Ronald Charles David Breslow - Publications

Affiliations: 
Columbia University, New York, NY 
Area:
physical organic chemistry
Website:
http://www.columbia.edu/cu/chemistry/breslow/boss.html

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Year Citation  Score
2017 Porter NJ, Mahendran A, Breslow R, Christianson DW. Unusual zinc-binding mode of HDAC6-selective hydroxamate inhibitors. Proceedings of the National Academy of Sciences of the United States of America. PMID 29203661 DOI: 10.1073/Pnas.1718823114  0.749
2015 Lee JH, Yao Y, Mahendran A, Ngo L, Venta-Perez G, Choy ML, Breslow R, Marks PA. Development of a histone deacetylase 6 inhibitor and its biological effects. Proceedings of the National Academy of Sciences of the United States of America. PMID 26371309 DOI: 10.1073/Pnas.1515882112  0.6
2015 Gopinath P, Ramalingam V, Breslow R. Magnesium pyrophosphates in enzyme mimics of nucleotide synthases and kinases and in their prebiotic chemistry. Proceedings of the National Academy of Sciences of the United States of America. 112: 12011-4. PMID 26371307 DOI: 10.1073/Pnas.1516239112  0.771
2015 Cheng L, Doubleday C, Breslow R. Evidence for tunneling in base-catalyzed isomerization of glyceraldehyde to dihydroxyacetone by hydride shift under formose conditions. Proceedings of the National Academy of Sciences of the United States of America. 112: 4218-20. PMID 25831511 DOI: 10.1073/Pnas.1503739112  0.402
2015 Mahendran A, Gopinath P, Breslow R. Single molecule conductance of aromatic, nonaromatic, and partially antiaromatic systems Tetrahedron Letters. 56: 4833-4835. DOI: 10.1016/J.Tetlet.2015.06.076  0.774
2014 Breslow R. Novel Aromatic and Antiaromatic Systems Chemical Record. 14: 1174-1182. PMID 25335917 DOI: 10.1002/Tcr.201402070  0.303
2014 Cheng L, Mahendran A, Gonzalez RL, Breslow R. Deoxypolypeptides bind and cleave RNA. Proceedings of the National Academy of Sciences of the United States of America. 111: 7920-4. PMID 24843145 DOI: 10.1073/Pnas.1407295111  0.674
2014 Appayee C, Breslow R. Deuterium studies reveal a new mechanism for the formose reaction involving hydride shifts. Journal of the American Chemical Society. 136: 3720-3. PMID 24575857 DOI: 10.1021/Ja410886C  0.775
2014 Chen W, Li H, Widawsky JR, Appayee C, Venkataraman L, Breslow R. Aromaticity decreases single-molecule junction conductance. Journal of the American Chemical Society. 136: 918-20. PMID 24397414 DOI: 10.1021/Ja411143S  0.775
2013 Breslow R, Ramalingam V, Appayee C. Catalysis of glyceraldehyde synthesis by primary or secondary amino acids under prebiotic conditions as a function of pH. Origins of Life and Evolution of the Biosphere : the Journal of the International Society For the Study of the Origin of Life. 43: 323-9. PMID 24346788 DOI: 10.1007/S11084-013-9347-0  0.766
2013 Lee JH, Mahendran A, Yao Y, Ngo L, Venta-Perez G, Choy ML, Kim N, Ham WS, Breslow R, Marks PA. Development of a histone deacetylase 6 inhibitor and its biological effects. Proceedings of the National Academy of Sciences of the United States of America. 110: 15704-9. PMID 24023063 DOI: 10.1073/Pnas.1313893110  0.723
2013 Breslow R, Appayee C. Transketolase reaction under credible prebiotic conditions. Proceedings of the National Academy of Sciences of the United States of America. 110: 4184-7. PMID 23440198 DOI: 10.1073/Pnas.1301522110  0.781
2012 Vazquez H, Skouta R, Schneebeli S, Kamenetska M, Breslow R, Venkataraman L, Hybertsen MS. Probing the conductance superposition law in single-molecule circuits with parallel paths. Nature Nanotechnology. 7: 663-7. PMID 22941403 DOI: 10.1038/Nnano.2012.147  0.633
2012 Cheng L, Abhilash KG, Breslow R. Binding and biomimetic cleavage of the RNA poly(U) by synthetic polyimidazoles Proceedings of the National Academy of Sciences of the United States of America. 109: 12884-12887. PMID 22826260 DOI: 10.1073/Pnas.1210846109  0.383
2011 Chen W, Widawsky JR, Vázquez H, Schneebeli ST, Hybertsen MS, Breslow R, Venkataraman L. Highly conducting π-conjugated molecular junctions covalently bonded to gold electrodes. Journal of the American Chemical Society. 133: 17160-3. PMID 21939263 DOI: 10.1021/Ja208020J  0.64
2011 Cheng ZL, Skouta R, Vazquez H, Widawsky JR, Schneebeli S, Chen W, Hybertsen MS, Breslow R, Venkataraman L. In situ formation of highly conducting covalent Au-C contacts for single-molecule junctions. Nature Nanotechnology. 6: 353-7. PMID 21552252 DOI: 10.1038/Nnano.2011.66  0.644
2011 Schneebeli ST, Kamenetska M, Cheng Z, Skouta R, Friesner RA, Venkataraman L, Breslow R. Single-molecule conductance through multiple π-π-stacked benzene rings determined with direct electrode-to-benzene ring connections. Journal of the American Chemical Society. 133: 2136-9. PMID 21265533 DOI: 10.1021/Ja111320N  0.706
2011 Breslow R, Schneebeli ST. Structure-property relationships in molecular wires Tetrahedron. 67: 10171-10178. DOI: 10.1016/J.Tet.2011.08.008  0.624
2010 Zhao H, Breslow R. A mimic of the pyruvate dehydrogenase complex. Bioorganic & Medicinal Chemistry Letters. 20: 5973-5. PMID 20826089 DOI: 10.1016/J.Bmcl.2010.08.077  0.627
2010 Schneebeli S, Kamenetska M, Foss F, Vazquez H, Skouta R, Hybertsen M, Venkataraman L, Breslow R. The electrical properties of biphenylenes. Organic Letters. 12: 4114-7. PMID 20722383 DOI: 10.1021/Ol1017036  0.775
2010 Breslow R, Levine M, Cheng ZL. Imitating prebiotic homochirality on Earth. Origins of Life and Evolution of the Biosphere : the Journal of the International Society For the Study of the Origin of Life. 40: 11-26. PMID 19911303 DOI: 10.1007/S11084-009-9179-0  0.52
2010 Skouta R, Wei S, Breslow R. High rates and substrate selectivities in water by polyvinylimidazoles as transaminase enzyme mimics with hydrophobically bound pyridoxamine derivatives as coenzyme mimics. Journal of the American Chemical Society. 131: 15604-5. PMID 19824661 DOI: 10.1021/Ja9072589  0.307
2009 Wei S, Wang J, Venhuizen S, Skouta R, Breslow R. Dendrimers in solution can have their remote catalytic groups folded back into the core: enantioselective transaminations by dendritic enzyme mimics-II. Bioorganic & Medicinal Chemistry Letters. 19: 5543-6. PMID 19729305 DOI: 10.1016/J.Bmcl.2009.08.061  0.498
2009 Schneebeli ST, Hall ML, Breslow R, Friesner R. Quantitative DFT modeling of the enantiomeric excess for dioxirane-catalyzed epoxidations. Journal of the American Chemical Society. 131: 3965-73. PMID 19243187 DOI: 10.1021/Ja806951R  0.691
2008 Levine M, Kenesky CS, Zheng S, Quinn J, Breslow R. Synthesis and catalytic properties of diverse chiral polyamines. Tetrahedron Letters. 49: 5746-5750. PMID 19794811 DOI: 10.1016/J.Tetlet.2008.07.108  0.715
2008 Zhao H, Foss FW, Breslow R. Artificial enzymes with thiazolium and imidazolium coenzyme mimics Journal of the American Chemical Society. 130: 12590-12591. PMID 18763766 DOI: 10.1021/Ja804577Q  0.769
2008 Levine M, Kenesky CS, Mazori D, Breslow R. Enantioselective synthesis and enantiomeric amplification of amino acids under prebiotic conditions. Organic Letters. 10: 2433-6. PMID 18491865 DOI: 10.1021/Ol8007099  0.515
2008 Breslow R, Foss FW. Charge transport in nanoscale aromatic and antiaromatic systems Journal of Physics Condensed Matter. 20. DOI: 10.1088/0953-8984/20/37/374104  0.677
2007 Quinn JR, Foss FW, Venkataraman L, Breslow R. Oxidation potentials correlate with conductivities of aromatic molecular wires. Journal of the American Chemical Society. 129: 12376-7. PMID 17887757 DOI: 10.1021/Ja0745097  0.769
2007 Quinn JR, Foss FW, Venkataraman L, Hybertsen MS, Breslow R. Single-molecule junction conductance through diaminoacenes. Journal of the American Chemical Society. 129: 6714-5. PMID 17488083 DOI: 10.1021/Ja0715804  0.77
2007 Bandyopadhyay S, Zhou W, Breslow R. Isotactic polyethylenimines induce formation of L-amino acids in transamination. Organic Letters. 9: 1009-12. PMID 17316011 DOI: 10.1021/Ol0630604  0.507
2007 Breslow R, Wei S, Kenesky C. Enantioselective transaminations by dendrimeric enzyme mimics Tetrahedron. 63: 6317-6321. DOI: 10.1016/J.Tet.2007.02.052  0.316
2006 Breslow R, Bandyopadhyay S, Levine M, Zhou W. Water exclusion and enantioselectivity in catalysis. Chembiochem : a European Journal of Chemical Biology. 7: 1491-6. PMID 16977662 DOI: 10.1002/Cbic.200600120  0.6
2006 Breslow R, Levine MS. Amplification of enantiomeric concentrations under credible prebiotic conditions. Proceedings of the National Academy of Sciences of the United States of America. 103: 12979-80. PMID 16938839 DOI: 10.1073/Pnas.0605863103  0.508
2006 Guo X, Small JP, Klare JE, Wang Y, Purewal MS, Tam IW, Hong BH, Caldwell R, Huang L, O'brien S, Yan J, Breslow R, Wind SJ, Hone J, Kim P, et al. Covalently bridging gaps in single-walled carbon nanotubes with conducting molecules. Science (New York, N.Y.). 311: 356-9. PMID 16424333 DOI: 10.1126/Science.1120986  0.775
2006 Fang Z, Breslow R. Metal coordination-directed hydroxylation of steroids with a novel artificial P-450 catalyst. Organic Letters. 8: 251-4. PMID 16408887 DOI: 10.1021/Ol052589I  0.513
2006 Tam IW, Yan J, Breslow R. An 11 nm molecular wire that switches electrochemically between an insulating and a fully conjugated conducting state. Organic Letters. 8: 183-5. PMID 16408870 DOI: 10.1021/Ol052252G  0.768
2006 Breslow R, Levine MS. Partial transfer of enantioselective chiralities from α-methylated amino acids, known to be of meteoritic origin, into normal amino acids Tetrahedron Letters. 47: 1809-1812. DOI: 10.1016/J.Tetlet.2006.01.018  0.514
2006 Uyeda C, Biscoe M, LePlae P, Breslow R. Hydrophobically directed selective reduction of ketones using amine boranes Tetrahedron Letters. 47: 127-130. DOI: 10.1016/J.Tetlet.2005.10.117  0.785
2006 Breslow R. The hydrophobic effect in reaction mechanism studies and in catalysis by artificial enzymes Journal of Physical Organic Chemistry. 19: 813-822. DOI: 10.1002/Poc.1037  0.321
2005 Fang Z, Breslow R. A thiolate ligand on a cytochrome P-450 mimic permits the use of simple environmentally benign oxidants for biomimetic steroid hydroxylation in water. Bioorganic & Medicinal Chemistry Letters. 15: 5463-6. PMID 16183271 DOI: 10.1016/J.Bmcl.2005.08.090  0.512
2005 Biscoe MR, Breslow R. Oxaziridinium salts as hydrophobic epoxidation reagents: remarkable hydrophobically-directed selectivity in olefin epoxidation. Journal of the American Chemical Society. 127: 10812-3. PMID 16076170 DOI: 10.1021/Ja053660I  0.729
2005 Chruma JJ, Liu L, Zhou W, Breslow R. Hydrophobic and electronic factors in the design of dialkylglycine decarboxylase mimics. Bioorganic & Medicinal Chemistry. 13: 5873-83. PMID 15953728 DOI: 10.1016/J.Bmc.2005.05.019  0.671
2005 Zhou W, Yerkes N, Chruma JJ, Liu L, Breslow R. Chiral polyamines from reduction of polypeptides: asymmetric pyridoxamine-mediated transaminations. Bioorganic & Medicinal Chemistry Letters. 15: 1351-5. PMID 15713385 DOI: 10.1016/J.Bmcl.2005.01.021  0.673
2004 Biscoe MR, Uyeda C, Breslow R. Requirements for selective hydrophobic acceleration in the reduction of ketones. Organic Letters. 6: 4331-4. PMID 15524476 DOI: 10.1021/Ol0481481  0.792
2004 Bong D, Tam I, Breslow R. Oligothiophene Isocyanides for Platinum-Based Molecular Electronic Applications Journal of the American Chemical Society. 126: 11796-11797. PMID 15382906 DOI: 10.1021/Ja045904P  0.76
2004 Liu L, Zhou W, Chruma J, Breslow R. Transamination reactions with multiple turnovers catalyzed by hydrophobic pyridoxamine cofactors in the presence of polyethylenimine polymers Journal of the American Chemical Society. 126: 8136-8137. PMID 15225053 DOI: 10.1021/Ja048671A  0.685
2004 Liu L, Breslow R. Dendrimeric pyridoxamine enzyme mimics. Journal of the American Chemical Society. 125: 12110-1. PMID 14518994 DOI: 10.1021/Ja0374473  0.323
2004 Leivers M, Tam I, Groves K, Leung D, Xie Y, Breslow R. A forbidden rearrangement. Organic Letters. 5: 3407-9. PMID 12967286 DOI: 10.1021/ol034997x  0.774
2003 Biscoe MR, Breslow R. Hydrophobically directed selective reduction of ketones. Journal of the American Chemical Society. 125: 12718-9. PMID 14558814 DOI: 10.1021/Ja0379924  0.732
