| Year |
Citation |
Score |
| 2023 |
Lyu MY, Morais GN, Chen S, Brown MK. Ni-Catalyzed 1,1- and 1,3-Aminoboration of Unactivated Alkenes. Journal of the American Chemical Society. PMID 38078874 DOI: 10.1021/jacs.3c12770 |
0.347 |
|
| 2023 |
Crook PF, Lear AR, Das S, Brown MK. Cu/Pd-catalyzed arylboration of a 1-silyl-1,3-cyclohexadiene for stereocontrolled and diverse cyclohexane/ene synthesis. Chemical Science. 14: 10467-10470. PMID 37799986 DOI: 10.1039/d3sc02536e |
0.469 |
|
| 2023 |
Guo R, Brown MK. Lewis Acid-Promoted [2 + 2] Cycloadditions of Allenes and Ketenes: Versatile Methods for Natural Product Synthesis. Accounts of Chemical Research. 56: 2253-2264. PMID 37540783 DOI: 10.1021/acs.accounts.3c00334 |
0.367 |
|
| 2022 |
Trammel GL, Kannangara PB, Vasko D, Datsenko O, Mykhailiuk P, Brown MK. Arylboration of Enecarbamates for the Synthesis of Borylated Saturated N-Heterocycles. Angewandte Chemie (International Ed. in English). e202212117. PMID 36250954 DOI: 10.1002/anie.202212117 |
0.383 |
|
| 2022 |
Dorn SK, Brown MK. Cooperative Pd/Cu Catalysis for Alkene Arylboration: Opportunities for Divergent Reactivity. Acs Catalysis. 12: 2058-2063. PMID 36212545 DOI: 10.1021/acscatal.1c05696 |
0.317 |
|
| 2021 |
Simlandy AK, Lyu MY, Brown MK. Catalytic Arylboration of Spirocyclic Cyclobutenes: Rapid Access to Highly Substituted Spiro[3.n]alkanes. Acs Catalysis. 11: 12815-12820. PMID 35464106 DOI: 10.1021/acscatal.1c03491 |
0.791 |
|
| 2021 |
Ni D, Brown MK. Three-Component Ni-Catalyzed Silylacylation of Alkenes. Acs Catalysis. 11: 1858-1862. PMID 35462625 DOI: 10.1021/acscatal.0c05449 |
0.338 |
|
| 2021 |
Simlandy AK, Sardini SR, Brown MK. Construction of congested Csp-Csp bonds by a formal Ni-catalyzed alkylboration. Chemical Science. 12: 5517-5521. PMID 34168789 DOI: 10.1039/d1sc00900a |
0.748 |
|
| 2021 |
Dorn SK, Tharp AE, Brown MK. Modular Synthesis of a Versatile Double-Allylation Reagent for Complex Diol Synthesis. Angewandte Chemie (International Ed. in English). PMID 34117685 DOI: 10.1002/anie.202103435 |
0.704 |
|
| 2021 |
Simlandy AK, Brown MK. Allenylidene Induced 1,2-Metalate Rearrangement of Indole-Boronates: Diastereoselective Access to Highly Substituted Indolines. Angewandte Chemie (International Ed. in English). PMID 33734546 DOI: 10.1002/anie.202103108 |
0.763 |
|
| 2021 |
Lambright AL, Liu Y, Joyner IA, Logan KM, Brown MK. Mechanism-Based Design of an Amide-Directed Ni-Catalyzed Arylboration of Cyclopentene Derivatives. Organic Letters. PMID 33395309 DOI: 10.1021/acs.orglett.0c04208 |
0.309 |
|
| 2020 |
Bergmann AM, Sardini SR, Smith KB, Brown MK. Regioselective Arylboration of 1,3-Butadiene. Israel Journal of Chemistry. 60: 394-397. PMID 33859442 DOI: 10.1002/Ijch.201900060 |
0.344 |
|
| 2020 |
Sardini SR, Brown MK. Nickel-Catalyzed Arylboration of Cyclopentene. Organic Syntheses; An Annual Publication of Satisfactory Methods For the Preparation of Organic Chemicals. 97: 355-367. PMID 33487777 DOI: 10.15227/orgsyn.097.0355 |
0.314 |
|
| 2020 |
Ni D, Witherspoon BP, Zhang H, Zhou C, Houk KN, Brown MK. Stereoselective [4+2]-Cycloaddition with Chiral Alkenylboranes. Angewandte Chemie (International Ed. in English). PMID 32390259 DOI: 10.1002/Anie.202000652 |
