Robert E. Gawley

Affiliations: 
Chemistry University of Arkansas, Little Rock, AR 
Area:
Organic Chemistry
Website:
http://news.uark.edu/articles/20539/bob-gawley-chair-of-chemistry-biochemistry-dies-at-64
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"Robert Gawley"
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Parents

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Steven W. Baldwin grad student 1970-1975 Duke
Richard G. Hiskey post-doc 1975-1977 UNC Chapel Hill
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Publications

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Spahn E, Albright A, Shevlin M, et al. (2013) Double-asymmetric hydrogenation strategy for the reduction of 1,1-diaryl olefins applied to an improved synthesis of CuIPhEt, a C2-symmetric N-heterocyclic carbenoid Journal of Organic Chemistry. 78: 2731-2735
Beng TK, Tyree WS, Parker T, et al. (2012) Dynamics of catalytic resolution of 2-lithio-N-Boc-piperidine by ligand exchange. Journal of the American Chemical Society. 134: 16845-55
Beng TK, Woo JS, Gawley RE. (2012) Synthetic applications and inversion dynamics of configurationally stable 2-lithio-2-arylpyrrolidines and -piperidines. Journal of the American Chemical Society. 134: 14764-71
Beng TK, Gawley RE. (2012) CATALYTIC DYNAMIC RESOLUTION APPLIED TO THE SYNTHESIS OF 2,6-DISUBSTITUTED PIPERIDINES: PREPARATION OF (+)-LUPETIDINE AND (-)-EPIDIHYDROPINIDINE. Heterocycles. 84: 697-718
Albright A, Gawley RE. (2011) Application of a C2-symmetric copper carbenoid in the enantioselective hydrosilylation of dialkyl and aryl-alkyl ketones. Journal of the American Chemical Society. 133: 19680-3
Gawley RE, Smith GA. (2011) Formal synthesis of the bisbenzylisoquinoline alkaloid berbamunine by asymmetric substitution of chiral organolithium compounds. Arkivoc : Free Online Journal of Organic Chemistry / Arkat-Usa, Inc. 2011: 167-179
Albright A, Eddings D, Black R, et al. (2011) Design and synthesis of C2-symmetric N-heterocyclic carbene precursors and metal carbenoids. The Journal of Organic Chemistry. 76: 7341-51
Beng TK, Gawley RE. (2011) Application of catalytic dynamic resolution of N-Boc-2-lithiopiperidine to the asymmetric synthesis of 2-aryl and 2-vinyl piperidines. Organic Letters. 13: 394-7
Beng TK, Gawley RE. (2010) Highly enantioselective catalytic dynamic resolution of N-Boc-2-lithiopiperidine: synthesis of (R)-(+)-N-Boc-pipecolic acid, (S)-(-)-coniine, (S)-(+)-pelletierine, (+)-beta-conhydrine, and (S)-(-)-ropivacaine and formal synthesis of (-)-lasubine II and (+)-cermizine C. Journal of the American Chemical Society. 132: 12216-7
Coldham I, Leonori D, Beng TK, et al. (2009) The barrier to enantiomerization and dynamic resolution of N-Boc-2-lithiopiperidine and the effect of TMEDA. Chemical Communications (Cambridge, England). 5239-41
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