2003 Leivers M, Tam I, Groves K, Leung D, Xie Y, Breslow R. A Forbidden Rearrangement Organic Letters. 5: 3407-3409. DOI: 10.1021/Ol034997X  0.766
2003 Light J, Breslow R. A Water‐Soluble Tin Hydride: Tris[3‐(2‐Methoxyethoxy)Propyl]Stannane Organic Syntheses. 199-199. DOI: 10.1002/0471264180.Os072.24  0.336
2002 Liu L, Rozenman M, Breslow R. Stereoselectivity in reactions of amino acids catalyzed by pyridoxal derivatives carrying rigidly-attached chirally-mounted basic groups - Transamination, racemization, decarboxylation, retro-aldol reaction, and aldol condensation Bioorganic and Medicinal Chemistry. 10: 3973-3979. PMID 12413849 DOI: 10.1016/S0968-0896(02)00334-6  0.357
2002 Yang J, Gabriele B, Belvedere S, Huang Y, Breslow R. Catalytic oxidations of steroid substrates by artificial cytochrome p-450 enzymes. The Journal of Organic Chemistry. 67: 5057-67. PMID 12126389 DOI: 10.1021/Jo020174U  0.793
2002 Liu L, Breslow R. A potent polymer/pyridoxamine enzyme mimic. Journal of the American Chemical Society. 124: 4978-9. PMID 11982360 DOI: 10.1021/Ja025895P  0.303
2002 Breslow R, Groves K, Mayer MU. Antihydrophobic cosolvent effects for alkylation reactions in water solution, particularly oxygen versus carbon alkylations of phenoxide ions. Journal of the American Chemical Society. 124: 3622-35. PMID 11929252 DOI: 10.1021/Ja012293H  0.753
2002 Liu L, Rozenman M, Breslow R. Hydrophobic effects on rates and substrate selectivities in polymeric transaminase mimics Journal of the American Chemical Society. 124: 12660-12661. DOI: 10.1021/Ja028151K  0.342
2002 Breslow R, Fang Z. Hydroxylation of steroids with an artificial P-450 catalyst bearing synthetic cyclophanes as binding groups Tetrahedron Letters. 43: 5197-5200. DOI: 10.1016/S0040-4039(02)01028-6  0.509
2002 Breslow R, Yan J, Belvedere S. Catalytic hydroxylation of steroids by cytochrome P-450 mimics. Hydroxylation at C-9 with novel catalysts and steroid substrates Tetrahedron Letters. 43: 363-365. DOI: 10.1016/S0040-4039(01)02142-6  0.744
2002 Breslow R, Yang J, Yan J. Biomimetic hydroxylation of saturated carbons with artificial cytochrome P-450 enzymes - Liberating chemistry from the tyranny of functional groups Tetrahedron. 58: 653-659. DOI: 10.1016/S0040-4020(01)01098-5  0.598
2002 Weiner W, Winkler J, Zimmerman SC, Czarnik AW, Breslow R. Mimics of tryptophan synthetase and of biochemical dehydroalanine formation Cheminform. 16. DOI: 10.1002/Chin.198543345  0.727
2001 Belvedere S, Breslow R. Regioselective oxidation of steroids by a manganese porphyrin carrying metal coordinating groups. Bioorganic Chemistry. 29: 321-31. PMID 16256701 DOI: 10.1006/Bioo.2001.1215  0.733
2001 Leivers M, Breslow R. Concerning two-metal cooperativity in model phosphate hydrolysis. Bioorganic Chemistry. 29: 345-356. PMID 11846433 DOI: 10.1006/Bioo.2001.1221  0.774
2001 Baugh SD, Yang Z, Leung DK, Wilson DM, Breslow R. Cyclodextrin dimers as cleavable carriers of photodynamic sensitizers. Journal of the American Chemical Society. 123: 12488-94. PMID 11741411 DOI: 10.1021/Ja011709O  0.608
2001 Leung DK, Atkins JH, Breslow R. Synthesis and binding properties of cyclodextrin trimers Tetrahedron Letters. 42: 6255-6258. DOI: 10.1016/S0040-4039(01)01200-X  0.73
2001 Liu L, Breslow R. Selective racemization in preference to transamination catalyzed by pyridoxal enzyme analogs Tetrahedron Letters. 42: 2775-2777. DOI: 10.1016/S0040-4039(01)00329-X  0.303
2000 Nesnas N, Lou J, Breslow R. The binding of cocaine to cyclodextrins Bioorganic and Medicinal Chemistry Letters. 10: 1931-1933. PMID 10987420 DOI: 10.1016/S0960-894X(00)00371-1  0.657
2000 Leung DK, Yang Z, Breslow R. Selective disruption of protein aggregation by cyclodextrin dimers. Proceedings of the National Academy of Sciences of the United States of America. 97: 5050-3. PMID 10805768 DOI: 10.1073/Pnas.97.10.5050  0.592
2000 Breslow R, Belvedere S, Gershell L, Leung D. The chelate effect in binding, catalysis, and chemotherapy Pure and Applied Chemistry. 72: 333-342. DOI: 10.1351/Pac200072030333  0.766
2000 Yang J, Weinberg R, Breslow R. The hydroxylation and amidation of equilenin acetate catalyzed by chloro[5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato]manganese(III) Chemical Communications. 531-532. DOI: 10.1039/B000463O  0.582
2000 Yang J, Breslow R. Regioselective oxidations of equilenin derivatives catalyzed by a rhodium(III) porphyrin complex—contrast with the manganese(III) porphyrin Tetrahedron Letters. 41: 8063-8067. DOI: 10.1016/S0040-4039(00)01402-7  0.567
2000 Yan J, Breslow R. An enzyme mimic that hydrolyzes an unactivated ester with catalytic turnover Tetrahedron Letters. 41: 2059-2062. DOI: 10.1016/S0040-4039(00)00114-3  0.305
2000 Breslow R, Belvedere S, Gershell L. Development of cytodifferentiating agents for cancer chemotherapy Helvetica Chimica Acta. 83: 1685-1692. DOI: 10.1002/1522-2675(20000809)83:8<1685::Aid-Hlca1685>3.0.Co;2-4  0.754
2000 Yang J, Breslow R. Selective hydroxylation of a steroid at C-9 by an artificial cytochrome P-450 Angewandte Chemie - International Edition. 39: 2692-2694. DOI: 10.1002/1521-3773(20000804)39:15<2692::Aid-Anie2692>3.0.Co;2-3  0.531
1999 Ruebner A, Yang Z, Leung D, Breslow R. A cyclodextrin dimer with a photocleavable linker as a possible carrier for the photosensitizer in photodynamic tumor therapy Proceedings of the National Academy of Sciences of the United States of America. 96: 14692-14693. PMID 10611274 DOI: 10.1073/Pnas.96.26.14692  0.6
1999 Fasella E, Dong SD, Breslow R. Reversal of optical induction in transamination by regioisomeric bifunctionalized cyclodextrins. Bioorganic & Medicinal Chemistry. 7: 709-714. PMID 10400323 DOI: 10.1016/S0968-0896(98)00193-X  0.317
1999 Webb Y, Zhou X, Ngo L, Cornish V, Stahl J, Erdjument-Bromage H, Tempst P, Rifkind RA, Marks PA, Breslow R, Richon VM. Photoaffinity labeling and mass spectrometry identify ribosomal protein S3 as a potential target for hybrid polar cytodifferentiation agents Journal of Biological Chemistry. 274: 14280-14287. PMID 10318849 DOI: 10.1074/Jbc.274.20.14280  0.581
1999 Breslow R, Nesnas N. Burst kinetics and turnover in an esterase mimic Tetrahedron Letters. 40: 3335-3338. DOI: 10.1016/S0040-4039(99)00460-8  0.696
1998 Breslow R, Dong SD. Biomimetic Reactions Catalyzed by Cyclodextrins and Their Derivatives. Chemical Reviews. 98: 1997-2012. PMID 11848956 DOI: 10.1021/Cr970011J  0.372
1998 Breslow R, Groves K, Mayer MU. The hydrophobic effect as a mechanistic tool Pure and Applied Chemistry. 70: 1933-1938. DOI: 10.1351/Pac199870101933  0.738
1998 Breslow R. Studies in biomimetic chemistry Pure and Applied Chemistry. 70: 267-270. DOI: 10.1351/Pac199870020267  0.321
1998 Zhang B, Breslow R. Ester Hydrolysis by a Catalytic Cyclodextrin Dimer Enzyme Mimic with a Metallobipyridyl Linking Group J. Am. Chem. Soc. 1997, 119, 1676−1681 Journal of the American Chemical Society. 120: 5854-5854. DOI: 10.1021/Ja985507C  0.309
1998 Breslow R, Gabriele B, Yang J. Geometrically directed selective steroid hydroxylation with high turnover by a fluorinated artificial cytochrome P-450 Tetrahedron Letters. 39: 2887-2890. DOI: 10.1016/S0040-4039(98)00425-0  0.573
1997 Breslow R, Huang Y, Zhang X, Yang J. An artificial cytochrome P450 that hydroxylates unactivated carbons with regio- and stereoselectivity and useful catalytic turnovers Proceedings of the National Academy of Sciences of the United States of America. 94: 11156-11158. PMID 9326577 DOI: 10.1073/Pnas.94.21.11156  0.598
1997 Zhang B, Breslow R. Ester Hydrolysis by a Catalytic Cyclodextrin Dimer Enzyme Mimic with a Metallobipyridyl Linking Group Journal of the American Chemical Society. 119: 1676-1681. DOI: 10.1021/Ja963769D  0.342
1997 Rezac M, Breslow R. A mutase mimic with cobalamin linked to cyclodextrin Tetrahedron Letters. 38: 5763-5766. DOI: 10.1016/S0040-4039(97)01289-6  0.311
1997 Klicic J, Rubin Y, Breslow R. Approaches to stable cyclopropenyl anions: Tris-1,2,3-p-nitrophenylcyclopropene Tetrahedron. 53: 4129-4136. DOI: 10.1016/S0040-4020(97)00129-4  0.6
1996 Breslow R, Chapman WH. On the mechanism of action of ribonuclease A: relevance of enzymatic studies with a p-nitrophenylphosphate ester and a thiophosphate ester. Proceedings of the National Academy of Sciences of the United States of America. 93: 10018-10021. PMID 8816743 DOI: 10.1073/Pnas.93.19.10018  0.358
1996 Breslow R, Zhang X, Xu R, Maletic aM, Merger R. Selective Catalytic Oxidation of Substrates That Bind to Metalloporphyrin Enzyme Mimics Carrying Two or Four Cyclodextrin Groups and Related Metallosalens Journal of the American Chemical Society. 118: 11678-11679. DOI: 10.1021/Ja962295F  0.322
1996 Breslow R, Schmuck C. Goodness of Fit in Complexes between Substrates and Ribonuclease Mimics:  Effects on Binding, Catalytic Rate Constants, and Regiochemistry Journal of the American Chemical Society. 118: 6601-6605. DOI: 10.1021/Ja954307N  0.678
1996 Breslow R, Dong SD, Webb Y, Xu R. Further Studies on the Buffer-Catalyzed Cleavage and Isomerization of Uridyluridine. Medium and Ionic Strength Effects on Catalysis by Morpholine, Imidazole, and Acetate Buffers Help Clarify the Mechanisms Involved and Their Relationship to the Mechanism Used by the Enzyme Ribonuclease and by a Ribonuclease Mimic Journal of the American Chemical Society. 118: 6588-6600. DOI: 10.1021/Ja9526933  0.357
1996 Breslow R, Schmuck C. The mechanism of thiazolium catalysis Tetrahedron Letters. 37: 8241-8242. DOI: 10.1016/0040-4039(96)01878-3  0.66
1996 Breslow R, Desper J, Huang Y. A selective intramolecular aldol condensation directed by a bifunctional enzyme mimic Tetrahedron Letters. 37: 2541-2544. DOI: 10.1016/0040-4039(96)00337-1  0.356
1995 Breslow R. Binding and catalysis with flexible locks and flexible keys1 Supramolecular Chemistry. 6: 41-47. DOI: 10.1080/10610279508032518  0.315
1995 Chapman WH, Breslow R. Selective Hydrolysis Of Phosphate Esters, Nitrophenyl Phosphates And Upu, By Dimeric Zinc Complexes Depends On The Spacer Length Journal of the American Chemical Society. 117: 5462-5469. DOI: 10.1021/Ja00125A005  0.307
1994 Desper JM, Breslow R. Catalysis Of An Intramolecular Aldol Condensation By Imidazole-Bearing Cyclodextrins Journal of the American Chemical Society. 116: 12080-12082. DOI: 10.1021/Ja00105A070  0.338
1994 Koh JT, Delaude L, Breslow R. Geometric Control of a Pyridoxal-Catalyzed Aldol Condensation Journal of the American Chemical Society. 116: 11234-11240. DOI: 10.1021/Ja00104A004  0.673
1994 Breslow R, Kim R. The thiazolium catalyzed benzoin condensation with mild base does not involve a “dimer” intermediate Tetrahedron Letters. 35: 699-702. DOI: 10.1016/S0040-4039(00)75794-7  0.326
1994 Breslow R. Bifunctional acid—base catalysis by imidazole groups in enzyme mimics Journal of Molecular Catalysis. 91: 161-174. DOI: 10.1016/0304-5102(94)00046-8  0.357
1993 Breslow R. Kinetics and mechanism in RNA cleavage. Proceedings of the National Academy of Sciences of the United States of America. 90: 1208-1211. PMID 7679493 DOI: 10.1073/Pnas.90.4.1208  0.326
1993 Breslow R, Xu R. Recognition and catalysis in nucleic acid chemistry Proceedings of the National Academy of Sciences of the United States of America. 90: 1201-1207. PMID 7679492 DOI: 10.1073/Pnas.90.4.1201  0.337
1993 Breslow R. Bifunctional binding and catalysis Supramolecular Chemistry. 1: 111-118. DOI: 10.1080/10610279308040656  0.346
1993 Breslow R, Wiedenfeld D. Quinoline and acridine templates in selective steroid chlorinations Tetrahedron Letters. 34: 1107-1110. DOI: 10.1016/S0040-4039(00)77502-2  0.305
1992 Dougherty JP, Rizzo CJ, Breslow R. Oligodeoxynucleotides that contain 2',5'' linkages: synthesis and hybridization properties Journal of the American Chemical Society. 114: 6254-6255. DOI: 10.1021/Ja00041A058  0.496
1992 Breslow R, Zhang B. Very fast ester hydrolysis by a cyclodextrin dimer with a catalytic linking group Journal of the American Chemical Society. 114: 5882-5883. DOI: 10.1021/Ja00040A073  0.319