0.413 |
|
| 2020 |
Guo R, Witherspoon BP, Brown MK. Evolution of a Strategy for the Enantioselective Synthesis of (-)-Cajanusine. Journal of the American Chemical Society. PMID 32149511 DOI: 10.1021/Jacs.0C00359 |
0.4 |
|
| 2019 |
Conner ML, Wiest JM, Brown MK. Thioallenoates in Catalytic Enantioselective [2+2]-Cycloadditions with Unactivated Alkenes. Tetrahedron. 75: 3265-3271. PMID 33100416 DOI: 10.1016/J.Tet.2019.04.028 |
0.404 |
|
| 2019 |
Joung S, Bergmann AM, Brown MK. Ni-catalyzed 1,2-benzylboration of 1,2-disubstituted unactivated alkenes. Chemical Science. 10: 10944-10947. PMID 32190251 DOI: 10.1039/C9Sc04199K |
0.437 |
|
| 2019 |
Hancock E, Kuker E, Tantillo D, Brown MK. Lessons in Strain and Stability: An Enantioselective Synthesis of (+)-[5]-Ladderanoic Acid. Angewandte Chemie (International Ed. in English). PMID 31650679 DOI: 10.1002/Anie.201910901 |
0.336 |
|
| 2019 |
Chen LA, Lear AR, Gao P, Brown MK. Nickel-Catalyzed Arylboration of Alkenylarenes: Synthesis of Boron-Substituted Quaternary Carbons and Regiodivergent Reactions. Angewandte Chemie (International Ed. in English). PMID 31250959 DOI: 10.1002/Anie.201904861 |
0.432 |
|
| 2019 |
Sardini SR, Lambright AL, Trammel GL, Omer HM, Liu P, Brown MK. Ni-Catalyzed Arylboration of Unactivated Alkenes: Scope and Mechanistic Studies. Journal of the American Chemical Society. PMID 31184148 DOI: 10.1021/Jacs.9B03991 |
0.468 |
|
| 2019 |
Huang Y, Bergmann AM, Brown MK. (Hetero)arylboration of alkynes: a strategy for the synthesis of α,α-bis(hetero)arylketones. Organic & Biomolecular Chemistry. PMID 31165124 DOI: 10.1039/C9Ob00961B |
0.337 |
|
| 2019 |
Silber Ashley O, Lane ME, Morgan JK, Charm S, Tharp A, Brown M. Perceptions of High-Risk Situations for Sexual Assault: Gender Differences in the U.S. Air Force. Military Medicine. 184: 443-450. PMID 30901445 DOI: 10.1093/milmed/usy350 |
0.542 |
|
| 2019 |
Huang Y, Brown MK. Synthesis of Bisheteroarylalkanes by Heteroarylboration: Development and Application of a Pyridylidene-Cu Complex. Angewandte Chemie (International Ed. in English). PMID 30838739 DOI: 10.1002/Anie.201902238 |
0.458 |
|
| 2018 |
Bergmann A, Dorn S, Smith K, Logan K, Brown MK. Catalyst-Controlled 1,2- and 1,1-Arylboration of α-Alkyl Alkenylarenes. Angewandte Chemie (International Ed. in English). PMID 30521697 DOI: 10.1002/Anie.201812533 |
0.328 |
|
| 2018 |
Fanning SW, Jeselsohn R, Dharmarajan V, Mayne CG, Karimi M, Buchwalter G, Houtman R, Toy W, Fowler CE, Han R, Lainé M, Carlson KE, Martin TA, Nowak J, Nwachukwu JC, ... ... Brown M, et al. The SERM/SERD bazedoxifene disrupts ESR1 helix 12 to overcome acquired hormone resistance in breast cancer cells. Elife. 7. PMID 30489256 DOI: 10.7554/Elife.37161 |
0.302 |
|
| 2018 |
Harcken C, Sarko C, Mao C, Lord J, Raudenbush B, Razavi H, Liu P, Swinamer A, Disalvo D, Lee T, Lin S, Kukulka A, Grbic H, Patel M, Patel M, ... ... Brown M, et al. Discovery and optimization of pyrazole amides as antagonists of CCR1. Bioorganic & Medicinal Chemistry Letters. PMID 30455146 DOI: 10.1016/j.bmcl.2018.11.015 |
0.35 |
|
| 2018 |
