John A. Weil - US grants

Affiliations:

Chemistry

University of Saskatchewan, Saskatoon, SK, Canada

Area:

Chemical Physics, NMR, EPR

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High-probability grants

According to our matching algorithm, John A. Weil is the likely recipient of the following grants.

Years	Recipients	Code	Title / Keywords	Matching score
1997	Weil, John A	P41Activity Code Description: Undocumented code - click on the grant title for more information.	Utility to Develop Single Crystal W Band Epr Spectrometry: Amethyst @ University of Illinois At Chicago technology /technique development; computers; spectrometry; biomedical resource; Show keywords Hide keywords	0.952
1997	Weil, John A	P41Activity Code Description: Undocumented code - click on the grant title for more information.	Utility to Develop Single Crystal W Band Epr Spectrometry: B Dicobalt Dioxygen @ University of Illinois At Chicago technology /technique development; computers; spectrometry; biomedical resource; Show keywords Hide keywords	0.952
1998	Weil, John A	P41Activity Code Description: Undocumented code - click on the grant title for more information.	Utility to Develop Single Crystal W Band Epr Spectrometry Amethyst @ University of Illinois At Chicago Project to study iron ions in amethyst single crystals, especially to detect/discover Fe(2+) and Fe(4+) resonances. 1) Line position angle roadmaps for 94.1 GHz EPR spectra were produced for all known Fe(3+) centres in [unreadable]-quartz, using 9.5 GHz previously measured spectra. These are serving as guidelines essential for the W-band work. 2) Major successful development work (months) was done to (learn to) produce 0.7mm diameter cylinders of carefully oriented amethyst crystals. 3) Preliminary W-band spectra at room temperature showed presence of several Fe(3+) centres, plus some as-yet unidentified centres. We seek to gain experience on use of W-band spectroscopy to detect and study Fe(4+) and transfer this experience to the characterization of Fe(+4) sites in metalloproteins. This is an ongoing project. Show summary Hide summary	0.952
1998	Weil, John A	P41Activity Code Description: Undocumented code - click on the grant title for more information.	Utility to Develop Single Crystal W Band Epr Spectrometry B Dicobalt Dioxygen @ University of Illinois At Chicago Project to study single crystals of magnetically diluted [[unreadable]-amido-[unreadable]nitrate(dicobalt)en4]tetranitrate. The idea is to measure the superoxo electron Zeeman splitting-factor matrix g at W-band to alleviate the severe problems in achieving this at lower frequencies, due to the multi-line complicated hyperfine structure caused by the 59Co nuclei. 1) Synthesis of the above magnetic dioxygen carrier, as of the diluent complex, were successful, and the desired mixed crystals were grown. 2) W-band measurements revealed EPR spectra very suitable for our purposes. Work will continue. Show summary Hide summary	0.952