1992 Rizzo CJ, Dougherty JP, Breslow R. 3′-Deoxy-2′-phosphoramidites of adenosine and 5-methyluridine used for the solid phase synthesis of unnatural 3′-deoxy-2′-5″-Oligonucleotides Tetrahedron Letters. 33: 4129-4132. DOI: 10.1016/S0040-4039(00)74670-3  0.499
1992 Breslow R. Bifunctional binding and catalysis in host-guest chemistry Israel Journal of Chemistry. 32: 23-30. DOI: 10.1002/Ijch.199200004  0.316
1991 Breslow R, Huang D. Effects of metal ions, including Mg2+ and lanthanides, on the cleavage of ribonucleotides and RNA model compounds. Proceedings of the National Academy of Sciences of the United States of America. 88: 4080-4083. PMID 1709734 DOI: 10.1073/Pnas.88.10.4080  0.328
1991 Breslow R, Rizzo CJ. Chaotropic salt effects in a hydrophobically accelerated Diels-Alder reaction Journal of the American Chemical Society. 113: 4340-4341. DOI: 10.1021/Ja00011A052  0.518
1991 Breslow R, Crispino GA. Tripyridylcyclopropene Derivatives And Their Conversion To Hexapyridylbenzene Tetrahedron Letters. 32: 601-604. DOI: 10.1016/S0040-4039(00)74837-4  0.33
1990 Breslow R, Huang DL. A negative catalytic term requires a common intermediate in the imidazole buffer-catalyzed cleavage and rearrangement of ribodinucleotides Journal of the American Chemical Society. 112: 9621-9623. DOI: 10.1021/Ja00182A022  0.357
1990 Breslow R, Canary JW, Varney M, Waddell ST, Yang D. Artificial transminases linking pyridoxamine to binding cavities: Controlling the geometry Journal of the American Chemical Society. 112: 5212-5219. DOI: 10.1021/Ja00169A032  0.415
1990 Breslow R, Chung S. Additional flexibility solves the leaving group problem in cyclodextrin acylation Tetrahedron Letters. 31: 631-634. DOI: 10.1016/S0040-4039(00)94586-6  0.305
1989 Breslow R, Huang DL, Anslyn E. On the mechanism of action of ribonucleases: dinucleotide cleavage catalyzed by imidazole and Zn2+. Proceedings of the National Academy of Sciences of the United States of America. 86: 1746-50. PMID 2467290 DOI: 10.1073/Pnas.86.6.1746  0.636
1989 Anslyn E, Breslow R. Proton inventory of a bifunctional ribonuclease model Journal of the American Chemical Society. 111: 8931-8932. DOI: 10.1021/Ja00206A033  0.561
1989 Anslyn E, Breslow R. Geometric evidence on the ribonuclease model mechanism Journal of the American Chemical Society. 111: 5972-5973. DOI: 10.1021/Ja00197A085  0.572
1989 Breslow R, Brown AB, McCullough RD, White PW. Substrate selectivity in epoxidation by metalloporphyrin and metallosalen catalysts carrying binding groups Journal of the American Chemical Society. 111: 4517-4518. DOI: 10.1021/Ja00194A067  0.577
1989 Anslyn E, Breslow R. On the mechanism of catalysis by ribonuclease: cleavage and isomerization of the dinucleotide UpU catalyzed by imidazole buffers Journal of the American Chemical Society. 111: 4473-4482. DOI: 10.1021/Ja00194A050  0.628
1989 Breslow R, Chung S. A novel synthesis of substituted imidazoles, and a reexamination of a purported chymotrypsin model Tetrahedron Letters. 30: 4353-4356. DOI: 10.1016/S0040-4039(00)99358-4  0.342
1989 Batra R, Breslow R. Double functionalization of cholestanol directed by selective bifunctional templates Tetrahedron Letters. 30: 535-538. DOI: 10.1016/S0040-4039(00)95246-8  0.322
1988 Kool ET, Breslow R. Dichotomous salt effects in the hydrophobic acceleration of the benzoin condensation Journal of the American Chemical Society. 110: 1596-1597. DOI: 10.1021/Ja00213A036  0.487
1988 Breslow R, Kool E. A γ-cyclodextrin thiazolium salt holoenzyme mimic for the benzoin condensation Tetrahedron Letters. 29: 1635-1638. DOI: 10.1016/S0040-4039(00)82004-3  0.499
1988 Breslow R, Chmielewski J, Foley D, Johnson B, Kumabe N, Varney M, Mehra R. Optically Active Amino Acid Synthesis by Artificial Transaminase Enzymes Tetrahedron. 44: 5515-5524. DOI: 10.1016/S0040-4020(01)86057-9  0.604
1988 Breslow R, Singh S. Phosphate ester cleavage catalyzed by bifunctional zinc complexes: Comments on the “p-nitrophenyl ester syndrome” Bioorganic Chemistry. 16: 408-417. DOI: 10.1016/0045-2068(88)90026-0  0.325
1987 Chmielewski J, Breslow R. Increasing the racemase activity versus transaminase activity of a pyridoxal enzyme model by the attachment of a rigid base Heterocycles. 25: 533-540. DOI: 10.3987/S-1987-01-0533  0.547
1987 Breslow R, Schepartz A. On the mechanism of peptide cleavage by carboxypeptidase A and related enzymes Chemistry Letters. 16: 1-4. DOI: 10.1246/Cl.1987.1  0.498
1987 Breslow R, Brandl M, Hunger J, Adams AD. Selective steroid chlorinations directed by attached pyridine ester templates Journal of the American Chemical Society. 109: 3799-3801. DOI: 10.1021/Ja00246A058  0.303
1987 Schepartz A, Breslow R. Hydrolysis of an amide in a carboxypeptidase model using cobalt(III) and bifunctional catalysts Journal of the American Chemical Society. 109: 1814-1826. DOI: 10.1021/Ja00240A036  0.539
1987 Breslow R, Mehta M. Correction. Thioxanthones as High Turnover Catalytic Templates in Directed Chlorination Reactions Journal of the American Chemical Society. 109: 1605-1605. DOI: 10.1021/Ja00239A601  0.305
1987 Breslow R, Guo T. The thioxanthone system as a template in free radical relaychlorination of a steroid Tetrahedron Letters. 28: 3187-3188. DOI: 10.1016/S0040-4039(00)95467-4  0.312
1986 Gellman SH, Petter R, Breslow R. Catalytic hydrolysis of a phosphate triester by tetracoordinated zinc complexes. Journal of the American Chemical Society. 108: 2388-94. PMID 22175588 DOI: 10.1021/Ja00269A041  0.525
1986 Breslow R, Mehta MP. Thioxanthones as high-turnover catalytic templates in directed chlorination reactions Journal of the American Chemical Society. 108: 6417-6418. DOI: 10.1021/Ja00280A065  0.308
1986 Breslow R, Czarnik AW, Lauer M, Leppkes R, Winkler J, Zimmerman S. Mimics of transaminase enzymes Journal of the American Chemical Society. 108: 1969-1979. DOI: 10.1021/Ja00268A040  0.717
1986 Maitra U, Breslow R. Conversion of the cholesterol sidechain to a 17-acetyl group by remote chlorination reactions Tetrahedron Letters. 27: 3087-3090. DOI: 10.1016/S0040-4039(00)84722-X  0.556
1986 Berkessel A, Breslow R. On the structures of some adducts of biotin with electrophiles: Does sulfur transannular interaction with the carbonyl group play a role in the chemistry or biochemistry of biotin? Bioorganic Chemistry. 14: 249-261. DOI: 10.1016/0045-2068(86)90036-2  0.674
1986 Breslow R, Czarnik AW, Lauer M, Leppkes R, Winkler J, Zimmerman S. Mimics of Transaminase Enzymes. Cheminform. 17. DOI: 10.1002/Chin.198632320  0.717
1985 Corcoran R, Labelle M, Czarnik AW, Breslow R. An assay to determine the kinetics of RNA cleavage Analytical Biochemistry. 144: 563-568. PMID 2581471 DOI: 10.1016/0003-2697(85)90154-X  0.57
1985 Svastits EW, Dawson JH, Breslow R, Gellman SH. Functionalized nitrogen atom transfer catalyzed by cytochrome P-450 Journal of the American Chemical Society. 107: 6427-6428. DOI: 10.1021/Ja00308A064  0.45
1985 Weiner W, Winkler J, Zimmerman SC, Czarnik AW, Breslow R. Mimics of Tryptophan Synthetase and of Biochemical Dehydroalanine Formation Journal of the American Chemical Society. 107: 4093-4094. DOI: 10.1021/Ja00299A064  0.727
1984 Czarnik AW, Breslow R. Hexadeoxycycloheptaamylose-pyridoxamine, an artifical transaminase with a "deeper" binding pocket Carbohydrate Research. 128: 133-139. PMID 6733723 DOI: 10.1016/0008-6215(84)85091-0  0.574
1984 Breslow R, Herman F, Schwabacher AW. Loss of the normal intramolecular preferential reactivity with a highly nonselective nitrene Journal of the American Chemical Society. 106: 5359-5360. DOI: 10.1021/Ja00330A058  0.645
1984 Zimmerman SC, Breslow R. Asymmetric Synthesis of Amino Acids by Pyridoxamine Enzyme Analogues Utilizing General Base-Acid Catalysis Journal of the American Chemical Society. 106: 1490-1491. DOI: 10.1021/Ja00317A054  0.55
1984 Breslow R, Maitra U, Heyer D. Remote functionalization on the steroid β-face: Attack on an angular methyl group, and into the sidechain Tetrahedron Letters. 25: 1123-1126. DOI: 10.1016/S0040-4039(01)91539-4  0.529
1984 Breslow R, Maitra U. Unusual structural effects on the chemical degradation of steroid sidechains Tetrahedron Letters. 25: 5843-5846. DOI: 10.1016/S0040-4039(01)81700-7  0.558
1984 Breslow R, Deuring LA. Concerning phosphirenium cations Tetrahedron Letters. 25: 1345-1348. DOI: 10.1016/S0040-4039(01)80153-2  0.301
1984 Breslow R, Maitra U. On the origin of product selectivity in aqueous diels-alder reactions Tetrahedron Letters. 25: 1239-1240. DOI: 10.1016/S0040-4039(01)80122-2  0.578
1984 Hilvert D, Breslow R. Functionalized cyclodextrins as holoenzyme mimics of thiamine-dependent enzymes Bioorganic Chemistry. 12: 206-220. DOI: 10.1016/0045-2068(84)90004-X  0.363
1984 Breslow R, Herman F, Schwabacher AW. Loss Of The Normal Intramolecular Preferential Reactivity With A Highly Nonselective Nitrene Cheminform. 15. DOI: 10.1002/Chin.198451141  0.645
1984 Zimmerman SC, Breslow R. Asymmetric Synthesis Of Amino Acids By Pyridoxamine Enzyme Analogs Utilizing General Base-Acid Catalysis Cheminform. 15. DOI: 10.1002/Chin.198424207  0.546
1984 Winkler J, Coutouli-Argyropoulou E, Leppkes R, Breslow R. Artificial Transaminase Carrying A Synthetic Macrocyclic Binding Group Cheminform. 15. DOI: 10.1002/Chin.198409127  0.52
1983 Breslow R, Chin J, Hilvert D, Trainor G. Evidence for the general base mechanism in carboxypeptidase A-catalyzed reactions: partitioning studies on nucleophiles and H2(18)O kinetic isotope effects Proceedings of the National Academy of Sciences of the United States of America. 80: 4585-4589. PMID 6576353 DOI: 10.1073/Pnas.80.14.4585  0.532
1983 Winkler J, Coutouli-Argyropoulou E, Leppkes R, Breslow R. Artificial transaminase carrying a synthetic macrocyclic binding group Journal of the American Chemical Society. 105: 7198-7199. DOI: 10.1021/Ja00362A045  0.52
1983 Breslow R, Gellman SH. Intramolecular nitrene carbon-hydrogen insertions mediated by transition-metal complexes as nitrogen analogs of cytochrome P-450 reactions Journal of the American Chemical Society. 105: 6728-6729. DOI: 10.1021/Ja00360A039  0.49
1983 Zimmerman SC, Czarnik AW, Breslow R. Intramolecular general base-acid catalysis in transaminations catalyzed by pyridoxamine enzyme analogs Journal of the American Chemical Society. 105: 1694-1695. DOI: 10.1021/Ja00344A069  0.691
1983 Breslow R, Czarnik AW. Transaminations by pyridoxamine selectively attached at C-3 in .beta.-cyclodextrin Journal of the American Chemical Society. 105: 1390-1391. DOI: 10.1021/Ja00343A063  0.53
1983 Breslow R, Heyer D. Directed steroid chlorination catalyzed by an ion-paired template Tetrahedron Letters. 24: 5039-5042. DOI: 10.1016/S0040-4039(00)94035-8  0.328
1983 Breslow R, Maitra U, Rideout D. Selective diels-alder reactions in aqueous solutions and suspensions Tetrahedron Letters. 24: 1901-1904. DOI: 10.1016/S0040-4039(00)81801-8  0.571
1983 Breslow R, Chin J, Hilvert D. Studies on zinc enzymes and models Inorganica Chimica Acta. 79: 61. DOI: 10.1016/S0020-1693(00)95087-4  0.359
1983 Breslow R, Czarnik AW. TRANSAMINATIONS BY PYRIDOXAMINE SELECTIVELY ATTACHED AT C‐3 IN β‐CYCLODEXTRIN Cheminform. 14. DOI: 10.1002/Chin.198326328  0.521
1982 Breslow R, Gellman SH. Tosylamidation of cyclohexane by a cytochrome P-450 model Journal of the Chemical Society, Chemical Communications. 1400-1401. DOI: 10.1039/C39820001400  0.462
1982 Breslow R, Cortés DA, Jaun B, Mitchell RD. Studies on the tricyanocyclopropenyl system Tetrahedron Letters. 23: 795-798. DOI: 10.1016/S0040-4039(00)86951-8  0.325
1980 Jaun B, Schwarz J, Breslow R. Determination of the basicities of benzyl, allyl, and tert-butylpropargyl anions by anodic oxidation of organolithium compounds Journal of the American Chemical Society. 102: 5741-5748. DOI: 10.1021/Ja00538A008  0.604
1980 Breslow R. Biomimetic control of chemical selectivity Accounts of Chemical Research. 11: 185-197. DOI: 10.1021/Ar50150A002  0.304
1980 Wilcox C, Breslow R. A convenient synthesis of bis-dialkylaminoacetylenes Tetrahedron Letters. 21: 3241-3242. DOI: 10.1016/S0040-4039(00)78656-4  0.582
