919513 DOI: 10.1021/Ja207635F  0.543
2011 Miyamura Y, Park C, Kinbara K, Leibfarth FA, Hawker CJ, Aida T. Controlling volume shrinkage in soft lithography through heat-induced cross-linking of patterned nanofibers. Journal of the American Chemical Society. 133: 2840-3. PMID 21314183 DOI: 10.1021/Ja110901H  0.539
2010 Leibfarth FA, Kang M, Ham M, Kim J, Campos LM, Gupta N, Moon B, Hawker CJ. A facile route to ketene-functionalized polymers for general materials applications. Nature Chemistry. 2: 207-12. PMID 21124478 DOI: 10.1038/Nchem.538  0.757
2010 Leibfarth FA, Schneider Y, Lynd NA, Schultz A, Moon B, Kramer EJ, Bazan GC, Hawker CJ. Ketene functionalized polyethylene: control of cross-link density and material properties. Journal of the American Chemical Society. 132: 14706-9. PMID 20923158 DOI: 10.1021/Ja1060643  0.731
2007 Nederberg F, Lohmeijer BG, Leibfarth F, Pratt RC, Choi J, Dove AP, Waymouth RM, Hedrick JL. Organocatalytic ring opening polymerization of trimethylene carbonate. Biomacromolecules. 8: 153-60. PMID 17206801 DOI: 10.1021/Bm060795N  0.407
2006 Lohmeijer BG, Dubois G, Leibfarth F, Pratt RC, Nederberg F, Nelson A, Waymouth RM, Wade C, Hedrick JL. Organocatalytic living ring-opening polymerization of cyclic carbosiloxanes. Organic Letters. 8: 4683-6. PMID 17020277 DOI: 10.1021/Ol0614166  0.407
2006 Lohmeijer BGG, Pratt RC, Leibfarth F, Logan JW, Long DA, Dove AP, Nederberg F, Choi J, Wade C, Waymouth RM, Hedrick JL. Guanidine and amidine organocatalysts for ring-opening polymerization of cyclic esters Macromolecules. 39: 8574-8583. DOI: 10.1021/Ma0619381  0.43
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