Wiest JM, Conner ML, Brown MK. Allenoates in Enantioselective [2+2] Cycloadditions: From a Mechanistic Curiosity to a Stereospecific Transformation. Journal of the American Chemical Society. PMID 30394735 DOI: 10.1021/Jacs.8B10008 |
0.384 |
|
| 2018 |
Gao P, Chen LA, Brown MK. Nickel-Catalyzed Stereoselective Diarylation of Alkenylarenes. Journal of the American Chemical Society. PMID 30125098 DOI: 10.1021/Jacs.8B05680 |
0.366 |
|
| 2018 |
Bergmann AM, Oldham AM, You W, Brown MK. Copper-catalyzed cross-coupling of aryl-, primary alkyl-, and secondary alkylboranes with heteroaryl bromides. Chemical Communications (Cambridge, England). PMID 29745398 DOI: 10.1039/C8Cc03145B |
0.45 |
|
| 2018 |
Smith KB, Huang Y, Brown MK. Copper-Catalyzed Heteroarylboration of 1,3-Dienes with 3-Bromopyridines: A cine Substitution. Angewandte Chemie (International Ed. in English). PMID 29697174 DOI: 10.1002/Anie.201801139 |
0.402 |
|
| 2018 |
Wiest J, Conner M, Brown MK. Synthesis of (-)-Hebelophyllene E: An Entry to geminal Dimethylcyclobutanes by [2+2] Cycloaddition of Alkenes and Allenoates. Angewandte Chemie (International Ed. in English). PMID 29481716 DOI: 10.1002/Anie.201801110 |
0.401 |
|
| 2017 |
Logan KM, Sardini SR, White SD, Brown MK. Nickel-Catalyzed Stereoselective Arylboration of Unactivated Alkenes. Journal of the American Chemical Society. PMID 29271650 DOI: 10.1021/Jacs.7B12160 |
0.438 |
|
| 2017 |
Line NJ, Witherspoon BP, Hancock EN, Brown MK. Synthesis of ent-[3]-Ladderanol: Development and Application of Intramolecular Chirality Transfer [2+2] Cycloadditions of Allenic Ketones and Alkenes. Journal of the American Chemical Society. PMID 28985064 DOI: 10.1021/Jacs.7B09844 |
0.425 |
|
| 2017 |
Brown MK, Huang Y, Smith K. Cu-Catalyzed Borylacylation of Activated Alkenes with Acid Chlorides. Angewandte Chemie (International Ed. in English). PMID 28849603 DOI: 10.1002/Anie.201707323 |
0.515 |
|
| 2017 |
Sardini SR, Brown MK. Catalyst Controlled Regiodivergent Arylboration of Dienes. Journal of the American Chemical Society. PMID 28699339 DOI: 10.1021/Jacs.7B05477 |
0.5 |
|
| 2017 |
Xu Y, Hong YJ, Tantillo DJ, Brown MK. Intramolecular Chirality Transfer [2 + 2] Cycloadditions of Allenoates and Alkenes. Organic Letters. PMID 28686031 DOI: 10.1021/Acs.Orglett.7B01420 |
0.411 |
|
| 2017 |
Smith KB, Brown MK. Regioselective Arylboration of Isoprene and Its Derivatives by Pd/Cu Cooperative Catalysis. Journal of the American Chemical Society. PMID 28581713 DOI: 10.1021/Jacs.7B04024 |
0.526 |
|
| 2016 |
Logan KM, Brown MK. Catalytic Enantioselective Arylboration of Alkenylarenes. Angewandte Chemie (International Ed. in English). PMID 28000415 DOI: 10.1002/Anie.201609844 |
0.465 |
|
| 2016 |
Conner ML, Brown MK. An unexpected Lewis acid catalyzed Diels-Alder cycloaddition of aryl allenes and acrylates. Tetrahedron. 72: 3759-3765. PMID 27695139 DOI: 10.1016/J.Tet.2016.02.028 |
0.427 |
|
| 2016 |
Conner ML, Brown MK. Synthesis of 1,3-Substituted Cyclobutanes by Allenoate-Alkene [2 + 2] Cycloaddition. The Journal of Organic Chemistry. PMID 27558964 DOI: 10.1021/Acs.Joc.6B01446 |
0.463 |
|
| 2015 |