1980 WILCOX C, BRESLOW R. ChemInform Abstract: A CONVENIENT SYNTHESIS OF BIS(DIALKYLAMINO)ACETYLENES Chemischer Informationsdienst. 11. DOI: 10.1002/Chin.198047143  0.596
1979 Breslow R. Chemical reactions of steroids which imitate the selectivity of enzymatic transformations Journal of Steroid Biochemistry. 11: 19-26. PMID 491590 DOI: 10.1016/0022-4731(79)90273-5  0.344
1979 Breslow R. Biomimetic Chemistry in Oriented Systems Israel Journal of Chemistry. 18: 187-191. DOI: 10.1002/Ijch.197900024  0.322
1977 Breslow R, Wernick DL. Unified picture of mechanisms of catalysis by carboxypeptidase A. Proceedings of the National Academy of Sciences of the United States of America. 74: 1303-1307. PMID 266172 DOI: 10.1073/Pnas.74.4.1303  0.318
1977 Breslow R, Grant JL. Electrochemical determination of the basicities of benzyl, allyl, and propargyl anions, and a study of solvent and electrolyte effects Journal of the American Chemical Society. 99: 7745-7746. DOI: 10.1021/Ja00465A075  0.307
1977 Siegel B, Pinter A, Breslow R. Synthesis of cycloheptaamylose 2-, 3-, and 6-phosphoric acids, and a comparative study of their effectiveness as general acid or general base catalysts with bound substrates Journal of the American Chemical Society. 99: 2309-2312. DOI: 10.1021/Ja00449A048  0.301
1976 Wasielewski MR, Breslow R. Thermodynamic measurements on unsubstituted cyclopropenyl radical and anion, and derivatives, by second harmonic alternating current voltammetry of cyclopropenyl cations Journal of the American Chemical Society. 98: 4222-4229. DOI: 10.1021/Ja00430A037  0.438
1976 Breslow R, Kohn H, Siegel B. Methylated cyclodextrin and a cyclodextrin polymer as catalysts in selective anisole chlorination Tetrahedron Letters. 17: 1645-1646. DOI: 10.1016/S0040-4039(00)92912-5  0.504
1976 Wong HNC, Sondheimer F, Goodin R, Breslow R. The synthesis of 2,3,6,7-dibenzobicyclo[6.2.0]deca-2,6,8-trien-4-yne-9,10-dione and 2,3,6,7-dibenzobicyclo[6.2.0]deca-2,4,6,8-tetraene-9,10-dione. The electrochemistry of cyclobutenediones ("cyclobutadienoquinones"). Tetrahedron Letters. 17: 2715-2718. DOI: 10.1016/S0040-4039(00)77805-1  0.504
1976 WASIELEWSKI MR, BRESLOW R. ChemInform Abstract: THERMODYNAMIC MEASUREMENTS ON UNSUBSTITUTED CYCLOPROPENYL RADICAL AND ANION, AND DERIVATIVES, BY SECOND HARMONIC ALTERNATING CURRENT VOLTAMMETRY OF CYCLOPROPENYL CATIONS Chemischer Informationsdienst. 7: no-no. DOI: 10.1002/Chin.197640074  0.445
1973 Breslow R, Murayama DR, Murahashi S, Grubbs R. Quantitative assessment of the antiaromatic city of cyclobutadiene by electrochemical studies on quinone derivatives Journal of the American Chemical Society. 95: 6688-6699. DOI: 10.1021/Ja00801A027  0.517
1973 Breslow R, Chu W. Thermodynamic determination of pKa's of weak hydrocarbon acids using electrochemical reduction data. Triarylmethyl anions, cycloheptatrienyl anion, and triphenyl- and trialkylcyclopropenyl anions Journal of the American Chemical Society. 95: 411-418. DOI: 10.1021/Ja00783A017  0.301
1972 Breslow R, Oda M, Pecoraro J. The chemistry of cyclopropenone. Reactions at the carbonyl group, and 1,2 cleavages Tetrahedron Letters. 13: 4415-4417. DOI: 10.1016/S0040-4039(01)94329-1  0.306
1971 Breslow R. Quantitative studies on aromaticity and antiaromaticity Pure and Applied Chemistry. 28: 111-130. DOI: 10.1351/Pac197128020111  0.317
1971 Breslow R, Campbell P. Selective aromatic substitution by hydrophobic binding of a substrate to a simple cyclodextrin catalyst Bioorganic Chemistry. 1: 140-156. DOI: 10.1016/0045-2068(71)90012-5  0.341
1970 Breslow R, Overman LE. An "artificial enzyme" combining a metal catalytic group and a hydrophobic binding cavity. Journal of the American Chemical Society. 92: 1075-7. PMID 5451011 DOI: 10.1021/Ja00707A062  0.47
1970 Breslow R, Grubbs R, Murahashi S. Electrochemical evidence for the antiaromaticity of cyclobutadiene Journal of the American Chemical Society. 92: 4139-4140. DOI: 10.1021/Ja00716A069  0.503
1970 Breslow R, Ryan G, Groves JT. Chlorocyclopropenes, chlorocyclopropenyl cations, and cyclopropenone Journal of the American Chemical Society. 92: 988-993. DOI: 10.1021/Ja00707A041  0.47
1970 Breslow R, Groves JT. Cyclopropenyl cation. Synthesis and characterization Journal of the American Chemical Society. 92: 984-987. DOI: 10.1021/Ja00707A040  0.5
1970 BRESLOW R, GRUBBS R, MURAHASHI S. ChemInform Abstract: ELEKTROCHEMISCHER BEWEIS FUER DIE ANTIAROMATIZITAET VON CYCLOBUTADIEN Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197040100  0.505
1970 BRESLOW R, RYAN G, GROVES JT. ChemInform Abstract: CHLORCYCLOPROPENE, CHLORPROPENYL-KATIONEN UND CYCLOPROPENON Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197020175  0.448
1970 Breslow R, Overman LE. Ein ′Kuenstliches Enzym′ Mit Metallkatalytischer Gruppe Und Hohlraum Mit Hydrophobem Bindungseffekt Cheminform. 1. DOI: 10.1002/Chin.197020089  0.392
1970 BRESLOW R, GROVES JT. ChemInform Abstract: CYCLOPROPENYL-KATION, SYNTH. UND CHARAKTERISIERUNG Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197019050  0.448
1969 Breslow R, Winnik MA. Remote oxidation of unactivated methylene groups Journal of the American Chemical Society. 91: 3083-3084. DOI: 10.1021/Ja01039A043  0.421
1969 Breslow R, Washburn W, Bergman RG. Detection of cyclobutadienocyclopentadienyl anion Journal of the American Chemical Society. 91: 196-196. DOI: 10.1021/Ja01029A039  0.386
1968 Breslow R, Olin SS, Groves JT. Oxidative cyclization of farnesyl acetate by a free radical path Tetrahedron Letters. 9: 1837-1840. DOI: 10.1016/S0040-4039(00)76376-3  0.467
1967 Grubbs R, Breslow R, Herber R, Lippard SJ. Iron tricarbonyl cyclooctatetraene complexes Journal of the American Chemical Society. 89: 6864-6870. DOI: 10.1021/Ja01002A010  0.487
1967 Breslow R, Brown J, Gajewski JJ. Antiaromaticity of cyclopropenyl anions Journal of the American Chemical Society. 89: 4383-4390. DOI: 10.1021/Ja00993A023  0.438
1966 Breslow R, Groves J, Olin S. A novel oxidative terpene cyclization Tetrahedron Letters. 7: 4717-4719. DOI: 10.1016/S0040-4039(00)72930-3  0.456
1965 Breslow R, Chipman D. Mixed metal complexes as enzyme models. I. Intracomplex nucleophilic catalysis by an oxime anion. Journal of the American Chemical Society. 87: 4195-4196. PMID 5845280 DOI: 10.1021/Ja01096A039  0.618
1963 Breslow R, Dowd P. The Dimerization Of Triphenylcyclopropene Journal of the American Chemical Society. 85: 2729-2735. DOI: 10.1021/Ja00901A012  0.308
1963 Breslow R, Posner J, Krebs A. Synthesis of Cyclopropenones by a Modified Favorskii Reaction Journal of the American Chemical Society. 85: 234-234. DOI: 10.1021/Ja00885A029  0.301
1962 Breslow R, Hover H, Chang HW. The Synthesis and Stability of Some Cyclopropenyl Cations with Alkyl Substituents Journal of the American Chemical Society. 84: 3168-3174. DOI: 10.1021/Ja00875A027  0.309
1960 Breslow R, Battiste M. An Unusual Rearrangement in the Cyclopropene Series1 Journal of the American Chemical Society. 82: 3626-3628. DOI: 10.1021/Ja01499A038  0.55
1960 Breslow R, Boikess R, Battiste M. Some cyclopropene rearrangements Tetrahedron Letters. 1: 42-44. DOI: 10.1016/S0040-4039(01)99401-8  0.551
1959 Breslow R, Winter R, Battiste M. Notes- On Darling's Cyclopropene Derivative and Its Rearrangement The Journal of Organic Chemistry. 24: 415-416. DOI: 10.1021/Jo01085A603  0.528
1959 Breslow R, Gal P. The Synthesis Of Bis-Triphenylcyclopropenyl, An Undissociated Dimer Of The Triphenylcyclopropenyl Radical, And Its Isomerization To Hexaphenylbenzene Journal of the American Chemical Society. 81: 4747-4748. DOI: 10.1021/Ja01526A077  0.31
1953 Stork G, Breslow R. THE REARRANGEMENT OF BROMONORCEDRENEDICARBOXYLIC ACID Journal of the American Chemical Society. 75: 3292-3292. DOI: 10.1021/Ja01109A525  0.48
1953 Stork G, Breslow R. THE STRUCTURE OF CEDRENE Journal of the American Chemical Society. 75: 3291-3291. DOI: 10.1021/Ja01109A524  0.438
Low-probability matches (unlikely to be authored by this person)
2004 Breslow R. Determining the geometries of transition States by use of antihydrophobic additives in water. Accounts of Chemical Research. 37: 471-478. PMID 15260509 DOI: 10.1021/Ar040001M  0.299
1982 Breslow R, Jaun B, Kluttz RQ, Xia C. Ground state Pi-electron triplet molecules of potential use in the synthesis of organic ferromagnets Tetrahedron. 38: 863-867. DOI: 10.1016/0040-4020(82)80167-1  0.299
1990 Light J, Breslow R. The hydrolysis of a Co(III) chelated amide catalyzed by an internal phosphonic acid group Bioorganic Chemistry. 18: 63-77. DOI: 10.1016/0045-2068(90)90016-X  0.297
1961 Breslow R, Lockhart J, Chang HW. The Diphenylcyclopropenyl Cation. Synthesis and Stability1 Journal of the American Chemical Society. 83: 2375-2379. DOI: 10.1021/Ja01471A032  0.296
1994 Breslow R, Zhang B. Cleavage of Phosphate Esters by a Cyclodextrin Dimer Catalyst That Binds the Substrates Together with La3+ and Hydrogen Peroxide Journal of the American Chemical Society. 116: 7893-7894. DOI: 10.1021/Ja00096A055  0.294
1998 Yuan D, Dong SD, Breslow R. Cyclodextrin-based class I aldolase enzyme mimics to catalyze crossed aldol condensations Tetrahedron Letters. 39: 7673-7676. DOI: 10.1016/S0040-4039(98)01717-1  0.294
1971 Breslow R, Scholl PC. Selective oxidation of unactivated methylene groups by reagent-substrate orientation in mixed complexes Journal of the American Chemical Society. 93: 2331-2333. DOI: 10.1021/Ja00738A049  0.293
2005 Liu L, Breslow R. Polymeric and dendrimeric pyridoxal enzyme mimics. Bioorganic & Medicinal Chemistry. 12: 3277-87. PMID 15158796 DOI: 10.1016/J.Bmc.2004.03.062  0.293
1977 Breslow R, Khanna PL. Further evidence for the formation of butalene in the reaction of 1-chloro-[2.2.0]bicyclohexa-2,5-dienes[dewar chlorobenzenes] with a strong base Tetrahedron Letters. 18: 3429-3432. DOI: 10.1016/S0040-4039(01)83258-5  0.292
1992 Breslow R, Halfon S. Quantitative effects of antihydrophobic agents on binding constants and solubilities in water Proceedings of the National Academy of Sciences of the United States of America. 89: 6916-6918. PMID 1495980 DOI: 10.1073/Pnas.89.15.6916  0.292
1998 Dong SD, Breslow R. Bifunctional cyclodextrin metalloenzyme mimics Tetrahedron Letters. 39: 9343-9346. DOI: 10.1016/S0040-4039(98)02160-1  0.292
1961 Breslow R, Chang HW. The Rearrangement Of The Pentaphenylcyclopentadienyl Cation1 Journal of the American Chemical Society. 83: 3727-3728. DOI: 10.1021/Ja01478A046  0.291
1983 Breslow R, Trainor G, Ueno A. Optimization of metallocene substrates for .beta.-cyclodextrin reactions Journal of the American Chemical Society. 105: 2739-2744. DOI: 10.1021/Ja00347A037  0.29
1985 Breslow R, Maslak P, Thomaides JS. Synthesis Of The Hexaaminobenzene Derivative Hexaazaoctadecahydrocoronene (Hoc) And Related Cations Cheminform. 16. DOI: 10.1002/Chin.198506250  0.289
1984 Breslow R, Maslak P, Thomaides JS. Synthesis of the hexaaminobenzene derivative hexaazaoctadecahydrocoronene (HOC) and related cations Journal of the American Chemical Society. 106: 6453-6454. DOI: 10.1021/Ja00333A076  0.289
1976 Breslow R, McClure DE. Letter: Cooperative catalysis of the cleavage of an amide by carboxylate and phenolic groups in a carboxypeptidase A model. Journal of the American Chemical Society. 98: 258-259. PMID 1244371 DOI: 10.1021/Ja00417A054  0.289
2013 Widawsky JR, Chen W, Vázquez H, Kim T, Breslow R, Hybertsen MS, Venkataraman L. Length-dependent thermopower of highly conducting Au-C bonded single molecule junctions. Nano Letters. 13: 2889-94. PMID 23682792 DOI: 10.1021/Nl4012276  0.289
1997 Breslow R, Zhang aX, Huang Y. Selective Catalytic Hydroxylation of a Steroid by an Artificial Cytochrome P-450 Enzyme Journal of the American Chemical Society. 119: 4535-4536. DOI: 10.1021/Ja9704951  0.289
1977 Breslow R, Corcoran RJ, Snider BB, Doll RJ, Khanna PL, Kaleya R. Selective halogenation of steroids using attached aryl iodide templates. Journal of the American Chemical Society. 99: 905-115. PMID 833385 DOI: 10.1021/Ja00445A038  0.289
1970 Breslow R, Bozimo H, Wolf P. Bicyclo[1.1.0]butyl-2-carbinyl cations☆ Tetrahedron Letters. 11: 2395-2397. DOI: 10.1016/S0040-4039(01)98238-3  0.289
1970 Breslow R, Bozimo H, Wolf P. Bicyclo(1,1,0)Butyl-2-Carbinyl-Kationen Cheminform. 1. DOI: 10.1002/Chin.197038242  0.289
1991 Breslow R, Canary JW. Rapid Nucleophilic Substitutions on Cyclopentadienyl Iodide and Bromide Journal of the American Chemical Society. 113: 3950-3952. DOI: 10.1021/Ja00010A041  0.287
1973 Ode M, Breslow R. A facile 1,5 alkyl shift converting bicyclo[3.2.0]hepta-1,3-diene into spiro[2,4]hepta-4,6-diene Tetrahedron Letters. 14: 2537-2540. DOI: 10.1016/S0040-4039(01)96199-4  0.286
1996 Breslow R, Connors R, Zhu Z. Mechanistic studies using antihydrophobic agents Pure and Applied Chemistry. 68: 1527-1533. DOI: 10.1351/Pac199668081527  0.285
1965 Breslow R, Gal P, Chang HW, Altman LJ. Isomerization of Biscyclopropenyls to Benzenes1,2 Journal of the American Chemical Society. 87: 5139-5144. DOI: 10.1021/Ja00950A028  0.285
1999 Breslow R, Werner C. A stable cyclopentenyl trication derivative Tetrahedron Letters. 40: 2447-2448. DOI: 10.1016/S0040-4039(99)00237-3  0.284
1986 Breslow R, Mehta MP. Catalytic directed steroid chlorination with billion-fold turnovers. Journal of the American Chemical Society. 108: 2485-2486. PMID 22175626 DOI: 10.1021/Ja00269A079  0.284
1983 Breslow R, Hunt JT, Smiley R, Tarnowski T. Synthesis of some polyimidazole ligands related to zinc enzymes Journal of the American Chemical Society. 105: 5337-5342. DOI: 10.1021/Ja00354A025  0.284
1995 Breslow R, Halfon S, Zhang B. Molecular recognition by cyclodextrin dimers Tetrahedron. 51: 377-388. DOI: 10.1016/0040-4020(94)00903-8  0.284
1959 Breslow R, McNelis E. Studies on Model Systems for Thiamine Action. Synthesis of Reactive Intermediates, and Evidence on the Function of the Pyrimidine Ring1 Journal of the American Chemical Society. 81: 3080-3082. DOI: 10.1021/Ja01521A042  0.284
1982 Breslow R, Heyer D. Catalytic multiple template-directed steroid chlorinations Journal of the American Chemical Society. 104: 2045-2046. DOI: 10.1021/Ja00371A053  0.283
2009 Breslow R, Cheng Z. On the origin of terrestrial homochirality for nucleosides and amino acids Proceedings of the National Academy of Sciences of the United States of America. 106: 9144-9146. PMID 19478058 DOI: 10.1073/Pnas.0904350106  0.283
1969 Breslow R, Campbell P. Selective aromatic substitution within a cyclodextrin mixed complex Journal of the American Chemical Society. 91: 3085-3085. DOI: 10.1021/Ja01039A044  0.282
1993 Jin R, Chapman WH, Srinivasan AR, Olson WK, Breslow R, Breslauer KJ. Comparative spectroscopic, calorimetric, and computational studies of nucleic acid complexes with 2',5"-versus 3',5"-phosphodiester linkages. Proceedings of the National Academy of Sciences of the United States of America. 90: 10568-72. PMID 8248146 DOI: 10.1073/Pnas.90.22.10568  0.282
1961 Breslow R, Bahary W, Reinmuth W. Concerning The Stability Of Some Substituted Cyclopropenyl Radicals; Evidence From Polarography Of The Corresponding Cations Journal of the American Chemical Society. 83: 1763-1764. DOI: 10.1021/Ja01468A051  0.282
2003 Xu R, Breslow R. 1,2,3‐Triphenylcyclopropenium Bromide Organic Syntheses. 72-72. DOI: 10.1002/0471264180.Os074.06  0.282
1995 Breslow R, Duggan PJ, Wiedenfeld D, Waddell ST. The binding properties of cyclophane dimers Tetrahedron Letters. 36: 2707-2710. DOI: 10.1016/0040-4039(95)00373-K  0.28
1978 Breslow R, Rothbard J, Herman F, Rodriguez ML. Remote functionalization reactions as conformational probes for flexible alkyl chains Journal of the American Chemical Society. 100: 1213-1218. DOI: 10.1021/Ja00472A030  0.28
1970 Breslow R, Washburn W. Antiaromatic Destabilization of Cyclobutadienocyclopentadienyl Anion Journal of the American Chemical Society. 92: 427-428. DOI: 10.1021/Ja00705A637  0.279
1974 Breslow R, Sugimoto T. Localized transition states for reactions of delocalized molecules. Ionic and radical reductions of chlorocyclopropenes with tri-n-butyltin hydride. Tetrahedron Letters. 15: 2437-2438. DOI: 10.1016/S0040-4039(01)92279-8  0.279
1970 Breslow R, Pagni R, Washburn WN. Studies on a 7-norbornenyl anion, a “bishomoantiaromatic” system Tetrahedron Letters. 11: 547-549. DOI: 10.1016/S0040-4039(01)97765-2  0.279
1991 Wiedenfeld D, Breslow R. Directed formation of carbon-bromine and carbon-sulfur bonds by tandem radical chain reactions Journal of the American Chemical Society. 113: 8977-8978. DOI: 10.1021/Ja00023A074  0.279
1987 Breslow R, Mehta M. Correction. Catalytic Directed Steroid Chlorination with Billiofold Turnovers Journal of the American Chemical Society. 109: 1605-1605. DOI: 10.1021/Ja00239A600  0.279
1994 Breslow R. The chelate effect in binding, catalysis, and chemotherapy Recueil Des Travaux Chimiques Des Pays-Bas. 113: 493-498. DOI: 10.1002/Recl.19941131102  0.279
1964 Breslow R. Concerning carbanion intermediates in elemination reactions Tetrahedron Letters. 5: 399-403. DOI: 10.1016/0040-4039(64)83004-5  0.278
1973 Breslow R, Hoffman JM, Perchonock C. Relative reactivities of the 5-halocyclopentadienes in diels-alder and 1,5 shift reactions Tetrahedron Letters. 14: 3723-3726. DOI: 10.1016/S0040-4039(01)87017-9  0.278
1991 Breslow R. How do imidazole groups catalyze the cleavage of RNA in enzyme models and in enzymes? Evidence from "negative catalysis" Accounts of Chemical Research. 24: 317-324. DOI: 10.1021/Ar00011A001  0.278
1975 Siegel B, Breslow R. Lyophobic binding of substrates by cyclodextrins in nonaqueous solvents Journal of the American Chemical Society. 97: 6869-6870. DOI: 10.1021/Ja00856A048  0.278
1977 Breslow R, Maresca LM. The template-directed remote epoxidation of olefins Tetrahedron Letters. 18: 623-626. DOI: 10.1016/S0040-4039(01)92709-1  0.277
1980 Rideout DC, Breslow R. Hydrophobic acceleration of Diels-Alder reactions Journal of the American Chemical Society. 102: 7816-7817. DOI: 10.1021/Ja00546A048  0.277
1975 Breslow R, McClure DE, Brown RS, Eisenach J. Very fast zinc-catalyzed hydrolysis of an anhydride. Model for the rate and mechanism of carboxypeptidase A catalysis Journal of the American Chemical Society. 97: 194-195. PMID 1133332 DOI: 10.1021/Ja00834A037  0.277
1992 Crispino GA, Breslow R. Synthesis of tripyridiniumylpropenyl anions from tripyridiniumylcyclopropanes and -cyclopropenes Journal of Organic Chemistry. 57: 1849-1855. DOI: 10.1021/Jo00032A044  0.276
1970 Breslow R, Pagni R, Washburn WN. 7-Norbornenyl-Anion, Ein ′Bis-Homoantiaromatisches′ Syst. Cheminform. 1. DOI: 10.1002/Chin.197020188  0.276
1999 Sprecher M, Breslow R, Philosof-Oppenheimer R, Chavet E. Steroid phosphate esters Tetrahedron. 55: 5465-5482. DOI: 10.1016/S0040-4020(99)00193-3  0.275
1978 Tang CC, Davalian D, Huang P, Breslow R. Models for metal binding sites in zinc enzymes. Syntheses of tris[4(5)-imidazolyl]carbinol (4-TIC), tris(2-imidazolyl)carbinol (2-TIC), and related ligands, and studies on metal complex binding constants and spectra Journal of the American Chemical Society. 100: 3918-3922. DOI: 10.1021/Ja00480A043  0.275
1991 Breslow R, Jursic B, Yan ZF, Friedman E, Leng L, Ngo L, Rifkind RA, Marks PA. Potent cytodifferentiating agents related to hexamethylenebisacetamide. Proceedings of the National Academy of Sciences of the United States of America. 88: 5542-5546. PMID 2062836 DOI: 10.1073/Pnas.88.13.5542  0.274
1963 Breslow R, Mohacsi E. Studies on d-Orbital Conjugation. III. Non-aromaticity of a Derivative of the 1,3-Dithiepinyl Anion, a Ten π-Electron Conjugated System Journal of the American Chemical Society. 85: 431-434. DOI: 10.1021/Ja00887A013  0.274
1989 Breslow R, Greenspoon N, Guo T, Zarzycki R. Very strong binding of appropriate substrates by cyclodextrin dimers Journal of the American Chemical Society. 111: 8296-8297. DOI: 10.1021/Ja00203A050  0.274
1974 Breslow R, Corcoran R, Dale JA, Liu S, Kalicky P. Selective steroid halogenations directed by proximity and substituent effects Journal of the American Chemical Society. 96: 1973-1974. DOI: 10.1021/Ja00813A073  0.273
1959 Breslow R. On the mechanism of the formose reaction Tetrahedron Letters. 1: 22-26. DOI: 10.1016/S0040-4039(01)99487-0  0.273
1976 Breslow R, Goodin R. An apparent direct-indirect combined mechanism in template-directed electrochemical steroid chlorination Tetrahedron Letters. 17: 2675-2676. DOI: 10.1016/S0040-4039(00)77792-6  0.272
2011 Breslow R. Formation of L Amino Acids and D Sugars, and Amplification of their Enantioexcesses in Aqueous Solutions, Under Simulated Prebiotic Conditions Israel Journal of Chemistry. 51: 990-996. DOI: 10.1002/Ijch.201100019  0.271
1971 Breslow R, McAllister C. Intramolecular bifunctional catalysis of ester hydrolysis by metal ion and carboxylate in a carboxypeptidase model. Journal of the American Chemical Society. 93: 7096-7097. PMID 5133100 DOI: 10.1021/Ja00754A073  0.271
1997 Yang Z, Breslow R. Very Strong Binding of Lithocholic Acid to β-Cyclodextrin Tetrahedron Letters. 38: 6171-6172. DOI: 10.1016/S0040-4039(97)01427-5  0.271
1982 Chin J, Breslow R. Some reactions of phenolic maleamic acids relevant to carboxypeptidase catalysis Tetrahedron Letters. 23: 4221-4224. DOI: 10.1016/S0040-4039(00)88709-2  0.271
2011 Breslow R. A likely possible origin of homochirality in amino acids and sugars on prebiotic earth Tetrahedron Letters. 52: 2028-2032. DOI: 10.1016/J.Tetlet.2010.08.094  0.271
2011 Breslow R. The origin of homochirality in amino acids and sugars on prebiotic earth Tetrahedron Letters. 52: 4228-4232. DOI: 10.1016/J.Tetlet.2011.06.002  0.27
1968 Breslow R. Small Antiaromatic Rings Angewandte Chemie. 7: 565-570. DOI: 10.1002/Anie.196805651  0.269
1998 and MUM, Breslow R. Antihydrophobic Evidence For The Single Electron Transfer Mechanism Of Nucleophilic Substitution Journal of the American Chemical Society. 120: 9098-9099. DOI: 10.1021/Ja982137J  0.269
1972 Breslow R, Dale JA, Kalicky P, Liu SY, Washburn WN. Introduction of a 9(11) double bond into steroids by selective free-radical halogenation. Journal of the American Chemical Society. 94: 3276-3278. PMID 5032504 DOI: 10.1021/Ja00764A085  0.268
1974 Breslow R. The application of electrochemistry to some physical organic problems Pure and Applied Chemistry. 40: 493-509. DOI: 10.1351/Pac197440040493  0.268
2010 Breslow R, Cheng Z. L-amino acids catalyze the formation of an excess of D-glyceraldehyde, and thus of other D sugars, under credible prebiotic conditions Proceedings of the National Academy of Sciences of the United States of America. 107: 5723-5725. PMID 20231487 DOI: 10.1073/Pnas.1001639107  0.267
1968 Breslow R, Katz I. Relative reactivities of p-nitrophenyl phosphate and phosphorothioate toward alkaline phosphatase and in aqueous hydrolysis Journal of the American Chemical Society. 90: 7376-7377. DOI: 10.1021/Ja01028A054  0.267
1965 Breslow R, Vitale W, Wendel K. A cycloőctatetraeno-cyclopentadienone Tetrahedron Letters. 6: 365-368. DOI: 10.1016/S0040-4039(00)89961-X  0.266
1988 Thomaides J, Maslak P, Breslow R. Electron-rich hexasubstituted benzene derivatives and their oxidized cation radicals, dications with potential triplet ground states, and polycations Journal of the American Chemical Society. 110: 3970-3979. DOI: 10.1021/Ja00220A040  0.266
1971 Breslow R, Schmir M. Strongly catalyzed ligand-ligand reaction within a mixed metal complex Journal of the American Chemical Society. 93: 4960-4961. DOI: 10.1021/Ja00748A078  0.266
2003 Zhou W, Liu L, Breslow R. Transamination by Polymeric Enzyme Mimics Helvetica Chimica Acta. 86: 3560-3567. DOI: 10.1002/Hlca.200390300  0.266
1971 Breslow R, Kalicky P. Remote oxidation of steroids by reagents attached to ring D. Introduction of a 9(11) double bond Journal of the American Chemical Society. 93: 3540-3541. DOI: 10.1021/Ja00743A047  0.266
1968 Breslow R, Douek M. Antiaromatic effects in cyanocyclopropenyl anions Journal of the American Chemical Society. 90: 2698-2699. DOI: 10.1021/Ja01012A046  0.265
1957 Breslow R. SYNTHESIS OF THE s-TRIPHENYLCYCLOPROPENYL CATION Journal of the American Chemical Society. 79: 5318-5318. DOI: 10.1021/Ja01576A067  0.264