You W, Brown MK. Catalytic Enantioselective Diarylation of Alkenes. Journal of the American Chemical Society. PMID 26565926 DOI: 10.1021/Jacs.5B10176 |
0.531 |
|
| 2015 |
Xu Y, Conner ML, Brown MK. Cyclobutane and Cyclobutene Synthesis: Catalytic Enantioselective [2+2] Cycloadditions. Angewandte Chemie (International Ed. in English). 54: 11918-28. PMID 26333192 DOI: 10.1002/Anie.201502815 |
0.431 |
|
| 2015 |
Conner ML, Xu Y, Brown MK. Catalytic enantioselective allenoate-alkene [2 + 2] cycloadditions. Journal of the American Chemical Society. 137: 3482-5. PMID 25756948 DOI: 10.1021/Jacs.5B00563 |
0.412 |
|
| 2015 |
Logan KM, Smith KB, Brown MK. Copper/palladium synergistic catalysis for the syn- and anti-selective carboboration of alkenes. Angewandte Chemie (International Ed. in English). 54: 5228-31. PMID 25727074 DOI: 10.1002/Anie.201500396 |
0.488 |
|
| 2014 |
Rasik CM, Brown MK. Total synthesis of gracilioether F: development and application of lewis Acid promoted ketene-alkene [2+2] cycloadditions and late-stage C-H oxidation. Angewandte Chemie (International Ed. in English). 53: 14522-6. PMID 25359632 DOI: 10.1002/Anie.201408055 |
0.329 |
|
| 2014 |
You W, Brown MK. Diarylation of alkenes by a Cu-catalyzed migratory insertion/cross-coupling cascade. Journal of the American Chemical Society. 136: 14730-3. PMID 25303225 DOI: 10.1021/Ja509056J |
0.533 |
|
| 2014 |
Rasik CM, Hong YJ, Tantillo DJ, Brown MK. Origins of diastereoselectivity in Lewis acid promoted ketene-alkene [2 + 2] cycloadditions. Organic Letters. 16: 5168-71. PMID 25230201 DOI: 10.1021/Ol5025184 |
0.306 |
|
| 2014 |
Smith KB, Logan KM, You W, Brown MK. Alkene carboboration enabled by synergistic catalysis. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 12032-6. PMID 25113669 DOI: 10.1002/Chem.201404310 |
0.446 |
|
| 2014 |
Zhou Y, You W, Smith KB, Brown MK. Copper-catalyzed cross-coupling of boronic esters with aryl iodides and application to the carboboration of alkynes and allenes. Angewandte Chemie (International Ed. in English). 53: 3475-9. PMID 24677502 DOI: 10.1002/Anie.201310275 |
0.453 |
|
| 2014 |
Rasik CM, Brown MK. Intermolecular ketene-alkene [2+2] cycloadditions: The significance of lewis acid promoted variants Synlett. 25: 760-765. DOI: 10.1055/S-0033-1340626 |
0.368 |
|
| 2013 |
Otrubova K, Brown M, McCormick MS, Han GW, O'Neal ST, Cravatt BF, Stevens RC, Lichtman AH, Boger DL. Rational design of fatty acid amide hydrolase inhibitors that act by covalently bonding to two active site residues. Journal of the American Chemical Society. 135: 6289-99. PMID 23581831 DOI: 10.1021/Ja4014997 |
0.316 |
|
| 2013 |
You W, Li Y, Brown MK. Stereoselective synthesis of all-carbon tetrasubstituted alkenes from in situ generated ketenes and organometallic reagents. Organic Letters. 15: 1610-3. PMID 23480662 DOI: 10.1021/Ol400392R |
0.452 |
|
| 2013 |
Rasik CM, Brown MK. Lewis acid-promoted ketene-alkene [2 + 2] cycloadditions. Journal of the American Chemical Society. 135: 1673-6. PMID 23351170 DOI: 10.1021/Ja3103007 |
0.407 |
|
| 2010 |
Brown MK, Blewett MM, Colombe JR, Corey EJ. Mechanism of the enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes. Journal of the American Chemical Society. 132: 11165-70. PMID 20666410 DOI: 10.1021/Ja103103D |