1993 Breslow R, Xu R. Quantitative evidence for the mechanism of RNA cleavage by enzyme mimics. Cleavage and isomerization of UpU by morpholine buffers Journal of the American Chemical Society. 115: 10705-10713. DOI: 10.1021/Ja00076A031  0.264
1974 Breslow R, Ehrlich K, Higgs T, Pecoraro J, Zanker F. Some reactions of 1,2,3-tribenzoylcyclopropene Tetrahedron Letters. 15: 1123-1126. DOI: 10.1016/S0040-4039(01)82423-0  0.263
1981 Trainor GL, Breslow R. High acylation rates and enantioselectivity with cyclodextrin complexes of rigid substrates Journal of the American Chemical Society. 103: 154-158. DOI: 10.1021/Ja00391A028  0.263
1987 LePage TJ, Breslow R. Charge-transfer complexes as potential organic ferromagnets Journal of the American Chemical Society. 109: 6412-6421. DOI: 10.1021/Ja00255A030  0.262
1973 Breslow R, Mazur S. Electrochemical determination of pKR+ for some antiaromatic cyclopentadienyl cations Journal of the American Chemical Society. 95: 584-585. DOI: 10.1021/Ja00783A046  0.262
1993 Zhang B, Breslow R. Enthalpic domination of the chelate effect in cyclodextrin dimers Journal of the American Chemical Society. 115: 9353-9354. DOI: 10.1021/Ja00073A087  0.262
1968 Breslow R, Garratt S, Kaplan L, LaFollette D. Carbonium ions with multiple neighboring groups. I. Synthesis Journal of the American Chemical Society. 90: 4051-4055. DOI: 10.1021/Ja01017A023  0.261
1959 Breslow R, Haynie R, Mirra J. The Synthesis Of Diphenylcyclopropenone Journal of the American Chemical Society. 81: 247-248. DOI: 10.1021/Ja01510A060  0.261
1976 Wife RL, Prezant D, Breslow R. Concerning The Regiospecificity And Stereospecificity Of Steroid Functionalization By Photolysis Of Attached Benzophenone Esters Tetrahedron Letters. 17: 517-520. DOI: 10.1016/S0040-4039(00)77899-3  0.26
1976 Johnson RW, Widlanski T, Breslow R. Evidence for an electron transfer mechanism in the coupling of cyclopropenyl cations with cyclopropenyl anions Tetrahedron Letters. 17: 4685-4686. DOI: 10.1016/S0040-4039(00)92995-2  0.26
1991 Breslow R. Hydrophobic effects on simple organic reactions in water Accounts of Chemical Research. 24: 159-164. DOI: 10.1021/Ar00006A001  0.26
1976 Breslow R, Wife RL, Prezant D. Radical relay chlorination of cholestanol directed by an attached diphenylsulfide template Tetrahedron Letters. 17: 1925-1926. DOI: 10.1016/S0040-4039(00)78080-4  0.26
1990 Breslow R, Guo T. Surface Tension Measurements Show That Chaotropic Salting-In Denaturants Are Not Just Water-Structure Breakers Proceedings of the National Academy of Sciences of the United States of America. 87: 167-169. PMID 2153285 DOI: 10.1073/Pnas.87.1.167  0.259
1995 Breslow R, Connors RV. Quantitative Antihydrophobic Effects as Probes for Transition State Structures. 1. Benzoin Condensation and Displacement Reactions Journal of the American Chemical Society. 117: 6601-6602. DOI: 10.1021/Ja00129A028  0.258
1995 Breslow R, Zhu Z. Quantitative Antihydrophobic Effects as Probes for Transition State Structures. 2. Diels-Alder Reactions Journal of the American Chemical Society. 117: 9923-9924. DOI: 10.1021/Ja00144A024  0.258
1972 Oda M, Breslow R, Pecoraro J. The chemistry of cyclopropenone. Reactions at the carbon-carbon double bond. Tetrahedron Letters. 13: 4419-4422. DOI: 10.1016/S0040-4039(01)94330-8  0.258
1978 Breslow R, Maresca LM. Template-directed epoxidation of farnesol and of geranylgeraniol as conformational probes Tetrahedron Letters. 19: 887-890. DOI: 10.1016/S0040-4039(01)91427-3  0.257
1995 Breslow R. Biomimetic Chemistry and Artificial Enzymes: Catalysis by Design Accounts of Chemical Research. 28: 146-153. DOI: 10.1021/Ar00051A008  0.257
1985 LePage T, Nakasuji K, Breslow R. Novel Conjugated Molecules from Oxidation of a Cyclopentadienone Iron Tricarbonyl Complex. Tetrahedron Letters. 26: 5919-5922. DOI: 10.1016/S0040-4039(00)98261-3  0.256
1990 Light J, Breslow R. A water soluble tin hydride reagent Tetrahedron Letters. 31: 2957-2958. DOI: 10.1016/S0040-4039(00)88997-2  0.256
2012 Breslow R. Evidence for the Likely Origin of Homochirality in Amino Acids, Sugars, and Nucleosides on Prebiotic Earth Journal of the American Chemical Society. 134: 6887-6892. PMID 22444622 DOI: 10.1021/Ja3012897  0.255
1986 O'krongly D, Denmeade SR, Chiang MY, Breslow R. Efficient Triple Coupling Reaction to Produce a Self-Adjusting Molecular Cage. Cheminform. 17. DOI: 10.1002/Chin.198601049  0.255
1985 O'Krongly D, Denmeade SR, Chiang MY, Breslow R. Efficient triple coupling reaction to produce a self-adjusting molecular cage Journal of the American Chemical Society. 107: 5544-5545. DOI: 10.1021/Ja00305A047  0.255
1994 Sheppard TL, Rosenblatt AT, Breslow R. Preparation of 2'-O-(β-cyanoethyl phosphoramidites) of 3'-deoxycytidine and 3'-deoxyguanosine and their use for solid-phase synthesis of oligodeoxynucleotides containing 2',5'-phosphodiester linkages Journal of Organic Chemistry. 59: 7243-7248. DOI: 10.1021/Jo00103A014  0.255
1985 Tabushi I, Kuroda Y, Yamada M, Higashimura H, Breslow R. A-(modified B6)-B-[.omega.-amino(ethylamino)]-.beta.-cyclodextrin as an artificial B6 enzyme for chiral aminotransfer reaction Journal of the American Chemical Society. 107: 5545-5546. DOI: 10.1021/Ja00305A048  0.254
2003 Wilson D, Perlson L, Breslow R. Helical templating of oligopeptides by cyclodextrin dimers Bioorganic and Medicinal Chemistry. 11: 2649-2653. PMID 12757731 DOI: 10.1016/S0968-0896(03)00153-6  0.254
1974 Breslow R, Feiring A, Herman F. Intermolecular insertion reactions of phosphoryl nitrenes Journal of the American Chemical Society. 96: 5937-5939. DOI: 10.1021/Ja00825A042  0.254
1974 Breslow R, Feiring A, Herman F. Intermolecular insertion reactions of phosphoryl nitrenes Cheminform. 5. DOI: 10.1002/Chin.197446347  0.254
1985 Tabushi I, Kuroda Y, Yamada M, Higashimura H, Breslow R. A-(MODIFIED B6)-B-(Ω-AMINO(ETHYLAMINO))-β-CYCLODEXTRIN AS AN ARTIFICIAL B6 ENZYME FOR CHIRAL AMINOTRANSFER REACTION Cheminform. 16. DOI: 10.1002/Chin.198552292  0.254
1999 Finnin MS, Donigian JR, Cohen A, Richon VM, Rifkind RA, Marks PA, Breslow R, Pavletich NP. Structures of a histone deacetylase homologue bound to the TSA and SAHA inhibitors Nature. 401: 188-193. PMID 10490031 DOI: 10.1038/43710  0.254
1975 Breslow R. The second centennial congress plenary lecture: Remote oxidation and related reactions Journal of Chemical Education. 52: 10. DOI: 10.1021/Ed052P10.1  0.254
1972 Breslow R. Centenary Lecture. Biomimetic chemistry Chemical Society Reviews. 1: 553-580. DOI: 10.1039/Cs9720100553  0.253
1990 White P, Breslow R. Molecular mechanics calculations on template-directed steroid chlorinations : are transition states rigidified by the geometric trajectory requirements for effective energy transfer ? Journal of the American Chemical Society. 112: 6842-6847. DOI: 10.1021/Ja00175A016  0.253
1961 Breslow R, Chang HW. Triarylcyclopropenium Ions. Synthesis and Stability in the Phenyl p-Anisyl Series1 Journal of the American Chemical Society. 83: 2367-2375. DOI: 10.1021/Ja01471A031  0.253
1997 Breslow R. What will physical organic chemistry achieve in the 21st century Pure and Applied Chemistry. 69: 223-226. DOI: 10.1351/Pac199769020223  0.252
1973 Lechkten P, Breslow R, Schmidt AH, Turro NJ. Thermal rearrangement of Dewar benzenes to benzene triplet states. Examples of spin forbidden nonadiabatic pericyclic reactions Journal of the American Chemical Society. 95: 3025-3027. DOI: 10.1021/Ja00790A054  0.251
1982 Ueno A, Breslow R. Selective sulfonation of a secondary hydroxyl group of β-cyclodextrin Tetrahedron Letters. 23: 3451-3454. DOI: 10.1016/S0040-4039(00)87639-X  0.251
1996 Richon VM, Webb Y, Merger R, Sheppard T, Jursic B, Ngo L, Civoli F, Breslow R, Rifkind RA, Marks PA. Second generation hybrid polar compounds are potent inducers of transformed cell differentiation. Proceedings of the National Academy of Sciences of the United States of America. 93: 5705-5708. PMID 8650156 DOI: 10.1073/Pnas.93.12.5705  0.251
1996 Breslow R, Sheppard TL. Why natural DNA is based on 2'-deoxyribose, with 3',5' phosphodiester links Pure and Applied Chemistry. 68: 2037-2041. DOI: 10.1351/Pac199668112037  0.25
1980 Breslow R, Bovy P, Hersh CL. Reversing the selectivity of cyclodextrin bisimidazole ribonuclease mimics by changing the catalyst geometry Journal of the American Chemical Society. 102: 2115-2117. DOI: 10.1021/Ja00526A072  0.25
1980 Breslow R, Bovy P, Hersh CL. Reversing The Selectivity Of Cyclodextrin Bisimidazole Ribonuclease Mimics By Changing The Catalyst Geometry Cheminform. 11. DOI: 10.1002/Chin.198025105  0.25
1974 BRESLOW R, CORCORAN RJ, SNIDER BB. ChemInform Abstract: REMOTE FUNCTIONALIZATION OF STEROIDS BY A RADICAL RELAY MECHANISM Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/Chin.197452447  0.25
2009 Breslow R. Reply to Bada: The relevance of meteoritic alpha-methyl amino acids to prebiotic homochirality. Proceedings of the National Academy of Sciences of the United States of America. 106. DOI: 10.1073/Pnas.0907800106  0.25
1980 Breslow R, Czarniecki MF, Emert J, Hamaguchi H. Improved acylation rates within cyclodextrin complexes from flexible capping of the cyclodextrin and from adjustment of the substrate geometry Journal of the American Chemical Society. 102: 762-770. DOI: 10.1021/Ja00522A054  0.25
1978 Breslow R, Rothbard J, Herman F, Rodriguez ML. Remote Functionalization Reactions As Conformational Probes For Flexible Alkyl Chains Cheminform. 9. DOI: 10.1002/Chin.197823098  0.249
1972 Breslow R, Hoffman JM. Antiaromaticity in the parent cyclopentadienyl cation. Reaction of 5-iodocyclopentadiene with silver ion Journal of the American Chemical Society. 94: 2110-2111. DOI: 10.1021/Ja00761A051  0.248
2013 Lee J, Choy ML, Ngo L, Venta-Perez G, Adaickapillai M, Yao Y, Breslow R, Marks PA. Abstract LB-308: Development of histone deacetylase 6 inhibitors: Effects of HDAC6 inhibitors in normal and cancer cells. Cancer Research. 73. DOI: 10.1158/1538-7445.Am2013-Lb-308  0.248
2002 Breslow R, Corcoran RJ, Snider BB, Doll RJ, Khanna PL, Kaleya R. Selective Halogenation Of Steroids Using Attached Aryl Iodide Templates Cheminform. 8. DOI: 10.1002/Chin.197717320  0.248
1990 Breslow R, Chung S. Strong binding of ditopic substrates by a doubly linked occlusive C1 clamshell as distinguished from an aversive C2 loveseat cyclodextrin dimer Journal of the American Chemical Society. 112: 9659-9660. DOI: 10.1021/Ja00182A046  0.248
1973 Breslow R, Baldwin S, Flechtner T, Kalicky P, Liu S, Washburn W. Remote oxidation of steroids by photolysis of attached benzophenone groups Journal of the American Chemical Society. 95: 3251-3262. PMID 4708826 DOI: 10.1021/Ja00791A031  0.247
1973 Breslow R, Baldwin S, Flechtner T, Kalicky P, Liu S, Washburn W. Remote Oxidation Of Steroids By Photolysis Of Attached Benzophenone Groups Cheminform. 4. DOI: 10.1002/Chin.197329427  0.247
1986 Breslow R. Artificial enzymes and enzyme models. Advances in Enzymology and Related Areas of Molecular Biology. 58: 1-60. PMID 3521215 DOI: 10.1002/9780470123041.Ch1  0.247
1974 Breslow R, Snider BB, Corcoran RJ. Letter: A cortisone synthesis using remote oxidation. Journal of the American Chemical Society. 96: 6792-4. PMID 4414092 DOI: 10.1021/Ja00828A059  0.247
1976 Breslow R, Wernick D. On the mechanism of catalysis by carboxypeptidase A Journal of the American Chemical Society. 98: 259-261. PMID 1244372 DOI: 10.1021/Ja00417A055  0.247
1962 Breslow R, Mohacsi E. Studies on d-Orbital Conjugation. II. Lack of Aromaticity in Systems Containing a Carbanion-Sulfone Double Bond Journal of the American Chemical Society. 84: 684-685. DOI: 10.1021/Ja00863A044  0.247
1976 Reuben RC, Wife RL, Breslow R, Rifkind RA, Marks PA. A new group of potent inducers of differentiation in murine erythroleukemia cells. Proceedings of the National Academy of Sciences of the United States of America. 73: 862-866. PMID 1062798 DOI: 10.1073/Pnas.73.3.862  0.247
1994 Sprecher M, Breslow R, Uziel O, Link TM. Monosubstituted 2, 2′-bipyridines Organic Preparations and Procedures International. 26: 696-701. DOI: 10.1080/00304949409458172  0.247
1979 Breslow R, Kluttz RQ, Khanna PL. Oxidative anodic tosylamidation at a vanadium electrode Tetrahedron Letters. 20: 3273-3274. DOI: 10.1016/S0040-4039(01)95382-1  0.246
1972 Breslow R. The Nature of Aromatic Molecules Scientific American. 227: 32-40. DOI: 10.1038/Scientificamerican0872-32  0.246
1986 Breslow R, Labelle M. Sequential general base-acid catalysis in the hydrolysis of RNA by imidazole Journal of the American Chemical Society. 108: 2655-2659. DOI: 10.1021/Ja00270A025  0.245
1971 Breslow R, Scholl PC. Selektive Ox. Inaktiver Methylengruppen Durch Reagenz-Substrat-Orientierung In Gemischten Komplexen Cheminform. 2. DOI: 10.1002/Chin.197131176  0.245
2011 Breslow R. Erratum to “The origin of homochirality in amino acids and sugars on prebiotic Earth” [Tetrahedron Letters 52 (2011) 2028-2032] Tetrahedron Letters. 52: 4227. DOI: 10.1016/J.Tetlet.2011.06.001  0.245
1973 Benson RC, Flygare WH, Oda M, Breslow R. Microwave spectrum, substitutional structure, and Stark and Zeeman effects in cyclopropenone Journal of the American Chemical Society. 95: 2772-2777. DOI: 10.1021/Ja00790A004  0.245
1958 Breslow R, Yuan C. The sym-Triphenylcyclopropenyl Cation, a Novel Aromatic System1 Journal of the American Chemical Society. 80: 5991-5994. DOI: 10.1021/Ja01555A026  0.244
1976 Breslow R, Khanna P. Additions and Corrections - An Intramolecular Model for the Enzymatic Insertion of Coenzyme B12into Unactivated Carbon-Hydrogen Bonds Journal of the American Chemical Society. 98: 6765-6765. DOI: 10.1021/Ja00437A610  0.244
1990 Breslow R, Berger D, Huang DL. Bifunctional zinc-imidazole and zinc-thiophenol catalysts Journal of the American Chemical Society. 112: 3686-3687. DOI: 10.1021/Ja00165A079  0.244
1970 Breslow R, Washburn W. Antiaromatische Destabilisierung Des Cyclobutadienocyclopentadienyl-Anions Cheminform. 1. DOI: 10.1002/Chin.197017026  0.244
1993 Breslow R, Graff A. Geometry of enolization using a bifunctional cyclodextrin-based catalyst Journal of the American Chemical Society. 115: 10988-10989. DOI: 10.1021/Ja00076A066  0.242
2002 Breslow R, Pandey PS. A novel synthesis of aryl orthoesters: trimethyl m-iodoorthobenzoate Cheminform. 11. DOI: 10.1002/Chin.198025180  0.242
1980 Breslow R, Pandey PS. A novel synthesis of aryl orthoesters: trimethyl m-iodoorthobenzoate Journal of Organic Chemistry. 45: 740-741. DOI: 10.1021/Jo01292A046  0.242
1974 Breslow R, Drury RF. Trapping of electrochemically generated cyclopropenyl and cycloheptatrienyl anions by charged reagents Journal of the American Chemical Society. 96: 4702-4703. DOI: 10.1021/Ja00821A072  0.242
1974 Breslow R, Drury RF. Trapping of electrochemically generated cyclopropenyl and cycloheptatrienyl anions by charged reagents Cheminform. 5. DOI: 10.1002/Chin.197438094  0.242
1967 Breslow R, Fairweather R, Keana J. Metal-Catalyzed Hydration of Phenanthroline Nitrile Journal of the American Chemical Society. 89: 2135-2138. DOI: 10.1021/Ja00985A027  0.242
1988 Breslow R, Guo T. Diels-Alder reactions in nonaqueous polar solvents. Kinetic effects of chaotropic and antichaotropic agents and of .beta.-cyclodextrin Journal of the American Chemical Society. 110: 5613-5617. DOI: 10.1021/Ja00225A003  0.242
1962 Breslow R, Barrett E, Mohacsi E. Free radical additions to squalene Tetrahedron Letters. 3: 1207-1211. DOI: 10.1016/S0040-4039(00)70586-7  0.241
1972 Breslow R, Napierski J, Schmidt AH. Unsymmetrical substituent effects on the antiaromatic transition state for the rearrangement of bicyclo[2.2.0]hexadiene to benzene Journal of the American Chemical Society. 94: 5906-5907. DOI: 10.1021/Ja00771A068  0.241
1960 Breslow R, Höver H. The Synthesis Of The Dipropylcyclopropenium Ion Journal of the American Chemical Society. 82: 2644-2645. DOI: 10.1021/Ja01495A065  0.24
1992 Breslow R, Duggan PJ, Light JP. Cyclodextrin-B12, a potential enzyme-coenzyme mimic. Journal of the American Chemical Society. 114: 3982-3983. DOI: 10.1021/Ja00036A059  0.238
1986 Breslow R, Mehta MP. Correction. A Novel Bifunctional Chlorination Mechanism in Template Catalyzed Driected Functionalization with High Effective Molarities and Rates Approaching Diffusion Control Journal of the American Chemical Society. 108: 6418-6420. DOI: 10.1021/Ja00239A602  0.238
1976 SNIDER BB, CORCORAN RJ, BRESLOW R. ChemInform Abstract: REMOVAL OF THE STEROID SIDE CHAIN USING REMOTE OXIDATION. CONVERSION OF 3β-CHOLESTANOL TO ANDROSTERONE ACETATE Chemischer Informationsdienst. 7: no-no. DOI: 10.1002/Chin.197602334  0.238
1976 Breslow R, Khanna PL. Letter: An intramolecular model for the enzymatic insertion of coenzyme B12 into unactivated carbon-hydrogen bonds. Journal of the American Chemical Society. 98: 1297-1299. PMID 1249362 DOI: 10.1021/Ja00421A060  0.237
1974 Breslow R, Corcoran RJ, Snider BB. Letter: Remote functionalization of steroids by a radical relay mechanism. Journal of the American Chemical Society. 96: 6791-2. PMID 4414371 DOI: 10.1021/Ja00828A058  0.237
1960 Breslow R, McNelis E. On The Mechanism Of Thiamine Action. Vi.1 2-Acetylthiazolium Salts As “Active Acetate” Journal of the American Chemical Society. 82: 2394-2395. DOI: 10.1021/Ja01494A070  0.237
2007 Marks PA, Breslow R. Dimethyl sulfoxide to vorinostat: development of this histone deacetylase inhibitor as an anticancer drug Nature Biotechnology. 25: 84-90. PMID 17211407 DOI: 10.1038/Nbt1272  0.236
1975 Breslow R, Mcclure DE, Brown RS, Eisenach J. Very Fast Zinc‐Catalyzed Hydrolysis Of An Anhydride, A Model For The Rate And Mechanism Of Carboxypeptidase A Catalysis Cheminform. 6. DOI: 10.1002/Chin.197513121  0.236
1970 Breslow R, Baldwin SW. Conversion of cholestanol to 12-oxocholestanol and to cholest-14-enol and-8(14)-enol by remote oxidation Journal of the American Chemical Society. 92: 732-734. DOI: 10.1021/Ja00706A068  0.236
1996 Breslow R, Connors R. Antihydrophobic Cosolvent Effects Detect Two Different Geometries for an SN2 Displacement and the Change to a Single-Electron-Transfer Mechanism in Related Cases Journal of the American Chemical Society. 118: 6323-6324. DOI: 10.1021/Ja960868I  0.236
1986 Breslow R. Approaches to artificial enzymes. Annals of the New York Academy of Sciences. 471: 60-69. PMID 3460500 DOI: 10.1111/J.1749-6632.1986.Tb48026.X  0.236
1980 Breslow R, Hammond M, Lauer M. Selective transamination and optical induction by a .beta.-cyclodextrin-pyridoxamine artificial enzyme Journal of the American Chemical Society. 102: 421-422. DOI: 10.1021/Ja00521A093  0.236
1961 Breslow R, Mohacsi E. STUDIES ON d-ORBITAL CONJUGATION. I. THE ABSENCE OF A THROUGH-CONJUGATION EFFECT IN SOME SULFONE CARBANIONS Journal of the American Chemical Society. 83: 4100-4101. DOI: 10.1021/Ja01480A039  0.235
2009 Breslow R. Biomimetic chemistry: biology as an inspiration. Journal of Biological Chemistry. 284: 1337-1342. PMID 18784073 DOI: 10.1074/Jbc.X800011200  0.235
1982 Breslow R. Stable 4n pi electron triplet molecules Pure and Applied Chemistry. 54: 927-938. DOI: 10.1351/Pac198254050927  0.234
1975 Breslow R, Johnson RW, Krebs A. Electrochemical oxidation and reduction of a tetraalkylated cyclobutadiene Tetrahedron Letters. 16: 3443-3446. DOI: 10.1016/S0040-4039(00)91378-9  0.233
1989 Batra R, Breslow R. The radical relay chlorination of flexible nicotinate esters Heterocycles. 28: 23-28. DOI: 10.3987/Com-88-S8  0.233
1961 Breslow R, Kivelevich D. Structure of Distyrinic Acid Journal of Organic Chemistry. 26: 679-681. DOI: 10.1021/Jo01062A008  0.232
1981 Breslow R, Rajagopalan R, Schwarz J. Selective functionalization of doubly coordinated flexible chains Journal of the American Chemical Society. 103: 2905-2907. DOI: 10.1021/Ja00400A088  0.232
1981 Breslow R, Rajagopalan R, Schwarz J. Selective functionalization of doubly coordinated flexible chains Cheminform. 12. DOI: 10.1002/Chin.198135164  0.232
1966 Hyde JS, Breslow R, DeBoer C. Observation of Conformational Isomers by Electron Nuclear Double Resonance Journal of the American Chemical Society. 88: 4763-4764. DOI: 10.1021/Ja00972A066  0.232
1988 Thiem HJ, Brandl M, Breslow R. Molecular modeling calculations on the acylation of .beta.-cyclodextrin by ferrocenylacrylate esters Journal of the American Chemical Society. 110: 8612-8616. DOI: 10.1021/Ja00234A006  0.231
1973 BENSON RC, FLYGARE WH, ODA M, BRESLOW R. ChemInform Abstract: MIKROWELLENSPEKTRUM, SUBSTITUTIONELLE STRUKTUR UND STARK- SOWIE ZEEMAN-EFFEKT VON CYCLOPROPENON Chemischer Informationsdienst. 4: no-no. DOI: 10.1002/Chin.197327066  0.231
1998 Richon VM, Emiliani S, Verdin E, Webb Y, Breslow R, Rifkind RA, Marks PA. A class of hybrid polar inducers of transformed cell differentiation inhibits histone deacetylases. Proceedings of the National Academy of Sciences of the United States of America. 95: 3003-7. PMID 9501205 DOI: 10.1073/Pnas.95.6.3003  0.231
1967 Deboer C, Breslow R. The photosensitized dimerization of 1,2,3-triphenylcyclopropene Tetrahedron Letters. 8: 1033-1038. DOI: 10.1016/S0040-4039(00)90631-2  0.23
1975 Snider BB, Corcoran RJ, Breslow R. Letter: Removal of the steroid side chain using remote oxidation. Conversion of 3beta-cholestranol to androsterone acetate. Journal of the American Chemical Society. 97: 6580-1. PMID 1102590 DOI: 10.1021/Ja00855A050  0.23
1989 Marks PA, Breslow R, Rifkind RA, Ngo L, Singh R. Polar/apolar chemical inducers of differentiation of transformed cells: strategies to improve therapeutic potential Proceedings of the National Academy of Sciences of the United States of America. 86: 6358-6362. PMID 2762329 DOI: 10.1073/Pnas.86.16.6358  0.23
1974 Breslow R, Murayama D, Drury R, Sondheimer F. Electrochemistry of some tetradehydro[18]annulenediones Journal of the American Chemical Society. 96: 249-251. DOI: 10.1021/Ja00808A041  0.23
1971 Breslow R, Kalicky P. Entfernte Ox. In Steroiden Durch Reagenzien, Die An Ring D Gebunden Sind, Einfuehrung Einer 9(11)-Doppelbindung Cheminform. 2. DOI: 10.1002/Chin.197140194  0.229
1998 Breslow R. Biomimetic Chemistry : A Frontier At The Chemistry/Biology Interface Chemistry & Biology. 5. PMID 9495828 DOI: 10.1016/S1074-5521(98)90138-7  0.228
1996 Breslow R, Zhang B. Cholesterol Recognition And Binding By Cyclodextrin Dimers Journal of the American Chemical Society. 118: 8495-8496. DOI: 10.1021/Ja961567B  0.228
1975 Tanaka M, Levy J, Terada M, Breslow R, Rifkind RA, Marks PA. Induction of erythroid differentiation in murine virus infected eythroleukemia cells by highly polar compounds. Proceedings of the National Academy of Sciences of the United States of America. 72: 1003-1006. PMID 165480 DOI: 10.1073/Pnas.72.3.1003  0.228
1962 Breslow R, Lockhart J, Small A. The Cyclopropenylcarbinyl Cation, a Non-classical Carbonium Ion Journal of the American Chemical Society. 84: 2793-2800. DOI: 10.1021/Ja00873A030  0.227
1983 Breslow R, Schwarz J. A correlation of carbon-13 NMR and electrochemical data for benzyllithium Journal of the American Chemical Society. 105: 6795-6796. DOI: 10.1021/Ja00361A006  0.227
1968 Breslow R. Kleine antiaromatische Ringe Angewandte Chemie. 80: 573-578. DOI: 10.1002/Ange.19680801502  0.226
1998 Breslow R, Yang Z, Ching R, Trojandt G, Odobel F. Sequence Selective Binding of Peptides by Artificial Receptors in Aqueous Solution Journal of the American Chemical Society. 120: 3536-3537. DOI: 10.1021/Ja973991Y  0.226
1967 Breslow R, Chang HW, Hill R, Wasserman E. Stable Triplet States of Some Cyclopentadienyl Cations Journal of the American Chemical Society. 89: 1112-1119. DOI: 10.1021/Ja00981A015  0.225
1973 Breslow R, Chu W. Thermodynamische Bestimmung Der Pk(A)-Werte Schwacher C-H-Acider Kohlenwasserstoffe Mittels Elektrochemischer Reduktionsdaten, Triarylmethylanionen, Cycloheptatrienylanion Und Triphenyl- Und Trialkylcyclopropenylanionen Cheminform. 4. DOI: 10.1002/Chin.197329117  0.224
1979 Breslow R, Kitabatake S, Rothbard J. Photoreactions Of Charged Benzophenone With Amphiphiles In Micelles And Multicomponent Aggregates As Conformational Probes Cheminform. 10. DOI: 10.1002/Chin.197912102  0.224
1978 Breslow R, Kitabatake S, Rothbard J. Photoreactions of charged benzophenone with amphiphiles in micelles and multicomponent aggregates as conformational probes Journal of the American Chemical Society. 100: 8156-8160. DOI: 10.1021/Ja00494A022  0.224