0.461 |
|
| 2010 |
Brown MK, Corey EJ. Catalytic enantioselective formation of chiral-bridged dienes which are themselves ligands for enantioselective catalysis. Organic Letters. 12: 172-5. PMID 19947622 DOI: 10.1021/Ol9025793 |
0.568 |
|
| 2008 |
Brown MK, Hoveyda AH. Enantioselective total synthesis of clavirolide C. Applications of Cu-catalyzed asymmetric conjugate additions and Ru-catalyzed ring-closing metathesis. Journal of the American Chemical Society. 130: 12904-6. PMID 18778057 DOI: 10.1021/Ja8058414 |
0.673 |
|
| 2008 |
May TL, Brown MK, Hoveyda AH. Enantioselective synthesis of all-carbon quaternary stereogenic centers by catalytic asymmetric conjugate additions of alkyl and aryl aluminum reagents to five-, six-, and seven-membered-ring beta-substituted cyclic enones. Angewandte Chemie (International Ed. in English). 47: 7358-62. PMID 18683828 DOI: 10.1002/Anie.200802910 |
0.769 |
|
| 2008 |
Lee Y, Akiyama K, Gillingham DG, Brown MK, Hoveyda AH. Highly site- and enantioselective Cu-catalyzed allylic alkylation reactions with easily accessible vinylaluminum reagents. Journal of the American Chemical Society. 130: 446-7. PMID 18088127 DOI: 10.1021/Ja0782192 |
0.798 |
|
| 2007 |
Burton PR, Clayton DG, Cardon LR, Craddock N, Deloukas P, Duncanson A, Kwiatkowski DP, McCarthy MI, Ouwehand WH, Samani NJ, Todd JA, Donnelly P, Barrett JC, ... ... Brown MJ, ... ... Brown MA, ... ... Brown MA, ... ... Brown M, et al. Association scan of 14,500 nonsynonymous SNPs in four diseases identifies autoimmunity variants. Nature Genetics. 39: 1329-37. PMID 17952073 DOI: 10.1038/Ng.2007.17 |
0.336 |
|
| 2007 |
Brown MK, May TL, Baxter CA, Hoveyda AH. All-carbon quaternary stereogenic centers by enantioselective cu-catalyzed conjugate additions promoted by a chiral N-heterocyclic carbene. Angewandte Chemie (International Ed. in English). 46: 1097-100. PMID 17200971 DOI: 10.1002/Anie.200604511 |
0.79 |
|
| 2007 |
Hoveyda A, Brown M, May T, Baxter C. Quaternary Carbon Stereocenters via NHC-Cu Induced Conjugate Addition Synfacts. 2007: 0516-0516. DOI: 10.1055/S-2007-968460 |
0.776 |
|
| 2006 |
Lee KS, Brown MK, Hird AW, Hoveyda AH. A practical method for enantioselective synthesis of all-carbon quaternary stereogenic centers through NHC-Cu-catalyzed conjugate additions of alkyl- and arylzinc reagents to beta-substituted cyclic enones. Journal of the American Chemical Society. 128: 7182-4. PMID 16734469 DOI: 10.1021/Ja062061O |
0.817 |
|
| 2006 |
Hoveyda A, Lee K, Brown M, Hird A. Enantioselective Conjugate Addition of Organozinc Reagents to Enones Synfacts. 2006: 0913-0913. DOI: 10.1055/S-2006-949261 |
0.766 |
|
| 2005 |
Brown MK, Degrado SJ, Hoveyda AH. Highly enantioselective Cu-catalyzed conjugate additions of dialkylzinc reagents to unsaturated furanones and pyranones: preparation of air-stable and catalytically active Cu-peptide complexes. Angewandte Chemie (International Ed. in English). 44: 5306-10. PMID 16041815 DOI: 10.1002/Anie.200501251 |
0.786 |
|
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