1972 Breslow R, Hoffman JM. Solvolytic Cope rearrangements Journal of the American Chemical Society. 94: 2111-2112. DOI: 10.1021/Ja00761A052  0.224
2009 Dadosh T, Sperling J, Bryant GW, Breslow R, Shegai T, Dyshel M, Haran G, Bar-Joseph I. Plasmonic control of the shape of the Raman spectrum of a single molecule in a silver nanoparticle dimer. Acs Nano. 3: 1988-94. PMID 19534506 DOI: 10.1021/Nn900422W  0.224
1996 Maletic M, Wennemers H, McDonald DQ, Breslow R, Still WC. Selective binding of the dipeptides L-Phe-D-Pro and D-Phe-L- Pro to β- cyclodextrin Angewandte Chemie - International Edition in English. 35: 1490-1492. DOI: 10.1002/Anie.199614901  0.223
1976 Breslow R, Goodin R. An electrochemical determination of the pKa of isobutane Journal of the American Chemical Society. 98: 6076-6077. DOI: 10.1021/Ja00435A070  0.221
1990 Breslow R. Partitioning ratios and a biochemical kinetic dilemma: The pH dependence of chymotrypsin catalysis Journal of Chemical Education. 67: 228. DOI: 10.1021/Ed067P228  0.221
1970 Breslow R, Baldwin SW. Ueberfuehrung Von Cholestanol In 12-Oxo-Cholestanol Und In Delta(14)- Und Delta(8(14))-Cholestenol Durch ′Fern′-Ox. Cheminform. 1. DOI: 10.1002/Chin.197018139  0.22
1957 Breslow R. Rapid Deuterium Exchange In Thiazolium Salts1 Journal of the American Chemical Society. 79: 1762-1763. DOI: 10.1021/Ja01564A064  0.22
1968 Kispert LD, Hyde JS, De Boer C, LaFollette D, Breslow R. Combined endor [electron-nuclear double resonance] and electron paramagnetic resonance techniques in a study of some low-symmetry triphenylmethyl derivatives The Journal of Physical Chemistry. 72: 4276-4284. DOI: 10.1021/J100858A057  0.219
1989 Breslow R. 4n PI electron triplet species and their potential use in organic ferromagnets Molecular Crystals and Liquid Crystals. 176: 199-210. DOI: 10.1080/00268948908037480  0.219
1958 Breslow R. On the Mechanism of Thiamine Action. IV.1 Evidence from Studies on Model Systems Journal of the American Chemical Society. 80: 3719-3726. DOI: 10.1021/Ja01547A064  0.218
1972 Breslow R, Napierski J, Schmidt AH. Unsymm. Substituenteneinfluesse Auf Den Antiaromatischen Uebergangszustand Bei Der Umlagerung Von Bicyclo(2,2,0)Hexadien Zu Benzol Cheminform. 3. DOI: 10.1002/Chin.197244155  0.218
1968 Breslow R, Kaplan L, LaFollette D. Carbonium ions with multiple neighboring groups. II. Physical studies Journal of the American Chemical Society. 90: 4056-4064. DOI: 10.1021/Ja01017A024  0.218
1966 Breslow R. Fundamentals of carbanion chemistry (Cram, Donald J.) Journal of Chemical Education. 43. DOI: 10.1021/Ed043Pa464.1  0.218
1998 Breslow R. Bioorganic Chemistry: A Natural and Unnatural Science Journal of Chemical Education. 75: 705-705. DOI: 10.1021/Ed075P705  0.215
1985 Breslow R. Approaches to Organic Ferromagnets Molecular Crystals and Liquid Crystals. 125: 261-267. DOI: 10.1080/00268948508080105  0.214
1993 Breslow R. Molecular recognition Proceedings of the National Academy of Sciences of the United States of America. 90: 1139-1139. DOI: 10.1073/Pnas.90.4.1139  0.213
1987 Breslow R, Brandl M, Hunger J, Turro N, Cassidy K, Krogh-Jespersen K, Westbrook JD. Pyridine complexes of chlorine atoms Journal of the American Chemical Society. 109: 7204-7206. DOI: 10.1021/Ja00257A059  0.213
1970 Breslow R, Chu W. Elektrochemische Bestimmung Von Pk(A)‐Werten, Triphenylmethane Und Cycloheptatrien Cheminform. 1. DOI: 10.1002/Chin.197026111  0.212
1973 Saunders M, Berger R, Jaffe A, McBride JM, O'Neill J, Breslow R, Hoffmann JM, Perchonock C, Wasserman E. Unsubstituted cyclopentadienyl cation, a ground-state triplet Journal of the American Chemical Society. 95: 3017-3018. DOI: 10.1021/Ja00790A049  0.211
2002 Liu L, Rozenman M, Breslow R. Hydrophobic effects on rates and substrate selectivities in polymeric transaminase mimics. Journal of the American Chemical Society. 124: 12660-1. PMID 12392403 DOI: 10.1021/ja028151k  0.211
1978 Czarniecki MF, Breslow R. Very Fast acylation of .beta.-cyclodextrin by bound p-nitrophenyl ferrocinnamate Journal of the American Chemical Society. 100: 7771-7772. DOI: 10.1021/Ja00492A079  0.211
1993 Breslow R. The correct use of partitioning ratios in the derivation of rate equations Journal of Chemical Education. 70: 999-1001. DOI: 10.1021/Ed070P999.2  0.211
1969 Breslow R, Balasubramanian K. pK.alpha. of triphenylcyclopropene. Electrochemical determination of an inaccessible equilibrium constant Journal of the American Chemical Society. 91: 5182-5183. DOI: 10.1021/Ja01046A055  0.21
1970 Breslow R, Chu W. Electrochemical determinations of p Ka's. Triphenylmethanes and cycloheptatriene Journal of the American Chemical Society. 92: 2165-2165. DOI: 10.1021/Ja00710A077  0.209
1964 Breslow R, Hill R, Wasserman E. Pentachlorocyclopentadienyl Cation, a Ground-State Triplet Journal of the American Chemical Society. 86: 5349-5350. DOI: 10.1021/Ja01077A072  0.207
1971 Breslow R, Schmir M. Katalysierte Ligand-Ligand-Rk. Innerhalb Eines Gemischten Metallkomplexes Cheminform. 2. DOI: 10.1002/Chin.197148059  0.207
1983 Noble WJL, Srivastava S, Breslow R, Trainor G. Effect of pressure on two cyclodextrin-promoted ester hydrolyses Journal of the American Chemical Society. 105: 2745-2748. DOI: 10.1021/Ja00347A038  0.205
1983 Noble WJL, Srivastava S, Breslow R, Trainor G. Effect of pressure on two cyclodextrin-promoted ester hydrolyses Cheminform. 14. DOI: 10.1002/Chin.198332288  0.205
1972 Breslow R, Mcallister C. Intramolekulare Bifunktionelle Katalyse Der Esterhydrolyse Durch Metall-Ionen Und Carboxylat-Gruppe In Einem Carboxypeptidase-Modell Cheminform. 3. DOI: 10.1002/Chin.197208119  0.203
1996 Maletic M, Wennemers H, McDonald DQ, Breslow R, Still WC. Selektive Wechselwirkung der DipeptideL-Phe-D-Pro undD-Phe-L-Pro mit β-Cyclodextrin Angewandte Chemie. 108: 1594-1596. DOI: 10.1002/Ange.19961081311  0.202
1973 Oda M, Breslow R, Pecoraro J. Die Chemie Von Cyclopropenon, Rk. An Der Kohlenstoff-Kohlenstoff-Doppelbindung Cheminform. 4. DOI: 10.1002/Chin.197308193  0.202
2001 Marks PA, Richon VM, Breslow R, Rifkind RA. Histone deacetylase inhibitors as new cancer drugs. Current Opinion in Oncology. 13: 477-483. PMID 11673688 DOI: 10.1097/00001622-200111000-00010  0.201
1973 Breslow R, Oda M, Pecoraro J. Die Chemie Von Cyclopropenon, Rk. An Der Carbonylgruppe Und 1,2-Spaltungen Cheminform. 4. DOI: 10.1002/Chin.197308192  0.201
1975 Emert J, Breslow R. Modification Of The Cavity Of Beta-Cyclodextrin By Flexible Capping Journal of the American Chemical Society. 97: 670-672. DOI: 10.1021/Ja00836A050  0.2
2006 Breslow R. The mechanism of thiamine action: predictions from model experiments. Annals of the New York Academy of Sciences. 98: 445-452. PMID 13872864 DOI: 10.1111/J.1749-6632.1962.Tb30565.X  0.2
1996 Turner CR, Breslow R, Conklyn MJ, Andresen CJ, Patterson DK, Lopez-Anaya A, Owens B, Lee P, Watson JW, Showell HJ. In vitro and in vivo effects of leukotriene B4 antagonism in a primate model of asthma. The Journal of Clinical Investigation. 97: 381-7. PMID 8567958 DOI: 10.1172/Jci118426  0.198
1979 Czarniecki MF, Breslow R. Photochemical probes for model membrane structures Journal of the American Chemical Society. 101: 3675-3676. DOI: 10.1021/Ja00507A052  0.198
1962 Breslow R, Chang HW. Heptaphenylcycloheptatrienyl Anion, a Singlet with Potential Spin Degeneracy Journal of the American Chemical Society. 84: 1484-1485. DOI: 10.1021/Ja00867A025  0.197
2004 Ito T, Fudamoto Y, Fukaya A, Gat-Malureanu IM, Larkin MI, Russo PL, Savici A, Uemura YJ, Groves K, Breslow R, Hotehama K, Yamanaka S, Kyriakou P, Rovers M, Luke GM, et al. Two-dimensional nature of superconductivity in the intercalated layered systems LixHfNCl and LixZrNCl: Muon spin relaxation and magnetization measurements Physical Review B - Condensed Matter and Materials Physics. 69: 134522-1-134522-13. DOI: 10.1103/Physrevb.69.134522  0.196
1972 Breslow R, Oda M. Isolierung Und Charakterisierung Von Reinem Cyclopropenon Cheminform. 3. DOI: 10.1002/Chin.197238190  0.195
1972 Breslow R, Oda M. Additions and Corrections - The Isolation and Characterization of Pure Cyclopropenone Journal of the American Chemical Society. 94: 8647-8647. DOI: 10.1021/Ja00779A607  0.195
2001 Marks PA, Rifkind RA, Richon VM, Breslow R, Miller T, Kelly WK. Histone deacetylases and cancer: causes and therapies. Nature Reviews Cancer. 1: 194-202. PMID 11902574 DOI: 10.1038/35106079  0.195
1972 Breslow R, Hoffman JMJ. Antiaromatizitaet Des Cyclopentadienylkations, Rk. Von 5-Jod-Cyclopentadien Mit Dem Silberion Cheminform. 3. DOI: 10.1002/Chin.197224152  0.194
1975 Breslow R, Napierski J, Clarke TC. Generation and trapping of butalene Journal of the American Chemical Society. 97: 6275-6276. DOI: 10.1021/Ja00854A072  0.193
1972 Breslow R, Dale JA, Kalicky P, Liu SY, Washburn WN. Einfuehrung Einer 9(11)-Doppelbindung In Steroide Durch Selektive Radikalische Halogenierung Cheminform. 3. DOI: 10.1002/Chin.197230441  0.192
1994 Le LP, Keren A, Luke GM, Wu WD, Uemura YJ, Jenks WS, Graff A, Breslow R, Dosanjh P. μSR studies in an I2-doped phenylenediamine polymer Hyperfine Interactions. 85: 287-292. DOI: 10.1007/Bf02069436  0.19
1978 Breslow R, Doherty JB, Guillot G, Lipsey C. .beta.-Cyclodextrinylbisimidazole, a model for ribonuclease Journal of the American Chemical Society. 100: 3227-3229. DOI: 10.1021/Ja00478A052  0.189
1965 Breslow R, Kivelevich D, Mitchell MJ, Fabian W, Wendel K. Approaches to “Push-Pull” Stabilized Cyclobutadienes1 Journal of the American Chemical Society. 87: 5132-5139. DOI: 10.1021/Ja00950A027  0.187
2016 Breslow R. Physical Organic Chemistry, the Richest Chemical Science Israel Journal of Chemistry. 56: 89-90. DOI: 10.1002/Ijch.201500029  0.187
1973 Saunders M, Berger R, Jaffe A, Mcbride JM, O'neill J, Breslow R, Hoffman JMJ, Perchonock C, Wasserman E, Hutton RS, Kuck VJ. Unsubstituiertes Cyclopentadienylkation, Ein Triplett Im Grundzustand Cheminform. 4. DOI: 10.1002/Chin.197327072  0.187
1978 Breslow R, Doherty JB, Guillot G, Lipsey C. β-CYCLODEXTRINYLBISIMIDAZOLE, A MODEL FOR RIBONUCLEASE Cheminform. 9. DOI: 10.1002/Chin.197834076  0.186
1999 Marks PA, Richon VM, Breslow R, Rifkind RA. Hybrid polar inducers of transformed cell differentiation/apoptosis. From the cell to the clinic. Comptes Rendus De L Academie Des Sciences Serie Iii-Sciences De La Vie-Life Sciences. 322: 161-165. PMID 10196668 DOI: 10.1016/S0764-4469(99)80039-0  0.186
1972 Breslow R, Oda M. Isolation and characterization of pure cyclopropenone Journal of the American Chemical Society. 94: 4787-4788. DOI: 10.1021/Ja00768A089  0.18
1966 Breslow R, Altman LJ. Methylcyclopropenone and Related Compounds1 Journal of the American Chemical Society. 88: 504-509. DOI: 10.1021/Ja00955A022  0.176
1973 Lechtken P, Breslow R, Schmidt AH, Turro NJ. Thermische Umlagerung Von Dewar-Benzolen Zu Triplett-Zustaenden Des Benzols, Beispiele Fuer Spin-Verbotene Nicht Adiabatische Pericyclische Rk. Cheminform. 4. DOI: 10.1002/Chin.197327129  0.175
1992 Breslow R. Breslow replies to criticism Nature. 360: 23-23. DOI: 10.1038/360023A0  0.172
2021 Breslow R, Wei S, Kenesky C. Enantioselective Transaminations by Dendrimeric Enzyme Mimics. Tetrahedron. 63: 6317-6321. PMID 18596840 DOI: 10.1016/j.tet.2007.02.052  0.171
1984 Breslow R. A figure of modern science: a time to remember. Science. 224: 1230-1231. PMID 17819491 DOI: 10.1126/Science.224.4654.1230  0.163
1972 Breslow R, Hoffman JMJ. Solvolytische Cope-Umlagerungen Cheminform. 3. DOI: 10.1002/Chin.197224153  0.162
1996 Sheppard TL, Breslow RC. Selective binding of RNA, but not DNA, by complementary 2',5'-linked DNA Journal of the American Chemical Society. 118: 9810-9811. DOI: 10.1021/ja962184g  0.06
1996 Breslow RC. Interesting times for chemistry Chemical and Engineering News. 74: 2-3+30.  0.039
1995 Breslow RC. Layoffs of chemical professionals Chemical and Engineering News. 73: 29.  0.031
1995 Breslow RC. The education of Ph.D.s in chemistry Chemical and Engineering News. 73: 65-66.  0.031
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